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WO2024038524A1 - Fat/oil composition, food containing fat/oil composition, and method for suppressing clouding of fat/oil composition - Google Patents

Fat/oil composition, food containing fat/oil composition, and method for suppressing clouding of fat/oil composition Download PDF

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Publication number
WO2024038524A1
WO2024038524A1 PCT/JP2022/031110 JP2022031110W WO2024038524A1 WO 2024038524 A1 WO2024038524 A1 WO 2024038524A1 JP 2022031110 W JP2022031110 W JP 2022031110W WO 2024038524 A1 WO2024038524 A1 WO 2024038524A1
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Prior art keywords
oil
mass
fat
fatty acid
fat composition
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PCT/JP2022/031110
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French (fr)
Japanese (ja)
Inventor
航輝 野田
Original Assignee
日清オイリオグループ株式会社
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Application filed by 日清オイリオグループ株式会社 filed Critical 日清オイリオグループ株式会社
Priority to KR1020247010462A priority Critical patent/KR20250049983A/en
Priority to PCT/JP2022/031110 priority patent/WO2024038524A1/en
Priority to CN202280066354.9A priority patent/CN118042935A/en
Publication of WO2024038524A1 publication Critical patent/WO2024038524A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings or cooking oils characterised by ingredients other than fatty acid triglycerides
    • A23D9/013Other fatty acid esters, e.g. phosphatides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings or cooking oils
    • A23D9/007Other edible oils or fats, e.g. shortenings or cooking oils characterised by ingredients other than fatty acid triglycerides

Definitions

  • the present invention relates to an oil and fat composition whose main component is an oil and fat containing a large amount of medium-chain fatty acids as a constituent fatty acid, a food containing the oil and fat composition, and a method for suppressing cloudiness of the oil and fat composition.
  • MCTs medium chain triglycerides
  • the present invention contains oil and fat containing a specific amount of medium-chain fatty acids in all constituent fatty acids, a specific emulsifier (glycerin fatty acid ester), and tocopherol, and suppresses clouding that occurs over time.
  • the present invention aims to provide an oil and fat composition, a food containing the oil and fat composition, and a method for suppressing cloudiness of the oil and fat composition.
  • the present inventor has found that the above problem can be solved by incorporating a specific amount of tocopherol into an oil or fat containing a specific amount of medium-chain fatty acids in all constituent fatty acids and an oil or fat composition containing a glycerin fatty acid ester.
  • the present invention has been completed. Specifically, the present invention provides the following.
  • oil and fat composition according to any one of (1) to (3), wherein the oil and fat composition is used for liquid food, food for the elderly, food for people with difficulty swallowing, or nursing care food.
  • Oil and fat composition (5) A food containing the oil and fat composition according to any one of (1) to (4).
  • An oil and fat composition containing 90 to 99.8% by mass of the oil and fat, 0.1 to 9.5% by mass of the glycerin fatty acid ester, and 0.002 to 0.3% by mass of the tocopherol. How to suppress cloudiness.
  • an oil and fat composition that does not become cloudy over time or when exposed to light, and a food that contains the oil and fat composition. Furthermore, a method for suppressing cloudiness of an oil or fat composition is also provided.
  • the oil and fat composition of the present invention contains 90 to 99.8% by mass of fats and oils having a medium chain fatty acid content of 70% by mass or more in all constituent fatty acids, 0.1 to 9.5% by mass of glycerin fatty acid ester, and Contains 0.002-0.3% by mass of tocopherol.
  • the oil and fat composition of the present invention is preferably clear.
  • “clear” refers to a state in which the transmittance at 660 nm (optical path length 10 mm, reference: water) is 95% or more, for example.
  • the oil and fat composition of the present invention is preferably in a liquid state at 20°C.
  • the oil and fat composition of the present invention When the oil and fat composition of the present invention is in a liquid state at 20° C., it is easily mixed with foods, and thus can be easily mixed by hand stirring or the like. Furthermore, the oil and fat composition of the present invention has the secondary effect that even when mixed with a food with a high water content, it blends well with the composition, so separation is difficult to occur and the energy density of the food is easily increased.
  • fats and oils in which the content of medium chain fatty acids in all constituent fatty acids is 70% by mass or more are preferably medium chain fatty acid triglycerides whose constituent fatty acids are only medium chain fatty acids ( (hereinafter also referred to as MCT) and/or medium-long chain fatty acid triglyceride (hereinafter also referred to as MLCT) whose constituent fatty acids are medium chain fatty acids and long chain fatty acids.
  • MCT medium chain fatty acid triglycerides whose constituent fatty acids are only medium chain fatty acids
  • MLCT medium-long chain fatty acid triglyceride
  • medium chain fatty acids refer to fatty acids having 6 to 12 carbon atoms (preferably straight chain saturated fatty acids having 8 and 10 carbon atoms).
  • a "constituent fatty acid” means the fatty acid which comprises a glyceride, and a free fatty acid.
  • the constituent fatty acids are essentially fatty acids that constitute glycerides.
  • the free fatty acid content is preferably 1% by mass or less, more preferably 0.1% by mass or less.
  • the fat and oil of the present invention preferably has a medium chain fatty acid content of 70 to 100% by mass, more preferably 85 to 100% by mass, even more preferably 90 to 100% by mass, and most preferably 95 to 100% by mass. It is 100% by mass.
  • the oil and fat of the present invention may be a mixture of a plurality of oils and fats as long as the content of medium chain fatty acids in all constituent fatty acids is 70% by mass or more, but MCT and/or it is preferable to use only MLCT.
  • the MCT and MLCT can be obtained by esterifying medium-chain fatty acids or long-chain fatty acids derived from coconut oil or palm kernel oil and glycerin as raw materials.
  • the conditions for the esterification reaction are not particularly limited, and the reaction may be carried out under pressure without a catalyst and without a solvent, or may be carried out using a catalyst or a solvent.
  • the above-mentioned MLCT can also be obtained by a method of transesterifying MCT and fats and oils other than MCT.
  • the transesterification method is not particularly limited, and may be carried out by commonly used methods such as chemical transesterification using sodium methoxide as a catalyst or enzymatic transesterification using a lipase preparation as a catalyst.
  • the fats and oils of the present invention may contain fats and oils other than the MCT and MLCT.
  • oils and fats other than MCT and MLCT include soybean oil, rapeseed oil, sesame oil, corn oil, cottonseed oil, safflower oil, sunflower oil, cacao oil, rice bran oil, peanut oil, olive oil, perilla oil, perilla oil, Examples include linseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, tea seed oil, borage oil, cottonseed oil, wheat germ oil, and fish oil. It may also be transesterified oils and fats obtained by transesterifying two or more of these oils and fats, fractionated oils and fats of these oils and fats, and the like. The above fats and oils may be used alone or in combination of two or more.
  • the MCT content in the fat or oil of the present invention is preferably 90 to 100% by mass, more preferably 95 to 100% by mass, even more preferably 96 to 99% by mass, and most preferably Preferably it is 97 to 99% by mass.
  • the MCT content is within the above range, the effects of the present invention can be more easily achieved.
  • the content of the fat or oil in the oil or fat composition of the present invention is preferably 92 to 99.8% by mass, more preferably 94 to 99.7% by mass, even more preferably 96 to 99.6% by mass, and most preferably is 98 to 99.5% by mass.
  • the content of the oil and fat of the present invention is within the above range, the effects of the present invention are more likely to be exhibited.
  • the glycerin fatty acid ester in the present invention is a food additive glycerin fatty acid ester, and refers to a fatty acid ester having a skeleton of glycerin and/or polyglycerin (glycerin polymer). That is, the glycerin fatty acid ester may include polyglycerin fatty acid ester, glycerin organic acid fatty acid ester, and the like. Further, the constituent fatty acids of the glycerin fatty acid ester in the present invention are preferably fatty acids having 16 or more carbon atoms, and more preferably contain oleic acid.
  • the glycerin fatty acid ester in the present invention preferably contains a glycerin fatty acid ester and/or a polyglycerin fatty acid ester, more preferably a polyglycerin fatty acid ester, and most preferably a polyglycerin fatty acid ester.
  • the average degree of polymerization of the polyglycerol fatty acid ester is preferably 4 to 12, more preferably 6 to 11, and most preferably 8 to 10.
  • the average degree of polymerization is a value calculated from the hydroxyl value of polyglycerin, which is a raw material for polyglycerin fatty acid ester.
  • the HLB of the glycerin fatty acid ester in the present invention is preferably 3 to 9, more preferably 5 to 8, and most preferably 6 to 7.5.
  • HLB represents the balance between hydrophilic groups and lipophilic groups in an emulsifier, and is a numerical value determined by a known measuring method. For example, when the emulsifier is a nonionic emulsifier, the HLB value is calculated using the Atlas method.
  • S Saponification value
  • A A method of calculating the HLB value from the neutralization value of the fatty acid in the ester.
  • the glycerin fatty acid ester in the present invention may be used alone or in a combination of two or more types, but when two or more types are used in combination, the average HLB is as high as the above.
  • the range is within the range.
  • the average HLB is a value calculated by multiplying the individual HLB of the emulsifier by the mixing ratio (mass).
  • the content of the glycerin fatty acid ester in the oil and fat composition of the present invention is preferably 0.2 to 7% by mass, more preferably 0.3 to 5% by mass, even more preferably 0.4 to 3% by mass, Most preferably it is 0.5 to 1.5% by weight.
  • the content of the glycerin fatty acid ester in the present invention is within the above range, the effects of the present invention can be easily achieved, and the unpleasant taste peculiar to emulsifiers is not felt easily.
  • the oil and fat composition of the present invention preferably does not contain any emulsifier other than glycerin fatty acid ester, or the content of emulsifier other than glycerin fatty acid ester is preferably 3% by mass or less, more preferably 1% by mass. The most preferred amount is 0.5% by mass or less.
  • Tocopherol in the present invention is ⁇ -tocopherol, ⁇ -tocopherol, ⁇ -tocopherol, or ⁇ -tocopherol alone or in a mixture of two or more.
  • the tocopherol in the present invention preferably contains ⁇ -tocopherol and/or ⁇ -tocopherol, and the content of ⁇ -tocopherol and/or ⁇ -tocopherol in the total tocopherol is preferably 50% by mass or more, more preferably 70% by mass. % or more.
  • the oil and fat composition of the present invention may satisfy the desired tocopherol content by blending food raw materials (vegetable oils and fats, etc.) containing tocopherol. Furthermore, when using a tocopherol preparation as a raw material for the oil and fat composition of the present invention, the amount of the tocopherol preparation may be adjusted so that the tocopherol content in the oil and fat composition of the present invention becomes a desired content. .
  • the content of the tocopherol in the oil and fat composition of the present invention is preferably 0.003 to 0.2% by mass, more preferably 0.004 to 0.1% by mass, and even more preferably 0.006 to 0.00% by mass. 0.05% by weight, most preferably 0.008-0.025% by weight.
  • the oil and fat composition of the present invention will be more effective in suppressing clouding over time and clouding due to exposure to light.
  • the content of tocopherol in an oil and fat composition can be measured in accordance with the "Standard Oil and Fat Analysis Test Method 2.4.10-2013 Tocopherol (Fluorescence Detector - High Performance Liquid Chromatography Method)" established by the Japan Oil Chemists' Society. can.
  • the oil and fat composition of the present invention may contain pigments, vitamins, fragrances, etc. as long as they do not impair the effects of the present invention.
  • the oil and fat composition of the present invention preferably contains 0.2 to 5 parts by mass, more preferably 0.3 to 4 parts by mass, and even more preferably 0.2 to 5 parts by mass, and even more preferably 0.2 to 5 parts by mass of the tocopherol per 100 parts by mass of the glycerin fatty acid ester. It contains 5 to 3.5 parts by weight, most preferably 0.7 to 2.5 parts by weight. When the content of tocopherol relative to the glycerin fatty acid ester is within the above range, the oil and fat composition of the present invention has an excellent effect of suppressing clouding over time and clouding due to exposure to light.
  • the oil and fat composition of the present invention can be used as a liquid food.
  • the oil and fat composition of the present invention can be added or included in liquid foods provided at elderly facilities, hospitals, etc. in an amount that can supplement desired energy.
  • the content of the oil and fat composition of the present invention in the liquid food is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass.
  • the energy density can be increased by about 1.5 to 2 times.
  • the oil and fat composition of the present invention can be used as food for the elderly.
  • the oil and fat composition of the present invention can be added or contained in foods for the elderly (soft foods, etc.) in an amount that can supplement desired energy.
  • the content of the oil and fat composition of the present invention is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. It is.
  • the energy density can be increased by about 1.5 to 2 times.
  • the term "elderly people" in the present invention refers to people over 60 years old, preferably over 65 years old, and more preferably over 70 years old.
  • the oil and fat composition of the present invention can be used for foods for people with swallowing difficulties.
  • the oil and fat composition of the present invention can be added or contained in foods for people with swallowing difficulties (such as kizami food) in an amount that can supplement desired energy.
  • the content of the oil and fat composition of the present invention in the food is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass.
  • the energy density can be increased by about 1.5 to 2 times.
  • a dysphagic person in the present invention refers to a person who has some difficulty in swallowing. Examples include elderly people with reduced swallowing ability, and people with cranial nerve disease or oral disease.
  • the food for people with swallowing difficulties according to the present invention has low adhesiveness and is therefore easy for people with swallowing problems to ingest.
  • the food for people with dysphagia in the present invention may be a food that satisfies the "standards for approval of labeling as food for people with dysphagia" stipulated by the Ministry of Health, Labor and Welfare.
  • the oil and fat composition of the present invention can be used as a nursing food.
  • the oil and fat composition of the present invention can be added or contained in nursing care foods in an amount that can supplement desired energy.
  • the content of the oil and fat composition of the present invention is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. %.
  • the energy density can be increased by about 1.5 to 2 times.
  • Nursing care food in the present invention refers to food for people who require nursing care in hospital facilities or at home.
  • a food containing the fat and oil composition of the present invention (hereinafter also referred to as a food of the present invention) is a food that has an increased energy density by containing the fat and oil composition of the present invention, and preferably has an increased energy density. It is a food product that is 1.5 to 2 times more expensive. Since the food of the present invention has a high energy density, desired energy can be supplied with a small amount of intake.
  • the food of the present invention may be, for example, the above liquid food, food for the elderly, food for people with difficulty swallowing, or food used as nursing care food.
  • the food of the present invention preferably has a water content (moisture) of 60% by mass or more, more preferably 65 to 99% by mass, even more preferably 65 to 95% by mass, and most preferably 70 to 90% by mass based on the whole food. %.
  • the moisture content in the food can be determined by a conventional loss on drying method.
  • the above-mentioned foods include staple foods (rice, soft rice, porridge, ojiya, etc.), side dishes (soaked dishes, marinated dishes, boiled dishes, vinegared dishes, etc.), soups (miso soup, soup, etc.), and beverages (water, tea, coffee, milk, etc.).
  • swallowing-adjusting foods foods with thickening agents added to beverages, soups, etc.
  • chopped foods foods prepared so that they are easy to chew and swallow
  • mixer foods foods prepared in a blender to make them into a paste
  • it is a staple food or a side dish.
  • the oil and fat composition of the present invention can be in any commercial form.
  • the product form refers to the form taken when transporting, storing, and selling the oil and fat composition itself.
  • the product form of the oil and fat composition of the present invention can be, for example, a glass bottle, a plastic bottle, a pillow package, or the like. Since the oil and fat composition of the present invention suppresses the occurrence of cloudiness even when exposed to light, it can be filled into a container at least partially transparent.
  • the term "container at least partially transparent to light” refers to a container in which at least a portion of the container is transparent enough to allow the contents to be visually confirmed under a fluorescent lamp. Specifically, examples include containers in which part or all of the container is made of materials such as uncolored PET, uncolored Laminated-container, and uncolored glass. .
  • the method of suppressing cloudiness of an oil or fat composition containing a glycerin fatty acid ester and an oil or fat having a medium-chain fatty acid content of 70% by mass or more in all the constituent fatty acids of the present invention (hereinafter also referred to as the method of suppressing cloudiness of the present invention). ) contains tocopherol in the fat/oil composition, containing 90 to 99.8% by mass of the fat, 0.1 to 9.5% by mass of glycerin fatty acid ester, and 0.002 to 0.3% by mass of tocopherol.
  • the "method for suppressing white turbidity" of the present invention means that when stored for a long time under light exposure, no cloudiness is observed in the oil and fat composition, and the same clear appearance is obtained compared to the oil and fat composition before long-term storage. It refers to the method of maintaining.
  • “clear” refers to a state in which the transmittance at 660 nm (optical path length 10 mm, reference: water) is 95% or more, for example.
  • under light exposure refers to a state where the product is stored under illuminance of 1000 lux or more for 12 hours or more a day.
  • long-term storage refers to a state in which 4 weeks or more have passed at room temperature (1 to 30°C) after the production of the fat or oil in the present invention.
  • oil and fat composition of the present invention In the method for suppressing white turbidity of the present invention, preferred embodiments, contents, etc. of the oil and fat, glycerin fatty acid ester, and tocopherol are the same as in the above-mentioned "oil and fat composition of the present invention.”
  • preferably 0.2 to 5 parts by mass, more preferably 0.3 to 4 parts by mass of tocopherol are added to 100 parts by mass of glycerin fatty acid ester in the oil or fat composition. , even more preferably 0.5 to 3.5 parts by weight, most preferably 0.7 to 2.5 parts by weight.
  • the oil and fat composition of the present invention has an excellent effect of suppressing clouding over time and clouding due to exposure to light.
  • ⁇ Rapeseed oil product name: Nissin Canola Oil, manufactured by Nisshin Oilli Group Co., Ltd.
  • ⁇ Glycerin fatty acid ester product name: Ryoto Polyglyester O-50D (decaglycerin oleate ester, HLB7), manufactured by Mitsubishi Chemical Foods Co., Ltd.
  • ⁇ Tocopherol preparation 1 (trade name: Tocopherol 80, manufactured by Nisshin Oillio Group Co., Ltd., total tocopherol content 80% by mass (out of total tocopherols, ⁇ -tocopherol content 70% by mass))
  • ⁇ Tocopherol preparation 2 trade name: Emix D, manufactured by Eisai Food Chemical Co., Ltd.
  • TOC/GSF ⁇ 100 in Tables 1 and 2 refers to parts by mass of tocopherol based on 100 parts by mass of glycerin fatty acid ester.
  • Transmittance (%) in Tables 1 and 2 refers to the transmittance (%) after storage for 12 weeks.
  • TOC/GSF ⁇ 100 in Tables 3 and 4 refers to parts by mass of tocopherol based on 100 parts by mass of glycerin fatty acid ester.
  • Transmittance (%) in Tables 3 and 4 refers to the transmittance (%) after storage for 12 weeks.
  • oil and fat compositions containing MCT as a base oil, 0.5 to 6% by mass of glycerin fatty acid ester, and 0.004 to 0.16% by mass of tocopherol Examples 5 to 11
  • the occurrence of cloudiness was suppressed during storage under light exposure.
  • the soft rice containing the oil and fat composition of the present invention produced above, 150 g was poured into a bowl, and after 5 minutes, the appearance of the soft rice and the condition of the wall of the bowl were visually observed, and no oil separation was observed. Therefore, the soft rice described above could be suitably used as a food for the elderly.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Edible Oils And Fats (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

The present invention addresses the problem of providing: a fat/oil composition that contains a fat/oil containing a specific amount of medium-chain fatty acids among all constituent fatty acids, a glycerin fatty acid ester, and tocopherol and that has suppressed development of clouding; a food containing the fat/oil composition; and a method for suppressing clouding of the fat/oil composition. The present invention is a fat/oil composition that contains 90-99.8 mass% of a fat/oil having a medium-chain fatty acid content of 70 mass% or more among all constituent fatty acids, 0.1-9.5 mass% of a glycerin fatty acid ester, and 0.002-0.3 mass% of tocopherol.

Description

油脂組成物、油脂組成物を含む食品、及び油脂組成物の白濁の抑制方法Oil and fat compositions, foods containing oil and fat compositions, and methods for suppressing cloudiness of oil and fat compositions

 本発明は、構成脂肪酸として中鎖脂肪酸を多く含有する油脂を主成分とする油脂組成物、該油脂組成物を含む食品、及び該油脂組成物の白濁の抑制方法に関する。 The present invention relates to an oil and fat composition whose main component is an oil and fat containing a large amount of medium-chain fatty acids as a constituent fatty acid, a food containing the oil and fat composition, and a method for suppressing cloudiness of the oil and fat composition.

 高齢者や術後患者は、食事の摂取量を増やせない、又は食事量が制限されるため、少量で高エネルギーの食事を摂取することが重要である。そして、1食当たりのエネルギー密度を上げるためには、糖質やたんぱく質と比べて、エネルギー価の高い油脂を含有する食品を摂取することが有効である。
 油脂の中でも、中鎖脂肪酸トリグリセリド(Medium Chain Triglyceride、MCT)は、消化吸収にすぐれ、エネルギーになりやすことから、高齢者や術後患者向けの食品の原料油脂に汎用されている。
Elderly people and post-surgery patients cannot increase their food intake or have a limited amount of food, so it is important for them to consume small amounts of high-energy food. In order to increase the energy density per meal, it is effective to consume foods containing fats and oils that have a higher energy value than carbohydrates and proteins.
Among fats and oils, medium chain triglycerides (MCTs) are widely used as raw material fats and oils for foods for the elderly and post-surgery patients because they are easily digested and absorbed and can be easily converted into energy.

 高齢者施設、介護施設等の現場では、対象者ごとに摂取カロリーのコントロールが必要になるため、出来上がった食事に対して、個別に必要量の油脂を添加する作業が行われている。したがって、後から添加することでカロリー調整ができる油脂が望まれている。しかし、水分の多い食品に油脂を添加する場合は、油脂の分離が起こりやすいため、食事の際に、分離した油脂が食器の壁面や、ドリップ(残り汁)に残存して所望の量の油脂を摂取できない問題があった。
 この問題を解決するために、油脂に乳化剤を配合し、水分の多い食品との馴染みを改善する必要があったが、中鎖脂肪酸トリグリセリドと乳化剤を配合した油脂組成物の場合、経時的に、該油脂組成物が白濁するなどの品質面で問題が生じた。そしてこの白濁は、曝光により顕著に発生した。
In facilities such as elderly facilities and nursing care facilities, it is necessary to control the calorie intake of each subject, so the necessary amount of fats and oils is added to each individual's prepared meals. Therefore, there is a demand for fats and oils that can be added later to adjust the calorie content. However, when fats and oils are added to foods with a high water content, separation of fats and oils tends to occur, so when eating, the separated fats and oils remain on the walls of dishes and drips (remaining juices), and the desired amount of fats and oils is obtained. There was a problem with not being able to take it.
In order to solve this problem, it was necessary to blend emulsifiers into fats and oils to improve compatibility with foods with a high water content. Quality problems arose, such as the oil and fat composition becoming cloudy. This clouding significantly occurred due to exposure to light.

 これまで、出来上がった食事に対して、後から添加することでカロリー調整ができる油脂組成物として、特定の固体脂含有量(SFC)を有する嚥下・咀嚼困難者用食品の摂食補助用油脂組成物が報告されている。しかし、上記の白濁の問題の解決方法についての報告はなかった。 Until now, oil and fat compositions for feeding aids for foods for people with swallowing and chewing difficulties that have a specific solid fat content (SFC) have been developed as oil and fat compositions that can be added later to the finished meal to adjust calories. things have been reported. However, there has been no report on how to solve the above clouding problem.

特開2012-70722号公報Japanese Patent Application Publication No. 2012-70722

 本発明は、上記の問題を鑑み、全構成脂肪酸中に特定量の中鎖脂肪酸を含有する油脂、特定の乳化剤(グリセリン脂肪酸エステル)、及びトコフェロールを含有し、経時的に発生する白濁が抑制された油脂組成物、該油脂組成物を含む食品、並びに、該油脂組成物の白濁の抑制方法の提供を目的とする。 In view of the above problems, the present invention contains oil and fat containing a specific amount of medium-chain fatty acids in all constituent fatty acids, a specific emulsifier (glycerin fatty acid ester), and tocopherol, and suppresses clouding that occurs over time. The present invention aims to provide an oil and fat composition, a food containing the oil and fat composition, and a method for suppressing cloudiness of the oil and fat composition.

 本発明者は、全構成脂肪酸中に特定量の中鎖脂肪酸を含有する油脂、及びグリセリン脂肪酸エステルを含有する油脂組成物に対して、特定量のトコフェロールを含有させることにより上記課題を解決できることを見出し、本発明を完成した。具体的に本発明は以下を提供する。 The present inventor has found that the above problem can be solved by incorporating a specific amount of tocopherol into an oil or fat containing a specific amount of medium-chain fatty acids in all constituent fatty acids and an oil or fat composition containing a glycerin fatty acid ester. The present invention has been completed. Specifically, the present invention provides the following.

(1)全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂を90~99.8質量%、グリセリン脂肪酸エステルを0.1~9.5質量%、及びトコフェロールを0.002~0.3質量%含有する油脂組成物。
(2)前記油脂が中鎖脂肪酸トリグリセリドを含有する(1)に記載の油脂組成物。
(3)前記グリセリン脂肪酸エステルがポリグリセリン脂肪酸エステルを含有する(1)又は(2)に記載の油脂組成物。
(4)前記油脂組成物が、流動食用、高齢者向け食品用、嚥下困難者向け食品用、又は介護食用の用途で使用される、(1)~(3)のいずれか1つに記載の油脂組成物。
(5)(1)~(4)のいずれか1つに記載の油脂組成物を含有する食品。
(6)前記食品の水分が60質量%以上である(5)に記載の食品。
(7)全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂、及びグリセリン脂肪酸エステルを含有する油脂組成物の白濁の抑制方法であって、該油脂組成物において、トコフェロールを含有させて、該油脂を90~99.8質量%、該グリセリン脂肪酸エステルを0.1~9.5質量%、及び該トコフェロールを0.002~0.3質量%含有することによる、油脂組成物の白濁の抑制方法。
(8)前記グリセリン脂肪酸エステル100質量部に対して前記トコフェロールを0.2~5質量部含有させることによる(7)に記載の油脂組成物の白濁の抑制方法。
(1) 90 to 99.8 mass % of fats and oils with a medium chain fatty acid content of 70 mass % or more in all constituent fatty acids, 0.1 to 9.5 mass % of glycerin fatty acid ester, and 0.002 mass % of tocopherol. An oil and fat composition containing ~0.3% by mass.
(2) The oil or fat composition according to (1), wherein the oil or fat contains medium chain fatty acid triglyceride.
(3) The oil or fat composition according to (1) or (2), wherein the glycerin fatty acid ester contains a polyglycerin fatty acid ester.
(4) The oil and fat composition according to any one of (1) to (3), wherein the oil and fat composition is used for liquid food, food for the elderly, food for people with difficulty swallowing, or nursing care food. Oil and fat composition.
(5) A food containing the oil and fat composition according to any one of (1) to (4).
(6) The food according to (5), wherein the moisture content of the food is 60% by mass or more.
(7) A method for suppressing cloudiness of an oil or fat composition containing a glycerin fatty acid ester and an oil or fat whose medium-chain fatty acid content in all constituent fatty acids is 70% by mass or more, wherein the oil or fat composition contains tocopherol. An oil and fat composition containing 90 to 99.8% by mass of the oil and fat, 0.1 to 9.5% by mass of the glycerin fatty acid ester, and 0.002 to 0.3% by mass of the tocopherol. How to suppress cloudiness.
(8) The method for suppressing cloudiness of an oil or fat composition according to (7), by containing 0.2 to 5 parts by mass of the tocopherol per 100 parts by mass of the glycerin fatty acid ester.

 本発明によれば、経時的な白濁や、曝光による白濁が起こらない油脂組成物、及び該油脂組成物を含有する食品が提供される。また、油脂組成物の白濁の抑制方法も提供される。 According to the present invention, there are provided an oil and fat composition that does not become cloudy over time or when exposed to light, and a food that contains the oil and fat composition. Furthermore, a method for suppressing cloudiness of an oil or fat composition is also provided.

〔油脂組成物〕
 本発明の油脂組成物は、全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂を90~99.8質量%、グリセリン脂肪酸エステルを0.1~9.5質量%、及びトコフェロールを0.002~0.3質量%含有する。
 本発明の油脂組成物は、澄明であることが好ましい。ここで、「澄明」とは、例えば660nm(光路長10mm、対照:水)の透過率が95%以上の状態を指す。また、本発明の油脂組成物は、20℃で液状の態様が好ましい。本発明の油脂組成物が20℃で液状の態様であると、食品と混ざりやすいため手撹拌等で容易に混合することができる。また、本発明の油脂組成物は、水分の多い食品と混合しても、よく馴染むため分離が起き難く、該食品のエネルギー密度を高めやすいという、副次的な効果も有する。
[Oil composition]
The oil and fat composition of the present invention contains 90 to 99.8% by mass of fats and oils having a medium chain fatty acid content of 70% by mass or more in all constituent fatty acids, 0.1 to 9.5% by mass of glycerin fatty acid ester, and Contains 0.002-0.3% by mass of tocopherol.
The oil and fat composition of the present invention is preferably clear. Here, "clear" refers to a state in which the transmittance at 660 nm (optical path length 10 mm, reference: water) is 95% or more, for example. Further, the oil and fat composition of the present invention is preferably in a liquid state at 20°C. When the oil and fat composition of the present invention is in a liquid state at 20° C., it is easily mixed with foods, and thus can be easily mixed by hand stirring or the like. Furthermore, the oil and fat composition of the present invention has the secondary effect that even when mixed with a food with a high water content, it blends well with the composition, so separation is difficult to occur and the energy density of the food is easily increased.

〔全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂〕
 本発明における全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂(以下、本発明の油脂ともいう。)は、好ましくは構成脂肪酸が中鎖脂肪酸のみからなる中鎖脂肪酸トリグリセリド(以下、MCTともいう。)を含有する油脂、及び/又は、構成脂肪酸が中鎖脂肪酸と長鎖脂肪酸からなる中長鎖脂肪酸トリグリセリド(以下、MLCTともいう。)を含有する。ここで、中鎖脂肪酸とは、炭素数が6~12の脂肪酸(好ましくは炭素数が8及び10の直鎖飽和脂肪酸)を指す。
 なお、本発明において、「構成脂肪酸」とは、グリセリドを構成する脂肪酸と、遊離脂肪酸を意味する。一般的に、油脂のほとんどは、グリセリドであり、遊離脂肪酸をほとんど含まないため、構成脂肪酸は実質的にグリセリドを構成する脂肪酸である。なお、遊離脂肪酸は好ましくは1質量%以下、より好ましくは0.1質量%以下である。
[Oils and fats whose medium-chain fatty acid content in all constituent fatty acids is 70% by mass or more]
In the present invention, fats and oils in which the content of medium chain fatty acids in all constituent fatty acids is 70% by mass or more (hereinafter also referred to as fats and oils of the present invention) are preferably medium chain fatty acid triglycerides whose constituent fatty acids are only medium chain fatty acids ( (hereinafter also referred to as MCT) and/or medium-long chain fatty acid triglyceride (hereinafter also referred to as MLCT) whose constituent fatty acids are medium chain fatty acids and long chain fatty acids. Here, medium chain fatty acids refer to fatty acids having 6 to 12 carbon atoms (preferably straight chain saturated fatty acids having 8 and 10 carbon atoms).
In addition, in this invention, a "constituent fatty acid" means the fatty acid which comprises a glyceride, and a free fatty acid. Generally, most of fats and oils are glycerides and contain almost no free fatty acids, so the constituent fatty acids are essentially fatty acids that constitute glycerides. Note that the free fatty acid content is preferably 1% by mass or less, more preferably 0.1% by mass or less.

 本発明の油脂は、全構成脂肪酸中の中鎖脂肪酸含有量が、好ましくは70~100質量%、より好ましくは85~100質量%、さらにより好ましくは90~100質量%、最も好ましくは95~100質量%である。また、本発明の油脂は、全構成脂肪酸中の中鎖脂肪酸の含量が70質量%以上であれば、複数の油脂の混合油であってもよいが、速やかにエネルギー補給ができる点から、MCT及び/又はMLCTのみを用いることが好ましい。
 なお、本発明の油脂の構成脂肪酸を確認、定量する方法としては、例えば、日本油化学会制定「基準油脂分析試験法 2.4.2.3-2013 脂肪酸組成(キャピラリーガスクロマトグラフ法)」に準拠して定量分析する方法が挙げられる。
The fat and oil of the present invention preferably has a medium chain fatty acid content of 70 to 100% by mass, more preferably 85 to 100% by mass, even more preferably 90 to 100% by mass, and most preferably 95 to 100% by mass. It is 100% by mass. In addition, the oil and fat of the present invention may be a mixture of a plurality of oils and fats as long as the content of medium chain fatty acids in all constituent fatty acids is 70% by mass or more, but MCT and/or it is preferable to use only MLCT.
In addition, as a method for confirming and quantifying the constituent fatty acids of the fats and oils of the present invention, for example, the method specified in "Standard Oil and Fat Analysis Test Method 2.4.2.3-2013 Fatty Acid Composition (Capillary Gas Chromatography Method)" established by the Japan Oil Chemists' Society One example is a method of quantitative analysis in accordance with the above.

 前記MCT及びMLCTは、ヤシ油やパーム核油由来の中鎖脂肪酸や長鎖脂肪酸と、グリセリンとを原料としてエステル化反応させることにより得ることができる。エステル化反応の条件は、特に限定されるものではなく、無触媒且つ無溶剤にて加圧下で反応させてもよく、触媒や溶剤を用いて反応させてもよい。また、上記MLCTは、MCTとMCT以外の油脂とをエステル交換する方法によっても得ることができる。エステル交換する方法としては、特に限定されるものではなく、ナトリウムメトキシドを触媒とした化学的エステル交換や、リパーゼ製剤を触媒とした酵素的エステル交換など、通常行われる方法で行えばよい。 The MCT and MLCT can be obtained by esterifying medium-chain fatty acids or long-chain fatty acids derived from coconut oil or palm kernel oil and glycerin as raw materials. The conditions for the esterification reaction are not particularly limited, and the reaction may be carried out under pressure without a catalyst and without a solvent, or may be carried out using a catalyst or a solvent. Moreover, the above-mentioned MLCT can also be obtained by a method of transesterifying MCT and fats and oils other than MCT. The transesterification method is not particularly limited, and may be carried out by commonly used methods such as chemical transesterification using sodium methoxide as a catalyst or enzymatic transesterification using a lipase preparation as a catalyst.

 本発明の油脂は、前記MCT及びMLCT以外の油脂を含有してもよい。MCT及びMLCT以外の油脂は、例えば、大豆油、菜種油、ゴマ油、コ-ン油、綿実油、紅花油、ヒマワリ油、カカオ油、米糠油、落花生油、オリ-ブ油、シソ油、エゴマ油、亜麻仁油、ブドウ種子油、マカデミアナッツ油、ヘ-ゼルナッツ油、カボチャ種子油、クルミ油、椿油、茶実油、ボラ-ジ油、綿実油、小麦胚芽油、魚油等が挙げられる。また、これらの油脂の2種以上をエステル交換したエステル交換油脂、これらの油脂の分別油脂等であってもよい。上記油脂は単独で用いてもよく、2種以上を混合して用いてもよい。 The fats and oils of the present invention may contain fats and oils other than the MCT and MLCT. Examples of oils and fats other than MCT and MLCT include soybean oil, rapeseed oil, sesame oil, corn oil, cottonseed oil, safflower oil, sunflower oil, cacao oil, rice bran oil, peanut oil, olive oil, perilla oil, perilla oil, Examples include linseed oil, grape seed oil, macadamia nut oil, hazelnut oil, pumpkin seed oil, walnut oil, camellia oil, tea seed oil, borage oil, cottonseed oil, wheat germ oil, and fish oil. It may also be transesterified oils and fats obtained by transesterifying two or more of these oils and fats, fractionated oils and fats of these oils and fats, and the like. The above fats and oils may be used alone or in combination of two or more.

 本発明の油脂がMCTを含有する場合、本発明の油脂中のMCT含有量は、好ましくは90~100質量%、より好ましくは95~100質量%、さらにより好ましくは96~99質量%、最も好ましくは97~99質量%である。MCT含有量が上記の範囲にあると本発明の効果をより奏しやすい。 When the fat or oil of the present invention contains MCT, the MCT content in the fat or oil of the present invention is preferably 90 to 100% by mass, more preferably 95 to 100% by mass, even more preferably 96 to 99% by mass, and most preferably Preferably it is 97 to 99% by mass. When the MCT content is within the above range, the effects of the present invention can be more easily achieved.

 本発明の油脂組成物中の前記油脂の含有量は、好ましくは92~99.8質量%、より好ましくは94~99.7質量%、さらにより好ましくは96~99.6質量%、最も好ましくは98~99.5質量%である。本発明の油脂の含有量が上記の範囲にあると本発明の効果をより奏しやすい。 The content of the fat or oil in the oil or fat composition of the present invention is preferably 92 to 99.8% by mass, more preferably 94 to 99.7% by mass, even more preferably 96 to 99.6% by mass, and most preferably is 98 to 99.5% by mass. When the content of the oil and fat of the present invention is within the above range, the effects of the present invention are more likely to be exhibited.

〔グリセリン脂肪酸エステル〕
 本発明におけるグリセリン脂肪酸エステルは、食品添加物のグリセリン脂肪酸エステルであり、グリセリン及び/又はポリグリセリン(グリセリン重合体)を骨格とする脂肪酸エステルを指す。すなわち、グリセリン脂肪酸エステルは、ポリグリセリン脂肪酸エステル、グリセリン有機酸脂肪酸エステルなどを含み得る。また、本発明におけるグリセリン脂肪酸エステルの構成脂肪酸は、好ましくは炭素数16以上の脂肪酸であり、より好ましくはオレイン酸を含有する。
[Glycerin fatty acid ester]
The glycerin fatty acid ester in the present invention is a food additive glycerin fatty acid ester, and refers to a fatty acid ester having a skeleton of glycerin and/or polyglycerin (glycerin polymer). That is, the glycerin fatty acid ester may include polyglycerin fatty acid ester, glycerin organic acid fatty acid ester, and the like. Further, the constituent fatty acids of the glycerin fatty acid ester in the present invention are preferably fatty acids having 16 or more carbon atoms, and more preferably contain oleic acid.

 本発明におけるグリセリン脂肪酸エステルは、好ましくはグリセリン脂肪酸エステル、及び/又はポリグリセリン脂肪酸エステルを含有し、より好ましくはポリグリセリン脂肪酸エステルを含有し、最も好ましくはポリグリセリン脂肪酸エステルである。前記ポリグリセリン脂肪酸エステルの平均重合度は、好ましくは4~12、より好ましくは6~11、最も好ましくは8~10である。ここで、平均重合度とは、ポリグリセリン脂肪酸エステルの原料であるポリグリセリンの水酸基価から算出される数値である。ポリグリセリン脂肪酸エステルの平均重合度、及び、構成脂肪酸が上記の範囲にあると、本発明の効果を奏しやすく、また、食品から油脂組成物の分離が起きにくい。 The glycerin fatty acid ester in the present invention preferably contains a glycerin fatty acid ester and/or a polyglycerin fatty acid ester, more preferably a polyglycerin fatty acid ester, and most preferably a polyglycerin fatty acid ester. The average degree of polymerization of the polyglycerol fatty acid ester is preferably 4 to 12, more preferably 6 to 11, and most preferably 8 to 10. Here, the average degree of polymerization is a value calculated from the hydroxyl value of polyglycerin, which is a raw material for polyglycerin fatty acid ester. When the average degree of polymerization and the constituent fatty acids of the polyglycerin fatty acid ester are within the above ranges, the effects of the present invention can be easily achieved, and separation of the oil and fat composition from foods is less likely to occur.

 本発明におけるグリセリン脂肪酸エステルのHLBは、好ましくは3~9、より好ましくは5~8、最も好ましくは6~7.5である。HLBが上記の範囲にあると、本発明の効果を奏しやすく、また、食品から油脂組成物の分離が起きにくい。ここで、HLBとは、乳化剤中の親水基と親油基のバランスを表しており、公知の測定方法により求めた数値である。例えば、前記乳化剤が非イオン性の乳化剤の場合、HLB値の算出はアトラス法の算出法を用いる。アトラス法の算出法は、
 HLB=20×(1-S/A)
 S:ケン化価
 A:エステル中の脂肪酸の中和価
からHLB値を算出する方法を言う。
 また、本発明におけるグリセリン脂肪酸エステルは、1種類で使用されてもよいし、2種類以上の組み合せで使用されてもよいが、2種類以上を組み合せて使用される場合は、平均HLBが上記の範囲であることが好ましい。ここで、平均HLBとは、乳化剤の個々のHLBに混合比率(質量)を乗じて算出される数値である。
The HLB of the glycerin fatty acid ester in the present invention is preferably 3 to 9, more preferably 5 to 8, and most preferably 6 to 7.5. When the HLB is within the above range, the effects of the present invention can be easily achieved, and separation of the fat and oil composition from the food is less likely to occur. Here, HLB represents the balance between hydrophilic groups and lipophilic groups in an emulsifier, and is a numerical value determined by a known measuring method. For example, when the emulsifier is a nonionic emulsifier, the HLB value is calculated using the Atlas method. The calculation method of the Atlas method is
HLB=20×(1-S/A)
S: Saponification value A: A method of calculating the HLB value from the neutralization value of the fatty acid in the ester.
In addition, the glycerin fatty acid ester in the present invention may be used alone or in a combination of two or more types, but when two or more types are used in combination, the average HLB is as high as the above. Preferably, the range is within the range. Here, the average HLB is a value calculated by multiplying the individual HLB of the emulsifier by the mixing ratio (mass).

 本発明の油脂組成物中の前記グリセリン脂肪酸エステルの含有量は、好ましくは0.2~7質量%、より好ましくは0.3~5質量%、さらにより好ましくは0.4~3質量%、最も好ましくは0.5~1.5質量%である。本発明におけるグリセリン脂肪酸エステルの含有量が上記の範囲にあると、本発明の効果を奏しやすく、また、乳化剤特有の異味を感じにくい。
 また、本発明の油脂組成物は、好ましくは、グリセリン脂肪酸エステル以外の乳化剤を含まないか、又は、グリセリン脂肪酸エステル以外の乳化剤の含有量は、好ましくは3質量%以下、より好ましくは1質量%以下、最も好ましくは0.5質量%以下である。
The content of the glycerin fatty acid ester in the oil and fat composition of the present invention is preferably 0.2 to 7% by mass, more preferably 0.3 to 5% by mass, even more preferably 0.4 to 3% by mass, Most preferably it is 0.5 to 1.5% by weight. When the content of the glycerin fatty acid ester in the present invention is within the above range, the effects of the present invention can be easily achieved, and the unpleasant taste peculiar to emulsifiers is not felt easily.
Further, the oil and fat composition of the present invention preferably does not contain any emulsifier other than glycerin fatty acid ester, or the content of emulsifier other than glycerin fatty acid ester is preferably 3% by mass or less, more preferably 1% by mass. The most preferred amount is 0.5% by mass or less.

〔トコフェロール〕
 本発明におけるトコフェロールは、α-トコフェロール、β-トコフェロール、γ-トコフェロール、δ-トコフェロールの単独又は2種以上の混合物である。本発明におけるトコフェロールは、γ-トコフェロール及び/またはδ-トコフェロールを含有することが好ましく、総トコフェロール中のγ-トコフェロール及び/またはδ-トコフェロール含有量が好ましくは50質量%以上、より好ましくは70質量%以上である。
[Tocopherol]
Tocopherol in the present invention is α-tocopherol, β-tocopherol, γ-tocopherol, or δ-tocopherol alone or in a mixture of two or more. The tocopherol in the present invention preferably contains γ-tocopherol and/or δ-tocopherol, and the content of γ-tocopherol and/or δ-tocopherol in the total tocopherol is preferably 50% by mass or more, more preferably 70% by mass. % or more.

 本発明の油脂組成物は、トコフェロールを含む食品原料(植物油脂等)を配合することで、所望のトコフェロール含有量を充足してもよい。また、本発明の油脂組成物の原材料にトコフェロール製剤を使用する場合は、本発明の油脂組成物中のトコフェロール含有量が、所望の含有量となるようにトコフェロール製剤の配合量を調整すればよい。 The oil and fat composition of the present invention may satisfy the desired tocopherol content by blending food raw materials (vegetable oils and fats, etc.) containing tocopherol. Furthermore, when using a tocopherol preparation as a raw material for the oil and fat composition of the present invention, the amount of the tocopherol preparation may be adjusted so that the tocopherol content in the oil and fat composition of the present invention becomes a desired content. .

 本発明の油脂組成物中の前記トコフェロールの含有量は、好ましくは0.003~0.2質量%、より好ましくは0.004~0.1質量%、さらにより好ましくは0.006~0.05質量%、最も好ましくは0.008~0.025質量%である。トコフェロールの含有量が上記の範囲にあると、本発明の油脂組成物の経時的な白濁や、曝光による白濁の抑制効果により優れる。
 油脂組成物中のトコフェロールの含有量は、日本油化学会制定「基準油脂分析試験法  2.4.10-2013  トコフェロール(蛍光検出器-高速液体クロマトグラフ法)」に準拠して測定することができる。
The content of the tocopherol in the oil and fat composition of the present invention is preferably 0.003 to 0.2% by mass, more preferably 0.004 to 0.1% by mass, and even more preferably 0.006 to 0.00% by mass. 0.05% by weight, most preferably 0.008-0.025% by weight. When the content of tocopherol is within the above range, the oil and fat composition of the present invention will be more effective in suppressing clouding over time and clouding due to exposure to light.
The content of tocopherol in an oil and fat composition can be measured in accordance with the "Standard Oil and Fat Analysis Test Method 2.4.10-2013 Tocopherol (Fluorescence Detector - High Performance Liquid Chromatography Method)" established by the Japan Oil Chemists' Society. can.

〔その他の原料〕
 本発明の油脂組成物は、本発明の効果を損なわない限り、色素、ビタミン、香料等を含有することができる。
[Other raw materials]
The oil and fat composition of the present invention may contain pigments, vitamins, fragrances, etc. as long as they do not impair the effects of the present invention.

 本発明の油脂組成物は、前記グリセリン脂肪酸エステル100質量部に対して、前記トコフェロールを、好ましくは0.2~5質量部、より好ましくは0.3~4質量部、さらにより好ましくは0.5~3.5質量部、最も好ましくは0.7~2.5質量部含有する。グリセリン脂肪酸エステルに対するトコフェロールの含有量が上記の範囲にあると、本発明の油脂組成物の経時的な白濁や、曝光による白濁の抑制効果により優れる。 The oil and fat composition of the present invention preferably contains 0.2 to 5 parts by mass, more preferably 0.3 to 4 parts by mass, and even more preferably 0.2 to 5 parts by mass, and even more preferably 0.2 to 5 parts by mass of the tocopherol per 100 parts by mass of the glycerin fatty acid ester. It contains 5 to 3.5 parts by weight, most preferably 0.7 to 2.5 parts by weight. When the content of tocopherol relative to the glycerin fatty acid ester is within the above range, the oil and fat composition of the present invention has an excellent effect of suppressing clouding over time and clouding due to exposure to light.

〔本発明の油脂組成物の用途〕
 本発明の油脂組成物は、流動食用として使用できる。本発明の油脂組成物は、高齢者施設や病院等で提供される流動食に、所望のエネルギーが補足できる量を添加又は含有させることができる。この場合、流動食中の本発明の油脂組成物の含有量は、好ましくは、1~15質量%、より好ましくは、3~12質量%、最も好ましくは、5~10質量%である。前記流動食中の前記油脂組成物の含有量が上記の範囲にあると、エネルギー密度を約1.5~2倍に高めることができる。
[Uses of the oil and fat composition of the present invention]
The oil and fat composition of the present invention can be used as a liquid food. The oil and fat composition of the present invention can be added or included in liquid foods provided at elderly facilities, hospitals, etc. in an amount that can supplement desired energy. In this case, the content of the oil and fat composition of the present invention in the liquid food is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. When the content of the oil and fat composition in the liquid food is within the above range, the energy density can be increased by about 1.5 to 2 times.

 本発明の油脂組成物は、高齢者向け食品用として使用できる。本発明の油脂組成物は、高齢者向けの食品(ソフト食等)に、所望のエネルギーが補足できる量を添加又は含有させることができる。例えば、前記食品が軟飯の態様の場合、本発明の油脂組成物の含有量は、好ましくは、1~15質量%、より好ましくは、3~12質量%、最も好ましくは、5~10質量%である。前記軟飯中の前記油脂組成物の含有量が上記の範囲にあると、エネルギー密度を約1.5~2倍に高めることができる。
 本発明における高齢者とは、60歳以上を意味し、好ましくは65歳以上であり、より好ましくは70歳以上の者である。
The oil and fat composition of the present invention can be used as food for the elderly. The oil and fat composition of the present invention can be added or contained in foods for the elderly (soft foods, etc.) in an amount that can supplement desired energy. For example, when the food is soft rice, the content of the oil and fat composition of the present invention is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. It is. When the content of the oil and fat composition in the soft rice is within the above range, the energy density can be increased by about 1.5 to 2 times.
The term "elderly people" in the present invention refers to people over 60 years old, preferably over 65 years old, and more preferably over 70 years old.

 本発明の油脂組成物は、嚥下困難者向け食品用に使用できる。本発明の油脂組成物は、嚥下困難者向け食品(キザミ食等)に、所望のエネルギーが補足できる量を添加又は含有させることができる。前記食品中の本発明の油脂組成物の含有量は、好ましくは、1~15質量%、より好ましくは、3~12質量%、最も好ましくは、5~10質量%である。前記軟飯中の前記油脂組成物の含有量が上記の範囲にあると、エネルギー密度を約1.5~2倍に高めることができる。
 本発明における嚥下困難者とは、嚥下に何らかの支障がある者を指す。例えば、嚥下能力が低下している高齢者、脳神経疾患や口腔疾患を有する者が挙げられる。本発明における嚥下困難者用の食品は、付着性が低いため、嚥下困難者にとって摂取しやすい。本発明における嚥下困難者用の食品は、厚生労働省が規定する「嚥下困難者用食品たる表示の許可基準における規格基準」を満たす食品であってもよい。
The oil and fat composition of the present invention can be used for foods for people with swallowing difficulties. The oil and fat composition of the present invention can be added or contained in foods for people with swallowing difficulties (such as kizami food) in an amount that can supplement desired energy. The content of the oil and fat composition of the present invention in the food is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. When the content of the oil and fat composition in the soft rice is within the above range, the energy density can be increased by about 1.5 to 2 times.
A dysphagic person in the present invention refers to a person who has some difficulty in swallowing. Examples include elderly people with reduced swallowing ability, and people with cranial nerve disease or oral disease. The food for people with swallowing difficulties according to the present invention has low adhesiveness and is therefore easy for people with swallowing problems to ingest. The food for people with dysphagia in the present invention may be a food that satisfies the "standards for approval of labeling as food for people with dysphagia" stipulated by the Ministry of Health, Labor and Welfare.

 本発明の油脂組成物は、介護食用として使用できる。本発明の油脂組成物は、介護用食品に、所望のエネルギーが補足できる量を添加又は含有させることができる。例えば、前記食品がお粥の態様の場合、本発明の油脂組成物の含有量は、好ましくは、1~15質量%、より好ましくは、3~12質量%、最も好ましくは、5~10質量%である。前記軟飯中の前記油脂組成物の含有量が上記の範囲にあると、エネルギー密度を約1.5~2倍に高めることができる。
 本発明における介護食とは、病院施設や在宅で介護を要する方向けの食品を指す。
The oil and fat composition of the present invention can be used as a nursing food. The oil and fat composition of the present invention can be added or contained in nursing care foods in an amount that can supplement desired energy. For example, when the food is in the form of porridge, the content of the oil and fat composition of the present invention is preferably 1 to 15% by mass, more preferably 3 to 12% by mass, and most preferably 5 to 10% by mass. %. When the content of the oil and fat composition in the soft rice is within the above range, the energy density can be increased by about 1.5 to 2 times.
Nursing care food in the present invention refers to food for people who require nursing care in hospital facilities or at home.

〔本発明の油脂組成物を含有する食品〕
 本発明の油脂組成物を含有する食品(以下、本発明の食品ともいう。)は、本発明の油脂組成物を含有することで、エネルギー密度が高められた食品であり、好ましくはエネルギー密度が1.5~2倍に高められた食品である。本発明の食品は、エネルギー密度が高いため、少量の摂取で所望とするエネルギーが補給できる。
 本発明の食品は、例えば、上記の流動食、高齢者向け食品、嚥下困難者向け食品、又は介護食として使用される食品であってもよい。
 本発明の食品は、食品全体に対する水の含有量(水分)が好ましくは60質量%以上、より好ましくは65~99質量%、さらにより好ましくは65~95質量%、最も好ましくは70~90質量%である。前記食品中の水分含量は、常用の乾燥減量法により求めることができる。前記食品としては、主食(ご飯、軟飯、おかゆ、おじや等)、副菜(お浸し、和え物、煮物、酢物等)、汁物(みそ汁、スープ等)、飲料(水、お茶、コーヒー、牛乳等)、嚥下調整食(飲料、汁物等にトロミ調整剤を添加してトロミを付与した食品、きざみ食、ソフト食(噛み切りやすく、飲み込みやすいよう調理した食品)、ミキサー食(ミキサーにかけてペースト状にした食品)等が挙げられるが、好ましくは、主食又は副菜である。
[Food containing the oil and fat composition of the present invention]
A food containing the fat and oil composition of the present invention (hereinafter also referred to as a food of the present invention) is a food that has an increased energy density by containing the fat and oil composition of the present invention, and preferably has an increased energy density. It is a food product that is 1.5 to 2 times more expensive. Since the food of the present invention has a high energy density, desired energy can be supplied with a small amount of intake.
The food of the present invention may be, for example, the above liquid food, food for the elderly, food for people with difficulty swallowing, or food used as nursing care food.
The food of the present invention preferably has a water content (moisture) of 60% by mass or more, more preferably 65 to 99% by mass, even more preferably 65 to 95% by mass, and most preferably 70 to 90% by mass based on the whole food. %. The moisture content in the food can be determined by a conventional loss on drying method. The above-mentioned foods include staple foods (rice, soft rice, porridge, ojiya, etc.), side dishes (soaked dishes, marinated dishes, boiled dishes, vinegared dishes, etc.), soups (miso soup, soup, etc.), and beverages (water, tea, coffee, milk, etc.). ), swallowing-adjusting foods (foods with thickening agents added to beverages, soups, etc.), chopped foods, soft foods (foods prepared so that they are easy to chew and swallow), mixer foods (foods prepared in a blender to make them into a paste) Preferably, it is a staple food or a side dish.

〔本発明の油脂組成物の商品形態〕
 本発明の油脂組成物は、いかなる商品形態を取ることも可能である。ここで、商品形態とは、油脂組成物その物を輸送、貯蔵及び販売する際に取られる形態のことを指す。本発明の油脂組成物の商品形態は、例えば、ガラスビン、プラスチックボトル、ピロー包装等の形態を取ることができる。
 本発明の油脂組成物は、曝光下においても白濁の発生が抑制されるので、少なくとも一部が光透過性である容器に充填することが可能である。ここで、少なくとも一部が光透過性である容器とは、少なくとも容器の一部が、蛍光灯の下で内容物を目視で確認できる程度の透過性を有する容器のことをいう。具体的には、容器の一部又は全部が、着色されていないPET、着色されていないラミコン(Laminated-container)、及び着色されていないガラス等の素材を使用している容器を挙げることができる。
[Product form of the oil and fat composition of the present invention]
The oil and fat composition of the present invention can be in any commercial form. Here, the product form refers to the form taken when transporting, storing, and selling the oil and fat composition itself. The product form of the oil and fat composition of the present invention can be, for example, a glass bottle, a plastic bottle, a pillow package, or the like.
Since the oil and fat composition of the present invention suppresses the occurrence of cloudiness even when exposed to light, it can be filled into a container at least partially transparent. Here, the term "container at least partially transparent to light" refers to a container in which at least a portion of the container is transparent enough to allow the contents to be visually confirmed under a fluorescent lamp. Specifically, examples include containers in which part or all of the container is made of materials such as uncolored PET, uncolored Laminated-container, and uncolored glass. .

〔白濁の抑制方法〕
 本発明の全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂、及びグリセリン脂肪酸エステルを含有する油脂組成物の白濁の抑制方法(以下、本発明の白濁の抑制方法ともいう。)は、該油脂組成物にトコフェロールを含有させて、該油脂を90~99.8質量%、グリセリン脂肪酸エステルを0.1~9.5質量%、トコフェロールを0.002~0.3質量%となるように含有させる方法である。ここで、本発明の「白濁の抑制方法」とは、曝光下で長期保存した場合に油脂組成物の白濁が認められず、長期保存前の油脂組成物と比較して同等の澄明な外観を維持する方法をいう。ここで、「澄明」とは、例えば660nm(光路長10mm、対照:水)の透過率が95%以上の状態を指す。また、本発明において「曝光下」とは、1日12時間以上、1000ルクス以上の照度下で保管されている状態を指す。また、本発明において「長期保存」とは、本発明における油脂の製造後、室温(1~30℃)で4週間以上経過した状態を指す。
[How to suppress cloudiness]
The method of suppressing cloudiness of an oil or fat composition containing a glycerin fatty acid ester and an oil or fat having a medium-chain fatty acid content of 70% by mass or more in all the constituent fatty acids of the present invention (hereinafter also referred to as the method of suppressing cloudiness of the present invention). ) contains tocopherol in the fat/oil composition, containing 90 to 99.8% by mass of the fat, 0.1 to 9.5% by mass of glycerin fatty acid ester, and 0.002 to 0.3% by mass of tocopherol. This is a method of containing it so that Here, the "method for suppressing white turbidity" of the present invention means that when stored for a long time under light exposure, no cloudiness is observed in the oil and fat composition, and the same clear appearance is obtained compared to the oil and fat composition before long-term storage. It refers to the method of maintaining. Here, "clear" refers to a state in which the transmittance at 660 nm (optical path length 10 mm, reference: water) is 95% or more, for example. Moreover, in the present invention, "under light exposure" refers to a state where the product is stored under illuminance of 1000 lux or more for 12 hours or more a day. Furthermore, in the present invention, "long-term storage" refers to a state in which 4 weeks or more have passed at room temperature (1 to 30°C) after the production of the fat or oil in the present invention.

 本発明の白濁の抑制方法において、前記油脂、グリセリン脂肪酸エステル、及びトコフェロールの好ましい態様、含有量等は、上記の「本発明の油脂組成物」と同様である。 In the method for suppressing white turbidity of the present invention, preferred embodiments, contents, etc. of the oil and fat, glycerin fatty acid ester, and tocopherol are the same as in the above-mentioned "oil and fat composition of the present invention."

 また、本発明の白濁の抑制方法は、前記油脂組成物中のグリセリン脂肪酸エステル100質量部に対して、トコフェロールを、好ましくは0.2~5質量部、より好ましくは0.3~4質量部、さらにより好ましくは0.5~3.5質量部、最も好ましくは0.7~2.5質量部含有する。グリセリン脂肪酸エステルに対するトコフェロールの含有量が上記の範囲にあると、本発明の油脂組成物の経時的な白濁や、曝光による白濁の抑制効果により優れる。 Further, in the method for suppressing cloudiness of the present invention, preferably 0.2 to 5 parts by mass, more preferably 0.3 to 4 parts by mass of tocopherol are added to 100 parts by mass of glycerin fatty acid ester in the oil or fat composition. , even more preferably 0.5 to 3.5 parts by weight, most preferably 0.7 to 2.5 parts by weight. When the content of tocopherol relative to the glycerin fatty acid ester is within the above range, the oil and fat composition of the present invention has an excellent effect of suppressing clouding over time and clouding due to exposure to light.

 以下、実施例を示して本発明をさらに具体的に説明するが、本発明の範囲はこれら実施例の記載に何ら限定されるものではない。 Hereinafter, the present invention will be explained in more detail with reference to Examples, but the scope of the present invention is not limited to the description of these Examples in any way.

〔白濁抑制の確認試験-1〕
(油脂組成物1~7の調製)
 表1及び2の配合に従い、各原料を均一にブレンドして油脂組成物1~7を得た。油脂組成物1~7は、澄明な液体であった。なお表中の各原料は、以下の原料を使用した。
・MCT(商品名:O.D.O(カプリル酸:カプリン酸=75:25(質量比)の中鎖脂肪酸トリグリセリド)、日清オイリオグループ(株)製)
・菜種油(商品名:日清キャノーラ油、日清オイリオグループ(株)製)
・グリセリン脂肪酸エステル(商品名:リョートーポリグリエステルO-50D(デカグリセリンオレイン酸エステル,HLB7)、三菱ケミカルフーズ(株)製)
・トコフェロール製剤1(商品名:トコフェロール80、日清オイリオグループ(株)製、総トコフェロール含量80質量%(総トコフェロール中、γ-トコフェロール含量70質量%))
・トコフェロール製剤2(商品名:イーミックスD、エーザイフード・ケミカル(株)製、総トコフェロール含量100質量%(総トコフェロール中、δ-トコフェロール含量90質量%))
[Confirmation test of white turbidity suppression-1]
(Preparation of oil and fat compositions 1 to 7)
According to the formulations in Tables 1 and 2, each raw material was uniformly blended to obtain oil and fat compositions 1 to 7. Oil and fat compositions 1 to 7 were clear liquids. The following raw materials were used for each raw material in the table.
・MCT (Product name: O.D.O (medium chain fatty acid triglyceride with caprylic acid: capric acid = 75:25 (mass ratio)), manufactured by Nisshin Oilio Group Co., Ltd.)
・Rapeseed oil (product name: Nissin Canola Oil, manufactured by Nisshin Oilli Group Co., Ltd.)
・Glycerin fatty acid ester (product name: Ryoto Polyglyester O-50D (decaglycerin oleate ester, HLB7), manufactured by Mitsubishi Chemical Foods Co., Ltd.)
・Tocopherol preparation 1 (trade name: Tocopherol 80, manufactured by Nisshin Oillio Group Co., Ltd., total tocopherol content 80% by mass (out of total tocopherols, γ-tocopherol content 70% by mass))
・Tocopherol preparation 2 (trade name: Emix D, manufactured by Eisai Food Chemical Co., Ltd., total tocopherol content 100% by mass (in total tocopherol, δ-tocopherol content 90% by mass))

(油脂組成物1~7の保存試験)
 上記で調製した油脂組成物1~7を透明のプラスチック製ボトル(1L)に950mL充填した。その後、静置したボトルに対し、1000ルクス(ボトル表面の照度)、20℃で12週間曝光した。曝光は、蛍光灯を壁面に備えたインキュベーターで行った。
(Storage test of oil and fat compositions 1 to 7)
950 mL of the oil and fat compositions 1 to 7 prepared above were filled into a transparent plastic bottle (1 L). Thereafter, the bottle that had been left standing was exposed to light at 1000 lux (illuminance on the bottle surface) at 20° C. for 12 weeks. Light exposure was performed in an incubator equipped with fluorescent lights on the wall.

(白濁発生の確認)
 上記保存試験で3週間保存した各油脂組成物について、50mLのガラスビーカーに40mLを注ぎ、ビーカーの側面(黒色背景)から油脂組成物の状態を目視確認した。目視確認は、5名のパネリストの総意により下記の2段階で評価した。同様にして、6週間及び12週間保存した各油脂組成物についても評価した。評価結果を表1及び2に示す。
(評価基準)
 ○:澄明であり、析出物も認められない。
 ×:白濁、または析出物が認められる。
(Confirmation of cloudiness)
For each oil and fat composition stored for three weeks in the above storage test, 40 mL was poured into a 50 mL glass beaker, and the state of the oil and fat composition was visually confirmed from the side of the beaker (black background). Visual confirmation was evaluated in the following two stages based on the consensus of five panelists. In the same manner, each oil and fat composition stored for 6 weeks and 12 weeks was also evaluated. The evaluation results are shown in Tables 1 and 2.
(Evaluation criteria)
○: Clear and no precipitates observed.
x: Cloudiness or precipitates are observed.

 上記保存試験で12週間保存した各油脂組成物について、660nm(光路長10mm、対照:水)の透過率を測定したところ、油脂組成物3~6(実施例1~4)は、全て95%以上であった。測定結果を表1及び2に示す。 When the transmittance at 660 nm (light path length 10 mm, control: water) was measured for each oil and fat composition stored for 12 weeks in the above storage test, all oil and fat compositions 3 to 6 (Examples 1 to 4) had a transmittance of 95%. That was it. The measurement results are shown in Tables 1 and 2.

 表1及び2中の「TOC/GSF×100」は、グリセリン脂肪酸エステル100質量部に対する、トコフェロールの質量部を指す。表1及び2中の「透過率(%)」は12週間保存後の透過率(%)を指す。 "TOC/GSF×100" in Tables 1 and 2 refers to parts by mass of tocopherol based on 100 parts by mass of glycerin fatty acid ester. "Transmittance (%)" in Tables 1 and 2 refers to the transmittance (%) after storage for 12 weeks.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

 表1及び2の結果より、MCTをベース油とし、グリセリン脂肪酸エステルを1質量%、及びトコフェロールを0.01又は0.02質量%含有する油脂組成物(実施例1~4)は、曝光下の長期間保存において、白濁の発生が抑制された。 From the results in Tables 1 and 2, the oil and fat compositions (Examples 1 to 4) containing MCT as a base oil, 1% by mass of glycerin fatty acid ester, and 0.01 or 0.02% by mass of tocopherol were During long-term storage, the occurrence of cloudiness was suppressed.

〔白濁抑制の確認試験-2〕
(油脂組成物8~15の調製)
 表3及び4の配合に従い、各原料を均一にブレンドして油脂組成物8~15を得た。油脂組成物8~15は、澄明な液体であった。なお表中の各原料は、上記「白濁抑制の確認試験-1」に記載の原料と同等のものを使用した。
[Confirmation test of white turbidity suppression-2]
(Preparation of oil and fat compositions 8 to 15)
According to the formulations in Tables 3 and 4, each raw material was uniformly blended to obtain oil and fat compositions 8 to 15. Oil and fat compositions 8 to 15 were clear liquids. Note that each raw material in the table was the same as the raw material described in "White turbidity suppression confirmation test-1" above.

(油脂組成物8~15の保存試験)
 上記で調製した油脂組成物8~15を透明のプラスチック製ボトル(1L)に950mL充填した。その後、静置したボトルに対し、1000ルクス(ボトル表面の照度)、20℃で12週間曝光した。曝光は、蛍光灯を壁面に備えたインキュベーター内で行った。
(Storage test of oil and fat compositions 8 to 15)
950 mL of the oil and fat compositions 8 to 15 prepared above were filled into a transparent plastic bottle (1 L). Thereafter, the bottle that had been left standing was exposed to light at 1000 lux (illuminance on the bottle surface) at 20° C. for 12 weeks. Light exposure was performed in an incubator equipped with fluorescent lights on the wall.

(白濁発生の確認)
 上記保存試験で4週間及び12週間保存した各油脂組成物について、上記「白濁抑制の確認試験-1」に記載の方法と同様にして評価した。評価結果を表3及び4に示す。
(Confirmation of cloudiness)
Each oil and fat composition stored for 4 weeks and 12 weeks in the above storage test was evaluated in the same manner as described in the above "White turbidity suppression confirmation test-1". The evaluation results are shown in Tables 3 and 4.

 上記保存試験で12週間保存した各油脂組成物について、660nm(光路長10mm、対照:水)の透過率を測定したところ、油脂組成物8~14(実施例5~11)は、全て95%以上であった。測定結果を表3及び4に示す。 When the transmittance at 660 nm (light path length 10 mm, control: water) was measured for each oil and fat composition stored for 12 weeks in the above storage test, all oil and fat compositions 8 to 14 (Examples 5 to 11) had a transmittance of 95%. That was it. The measurement results are shown in Tables 3 and 4.

 表3及び4中の「TOC/GSF×100」は、グリセリン脂肪酸エステル100質量部に対する、トコフェロールの質量部を指す。表3及び4中の「透過率(%)」は12週間保存後の透過率(%)を指す。 "TOC/GSF×100" in Tables 3 and 4 refers to parts by mass of tocopherol based on 100 parts by mass of glycerin fatty acid ester. "Transmittance (%)" in Tables 3 and 4 refers to the transmittance (%) after storage for 12 weeks.

Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004

 表3及び4の結果より、MCTをベース油とし、グリセリン脂肪酸エステルを0.5~6質量%、及びトコフェロールを0.004~0.16質量%含有する油脂組成物(実施例5~11)は、曝光下の保存において、白濁の発生が抑制された。 From the results in Tables 3 and 4, oil and fat compositions containing MCT as a base oil, 0.5 to 6% by mass of glycerin fatty acid ester, and 0.004 to 0.16% by mass of tocopherol (Examples 5 to 11) The occurrence of cloudiness was suppressed during storage under light exposure.

〔油脂組成物3を含有する軟飯の製造〕
 炊飯器に、生米と、生米の3.3倍質量の炊き水を投入し、炊き上げて軟飯を製造した。なお、軟飯中の水分を乾燥減量法(105℃、4時間)で測定した結果、75質量%であった。次に、20℃まで冷ました軟飯150gに油脂組成物3を13g添加し、へらで十分に混ぜ込み、本発明の油脂組成物を含有する軟飯を製造した。
 軟飯のエネルギーは1.1Kcal/g、油脂組成物3を含有する軟飯のエネルギーは1.8Kcal/gであった。
[Production of soft rice containing oil and fat composition 3]
Raw rice and cooking water 3.3 times the mass of the raw rice were put into a rice cooker and cooked to produce soft rice. In addition, as a result of measuring the water content in the soft rice by the loss on drying method (105° C., 4 hours), it was found to be 75% by mass. Next, 13 g of oil and fat composition 3 was added to 150 g of soft rice that had been cooled to 20° C., and thoroughly mixed with a spatula to produce soft rice containing the oil and fat composition of the present invention.
The energy of the soft rice was 1.1 Kcal/g, and the energy of the soft rice containing fat composition 3 was 1.8 Kcal/g.

 上記で製造した本発明の油脂組成物を含有する軟飯について、茶碗に150gをよそい、5分後に軟飯の外観と茶碗壁面の状態を目視で観察したところ、油の分離は認められなかった。したがって、前記の軟飯は、高齢者向け食品として好適に使用できるものであった。 Regarding the soft rice containing the oil and fat composition of the present invention produced above, 150 g was poured into a bowl, and after 5 minutes, the appearance of the soft rice and the condition of the wall of the bowl were visually observed, and no oil separation was observed. Therefore, the soft rice described above could be suitably used as a food for the elderly.

Claims (8)

 全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂を90~99.8質量%、グリセリン脂肪酸エステルを0.1~9.5質量%、及びトコフェロールを0.002~0.3質量%含有する油脂組成物。 90 to 99.8 mass % of fats and oils with a medium chain fatty acid content of 70 mass % or more in all constituent fatty acids, 0.1 to 9.5 mass % of glycerin fatty acid ester, and 0.002 to 0.0 mass % of tocopherol. An oil and fat composition containing 3% by mass.  前記油脂が中鎖脂肪酸トリグリセリドを含有する請求項1に記載の油脂組成物。 The oil or fat composition according to claim 1, wherein the oil or fat contains medium chain fatty acid triglyceride.  前記グリセリン脂肪酸エステルがポリグリセリン脂肪酸エステルを含有する、請求項1又は2に記載の油脂組成物。 The oil or fat composition according to claim 1 or 2, wherein the glycerin fatty acid ester contains a polyglycerin fatty acid ester.  前記油脂組成物が、流動食用、高齢者向け食品用、嚥下困難者向け食品用、又は介護食用の用途で使用される、請求項1~3のいずれか1項に記載の油脂組成物。 The oil and fat composition according to any one of claims 1 to 3, wherein the oil and fat composition is used for liquid food, food for the elderly, food for people with difficulty swallowing, or nursing care food.  請求項1~4のいずれか1項に記載の油脂組成物を含有する食品。 A food containing the oil and fat composition according to any one of claims 1 to 4.  前記食品の水分が60質量%以上である請求項5に記載の食品。 The food according to claim 5, wherein the moisture content of the food is 60% by mass or more.  全構成脂肪酸中の中鎖脂肪酸含有量が70質量%以上である油脂、及びグリセリン脂肪酸エステルを含有する油脂組成物の白濁の抑制方法であって、該油脂組成物において、トコフェロールを含有させて、該油脂を90~99.8質量%、該グリセリン脂肪酸エステルを0.1~9.5質量%、及び該トコフェロールを0.002~0.3質量%含有することによる、油脂組成物の白濁の抑制方法。 A method for suppressing cloudiness of an oil or fat composition containing a glycerin fatty acid ester and an oil or fat whose medium-chain fatty acid content in all constituent fatty acids is 70% by mass or more, comprising: containing tocopherol in the oil or fat composition; By containing 90 to 99.8% by mass of the oil and fat, 0.1 to 9.5% by mass of the glycerin fatty acid ester, and 0.002 to 0.3% by mass of the tocopherol, the cloudiness of the oil and fat composition can be reduced. Suppression method.  前記グリセリン脂肪酸エステル100質量部に対して前記トコフェロールを0.2~5質量部含有させることによる請求項7に記載の油脂組成物の白濁の抑制方法。 The method for suppressing cloudiness of an oil or fat composition according to claim 7, by containing 0.2 to 5 parts by mass of the tocopherol based on 100 parts by mass of the glycerin fatty acid ester.
PCT/JP2022/031110 2022-08-17 2022-08-17 Fat/oil composition, food containing fat/oil composition, and method for suppressing clouding of fat/oil composition WO2024038524A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5747446A (en) * 1980-09-05 1982-03-18 Nippon Oil & Fats Co Ltd Nutrious food composition
WO2011037092A1 (en) * 2009-09-24 2011-03-31 油化産業株式会社 Livestock feed composition and method for feeding livestock with same
JP2013159730A (en) * 2012-02-07 2013-08-19 Ogawa & Co Ltd Oil-soluble antioxidant and method for producing the same

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JP5938161B2 (en) 2010-09-01 2016-06-22 日清オイリオグループ株式会社 Oil and fat composition for feeding aids for foods for people with difficulty in swallowing and chewing and foods for people with difficulty in swallowing and chewing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5747446A (en) * 1980-09-05 1982-03-18 Nippon Oil & Fats Co Ltd Nutrious food composition
WO2011037092A1 (en) * 2009-09-24 2011-03-31 油化産業株式会社 Livestock feed composition and method for feeding livestock with same
JP2013159730A (en) * 2012-02-07 2013-08-19 Ogawa & Co Ltd Oil-soluble antioxidant and method for producing the same

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