WO2023013054A1 - Production method for fastener stringer, fastener chain, and slide fastener, and electroplating apparatus - Google Patents
Production method for fastener stringer, fastener chain, and slide fastener, and electroplating apparatus Download PDFInfo
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- WO2023013054A1 WO2023013054A1 PCT/JP2021/029394 JP2021029394W WO2023013054A1 WO 2023013054 A1 WO2023013054 A1 WO 2023013054A1 JP 2021029394 W JP2021029394 W JP 2021029394W WO 2023013054 A1 WO2023013054 A1 WO 2023013054A1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/22—Electroplating combined with mechanical treatment during the deposition
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/02—Slide fasteners
Definitions
- the present disclosure relates to methods for manufacturing fastener stringers, fastener chains and slide fasteners, and electroplating equipment.
- Patent Documents 1 and 2 disclose electroplating metal elements of fastener chains. As shown in FIGS. 3, 4, 5, etc. of Patent Document 1, a conductive medium 111 is accommodated in an insulating container 110, and a fastener chain 7 is passed through it. The metal element 3 of the fastener chain 7 and the plate-like cathode 118 are electrically connected via the conductive medium 111 .
- the insulating container 110 is provided with an opening 116 to ensure contact between the metal element 3 and the plating solution.
- the anode 119 is arranged to face the fastener chain 7 with the opening 116 of the insulating container 110 interposed therebetween. A plating film is formed on the metal element 3 mainly on the side facing the anode 119 .
- a similar technique is also disclosed in Patent Document 2 (see FIGS. 2, 3, etc. of Patent Document 2).
- Patent Documents 3 and 4 disclose that a substrate such as a button is put into a plating tank and electroplated.
- a special plating layer is formed by using a permanent magnet to flow the magnetic media together with the base material such as the button, and plating while the magnetic media collides with the base material such as the button. is disclosed (see, for example, FIG. 20 of Patent Document 3 and FIG. 20 of Patent Document 4).
- Patent Documents 3 and 4 are plating methods intended for small items such as buttons and sliders, and are not intended for long fastener chains in which elements are attached to fastener tapes.
- Patent Document 5 discloses a technique in which a fastener chain is passed between an anode 23 and a cathode 24, and the fastener element on the anode 23 side is given a first metallic color, and the fastener element on the cathode 24 side is given a second metallic color. disclosed. In order to obtain these two metallic colors, the fastener element is arranged away from the cathode (see FIG. 1, paragraph 0012 of Patent Document 5).
- a manufacturing method is a method for manufacturing a fastener chain or fastener stringer in which a plating film is formed on a metal element, and includes one or more fasteners at least partially immersed in an electrolytic solution in a plating bath.
- the position and orientation of the fastener chain or fastener stringer may be controlled as a result of the fastener chain or fastener stringer traveling continuously or intermittently in a predetermined travel path, although this need not be the case.
- the fastener chain manufacturing method can also be understood as an electroplating method for forming a plating film on the metal elements of the fastener chain.
- a method for manufacturing a slide fastener includes steps of cutting the fastener chain obtained by the above-described manufacturing method, and attaching a slider to the short fastener chain obtained by the cutting to form a short fastener. It includes enabling the engagement and disengagement of the metallic elements of a pair of fastener stringers of the chain.
- An electroplating apparatus for producing a plating film on metallic elements of fastener chains or fastener stringers, wherein one or more cathodes and one or more anodes are at least partially A plating bath for storing an electrolytic solution to be immersed in the plating bath, an alternating magnetic field generating section for generating an alternating magnetic field in the electrolytic solution of the plating bath, and a space where at least the metal element of the fastener chain or fastener stringer generates an alternating magnetic field.
- the cathode allows a plurality of magnetic media to move in response to an alternating magnetic field between the cathode and the metallic elements of a fastener chain or fastener stringer supported by one or more supports, and through the plurality of magnetic media. is electrically connectable to the metal element.
- the position and orientation of the fastener chain or fastener stringer is controlled such that the longitudinal direction of the fastener chain or fastener stringer is along a predetermined direction with alternating different magnetic poles for generating an alternating magnetic field.
- One or more supports may be provided for this purpose.
- the major faces of the metallic elements are substantially perpendicular to the magnetic axis with respect to the magnetic poles, and/or (ii) the fastener chains or stringers are aligned with the magnetic poles in their width direction. The position and orientation of the fastener chains or fastener stringers are controlled so that they face each other in a flat position.
- the fastener chain runway includes one or more helical runways and/or the one or more cathodes include one or more helical cathodes.
- generating an alternating magnetic field in the electrolyte includes rotating one or more magnetic rotating parts with different magnetic poles alternating in the direction of rotation.
- the position and orientation of the fastener chain or fastener stringer is controlled as a result of running the fastener chain or fastener stringer (eg, spirally) around the magnetic rotating portion.
- the magnetic rotating portion is housed in a magnetically permeable housing that is rotatably sealed.
- the step of generating an alternating magnetic field in the electrolyte comprises rotating each of the different magnetic rotators provided as one or more magnetic rotators, wherein the fastener chain is rotated across the different magnetic rotators.
- the position and orientation of the fastener chain or fastener stringer is controlled as a result of running the .
- running the fastener chain over the different magnetic rotating parts includes running the fastener chain in opposite directions in a helical track around the different magnetic rotating parts.
- the position and orientation of the fastener chain or fastener stringer is controlled as a result of the fastener chain running along the direction of rotation of the magnetic rotating portion.
- a plating film can be formed on the metal element of the fastener chain by a new method different from existing methods.
- FIG. 1 is a schematic diagram of a method of electroplating a metal element of a fastener chain according to one aspect of the present disclosure
- FIG. It is a schematic diagram which shows an example of a fastener chain.
- FIG. 4 is a schematic cross-sectional view showing a state in which a plating film is formed on the base material of the metal element; It is a time chart regarding an electroplating method. 4 is another time chart relating to the electroplating method;
- 1 is a schematic diagram of an electroplating apparatus according to one aspect of the present disclosure;
- FIG. 1 is a schematic side view of a magnetic rotating portion rotatably received in a magnetically permeable housing of an electroplating apparatus;
- FIG. 3 is a schematic side view showing an arrangement example of permanent magnets in a magnetic rotating section
- FIG. 4 is a schematic side view of a frame for mounting an anode outside the magnetically permeable housing of the electroplating apparatus
- FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media, where (a) shows a state in which the magnetic media are placed in a magnetic field formed by a magnetic flux directed radially outward from the north pole of a permanent magnet; , (b) show the magnetic media placed in the magnetic field formed by the magnetic flux directed radially inward toward the S pole of the permanent magnet.
- FIG. 4 is a schematic top view showing that the fastener chain is turned upside down between the spiral running paths.
- FIG. 1 is a schematic diagram showing an electroplating apparatus provided with four helical tracks
- FIG. FIG. 13 is a schematic diagram showing an electroplating apparatus according to another example provided with four spiral running paths, and the direction of rotation of the magnetic rotating portion is different from that in FIG. 12
- FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure
- FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media in an electroplating apparatus according to another aspect of the present disclosure
- (b) shows a state in which the lower cathode is arranged between the bottom surface of the metallic element and the south pole, and (b) shows a state in which the upper cathode is arranged between the top surface of the metallic element and the south pole.
- FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure. It is a table
- a method for manufacturing a fastener chain according to the present disclosure includes four steps S1 to S4 schematically shown in FIG.
- step S1 a voltage is applied between a cathode and an anode that are at least partially immersed in the electrolyte of the plating bath.
- step S2 an alternating magnetic field is generated in the electrolyte when or during the time a voltage is applied between the cathode and the anode.
- step S3 the position and orientation of the fastener chain are controlled such that at least the metallic elements of the fastener chain are arranged in the space in which the alternating magnetic field is generated.
- the fastener chain is caused to travel continuously or intermittently along a predetermined path so that the fastener chain passes through an alternating magnetic field, thereby controlling the position and orientation of the fastener chain.
- step S4 a plurality of magnetic media move according to the alternating magnetic field, the metal elements of the fastener chain are electrically connected to the cathode through the plurality of magnetic media, and the plating film growing on the metal elements A plurality of magnetic media collide with each other.
- the step S4 can be achieved by performing the steps S1 and S2 while the magnetic media are put into the plating bath.
- step S3 is performed as a result of running of the fastener chain, it can be performed so as to overlap with steps S1, S2, and S4 on the time axis, but this is not necessarily the case.
- the growth of the plating film and the collision of the magnetic media against the plating film occur simultaneously, which promotes the formation of a plating film of sufficient quality (for example, sufficient processing resistance).
- the position and orientation of the fastener chain is controlled to prevent the fastener tape from interfering with the electrical connection between the metallic element and the cathode.
- the fastener chain 1 In order to increase the utilization efficiency of the alternating magnetic field, it is preferable to control the position and orientation of the fastener chain 1 so that the longitudinal direction of the fastener chain 1 is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. Furthermore, the fastener chain 1 is arranged so that the main surface of the metal element is substantially perpendicular to the magnetic axis of the magnetic pole and/or so that the fastener chain 1 faces the magnetic pole in a flat posture in its width direction. It is preferable to control the position and orientation of . This promotes formation of a plated film with uniform quality and/or thickness.
- the flat posture means that the fastener chain 1 is not greatly bent in its width direction, and does not mean that both fastener tapes of the fastener chain 1 are flat enough to be arranged on the same plane. It also includes the occurrence of local bending and waviness in the fastener tape. Of course, the bent state in which the metal elements of the fastener chain 1 are covered with the fastener tape is not included in the above-described flat posture.
- Substantially orthogonal, with respect to the orientation of the metallic elements means an angle within the range of 80° to 100°.
- Electroplating can be performed efficiently if the position and orientation of the fastener chain 1 are controlled as a result of the fastener chain 1 running continuously or intermittently on the predetermined running path 80 .
- the predetermined travel path 80 may be defined by a plurality of support members 78, but this is not necessarily the case.
- the process of controlling the position and orientation of the fastener chain 1 can also be read as a process of continuously or intermittently running the fastener chain along a predetermined running path so that the fastener chain passes through the alternating magnetic field.
- the above process can be performed on (one side) fastener stringer.
- the method of manufacturing the fastener chain will be exclusively described, but the method of manufacturing (one side) of the fastener stringer can also be similarly applied, and redundant description will be omitted.
- the magnetic media moves in response to an alternating magnetic field and has sufficient conductivity to ensure electrical connection (that is, short circuit) between the cathode 10 and the metal elements 4a and 4b.
- Various shapes of magnetic media can be used, and in some cases non-spherical media are used.
- pin media such as cylinders or prisms are used.
- the pin media can be stainless steel pins with a diameter or maximum width on the order of 0.2 mm to 1.0 mm and a length of 3 mm to 15 mm. Ferromagnetic materials other than stainless steel can also be used.
- the pin media rotates according to the alternating magnetic field (when the direction of the magnetic field changes, the pin media changes from the first posture corresponding to the direction of the magnetic field before the change to the second posture corresponding to the direction of the magnetic field after the change). do). Also, the pin media are displaced by being entrained by the magnetic poles. In addition to such pin media behavior, pin media collide with each other, and pin media collide with fastener chains (especially metal elements). Although the individual behavior of the pin media is chaotic, the collection of pin media maintains an electrical connection between the cathode and the metallic element continuously or intermittently rather than accidentally.
- collision means that the rotational momentum and translational momentum obtained from the alternating magnetic field when the magnetic media are separated from the metal element (the magnetic media need not be separated from each other) are applied to the metal element.
- the electrode and the object to be plated when the electrode and the object to be plated are in constant contact, the electrode and the object to be plated move relative to each other. They are different.
- the collision of the magnetic media may flatten the plated film or scrape a part of its surface, resulting in a delay in the growth of the plated film.
- the collision of the magnetic media with the plated film can improve the quality of the plated film (for example, processing resistance or adhesion to the substrate).
- the collision can be said to mean collision with momentum that affects the change in the crystal structure of the plating layer.
- the fastener chain 1 is a long object that extends in a predetermined direction with a predetermined width, and has a pair of fastener stringers 2a and 2b.
- Each fastener stringer 2a, 2b has a fastener tape 3a, 3b and metallic elements 4a, 4b attached to the side edges of the fastener tape 3a, 3b.
- a fastener chain 1 is formed by engaging metal elements 4a and 4b of a pair of fastener stringers 2a and 2b.
- the metal elements 4a, 4b of the pair of fastener stringers 2a, 2b are engageable and disengageable in the same way using sliders (not shown).
- the metal elements 4a are attached to the side edges of the fastener tape 3a at predetermined intervals, and therefore are not electrically connected to each other on the fastener tape 3a.
- the metallic elements 4b are attached to the side edges of the fastener tape 3b at predetermined intervals and are therefore not electrically connected to each other on the fastener tape 3b.
- the fastener chain 1 is made into a short fastener chain by a cutting process, a slider is attached to the short fastener chain, and then, if necessary, the fastener chain is cut. A fastener is attached.
- a short fastener chain to which a slider (or a fastener in addition to this) is attached is generally called a slide fastener.
- the fastener chain 1 is not attached with a slider, which is a constituent part of the slide fastener as the final product, and can be efficiently and smoothly conveyed downstream.
- the fastener tapes 3a, 3b are flexible belts made of woven fabric, knitted fabric, or a mixture thereof.
- the fastener tapes 3a and 3b have a pair of main surfaces, a surface visible from the front side of the fastener chain 1 and a back surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces.
- the metal elements 4a, 4b are attached to the core cords of the fastener tapes 3a, 3b through their plastic deformation.
- the metal elements 4a, 4b have a pair of legs attached to the side edges (typically core cords) of the fastener tapes 3a, 3b and a head connecting the pair of legs.
- one side surface is provided with an engaging projection and the other side surface is provided with an engaging recess.
- each of the aforementioned pair of side surfaces is provided with an engaging projection.
- the metal elements 4a and 4b have a pair of main surfaces, a front surface visible from the front side of the fastener chain 1 and a rear surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces.
- FIG. 3 is a conceptual diagram showing how the base material 4g of the metal elements 4a and 4b is coated with the plating film 4h.
- the plated film 4h also contains the metal elements (Cu, Zn) of the substrate 4g in addition to tin (Sn).
- the ratio of Cu and Zn (referred to as first plating film metal elements) in the plating film 4h decreases continuously as the plating film 4h is separated from the substrate 4g in the thickness direction.
- the ratio of Sn corresponding to the anode (referred to as a second plating film metal element) decreases in the thickness direction of the plating film 4h as it approaches the substrate 4g.
- the ratio of the second plating film metal element is maximum on the top surface of the plating film 4h, and the ratio of the first plating film metal element is minimum or zero on the top surface of the plating film 4h. Needless to say, it is also possible to form one or more additional plating films on the plating film 4h.
- Various combinations are possible with respect to the metallic elements of the substrate 4g and the metallic elements of the anode, and it should be understood that the ones mentioned here are only non-limiting examples.
- Step S1 and step S2 do not have to be performed completely synchronously, and there may be a time difference between the start timing and the end timing (see FIG. 4). Moreover, step S1 and step S2 may be performed intermittently (see FIG. 5).
- step S3 is performed as a result of the running of the fastener chain, it is performed overlapping steps S1 and S2 along the time axis (see FIG. 4), or it is performed without overlapping steps S1 and S2 along the time axis. (complementary) (see FIG. 5).
- Step S4 is superimposed on steps S1 and S2 along the time axis.
- the metal element is supplied with electrons from the cathode, and metal ions derived from the anode are continuously deposited on the metal element.
- the magnetic media continuously collide with the plated film that grows with the deposition of metal ions.
- a plated film is formed on the metal element of the stopped fastener chain during the period between time t1 and time t2, and the magnetic media continuously collides with the plated film.
- the fastener chain is run for a predetermined distance. This is repeated to form a desired plating film on the metal element.
- the electroplating apparatus 100 has a plating bath 30 , a transport mechanism 40 , an alternating magnetic field generator 50 , and a running path 80 for the fastener chain 1 .
- the fastener chain 1 enters the plating bath 30 from outside the plating bath 30 via the rollers 41 and 42 of the transport mechanism 40, and passes from the inside of the plating bath 30 to the outside of the plating bath 30 via the rollers 43 and 44 of the transport mechanism 40. exit.
- a specific method for conveying the fastener chain 1 is arbitrary, and for example, a take-up roller, a gripper, or a roller pair (a combination of a drive roller and a pressure roller) can be used for the conveyance.
- the fastener chain 1 travels along the running path 80 in the plating bath 30 and includes a immersed portion immersed in the electrolytic solution 35 of the plating bath 30 and other portions.
- the plating bath 30 stores an electrolytic solution 35 in which one or more cathodes 10 and one or more anodes 20 are immersed.
- Plating bath 30 is an insulating vessel having a bottom plate 31 and side plates 32, optionally closable by a lid.
- the electrolytic solution 35 in the plating tank 30 is, for example, a cyanide plating solution, which is circulated between the external sub tanks. From the viewpoint of reducing the burden on the environment, it is preferable to use a plating solution that does not contain specific harmful substances such as cyanide, chromium, and selenium.
- a cathode 10 and an anode 20 are connected to a DC power supply E1, and a voltage is applied between them.
- the voltage application state can be controlled by turning on/off the switch SW.
- Anode 20 can be a soluble or insoluble anode.
- the metal element of the anode 20 is appropriately determined according to the target metal element of the plating film.
- the cathode 10 is provided in the electrolyte 35 away from the anode 20 in order to supply electrons to the metal elements 4a, 4b of the fastener chain 1 (to bring the metal elements 4a, 4b to a cathodic potential).
- the alternating magnetic field generator 50 generates an alternating magnetic field in the electrolytic solution 35 of the plating bath 30 .
- An alternating magnetic field means a magnetic field that changes in magnitude and direction with time.
- the running path 80 of the fastener chain 1 is provided so that the fastener chain 1 is arranged in the alternating magnetic field generated by the alternating magnetic field generating section 50 .
- the metal elements 4 a and 4 b of the fastener chain 1 pass through the alternating magnetic field generated by the alternating magnetic field generator 50 .
- a plurality of magnetic media move (for example, (rotation) and electrically connectable to the metal elements 4a and 4b via a plurality of magnetic media.
- a space is provided in which a plurality of magnetic media move according to the alternating magnetic field, and (ii) )
- the metal elements 4a and 4b are electrically connected to the cathode 10 via a plurality of magnetic media, and the plurality of magnetic media are provided for the plated film growing on the metal elements 4a and 4b. It is set so that it can collide.
- the support member 78 extends along a predetermined direction in which different magnetic poles are alternately arranged for generating an alternating magnetic field (for example, the circumferential direction and/or the rotational direction of the magnetic rotating portion 60 described later) in the longitudinal direction of the fastener chain 1 and , to control the position and orientation of the fastener chain 1 so that the fastener chain 1 faces the magnetic poles in a flat posture in its width direction. This promotes formation of a plated film with uniform quality and/or thickness.
- the alternating magnetic field generating section 50 includes a motor 61 and a magnetic rotating section 60 rotated by the motor 61 .
- Motor 61 is, for example, a DC or AC motor.
- different magnetic poles ie, N poles and S poles
- Permanent magnets, electromagnets, or combinations thereof can be used as the magnetic poles. In the case shown in FIG. 7, permanent magnets are used for the magnetic poles.
- the magnetic rotating section 60 has a rotating body 63 rotatably fixed to a rotating shaft 62 of a motor 61 and a plurality of permanent magnets 64 provided on the outer surface of the rotating body 63 .
- the rotating body 63 is, for example, a hollow cylindrical member made of stainless steel.
- Permanent magnets 64 may be rare earth magnets such as neodymium magnets, although other types are also possible. It is not essential to provide one motor 61 corresponding to one magnetic rotating portion 60 .
- the output of the motor 61 can also be supplied to multiple magnetic rotating parts 60 via a suitable drive train.
- the rotating shaft 62 of the motor 61 can be fixed to the opening of the bottom plate 31 of the plating tank 30 via waterproof bearings.
- the plurality of permanent magnets 64 are arranged so that the S poles and the N poles are alternately arranged in the rotation direction of the magnetic rotating portion 60 (see FIG. 8).
- the magnetic rotating portion 60 rotates in response to the operation of the motor 61 , the magnetic rotating portion 60 is alternately switched between the S pole and the N pole when viewed from a predetermined radially outer position of the magnetic rotating portion 60 .
- a magnetic medium e.g., a pin medium
- the rotational speed of the magnetic rotating portion 60 is, for example, 100 to 4,000 rpm.
- N pole placement zones Z1, Z3, Z5 in which permanent magnets 64 with N poles facing outward and permanent magnets 64 with S poles facing outward are arranged.
- the arranged S pole arrangement zones Z2 and Z4 can be provided alternately in the rotation direction of the magnetic rotating part 60.
- FIG. 8 the north pole zones Z1, Z3, Z5 and the south pole zones Z2, Z4 extend straight up and down in parallel with the rotation axis of the magnetic rotating part 60, but the configuration is not limited to this.
- the north pole placement zones Z1, Z3, Z5 and the south pole placement zones Z2, Z4 extend obliquely up and down non-parallel to the rotation axis of the magnetic rotating part 60, taking into consideration the sedimentation of the magnetic media due to gravity. , or extend in a zigzag up and down direction non-parallel to the rotation axis of the magnetic rotating portion 60 .
- the electroplating apparatus 100 further has a magnetically permeable housing 70, in which the magnetic rotating part 60 is rotatably and hermetically accommodated.
- the magnetically permeable housing 70 transmits the magnetic flux directed from the N pole to the S pole of the permanent magnet 64 of the magnetic rotating part 60 inside thereof, so that a magnetic field can be formed outside the magnetically permeable housing 70 .
- the magnetically permeable housing 70 does not rotate with the magnetic rotating part 60 under the operation of the motor 61 and remains stationary in place, e.g. are connected via By providing the magnetically permeable housing 70, the magnetic rotating part 60 can be protected from the electrolyte 35 and/or the rotational resistance of the magnetic rotating part 60 can be reduced.
- the magnetically permeable housing 70 is made of resin such as polypropylene, acryl, vinyl chloride, or the like.
- a plurality of support members 78 are provided on the outer surface of the magnetically permeable housing 70 as one or more supports for supporting the fastener chain 1 .
- the position and posture of the fastener chain 1 are controlled and the running path 80 is defined.
- the fastener chain 1 is supported in a flat posture by a support (for example, a support member 78).
- the fastener chain 1 can run in the circumferential direction around the magnetic rotating portion 60 , more specifically, at a radially outer position of the rotating shaft 62 of the magnetic rotating portion 60 .
- the fastener chain 1 can run in the vicinity of the magnetic rotating portion 60 by providing the support member 78 in the magnetically permeable housing 70 .
- the magnetic media can move greatly according to the alternating magnetic field, and the magnetic media can strongly collide with the plating film.
- a plurality of support members 78 are attached to the outer surface of magnetically permeable housing 70 to define a helical runway 80 for fastener chain 1 . Making the running path 80 spiral makes it possible to avoid an increase in the size of the electroplating apparatus 100 .
- Each support member 78 is an L-shaped member, more specifically, a first rod portion 78a extending radially outward from the rotation axis 62 of the magnetic rotating portion 60 and spaced apart from the outer surface of the magnetically permeable housing 70 by a predetermined distance. It has a second rod portion 78b extending upwardly.
- the first rod portion 78a prevents the fastener chain 1 from settling in the electrolytic solution 35 due to gravity.
- the second rod portion 78b prevents the fastener chain 1 from falling away from the outer surface of the magnetically permeable housing 70 due to gravity, magnetic media, water flow, or the like.
- Support member 78 may be secured to the perimeter of magnetically permeable housing 70 in any manner, such as by screwing or gluing.
- a cathode 10 can be provided on the outer surface of the magnetically permeable housing 70 .
- Cathode 10 is provided so as to extend along the running path of fastener chain 1 . This is expected to improve the electrical connection of the metal elements 4a and 4b to the cathode 10 via the magnetic media.
- the cathode 10 is provided spirally around the permeable housing 70 corresponding to the spiral running path 80 of the fastener chain 1 . Additionally or alternatively, the cathode 10 is provided at a position where the metal elements 4 a and 4 b of the fastener chain 1 running on the running path 80 face the cathode 10 .
- the permanent magnet 64 , the magnetically permeable housing 70 , the cathode 10 , the magnetic media, and the metal elements 4 a and 4 b are arranged coaxially in the radial direction with respect to the rotation axis of the magnetic rotating portion 60 .
- the cathode 10 When the cathode 10 is provided on the outer surface of the magnetically permeable housing 70 , an induced electromotive force is generated in the cathode 10 by the rotation of the magnetic rotating part 60 and an induced current flows through the cathode 10 . To reduce this effect, the cathode 10 is linear (rather than cylindrical) on the outer surface of the magnetically permeable housing 70 . The magnetic flux interlinking with the cathode 10 is reduced, and the induced electromotive force and induced current can be suppressed.
- the spiral cathode 10 can be constructed by spirally winding the linear cathode 10 around the outer surface of the magnetically permeable housing 70 .
- the linear cathode 10 may be provided on the outer surface of the magnetically permeable housing 70 in a manner other than spiral. Cathode 10 may be secured to the outer surface of magnetically permeable housing 70 by means of screws, adhesives, snap fit, or the like.
- the cathode 10 When the cathode 10 is provided linearly or spirally, the length of the cathode 10 becomes long.
- the cathode 10 in one magnetically permeable housing 70, can be provided with a plurality of contacts with the DC power supply E1, or the cathode 10 can be divided to provide individual contacts with the DC power supply E1. can be provided.
- a frame 72 can be used to arrange the anode 20 in the vicinity of the running path 80 of the fastener chain 1 (see FIG. 9).
- a plurality of anodes 20 can be arranged at different locations along the running path 80 of the fastener chain 1 by directly or indirectly attaching the plurality of anodes 20 to the frame 72 via a basket or the like.
- a mesh basket is attached to the frame 72, and a metal plate (functioning as the anode 20) is placed in the basket.
- the frame 72 is located radially outside the magnetically permeable housing 70 with respect to the rotating shaft 62 of the magnetic rotating portion 60 .
- the frame 72 is a cylindrical net member having horizontal members 73 spaced apart in the vertical direction and vertical members 74 connecting the horizontal members 73 together in the vertical direction.
- the frame 72 is constructed so as not to interfere with the running path 80 of the fastener chain 1.
- - ⁇ Metal ions eluted from the anode 20 can reach the metal elements 4 a and 4 b of the fastener chain 1 on the running path 80 through the mesh of the frame 72 .
- the anode 20 can also be placed near the running path 80 of the fastener chain 1 without using the frame 72 .
- the north pole arrangement zone of the magnetic rotating part 60 is located inside a predetermined position on the outer circumference of the magnetically permeable housing 70.
- the south pole arrangement zone of the magnetic rotating part 60 is positioned inside thereof.
- An appropriate amount of the magnetic media 9 exists between the cathode 10 and the metal elements 4a and 4b in either state of FIGS. 10(a) and 10(b).
- the magnetic flux is indicated by dashed lines in FIGS. 10(a) and 10(b).
- Each magnetic medium 9 rotates and displaces in the process of changing the direction of the magnetic flux from FIG. 10(a) to FIG. 10(b).
- the metal elements 4a and 4b can be electrically connected to the cathode 10 through a plurality of media before, after, or in the entire process regardless of changes in the orientation and displacement of each magnetic medium 9.
- FIG. Some magnetic media 9 collide with the growing plating film on the metal elements 4a, 4b as they rotate.
- the metal elements 4a and 4b are electrically connected to the cathode 10 via the other metal elements 4a and 4b even if they are not electrically connected to the cathode 10 via the magnetic media 9. can be
- the magnetic media 9 can be used to assist the transportation of the fastener chain 1.
- the rotational direction of the magnetic rotating portion 60 and the running direction of the fastener chain 1 running around it are set to be the same.
- the magnetic medium 9 not only rotates according to the alternating magnetic field, but also flows in the same direction as the magnetic rotating section 60 along with the permanent magnets 64 of the magnetic rotating section 60 .
- the flow of the magnetic media 9 pushes the fastener chain 1, making it easier for the fastener chain 1 to run in the same direction.
- the metal elements 4a, 4b of the fastener chain 1 have a first surface 5 facing the cathode 10 and a second surface 6 facing away from the cathode 10 (see FIG. 10). It is assumed that the anode 20 is arranged radially outside the fastener chain 1 from the magnetically permeable housing 70, and equivalent magnetic media are present on the first surface 5 side and the second surface 6 side of the metal elements 4a and 4b. Then, the growth rate of the plating film on the second surface 6 side of the metal elements 4a and 4b becomes higher than the growth rate of the plating film on the first surface 5 side of the metal elements 4a and 4b. In order to suppress the difference in the thickness of the plating film between the front and back surfaces of the metal elements 4a and 4b, it is preferable to turn over the fastener chain 1 on the travel path of the fastener chain 1.
- the plating tank 30 is provided with two alternating magnetic field generators 50, and the upstream spiral running path is provided on the outer periphery of the magnetically permeable housing 70 of the upstream alternating magnetic field generator 50.
- a spiral running path on the downstream side is provided on the outer circumference of the permeable housing 70 of the alternating magnetic field generating section 50 on the downstream side, and a reversing section 90 of the fastener chain 1 is provided between these spiral running paths.
- the reverse of the fastener chain 1 is achieved by reversing the running direction of the fastener chain 1 between the magnetically permeable housing 70 on the upstream side and the magnetically permeable housing 70 on the downstream side. That is, as shown in FIG. 11, when the plating bath 30 is viewed from above, the fastener chain 1 runs clockwise on the spiral running path on the upstream side and rotates counterclockwise on the spiral running path on the downstream side. run. In this manner, the fastener chain 1 is turned upside down, and the thickness of the plating film on the front and back sides of the metal elements 4a and 4b is made uniform. Note that the fastener chain 1 can be turned upside down by various other methods.
- the operation method of the electroplating apparatus 100 will be described with a focus on a predetermined portion of the fastener chain 1.
- a predetermined portion of the fastener chain 1 is guided by the rollers 41 and 42 and reaches the running path 80 in the electrolytic solution 35 .
- the magnetic rotating part 60 is rotating based on the operation of the motor 61, and an alternating magnetic field is generated around it.
- the running path 80 of the fastener chain 1 is arranged in an alternating magnetic field, where the magnetic media 9 are in motion.
- a voltage is applied between the cathode 10 and the anode 20 by a DC power supply E1.
- the metal elements 4 a and 4 b are electrically connected to the cathode 10 provided on the outer surface of the magnetically permeable housing 70 via the magnetic media 9 .
- the magnetic media 9 repeatedly collide with the plated films formed on the metal elements 4a and 4b. Growth of the plated film and collision of the magnetic media 9 against the plated film occur continuously during a period in which a predetermined portion of the fastener chain 1 travels from the lower end to the upper end of the spiral travel path 80 . In this way, formation of a sufficiently thick plated film is promoted while avoiding an increase in size of the electroplating apparatus 100 .
- a predetermined portion of the fastener chain 1 is then turned inside out and runs on the next spiral running path 80 in the opposite direction, that is, from its upper end to its lower end. During this running period, growth of the plated film and collision of the magnetic media 9 with the plated film occur continuously in the same manner as described above. In this manner, plating films are formed on the front and back surfaces of the metal elements 4a and 4b of the fastener chain 1. As shown in FIG. After running along the spiral running path 80 , a predetermined portion of the fastener chain 1 is guided by the rollers 43 and 44 and leaves the electrolytic solution 35 .
- Metal ions are also deposited on the contact portions of the metal elements 4a and 4b, forming a plating film.
- the engagement rows of the metal elements 4a and 4b along the longitudinal direction of the fastener chain 1 are continuously electrically connected to the cathode 10 through the magnetic media 9, thus The occurrence of a potential gradient in the engagement rows of the metal elements 4a, 4b along is suppressed.
- a sequencer can be used for on/off control of each motor 61 and on/off control of the switch SW. The sequencer may also be able to control the start/stop of transport of the fastener chain.
- the running path 80 of the fastener chain 1 is not necessarily helical, but may be linear, zigzag, or the like.
- the fastener chain 1 may be meanderingly wound around a plurality of magnetically permeable housings 70 , and this may be repeated along the rotation axis of the magnetic rotating portion 60 .
- FIG. 12 and 13 show a configuration in which four alternating magnetic field generators 50, four spiral running paths, and two front/back reversing sections 90 are provided.
- the fastener chain 1 runs clockwise on the first spiral running path, runs counterclockwise downward on the second spiral running path, and runs on the third spiral running path. Run counter-clockwise upwards, then clockwise downwards on the fourth spiral track.
- the fastener chain 1 runs counterclockwise upward on the first spiral running path, runs clockwise downward on the second spiral running path, and runs on the third spiral running path. Run clockwise upwards and counterclockwise downwards on the fourth spiral track.
- alternating magnetic field generators 50' are provided above and below the horizontal running path of the fastener chain 1.
- the alternating magnetic field generator 50' has a magnetic rotor 60' (the magnetic rotor is schematically shown in FIG. 15) and a magnetically permeable housing 70'.
- the magnetic rotating portion 60' is rotatably enclosed in a magnetically permeable housing 70' and rotates in response to motor operation.
- a plurality of magnetic rotating parts 6' may be provided in the magnetically permeable housing 70'.
- the rotating shaft of the motor is arranged horizontally.
- a running path 80 for the fastener chain 1 is provided between the upper and lower magnetically permeable housings 70'.
- the cathodes 10 are arranged vertically with a predetermined interval so as to sandwich the metal elements 4a and 4b of the fastener chain 1 running on the running path 80.
- Anodes 20 are arranged on both upper and lower sides of the fastener tape of the fastener chain 1 .
- the magnetic medium 9 rotates according to the rotation of the magnetic rotating part 60, the electrical connection between the cathode 10 and the metal elements 4a and 4b is ensured, and the plating film grows on the metal elements 4a and 4b.
- the magnetic media 9 repeatedly collide with the plating film. As a result, a plated film of good quality similar to that described above is formed.
- the fastener chain 1 passes through the pair of alternating magnetic field generators 50' only once. You may make it pass several times.
- FIG. 16 shows that the fastener chain 1 is supplied in the electrolytic solution of the plating bath 30 at a predetermined position and orientation, and a plating film is formed on the metal element by electroplating.
- one end is supported by one or more supports 120 and the other end is supported by another one or more supports 120 .
- the position and orientation of the fastener chain 1 can also be controlled in this way.
- the specific configuration of the support 120 may vary, and the number thereof may also vary. In the illustrated example, a total of four supports 120 are provided, two of which are assigned to one end of the fastener chain 1 and the other two to the other end of the fastener chain 1 .
- Each support 120 is composed of fixing members 121 , 124 , springs 122 and pressing balls 123 .
- the fixing members 121 and 124 are fixed at predetermined positions in the plating bath 30 .
- One end of the spring 122 is fixed to the fixing member 121 and the other end of the spring 122 is fixed to the pressing ball 123 .
- the fastener tape of the fastener chain 1 is sandwiched and positioned between the pressing ball 123 and the supporting surface of the fixing member 124 .
- running the fastener chain is not essential.
- the fastener stringers can also be supported in place and orientation by supports 120 in FIG.
- Example A plating film was formed on a metal element of a fastener chain using the plating apparatus shown in FIG. 13 of the present application.
- the rotational speed of the magnetic rotating portion is 400 rpm.
- the running speed of the fastener chain is 3.5 m/min.
- the power supply voltage was 1 V, and a current of 10 A was passed through each cathode. Electroplating time is 7 minutes.
- This fastener chain was sewn onto the denim fabric and washed. As the washing process, a dark color process to maintain the dark color of the denim fabric and a light color process to lighten the denim fabric were performed.
- the denim fabric with a zipper chain was pretreated, stonewashed, biowashed, and eco-bleached in this order.
- strong bleaching was further performed after eco-bleaching.
- the pretreatment was a step of hot water washing for desizing, which included washing with hot water at 90°C for 20 minutes, washing with hot water at 60°C for 5 minutes, and washing with hot water at 30°C for 5 minutes.
- Stonewashing is the process of co-washing with pumice stone and was washed for 30 minutes.
- Bio-washing is a process in which fibers are dissolved using an enzyme to soften the denim fabric, and the denim fabric is washed for 20 minutes with cellulase added to hot water at 55°C.
- Eco-bleaching is a process of removing the color of the denim fabric using glucose to bring out the whiteness.
- Glucose (20 g/L) and NaOH (15 g/L) were added to hot water at 90° C. and washed for 20 minutes.
- Bleaching is a process of removing the color of the denim fabric with a bleaching agent to bring out whiteness, and sodium hypochlorite was added and washed with hot water at 50° for 15 minutes.
- dyeing was also applied.
- the dyeing process the dyeing process using a sulfur dye and the dyeing process using a reactive dye were performed.
- alkaline materials, dyes, dyeing accelerators, and reducing agents (thiogen) are added to hot water at 50°, and denim fabric with a zipper chain is immersed at 85° for 20 minutes. rice field.
- the dyeing process using a reactive dye the reactive dye was put into hot water at a predetermined temperature, and the denim fabric with a fastener chain was immersed in it for a predetermined period of time.
- a further 24-hour salt spray test was carried out separately from the washing and dyeing processes.
- Comparative Examples 1 and 2 In Comparative Example 1, electroplating was performed by directly contacting the cathode electrode (for example, the conductive medium of Patent Documents 1 and 2) to the metal element. In Comparative Example 2, a plating film was formed on the metal element by an electroless plating method. The running speed of the fastener chain is 30 m/min. Subsequently, washing processing, dyeing processing, and a salt spray test were performed in the same manner as in Examples.
- the plating film of the metal element of the fastener chain manufactured by the manufacturing method (electroplating method) of the present disclosure is the same as the metal plating film of the fastener chain manufactured by the existing manufacturing method (electroplating method or electroless plating method). It was confirmed that it has processing resistance comparable to that of the plated film of the element.
- the uniformity of the surface of the plating layer of the metal element is higher in the example.
- the degree of glossiness of the plated layer of the metal element is kept high compared to the comparative examples 1 and 2.
- the uniformity and glossiness of the surface of the plating layer are improved.
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Abstract
Description
本願の図13に示すめっき装置を用いてファスナーチェーンの金属製エレメントにめっき膜を形成した。なお、磁性回転部の回転速度は、400rpmである。ファスナーチェーンの走行速度は、3.5m/分である。電源電圧は、1Vであり、各カソードに10Aの電流を流した。電気めっき時間は、7分である。このファスナーチェーンをデニム生地に対して縫い付け、洗い加工を施した。洗い加工として、デニム生地が濃色を維持する濃色加工と、デニム生地が淡色になる淡色加工を行った。 Example A plating film was formed on a metal element of a fastener chain using the plating apparatus shown in FIG. 13 of the present application. The rotational speed of the magnetic rotating portion is 400 rpm. The running speed of the fastener chain is 3.5 m/min. The power supply voltage was 1 V, and a current of 10 A was passed through each cathode. Electroplating time is 7 minutes. This fastener chain was sewn onto the denim fabric and washed. As the washing process, a dark color process to maintain the dark color of the denim fabric and a light color process to lighten the denim fabric were performed.
比較例1では、金属製エレメントに対してカソード電極(例えば、特許文献1,2の導電性媒体)を直接的に接触させて電気めっきを行った。比較例2では、無電解めっき方法によって金属製エレメントに対してめっき膜を形成した。ファスナーチェーンの走行速度は、30m/分である。続いて、実施例と同様に、洗い加工、染加工、及び塩水噴霧試験を施した。 Comparative Examples 1 and 2
In Comparative Example 1, electroplating was performed by directly contacting the cathode electrode (for example, the conductive medium of
2a :ファスナーストリンガー
2b :ファスナーストリンガー
4a :金属製エレメント
4b :金属製エレメント
7 :ファスナーチェーン
10 :カソード
20 :アノード
30 :めっき槽
35 :電解液
50 :交番磁界生成部
60 :磁性回転部
70 :透磁性ハウジング Reference Signs List 1:
Claims (25)
- 金属製エレメント(4a,4b)にめっき膜が生成されたファスナーチェーン(1)又はファスナーストリンガー(2a,2b)の製造方法であって、
めっき槽(30)の電解液中に少なくとも部分的に浸漬された1以上のカソード(10)と1以上のアノード(20)の間に電圧を印加する工程と、
前記1以上のカソード(10)と前記1以上のアノード(20)の間に電圧が印加されている時又は期間において前記電解液中に交番磁界を生成する工程と、
少なくとも前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記交番磁界が生成された空間に配されるように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向を制御する工程と、
前記交番磁界に応じて複数の磁性メディア(9)を運動させ、前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記複数の磁性メディア(9)を介して前記カソード(10)に電気的に接続し、かつ前記金属製エレメント(4a,4b)上で成長するめっき膜に対して前記複数の磁性メディア(9)が衝突する工程を含む、製造方法。 A method for manufacturing a fastener chain (1) or a fastener stringer (2a, 2b) in which a plating film is formed on metal elements (4a, 4b), comprising:
applying a voltage between one or more cathodes (10) and one or more anodes (20) at least partially immersed in the electrolyte of a plating bath (30);
generating an alternating magnetic field in the electrolyte when or during a voltage is applied between the one or more cathodes (10) and the one or more anodes (20);
The fastener chain (1) or the fastener is arranged such that at least the metal elements (4a, 4b) of the fastener chain (1) or the fastener stringer (2a, 2b) are arranged in the space where the alternating magnetic field is generated. controlling the position and orientation of the stringers (2a, 2b);
A plurality of magnetic media (9) are moved in accordance with the alternating magnetic field, and the metal elements (4a, 4b) of the fastener chain (1) or the fastener stringers (2a, 2b) move the plurality of magnetic media (9). ) to the cathode (10) and impinging the plurality of magnetic media (9) against a plated film growing on the metal elements (4a, 4b); Production method. - 前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の長手方向が前記交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項1に記載の製造方法。 The fastener chain (1) or the fastener is arranged such that the longitudinal direction of the fastener chain (1) or the fastener stringers (2a, 2b) is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. Method according to claim 1, characterized in that the position and orientation of the stringers (2a, 2b) are controlled.
- (i)前記金属製エレメント(4a,4b)の主面が前記磁極に関する磁軸に対して略直交するように、及び/又は、(ii)前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)がその幅方向において前記磁極に対して平坦な姿勢で対面するように、前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項2に記載の製造方法。 (i) the major faces of the metallic elements (4a, 4b) are substantially perpendicular to the magnetic axes with respect to the magnetic poles; and/or (ii) the fastener chain (1) or the fastener stringers (2a, 4b). The position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled so that the fastener chain (1) or the fastener stringers (2a, 2b) face the magnetic poles in a flat posture in the width direction thereof. Item 2. The manufacturing method according to item 2.
- 前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)が所定の走行路(80)において連続的又は断続的に走行することの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項1乃至3のいずれか一項に記載の製造方法。 As a result of the fastener chain (1) or the fastener stringers (2a, 2b) running continuously or intermittently on a predetermined running path (80), the fastener chain (1) or the fastener stringers (2a, 2b) ) is controlled in position and orientation.
- 前記所定の走行路(80)は、複数の支持部材(78)によって画定されることを特徴とする請求項4に記載の製造方法。 A method according to claim 4, characterized in that said predetermined travel path (80) is defined by a plurality of support members (78).
- 前記カソード(10)は、前記ファスナーチェーン(1)の走行路(80)に沿って延びることを特徴とする請求項4又は5に記載の製造方法。 The manufacturing method according to claim 4 or 5, characterized in that the cathode (10) extends along the running path (80) of the fastener chain (1).
- 前記1以上のアノード(20)は、前記ファスナーチェーン(1)の走行路(80)に沿って異なる場所に配置された複数のアノード(20)を含む、請求項4乃至6のいずれか一項に記載の製造方法。 7. Any one of claims 4 to 6, wherein said one or more anodes (20) comprises a plurality of anodes (20) arranged at different locations along the running path (80) of said fastener chain (1). The manufacturing method described in .
- 前記ファスナーチェーン(1)の走行路(80)は、1以上の螺旋状走行路(80)を含む、及び/又は、前記1以上のカソード(10)は、1以上の螺旋状カソード(10)を含むことを特徴とする請求項4乃至7のいずれか一項に記載の製造方法。 The runway (80) of the fastener chain (1) comprises one or more helical runways (80) and/or the one or more cathodes (10) comprise one or more helical cathodes (10) 8. The manufacturing method according to any one of claims 4 to 7, comprising:
- 前記電解液中に交番磁界を生成する工程は、異なる磁極が回転方向に交互に配置された1以上の磁性回転部(60)を回転させることを含むことを特徴とする請求項1乃至8のいずれか一項に記載の製造方法。 9. The method of any one of claims 1 to 8, wherein the step of generating an alternating magnetic field in the electrolyte comprises rotating one or more magnetic rotating parts (60) in which different magnetic poles are alternately arranged in the direction of rotation. The manufacturing method according to any one of the items.
- 前記磁性回転部(60)の周囲で前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9に記載の製造方法。 position and position of the fastener chain (1) or the fastener stringers (2a, 2b) as a result of running the fastener chain (1) or the fastener stringers (2a, 2b) around the magnetic rotating part (60); 10. The method of claim 9, wherein orientation is controlled.
- 前記磁性回転部(60)の周囲で螺旋状に前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9又は10に記載の製造方法。 As a result of running the fastener chain (1) or the fastener stringers (2a, 2b) spirally around the magnetic rotating part (60), the fastener chain (1) or the fastener stringers (2a, 2b) 11. A method according to claim 9 or 10, characterized in that the position and orientation of the are controlled.
- 前記磁性回転部(60)は、回転可能な態様で密閉された透磁性ハウジング(70)に収容されることを特徴とする請求項9乃至11のいずれか一項に記載の製造方法。 The manufacturing method according to any one of claims 9 to 11, characterized in that the magnetic rotating part (60) is housed in a magnetically permeable housing (70) which is sealed in a rotatable manner.
- 前記透磁性ハウジング(70)の外面には前記ファスナーチェーン(1)を支持するための複数の支持部材(78)が設けられることを特徴とする請求項12に記載の製造方法。 The manufacturing method according to claim 12, wherein the outer surface of the magnetically permeable housing (70) is provided with a plurality of support members (78) for supporting the fastener chain (1).
- 前記カソード(10)は、前記透磁性ハウジング(70)の外面に設けられた線状又は螺旋状カソード(10)を含む、請求項12又は13に記載の製造方法。 The manufacturing method according to claim 12 or 13, wherein the cathode (10) comprises a linear or spiral cathode (10) provided on the outer surface of the magnetically permeable housing (70).
- 前記電解液中に交番磁界を生成する工程は、前記1以上の磁性回転部(60)として設けられた異なる磁性回転部(60)それぞれを回転させることを含み、
前記異なる磁性回転部(60)に亘って前記ファスナーチェーン(1)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9乃至14のいずれか一項に記載の製造方法。 The step of generating an alternating magnetic field in the electrolytic solution includes rotating each of the different magnetic rotating parts (60) provided as the one or more magnetic rotating parts (60),
characterized in that the position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled as a result of running the fastener chain (1) over the different magnetic rotating parts (60). The manufacturing method according to any one of claims 9 to 14. - 前記異なる磁性回転部(60)に亘って前記ファスナーチェーン(1)を走行させることは、前記異なる磁性回転部(60)の周囲の螺旋状の走行路(80)において逆方向に前記ファスナーチェーン(1)を走行させることを含むことを特徴とする請求項15に記載の製造方法。 Running the fastener chain (1) over the different magnetic rotating parts (60) means that the fastener chain (1) is reversed in the spiral running path (80) around the different magnetic rotating parts (60). 16. The method of claim 15, comprising running 1).
- 前記ファスナーチェーン(1)は、前記異なる磁性回転部(60)の間で表裏が反転されることを特徴とする請求項15又は16に記載の製造方法。 The manufacturing method according to claim 15 or 16, wherein the fastener chain (1) is turned upside down between the different magnetic rotating parts (60).
- 前記磁性回転部(60)の回転方向に沿って前記ファスナーチェーン(1)が走行することの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9乃至17のいずれか一項に記載の製造方法。 The position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled as a result of the fastener chain (1) running along the rotational direction of the magnetic rotating part (60). 18. The manufacturing method according to any one of claims 9 to 17, characterized by:
- 請求項1乃至18のいずれか一項に記載の製造方法で得られたファスナーチェーン(1)を切断する工程と、
前記切断により得られた短尺なファスナーチェーン(1)に対してスライダーを取り付けて、前記短尺なファスナーチェーン(1)の一対のファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)の係合及び係合解除を可能とする工程を含む、スライドファスナーの製造方法。 A step of cutting a fastener chain (1) obtained by the manufacturing method according to any one of claims 1 to 18;
A slider is attached to the short fastener chain (1) obtained by the cutting, and the metal elements (4a, 4b) of the pair of fastener stringers (2a, 2b) of the short fastener chain (1) are cut. A method of manufacturing a slide fastener, comprising a step of enabling engagement and disengagement. - ファスナーチェーン(1)又はファスナーストリンガー(2a,2b)の金属製エレメント(4a,4b)にめっき膜を生成するための電気めっき装置(100)であって、
1以上のカソード(10)と1以上のアノード(20)が少なくとも部分的に浸漬される電解液を貯留するめっき槽(30)と、
前記めっき槽(30)の電解液中で交番磁界を生成する交番磁界生成部(50)と、
少なくとも前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記交番磁界が生成された空間に配されるように設けられた前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の1以上の支持具(78,42,43,120)を備え、
前記カソード(10)は、前記1以上の支持具(78,42,43,120)により支持された前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)と前記カソード(10)の間で複数の磁性メディア(9)が前記交番磁界に応じて運動することを許容し、かつ前記複数の磁性メディア(9)を介して前記金属製エレメント(4a,4b)に電気的に接続可能に設けられる、電気めっき装置。 An electroplating apparatus (100) for forming a plating film on metal elements (4a, 4b) of a fastener chain (1) or fastener stringers (2a, 2b),
a plating bath (30) containing an electrolyte in which one or more cathodes (10) and one or more anodes (20) are at least partially submerged;
an alternating magnetic field generator (50) for generating an alternating magnetic field in the electrolytic solution of the plating bath (30);
The fastener chain (1) provided such that at least the fastener chain (1) or the metal elements (4a, 4b) of the fastener stringers (2a, 2b) are arranged in the space where the alternating magnetic field is generated. or one or more supports (78, 42, 43, 120) of said fastener stringers (2a, 2b),
The cathode (10) comprises the metal elements (4a, 4b) of the fastener chain (1) or fastener stringers (2a, 2b) supported by the one or more supports (78, 42, 43, 120). ) and the cathode (10), allowing a plurality of magnetic media (9) to move in response to the alternating magnetic field, and through the plurality of magnetic media (9), the metal elements (4a, 4b) is electrically connectable to the electroplating apparatus. - 前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の長手方向が前記交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向を制御するように前記1以上の支持具(78,42,43,120)が設けられることを特徴とする請求項20に記載の電気めっき装置。 The fastener chain (1) or the fastener is arranged such that the longitudinal direction of the fastener chain (1) or the fastener stringers (2a, 2b) is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. 21. Electroplating apparatus according to claim 20, characterized in that the one or more supports (78, 42, 43, 120) are provided to control the position and orientation of the stringers (2a, 2b).
- 前記交番磁界生成部(50)は、異なる磁極が回転方向に交互に配置された1以上の磁性回転部(60)を含むことを特徴とする請求項20又は21に記載の電気めっき装置。 The electroplating apparatus according to claim 20 or 21, wherein the alternating magnetic field generator (50) includes one or more magnetic rotating parts (60) in which different magnetic poles are alternately arranged in the rotating direction.
- 前記磁性回転部(60)が、回転可能にかつ密閉された透磁性ハウジング(70)に収容されることを特徴とする請求項22に記載の電気めっき装置。 23. Electroplating apparatus according to claim 22, characterized in that said magnetic rotating part (60) is housed in a magnetically permeable housing (70) that is rotatable and sealed.
- 前記1以上の支持具(78,42,43,120)は、前記透磁性ハウジング(70)の外面に設けられた1以上の支持部材(78)を含むことを特徴とする請求項23に記載の電気めっき装置。 24. The method of claim 23, wherein said one or more supports (78, 42, 43, 120) comprise one or more support members (78) provided on an outer surface of said magnetically permeable housing (70). electroplating equipment.
- 前記カソード(10)は、前記1以上の支持具(78,42,43,120)により支持された前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の走行路(80)に沿って延びることを特徴とする請求項20乃至24のいずれか一項に記載の電気めっき装置。 The cathode (10) travels along the running path (80) of the fastener chain (1) or the fastener stringers (2a, 2b) supported by the one or more supports (78, 42, 43, 120). 25. The electroplating apparatus of any one of claims 20-24, wherein the electroplating apparatus extends.
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