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WO2023013054A1 - Production method for fastener stringer, fastener chain, and slide fastener, and electroplating apparatus - Google Patents

Production method for fastener stringer, fastener chain, and slide fastener, and electroplating apparatus Download PDF

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Publication number
WO2023013054A1
WO2023013054A1 PCT/JP2021/029394 JP2021029394W WO2023013054A1 WO 2023013054 A1 WO2023013054 A1 WO 2023013054A1 JP 2021029394 W JP2021029394 W JP 2021029394W WO 2023013054 A1 WO2023013054 A1 WO 2023013054A1
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WO
WIPO (PCT)
Prior art keywords
fastener
fastener chain
chain
stringers
magnetic
Prior art date
Application number
PCT/JP2021/029394
Other languages
French (fr)
Japanese (ja)
Inventor
侑己 瓜田
誠 佐々木
卓也 阿部
隆志 中村
雅之 飯森
諒佑 竹田
Original Assignee
Ykk株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ykk株式会社 filed Critical Ykk株式会社
Priority to PCT/JP2021/029394 priority Critical patent/WO2023013054A1/en
Priority to JP2023539564A priority patent/JP7600407B2/en
Priority to CN202180101364.7A priority patent/CN117836472A/en
Priority to TW111102511A priority patent/TWI787066B/en
Publication of WO2023013054A1 publication Critical patent/WO2023013054A1/en

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/22Electroplating combined with mechanical treatment during the deposition
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/02Slide fasteners

Definitions

  • the present disclosure relates to methods for manufacturing fastener stringers, fastener chains and slide fasteners, and electroplating equipment.
  • Patent Documents 1 and 2 disclose electroplating metal elements of fastener chains. As shown in FIGS. 3, 4, 5, etc. of Patent Document 1, a conductive medium 111 is accommodated in an insulating container 110, and a fastener chain 7 is passed through it. The metal element 3 of the fastener chain 7 and the plate-like cathode 118 are electrically connected via the conductive medium 111 .
  • the insulating container 110 is provided with an opening 116 to ensure contact between the metal element 3 and the plating solution.
  • the anode 119 is arranged to face the fastener chain 7 with the opening 116 of the insulating container 110 interposed therebetween. A plating film is formed on the metal element 3 mainly on the side facing the anode 119 .
  • a similar technique is also disclosed in Patent Document 2 (see FIGS. 2, 3, etc. of Patent Document 2).
  • Patent Documents 3 and 4 disclose that a substrate such as a button is put into a plating tank and electroplated.
  • a special plating layer is formed by using a permanent magnet to flow the magnetic media together with the base material such as the button, and plating while the magnetic media collides with the base material such as the button. is disclosed (see, for example, FIG. 20 of Patent Document 3 and FIG. 20 of Patent Document 4).
  • Patent Documents 3 and 4 are plating methods intended for small items such as buttons and sliders, and are not intended for long fastener chains in which elements are attached to fastener tapes.
  • Patent Document 5 discloses a technique in which a fastener chain is passed between an anode 23 and a cathode 24, and the fastener element on the anode 23 side is given a first metallic color, and the fastener element on the cathode 24 side is given a second metallic color. disclosed. In order to obtain these two metallic colors, the fastener element is arranged away from the cathode (see FIG. 1, paragraph 0012 of Patent Document 5).
  • a manufacturing method is a method for manufacturing a fastener chain or fastener stringer in which a plating film is formed on a metal element, and includes one or more fasteners at least partially immersed in an electrolytic solution in a plating bath.
  • the position and orientation of the fastener chain or fastener stringer may be controlled as a result of the fastener chain or fastener stringer traveling continuously or intermittently in a predetermined travel path, although this need not be the case.
  • the fastener chain manufacturing method can also be understood as an electroplating method for forming a plating film on the metal elements of the fastener chain.
  • a method for manufacturing a slide fastener includes steps of cutting the fastener chain obtained by the above-described manufacturing method, and attaching a slider to the short fastener chain obtained by the cutting to form a short fastener. It includes enabling the engagement and disengagement of the metallic elements of a pair of fastener stringers of the chain.
  • An electroplating apparatus for producing a plating film on metallic elements of fastener chains or fastener stringers, wherein one or more cathodes and one or more anodes are at least partially A plating bath for storing an electrolytic solution to be immersed in the plating bath, an alternating magnetic field generating section for generating an alternating magnetic field in the electrolytic solution of the plating bath, and a space where at least the metal element of the fastener chain or fastener stringer generates an alternating magnetic field.
  • the cathode allows a plurality of magnetic media to move in response to an alternating magnetic field between the cathode and the metallic elements of a fastener chain or fastener stringer supported by one or more supports, and through the plurality of magnetic media. is electrically connectable to the metal element.
  • the position and orientation of the fastener chain or fastener stringer is controlled such that the longitudinal direction of the fastener chain or fastener stringer is along a predetermined direction with alternating different magnetic poles for generating an alternating magnetic field.
  • One or more supports may be provided for this purpose.
  • the major faces of the metallic elements are substantially perpendicular to the magnetic axis with respect to the magnetic poles, and/or (ii) the fastener chains or stringers are aligned with the magnetic poles in their width direction. The position and orientation of the fastener chains or fastener stringers are controlled so that they face each other in a flat position.
  • the fastener chain runway includes one or more helical runways and/or the one or more cathodes include one or more helical cathodes.
  • generating an alternating magnetic field in the electrolyte includes rotating one or more magnetic rotating parts with different magnetic poles alternating in the direction of rotation.
  • the position and orientation of the fastener chain or fastener stringer is controlled as a result of running the fastener chain or fastener stringer (eg, spirally) around the magnetic rotating portion.
  • the magnetic rotating portion is housed in a magnetically permeable housing that is rotatably sealed.
  • the step of generating an alternating magnetic field in the electrolyte comprises rotating each of the different magnetic rotators provided as one or more magnetic rotators, wherein the fastener chain is rotated across the different magnetic rotators.
  • the position and orientation of the fastener chain or fastener stringer is controlled as a result of running the .
  • running the fastener chain over the different magnetic rotating parts includes running the fastener chain in opposite directions in a helical track around the different magnetic rotating parts.
  • the position and orientation of the fastener chain or fastener stringer is controlled as a result of the fastener chain running along the direction of rotation of the magnetic rotating portion.
  • a plating film can be formed on the metal element of the fastener chain by a new method different from existing methods.
  • FIG. 1 is a schematic diagram of a method of electroplating a metal element of a fastener chain according to one aspect of the present disclosure
  • FIG. It is a schematic diagram which shows an example of a fastener chain.
  • FIG. 4 is a schematic cross-sectional view showing a state in which a plating film is formed on the base material of the metal element; It is a time chart regarding an electroplating method. 4 is another time chart relating to the electroplating method;
  • 1 is a schematic diagram of an electroplating apparatus according to one aspect of the present disclosure;
  • FIG. 1 is a schematic side view of a magnetic rotating portion rotatably received in a magnetically permeable housing of an electroplating apparatus;
  • FIG. 3 is a schematic side view showing an arrangement example of permanent magnets in a magnetic rotating section
  • FIG. 4 is a schematic side view of a frame for mounting an anode outside the magnetically permeable housing of the electroplating apparatus
  • FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media, where (a) shows a state in which the magnetic media are placed in a magnetic field formed by a magnetic flux directed radially outward from the north pole of a permanent magnet; , (b) show the magnetic media placed in the magnetic field formed by the magnetic flux directed radially inward toward the S pole of the permanent magnet.
  • FIG. 4 is a schematic top view showing that the fastener chain is turned upside down between the spiral running paths.
  • FIG. 1 is a schematic diagram showing an electroplating apparatus provided with four helical tracks
  • FIG. FIG. 13 is a schematic diagram showing an electroplating apparatus according to another example provided with four spiral running paths, and the direction of rotation of the magnetic rotating portion is different from that in FIG. 12
  • FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure
  • FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media in an electroplating apparatus according to another aspect of the present disclosure
  • (b) shows a state in which the lower cathode is arranged between the bottom surface of the metallic element and the south pole, and (b) shows a state in which the upper cathode is arranged between the top surface of the metallic element and the south pole.
  • FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure. It is a table
  • a method for manufacturing a fastener chain according to the present disclosure includes four steps S1 to S4 schematically shown in FIG.
  • step S1 a voltage is applied between a cathode and an anode that are at least partially immersed in the electrolyte of the plating bath.
  • step S2 an alternating magnetic field is generated in the electrolyte when or during the time a voltage is applied between the cathode and the anode.
  • step S3 the position and orientation of the fastener chain are controlled such that at least the metallic elements of the fastener chain are arranged in the space in which the alternating magnetic field is generated.
  • the fastener chain is caused to travel continuously or intermittently along a predetermined path so that the fastener chain passes through an alternating magnetic field, thereby controlling the position and orientation of the fastener chain.
  • step S4 a plurality of magnetic media move according to the alternating magnetic field, the metal elements of the fastener chain are electrically connected to the cathode through the plurality of magnetic media, and the plating film growing on the metal elements A plurality of magnetic media collide with each other.
  • the step S4 can be achieved by performing the steps S1 and S2 while the magnetic media are put into the plating bath.
  • step S3 is performed as a result of running of the fastener chain, it can be performed so as to overlap with steps S1, S2, and S4 on the time axis, but this is not necessarily the case.
  • the growth of the plating film and the collision of the magnetic media against the plating film occur simultaneously, which promotes the formation of a plating film of sufficient quality (for example, sufficient processing resistance).
  • the position and orientation of the fastener chain is controlled to prevent the fastener tape from interfering with the electrical connection between the metallic element and the cathode.
  • the fastener chain 1 In order to increase the utilization efficiency of the alternating magnetic field, it is preferable to control the position and orientation of the fastener chain 1 so that the longitudinal direction of the fastener chain 1 is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. Furthermore, the fastener chain 1 is arranged so that the main surface of the metal element is substantially perpendicular to the magnetic axis of the magnetic pole and/or so that the fastener chain 1 faces the magnetic pole in a flat posture in its width direction. It is preferable to control the position and orientation of . This promotes formation of a plated film with uniform quality and/or thickness.
  • the flat posture means that the fastener chain 1 is not greatly bent in its width direction, and does not mean that both fastener tapes of the fastener chain 1 are flat enough to be arranged on the same plane. It also includes the occurrence of local bending and waviness in the fastener tape. Of course, the bent state in which the metal elements of the fastener chain 1 are covered with the fastener tape is not included in the above-described flat posture.
  • Substantially orthogonal, with respect to the orientation of the metallic elements means an angle within the range of 80° to 100°.
  • Electroplating can be performed efficiently if the position and orientation of the fastener chain 1 are controlled as a result of the fastener chain 1 running continuously or intermittently on the predetermined running path 80 .
  • the predetermined travel path 80 may be defined by a plurality of support members 78, but this is not necessarily the case.
  • the process of controlling the position and orientation of the fastener chain 1 can also be read as a process of continuously or intermittently running the fastener chain along a predetermined running path so that the fastener chain passes through the alternating magnetic field.
  • the above process can be performed on (one side) fastener stringer.
  • the method of manufacturing the fastener chain will be exclusively described, but the method of manufacturing (one side) of the fastener stringer can also be similarly applied, and redundant description will be omitted.
  • the magnetic media moves in response to an alternating magnetic field and has sufficient conductivity to ensure electrical connection (that is, short circuit) between the cathode 10 and the metal elements 4a and 4b.
  • Various shapes of magnetic media can be used, and in some cases non-spherical media are used.
  • pin media such as cylinders or prisms are used.
  • the pin media can be stainless steel pins with a diameter or maximum width on the order of 0.2 mm to 1.0 mm and a length of 3 mm to 15 mm. Ferromagnetic materials other than stainless steel can also be used.
  • the pin media rotates according to the alternating magnetic field (when the direction of the magnetic field changes, the pin media changes from the first posture corresponding to the direction of the magnetic field before the change to the second posture corresponding to the direction of the magnetic field after the change). do). Also, the pin media are displaced by being entrained by the magnetic poles. In addition to such pin media behavior, pin media collide with each other, and pin media collide with fastener chains (especially metal elements). Although the individual behavior of the pin media is chaotic, the collection of pin media maintains an electrical connection between the cathode and the metallic element continuously or intermittently rather than accidentally.
  • collision means that the rotational momentum and translational momentum obtained from the alternating magnetic field when the magnetic media are separated from the metal element (the magnetic media need not be separated from each other) are applied to the metal element.
  • the electrode and the object to be plated when the electrode and the object to be plated are in constant contact, the electrode and the object to be plated move relative to each other. They are different.
  • the collision of the magnetic media may flatten the plated film or scrape a part of its surface, resulting in a delay in the growth of the plated film.
  • the collision of the magnetic media with the plated film can improve the quality of the plated film (for example, processing resistance or adhesion to the substrate).
  • the collision can be said to mean collision with momentum that affects the change in the crystal structure of the plating layer.
  • the fastener chain 1 is a long object that extends in a predetermined direction with a predetermined width, and has a pair of fastener stringers 2a and 2b.
  • Each fastener stringer 2a, 2b has a fastener tape 3a, 3b and metallic elements 4a, 4b attached to the side edges of the fastener tape 3a, 3b.
  • a fastener chain 1 is formed by engaging metal elements 4a and 4b of a pair of fastener stringers 2a and 2b.
  • the metal elements 4a, 4b of the pair of fastener stringers 2a, 2b are engageable and disengageable in the same way using sliders (not shown).
  • the metal elements 4a are attached to the side edges of the fastener tape 3a at predetermined intervals, and therefore are not electrically connected to each other on the fastener tape 3a.
  • the metallic elements 4b are attached to the side edges of the fastener tape 3b at predetermined intervals and are therefore not electrically connected to each other on the fastener tape 3b.
  • the fastener chain 1 is made into a short fastener chain by a cutting process, a slider is attached to the short fastener chain, and then, if necessary, the fastener chain is cut. A fastener is attached.
  • a short fastener chain to which a slider (or a fastener in addition to this) is attached is generally called a slide fastener.
  • the fastener chain 1 is not attached with a slider, which is a constituent part of the slide fastener as the final product, and can be efficiently and smoothly conveyed downstream.
  • the fastener tapes 3a, 3b are flexible belts made of woven fabric, knitted fabric, or a mixture thereof.
  • the fastener tapes 3a and 3b have a pair of main surfaces, a surface visible from the front side of the fastener chain 1 and a back surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces.
  • the metal elements 4a, 4b are attached to the core cords of the fastener tapes 3a, 3b through their plastic deformation.
  • the metal elements 4a, 4b have a pair of legs attached to the side edges (typically core cords) of the fastener tapes 3a, 3b and a head connecting the pair of legs.
  • one side surface is provided with an engaging projection and the other side surface is provided with an engaging recess.
  • each of the aforementioned pair of side surfaces is provided with an engaging projection.
  • the metal elements 4a and 4b have a pair of main surfaces, a front surface visible from the front side of the fastener chain 1 and a rear surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces.
  • FIG. 3 is a conceptual diagram showing how the base material 4g of the metal elements 4a and 4b is coated with the plating film 4h.
  • the plated film 4h also contains the metal elements (Cu, Zn) of the substrate 4g in addition to tin (Sn).
  • the ratio of Cu and Zn (referred to as first plating film metal elements) in the plating film 4h decreases continuously as the plating film 4h is separated from the substrate 4g in the thickness direction.
  • the ratio of Sn corresponding to the anode (referred to as a second plating film metal element) decreases in the thickness direction of the plating film 4h as it approaches the substrate 4g.
  • the ratio of the second plating film metal element is maximum on the top surface of the plating film 4h, and the ratio of the first plating film metal element is minimum or zero on the top surface of the plating film 4h. Needless to say, it is also possible to form one or more additional plating films on the plating film 4h.
  • Various combinations are possible with respect to the metallic elements of the substrate 4g and the metallic elements of the anode, and it should be understood that the ones mentioned here are only non-limiting examples.
  • Step S1 and step S2 do not have to be performed completely synchronously, and there may be a time difference between the start timing and the end timing (see FIG. 4). Moreover, step S1 and step S2 may be performed intermittently (see FIG. 5).
  • step S3 is performed as a result of the running of the fastener chain, it is performed overlapping steps S1 and S2 along the time axis (see FIG. 4), or it is performed without overlapping steps S1 and S2 along the time axis. (complementary) (see FIG. 5).
  • Step S4 is superimposed on steps S1 and S2 along the time axis.
  • the metal element is supplied with electrons from the cathode, and metal ions derived from the anode are continuously deposited on the metal element.
  • the magnetic media continuously collide with the plated film that grows with the deposition of metal ions.
  • a plated film is formed on the metal element of the stopped fastener chain during the period between time t1 and time t2, and the magnetic media continuously collides with the plated film.
  • the fastener chain is run for a predetermined distance. This is repeated to form a desired plating film on the metal element.
  • the electroplating apparatus 100 has a plating bath 30 , a transport mechanism 40 , an alternating magnetic field generator 50 , and a running path 80 for the fastener chain 1 .
  • the fastener chain 1 enters the plating bath 30 from outside the plating bath 30 via the rollers 41 and 42 of the transport mechanism 40, and passes from the inside of the plating bath 30 to the outside of the plating bath 30 via the rollers 43 and 44 of the transport mechanism 40. exit.
  • a specific method for conveying the fastener chain 1 is arbitrary, and for example, a take-up roller, a gripper, or a roller pair (a combination of a drive roller and a pressure roller) can be used for the conveyance.
  • the fastener chain 1 travels along the running path 80 in the plating bath 30 and includes a immersed portion immersed in the electrolytic solution 35 of the plating bath 30 and other portions.
  • the plating bath 30 stores an electrolytic solution 35 in which one or more cathodes 10 and one or more anodes 20 are immersed.
  • Plating bath 30 is an insulating vessel having a bottom plate 31 and side plates 32, optionally closable by a lid.
  • the electrolytic solution 35 in the plating tank 30 is, for example, a cyanide plating solution, which is circulated between the external sub tanks. From the viewpoint of reducing the burden on the environment, it is preferable to use a plating solution that does not contain specific harmful substances such as cyanide, chromium, and selenium.
  • a cathode 10 and an anode 20 are connected to a DC power supply E1, and a voltage is applied between them.
  • the voltage application state can be controlled by turning on/off the switch SW.
  • Anode 20 can be a soluble or insoluble anode.
  • the metal element of the anode 20 is appropriately determined according to the target metal element of the plating film.
  • the cathode 10 is provided in the electrolyte 35 away from the anode 20 in order to supply electrons to the metal elements 4a, 4b of the fastener chain 1 (to bring the metal elements 4a, 4b to a cathodic potential).
  • the alternating magnetic field generator 50 generates an alternating magnetic field in the electrolytic solution 35 of the plating bath 30 .
  • An alternating magnetic field means a magnetic field that changes in magnitude and direction with time.
  • the running path 80 of the fastener chain 1 is provided so that the fastener chain 1 is arranged in the alternating magnetic field generated by the alternating magnetic field generating section 50 .
  • the metal elements 4 a and 4 b of the fastener chain 1 pass through the alternating magnetic field generated by the alternating magnetic field generator 50 .
  • a plurality of magnetic media move (for example, (rotation) and electrically connectable to the metal elements 4a and 4b via a plurality of magnetic media.
  • a space is provided in which a plurality of magnetic media move according to the alternating magnetic field, and (ii) )
  • the metal elements 4a and 4b are electrically connected to the cathode 10 via a plurality of magnetic media, and the plurality of magnetic media are provided for the plated film growing on the metal elements 4a and 4b. It is set so that it can collide.
  • the support member 78 extends along a predetermined direction in which different magnetic poles are alternately arranged for generating an alternating magnetic field (for example, the circumferential direction and/or the rotational direction of the magnetic rotating portion 60 described later) in the longitudinal direction of the fastener chain 1 and , to control the position and orientation of the fastener chain 1 so that the fastener chain 1 faces the magnetic poles in a flat posture in its width direction. This promotes formation of a plated film with uniform quality and/or thickness.
  • the alternating magnetic field generating section 50 includes a motor 61 and a magnetic rotating section 60 rotated by the motor 61 .
  • Motor 61 is, for example, a DC or AC motor.
  • different magnetic poles ie, N poles and S poles
  • Permanent magnets, electromagnets, or combinations thereof can be used as the magnetic poles. In the case shown in FIG. 7, permanent magnets are used for the magnetic poles.
  • the magnetic rotating section 60 has a rotating body 63 rotatably fixed to a rotating shaft 62 of a motor 61 and a plurality of permanent magnets 64 provided on the outer surface of the rotating body 63 .
  • the rotating body 63 is, for example, a hollow cylindrical member made of stainless steel.
  • Permanent magnets 64 may be rare earth magnets such as neodymium magnets, although other types are also possible. It is not essential to provide one motor 61 corresponding to one magnetic rotating portion 60 .
  • the output of the motor 61 can also be supplied to multiple magnetic rotating parts 60 via a suitable drive train.
  • the rotating shaft 62 of the motor 61 can be fixed to the opening of the bottom plate 31 of the plating tank 30 via waterproof bearings.
  • the plurality of permanent magnets 64 are arranged so that the S poles and the N poles are alternately arranged in the rotation direction of the magnetic rotating portion 60 (see FIG. 8).
  • the magnetic rotating portion 60 rotates in response to the operation of the motor 61 , the magnetic rotating portion 60 is alternately switched between the S pole and the N pole when viewed from a predetermined radially outer position of the magnetic rotating portion 60 .
  • a magnetic medium e.g., a pin medium
  • the rotational speed of the magnetic rotating portion 60 is, for example, 100 to 4,000 rpm.
  • N pole placement zones Z1, Z3, Z5 in which permanent magnets 64 with N poles facing outward and permanent magnets 64 with S poles facing outward are arranged.
  • the arranged S pole arrangement zones Z2 and Z4 can be provided alternately in the rotation direction of the magnetic rotating part 60.
  • FIG. 8 the north pole zones Z1, Z3, Z5 and the south pole zones Z2, Z4 extend straight up and down in parallel with the rotation axis of the magnetic rotating part 60, but the configuration is not limited to this.
  • the north pole placement zones Z1, Z3, Z5 and the south pole placement zones Z2, Z4 extend obliquely up and down non-parallel to the rotation axis of the magnetic rotating part 60, taking into consideration the sedimentation of the magnetic media due to gravity. , or extend in a zigzag up and down direction non-parallel to the rotation axis of the magnetic rotating portion 60 .
  • the electroplating apparatus 100 further has a magnetically permeable housing 70, in which the magnetic rotating part 60 is rotatably and hermetically accommodated.
  • the magnetically permeable housing 70 transmits the magnetic flux directed from the N pole to the S pole of the permanent magnet 64 of the magnetic rotating part 60 inside thereof, so that a magnetic field can be formed outside the magnetically permeable housing 70 .
  • the magnetically permeable housing 70 does not rotate with the magnetic rotating part 60 under the operation of the motor 61 and remains stationary in place, e.g. are connected via By providing the magnetically permeable housing 70, the magnetic rotating part 60 can be protected from the electrolyte 35 and/or the rotational resistance of the magnetic rotating part 60 can be reduced.
  • the magnetically permeable housing 70 is made of resin such as polypropylene, acryl, vinyl chloride, or the like.
  • a plurality of support members 78 are provided on the outer surface of the magnetically permeable housing 70 as one or more supports for supporting the fastener chain 1 .
  • the position and posture of the fastener chain 1 are controlled and the running path 80 is defined.
  • the fastener chain 1 is supported in a flat posture by a support (for example, a support member 78).
  • the fastener chain 1 can run in the circumferential direction around the magnetic rotating portion 60 , more specifically, at a radially outer position of the rotating shaft 62 of the magnetic rotating portion 60 .
  • the fastener chain 1 can run in the vicinity of the magnetic rotating portion 60 by providing the support member 78 in the magnetically permeable housing 70 .
  • the magnetic media can move greatly according to the alternating magnetic field, and the magnetic media can strongly collide with the plating film.
  • a plurality of support members 78 are attached to the outer surface of magnetically permeable housing 70 to define a helical runway 80 for fastener chain 1 . Making the running path 80 spiral makes it possible to avoid an increase in the size of the electroplating apparatus 100 .
  • Each support member 78 is an L-shaped member, more specifically, a first rod portion 78a extending radially outward from the rotation axis 62 of the magnetic rotating portion 60 and spaced apart from the outer surface of the magnetically permeable housing 70 by a predetermined distance. It has a second rod portion 78b extending upwardly.
  • the first rod portion 78a prevents the fastener chain 1 from settling in the electrolytic solution 35 due to gravity.
  • the second rod portion 78b prevents the fastener chain 1 from falling away from the outer surface of the magnetically permeable housing 70 due to gravity, magnetic media, water flow, or the like.
  • Support member 78 may be secured to the perimeter of magnetically permeable housing 70 in any manner, such as by screwing or gluing.
  • a cathode 10 can be provided on the outer surface of the magnetically permeable housing 70 .
  • Cathode 10 is provided so as to extend along the running path of fastener chain 1 . This is expected to improve the electrical connection of the metal elements 4a and 4b to the cathode 10 via the magnetic media.
  • the cathode 10 is provided spirally around the permeable housing 70 corresponding to the spiral running path 80 of the fastener chain 1 . Additionally or alternatively, the cathode 10 is provided at a position where the metal elements 4 a and 4 b of the fastener chain 1 running on the running path 80 face the cathode 10 .
  • the permanent magnet 64 , the magnetically permeable housing 70 , the cathode 10 , the magnetic media, and the metal elements 4 a and 4 b are arranged coaxially in the radial direction with respect to the rotation axis of the magnetic rotating portion 60 .
  • the cathode 10 When the cathode 10 is provided on the outer surface of the magnetically permeable housing 70 , an induced electromotive force is generated in the cathode 10 by the rotation of the magnetic rotating part 60 and an induced current flows through the cathode 10 . To reduce this effect, the cathode 10 is linear (rather than cylindrical) on the outer surface of the magnetically permeable housing 70 . The magnetic flux interlinking with the cathode 10 is reduced, and the induced electromotive force and induced current can be suppressed.
  • the spiral cathode 10 can be constructed by spirally winding the linear cathode 10 around the outer surface of the magnetically permeable housing 70 .
  • the linear cathode 10 may be provided on the outer surface of the magnetically permeable housing 70 in a manner other than spiral. Cathode 10 may be secured to the outer surface of magnetically permeable housing 70 by means of screws, adhesives, snap fit, or the like.
  • the cathode 10 When the cathode 10 is provided linearly or spirally, the length of the cathode 10 becomes long.
  • the cathode 10 in one magnetically permeable housing 70, can be provided with a plurality of contacts with the DC power supply E1, or the cathode 10 can be divided to provide individual contacts with the DC power supply E1. can be provided.
  • a frame 72 can be used to arrange the anode 20 in the vicinity of the running path 80 of the fastener chain 1 (see FIG. 9).
  • a plurality of anodes 20 can be arranged at different locations along the running path 80 of the fastener chain 1 by directly or indirectly attaching the plurality of anodes 20 to the frame 72 via a basket or the like.
  • a mesh basket is attached to the frame 72, and a metal plate (functioning as the anode 20) is placed in the basket.
  • the frame 72 is located radially outside the magnetically permeable housing 70 with respect to the rotating shaft 62 of the magnetic rotating portion 60 .
  • the frame 72 is a cylindrical net member having horizontal members 73 spaced apart in the vertical direction and vertical members 74 connecting the horizontal members 73 together in the vertical direction.
  • the frame 72 is constructed so as not to interfere with the running path 80 of the fastener chain 1.
  • - ⁇ Metal ions eluted from the anode 20 can reach the metal elements 4 a and 4 b of the fastener chain 1 on the running path 80 through the mesh of the frame 72 .
  • the anode 20 can also be placed near the running path 80 of the fastener chain 1 without using the frame 72 .
  • the north pole arrangement zone of the magnetic rotating part 60 is located inside a predetermined position on the outer circumference of the magnetically permeable housing 70.
  • the south pole arrangement zone of the magnetic rotating part 60 is positioned inside thereof.
  • An appropriate amount of the magnetic media 9 exists between the cathode 10 and the metal elements 4a and 4b in either state of FIGS. 10(a) and 10(b).
  • the magnetic flux is indicated by dashed lines in FIGS. 10(a) and 10(b).
  • Each magnetic medium 9 rotates and displaces in the process of changing the direction of the magnetic flux from FIG. 10(a) to FIG. 10(b).
  • the metal elements 4a and 4b can be electrically connected to the cathode 10 through a plurality of media before, after, or in the entire process regardless of changes in the orientation and displacement of each magnetic medium 9.
  • FIG. Some magnetic media 9 collide with the growing plating film on the metal elements 4a, 4b as they rotate.
  • the metal elements 4a and 4b are electrically connected to the cathode 10 via the other metal elements 4a and 4b even if they are not electrically connected to the cathode 10 via the magnetic media 9. can be
  • the magnetic media 9 can be used to assist the transportation of the fastener chain 1.
  • the rotational direction of the magnetic rotating portion 60 and the running direction of the fastener chain 1 running around it are set to be the same.
  • the magnetic medium 9 not only rotates according to the alternating magnetic field, but also flows in the same direction as the magnetic rotating section 60 along with the permanent magnets 64 of the magnetic rotating section 60 .
  • the flow of the magnetic media 9 pushes the fastener chain 1, making it easier for the fastener chain 1 to run in the same direction.
  • the metal elements 4a, 4b of the fastener chain 1 have a first surface 5 facing the cathode 10 and a second surface 6 facing away from the cathode 10 (see FIG. 10). It is assumed that the anode 20 is arranged radially outside the fastener chain 1 from the magnetically permeable housing 70, and equivalent magnetic media are present on the first surface 5 side and the second surface 6 side of the metal elements 4a and 4b. Then, the growth rate of the plating film on the second surface 6 side of the metal elements 4a and 4b becomes higher than the growth rate of the plating film on the first surface 5 side of the metal elements 4a and 4b. In order to suppress the difference in the thickness of the plating film between the front and back surfaces of the metal elements 4a and 4b, it is preferable to turn over the fastener chain 1 on the travel path of the fastener chain 1.
  • the plating tank 30 is provided with two alternating magnetic field generators 50, and the upstream spiral running path is provided on the outer periphery of the magnetically permeable housing 70 of the upstream alternating magnetic field generator 50.
  • a spiral running path on the downstream side is provided on the outer circumference of the permeable housing 70 of the alternating magnetic field generating section 50 on the downstream side, and a reversing section 90 of the fastener chain 1 is provided between these spiral running paths.
  • the reverse of the fastener chain 1 is achieved by reversing the running direction of the fastener chain 1 between the magnetically permeable housing 70 on the upstream side and the magnetically permeable housing 70 on the downstream side. That is, as shown in FIG. 11, when the plating bath 30 is viewed from above, the fastener chain 1 runs clockwise on the spiral running path on the upstream side and rotates counterclockwise on the spiral running path on the downstream side. run. In this manner, the fastener chain 1 is turned upside down, and the thickness of the plating film on the front and back sides of the metal elements 4a and 4b is made uniform. Note that the fastener chain 1 can be turned upside down by various other methods.
  • the operation method of the electroplating apparatus 100 will be described with a focus on a predetermined portion of the fastener chain 1.
  • a predetermined portion of the fastener chain 1 is guided by the rollers 41 and 42 and reaches the running path 80 in the electrolytic solution 35 .
  • the magnetic rotating part 60 is rotating based on the operation of the motor 61, and an alternating magnetic field is generated around it.
  • the running path 80 of the fastener chain 1 is arranged in an alternating magnetic field, where the magnetic media 9 are in motion.
  • a voltage is applied between the cathode 10 and the anode 20 by a DC power supply E1.
  • the metal elements 4 a and 4 b are electrically connected to the cathode 10 provided on the outer surface of the magnetically permeable housing 70 via the magnetic media 9 .
  • the magnetic media 9 repeatedly collide with the plated films formed on the metal elements 4a and 4b. Growth of the plated film and collision of the magnetic media 9 against the plated film occur continuously during a period in which a predetermined portion of the fastener chain 1 travels from the lower end to the upper end of the spiral travel path 80 . In this way, formation of a sufficiently thick plated film is promoted while avoiding an increase in size of the electroplating apparatus 100 .
  • a predetermined portion of the fastener chain 1 is then turned inside out and runs on the next spiral running path 80 in the opposite direction, that is, from its upper end to its lower end. During this running period, growth of the plated film and collision of the magnetic media 9 with the plated film occur continuously in the same manner as described above. In this manner, plating films are formed on the front and back surfaces of the metal elements 4a and 4b of the fastener chain 1. As shown in FIG. After running along the spiral running path 80 , a predetermined portion of the fastener chain 1 is guided by the rollers 43 and 44 and leaves the electrolytic solution 35 .
  • Metal ions are also deposited on the contact portions of the metal elements 4a and 4b, forming a plating film.
  • the engagement rows of the metal elements 4a and 4b along the longitudinal direction of the fastener chain 1 are continuously electrically connected to the cathode 10 through the magnetic media 9, thus The occurrence of a potential gradient in the engagement rows of the metal elements 4a, 4b along is suppressed.
  • a sequencer can be used for on/off control of each motor 61 and on/off control of the switch SW. The sequencer may also be able to control the start/stop of transport of the fastener chain.
  • the running path 80 of the fastener chain 1 is not necessarily helical, but may be linear, zigzag, or the like.
  • the fastener chain 1 may be meanderingly wound around a plurality of magnetically permeable housings 70 , and this may be repeated along the rotation axis of the magnetic rotating portion 60 .
  • FIG. 12 and 13 show a configuration in which four alternating magnetic field generators 50, four spiral running paths, and two front/back reversing sections 90 are provided.
  • the fastener chain 1 runs clockwise on the first spiral running path, runs counterclockwise downward on the second spiral running path, and runs on the third spiral running path. Run counter-clockwise upwards, then clockwise downwards on the fourth spiral track.
  • the fastener chain 1 runs counterclockwise upward on the first spiral running path, runs clockwise downward on the second spiral running path, and runs on the third spiral running path. Run clockwise upwards and counterclockwise downwards on the fourth spiral track.
  • alternating magnetic field generators 50' are provided above and below the horizontal running path of the fastener chain 1.
  • the alternating magnetic field generator 50' has a magnetic rotor 60' (the magnetic rotor is schematically shown in FIG. 15) and a magnetically permeable housing 70'.
  • the magnetic rotating portion 60' is rotatably enclosed in a magnetically permeable housing 70' and rotates in response to motor operation.
  • a plurality of magnetic rotating parts 6' may be provided in the magnetically permeable housing 70'.
  • the rotating shaft of the motor is arranged horizontally.
  • a running path 80 for the fastener chain 1 is provided between the upper and lower magnetically permeable housings 70'.
  • the cathodes 10 are arranged vertically with a predetermined interval so as to sandwich the metal elements 4a and 4b of the fastener chain 1 running on the running path 80.
  • Anodes 20 are arranged on both upper and lower sides of the fastener tape of the fastener chain 1 .
  • the magnetic medium 9 rotates according to the rotation of the magnetic rotating part 60, the electrical connection between the cathode 10 and the metal elements 4a and 4b is ensured, and the plating film grows on the metal elements 4a and 4b.
  • the magnetic media 9 repeatedly collide with the plating film. As a result, a plated film of good quality similar to that described above is formed.
  • the fastener chain 1 passes through the pair of alternating magnetic field generators 50' only once. You may make it pass several times.
  • FIG. 16 shows that the fastener chain 1 is supplied in the electrolytic solution of the plating bath 30 at a predetermined position and orientation, and a plating film is formed on the metal element by electroplating.
  • one end is supported by one or more supports 120 and the other end is supported by another one or more supports 120 .
  • the position and orientation of the fastener chain 1 can also be controlled in this way.
  • the specific configuration of the support 120 may vary, and the number thereof may also vary. In the illustrated example, a total of four supports 120 are provided, two of which are assigned to one end of the fastener chain 1 and the other two to the other end of the fastener chain 1 .
  • Each support 120 is composed of fixing members 121 , 124 , springs 122 and pressing balls 123 .
  • the fixing members 121 and 124 are fixed at predetermined positions in the plating bath 30 .
  • One end of the spring 122 is fixed to the fixing member 121 and the other end of the spring 122 is fixed to the pressing ball 123 .
  • the fastener tape of the fastener chain 1 is sandwiched and positioned between the pressing ball 123 and the supporting surface of the fixing member 124 .
  • running the fastener chain is not essential.
  • the fastener stringers can also be supported in place and orientation by supports 120 in FIG.
  • Example A plating film was formed on a metal element of a fastener chain using the plating apparatus shown in FIG. 13 of the present application.
  • the rotational speed of the magnetic rotating portion is 400 rpm.
  • the running speed of the fastener chain is 3.5 m/min.
  • the power supply voltage was 1 V, and a current of 10 A was passed through each cathode. Electroplating time is 7 minutes.
  • This fastener chain was sewn onto the denim fabric and washed. As the washing process, a dark color process to maintain the dark color of the denim fabric and a light color process to lighten the denim fabric were performed.
  • the denim fabric with a zipper chain was pretreated, stonewashed, biowashed, and eco-bleached in this order.
  • strong bleaching was further performed after eco-bleaching.
  • the pretreatment was a step of hot water washing for desizing, which included washing with hot water at 90°C for 20 minutes, washing with hot water at 60°C for 5 minutes, and washing with hot water at 30°C for 5 minutes.
  • Stonewashing is the process of co-washing with pumice stone and was washed for 30 minutes.
  • Bio-washing is a process in which fibers are dissolved using an enzyme to soften the denim fabric, and the denim fabric is washed for 20 minutes with cellulase added to hot water at 55°C.
  • Eco-bleaching is a process of removing the color of the denim fabric using glucose to bring out the whiteness.
  • Glucose (20 g/L) and NaOH (15 g/L) were added to hot water at 90° C. and washed for 20 minutes.
  • Bleaching is a process of removing the color of the denim fabric with a bleaching agent to bring out whiteness, and sodium hypochlorite was added and washed with hot water at 50° for 15 minutes.
  • dyeing was also applied.
  • the dyeing process the dyeing process using a sulfur dye and the dyeing process using a reactive dye were performed.
  • alkaline materials, dyes, dyeing accelerators, and reducing agents (thiogen) are added to hot water at 50°, and denim fabric with a zipper chain is immersed at 85° for 20 minutes. rice field.
  • the dyeing process using a reactive dye the reactive dye was put into hot water at a predetermined temperature, and the denim fabric with a fastener chain was immersed in it for a predetermined period of time.
  • a further 24-hour salt spray test was carried out separately from the washing and dyeing processes.
  • Comparative Examples 1 and 2 In Comparative Example 1, electroplating was performed by directly contacting the cathode electrode (for example, the conductive medium of Patent Documents 1 and 2) to the metal element. In Comparative Example 2, a plating film was formed on the metal element by an electroless plating method. The running speed of the fastener chain is 30 m/min. Subsequently, washing processing, dyeing processing, and a salt spray test were performed in the same manner as in Examples.
  • the plating film of the metal element of the fastener chain manufactured by the manufacturing method (electroplating method) of the present disclosure is the same as the metal plating film of the fastener chain manufactured by the existing manufacturing method (electroplating method or electroless plating method). It was confirmed that it has processing resistance comparable to that of the plated film of the element.
  • the uniformity of the surface of the plating layer of the metal element is higher in the example.
  • the degree of glossiness of the plated layer of the metal element is kept high compared to the comparative examples 1 and 2.
  • the uniformity and glossiness of the surface of the plating layer are improved.

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Abstract

A production method for a fastener chain (1) or fastener stringers (2a, 2b) comprising: a step for applying a voltage between at least one anode (20) and at least one cathode (10) at least partially immersed in an electrolyte solution in a plating bath (30); a step for generating an alternating magnetic field in the electrolyte solution when or during periods in which voltage is applied between at least one cathode (10) and at least one anode (20); a step for controlling the position and orientation of the fastener chain (1) or fastener stringers (2a, 2b) so that at least the metal elements (4a, 4b) of the fastener chain (1) or fastener stringers (2a, 2b) are disposed in the space in which the alternating magnetic field is generated; and a step in which a plurality of magnetic media (9) are moved in response to the alternating magnetic field, the metal elements (4a, 4b) are electrically connected to the cathode (10) via the plurality of magnetic media (9), and the plurality of magnetic media (9) are made to impact the plating film that is developing on the metal elements (4a, 4b).

Description

ファスナーストリンガー、ファスナーチェーン及びスライドファスナーの製造方法、並びに電気めっき装置Method for manufacturing fastener stringer, fastener chain and slide fastener, and electroplating device
 本開示は、ファスナーストリンガー、ファスナーチェーン及びスライドファスナーの製造方法、並びに電気めっき装置に関する。 The present disclosure relates to methods for manufacturing fastener stringers, fastener chains and slide fasteners, and electroplating equipment.
 特許文献1,2には、ファスナーチェーンの金属製エレメントに対して電気めっきをすることが開示されている。特許文献1の図3,4,5等に図示のように、絶縁性容器110内に導電性媒体111を収容し、ファスナーチェーン7を通過させている。ファスナーチェーン7の金属製エレメント3と板状陰極118が導電性媒体111を介して電気的に接続されている。絶縁性容器110には開口116が設けられており、金属製エレメント3とめっき液の接触が確保されている。陽極119は、絶縁性容器110の開口116を間に挟んでファスナーチェーン7に対向して配置される。金属製エレメント3には主に陽極119に対向する側でめっき膜が形成される。特許文献2にも同様の技術が開示されている(特許文献2の図2,3等参照)。 Patent Documents 1 and 2 disclose electroplating metal elements of fastener chains. As shown in FIGS. 3, 4, 5, etc. of Patent Document 1, a conductive medium 111 is accommodated in an insulating container 110, and a fastener chain 7 is passed through it. The metal element 3 of the fastener chain 7 and the plate-like cathode 118 are electrically connected via the conductive medium 111 . The insulating container 110 is provided with an opening 116 to ensure contact between the metal element 3 and the plating solution. The anode 119 is arranged to face the fastener chain 7 with the opening 116 of the insulating container 110 interposed therebetween. A plating film is formed on the metal element 3 mainly on the side facing the anode 119 . A similar technique is also disclosed in Patent Document 2 (see FIGS. 2, 3, etc. of Patent Document 2).
 特許文献3,4には、ボタン等の基材をめっき槽に投入して電気めっきをすることが開示されている。特には、永久磁石を用いて磁性メディアをボタン等の基材と一緒に流動させて、磁性メディアをボタン等の基材に衝突させながらめっきを行うことで、特殊なめっき層が形成されることが開示されている(例えば、特許文献3の図20及び特許文献4の図20参照)。特許文献3,4はボタンやスライダーのような小物を対象としためっき方法であり、ファスナーテープにエレメントが取り付けられた状態の長尺のファスナーチェーンを対象とするものではない。 Patent Documents 3 and 4 disclose that a substrate such as a button is put into a plating tank and electroplated. In particular, a special plating layer is formed by using a permanent magnet to flow the magnetic media together with the base material such as the button, and plating while the magnetic media collides with the base material such as the button. is disclosed (see, for example, FIG. 20 of Patent Document 3 and FIG. 20 of Patent Document 4). Patent Documents 3 and 4 are plating methods intended for small items such as buttons and sliders, and are not intended for long fastener chains in which elements are attached to fastener tapes.
 特許文献5には、ファスナーチェーンを陽極23と陰極24の間を通過させ、陽極23側でファスナーエレメントを第1の金属色とし、陰極24側でファスナーエレメントを第2の金属色とする技術が開示されている。なお、この2色の金属色を得るため、ファスナーエレメントは、カソードから離れて配置される(特許文献5の図1、段落0012参照)。 Patent Document 5 discloses a technique in which a fastener chain is passed between an anode 23 and a cathode 24, and the fastener element on the anode 23 side is given a first metallic color, and the fastener element on the cathode 24 side is given a second metallic color. disclosed. In order to obtain these two metallic colors, the fastener element is arranged away from the cathode (see FIG. 1, paragraph 0012 of Patent Document 5).
国際公開第2018/109983号WO2018/109983 国際公開第2018/109998号WO2018/109998 国際公開第2018/189916号WO2018/189916 国際公開第2018/190202号WO2018/190202 国際公開第2016/075828号WO2016/075828
 既存の方法とは異なる新たな方法でファスナーチェーンの金属製エレメントにめっき膜を形成することに意義がある。なお、特許文献3,4の基材(端的には、ボタンのシェル)の代替としてファスナーストリンガー又はファスナーチェーンをめっき槽に投入する場合、その撹拌がうまくできず、また、ファスナーテープにより金属製エレメントとカソードの電気的な接続が阻害されてしまうおそれがある。  There is significance in forming a plating film on the metal elements of the fastener chain using a new method that is different from existing methods. In addition, when a fastener stringer or fastener chain is put into the plating tank as a substitute for the base material (simply, button shell) of Patent Documents 3 and 4, the agitation cannot be performed well, and the fastener tape prevents the metal element from and cathode electrical connection may be disturbed.
 本開示の一態様に係る製造方法は、金属製エレメントにめっき膜が生成されたファスナーチェーン又はファスナーストリンガーの製造方法であって、めっき槽の電解液中に少なくとも部分的に浸漬された1以上のカソードと1以上のアノードの間に電圧を印加する工程と、1以上のカソードと1以上のアノードの間に電圧が印加されている時又は期間において電解液中に交番磁界を生成する工程と、少なくともファスナーチェーン又はファスナーストリンガーの金属製エレメントが交番磁界が生成された空間に配されるようにファスナーチェーン又はファスナーストリンガーの位置及び配向を制御する工程と、交番磁界に応じて複数の磁性メディアを運動させ、ファスナーチェーン又はファスナーストリンガーの金属製エレメントが複数の磁性メディアを介してカソードに電気的に接続し、かつ金属製エレメント上で成長するめっき膜に対して複数の磁性メディアが衝突する工程を含む。ファスナーチェーン又はファスナーストリンガーが所定の走行路において連続的又は断続的に走行することの結果としてファスナーチェーン又はファスナーストリンガーの位置及び配向が制御され得るが、必ずしもこの限りではない。なお、ファスナーチェーンの製造方法は、ファスナーチェーンの金属製エレメントにめっき膜を生成する電気めっき方法としても理解可能である。 A manufacturing method according to an aspect of the present disclosure is a method for manufacturing a fastener chain or fastener stringer in which a plating film is formed on a metal element, and includes one or more fasteners at least partially immersed in an electrolytic solution in a plating bath. applying a voltage between the cathode and the one or more anodes; generating an alternating magnetic field in the electrolyte when or during the time the voltage is applied between the one or more cathodes and the one or more anodes; controlling the position and orientation of the fastener chain or fastener stringer so that at least the metallic elements of the fastener chain or fastener stringer are disposed in the space in which the alternating magnetic field is generated; and moving the plurality of magnetic media in response to the alternating magnetic field. and electrically connecting the metal elements of the fastener chain or fastener stringer to the cathode through a plurality of magnetic media, and colliding the plurality of magnetic media against the plated film growing on the metal elements. . The position and orientation of the fastener chain or fastener stringer may be controlled as a result of the fastener chain or fastener stringer traveling continuously or intermittently in a predetermined travel path, although this need not be the case. The fastener chain manufacturing method can also be understood as an electroplating method for forming a plating film on the metal elements of the fastener chain.
 本開示の別態様に係るスライドファスナーの製造方法は、上述の製造方法で得られたファスナーチェーンを切断する工程と、切断により得られた短尺なファスナーチェーンに対してスライダーを取り付けて、短尺なファスナーチェーンの一対のファスナーストリンガーの金属製エレメントの係合及び係合解除を可能とする工程を含む。 A method for manufacturing a slide fastener according to another aspect of the present disclosure includes steps of cutting the fastener chain obtained by the above-described manufacturing method, and attaching a slider to the short fastener chain obtained by the cutting to form a short fastener. It includes enabling the engagement and disengagement of the metallic elements of a pair of fastener stringers of the chain.
 本開示の更なる別態様に係る電気めっき装置は、ファスナーチェーン又はファスナーストリンガーの金属製エレメントにめっき膜を生成するための電気めっき装置であって、1以上のカソードと1以上のアノードが少なくとも部分的に浸漬される電解液を貯留するめっき槽と、めっき槽の電解液中で交番磁界を生成する交番磁界生成部と、少なくともファスナーチェーン又はファスナーストリンガーの金属製エレメントが交番磁界が生成された空間に配されるように設けられたファスナーチェーン又はファスナーストリンガーの1以上の支持具を備える。カソードは、1以上の支持具により支持されたファスナーチェーン又はファスナーストリンガーの金属製エレメントとカソードの間で複数の磁性メディアが交番磁界に応じて運動することを許容し、かつ複数の磁性メディアを介して金属製エレメントに電気的に接続可能に設けられる。 An electroplating apparatus according to yet another aspect of the present disclosure is an electroplating apparatus for producing a plating film on metallic elements of fastener chains or fastener stringers, wherein one or more cathodes and one or more anodes are at least partially A plating bath for storing an electrolytic solution to be immersed in the plating bath, an alternating magnetic field generating section for generating an alternating magnetic field in the electrolytic solution of the plating bath, and a space where at least the metal element of the fastener chain or fastener stringer generates an alternating magnetic field. one or more supports for fastener chains or fastener stringers arranged to be placed in the The cathode allows a plurality of magnetic media to move in response to an alternating magnetic field between the cathode and the metallic elements of a fastener chain or fastener stringer supported by one or more supports, and through the plurality of magnetic media. is electrically connectable to the metal element.
 幾つかの実施形態では、ファスナーチェーン又はファスナーストリンガーの長手方向が交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うようにファスナーチェーン又はファスナーストリンガーの位置及び配向が制御される。この目的のために1以上の支持具が設けられ得る。 In some embodiments, the position and orientation of the fastener chain or fastener stringer is controlled such that the longitudinal direction of the fastener chain or fastener stringer is along a predetermined direction with alternating different magnetic poles for generating an alternating magnetic field. . One or more supports may be provided for this purpose.
 幾つかの実施形態では、(i)金属製エレメントの主面が磁極に関する磁軸に対して略直交するように、及び/又は、(ii)ファスナーチェーン又はファスナーストリンガーがその幅方向において磁極に対して平坦な姿勢で対面するように、ファスナーチェーン又はファスナーストリンガーの位置及び配向が制御される。 In some embodiments, (i) the major faces of the metallic elements are substantially perpendicular to the magnetic axis with respect to the magnetic poles, and/or (ii) the fastener chains or stringers are aligned with the magnetic poles in their width direction. The position and orientation of the fastener chains or fastener stringers are controlled so that they face each other in a flat position.
 幾つかの実施形態では、ファスナーチェーンの走行路は、1以上の螺旋状走行路を含む、及び/又は、1以上のカソードは、1以上の螺旋状カソードを含む。 In some embodiments, the fastener chain runway includes one or more helical runways and/or the one or more cathodes include one or more helical cathodes.
 幾つかの実施形態では、電解液中に交番磁界を生成する工程は、異なる磁極が回転方向に交互に配置された1以上の磁性回転部を回転させることを含む。 In some embodiments, generating an alternating magnetic field in the electrolyte includes rotating one or more magnetic rotating parts with different magnetic poles alternating in the direction of rotation.
 幾つかの実施形態では、磁性回転部の周囲で(例えば、螺旋状に)ファスナーチェーン又はファスナーストリンガーを走行させることの結果としてファスナーチェーン又はファスナーストリンガーの位置及び配向が制御される。 In some embodiments, the position and orientation of the fastener chain or fastener stringer is controlled as a result of running the fastener chain or fastener stringer (eg, spirally) around the magnetic rotating portion.
 幾つかの実施形態では、磁性回転部は、回転可能な態様で密閉された透磁性ハウジングに収容される。 In some embodiments, the magnetic rotating portion is housed in a magnetically permeable housing that is rotatably sealed.
 幾つかの実施形態では、電解液中に交番磁界を生成する工程は、1以上の磁性回転部として設けられた異なる磁性回転部それぞれを回転させることを含み、異なる磁性回転部に亘ってファスナーチェーンを走行させることの結果としてファスナーチェーン又はファスナーストリンガーの位置及び配向が制御される。 In some embodiments, the step of generating an alternating magnetic field in the electrolyte comprises rotating each of the different magnetic rotators provided as one or more magnetic rotators, wherein the fastener chain is rotated across the different magnetic rotators. The position and orientation of the fastener chain or fastener stringer is controlled as a result of running the .
 幾つかの実施形態では、異なる磁性回転部に亘ってファスナーチェーンを走行させることは、異なる磁性回転部の周囲の螺旋状の走行路において逆方向にファスナーチェーンを走行させることを含む。 In some embodiments, running the fastener chain over the different magnetic rotating parts includes running the fastener chain in opposite directions in a helical track around the different magnetic rotating parts.
 幾つかの実施形態では、磁性回転部の回転方向に沿ってファスナーチェーンが走行することの結果としてファスナーチェーン又はファスナーストリンガーの位置及び配向が制御される。 In some embodiments, the position and orientation of the fastener chain or fastener stringer is controlled as a result of the fastener chain running along the direction of rotation of the magnetic rotating portion.
 本開示の一態様によれば、既存の方法とは異なる新たな方法でファスナーチェーンの金属製エレメントにめっき膜を形成することができる。 According to one aspect of the present disclosure, a plating film can be formed on the metal element of the fastener chain by a new method different from existing methods.
本開示の一態様に係るファスナーチェーンの金属製エレメントに対する電気めっき方法に関する概略図である。1 is a schematic diagram of a method of electroplating a metal element of a fastener chain according to one aspect of the present disclosure; FIG. ファスナーチェーンの一例を示す模式図である。It is a schematic diagram which shows an example of a fastener chain. 金属製エレメントの基材上にめっき膜が形成された状態を示す概略的な断面図である。FIG. 4 is a schematic cross-sectional view showing a state in which a plating film is formed on the base material of the metal element; 電気めっき方法に関するタイムチャートである。It is a time chart regarding an electroplating method. 電気めっき方法に関する別のタイムチャートである。4 is another time chart relating to the electroplating method; 本開示の一態様に係る電気めっき装置の概略図である。1 is a schematic diagram of an electroplating apparatus according to one aspect of the present disclosure; FIG. 電気めっき装置の透磁性ハウジングに回転可能に収容される磁性回転部の概略的な側面図である。1 is a schematic side view of a magnetic rotating portion rotatably received in a magnetically permeable housing of an electroplating apparatus; FIG. 磁性回転部における永久磁石の配置例を示す概略的な側面図である。FIG. 3 is a schematic side view showing an arrangement example of permanent magnets in a magnetic rotating section; 電気めっき装置の透磁性ハウジング外に設けられたアノード取付用のフレームの概略的な側面図である。FIG. 4 is a schematic side view of a frame for mounting an anode outside the magnetically permeable housing of the electroplating apparatus; 複数の磁性メディアの挙動及び作用を説明するための模式図であり、(a)は、永久磁石のN極から径方向外向きの磁束により形成される磁場に磁性メディアが置かれた状態を示し、(b)は、永久磁石のS極に向けて径方向内向きの磁束により形成される磁場に磁性メディアが置かれた状態を示す。FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media, where (a) shows a state in which the magnetic media are placed in a magnetic field formed by a magnetic flux directed radially outward from the north pole of a permanent magnet; , (b) show the magnetic media placed in the magnetic field formed by the magnetic flux directed radially inward toward the S pole of the permanent magnet. 螺旋状走行路の間でファスナーチェーンの表裏が反転することを示す上面模式図である。FIG. 4 is a schematic top view showing that the fastener chain is turned upside down between the spiral running paths. 4つの螺旋状走行路が設けられた電気めっき装置を示す概略図である。1 is a schematic diagram showing an electroplating apparatus provided with four helical tracks; FIG. 4つの螺旋状走行路が設けられた別例に係る電気めっき装置を示す概略図であり、図12と比較して磁性回転部の回転方向に違いがある。FIG. 13 is a schematic diagram showing an electroplating apparatus according to another example provided with four spiral running paths, and the direction of rotation of the magnetic rotating portion is different from that in FIG. 12 ; 本開示の別態様に係る電気めっき装置の概略図である。FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure; 本開示の別態様に係る電気めっき装置における複数の磁性メディアの挙動及び作用を説明するための模式図であり、(a)は、上部カソードが金属製エレメントの上面とN極の間に配置された状態を示し、下部カソードが金属製エレメントの下面とS極の間に配置された状態を示し、(b)は、上部カソードが金属製エレメントの上面とS極の間に配置された状態を示し、下部カソードが金属製エレメントの下面とN極の間に配置された状態を示す。FIG. 4A is a schematic diagram for explaining the behavior and action of a plurality of magnetic media in an electroplating apparatus according to another aspect of the present disclosure; (b) shows a state in which the lower cathode is arranged between the bottom surface of the metallic element and the south pole, and (b) shows a state in which the upper cathode is arranged between the top surface of the metallic element and the south pole. 4, showing the bottom cathode positioned between the bottom surface of the metallic element and the north pole. 本開示の別態様に係る電気めっき装置の概略図である。FIG. 4 is a schematic diagram of an electroplating apparatus according to another aspect of the present disclosure; 洗い加工及び染加工に関する評価結果を示す表である。It is a table|surface which shows the evaluation result regarding washing processing and dyeing processing.
 以下、図面を参照しつつ、様々な実施形態及び特徴について説明する。当業者は、過剰説明を要せず、各実施形態及び/又は各特徴を組み合わせることができ、この組み合わせによる相乗効果も理解可能である。実施形態間の重複説明は、原則的に省略する。参照図面は、発明の記述を主たる目的とするものであり、作図の便宜のために簡略化されている。各特徴は、本願に開示された電気めっき装置及びファスナーチェーンの製造方法にのみ有効であるものではなく、本明細書に開示されていない他の様々な電気めっき装置及びファスナーチェーンの製造方法にも通用する普遍的な特徴として理解される。 Various embodiments and features will be described below with reference to the drawings. A person skilled in the art can combine each embodiment and/or each feature without undue explanation, and can also understand the synergistic effect of this combination. Redundant explanations among the embodiments will be omitted in principle. The referenced drawings are primarily for the purpose of describing the invention and are simplified for drawing convenience. Each feature is effective not only for the electroplating apparatus and fastener chain manufacturing method disclosed herein, but also for various other electroplating apparatuses and fastener chain manufacturing methods not disclosed herein. It is understood as a common universal feature.
 本開示に係るファスナーチェーンの製造方法は、図1に概略的に示す4つの工程S1~S4を含む。工程S1では、めっき槽の電解液中に少なくとも部分的に浸漬されたカソードとアノードの間に電圧が印加される。工程S2では、カソードとアノードの間に電圧が印加されている時又は期間において電解液中に交番磁界が生成される。工程S3では、少なくともファスナーチェーンの金属製エレメントが交番磁界が生成された空間に配されるようにファスナーチェーンの位置及び配向が制御される。例えば、ファスナーチェーンが交番磁界を通過するようにファスナーチェーンが所定の走行路を連続的又は断続的に走行させられ、この結果として、ファスナーチェーンの位置及び配向が制御される。工程S4では、交番磁界に応じて複数の磁性メディアが運動し、ファスナーチェーンの金属製エレメントが複数の磁性メディアを介してカソードに電気的に接続し、かつ金属製エレメント上で成長するめっき膜に対して複数の磁性メディアが衝突する。なお、工程S4は、めっき槽に対して磁性メディアを投入した状態で工程S1,S2を行うことにより達成可能である。工程S3は、ファスナーチェーンの走行の結果として行われる時、工程S1,S2,S4と時間軸において重畳するように実施され得るが、必ずしもこの限りではない。 A method for manufacturing a fastener chain according to the present disclosure includes four steps S1 to S4 schematically shown in FIG. In step S1, a voltage is applied between a cathode and an anode that are at least partially immersed in the electrolyte of the plating bath. In step S2, an alternating magnetic field is generated in the electrolyte when or during the time a voltage is applied between the cathode and the anode. In step S3, the position and orientation of the fastener chain are controlled such that at least the metallic elements of the fastener chain are arranged in the space in which the alternating magnetic field is generated. For example, the fastener chain is caused to travel continuously or intermittently along a predetermined path so that the fastener chain passes through an alternating magnetic field, thereby controlling the position and orientation of the fastener chain. In step S4, a plurality of magnetic media move according to the alternating magnetic field, the metal elements of the fastener chain are electrically connected to the cathode through the plurality of magnetic media, and the plating film growing on the metal elements A plurality of magnetic media collide with each other. The step S4 can be achieved by performing the steps S1 and S2 while the magnetic media are put into the plating bath. When step S3 is performed as a result of running of the fastener chain, it can be performed so as to overlap with steps S1, S2, and S4 on the time axis, but this is not necessarily the case.
 上述の製法によると、めっき膜の成長とめっき膜に対する磁性メディアの衝突が同時に起き、これにより十分な品質(例えば、十分な加工耐性)のめっき膜の形成が促進される。ファスナーチェーンの位置及び配向が制御され、ファスナーテープによって金属製エレメントとカソード間の電気的な接続が阻害されることが抑制される。 According to the manufacturing method described above, the growth of the plating film and the collision of the magnetic media against the plating film occur simultaneously, which promotes the formation of a plating film of sufficient quality (for example, sufficient processing resistance). The position and orientation of the fastener chain is controlled to prevent the fastener tape from interfering with the electrical connection between the metallic element and the cathode.
 交番磁界の利用効率を高めるためにファスナーチェーン1の長手方向が交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うようにファスナーチェーン1の位置及び配向を制御すると良い。更には、金属製エレメントの主面が磁極に関する磁軸に対して略直交するように、及び/又は、ファスナーチェーン1がその幅方向において磁極に対して平坦な姿勢で対面するようにファスナーチェーン1の位置及び配向を制御すると良い。これにより均一な品質及び/又は厚みでめっき膜を形成することが促進される。なお、平坦な姿勢は、ファスナーチェーン1がその幅方向で大きく屈曲してしない状態を意味し、ファスナーチェーン1の両方のファスナーテープが同一平面に配される程の平坦さを意味せず、各ファスナーテープに局所的な撓み、波打ちが生じることも包含する。勿論、ファスナーチェーン1において金属製エレメントがファスナーテープにより被覆される屈曲状態は、上述の平坦な姿勢に包含されない。金属製エレメントの配向に関して、略直交は、80°~100°の範囲内の角度を意味する。 In order to increase the utilization efficiency of the alternating magnetic field, it is preferable to control the position and orientation of the fastener chain 1 so that the longitudinal direction of the fastener chain 1 is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. Furthermore, the fastener chain 1 is arranged so that the main surface of the metal element is substantially perpendicular to the magnetic axis of the magnetic pole and/or so that the fastener chain 1 faces the magnetic pole in a flat posture in its width direction. It is preferable to control the position and orientation of . This promotes formation of a plated film with uniform quality and/or thickness. The flat posture means that the fastener chain 1 is not greatly bent in its width direction, and does not mean that both fastener tapes of the fastener chain 1 are flat enough to be arranged on the same plane. It also includes the occurrence of local bending and waviness in the fastener tape. Of course, the bent state in which the metal elements of the fastener chain 1 are covered with the fastener tape is not included in the above-described flat posture. Substantially orthogonal, with respect to the orientation of the metallic elements, means an angle within the range of 80° to 100°.
 ファスナーチェーン1が所定の走行路80において連続的又は断続的に走行することの結果としてファスナーチェーン1の位置及び配向が制御される場合、電気めっきを効率的に行うことができる。所定の走行路80は、複数の支持部材78により画定することができるが、必ずしもこの限りではない。なお、ファスナーチェーン1の位置及び配向を制御する工程を、ファスナーチェーンが交番磁界を通過するようにファスナーチェーンを所定の走行路で連続的又は断続的に走行させる工程で読み替えることもできる。 Electroplating can be performed efficiently if the position and orientation of the fastener chain 1 are controlled as a result of the fastener chain 1 running continuously or intermittently on the predetermined running path 80 . The predetermined travel path 80 may be defined by a plurality of support members 78, but this is not necessarily the case. The process of controlling the position and orientation of the fastener chain 1 can also be read as a process of continuously or intermittently running the fastener chain along a predetermined running path so that the fastener chain passes through the alternating magnetic field.
 ファスナーチェーンの代替として(片方の)ファスナーストリンガーに対して上述の工程を実施することができる。本明細書では、専らファスナーチェーンの製法に関して説明するが、(片方の)ファスナーストリンガーの製法にも同様に適用可能であり、重複説明は省略する。 As an alternative to the fastener chain, the above process can be performed on (one side) fastener stringer. In this specification, the method of manufacturing the fastener chain will be exclusively described, but the method of manufacturing (one side) of the fastener stringer can also be similarly applied, and redundant description will be omitted.
 磁性メディアは、交番磁界に応じて運動し、かつカソード10と金属製エレメント4a,4bの電気的な接続(即ち、短絡)を確保するのに十分な導電性を有する。様々な形状の磁性メディアを用いることができ、幾つかの場合、非球状メディアが用いられる。例えば、円柱又は角柱といったピンメディアが用いられる。ピンメディアは、0.2mm~1.0mm程度の直径又は最大幅、3mm~15mmの長さのステンレスピンであり得る。ステンレス以外の強磁性材料も採用可能である。 The magnetic media moves in response to an alternating magnetic field and has sufficient conductivity to ensure electrical connection (that is, short circuit) between the cathode 10 and the metal elements 4a and 4b. Various shapes of magnetic media can be used, and in some cases non-spherical media are used. For example, pin media such as cylinders or prisms are used. The pin media can be stainless steel pins with a diameter or maximum width on the order of 0.2 mm to 1.0 mm and a length of 3 mm to 15 mm. Ferromagnetic materials other than stainless steel can also be used.
 ピンメディアは、交番磁界に応じて回転する(磁界の向きが変わる時、ピンメディアは、変化前の磁界の向きに対応した第1姿勢から変化後の磁界の向きに対応した第2姿勢に変化する)。また、ピンメディアは、磁極に連行されて変位する。このようなピンメディアの挙動に加え、ピンメディア同士が衝突し、更には、ピンメディアがファスナーチェーン(特には金属製エレメント)に衝突する。ピンメディアの個々の挙動は無秩序であるが、それらのピンメディアの集合によりカソードと金属製エレメント間の電気的な接続が偶発的ではなく連続的又は間欠的に維持される。ここで、衝突とは、磁性メディアが金属製エレメントから離れた状態(磁性メディア同士は離れていなくてもよい状態)にあるときに交番磁界から得た回転運動量と並進運動量を、金属製エレメントに与えることであり、特許文献1や特許文献2に記載の既存のめっき技術における電極と被めっき対象物とが常時接触した状態において、電極と被めっき物とが相対的に動くような場合とは異なるものである。 The pin media rotates according to the alternating magnetic field (when the direction of the magnetic field changes, the pin media changes from the first posture corresponding to the direction of the magnetic field before the change to the second posture corresponding to the direction of the magnetic field after the change). do). Also, the pin media are displaced by being entrained by the magnetic poles. In addition to such pin media behavior, pin media collide with each other, and pin media collide with fastener chains (especially metal elements). Although the individual behavior of the pin media is chaotic, the collection of pin media maintains an electrical connection between the cathode and the metallic element continuously or intermittently rather than accidentally. Here, collision means that the rotational momentum and translational momentum obtained from the alternating magnetic field when the magnetic media are separated from the metal element (the magnetic media need not be separated from each other) are applied to the metal element. In the existing plating technology described in Patent Document 1 and Patent Document 2, when the electrode and the object to be plated are in constant contact, the electrode and the object to be plated move relative to each other. They are different.
 磁界の変化速度を適切に設定することにより磁性メディアによるめっき膜の打撃力を適正化することができる。磁性メディアの衝突により、めっき膜が平坦化され、又は、その表面の一部が削られ、結果として、めっき膜の成長が遅れてしまうおそれがある。しかしながら、めっき膜への磁性メディアの衝突によってめっき膜の品質(例えば、加工耐性、又は、基材への密着性)が高められ得る。基材への密着性が高められる場合、衝突は、めっき層の結晶構造の変化に影響を与える程度の運動量をもった衝突を意味するともいえる。 By appropriately setting the change speed of the magnetic field, it is possible to optimize the impact force of the magnetic media on the plated film. The collision of the magnetic media may flatten the plated film or scrape a part of its surface, resulting in a delay in the growth of the plated film. However, the collision of the magnetic media with the plated film can improve the quality of the plated film (for example, processing resistance or adhesion to the substrate). When the adhesion to the base material is enhanced, the collision can be said to mean collision with momentum that affects the change in the crystal structure of the plating layer.
 図2に示すように、ファスナーチェーン1は、所定幅で所定方向に長尺に延びる長尺物であり、一対のファスナーストリンガー2a,2bを有する。各ファスナーストリンガー2a,2bは、ファスナーテープ3a,3bと、ファスナーテープ3a,3bの側縁部に取り付けられた金属製エレメント4a,4bを有する。ファスナーチェーン1は、一対のファスナーストリンガー2a,2bの金属製エレメント4a,4bがお互いに係合したものである。一対のファスナーストリンガー2a,2bの金属製エレメント4a,4bは、不図示のスライダーを用いて係合可能であり、また同様に係合解除可能である。 As shown in FIG. 2, the fastener chain 1 is a long object that extends in a predetermined direction with a predetermined width, and has a pair of fastener stringers 2a and 2b. Each fastener stringer 2a, 2b has a fastener tape 3a, 3b and metallic elements 4a, 4b attached to the side edges of the fastener tape 3a, 3b. A fastener chain 1 is formed by engaging metal elements 4a and 4b of a pair of fastener stringers 2a and 2b. The metal elements 4a, 4b of the pair of fastener stringers 2a, 2b are engageable and disengageable in the same way using sliders (not shown).
 金属製エレメント4aは、ファスナーテープ3aの側縁部に所定間隔で取り付けられ、従って、ファスナーテープ3a上においてお互いに電気的に接続されていない。同様、金属製エレメント4bは、ファスナーテープ3bの側縁部に所定間隔で取り付けられ、従って、ファスナーテープ3b上においてお互いに電気的に接続されていない。金属製エレメント4aと金属製エレメント4bが係合する時、両者が接触可能となり、両者が共通の電位を持つことができる。なお、金属製エレメント4aと金属製エレメント4b同士の接触状態は、ファスナーチェーン1の走行時に磁性メディアの衝突等により変化するおそれがある。 The metal elements 4a are attached to the side edges of the fastener tape 3a at predetermined intervals, and therefore are not electrically connected to each other on the fastener tape 3a. Similarly, the metallic elements 4b are attached to the side edges of the fastener tape 3b at predetermined intervals and are therefore not electrically connected to each other on the fastener tape 3b. When the metallic element 4a and the metallic element 4b are engaged, they can be in contact and have a common electrical potential. The contact state between the metal element 4a and the metal element 4b may change due to collision of magnetic media or the like while the fastener chain 1 is running.
 ファスナーチェーン1は、金属製エレメント4a,4bに対する電気めっき後、切断工程により短尺なファスナーチェーンにされ、この短尺なファスナーチェーンに対してスライダーが取り付けられ、その後、必要に応じてファスナーチェーンに対して止め具が取り付けられる。短尺なファスナーチェーンにスライダー(又はこれに加えて止め具)が取り付けられたものが、一般的にスライドファスナーと呼ばれる。ファスナーチェーン1には、最終製品であるスライドファスナーの構成部品のスライダーが取り付けられておらず、効率的かつ円滑に下流側に搬送可能である。 After electroplating the metal elements 4a and 4b, the fastener chain 1 is made into a short fastener chain by a cutting process, a slider is attached to the short fastener chain, and then, if necessary, the fastener chain is cut. A fastener is attached. A short fastener chain to which a slider (or a fastener in addition to this) is attached is generally called a slide fastener. The fastener chain 1 is not attached with a slider, which is a constituent part of the slide fastener as the final product, and can be efficiently and smoothly conveyed downstream.
 ファスナーテープ3a,3bは、織物、編物、又はこれらの混在物から成る可撓性帯である。ファスナーテープ3a,3bは、ファスナーチェーン1の表面側から見える表面とファスナーチェーン1の裏面側から見える裏面の一対の主面を有し、また一対の主面により画定される厚みを有する。金属製エレメント4a,4bは、その塑性変形を介してファスナーテープ3a,3bの芯紐に取り付けられる。金属製エレメント4a,4bは、ファスナーテープ3a,3bの側縁部(典型的には、芯紐)に取り付けられた一対の脚部と、一対の脚部を連結する頭部を有する。ある場合、ファスナーチェーン1の長手方向に交差する頭部の一対の側面に関して、一方の側面に係合突起が設けられ、他方の側面に係合凹部が設けられる。別の場合、上述の一対の側面それぞれに係合突起が設けられる。金属製エレメント4a,4bは、ファスナーチェーン1の表面側から見える表面とファスナーチェーン1の裏面側から見える裏面の一対の主面を有し、また一対の主面により画定される厚みを有する。 The fastener tapes 3a, 3b are flexible belts made of woven fabric, knitted fabric, or a mixture thereof. The fastener tapes 3a and 3b have a pair of main surfaces, a surface visible from the front side of the fastener chain 1 and a back surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces. The metal elements 4a, 4b are attached to the core cords of the fastener tapes 3a, 3b through their plastic deformation. The metal elements 4a, 4b have a pair of legs attached to the side edges (typically core cords) of the fastener tapes 3a, 3b and a head connecting the pair of legs. In some cases, with respect to a pair of side surfaces of the head portion intersecting the longitudinal direction of the fastener chain 1, one side surface is provided with an engaging projection and the other side surface is provided with an engaging recess. Alternatively, each of the aforementioned pair of side surfaces is provided with an engaging projection. The metal elements 4a and 4b have a pair of main surfaces, a front surface visible from the front side of the fastener chain 1 and a rear surface visible from the back side of the fastener chain 1, and have a thickness defined by the pair of main surfaces.
 本開示の電気めっき工程の後、図3に示すように、金属製エレメント4a,4bの基材4gがめっき膜4hにより被覆される。図3は、金属製エレメント4a,4bの基材4gがめっき膜4hにより被覆される様子を示す概念図である。 After the electroplating process of the present disclosure, the base material 4g of the metallic elements 4a, 4b is coated with a plating film 4h, as shown in FIG. FIG. 3 is a conceptual diagram showing how the base material 4g of the metal elements 4a and 4b is coated with the plating film 4h.
 金属製エレメントの基材4gが黄銅(CuZn)から成り、アノードとして錫(Sn)が用いられる場合を一例に挙げて説明する。本開示の電気めっきによると、めっき膜4hは、錫(Sn)に加えて基材4gの金属元素(Cu,Zn)も含む。めっき膜4hの厚み方向において基材4gから離間するに応じてめっき膜4hにおけるCu,Zn(第1のめっき膜金属元素と呼ぶ)の割合が連続的に減少する。アノードに対応のSn(第2のめっき膜金属元素と呼ぶ)の割合は、めっき膜4hの厚み方向において基材4gに接近するに応じて減少する。第2のめっき膜金属元素の割合は、めっき膜4hの上面で最大であり、第1のめっき膜金属元素の割合は、めっき膜4hの上面で最小又はゼロである。言うまでも無く、めっき膜4h上に1以上の追加のめっき膜を形成することも可能である。基材4gの金属元素とアノードの金属元素に関して様々な組み合わせが可能であり、ここで述べたものは非限定の単なる一例と理解すべきである。 A case where the base material 4g of the metal element is made of brass (CuZn) and tin (Sn) is used as the anode will be described as an example. According to the electroplating of the present disclosure, the plated film 4h also contains the metal elements (Cu, Zn) of the substrate 4g in addition to tin (Sn). The ratio of Cu and Zn (referred to as first plating film metal elements) in the plating film 4h decreases continuously as the plating film 4h is separated from the substrate 4g in the thickness direction. The ratio of Sn corresponding to the anode (referred to as a second plating film metal element) decreases in the thickness direction of the plating film 4h as it approaches the substrate 4g. The ratio of the second plating film metal element is maximum on the top surface of the plating film 4h, and the ratio of the first plating film metal element is minimum or zero on the top surface of the plating film 4h. Needless to say, it is also possible to form one or more additional plating films on the plating film 4h. Various combinations are possible with respect to the metallic elements of the substrate 4g and the metallic elements of the anode, and it should be understood that the ones mentioned here are only non-limiting examples.
 上述の工程S1~S4の順番について補足的に説明する。工程S1と工程S2は完全に同期して行う必要はなく、開始タイミング又は終了タイミングにおいて時間差があっても良い(図4参照)。また、工程S1と工程S2を間欠的に実施しても良い(図5参照)。工程S3は、ファスナーチェーンの走行の結果として行われる時、工程S1,S2と時間軸沿いに重畳して行われ(図4参照)、又は、工程S1,S2と時間軸沿いに重畳せずに(相補的に)行われる(図5参照)。工程S4は、工程S1,S2と時間軸沿いに重畳して行われる。 The order of the above steps S1 to S4 will be supplementarily explained. Step S1 and step S2 do not have to be performed completely synchronously, and there may be a time difference between the start timing and the end timing (see FIG. 4). Moreover, step S1 and step S2 may be performed intermittently (see FIG. 5). When step S3 is performed as a result of the running of the fastener chain, it is performed overlapping steps S1 and S2 along the time axis (see FIG. 4), or it is performed without overlapping steps S1 and S2 along the time axis. (complementary) (see FIG. 5). Step S4 is superimposed on steps S1 and S2 along the time axis.
 図4では、時刻t2以降、金属製エレメントがカソードから電子の供給を受けてアノード由来の金属イオンが金属製エレメント上に連続的に析出する。また、金属イオンの析出に伴って成長するめっき膜に対して磁性メディアが連続的に衝突する。図5では、時刻t1と時刻t2の間の期間で停止中のファスナーチェーンの金属製エレメントにめっき膜が形成され、かつめっき膜に対して磁性メディアが連続的に衝突する。時刻t2と時刻t3の間の期間ではファスナーチェーンが所定距離だけ走行させられる。これが繰り返され、金属製エレメントに所望のめっき膜が形成される。 In FIG. 4, after time t2, the metal element is supplied with electrons from the cathode, and metal ions derived from the anode are continuously deposited on the metal element. In addition, the magnetic media continuously collide with the plated film that grows with the deposition of metal ions. In FIG. 5, a plated film is formed on the metal element of the stopped fastener chain during the period between time t1 and time t2, and the magnetic media continuously collides with the plated film. During the period between time t2 and time t3, the fastener chain is run for a predetermined distance. This is repeated to form a desired plating film on the metal element.
 以下、本開示に係るファスナーチェーンの製造(電気めっき)方法及び装置について詳述する。なお、本開示に係る方法のために様々な電気めっき装置を用いることができ、本開示に開示の電気めっき装置は単なる一例であるに過ぎない。図6に示すように、電気めっき装置100は、めっき槽30、搬送機構40、交番磁界生成部50、及びファスナーチェーン1の走行路80を有する。ファスナーチェーン1は、搬送機構40のローラ41,42を介してめっき槽30外からめっき槽30内に進入し、搬送機構40のローラ43,44を介してめっき槽30内からめっき槽30外に退出する。ファスナーチェーン1の搬送の具体的な方法は任意であり、例えば、その搬送のために巻き取りローラ、グリッパー、又はローラ対(駆動ローラと押圧ローラの組み合わせ)を用いることができる。ファスナーチェーン1は、めっき槽30内において走行路80を走行し、めっき槽30の電解液35に浸漬した浸漬部分と、それ以外の部分を含むことになる。 The method and apparatus for manufacturing (electroplating) a fastener chain according to the present disclosure will be described in detail below. It should be noted that various electroplating apparatuses can be used for the methods of the present disclosure, and the electroplating apparatus disclosed in this disclosure is merely one example. As shown in FIG. 6 , the electroplating apparatus 100 has a plating bath 30 , a transport mechanism 40 , an alternating magnetic field generator 50 , and a running path 80 for the fastener chain 1 . The fastener chain 1 enters the plating bath 30 from outside the plating bath 30 via the rollers 41 and 42 of the transport mechanism 40, and passes from the inside of the plating bath 30 to the outside of the plating bath 30 via the rollers 43 and 44 of the transport mechanism 40. exit. A specific method for conveying the fastener chain 1 is arbitrary, and for example, a take-up roller, a gripper, or a roller pair (a combination of a drive roller and a pressure roller) can be used for the conveyance. The fastener chain 1 travels along the running path 80 in the plating bath 30 and includes a immersed portion immersed in the electrolytic solution 35 of the plating bath 30 and other portions.
 めっき槽30は、1以上のカソード10と1以上のアノード20が浸漬される電解液35を貯留する。めっき槽30は、底板31と側板32を有する絶縁性容器であり、オプションとして蓋により閉鎖可能である。めっき槽30の電解液35は、例えば、シアン系めっき液であり、これが外部の副槽との間で循環される。なお、環境負荷低減の観点から、シアン、クロム、セレンのような特定有害物質を含まないめっき液を利用することが好ましい。カソード10とアノード20が直流電源E1に接続され、両者の間に電圧が印加される。スイッチSWのオン・オフにより電圧印加状態を制御可能である。アノード20は、可溶性又は不溶性アノードであり得る。アノード20の金属元素は、目的とするめっき膜の金属元素に応じて適切に決定される。カソード10は、ファスナーチェーン1の金属製エレメント4a,4bに電子を供給するため(金属製エレメント4a,4bをカソード電位とするため)に電解液35中でアノード20から離れて設けられる。 The plating bath 30 stores an electrolytic solution 35 in which one or more cathodes 10 and one or more anodes 20 are immersed. Plating bath 30 is an insulating vessel having a bottom plate 31 and side plates 32, optionally closable by a lid. The electrolytic solution 35 in the plating tank 30 is, for example, a cyanide plating solution, which is circulated between the external sub tanks. From the viewpoint of reducing the burden on the environment, it is preferable to use a plating solution that does not contain specific harmful substances such as cyanide, chromium, and selenium. A cathode 10 and an anode 20 are connected to a DC power supply E1, and a voltage is applied between them. The voltage application state can be controlled by turning on/off the switch SW. Anode 20 can be a soluble or insoluble anode. The metal element of the anode 20 is appropriately determined according to the target metal element of the plating film. The cathode 10 is provided in the electrolyte 35 away from the anode 20 in order to supply electrons to the metal elements 4a, 4b of the fastener chain 1 (to bring the metal elements 4a, 4b to a cathodic potential).
 交番磁界生成部50は、めっき槽30の電解液35中で交番磁界を生成する。交番磁界は、時間と共に大きさと方向が変化する磁界を意味する。ファスナーチェーン1の走行路80は、ファスナーチェーン1が交番磁界生成部50により生成される交番磁界に配されるように設けられる。交番磁界の生成とファスナーチェーン1の走行が同時に又は同じ期間に行われる時、ファスナーチェーン1の金属製エレメント4a,4bは、交番磁界生成部50により生成されている交番磁界を通過する。 The alternating magnetic field generator 50 generates an alternating magnetic field in the electrolytic solution 35 of the plating bath 30 . An alternating magnetic field means a magnetic field that changes in magnitude and direction with time. The running path 80 of the fastener chain 1 is provided so that the fastener chain 1 is arranged in the alternating magnetic field generated by the alternating magnetic field generating section 50 . When the generation of the alternating magnetic field and the running of the fastener chain 1 are performed at the same time or during the same period, the metal elements 4 a and 4 b of the fastener chain 1 pass through the alternating magnetic field generated by the alternating magnetic field generator 50 .
 本電気めっき装置100では、カソード10は、支持部材78により支持されたファスナーチェーン1の金属製エレメント4a,4bとカソード10の間で複数の磁性メディアが上述の交番磁界に応じて運動(例えば、回転)することを許容し、かつ複数の磁性メディアを介して金属製エレメント4a,4bに電気的に接続可能に設けられる。換言すれば、(i)支持部材78により支持されたファスナーチェーン1の金属製エレメント4a,4bとカソード10の間には交番磁界に応じて複数の磁性メディアが運動する空間が設けられ、(ii)この空間は、その金属製エレメント4a,4bが複数の磁性メディアを介してカソード10に電気的に接続され、かつ金属製エレメント4a,4b上で成長するめっき膜に対して複数の磁性メディアが衝突可能なように設定される。 In this electroplating apparatus 100, a plurality of magnetic media move (for example, (rotation) and electrically connectable to the metal elements 4a and 4b via a plurality of magnetic media. In other words, (i) between the metal elements 4a, 4b of the fastener chain 1 supported by the support member 78 and the cathode 10, a space is provided in which a plurality of magnetic media move according to the alternating magnetic field, and (ii) ) In this space, the metal elements 4a and 4b are electrically connected to the cathode 10 via a plurality of magnetic media, and the plurality of magnetic media are provided for the plated film growing on the metal elements 4a and 4b. It is set so that it can collide.
 上述の構成によると、金属製エレメント4a,4b上へのめっき膜の成長と、めっき膜に対する磁性メディアの衝突の両方が同時に起きることを確保できる。これにより十分な品質のめっき膜(例えば、加工耐性)の形成が促進される。また、支持部材78により画定される走行路80においてファスナーチェーンを連続的又は断続的に走行させる場合には、電気めっき工程を効率的に行うことができる。 According to the above configuration, it is possible to ensure that both the growth of the plating film on the metal elements 4a and 4b and the collision of the magnetic media against the plating film occur simultaneously. This promotes formation of a plating film of sufficient quality (for example, processing resistance). Further, when the fastener chain is caused to run continuously or intermittently on the running path 80 defined by the support member 78, the electroplating process can be performed efficiently.
 支持部材78は、ファスナーチェーン1の長手方向が交番磁界の生成のために異なる磁極が交互に配置された所定方向(例えば、後述の磁性回転部60の周方向及び/又は回転方向)に沿うと共に、ファスナーチェーン1がその幅方向において磁極に対して平坦な姿勢で対面するようにファスナーチェーン1の位置及び配向を制御するように設けられ得る。これにより均一な品質及び/又は厚みでめっき膜を形成することが促進される。 The support member 78 extends along a predetermined direction in which different magnetic poles are alternately arranged for generating an alternating magnetic field (for example, the circumferential direction and/or the rotational direction of the magnetic rotating portion 60 described later) in the longitudinal direction of the fastener chain 1 and , to control the position and orientation of the fastener chain 1 so that the fastener chain 1 faces the magnetic poles in a flat posture in its width direction. This promotes formation of a plated film with uniform quality and/or thickness.
 交番磁界生成部50は、モータ61と、モータ61により回転される磁性回転部60を含む。モータ61は、例えば、直流又は交流モータである。磁性回転部60では、異なる磁極(即ち、N極とS極)がその回転方向に交互に配置される。磁極として永久磁石、電磁石、又はこれらの組み合わせを用いることができる。図7に示す場合、磁極のために永久磁石が用いられる。磁性回転部60は、モータ61の回転軸62に回転可能に固定された回転体63と、その回転体63の外面に設けられた複数の永久磁石64を有する。回転体63は、例えば、ステンレス製の中空の円柱部材である。永久磁石64は、ネオジウム磁石といった希土類磁石であり得るが、他の種類も採用可能である。一つの磁性回転部60に対応して一つのモータ61を設けることは必須ではない。適切な動力伝達系を介してモータ61の出力を複数の磁性回転部60に供給することもできる。なお、モータ61の回転軸62は、めっき槽30の底板31の開口に防水ベアリングを介して固定され得る。 The alternating magnetic field generating section 50 includes a motor 61 and a magnetic rotating section 60 rotated by the motor 61 . Motor 61 is, for example, a DC or AC motor. In the magnetic rotating portion 60, different magnetic poles (ie, N poles and S poles) are alternately arranged in the direction of rotation. Permanent magnets, electromagnets, or combinations thereof can be used as the magnetic poles. In the case shown in FIG. 7, permanent magnets are used for the magnetic poles. The magnetic rotating section 60 has a rotating body 63 rotatably fixed to a rotating shaft 62 of a motor 61 and a plurality of permanent magnets 64 provided on the outer surface of the rotating body 63 . The rotating body 63 is, for example, a hollow cylindrical member made of stainless steel. Permanent magnets 64 may be rare earth magnets such as neodymium magnets, although other types are also possible. It is not essential to provide one motor 61 corresponding to one magnetic rotating portion 60 . The output of the motor 61 can also be supplied to multiple magnetic rotating parts 60 via a suitable drive train. The rotating shaft 62 of the motor 61 can be fixed to the opening of the bottom plate 31 of the plating tank 30 via waterproof bearings.
 複数の永久磁石64は、磁性回転部60の回転方向においてS極とN極が交互に並ぶように配置される(図8参照)。モータ61の作動に応じて磁性回転部60が回転する時、磁性回転部60の径方向外側の所定位置から見て磁性回転部60がS極とN極の間で交互に切り替えられる。磁性回転部60の径方向外側の所定位置にある磁性メディア(例えば、ピンメディア)は、(その磁性メディアに最も近い)磁極の変化に応じて回転しつつ、磁性回転部60の回転方向に流動する。磁性回転部60の回転速度は、例えば、100~4,000rpmである。 The plurality of permanent magnets 64 are arranged so that the S poles and the N poles are alternately arranged in the rotation direction of the magnetic rotating portion 60 (see FIG. 8). When the magnetic rotating portion 60 rotates in response to the operation of the motor 61 , the magnetic rotating portion 60 is alternately switched between the S pole and the N pole when viewed from a predetermined radially outer position of the magnetic rotating portion 60 . A magnetic medium (e.g., a pin medium) at a predetermined position radially outside the magnetic rotating section 60 rotates according to a change in the magnetic pole (closest to the magnetic medium) and flows in the rotating direction of the magnetic rotating section 60. do. The rotational speed of the magnetic rotating portion 60 is, for example, 100 to 4,000 rpm.
 図8に示すように、磁性回転部60の外面には、N極が外向きの永久磁石64が配置されたN極配置ゾーンZ1,Z3,Z5と、S極が外向きの永久磁石64が配置されたS極配置ゾーンZ2,Z4が磁性回転部60の回転方向において交互に設けられ得る。図8では、N極配置ゾーンZ1,Z3,Z5とS極配置ゾーンZ2,Z4が磁性回転部60の回転軸に平行に上下に真っ直ぐに延びているが、このような態様に限られない。幾つかの場合、磁性メディアの重力による沈降を考慮し、N極配置ゾーンZ1,Z3,Z5とS極配置ゾーンZ2,Z4は、磁性回転部60の回転軸に非平行に上下に斜めに延び、又は、磁性回転部60の回転軸に非平行に上下にジグザグに延びる。 As shown in FIG. 8, on the outer surface of the magnetic rotating portion 60, N pole placement zones Z1, Z3, Z5 in which permanent magnets 64 with N poles facing outward and permanent magnets 64 with S poles facing outward are arranged. The arranged S pole arrangement zones Z2 and Z4 can be provided alternately in the rotation direction of the magnetic rotating part 60. FIG. In FIG. 8, the north pole zones Z1, Z3, Z5 and the south pole zones Z2, Z4 extend straight up and down in parallel with the rotation axis of the magnetic rotating part 60, but the configuration is not limited to this. In some cases, the north pole placement zones Z1, Z3, Z5 and the south pole placement zones Z2, Z4 extend obliquely up and down non-parallel to the rotation axis of the magnetic rotating part 60, taking into consideration the sedimentation of the magnetic media due to gravity. , or extend in a zigzag up and down direction non-parallel to the rotation axis of the magnetic rotating portion 60 .
 電気めっき装置100は、透磁性ハウジング70を更に有し、磁性回転部60が回転可能にかつ密閉性を持たせて収容される。透磁性ハウジング70は、その内部の磁性回転部60の永久磁石64のN極からS極に向かう磁束を透過し、透磁性ハウジング70外に磁界を形成可能とする。透磁性ハウジング70は、モータ61の作動に基づいて磁性回転部60と一緒に回転せずに所定場所で静止を維持し、例えば、(その底板と上板で)回転軸62に対して防水ベアリングを介して結合される。透磁性ハウジング70を設けることにより磁性回転部60を電解液35から保護することができ、及び/又は、磁性回転部60の回転抵抗を小さくすることができる。透磁性ハウジング70は、例えば、ポリプロピレン、アクリル、塩化ビニル等の樹脂から成る。 The electroplating apparatus 100 further has a magnetically permeable housing 70, in which the magnetic rotating part 60 is rotatably and hermetically accommodated. The magnetically permeable housing 70 transmits the magnetic flux directed from the N pole to the S pole of the permanent magnet 64 of the magnetic rotating part 60 inside thereof, so that a magnetic field can be formed outside the magnetically permeable housing 70 . The magnetically permeable housing 70 does not rotate with the magnetic rotating part 60 under the operation of the motor 61 and remains stationary in place, e.g. are connected via By providing the magnetically permeable housing 70, the magnetic rotating part 60 can be protected from the electrolyte 35 and/or the rotational resistance of the magnetic rotating part 60 can be reduced. The magnetically permeable housing 70 is made of resin such as polypropylene, acryl, vinyl chloride, or the like.
 透磁性ハウジング70の外面にはファスナーチェーン1を支持するための1以上の支持具として複数の支持部材78が設けられる。これにより、ファスナーチェーン1の位置及び姿勢が制御されると共にその走行路80が画定される。好適には、支持具(例えば、支持部材78)によりファスナーチェーン1が平坦な姿勢で支持される。ファスナーチェーン1は、磁性回転部60の周囲を、具体的には、磁性回転部60の回転軸62の径方向外側の位置で周方向に走行できる。磁性回転部60から径方向外側に離間するに応じて磁束密度が低下するが、透磁性ハウジング70に支持部材78を設けることでファスナーチェーン1を磁性回転部60の近傍で走行させることができる。透磁性ハウジング70とファスナーチェーン1の間で磁性メディアが交番磁界に応じて大きく運動することができ、めっき膜に対して磁性メディアが強く衝突できる。幾つかの場合、複数の支持部材78は、ファスナーチェーン1の螺旋状の走行路80を画定するように透磁性ハウジング70の外面に取り付けられる。走行路80を螺旋状とすることで電気めっき装置100の大型化を回避することができる。 A plurality of support members 78 are provided on the outer surface of the magnetically permeable housing 70 as one or more supports for supporting the fastener chain 1 . As a result, the position and posture of the fastener chain 1 are controlled and the running path 80 is defined. Preferably, the fastener chain 1 is supported in a flat posture by a support (for example, a support member 78). The fastener chain 1 can run in the circumferential direction around the magnetic rotating portion 60 , more specifically, at a radially outer position of the rotating shaft 62 of the magnetic rotating portion 60 . Although the magnetic flux density decreases with increasing distance from the magnetic rotating portion 60 in the radial direction, the fastener chain 1 can run in the vicinity of the magnetic rotating portion 60 by providing the support member 78 in the magnetically permeable housing 70 . Between the magnetically permeable housing 70 and the fastener chain 1, the magnetic media can move greatly according to the alternating magnetic field, and the magnetic media can strongly collide with the plating film. In some cases, a plurality of support members 78 are attached to the outer surface of magnetically permeable housing 70 to define a helical runway 80 for fastener chain 1 . Making the running path 80 spiral makes it possible to avoid an increase in the size of the electroplating apparatus 100 .
 各支持部材78は、L字形状部材であり、詳細には、磁性回転部60の回転軸62から径方向外側に延びる第1棒部78aと、透磁性ハウジング70の外面から所定の間隔を空けて上方に延びる第2棒部78bを有する。第1棒部78aによって、重力に応じた電解液35中でのファスナーチェーン1の沈降が阻止される。第2棒部78bによって、重力、磁性メディア又は水流等によってファスナーチェーン1が透磁性ハウジング70の外面から離れる側に倒れることが阻止される。支持部材78は、ネジ止め、接着といった任意の方法で透磁性ハウジング70の外周に固定され得る。 Each support member 78 is an L-shaped member, more specifically, a first rod portion 78a extending radially outward from the rotation axis 62 of the magnetic rotating portion 60 and spaced apart from the outer surface of the magnetically permeable housing 70 by a predetermined distance. It has a second rod portion 78b extending upwardly. The first rod portion 78a prevents the fastener chain 1 from settling in the electrolytic solution 35 due to gravity. The second rod portion 78b prevents the fastener chain 1 from falling away from the outer surface of the magnetically permeable housing 70 due to gravity, magnetic media, water flow, or the like. Support member 78 may be secured to the perimeter of magnetically permeable housing 70 in any manner, such as by screwing or gluing.
 透磁性ハウジング70の外面にカソード10を設けることができる。カソード10は、ファスナーチェーン1の走行路に沿って延びるように設けられる。これによりカソード10に対する磁性メディアを介して金属製エレメント4a,4bの電気的な接続が良好になることが見込まれる。幾つかの場合、カソード10は、ファスナーチェーン1の螺旋状の走行路80に対応して透磁性ハウジング70の周囲に螺旋状に設けられる。この追加又は代替として、カソード10は、走行路80を走行中のファスナーチェーン1の金属製エレメント4a,4bがカソード10に対面する位置に設けられる。なお、永久磁石64、透磁性ハウジング70、カソード10、磁性メディア、及び金属製エレメント4a,4bが磁性回転部60の回転軸に関する径方向において同軸上に配置される状態になる。 A cathode 10 can be provided on the outer surface of the magnetically permeable housing 70 . Cathode 10 is provided so as to extend along the running path of fastener chain 1 . This is expected to improve the electrical connection of the metal elements 4a and 4b to the cathode 10 via the magnetic media. In some cases, the cathode 10 is provided spirally around the permeable housing 70 corresponding to the spiral running path 80 of the fastener chain 1 . Additionally or alternatively, the cathode 10 is provided at a position where the metal elements 4 a and 4 b of the fastener chain 1 running on the running path 80 face the cathode 10 . The permanent magnet 64 , the magnetically permeable housing 70 , the cathode 10 , the magnetic media, and the metal elements 4 a and 4 b are arranged coaxially in the radial direction with respect to the rotation axis of the magnetic rotating portion 60 .
 透磁性ハウジング70の外面にカソード10を設ける場合、磁性回転部60の回転によってカソード10に誘導起電力が生じ、カソード10に誘導電流が流れる。この影響を低減するため透磁性ハウジング70の外面においてカソード10が(円筒状ではなく)線状に設けられる。カソード10に鎖交する磁束が低減し、誘導起電力及び誘導電流を抑制することができる。なお、螺旋状のカソード10は、線状のカソード10を透磁性ハウジング70の外面に螺旋状に巻くことにより構築可能である。線状のカソード10は、螺旋状以外の態様で透磁性ハウジング70の外面に設けられ得る。カソード10は、ネジ、接着剤、嵌合といった方法で透磁性ハウジング70の外面に固定され得る。 When the cathode 10 is provided on the outer surface of the magnetically permeable housing 70 , an induced electromotive force is generated in the cathode 10 by the rotation of the magnetic rotating part 60 and an induced current flows through the cathode 10 . To reduce this effect, the cathode 10 is linear (rather than cylindrical) on the outer surface of the magnetically permeable housing 70 . The magnetic flux interlinking with the cathode 10 is reduced, and the induced electromotive force and induced current can be suppressed. The spiral cathode 10 can be constructed by spirally winding the linear cathode 10 around the outer surface of the magnetically permeable housing 70 . The linear cathode 10 may be provided on the outer surface of the magnetically permeable housing 70 in a manner other than spiral. Cathode 10 may be secured to the outer surface of magnetically permeable housing 70 by means of screws, adhesives, snap fit, or the like.
 カソード10が線状又は螺旋状に設けられる場合、カソード10の長さが長くなってしまう。カソード電位の安定化を図るため、一つの透磁性ハウジング70において、直流電源E1との複数の接点をカソード10に設けることができ、又はカソード10を分割して直流電源E1との接点を個別に設けることができる。 When the cathode 10 is provided linearly or spirally, the length of the cathode 10 becomes long. In order to stabilize the cathode potential, in one magnetically permeable housing 70, the cathode 10 can be provided with a plurality of contacts with the DC power supply E1, or the cathode 10 can be divided to provide individual contacts with the DC power supply E1. can be provided.
 ファスナーチェーン1の走行路80の近傍にアノード20を配置するためにフレーム72を用いることができる(図9参照)。フレーム72に対して複数のアノード20を直接的又はカゴ等を介して間接的に取り付けることによってファスナーチェーン1の走行路80に沿って異なる場所に複数のアノード20を配置することができる。これによりファスナーチェーン1の走行路80沿いにおける金属イオン濃度の偏りを低減することができる。例えば、フレーム72に対してメッシュ状のカゴが取り付けられ、カゴ内に(アノード20として機能する)金属板が入れられる。 A frame 72 can be used to arrange the anode 20 in the vicinity of the running path 80 of the fastener chain 1 (see FIG. 9). A plurality of anodes 20 can be arranged at different locations along the running path 80 of the fastener chain 1 by directly or indirectly attaching the plurality of anodes 20 to the frame 72 via a basket or the like. As a result, the uneven concentration of metal ions along the running path 80 of the fastener chain 1 can be reduced. For example, a mesh basket is attached to the frame 72, and a metal plate (functioning as the anode 20) is placed in the basket.
 フレーム72は、磁性回転部60の回転軸62に関して透磁性ハウジング70よりも径方向外側に位置する。フレーム72は、上下方向に間隔を空けて設けられた横材73と、横材73同士を上下方向で連結する縦材74を有する円筒状の網部材である。フレーム72は、ファスナーチェーン1の走行路80と干渉しないように構築される。アノード20から溶出する金属イオンは、フレーム72の網目を通して走行路80に在るファスナーチェーン1の金属製エレメント4a,4bに到達することができる。当業者には明らかなように、フレーム72を用いることなく、ファスナーチェーン1の走行路80の近傍にアノード20を配置することもできる。 The frame 72 is located radially outside the magnetically permeable housing 70 with respect to the rotating shaft 62 of the magnetic rotating portion 60 . The frame 72 is a cylindrical net member having horizontal members 73 spaced apart in the vertical direction and vertical members 74 connecting the horizontal members 73 together in the vertical direction. The frame 72 is constructed so as not to interfere with the running path 80 of the fastener chain 1. - 特許庁Metal ions eluted from the anode 20 can reach the metal elements 4 a and 4 b of the fastener chain 1 on the running path 80 through the mesh of the frame 72 . As will be apparent to those skilled in the art, the anode 20 can also be placed near the running path 80 of the fastener chain 1 without using the frame 72 .
 図10を参照して磁性メディアの役割について更に説明する。図10(a)の時、透磁性ハウジング70の外周の所定位置において、その内側に磁性回転部60のN極配置ゾーンが位置する。図10(b)の時、透磁性ハウジング70の外周の所定位置において、その内側に磁性回転部60のS極配置ゾーンが位置する。図10(a)、図10(b)のいずれの状態においても適切な量の磁性メディア9がカソード10と金属製エレメント4a,4bの間に存在する。図10(a)、10(b)において磁束が破線で示されている。 The role of the magnetic media will be further explained with reference to FIG. 10(a), the north pole arrangement zone of the magnetic rotating part 60 is located inside a predetermined position on the outer circumference of the magnetically permeable housing 70. In FIG. 10(b), at a predetermined position on the outer periphery of the magnetically permeable housing 70, the south pole arrangement zone of the magnetic rotating part 60 is positioned inside thereof. An appropriate amount of the magnetic media 9 exists between the cathode 10 and the metal elements 4a and 4b in either state of FIGS. 10(a) and 10(b). The magnetic flux is indicated by dashed lines in FIGS. 10(a) and 10(b).
 図10(a)から図10(b)に磁束の向きが変わる過程で、各磁性メディア9が回転及び変位する。各磁性メディア9の配向及び変位の変化に関わらず、その前後又はその全過程において複数のメディアを介して金属製エレメント4a,4bがカソード10に電気的に接続され得る。幾つかの磁性メディア9は、その回転時、金属製エレメント4a,4b上で成長中のめっき膜に衝突する。ファスナーチェーン1においては、金属製エレメント4a,4bは、磁性メディア9を介してカソード10に電気的に接続されなくても、他の金属製エレメント4a,4bを介してカソード10に電気的に接続され得る。 Each magnetic medium 9 rotates and displaces in the process of changing the direction of the magnetic flux from FIG. 10(a) to FIG. 10(b). The metal elements 4a and 4b can be electrically connected to the cathode 10 through a plurality of media before, after, or in the entire process regardless of changes in the orientation and displacement of each magnetic medium 9. FIG. Some magnetic media 9 collide with the growing plating film on the metal elements 4a, 4b as they rotate. In the fastener chain 1, the metal elements 4a and 4b are electrically connected to the cathode 10 via the other metal elements 4a and 4b even if they are not electrically connected to the cathode 10 via the magnetic media 9. can be
 必ずしもこの限りではないが、ファスナーチェーン1の搬送を補助するように磁性メディア9を用いることができる。例えば、磁性回転部60の回転方向とその周囲を走行するファスナーチェーン1の走行方向が同じ方向に設定される。磁性メディア9は、交番磁界に応じて回転することの他、磁性回転部60の永久磁石64に連行して磁性回転部60と同じ方向に流動する。この磁性メディア9の流動によってファスナーチェーン1が押され、ファスナーチェーン1が同じ方向に走行し易くなる。 Although not necessarily limited to this, the magnetic media 9 can be used to assist the transportation of the fastener chain 1. For example, the rotational direction of the magnetic rotating portion 60 and the running direction of the fastener chain 1 running around it are set to be the same. The magnetic medium 9 not only rotates according to the alternating magnetic field, but also flows in the same direction as the magnetic rotating section 60 along with the permanent magnets 64 of the magnetic rotating section 60 . The flow of the magnetic media 9 pushes the fastener chain 1, making it easier for the fastener chain 1 to run in the same direction.
 ファスナーチェーン1の金属製エレメント4a,4bは、カソード10に対面した第1面5とカソード10とは反対側に向いた第2面6を有する(図10参照)。透磁性ハウジング70からファスナーチェーン1よりも径方向外側にアノード20が配置され、金属製エレメント4a,4bの第1面5側と第2面6側において同等の磁性メディアが存在しているものとすると、金属製エレメント4a,4bの第2面6側でのめっき膜の成長速度は、金属製エレメント4a,4bの第1面5側でのめっき膜の成長速度よりも大きくなる。金属製エレメント4a,4bの表裏でめっき膜の厚みに違いが出ることを抑制するために、ファスナーチェーン1の走行路においてファスナーチェーン1の表裏を反転させると良い。 The metal elements 4a, 4b of the fastener chain 1 have a first surface 5 facing the cathode 10 and a second surface 6 facing away from the cathode 10 (see FIG. 10). It is assumed that the anode 20 is arranged radially outside the fastener chain 1 from the magnetically permeable housing 70, and equivalent magnetic media are present on the first surface 5 side and the second surface 6 side of the metal elements 4a and 4b. Then, the growth rate of the plating film on the second surface 6 side of the metal elements 4a and 4b becomes higher than the growth rate of the plating film on the first surface 5 side of the metal elements 4a and 4b. In order to suppress the difference in the thickness of the plating film between the front and back surfaces of the metal elements 4a and 4b, it is preferable to turn over the fastener chain 1 on the travel path of the fastener chain 1.
 図6に示す場合、めっき槽30には2つの交番磁界生成部50が設けられており、上流側の交番磁界生成部50の透磁性ハウジング70の外周に上流側の螺旋状走行路が設けられ、下流側の交番磁界生成部50の透磁性ハウジング70の外周に下流側の螺旋状走行路が設けられ、これらの螺旋状走行路の間にはファスナーチェーン1の表裏反転部90が設けられる。 In the case shown in FIG. 6, the plating tank 30 is provided with two alternating magnetic field generators 50, and the upstream spiral running path is provided on the outer periphery of the magnetically permeable housing 70 of the upstream alternating magnetic field generator 50. , a spiral running path on the downstream side is provided on the outer circumference of the permeable housing 70 of the alternating magnetic field generating section 50 on the downstream side, and a reversing section 90 of the fastener chain 1 is provided between these spiral running paths.
 図11に示す場合、表裏反転部90は、2つのガイドローラ91,92を有するだけである。ファスナーチェーン1の表裏反転は、上流側の透磁性ハウジング70と下流側の透磁性ハウジング70の間でファスナーチェーン1の走行方向を逆向きにすることにより達成される。即ち、図11に示すように、めっき槽30を上方から見た時、ファスナーチェーン1は、上流側の螺旋状走行路において時計回りに走行し、下流側の螺旋状走行路において半時計回りに走行する。このようにしてファスナーチェーン1の表裏が反転され、金属製エレメント4a,4bの表裏でのめっき膜の厚みの均一化が促進される。なお、ファスナーチェーン1の表裏反転は、他の様々な方法で実行することができる。  In the case shown in FIG. The reverse of the fastener chain 1 is achieved by reversing the running direction of the fastener chain 1 between the magnetically permeable housing 70 on the upstream side and the magnetically permeable housing 70 on the downstream side. That is, as shown in FIG. 11, when the plating bath 30 is viewed from above, the fastener chain 1 runs clockwise on the spiral running path on the upstream side and rotates counterclockwise on the spiral running path on the downstream side. run. In this manner, the fastener chain 1 is turned upside down, and the thickness of the plating film on the front and back sides of the metal elements 4a and 4b is made uniform. Note that the fastener chain 1 can be turned upside down by various other methods.
 電気めっき装置100の動作方法に関して、ファスナーチェーン1の所定部分について着目して説明する。まず、ファスナーチェーン1の搬送に応じて、ファスナーチェーン1の所定部分は、ローラ41,42に案内されて電解液35中の走行路80に到達する。ファスナーチェーン1の所定部分が走行路80を走行する前、モータ61の作動に基づいて磁性回転部60が回転しており、この周囲に交番磁界が生成される。ファスナーチェーン1の走行路80は交番磁界に配されており、そこで磁性メディア9が運動している。また、カソード10とアノード20間には直流電源E1により電圧が印加されている。 The operation method of the electroplating apparatus 100 will be described with a focus on a predetermined portion of the fastener chain 1. First, as the fastener chain 1 is conveyed, a predetermined portion of the fastener chain 1 is guided by the rollers 41 and 42 and reaches the running path 80 in the electrolytic solution 35 . Before a predetermined portion of the fastener chain 1 runs on the running path 80, the magnetic rotating part 60 is rotating based on the operation of the motor 61, and an alternating magnetic field is generated around it. The running path 80 of the fastener chain 1 is arranged in an alternating magnetic field, where the magnetic media 9 are in motion. A voltage is applied between the cathode 10 and the anode 20 by a DC power supply E1.
 ファスナーチェーン1の所定部分が走行路80を走行する時、その金属製エレメント4a,4bが磁性メディア9を介して透磁性ハウジング70の外面に設けられたカソード10に電気的に接続される。また、金属製エレメント4a,4b上に形成されるめっき膜に磁性メディア9が繰り返し衝突する。ファスナーチェーン1の所定部分が螺旋状の走行路80の下端から上端に向けて走行する期間においてめっき膜の成長と磁性メディア9のめっき膜への衝突が連続的に起きる。このようにして、電気めっき装置100の大型化を回避しつつ、十分な厚みのめっき膜を形成することが促進される。 When a predetermined portion of the fastener chain 1 runs on the running path 80 , the metal elements 4 a and 4 b are electrically connected to the cathode 10 provided on the outer surface of the magnetically permeable housing 70 via the magnetic media 9 . In addition, the magnetic media 9 repeatedly collide with the plated films formed on the metal elements 4a and 4b. Growth of the plated film and collision of the magnetic media 9 against the plated film occur continuously during a period in which a predetermined portion of the fastener chain 1 travels from the lower end to the upper end of the spiral travel path 80 . In this way, formation of a sufficiently thick plated film is promoted while avoiding an increase in size of the electroplating apparatus 100 .
 ファスナーチェーン1の所定部分は、続いて、表裏反転され、次の螺旋状の走行路80を逆方向に、即ち、その上端から下端に向けて走行する。この走行期間において上述と同様、めっき膜の成長と磁性メディア9のめっき膜への衝突が連続的に起きる。このようにしてファスナーチェーン1の金属製エレメント4a,4bの表裏にめっき膜が形成される。螺旋状の走行路80を走行し終えると、ファスナーチェーン1の所定部分は、ローラ43,44に案内されて電解液35から退出する。 A predetermined portion of the fastener chain 1 is then turned inside out and runs on the next spiral running path 80 in the opposite direction, that is, from its upper end to its lower end. During this running period, growth of the plated film and collision of the magnetic media 9 with the plated film occur continuously in the same manner as described above. In this manner, plating films are formed on the front and back surfaces of the metal elements 4a and 4b of the fastener chain 1. As shown in FIG. After running along the spiral running path 80 , a predetermined portion of the fastener chain 1 is guided by the rollers 43 and 44 and leaves the electrolytic solution 35 .
 なお、金属製エレメント4a,4bの接触部分にも金属イオンが析出し、めっき膜が形成される。電気めっきに際して、ファスナーチェーン1の長手方向に沿って金属製エレメント4a,4bの係合列が磁性メディア9を介して連続的にカソード10に電気的に接続され、従って、ファスナーチェーン1の長手方向に沿って金属製エレメント4a,4bの係合列に電位勾配が生じることが抑制される。各モータ61のオン・オフ、スイッチSWのオン、オフの制御のため、シーケンサーを用いることができる。シーケンサーは、ファスナーチェーンの搬送開始・搬送停止も制御することができ得る。 Metal ions are also deposited on the contact portions of the metal elements 4a and 4b, forming a plating film. During electroplating, the engagement rows of the metal elements 4a and 4b along the longitudinal direction of the fastener chain 1 are continuously electrically connected to the cathode 10 through the magnetic media 9, thus The occurrence of a potential gradient in the engagement rows of the metal elements 4a, 4b along is suppressed. A sequencer can be used for on/off control of each motor 61 and on/off control of the switch SW. The sequencer may also be able to control the start/stop of transport of the fastener chain.
 上述の説明では、主に図6を参照して、2つの交番磁界生成部50、2つの螺旋状走行路、及び1つの表裏反転部90が設けられる形態について説明したが、1つの交番磁界生成部50と1つの螺旋状走行路のみが設けられる形態も想定される。ファスナーチェーン1の走行路80は必ずしも螺旋状に限らず、直線上、ジグザグ状等も有り得る。また、複数の透磁性ハウジング70にファスナーチェーン1を蛇行状に掛け渡し、これを磁性回転部60の回転軸に沿って繰り返すこともできる。 In the above description, mainly with reference to FIG. 6, a configuration in which two alternating magnetic field generating sections 50, two spiral running paths, and one front/back reversing section 90 are provided has been described. A configuration in which only the portion 50 and one spiral track is provided is also envisioned. The running path 80 of the fastener chain 1 is not necessarily helical, but may be linear, zigzag, or the like. Alternatively, the fastener chain 1 may be meanderingly wound around a plurality of magnetically permeable housings 70 , and this may be repeated along the rotation axis of the magnetic rotating portion 60 .
 以下、図12~図16を参照してバリエーションについて説明する。図12及び図13は、4つの交番磁界生成部50、4つの螺旋状走行路、2つの表裏反転部90が設けられる形態を示す。図12では、ファスナーチェーン1は、1番目の螺旋状走行路を時計回りに上向きに走行し、2番目の螺旋状走行路を反時計回りに下向きに走行し、3番目の螺旋状走行路を反時計回りに上向きに走行し、4番目の螺旋状走行路を時計回りに下向きに走行する。図13では、ファスナーチェーン1は、1番目の螺旋状走行路を反時計回りに上向きに走行し、2番目の螺旋状走行路を時計回りに下向きに走行し、3番目の螺旋状走行路を時計回りに上向きに走行し、4番目の螺旋状走行路を反時計回りに下向きに走行する。4つ以上の交番磁界生成部50と4つの螺旋状走行路を設けることによりファスナーチェーン1の走行速度を増加しても十分なめっき膜の厚みを確保することができる。 Variations will be described below with reference to FIGS. 12 to 16. FIG. 12 and 13 show a configuration in which four alternating magnetic field generators 50, four spiral running paths, and two front/back reversing sections 90 are provided. In FIG. 12, the fastener chain 1 runs clockwise on the first spiral running path, runs counterclockwise downward on the second spiral running path, and runs on the third spiral running path. Run counter-clockwise upwards, then clockwise downwards on the fourth spiral track. In FIG. 13, the fastener chain 1 runs counterclockwise upward on the first spiral running path, runs clockwise downward on the second spiral running path, and runs on the third spiral running path. Run clockwise upwards and counterclockwise downwards on the fourth spiral track. By providing four or more alternating magnetic field generators 50 and four spiral running paths, a sufficient thickness of the plating film can be ensured even if the running speed of the fastener chain 1 is increased.
 図14及び図15は、支持部材78ではなく搬送機構40のローラ41,42によりファスナーチェーン1の位置及び配向が制御される形態を示す(即ち、搬送機構40のローラ41,42が、ファスナーチェーン1の支持具として機能する)。このような場合においても矛盾のない範囲で上述と同様の効果が得られる。 14 and 15 show a form in which the position and orientation of the fastener chain 1 are controlled by the rollers 41, 42 of the transport mechanism 40 rather than the support member 78 (that is, the rollers 41, 42 of the transport mechanism 40 control the direction of the fastener chain). 1). Even in such a case, the same effect as described above can be obtained within a consistent range.
 図14及び図15では、ファスナーチェーン1の水平走行路の上下に交番磁界生成部50’が設けられる。上述の説明と同様、交番磁界生成部50’は、磁性回転部60’(図15では、磁性回転部が簡略的に示される)、透磁性ハウジング70’を有する。上述と同様、磁性回転部60’は透磁性ハウジング70’に回転可能に密閉されて収容され、モータの作動に応じて回転する。磁性回転部6’は透磁性ハウジング70’内に複数個設けられていてもよい。なお、ここでは、モータの回転軸が水平に配置されている。上下の透磁性ハウジング70’の間にファスナーチェーン1の走行路80が設けられる。この走行路80を走行するファスナーチェーン1の金属製エレメント4a,4bを挟むように上下に所定間隔を空けてカソード10が配置される。また、ファスナーチェーン1のファスナーテープの上下両側にアノード20が配置される。磁性回転部60の回転に応じて磁性メディア9が回転し、カソード10と金属製エレメント4a,4bの電気的な接続が確保され、金属製エレメント4a,4b上にめっき膜が成長する。めっき膜の成長中、磁性メディア9がめっき膜に繰り返し衝突する。これにより上述と同様の良好な品質のめっき膜が形成される。なお、図14では一対の交番磁界生成部50’の間をファスナーチェーン1が1回のみ通過するが、めっき槽30内に複数対の交番磁界生成部50’を設置して、ファスナーチェーン1を複数回通過させるようにしてもよい。 14 and 15, alternating magnetic field generators 50' are provided above and below the horizontal running path of the fastener chain 1. As shown in FIG. Similar to the above description, the alternating magnetic field generator 50' has a magnetic rotor 60' (the magnetic rotor is schematically shown in FIG. 15) and a magnetically permeable housing 70'. As before, the magnetic rotating portion 60' is rotatably enclosed in a magnetically permeable housing 70' and rotates in response to motor operation. A plurality of magnetic rotating parts 6' may be provided in the magnetically permeable housing 70'. In addition, here, the rotating shaft of the motor is arranged horizontally. A running path 80 for the fastener chain 1 is provided between the upper and lower magnetically permeable housings 70'. The cathodes 10 are arranged vertically with a predetermined interval so as to sandwich the metal elements 4a and 4b of the fastener chain 1 running on the running path 80. As shown in FIG. Anodes 20 are arranged on both upper and lower sides of the fastener tape of the fastener chain 1 . The magnetic medium 9 rotates according to the rotation of the magnetic rotating part 60, the electrical connection between the cathode 10 and the metal elements 4a and 4b is ensured, and the plating film grows on the metal elements 4a and 4b. During growth of the plating film, the magnetic media 9 repeatedly collide with the plating film. As a result, a plated film of good quality similar to that described above is formed. In FIG. 14, the fastener chain 1 passes through the pair of alternating magnetic field generators 50' only once. You may make it pass several times.
 図16は、めっき槽30の電解液中にファスナーチェーン1が所定の位置及び配向で供給され、電気めっきにより金属製エレメントにめっき膜が形成されることを示す。ファスナーチェーン1の長手方向において、その一端が1以上の支持具120により支持され、その他端が別の1以上の支持具120により支持される。このような方法でファスナーチェーン1の位置及び配向を制御することもできる。支持具120の具体的な構成は様々であり、その個数も様々である。図示例では、合計4つの支持具120が設けられ、そのうちの2つがファスナーチェーン1の一端に割り当てられ、他の2つがファスナーチェーン1の他端に割り当てられる。 FIG. 16 shows that the fastener chain 1 is supplied in the electrolytic solution of the plating bath 30 at a predetermined position and orientation, and a plating film is formed on the metal element by electroplating. In the longitudinal direction of the fastener chain 1 , one end is supported by one or more supports 120 and the other end is supported by another one or more supports 120 . The position and orientation of the fastener chain 1 can also be controlled in this way. The specific configuration of the support 120 may vary, and the number thereof may also vary. In the illustrated example, a total of four supports 120 are provided, two of which are assigned to one end of the fastener chain 1 and the other two to the other end of the fastener chain 1 .
 各支持具120は、固定部材121,124、バネ122及び押圧ボール123から構成される。固定部材121,124は、めっき槽30中の所定位置に固定されている。バネ122の一端が固定部材121に固定され、バネ122の他端に押圧ボール123が固定される。押圧ボール123と固定部材124の支持面の間でファスナーチェーン1のファスナーテープが挟まれて位置決めされる。図16から明らかなように、ファスナーチェーンを走行させることは必須ではない。念のため述べれば、図16においてファスナーストリンガーを支持具120により所定位置及び配向で支持することもできる。 Each support 120 is composed of fixing members 121 , 124 , springs 122 and pressing balls 123 . The fixing members 121 and 124 are fixed at predetermined positions in the plating bath 30 . One end of the spring 122 is fixed to the fixing member 121 and the other end of the spring 122 is fixed to the pressing ball 123 . The fastener tape of the fastener chain 1 is sandwiched and positioned between the pressing ball 123 and the supporting surface of the fixing member 124 . As is clear from FIG. 16, running the fastener chain is not essential. As a reminder, the fastener stringers can also be supported in place and orientation by supports 120 in FIG.
 実施例
 本願の図13に示すめっき装置を用いてファスナーチェーンの金属製エレメントにめっき膜を形成した。なお、磁性回転部の回転速度は、400rpmである。ファスナーチェーンの走行速度は、3.5m/分である。電源電圧は、1Vであり、各カソードに10Aの電流を流した。電気めっき時間は、7分である。このファスナーチェーンをデニム生地に対して縫い付け、洗い加工を施した。洗い加工として、デニム生地が濃色を維持する濃色加工と、デニム生地が淡色になる淡色加工を行った。
Example A plating film was formed on a metal element of a fastener chain using the plating apparatus shown in FIG. 13 of the present application. The rotational speed of the magnetic rotating portion is 400 rpm. The running speed of the fastener chain is 3.5 m/min. The power supply voltage was 1 V, and a current of 10 A was passed through each cathode. Electroplating time is 7 minutes. This fastener chain was sewn onto the denim fabric and washed. As the washing process, a dark color process to maintain the dark color of the denim fabric and a light color process to lighten the denim fabric were performed.
 洗い加工では、ファスナーチェーン付きのデニム生地に対して、前処理、ストーンウォッシュ、バイオウォッシュ、及びエコブリーチをこの順で行った。淡色加工では、エコブリーチ後に強ブリーチを更に行った。前処理は、糊抜きのための湯洗い工程であり、90℃の熱水で20分洗い、60℃の熱水で5分洗い、30℃の温水で5分洗った。ストーンウォッシュは、軽石と共洗いする工程であり、30分洗った。バイオウォッシュは、酵素を用いて繊維を溶かしてデニム生地を柔らかくし、鳥羽取りする工程であり、55℃の熱水にセルラーゼを投入して20分洗った。エコブリーチは、ブドウ糖を用いてデニム生地の色を落として白度を出す工程であり、90℃の熱水にグルコース(20g/L)とNaOH(15g/L)を加えて20分洗った。ブリーチは、漂白剤でデニム生地の色を落として白度を出す工程であり、次亜塩素酸ソーダを加えて50°の熱水で15分洗った。 In the washing process, the denim fabric with a zipper chain was pretreated, stonewashed, biowashed, and eco-bleached in this order. In light color processing, strong bleaching was further performed after eco-bleaching. The pretreatment was a step of hot water washing for desizing, which included washing with hot water at 90°C for 20 minutes, washing with hot water at 60°C for 5 minutes, and washing with hot water at 30°C for 5 minutes. Stonewashing is the process of co-washing with pumice stone and was washed for 30 minutes. Bio-washing is a process in which fibers are dissolved using an enzyme to soften the denim fabric, and the denim fabric is washed for 20 minutes with cellulase added to hot water at 55°C. Eco-bleaching is a process of removing the color of the denim fabric using glucose to bring out the whiteness. Glucose (20 g/L) and NaOH (15 g/L) were added to hot water at 90° C. and washed for 20 minutes. Bleaching is a process of removing the color of the denim fabric with a bleaching agent to bring out whiteness, and sodium hypochlorite was added and washed with hot water at 50° for 15 minutes.
 洗い加工とは別に染加工も施した。染加工として、硫化染料を用いた染加工と、反応性染料を用いた染加工を行った。硫化染料を用いた染加工では、50°の熱水にアルカリ材、染料、染着促進剤、還元剤(チオゲン)を投入し、ファスナーチェーン付きのデニム生地を85°で20分に亘り浸漬させた。反応性染料を用いた染加工では、反応性染料を所定温度の熱水に投入し、ファスナーチェーン付きのデニム生地を所定時間に亘り浸漬させた。洗い加工と染加工とは別に更に24時間の塩水噴霧試験を行った。 In addition to the washing process, dyeing was also applied. As the dyeing process, the dyeing process using a sulfur dye and the dyeing process using a reactive dye were performed. In the dyeing process using sulfur dyes, alkaline materials, dyes, dyeing accelerators, and reducing agents (thiogen) are added to hot water at 50°, and denim fabric with a zipper chain is immersed at 85° for 20 minutes. rice field. In the dyeing process using a reactive dye, the reactive dye was put into hot water at a predetermined temperature, and the denim fabric with a fastener chain was immersed in it for a predetermined period of time. A further 24-hour salt spray test was carried out separately from the washing and dyeing processes.
 比較例1,2
 比較例1では、金属製エレメントに対してカソード電極(例えば、特許文献1,2の導電性媒体)を直接的に接触させて電気めっきを行った。比較例2では、無電解めっき方法によって金属製エレメントに対してめっき膜を形成した。ファスナーチェーンの走行速度は、30m/分である。続いて、実施例と同様に、洗い加工、染加工、及び塩水噴霧試験を施した。
Comparative Examples 1 and 2
In Comparative Example 1, electroplating was performed by directly contacting the cathode electrode (for example, the conductive medium of Patent Documents 1 and 2) to the metal element. In Comparative Example 2, a plating film was formed on the metal element by an electroless plating method. The running speed of the fastener chain is 30 m/min. Subsequently, washing processing, dyeing processing, and a salt spray test were performed in the same manner as in Examples.
 図17に示すように、実施例において比較例1,2と同等又はそれ以上の品質のめっき膜が形成されたことが確認できた。洗い加工前後で、比較例1、2、実施例ともに若干の剥離はあるものの、実施例においてはより軽度な剥離となっていることが確認できた。また、反応性染料による染加工において比較例1,2と同様、実施例において染加工の前後でめっき膜の剥離が見られない。硫化染料による染加工については比較例1,2と同様に変色が見られるものの、実施例は比較例1,2に対し、変色が発生した面積は少ない。また、24時間にわたり塩水を噴霧し続ける試験についても確認したところ、実施例について、比較例1,2と同様に表面の変色が見られなかった。 As shown in FIG. 17, it was confirmed that a plating film of quality equal to or higher than that of Comparative Examples 1 and 2 was formed in the example. Before and after the washing process, although there was some peeling in both Comparative Examples 1 and 2 and the example, it was confirmed that the peeling was milder in the example. Further, in dyeing with a reactive dye, as in Comparative Examples 1 and 2, peeling of the plating film was not observed before and after dyeing in the example. As for dyeing with a sulfur dye, although discoloration is observed in the same manner as in Comparative Examples 1 and 2, the area in which discoloration occurs is smaller in Example than in Comparative Examples 1 and 2. In addition, when a test in which salt water was continued to be sprayed for 24 hours was also confirmed, no discoloration of the surface was observed in the Example, as in Comparative Examples 1 and 2.
 上述の結果から、本開示の製法(電気めっき方法)により製造されたファスナーチェーンの金属製エレメントのめっき膜は、既存の製法(電気めっき方法又は無電解めっき方法)により製造されたファスナーチェーンの金属製エレメントのめっき膜と比較して劣らない加工耐性を有することが確認できた。 From the above results, it can be concluded that the plating film of the metal element of the fastener chain manufactured by the manufacturing method (electroplating method) of the present disclosure is the same as the metal plating film of the fastener chain manufactured by the existing manufacturing method (electroplating method or electroless plating method). It was confirmed that it has processing resistance comparable to that of the plated film of the element.
 詳細には、淡色の洗い加工について、実施例は、比較例1,2と比較して金属製エレメントのめっき層の表面の一様性が高い。反応性染料による染加工について、実施例は、比較例1,2と比較して金属製エレメントのめっき層の光沢度合いが高く維持されている。このように実施例は、比較例1,2と比較してめっき層の表面の一様性及び光沢度において改善が見られる。 Specifically, with regard to the light-colored washing process, in comparison with Comparative Examples 1 and 2, the uniformity of the surface of the plating layer of the metal element is higher in the example. As for dyeing with reactive dyes, in the example, the degree of glossiness of the plated layer of the metal element is kept high compared to the comparative examples 1 and 2. As described above, in the example, compared with the comparative examples 1 and 2, the uniformity and glossiness of the surface of the plating layer are improved.
 上述の開示を踏まえ、当業者は、各実施形態及び各特徴に対して様々な変更を加えることができる。請求の範囲に盛り込まれた符号は、参考のためであり、請求の範囲を限定解釈する目的で参照されるべきものではない。 Based on the above disclosure, a person skilled in the art can make various modifications to each embodiment and each feature. Reference signs in the claims are for reference only and should not be construed for the purpose of limiting the scope of the claims.
1    :ファスナーチェーン
2a   :ファスナーストリンガー
2b   :ファスナーストリンガー
4a   :金属製エレメント
4b   :金属製エレメント
7    :ファスナーチェーン
10   :カソード
20   :アノード
30   :めっき槽
35   :電解液
50   :交番磁界生成部
60   :磁性回転部
70   :透磁性ハウジング
Reference Signs List 1: Fastener chain 2a: Fastener stringer 2b: Fastener stringer 4a: Metal element 4b: Metal element 7: Fastener chain 10: Cathode 20: Anode 30: Plating tank 35: Electrolyte 50: Alternating magnetic field generator 60: Magnetic rotation Part 70: magnetically permeable housing

Claims (25)

  1.  金属製エレメント(4a,4b)にめっき膜が生成されたファスナーチェーン(1)又はファスナーストリンガー(2a,2b)の製造方法であって、
     めっき槽(30)の電解液中に少なくとも部分的に浸漬された1以上のカソード(10)と1以上のアノード(20)の間に電圧を印加する工程と、
     前記1以上のカソード(10)と前記1以上のアノード(20)の間に電圧が印加されている時又は期間において前記電解液中に交番磁界を生成する工程と、
     少なくとも前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記交番磁界が生成された空間に配されるように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向を制御する工程と、
     前記交番磁界に応じて複数の磁性メディア(9)を運動させ、前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記複数の磁性メディア(9)を介して前記カソード(10)に電気的に接続し、かつ前記金属製エレメント(4a,4b)上で成長するめっき膜に対して前記複数の磁性メディア(9)が衝突する工程を含む、製造方法。
    A method for manufacturing a fastener chain (1) or a fastener stringer (2a, 2b) in which a plating film is formed on metal elements (4a, 4b), comprising:
    applying a voltage between one or more cathodes (10) and one or more anodes (20) at least partially immersed in the electrolyte of a plating bath (30);
    generating an alternating magnetic field in the electrolyte when or during a voltage is applied between the one or more cathodes (10) and the one or more anodes (20);
    The fastener chain (1) or the fastener is arranged such that at least the metal elements (4a, 4b) of the fastener chain (1) or the fastener stringer (2a, 2b) are arranged in the space where the alternating magnetic field is generated. controlling the position and orientation of the stringers (2a, 2b);
    A plurality of magnetic media (9) are moved in accordance with the alternating magnetic field, and the metal elements (4a, 4b) of the fastener chain (1) or the fastener stringers (2a, 2b) move the plurality of magnetic media (9). ) to the cathode (10) and impinging the plurality of magnetic media (9) against a plated film growing on the metal elements (4a, 4b); Production method.
  2.  前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の長手方向が前記交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項1に記載の製造方法。 The fastener chain (1) or the fastener is arranged such that the longitudinal direction of the fastener chain (1) or the fastener stringers (2a, 2b) is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. Method according to claim 1, characterized in that the position and orientation of the stringers (2a, 2b) are controlled.
  3.  (i)前記金属製エレメント(4a,4b)の主面が前記磁極に関する磁軸に対して略直交するように、及び/又は、(ii)前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)がその幅方向において前記磁極に対して平坦な姿勢で対面するように、前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項2に記載の製造方法。 (i) the major faces of the metallic elements (4a, 4b) are substantially perpendicular to the magnetic axes with respect to the magnetic poles; and/or (ii) the fastener chain (1) or the fastener stringers (2a, 4b). The position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled so that the fastener chain (1) or the fastener stringers (2a, 2b) face the magnetic poles in a flat posture in the width direction thereof. Item 2. The manufacturing method according to item 2.
  4.  前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)が所定の走行路(80)において連続的又は断続的に走行することの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項1乃至3のいずれか一項に記載の製造方法。 As a result of the fastener chain (1) or the fastener stringers (2a, 2b) running continuously or intermittently on a predetermined running path (80), the fastener chain (1) or the fastener stringers (2a, 2b) ) is controlled in position and orientation.
  5.  前記所定の走行路(80)は、複数の支持部材(78)によって画定されることを特徴とする請求項4に記載の製造方法。 A method according to claim 4, characterized in that said predetermined travel path (80) is defined by a plurality of support members (78).
  6.  前記カソード(10)は、前記ファスナーチェーン(1)の走行路(80)に沿って延びることを特徴とする請求項4又は5に記載の製造方法。 The manufacturing method according to claim 4 or 5, characterized in that the cathode (10) extends along the running path (80) of the fastener chain (1).
  7.  前記1以上のアノード(20)は、前記ファスナーチェーン(1)の走行路(80)に沿って異なる場所に配置された複数のアノード(20)を含む、請求項4乃至6のいずれか一項に記載の製造方法。 7. Any one of claims 4 to 6, wherein said one or more anodes (20) comprises a plurality of anodes (20) arranged at different locations along the running path (80) of said fastener chain (1). The manufacturing method described in .
  8.  前記ファスナーチェーン(1)の走行路(80)は、1以上の螺旋状走行路(80)を含む、及び/又は、前記1以上のカソード(10)は、1以上の螺旋状カソード(10)を含むことを特徴とする請求項4乃至7のいずれか一項に記載の製造方法。 The runway (80) of the fastener chain (1) comprises one or more helical runways (80) and/or the one or more cathodes (10) comprise one or more helical cathodes (10) 8. The manufacturing method according to any one of claims 4 to 7, comprising:
  9.  前記電解液中に交番磁界を生成する工程は、異なる磁極が回転方向に交互に配置された1以上の磁性回転部(60)を回転させることを含むことを特徴とする請求項1乃至8のいずれか一項に記載の製造方法。 9. The method of any one of claims 1 to 8, wherein the step of generating an alternating magnetic field in the electrolyte comprises rotating one or more magnetic rotating parts (60) in which different magnetic poles are alternately arranged in the direction of rotation. The manufacturing method according to any one of the items.
  10.  前記磁性回転部(60)の周囲で前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9に記載の製造方法。 position and position of the fastener chain (1) or the fastener stringers (2a, 2b) as a result of running the fastener chain (1) or the fastener stringers (2a, 2b) around the magnetic rotating part (60); 10. The method of claim 9, wherein orientation is controlled.
  11.  前記磁性回転部(60)の周囲で螺旋状に前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9又は10に記載の製造方法。 As a result of running the fastener chain (1) or the fastener stringers (2a, 2b) spirally around the magnetic rotating part (60), the fastener chain (1) or the fastener stringers (2a, 2b) 11. A method according to claim 9 or 10, characterized in that the position and orientation of the are controlled.
  12.  前記磁性回転部(60)は、回転可能な態様で密閉された透磁性ハウジング(70)に収容されることを特徴とする請求項9乃至11のいずれか一項に記載の製造方法。 The manufacturing method according to any one of claims 9 to 11, characterized in that the magnetic rotating part (60) is housed in a magnetically permeable housing (70) which is sealed in a rotatable manner.
  13.  前記透磁性ハウジング(70)の外面には前記ファスナーチェーン(1)を支持するための複数の支持部材(78)が設けられることを特徴とする請求項12に記載の製造方法。 The manufacturing method according to claim 12, wherein the outer surface of the magnetically permeable housing (70) is provided with a plurality of support members (78) for supporting the fastener chain (1).
  14.  前記カソード(10)は、前記透磁性ハウジング(70)の外面に設けられた線状又は螺旋状カソード(10)を含む、請求項12又は13に記載の製造方法。 The manufacturing method according to claim 12 or 13, wherein the cathode (10) comprises a linear or spiral cathode (10) provided on the outer surface of the magnetically permeable housing (70).
  15.  前記電解液中に交番磁界を生成する工程は、前記1以上の磁性回転部(60)として設けられた異なる磁性回転部(60)それぞれを回転させることを含み、
     前記異なる磁性回転部(60)に亘って前記ファスナーチェーン(1)を走行させることの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9乃至14のいずれか一項に記載の製造方法。
    The step of generating an alternating magnetic field in the electrolytic solution includes rotating each of the different magnetic rotating parts (60) provided as the one or more magnetic rotating parts (60),
    characterized in that the position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled as a result of running the fastener chain (1) over the different magnetic rotating parts (60). The manufacturing method according to any one of claims 9 to 14.
  16.  前記異なる磁性回転部(60)に亘って前記ファスナーチェーン(1)を走行させることは、前記異なる磁性回転部(60)の周囲の螺旋状の走行路(80)において逆方向に前記ファスナーチェーン(1)を走行させることを含むことを特徴とする請求項15に記載の製造方法。 Running the fastener chain (1) over the different magnetic rotating parts (60) means that the fastener chain (1) is reversed in the spiral running path (80) around the different magnetic rotating parts (60). 16. The method of claim 15, comprising running 1).
  17.  前記ファスナーチェーン(1)は、前記異なる磁性回転部(60)の間で表裏が反転されることを特徴とする請求項15又は16に記載の製造方法。 The manufacturing method according to claim 15 or 16, wherein the fastener chain (1) is turned upside down between the different magnetic rotating parts (60).
  18.  前記磁性回転部(60)の回転方向に沿って前記ファスナーチェーン(1)が走行することの結果として前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向が制御されることを特徴とする請求項9乃至17のいずれか一項に記載の製造方法。 The position and orientation of the fastener chain (1) or the fastener stringers (2a, 2b) are controlled as a result of the fastener chain (1) running along the rotational direction of the magnetic rotating part (60). 18. The manufacturing method according to any one of claims 9 to 17, characterized by:
  19.  請求項1乃至18のいずれか一項に記載の製造方法で得られたファスナーチェーン(1)を切断する工程と、
     前記切断により得られた短尺なファスナーチェーン(1)に対してスライダーを取り付けて、前記短尺なファスナーチェーン(1)の一対のファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)の係合及び係合解除を可能とする工程を含む、スライドファスナーの製造方法。
    A step of cutting a fastener chain (1) obtained by the manufacturing method according to any one of claims 1 to 18;
    A slider is attached to the short fastener chain (1) obtained by the cutting, and the metal elements (4a, 4b) of the pair of fastener stringers (2a, 2b) of the short fastener chain (1) are cut. A method of manufacturing a slide fastener, comprising a step of enabling engagement and disengagement.
  20.  ファスナーチェーン(1)又はファスナーストリンガー(2a,2b)の金属製エレメント(4a,4b)にめっき膜を生成するための電気めっき装置(100)であって、
     1以上のカソード(10)と1以上のアノード(20)が少なくとも部分的に浸漬される電解液を貯留するめっき槽(30)と、
     前記めっき槽(30)の電解液中で交番磁界を生成する交番磁界生成部(50)と、
     少なくとも前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)が前記交番磁界が生成された空間に配されるように設けられた前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の1以上の支持具(78,42,43,120)を備え、
     前記カソード(10)は、前記1以上の支持具(78,42,43,120)により支持された前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の前記金属製エレメント(4a,4b)と前記カソード(10)の間で複数の磁性メディア(9)が前記交番磁界に応じて運動することを許容し、かつ前記複数の磁性メディア(9)を介して前記金属製エレメント(4a,4b)に電気的に接続可能に設けられる、電気めっき装置。
    An electroplating apparatus (100) for forming a plating film on metal elements (4a, 4b) of a fastener chain (1) or fastener stringers (2a, 2b),
    a plating bath (30) containing an electrolyte in which one or more cathodes (10) and one or more anodes (20) are at least partially submerged;
    an alternating magnetic field generator (50) for generating an alternating magnetic field in the electrolytic solution of the plating bath (30);
    The fastener chain (1) provided such that at least the fastener chain (1) or the metal elements (4a, 4b) of the fastener stringers (2a, 2b) are arranged in the space where the alternating magnetic field is generated. or one or more supports (78, 42, 43, 120) of said fastener stringers (2a, 2b),
    The cathode (10) comprises the metal elements (4a, 4b) of the fastener chain (1) or fastener stringers (2a, 2b) supported by the one or more supports (78, 42, 43, 120). ) and the cathode (10), allowing a plurality of magnetic media (9) to move in response to the alternating magnetic field, and through the plurality of magnetic media (9), the metal elements (4a, 4b) is electrically connectable to the electroplating apparatus.
  21.  前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の長手方向が前記交番磁界の生成のために異なる磁極が交互に配置された所定方向に沿うように前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の位置及び配向を制御するように前記1以上の支持具(78,42,43,120)が設けられることを特徴とする請求項20に記載の電気めっき装置。 The fastener chain (1) or the fastener is arranged such that the longitudinal direction of the fastener chain (1) or the fastener stringers (2a, 2b) is along a predetermined direction in which different magnetic poles are alternately arranged for generating the alternating magnetic field. 21. Electroplating apparatus according to claim 20, characterized in that the one or more supports (78, 42, 43, 120) are provided to control the position and orientation of the stringers (2a, 2b).
  22.  前記交番磁界生成部(50)は、異なる磁極が回転方向に交互に配置された1以上の磁性回転部(60)を含むことを特徴とする請求項20又は21に記載の電気めっき装置。 The electroplating apparatus according to claim 20 or 21, wherein the alternating magnetic field generator (50) includes one or more magnetic rotating parts (60) in which different magnetic poles are alternately arranged in the rotating direction.
  23.  前記磁性回転部(60)が、回転可能にかつ密閉された透磁性ハウジング(70)に収容されることを特徴とする請求項22に記載の電気めっき装置。 23. Electroplating apparatus according to claim 22, characterized in that said magnetic rotating part (60) is housed in a magnetically permeable housing (70) that is rotatable and sealed.
  24.  前記1以上の支持具(78,42,43,120)は、前記透磁性ハウジング(70)の外面に設けられた1以上の支持部材(78)を含むことを特徴とする請求項23に記載の電気めっき装置。 24. The method of claim 23, wherein said one or more supports (78, 42, 43, 120) comprise one or more support members (78) provided on an outer surface of said magnetically permeable housing (70). electroplating equipment.
  25.  前記カソード(10)は、前記1以上の支持具(78,42,43,120)により支持された前記ファスナーチェーン(1)又は前記ファスナーストリンガー(2a,2b)の走行路(80)に沿って延びることを特徴とする請求項20乃至24のいずれか一項に記載の電気めっき装置。 The cathode (10) travels along the running path (80) of the fastener chain (1) or the fastener stringers (2a, 2b) supported by the one or more supports (78, 42, 43, 120). 25. The electroplating apparatus of any one of claims 20-24, wherein the electroplating apparatus extends.
PCT/JP2021/029394 2021-08-06 2021-08-06 Production method for fastener stringer, fastener chain, and slide fastener, and electroplating apparatus WO2023013054A1 (en)

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