[go: up one dir, main page]

WO2022200364A1 - Lutte contre les insectes, les acariens et les nématodes - Google Patents

Lutte contre les insectes, les acariens et les nématodes Download PDF

Info

Publication number
WO2022200364A1
WO2022200364A1 PCT/EP2022/057514 EP2022057514W WO2022200364A1 WO 2022200364 A1 WO2022200364 A1 WO 2022200364A1 EP 2022057514 W EP2022057514 W EP 2022057514W WO 2022200364 A1 WO2022200364 A1 WO 2022200364A1
Authority
WO
WIPO (PCT)
Prior art keywords
cas
pyridyl
spp
methyl
indazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2022/057514
Other languages
English (en)
Inventor
Patrik Hoegger
Ottmar Franz Hueter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Crop Protection AG Switzerland
Original Assignee
Syngenta Crop Protection AG Switzerland
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection AG Switzerland filed Critical Syngenta Crop Protection AG Switzerland
Publication of WO2022200364A1 publication Critical patent/WO2022200364A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P5/00—Nematocides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides

Definitions

  • the present invention relates to a combination for the control of damage caused by insect, acarina and/or nematode pests, in particular on plants, which combination comprises a mixture of active ingredients.
  • compositions comprising a benzimidazole compound and one or more further pesticidal compounds.
  • pesticidal combinations which provide improved, for example, biological properties, for example, synergistic properties, especially for controlling insect, acarina and nematode pests.
  • the benefits may also be an increased safety profile, improved physico-chemical properties, or increased biodegradability.
  • the present invention provides a method of controlling or preventing damage to a plant, which comprises applying, in any desired sequence or simultaneously, on the plant, the locus thereof or its propagation material, a combination comprising, as component (A), a compound of formula (I): wherein:
  • Ri is C1-C3 alkylene or halo C1-C3 alkylene
  • R2 is C1-C6 alkyl or Ci-C6alkoxy-Ci-C6 alkyl or halo- C1-C6 alkyl;
  • R3 is H or CN; and n is 0, 1 or 2; or an agrochemically acceptable salt thereof; and, as component (B), a compound selected from the group consisting of: B-3 fluxametamide (CAS 928783-29-3)
  • B-62 tioxazafen (CAS 330459-31-9); or agrochemically acceptable salts thereof.
  • the present invention provides a composition comprising, as component (A), a compound of formula (I): wherein:
  • Ri is C1-C3 alkylene or halo C1-C3 alkylene
  • R2 is C1-C6 alkyl or Ci-C6alkoxy-Ci-C6 alkyl or halo- C1-C6 alkyl;
  • R3 is H or CN; and n is 0, 1 or 2; or an agrochemically acceptable salt thereof; and, as component (B), a compound selected from the group consisting of B-1 to B-62 as defined above, or agrochemically acceptable salts thereof.
  • composition further comprises one or more auxiliaries and/or diluents.
  • the combination or composition of (A) and (B) may be in a suitable ratio by weight, examples of which are between 500:1 to 1 :500, 100:1 to 1 :100, 50:1 to 1 :50, or 20:1 to 1 :20, or preferably 10:1 to 1 :10 or 5:1 to 1 :5; more preferably 3.1 to 1 :3 by weight.
  • the ratio is within the range of 2:1 to 1 :2, advantageously 1 :1 , by weight.
  • the present invention provides a method of controlling or preventing damage to a plant, which comprises applying, in any desired sequence or simultaneously, on the plant, the locus thereof or its propagation material, a combination comprising, as component (A), a compound of formula
  • Ri is C1-C3 alkylene or halo C1-C3 alkylene
  • R2 is C1-C6 alkyl or Ci-C6alkoxy-Ci-C6 alkyl or halo- C1-C6 alkyl;
  • R3 is H or CN; and n is 0, 1 or 2; or an agrochemically acceptable salt thereof; and, as component (B), a compound selected from the group consisting of:
  • B-88 chlorfenapyr (CAS 122453-73-0); or agrochemically acceptable salts thereof; wherein the combination of (A) and (B) is in a ratio by weight of 500:1 to 1 :500, 100:1 to 1 :100, 50:1 to 1 :50, or 20:1 to 1 :20, 10:1 to 1 :10; 5:1 to 1 :5; or 3.1 to 1 :3 by weight.
  • the present invention provides a composition comprising, as component (A), a compound of formula (I): wherein:
  • Ri is C1-C3 alkylene or halo C1-C3 alkylene
  • R2 is C1-C6 alkyl or Ci-C6alkoxy-Ci-C6 alkyl or halo- C1-C6 alkyl;
  • R3 is H or CN; and n is 0, 1 or 2; or an agrochemically acceptable salt thereof; and, as component (B), a compound selected from the group consisting of B-63 to B-88 as defined above, or agrochemically acceptable salts thereof; wherein the composition comprises (A) and (B) in a ratio by weight of 500:1 to 1 :500, 100:1 to 1 : 100, 50:1 to 1 :50, or 20:1 to 1 :20, 10:1 to 1 :10; 5:1 to 1 :5; or 3.1 to 1 :3 by weight.
  • composition further comprises one or more auxiliaries and/or diluents.
  • the ratio of component (A) to component (B) is within the range of 3:1 to 1 :3, 2:1 to 1 :2, or about 1 :1 , by weight.
  • the present invention provides the use of a composition of the invention as an insecticide, acaricide and/or nematicide.
  • the present invention provides a formulation comprising a composition of the invention, the formulation comprising from 0.01 to 90% by weight of active agents, from 0 to 25% by weight of agriculturally acceptable surfactant and from 10 to 99.9 percent by weight of solid or liquid formulation inerts and adjuvants.
  • the present invention provides a concentrate composition for dilution by a user, the concentrate composition comprising a composition of the invention, comprising from 2% to 80% by weight, preferably between about 5% and 70% by weight of active agents.
  • the present invention also provides the use of the combination or composition as defined above for controlling insect, acarina and/or nematode pests.
  • the compound of formula (I) is a compound of formula (I) in which Ri is
  • the compound of formula (I) is a compound of formula (I) in which R2 IS methyl, difluoromethyl, ethyl, or methoxymethyl. In certain examples, the compound of formula (I) is a compound of formula (I) in which R3 IS cyano.
  • the compound of formula (I) is a compound of formula (I) in which n is 0 or
  • Ri is CF2
  • R2 is methyl
  • R3 is H or CN
  • n is 2.
  • the combinations according to the invention can also have further surprising advantageous properties.
  • advantageous properties are: more advantageous degradability, improved toxicological and/or ecotoxicological behaviour, or improved characteristics of the useful plants including: emergence, crop yields, more developed root system, tillering increase, increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, greener leaf colour, less fertilizers needed, less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, improved plant vigour, and early germination.
  • component (A) may give rise to synergistic activity. Therefore, according to a further aspect of the invention there is provided a composition, wherein component (A) and component (B) are present in the composition in amounts producing a synergistic effect. This synergistic activity is apparent from the fact that the activity of the composition comprising component (A) and component (B) is greaterthan the sum of the corresponding activities of component
  • the active ingredients in the combinations of the present invention may be applied to a pest, plant, plant propagation material or plant growing locus either simultaneously (for example as a preformulated mixture or a tank mix), or sequentially in a suitable timescale.
  • the compounds of the combination may be used either in pure form, i.e., as a solid active ingredient, for example, in a specific particle size, or preferably together with at least one of the auxiliary (also known as adjuvants) customary in formulation technology, such as extenders, e.g., solvents or solid carriers, or surface-active compounds (surfactants), in the form of a formulation, in the present invention.
  • auxiliary also known as adjuvants
  • extenders e.g., solvents or solid carriers, or surface-active compounds (surfactants)
  • surfactants surface-active compounds
  • (B) are each in the form of a formulation composition with one or more of customary formulation auxiliaries.
  • compounds (A) and (B) can be used in the form of separate formulations.
  • the compounds can be applied to the locus where control is desired either simultaneously or in succession at short interval, for example on the same day, if desired together with further carriers, surfactants or other application-promoting adjuvants customarily employed in formulation technology.
  • (A) and (B) are applied simultaneously.
  • Co-application or simultaneous application of components (A) and (B) has the added benefit of minimising farmer time spent applying products to crops.
  • the combination may also encompass specific plant traits incorporated into the plant using any means, for example conventional breeding or genetic modification.
  • each of (A), and (B) can be obtained from a separate formulation source and mixed together (known as a tank-mix, ready-to-apply, spray broth, or slurry), optionally with other pesticides, or (A), and (B) can be obtained as single formulation mixture source (known as a pre-mix, concentrate, formulated product), and optionally mixed together with other pesticides.
  • the composition comprises an agriculturally acceptable formulation adjuvant.
  • a composition consisting essentially of component (A), component (B) and an agriculturally acceptable adjuvant In a further embodiment, there is provided a composition consisting of component (A), component (B) and an agriculturally acceptable adjuvant.
  • formulation adjuvants such as carriers, solvents and surface-active agents (SFAs).
  • the combinations and compositions of the present invention may be useful for the control of pests, such as insects, in improving the tolerance of crop plants to abiotic stress conditions, and/or in improving the yield of crop plants.
  • the combinations and compositions of the present invention may be useful for the control of insect and/or acarina and/or nematode pests.
  • the present invention provides a method for controlling pests in or on crop plants, improving the tolerance of crop plants to abiotic stress conditions, and/or improving the yield of crop plants, comprising treating the pests, plants, plant part, plant propagation material, or plant growing locus with a composition as described herein.
  • the combinations and compositions of the present invention may be useful for extending the duration of protection afforded to the plant material.
  • the combinations and compositions of the present invention may show both a fast-acting curative action and a preventative or protective action.
  • the combinations and compositions of the present invention may be useful for extending the range of crops with which the combinations and compositions are useful and/or the range of pests against which the combinations and compositions provide effective control.
  • the combinations and compositions of the present invention provide an enhanced biological profile which may include a more complete activity spectrum and/or complementary modes of activity.
  • the component (A) compounds and the component (B) compounds may provide complementary mobilities in the plant.
  • the component (A) compound has a greater acropetal movement in the plant compared with the component (B) compound, such that the component (B) compound provides more localised protection.
  • Examples include component (B) compounds B1 to B3, B6 and B7.
  • the component (A) compound has a lower acropetal movement in the plant compared with the component (B) compound, such that the component (A) compound provides more localised protection.
  • Examples include component (B) compound B87, which shows acropetal and basipetal movement and also protects new growth of the plant.
  • Compounds of formula (I) are described in WO 2020/013147.
  • Compound B-1 nicofluprole (CAS 1771741-86-6), is described in WO 2015067647.
  • B-2 broflanilide (CAS 1207727-04-5), is described in WO 2010018714.
  • B-3 fluxametamide (CAS 928783-29-3), is described in WO 2007026965.
  • B-4 tetraniliprole (CAS 1229654-66-3), is described in WO 2010069502.
  • B-5 spidoxamat (CAS 907187- 07-9), is described in WO 2006089633.
  • B-6 and B-7 N-[[2-fluoro-4-[2-hydroxy-3-(3,4,5- trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl]methyl]cyclopropanecarboxamide (CAS 2044701-44-0 and 1365070-72-9), are described in WO 2012035011.
  • B-8 4-dimethyl-2-[2-(3- pyridyl)indazol-5-yl]-1 ,2,4-triazolidine-3,5-dione (CAS 2171099-09-3), is described in WO 2018011111.
  • B-9 N-[3-chloro-1-(3-pyridyl)pyrazol-4-yl]-2-methylsulfonyl-propanamide (CAS 2396747-83-2), is described in WO 2019236274.
  • B-10 (3R)-3-(2-chlorothiazol-5-yl)-8-methyl-6-phenyl-2,3- dihydrothiazolo[3,2-a]pyrimidin-8-ium-5,7-dione (CAS 2246757-58-2), B-11 , fenmezoditiaz (CAS 2413390-32-4), B-12, (3R)-3-(2-chlorothiazol-5-yl)-8-methyl-5-oxo-6-phenyl-2,3-dihydrothiazolo[3,2- a]pyrimidin-8-ium-7-olate (CAS 2413839-58-2) and B-13, 3-(2-chlorothiazol-5-yl)-8-methyl-5-oxo-6- pheny
  • B-14 tyclopyrazoflor (CAS 1477919-27-9), is described in WO 2013162715.
  • B-16 afidopyropen (CAS 915972-17-7), is described in WO 2006129714.
  • B-18 flupyradifurone (CAS 951659-40-8), is described in DE
  • B-23 1-(2-cyanoethyl)-4-oxo-3-[3-(trifluoromethyl)phenyl]pyrido[1 ,2- a]pyrimidin-1-ium-2-olate (CAS 2032403-97-5), is described in WO 2016171053.
  • B-24 N-isopropyl-2- (3-pyridyl)indazole-4-carboxamide (CAS 1680187-98-7), is described in WO 2015038503.
  • B-25 N- cyclopropyl-2-(3-pyridyl)indazole-4-carboxamide (CAS 1680188-04-8), is described in WO 2015038503.
  • B-26 N-cyclohexyl-2-(3-pyridyl)indazole-4-carboxamide (CAS 1680188-06-0), is described in WO 2015038503.
  • B-27 2-(3-pyridyl)-N-(2,2,2-trifluoroethyl)indazole-4-carboxamide (CAS 1680188-09-3), is described in WO 2015038503.
  • B-28 methyl N-[[2-(3-pyridyl)indazole-5- carbonyl]amino]carbamate (CAS 1680188-56-0), is described in WO 2015038503.
  • B-29 2-(3-pyridyl)- N-(tetrahydrofuran-2-ylmethyl)indazole-5-carboxamide (CAS 1680188-55-9), is described in WO 2015038503.
  • B-30 N-[(2,2-difluorocyclopropyl)methyl]-2-(3-pyridyl)indazole-5-carboxamide (CAS 1680188-65-1), is described in WO 2015038503.
  • B-31 N-(2,2-difluoropropyl)-2-(3-pyridyl)indazole-5- carboxamide (CAS 1680188-68-4), is described in WO 2015038503.
  • B-32 2-(3-pyridyl)-N-(pyrimidin- 2-ylmethyl)indazole-5-carboxamide (CAS 1680188-69-5 ), is described in WO 2015038503.
  • B-33 N- [(5-methylpyrazin-2-yl)methyl]-2-(3-pyridyl)indazole-5-carboxamide (CAS 1680188-91-3), is described in WO 2015038503.
  • B-34 indazapyroxamet (CAS 1689545-27-4, is described in WO 2015038503.
  • B- 35 N-[1-(difluoromethyl)cyclopropyl]-2-(3-pyridyl)indazole-4-carboxamide (CAS 2408908-90-5), is described in WO 2020018362.
  • B-36 N-(1 ,1-dimethyl-2-methylsulfanyl-ethyl)-7-fluoro-2-(3- pyridyl)indazole-4-carboxamide (CAS 2408908-91-6), is described in WO 2020018362.
  • B-37 N-(1 ,1- dimethyl-2-methylsulfinyl-ethyl)-7-fluoro-2-(3-pyridyl)indazole-4-carboxamide (CAS 2408908-92-7), is described in WO 2020018362.
  • B-38 1 ,1-dimethyl-2-methylsulfonyl-ethyl)-7-fluoro-2-(3- pyridyl)indazole-4-carboxamide (CAS 2408908-93-8 ), is described in WO 2020018362.
  • B-39, cyproflanilide (CAS 2375110-88-4), is described in WO 2020001067.
  • B-40 dicloromezotiaz (CAS 1263629-39-5), is described in WO 2011017342.
  • B-41 dinotefuran (CAS 165252-70-0), is described in EP 649845 (1995).
  • B-42 flupyrimin (CAS 1363400-41-2), is described in WO 2012029672.
  • B-43 guadipyr (CAS 1227849-60-6), is described in WO 2010060231.
  • B-44 flometoquin (CAS 875775-74- 9), is described in WO 2006013896.
  • B-48 cyetpyrafen (CAS 1253429-01-4), is described in WO 2010124617.
  • B-49 pyflubumide (CAS 926914-55-8), is described in WO
  • B-50 pyriminostrobin (CAS 1257598-43-8), is described in WO 2010139271.
  • B-51 acynonapyr (CAS 1333001-59-4), is described in WO 2011105506.
  • B-52 to B-54 2-[2-fluoro-4-methyl- 5-(2,2,2-trifluoroethylsulfinyl)phenyl]imino-3-(2,2,2-trifluoroethyl)thiazolidin-4-one (CAS 2377084-09-6, 1445684-82-1 and 1445683-71-5), are described in WO 2013092350.
  • B-55 oxazosulfyl (CAS 2377084-09-6, 1445684-82-1 and 1445683-71-5), are described in WO 2013092350.
  • B-55 oxazosulfyl (CAS 1257598-43-8), is described in WO 2010139271.
  • B-51 acynonapyr (CAS 13
  • B-56 2-(5-cyclopropyl-3-ethylsulfonyl-2-pyridyl)-5- (trifluoromethylsulfonyl)-l ,3-benzoxazole (CAS 2128706-05-6), is described in WO 2017146226.
  • B-57 2-[3-ethylsulfonyl-6-(1 ,2,4-triazol-1-yl)-2-pyridyl]-3-methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine (CAS 1808115-49-2), is described in WO 2015133603.
  • B-58 (3-ethylsulfonyl-2-pyridyl)-5-(2,2,3,3,3- pentafluoropropoxy)pyrazine (CAS 2095470-94-1), is described in WO 2017065228.
  • B-59 2-[3- ethylsulfonyl-6-(trifluoromethyl)pyrazolo[1 ,5-a]pyridin-2-yl]-3-methyl-6-(trifluoromethyl)imidazo[4,5- b]pyridine (CAS 2133042-31-4), is described in WO 2017155103.
  • B-60 2-[3-ethylsulfonyl-5-
  • B-71 cyantraniliprole (CAS 736994-63-1), is described in WO 2004067528.
  • B-72 pyridalyl (CAS 179101- 81-6), is described in WO 9611909.
  • B-73 indoxacarb (CAS 173584-44-6), is described in WO 9529171.
  • B-74 deltamethrin (CAS 52918-63-5), is described in DE 2439177 (1975).
  • B-76 bifenthrin (CAS 82657-04-3), is described in GB 2085005 (1982).
  • B-77 zeta-cypermethrin (CAS 1315501-18-8), is described in WO 2008005764.
  • B-78 gamma-cyhalothrin (CAS 76703-62-3, GB 2143823 (1985).
  • B-79 acrinathrin (CAS 101007-06- 1), is described in US 4542142 (1985).
  • B-80 permethrin (CAS 52645-53-1), is described in DE 2437882 (1975).
  • B-81 alpha-cypermethrin (CAS 67375-30-8), is described in DE 2850502 (1979).
  • B- 82, fenpropathrin (CAS 39515-41-8), is described in DE 2231312 (1973).
  • B- 86, lambda-cyhalothrin (CAS 91465-08-6), is described in EP 106469 (1984).
  • Haematopinus spp. Linognathus spp., Pediculus spp., Pemphigus spp. and Phylloxera spp.; from the order Coleoptera, for example,
  • Agriotes spp. Amphimallon majale, Anomala orientalis, Anthonomus spp., Aphodius spp, Astylus atromaculatus, Ataenius spp, Atomaria linearis, Chaetocnema tibialis, Cerotoma spp, Conoderus spp, Cosmopolites spp., Cotinis nitida, Curculio spp., Cyclocephala spp, Dermestes spp., Diabrotica spp., Diloboderus abderus, Epilachna spp., Eremnus spp., Heteronychus arator, Hypothenemus hampei, Lagria vilosa, Leptinotarsa decemlineata, Lissorhoptrus spp., Liogenys spp, Maecolaspis spp, Maladera castanea, Megas
  • Thyanta spp Triatoma spp., Vatiga illudens; Acyrthosium pisum, Adalges spp, Agalliana ensigera, Agonoscena targionii, Aleurodicus spp, Aleurocanthus spp, Aleurolobus barodensis, Aleurothrixus floccosus, Aleyrodes brassicae, Amarasca biguttula, Amritodus atkinsoni, Aonidiella spp., Aphididae, Aphis spp., Aspidiotus spp., Aulacorthum solani, Bactericera cockerelli, Bemisia spp, Brachycaudus spp, Brevicoryne brassicae, Cacopsylla spp, Cavariella aegopodii Scop., Ceroplaster spp., Chrysomphalus aoni
  • Coptotermes spp Corniternes cumulans, Incisitermes spp, Macrotermes spp, Mastotermes spp, Microtermes spp, Reticulitermes spp.; Solenopsis geminate; from the order Lepidoptera, for example,
  • Blatta spp. Blattella spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Neocurtilla hexadactyla, Periplaneta spp. , Scapteriscus spp, and Schistocerca spp.; from the order Psocoptera, for example,
  • Liposcelis spp. from the order Siphonaptera, for example,
  • Calliothrips phaseoli Frankliniella spp., Heliothrips spp, Hercinothrips spp., Parthenothrips spp, Scirtothrips aurantii, Sericothrips variabilis, Taeniothrips spp., Thrips spp; from the order Thysanura, for example, Lepisma saccharina.
  • the invention may also relate to a method of controlling damage to plant and parts thereof by plant parasitic nematodes (Endoparasitic-, Semiendoparasitic- and Ectoparasitic nematodes), especially plant parasitic nematodes such as root knot nematodes, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, Meloidogyne arenaria and other Meloidogyne species; cyst-forming nematodes, Globodera rostochiensis and other Globodera species; Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other Heterodera species; Seed gall nematodes, Anguina species; Stem and foliar nematodes, Aphelenchoides species; Sting nematodes, Belonolai
  • the combinations and compositions of the invention may also have activity against the molluscs.
  • Examples of which include, for example, Ampullariidae; Arion (A. ater, A. circumscriptus, A. hortensis, A. rufus); Bradybaenidae (Bradybaena fruticum); Cepaea (C. hortensis, C. Nemoralis); ochlodina; Deroceras (D. agrestis, D. empiricorum, D. laeve, D. reticulatum); Discus (D. rotundatus); Euomphalia; Galba (G. trunculata); Helicelia (H. itala, H.
  • H. aperta Limax (L. cinereoniger, L. flavus, L. marginatus, L. maximus, L. tenellus); Lymnaea; Milax (M. gagates, M. marginatus, M. sowerbyi); Opeas; Pomacea (P. canaticulata); Vallonia and Zanitoides.
  • the combinations and compositions according to the invention can be used for controlling, i. e. containing or destroying, pests of the abovementioned type which occur in particular on plants, especially on useful plants and ornamentals in agriculture, in horticulture and in forests, or on organs, such as fruits, flowers, foliage, stalks, tubers or roots, of such plants, and in some cases even plant organs which are formed at a later point in time remain protected against these pests.
  • Suitable target crops are, in particular, cereals, such as wheat, barley, rye, oats, rice, maize or sorghum; beet, such as sugar or fodder beet; fruit, for example pomaceous fruit, stone fruit or soft fruit, such as apples, pears, plums, peaches, almonds, cherries or berries, for example strawberries, raspberries or blackberries; leguminous crops, such as beans, lentils, peas or soya; oil crops, such as oilseed rape, mustard, poppies, olives, sunflowers, coconut, castor, cocoa or ground nuts; cucurbits, such as pumpkins, cucumbers or melons; fibre plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruit or tangerines; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes or bell peppers; Lauraceae, such as avocado, Cinnamonium or camphor; and also tobacco, nuts,
  • compositions of the present invention may be also used on any ornamental and/or vegetable crops, including flowers, shrubs, broad-leaved trees and evergreens.
  • the invention may be used on any of the following ornamental species: Ageratum spp., Alonsoa spp., Anemone spp., Anisodontea capsenisis, Anthemis spp., Antirrhinum spp., Aster spp., Begonia spp. (e.g. B. elatior, B. semperflorens, B. tubereux), Bougainvillea spp., Brachycome spp., Brassica spp.
  • Ageratum spp. Ageratum spp., Alonsoa spp., Anemone spp., Anisodontea capsenisis, Anthemis spp., Antirrhinum spp., Aster spp., Begonia spp. (e.g. B. elatior, B. semperflorens, B. tubereux), Bougainvillea spp., Brachycome spp.
  • Coreopsis spp. Crassula coccinea, Cuphea ignea, Dahlia spp., Delphinium spp., Dicentra spectabilis, Dorotheantus spp., Eustoma grandiflorum, Forsythia spp., Fuchsia spp., Geranium gnaphalium, Gerbera spp., Gomphrena globosa, Heliotropium spp., Helianthus spp., Hibiscus spp., Hortensia spp., Hydrangea spp., Hypoestes phyllostachya , Impatiens spp. (/.
  • Iresines spp. Kalanchoe spp., Lantana camara, Lavatera trimestris, Leonotis leonurus, Lilium spp., Mesembryanthemum spp., Mimulus spp., Monarda spp., Nemesia spp., Tagetes spp., Dianthus spp. (carnation), Canna spp., Oxalis spp., Beilis spp., Pelargonium spp. (P. peltatum, P. Zonaie), Viola spp.
  • the invention may be used on any of the following vegetable species: Allium spp. ⁇ A. sativum, A. cepa, A. oschaninii, A. Porrum, A. ascalonicum, A. fistulosum), Anthriscus cerefolium, Apium graveolus, Asparagus officinalis, Beta vulgarus, Brassica spp. (B. Oleracea, B. Pekinensis, B. rapa), Capsicum annuum, Cicer arietinum, Cichorium endivia, Cichorum spp. (C. intybus, C. endivia), Citrillus lanatus, Cucumis spp. (C. sativus, C.
  • Cucurbita spp. C. pepo, C. maxima
  • Cyanara spp. C. scolymus, C. carduncuius
  • Daucus carota Foeniculum vulgare, Hypericum spp., Lactuca sativa, Lycopersicon spp. (L esculentum, L lycopersicum), Mentha spp., Ocimum basilicum, Petroselinum crispum, Phaseolus spp. (P. vulgaris, P.
  • Preferred ornamental species include African violet, Begonia, Dahlia, Gerbera, Hydrangea, Verbena, Rosa, Kalanchoe, Poinsettia, Aster, Centaurea, Coreopsis, Delphinium, Monarda, Phlox, Rudbeckia, Sedum, Petunia, Viola, Impatiens, Geranium, Chrysanthemum, Ranunculus, Fuchsia, Salvia, Hortensia, rosemary, sage, St. Johnswort, mint, sweet pepper, tomato and cucumber.
  • compositions of the invention are particularly suitable for control of
  • a pest of the order Hemiptera for example, one or more of the species Bemisia tabaci , Aphis craccivora, Myzus persicae, Rhopalosiphum Padi, Nilaparvata lugens, and Euschistus heros (preferably in vegetables, soybeans, and sugarcane);
  • a pest of the order Lepidoptera for example, one or more of the species Spodoptera littoralis, Spodoptera frugiperda, Plutella xylostella, Cnaphalocrocis medinalis, Cydia pomonella, Chrysodeixis includes, Chilo suppressalis, Elasmopalpus lignosellus, Pseudoplusia includens, and Tuta absoluta (preferably in rice, vegetables and corn);
  • Thysanoptera such as the family Thripidae, for example, one or more of Thrips tabaci and Frankliniella occidentalis (preferably in vegetables);
  • soil pests such as of the order Coleoptera
  • soil pests such as of the order Coleoptera
  • the species Diabrotica balteata, Agriotes spp. and Leptinotarsa decemlineata preferably in vegetables and corn.
  • the term "crops" is to be understood as including also crop plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesising one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria, especially those of the genus Bacillus.
  • Toxins that can be expressed by such transgenic plants include, for example, insecticidal proteins, for example insecticidal proteins from Bacillus cereus or Bacillus popilliae; or insecticidal proteins from Bacillus thuringiensis, such as d-endotoxins, e.g. CrylAb, CrylAc, Cry1 F, Cry1 Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), e.g. Vip1 , Vip2, Vip3 or Vip3A; or insecticidal proteins of bacteria colonising nematodes, for example Photorhabdus spp.
  • insecticidal proteins for example insecticidal proteins from Bacillus cereus or Bacillus popilliae
  • Bacillus thuringiensis such as d-endotoxins, e.g. CrylAb, CrylAc, Cry1 F, Cry1 Fa2, Cry2
  • Xenorhabdus spp. such as Photorhabdus luminescens, Xenorhabdus nematophilus
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins and other insect-specific neurotoxins
  • toxins produced by fungi such as Streptomycetes toxins, plant lectins, such as pea lectins, barley lectins or snowdrop lectins
  • agglutinins proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, papain inhibitors
  • steroid metabolism enzymes such as 3-hydroxysteroidoxidase, ecdysteroid-UDP-glycosyl-transferase, cholesterol oxidases, ec
  • d-endotoxins for example CrylAb, CrylAc, Cry1 F, Cry1 Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, or vegetative insecticidal proteins (Vip), for example Vip1 , Vip2, Vip3 or Vip3A, expressly also hybrid toxins, truncated toxins and modified toxins.
  • Hybrid toxins are produced recombinantly by a new combination of different domains of those proteins (see, for example, WO 02/15701).
  • Truncated toxins for example a truncated CrylAb, are known.
  • modified toxins one or more amino acids of the naturally occurring toxin are replaced.
  • amino acid replacements preferably non-naturally present protease recognition sequences are inserted into the toxin, such as, for example, in the case of Cry3A055, a cathepsin-G- recognition sequence is inserted into a Cry3A toxin (see WO 03/018810).
  • Examples of such toxins ortransgenic plants capable of synthesising such toxins are disclosed, for example, in EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-451 878 and WO 03/052073.
  • Cryl-type deoxyribonucleic acids and their preparation are known, for example, from WO 95/34656, EP-A-0 367 474, EP-A-0 401 979 and WO 90/13651.
  • the toxin contained in the transgenic plants imparts to the plants tolerance to harmful insects.
  • insects can occur in any taxonomic group of insects, but are especially commonly found in the beetles (Coleoptera), two-winged insects (Diptera) and moths (Lepidoptera).
  • Transgenic plants containing one or more genes that code for an insecticidal resistance and express one or more toxins are known and some of them are commercially available.
  • YieldGard® (maize variety that expresses a CrylAb toxin); YieldGard Rootworm® (maize variety that expresses a Cry3Bb1 toxin); YieldGard Plus® (maize variety that expresses a CrylAb and a Cry3Bb1 toxin); Starlink® (maize variety that expresses a Cry9C toxin); Herculex I® (maize variety that expresses a Cry1 Fa2 toxin and the enzyme phosphinothricine N-acetyltransferase (PAT) to achieve tolerance to the herbicide glufosinate ammonium); NuCOTN 33B® (cotton variety that expresses a CrylAc toxin); Bollgard I® (cotton variety that expresses a CrylAc toxin); Bollgard II® (cotton variety that expresses a CrylAc and a Cry2Ab toxin
  • transgenic crops are:
  • MIR604 Maize from Syngenta Seeds SAS, Chemin de I'Hobit 27, F-31 790 St. Sauveur, France, registration number C/FR/96/05/10. Maize which has been rendered insect-resistant by transgenic expression of a modified Cry3A toxin. This toxin is Cry3A055 modified by insertion of a cathepsin-G- protease recognition sequence. The preparation of such transgenic maize plants is described in WO 03/018810.
  • MON 863 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/DE/02/9. MON 863 expresses a Cry3Bb1 toxin and has resistance to certain Coleoptera insects.
  • NK603 x MON 810 Maize from Monsanto Europe S.A. 270-272 Avenue de Tervuren, B-1150 Brussels, Belgium, registration number C/GB/02/M3/03. Consists of conventionally bred hybrid maize varieties by crossing the genetically modified varieties NK603 and MON 810.
  • NK603 c MON 810 Maize transgenically expresses the protein CP4 EPSPS, obtained from Agrobacterium sp. strain CP4, which imparts tolerance to the herbicide Roundup® (contains glyphosate), and also a CrylAb toxin obtained from Bacillus thuringiensis subsp. kurstaki which brings about tolerance to certain Lepidoptera, include the European corn borer.
  • crops is to be understood as including also crop plants which have been so transformed by the use of recombinant DNA techniques that they are capable of synthesising antipathogenic substances having a selective action, such as, for example, the so-called "pathogenesis- related proteins" (PRPs, see e.g. EP-A-0 392 225).
  • PRPs pathogenesis- related proteins
  • Examples of such antipathogenic substances and transgenic plants capable of synthesising such antipathogenic substances are known, for example, from EP-A-0 392 225, WO 95/33818 and EP-A-0 353 191 .
  • the methods of producing such transgenic plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.
  • Crops may also be modified for enhanced resistance to fungal (for example Fusarium, Anthracnose, or Phytophthora), bacterial (for example Pseudomonas) or viral (for example potato leafroll virus, tomato spotted wilt virus, cucumber mosaic virus) pathogens.
  • fungal for example Fusarium, Anthracnose, or Phytophthora
  • bacterial for example Pseudomonas
  • viral for example potato leafroll virus, tomato spotted wilt virus, cucumber mosaic virus
  • Crops also include those that have enhanced resistance to nematodes, such as the soybean cyst nematode.
  • Crops that are tolerance to abiotic stress include those that have enhanced tolerance to drought, high salt, high temperature, chill, frost, or light radiation, for example through expression of NF-YB or other proteins known in the art.
  • Antipathogenic substances which can be expressed by such transgenic plants include, for example, ion channel blockers, such as blockers for sodium and calcium channels, for example the viral KP1 , KP4 or KP6 toxins; stilbene synthases; bibenzyl synthases; chitinases; glucanases; the so-called "pathogenesis-related proteins" (PRPs; see e.g. EP-A-0392225); antipathogenic substances produced by microorganisms, for example peptide antibiotics or heterocyclic antibiotics (see e.g. WO 95/33818) or protein or polypeptide factors involved in plant pathogen defence (so-called "plant disease resistance genes", as described in WO 03/000906).
  • ion channel blockers such as blockers for sodium and calcium channels
  • the viral KP1 , KP4 or KP6 toxins for example the viral KP1 , KP4 or KP6 toxins
  • stilbene synthases such as the viral KP1
  • compositions according to the invention are the protection of stored goods and store rooms and the protection of raw materials, such as wood, textiles, floor coverings or buildings, and also in the hygiene sector, especially the protection of humans, domestic animals and productive livestock against pests of the mentioned type.
  • the present invention provides a method of improving the tolerance of a plant to abiotic stress, wherein the method comprises applying to the plant, plant part, plant propagation material, or plant growing locus a composition as described herein.
  • the present invention provides a method for regulating or improving the growth of a plant, wherein the method comprises applying to the plant, plant part, plant propagation material, or plant growing locus a composition as described herein.
  • plant growth is regulated or improved when the plant is subject to abiotic stress conditions.
  • regulating or improving the growth of a crop means an improvement in plant vigour, an improvement in plant quality, improved tolerance to stress factors, and/or improved input use efficiency.
  • plants refers to all physical parts of a plant, including seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage, and fruits.
  • locus means fields in or on which plants are growing, or where seeds of cultivated plants are sown, or where seed will be placed into the soil. It includes soil, seeds, and seedlings, as well as established vegetation.
  • plant propagation material denotes all generative parts of a plant, for example seeds or vegetative parts of plants such as cuttings and tubers. It includes seeds in the strict sense, as well as roots, fruits, tubers, bulbs, rhizomes, and parts of plants.
  • range of numbers is disclosed herein (for example, 1 to 10), this is intended to include all numbers and intervening values within that range (for example, 1 , 1 .1 , 2, 3, 3.9, 4, 5, 6, 6.5, 7, 8, 9 and 10) and also any sub-range of numbers and intervening values within that range (for example, 2 to 8, 1 .5 to 5.5 and 3.1 to 4.7). Additionally, it is intended that the both the upper and lower limits specified are included within the range.
  • composition can be in the form of concentrates which are diluted prior to use, although ready-to-use compositions can also be made.
  • the final dilution is usually made with water, but can be made instead of, or in addition to, water, with, for example, liquid fertilisers, micronutrients, biological organisms, oil or solvents.
  • compositions according to the invention are generally formulated in various ways using formulation adjuvants, such as carriers, solvents and surface-active substances.
  • the formulations can be in various physical forms, e.g. in the form of dusting powders, gels, wettable powders, water- dispersible granules, water-dispersible tablets, effervescent pellets, emulsifiable concentrates, micro- emulsifiable concentrates, oil-in-water emulsions, oil-flowables, aqueous dispersions, oily dispersions, suspo-emulsions, capsule suspensions, emulsifiable granules, soluble liquids, water-soluble concentrates (with water or a water-miscible organic solvent as carrier), impregnated polymer films or in other forms known e.g.
  • Such formulations can either be used directly or diluted prior to use.
  • the dilutions can be made, for example, with water, liquid fertilisers, micronutrients, biological organisms, oil or solvents.
  • the formulations can be prepared e.g. by mixing the active ingredient with the formulation adjuvants in order to obtain compositions in the form of finely divided solids, granules, solutions, dispersions or emulsions.
  • the active ingredients can also be formulated with other adjuvants, such as finely divided solids, mineral oils, oils of vegetable or animal origin, modified oils of vegetable or animal origin, organic solvents, water, surface-active substances or combinations thereof.
  • the active ingredients can also be contained in very fine microcapsules.
  • Microcapsules contain the active ingredients in a porous carrier. This enables the active ingredients to be released into the environment in controlled amounts (e.g. slow-release).
  • Microcapsules usually have a diameter of from 0.1 to 500 microns. They contain active ingredients in an amount of about from 25 to 95 % by weight of the capsule weight.
  • the active ingredients can be in the form of a monolithic solid, in the form of fine particles in solid or liquid dispersion or in the form of a suitable solution.
  • the encapsulating membranes can comprise, for example, natural or synthetic rubbers, cellulose, styrene/butadiene copolymers, polyacrylonitrile, polyacrylate, polyesters, polyamides, polyureas, polyurethane or chemically modified polymers and starch xanthates or other polymers that are known to the person skilled in the art.
  • very fine microcapsules can be formed in which the active ingredient is contained in the form of finely divided particles in a solid matrix of base substance, but the microcapsules are not themselves encapsulated.
  • liquid carriers there may be used: water, toluene, xylene, petroleum ether, vegetable oils, acetone, methyl ethyl ketone, cyclohexanone, acid anhydrides, acetonitrile, acetophenone, amyl acetate, 2-butanone, butylene carbonate, chlorobenzene, cyclohexane, cyclohexanol, alkyl esters of acetic acid, diacetone alcohol, 1 ,2-dichloropropane, diethanolamine, p-diethylbenzene, diethylene glycol, diethylene glycol abietate, diethylene glycol butyl ether, diethylene glycol ethyl ether, diethylene glycol methyl ether, N,N-dimethylformamide, dimethyl sulfoxide, 1 ,4-dioxane, diprop
  • Suitable solid carriers are, for example, talc, titanium dioxide, pyrophyllite clay, silica, attapulgite clay, kieselguhr, limestone, calcium carbonate, bentonite, calcium montmorillonite, cottonseed husks, wheat flour, soybean flour, pumice, wood flour, ground walnut shells, lignin and similar substances.
  • a large number of surface-active substances can advantageously be used in both solid and liquid formulations, especially in those formulations which can be diluted with a carrier prior to use.
  • Surface-active substances may be anionic, cationic, non-ionic or polymeric and they can be used as emulsifiers, wetting agents or suspending agents or for other purposes.
  • Typical surface-active substances include, for example, salts of alkyl sulfates, such as diethanolammonium lauryl sulfate salts of alkylarylsulfonates, such as calcium dodecyhbenzenesulfonate alkylphenol/alkylene oxide addition products, such as nonylphenol ethoxylate alcohol/alkylene oxide addition products, such as tridecylalcohol ethoxylate soaps, such as sodium stearate salts of alkylnaphthalenesulfonates, such as sodium dibutylnaphthalenesulfonate dialkyl esters of sulfosuccinate salts, such as sodium di(2-ethylhexyl)sulfosuccinate sorbitol esters, such as sorbitol oleate quaternary amines, such as lauryltrimethylammonium chloride, polyethylene glycol esters of fatty acids, such as polyethylene glycol
  • compositions according to the invention can include an additive comprising an oil of vegetable or animal origin, a mineral oil, alkyl esters of such oils or mixtures of such oils and oil derivatives.
  • the amount of oil additive in the composition according to the invention is generally from 0.01 to 10 %, based on the mixture to be applied.
  • the oil additive can be added to a spray tank in the desired concentration after a spray mixture has been prepared.
  • Preferred oil additives comprise mineral oils or an oil of vegetable origin, for example rapeseed oil, olive oil or sunflower oil, emulsified vegetable oil, alkyl esters of oils of vegetable origin, for example the methyl derivatives, or an oil of animal origin, such as fish oil or beef tallow.
  • Preferred oil additives comprise alkyl esters of C8 C22 fatty acids, especially the methyl derivatives of C12-C18 fatty acids, for example the methyl esters of lauric acid, palmitic acid and oleic acid (methyl laurate, methyl palmitate and methyl oleate, respectively).
  • Many oil derivatives are known from the Compendium of Herbicide Adjuvants, 10th Edition, Southern Illinois University, 2010.
  • inventive compositions generally comprise from 0.1 to 99 % by weight, especially from 0.1 to 95 % by weight, of active ingredients and from 1 to 99.9 % by weight of a formulation adjuvant which preferably includes from 0 to 25 % by weight of a surface-active substance.
  • a formulation adjuvant which preferably includes from 0 to 25 % by weight of a surface-active substance.
  • commercial products may preferably be formulated as concentrates, the end user will normally employ dilute formulations.
  • the rates of application vary within wide limits and depend on the nature of the soil, the method of application, the crop plant, the pest to be controlled, the prevailing climatic conditions, and other factors governed by the method of application, the time of application and the target crop.
  • active ingredients may be applied at a rate of from 1 to 2000 g/ha, especially from 10 to 1000 g/ha.
  • the rate of application of component (A) is from 20 to 200 g/ha. In some examples, the rate of application of component (A) is from 50 to 150 g/ha, optionally from 50 to 70 g/ha or about 100 g/ha.
  • the rate of application of component (B) is from 20 to 200 g/ha.
  • Preferred formulations can have the following compositions (weight %):
  • Emulsifiable concentrates active ingredient: 1 to 95 %, preferably 60 to 90 % surface-active agent: 1 to 30 %, preferably 5 to 20 % liquid carrier: 1 to 80 %, preferably 1 to 35 %
  • Dusts active ingredient: 0.1 to 10 %, preferably 0.1 to 5 % solid carrier: 99.9 to 90 %, preferably 99.9 to 99 %
  • Suspension concentrates active ingredient: 5 to 75 %, preferably 10 to 50 % water: 94 to 24 %, preferably 88 to 30 % surface-active agent: 1 to 40 %, preferably 2 to 30 %
  • Wettable powders active ingredient: 0.5 to 90 %, preferably 1 to 80 % surface-active agent: 0.5 to 20 %, preferably 1 to 15 % solid carrier: 5 to 95 %, preferably 15 to 90 %
  • Granules active ingredient: 0.1 to 30 %, preferably 0.1 to 15 % solid carrier: 99.5 to 70 %, preferably 97 to 85 %
  • the combination is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording wettable powders that can be diluted with water to give suspensions of the desired concentration.
  • the combination is thoroughly mixed with the adjuvants and the mixture is thoroughly ground in a suitable mill, affording powders that can be used directly for seed treatment.
  • Emulsions of any required dilution which can be used in plant protection, can be obtained from this concentrate by dilution with water.
  • Ready-for-use dusts are obtained by mixing the combination with the carrier and grinding the mixture in a suitable mill. Such powders can also be used for dry dressings for seed. The combination is mixed and ground with the adjuvants, and the mixture is moistened with water. The mixture is extruded and then dried in a stream of air.
  • the finely ground combination is uniformly applied, in a mixer, to the kaolin moistened with polyethylene glycol.
  • Non-dusty coated granules are obtained in this manner.
  • the finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion.
  • the finely ground combination is intimately mixed with the adjuvants, giving a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • a suspension concentrate from which suspensions of any desired dilution can be obtained by dilution with water.
  • living plants as well as plant propagation material can be treated and protected against infestation by microorganisms, by spraying, pouring or immersion.
  • 28 parts of the combination are mixed with 2 parts of an aromatic solvent and 7 parts of toluene diisocyanate/polymethylene-polyphenylisocyanate-mixture (8:1).
  • This mixture is emulsified in a mixture of 1 .2 parts of polyvinylalcohol, 0.05 parts of a defoamerand 51 .6 parts of water until the desired particle size is achieved.
  • a mixture of 2.8 parts 1 ,6-diaminohexane in 5.3 parts of water is added.
  • the mixture is agitated until the polymerization reaction is completed.
  • the obtained capsule suspension is stabilized by adding 0.25 parts of a thickener and 3 parts of a dispersing agent.
  • the capsule suspension formulation contains 28% of the active ingredients.
  • the medium capsule diameter is 8-15 microns.
  • the resulting formulation is applied to seeds as an aqueous suspension in an apparatus suitable for that purpose.
  • the combination or composition of the present invention may be applied to a plant, part of the plant, plant organ, plant propagation material or a plant growing locus.
  • the application is generally made by spraying (A) and (B) separately (i.e the combination) or (A) and (B) together (i.e the composition), typically by tractor mounted sprayer for large areas, but other methods such as dusting (for powders), drip or drench can also be used.
  • the combination or composition may be applied in furrow or directly to a seed before or at the time of planting.
  • the combination or composition of the present invention may be applied pre-emergence or post-emergence. Where the combination or composition is used to regulate the growth of crop plants or enhance the tolerance to abiotic stress, it may be applied post-emergence of the crop. Where the combination or composition is used to inhibit or delay the germination of seeds, it may be applied preemergence. Where the combination or composition is used to control pests, it may be applied as a preventative (before pest establishment) or curative (after pest establishment) treatment.
  • the present invention envisages application of the combinations and compositions of the invention to plant propagation material prior to, during, or after planting, or any combination of these.
  • seed in a sufficiently durable state to incur no damage during the treatment process.
  • seed would have been harvested from the field removed from the plant and separated from any cob, stalk, outer husk, and surrounding pulp or other non-seed plant material. Seed would preferably also be biologically stable to the extent that treatment would not cause biological damage to the seed. It is believed that treatment can be applied to seed at any time between seed harvest and sowing of seed including during the sowing process.
  • Methods for applying or treating active ingredients on to plant propagation material or to the locus of planting include dressing, coating, pelleting and soaking as well as nursery tray application, in furrow application, soil drenching, soil injection, drip irrigation, application through sprinklers or central pivot, or incorporation into soil (broad cast or in band).
  • active ingredients may be applied on a suitable substrate sown together with the plant propagation material.
  • the rates of application of combinations and compositions of the present invention may vary within wide limits and depend on the nature of the soil, the method of application (pre- or postemergence, seed dressing, application to the seed furrow, no tillage application etc.), the crop plant, the prevailing climatic conditions, and other factors governed by the method of application, the time of application and the target crop.
  • the combinations and compositions of the present invention are generally applied at a rate of from 1 to 2000 g/ha, especially from 5 to 1000 g/ha.
  • the rate of application is generally between 0.0005 and 150g per 100kg of seed.
  • compositions according to the invention can be used in combination with other pesticides, including other pesticides such as insecticides, acaricides, nematicides, fungicides, or agents that enhance the activity of the composition according to the invention, in for example chemical treatment or pest control programs.
  • pesticides including other pesticides such as insecticides, acaricides, nematicides, fungicides, or agents that enhance the activity of the composition according to the invention, in for example chemical treatment or pest control programs.
  • the combination may have further surprising advantages, which could be described as synergistic effects.
  • Suitable other pesticides are, for example, pestcides of the following classes of active ingredients: organophosphates, nitrophenol derivatives, thioureas, juvenile hormones, formamidines, benzophenone derivatives, ureas, pyrrole derivatives, carbamates, pyrethroids, chlorinated hydrocarbons, acylureas, pyridylmethyleneamino derivatives, macrolides, benzoylureas, neonicotinoids and biological agents such as Bacillus thurigiensis strains or bacterially-derived pesticides such as spinosads, avermectins and Cry proteins.
  • active ingredients organophosphates, nitrophenol derivatives, thioureas, juvenile hormones, formamidines, benzophenone derivatives, ureas, pyrrole derivatives, carbamates, pyrethroids, chlorinated hydrocarbons, acylureas, pyridylmethylene
  • compositions of the present invention may be applied to dicotyledonous or monocotyledonous crops.
  • Crops of useful plants in which the composition according to the invention can be used include perennial and annual crops, such as berry plants for example blackberries, blueberries, cranberries, raspberries and strawberries, cereals for example barley, maize (corn), millet, oats, rice, rye, sorghum triticale and wheat, fibre plants for example cotton, flax, hemp, jute and sisal, field crops for example sugar and fodder beet, coffee, hops, mustard, oilseed rape (canola), poppy, sugar cane, sunflower, tea and tobacco, fruit trees for example apple, apricot, avocado, banana, cherry, citrus, nectarine, peach, pear and plum, grasses for example Bermuda grass, bluegrass, bentgrass, centipede grass, fescue, ryegrass, St.
  • perennial and annual crops such as berry plants for example blackberries, blue
  • Augustine grass and Zoysia grass herbs such as basil, borage, chives, coriander, lavender, lovage, mint, oregano, parsley, rosemary, sage and thyme, legumes for example beans, lentils, peas and soya beans, nuts for example almond, cashew, ground nut, hazelnut, peanut, pecan, pistachio and walnut, palms for example oil palm, ornamentals for example flowers, shrubs and trees, other trees, for example cacao, coconut, olive and rubber, vegetables for example asparagus, aubergine, broccoli, cabbage, carrot, cucumber, garlic, lettuce, marrow, melon, okra, onion, pepper, potato, pumpkin, rhubarb, spinach and tomato, and vines for example grapes.
  • herbs such as basil, borage, chives, coriander, lavender, lovage, mint, oregano, parsley, rosemary, sage and thyme, legumes for example beans, lentils, peas and soya beans,
  • Crops are to be understood as being those which are naturally occurring, obtained by conventional methods of breeding, or obtained by genetic engineering. They include crops which contain so-called output traits (e.g. improved storage stability, higher nutritional value and improved flavour).
  • output traits e.g. improved storage stability, higher nutritional value and improved flavour.
  • Crops are to be understood as also including those crops which have been rendered tolerant to herbicides like bromoxynil or classes of herbicides such as ALS-, EPSPS-, GS-, HPPD- and PPO- inhibitors.
  • herbicides like bromoxynil or classes of herbicides such as ALS-, EPSPS-, GS-, HPPD- and PPO- inhibitors.
  • An example of a crop that has been rendered tolerant to imidazolinones, e.g. imazamox, by conventional methods of breeding is Clearfield® summer canola.
  • crops that have been rendered tolerant to herbicides by genetic engineering methods include e.g. glyphosate- and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady®, Herculex I® and LibertyLink®.
  • Crops are also to be understood as being those which naturally are or have been rendered resistant to harmful insects. This includes plants transformed by the use of recombinant DNA techniques, for example, to be capable of synthesising one or more selectively acting toxins, such as are known, for example, from toxin-producing bacteria. Examples of toxins which can be expressed include d-endotoxins, vegetative insecticidal proteins (Vip), insecticidal proteins of bacteria colonising nematodes, and toxins produced by scorpions, arachnids, wasps and fungi.
  • Vip vegetative insecticidal proteins
  • insecticidal proteins of bacteria colonising nematodes and toxins produced by scorpions, arachnids, wasps and fungi.
  • An example of a crop that has been modified to express the Bacillus thuringiensis toxin is the Bt maize KnockOut (Syngenta Seeds).
  • An example of a crop comprising more than one gene that codes for insecticidal resistance and thus expresses more than one toxin is VipCot® (Syngenta Seeds).
  • Crops or seed material thereof can also be resistant to multiple types of pests (so-called stacked transgenic events when created by genetic modification).
  • a plant can have the ability to express an insecticidal protein while at the same time being herbicide tolerant, for example Herculex I® (Dow AgroSciences, Pioneer Hi-Bred International).
  • the present invention also provides the use of the combination or composition as defined above for controlling insect and/or acarina and/or nematode pests.
  • X % action by first active ingredient using p ppm of the active ingredient
  • Y % action by second active ingredient using q ppm of the active ingredient.
  • synergism corresponds to a positive value forthe difference of (O-E).
  • said difference (O-E) is zero.
  • a negative value of said difference (O-E) signals a loss of activity compared to the expected activity.
  • Table 2 sets out certain preferred combinations.
  • Table 1 lists example application rates, stating the application rate for component (A), the compound of formula (I), and each specified compound forming component (B). Application rates are given as grams per hectare. Table 1 also lists key pests against which the combinations are particularly effective and key crops for which the inventive combinations are particularly advantageous.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne un procédé de lutte contre les dommages ou de prévention des dommages pour une plante, qui comprend l'application sur la plante, son locus ou son matériau de propagation, d'une combinaison comprenant, en tant que composant (A), un composé de formule (I) : dans laquelle : R1 représente un alkylène en C1-C3 ou halo alkylène en C1-C3 ; R2 représente un alkyle en C1-C6 ou C1-C6alcoxy-C1-C6alkyle ; R3 représente H ou CN ; et n vaut 0, 1 ou 2 ; ou un sel agrochimiquement acceptable de celui-ci ; et, en tant que composant (B), un composé choisi dans un groupe constitué de partenaires de mélange ; et des compositions, des formulations et des concentrés comprenant de telles combinaisons.
PCT/EP2022/057514 2021-03-25 2022-03-22 Lutte contre les insectes, les acariens et les nématodes Ceased WO2022200364A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21165074 2021-03-25
EP21165074.2 2021-03-25

Publications (1)

Publication Number Publication Date
WO2022200364A1 true WO2022200364A1 (fr) 2022-09-29

Family

ID=75252328

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2022/057514 Ceased WO2022200364A1 (fr) 2021-03-25 2022-03-22 Lutte contre les insectes, les acariens et les nématodes

Country Status (1)

Country Link
WO (1) WO2022200364A1 (fr)

Citations (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2231312A1 (de) 1971-06-29 1973-01-11 Sumitomo Chemical Co Cyclopropancarbonsaeure-alpha-cyanbenzylester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
DE2326077A1 (de) 1972-05-25 1974-01-03 Nat Res Dev Insektizide auf der grundlage von pyrethrinderivaten
DE2335347A1 (de) 1972-07-11 1974-02-14 Sumitomo Chemical Co Substituierte acetatverbindungen, verfahren zu ihrer herstellung und ihre verwendung als pestizide
DE2439177A1 (de) 1973-08-15 1975-02-27 Nat Res Dev Insektizide auf der grundlage von pyrethrinderivaten
DE2437882A1 (de) 1973-08-06 1975-04-24 Sumitomo Chemical Co Verfahren zur herstellung von estern des 3-phenoxybenzylalkohols
DE2737297A1 (de) 1976-08-18 1978-02-23 Sumitomo Chemical Co Insektizide mittel und verwendung von optisch aktiven 2-(4-chlorphenyl)- isovaleriansaeure-alpha-cyan-3-phenoxybenzylestern als insektizide
DE2709264A1 (de) 1977-03-03 1978-09-07 Bayer Ag Substituierte phenoxybenzyloxycarbonylderivate, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
DE2850502A1 (de) 1977-11-24 1979-05-31 Ciba Geigy Ag 2,4,4,4-tetrachlorbuttersaeure-1,2,4, 4,4-pentachlor-but-1-enylester
GB2085005A (en) 1980-10-08 1982-04-21 Fmc Corp Control of Acarids with Biphenylmethyl Perhaloalkylvinylcyclopropanecarboxylates
EP0106469A1 (fr) 1982-10-11 1984-04-25 Imperial Chemical Industries Plc Produit insecticide et sa préparation
GB2143823A (en) 1983-07-22 1985-02-20 Ici Australia Ltd Process for the preparation of -substituted -cyanomethyl alcohol enantiomers
US4542142A (en) 1982-11-22 1985-09-17 Roussel Uclaf Insecticidal cyclopropane carboxylic acid derivatives with 3-unsaturated-side chain
EP0192060A1 (fr) 1985-02-04 1986-08-27 Nihon Bayer Agrochem K.K. Composés hétérocycliques
EP0235725A2 (fr) 1986-03-07 1987-09-09 Nihon Bayer Agrochem K.K. Composés hétérocycliques
BR8803788A (pt) 1987-07-29 1989-02-21 American Cyanamid Co Composto pesticida,processo para controlar insetos,processo para proteger plantas em crescimento de ataque de insetos,nematodios e acaros e processo para preparar um novo composto de aril-pirrol
EP0353191A2 (fr) 1988-07-29 1990-01-31 Ciba-Geigy Ag Séquences d'ADN codant des polypeptides avec activité béta-1,3-glucanase
EP0367474A1 (fr) 1988-11-01 1990-05-09 Mycogen Corporation Souche de bacillus thuringiensis appelée b.t. ps81gg, active contre les lépidoptères nuisibles et gène codant une toxine active contre les lépidoptères.
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
EP0392560A2 (fr) 1989-04-14 1990-10-17 Takeda Chemical Industries, Ltd. Composés diaminoéthylènes
WO1990013651A1 (fr) 1989-05-09 1990-11-15 Imperial Chemical Industries Plc Genes bacteriens
EP0401979A2 (fr) 1989-05-18 1990-12-12 Mycogen Corporation Souches de bacillus thuringiensis actives contre les lépidoptères nuisibles, et gènes codant pour des toxines actives contre les lépidoptères
WO1991004965A1 (fr) 1989-10-06 1991-04-18 Nippon Soda Co., Ltd. Derives d'amine
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
EP0580553A2 (fr) 1992-07-22 1994-01-26 Ciba-Geigy Ag Dérivés d'oxadiazine
EP0649845A1 (fr) 1993-10-26 1995-04-26 MITSUI TOATSU CHEMICALS, Inc. Insecticide furanyl
WO1995029171A1 (fr) 1994-04-20 1995-11-02 E.I. Du Pont De Nemours And Company Preparation d'oxadiazines arthropodicides
WO1995033818A2 (fr) 1994-06-08 1995-12-14 Ciba-Geigy Ag Genes pour la synthese des substances antipathogenes
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
WO1996011909A1 (fr) 1994-10-14 1996-04-25 Sumitomo Chemical Company, Limited Composes a base de dihalopropene, agents insecticides/acaricides les contenant et intermediaires servant a les produire
WO1998027074A1 (fr) 1996-12-19 1998-06-25 Novartis Ag Procede destine a la preparation de derives thiazoliques
EP1006107A2 (fr) 1998-11-30 2000-06-07 Nihon Nohyaku Co., Ltd. Dérivés de phtalamide ou leur sels, insecticides pour l'agriculture et l'horticulture et procédé pour leur mise en oeuvre
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003000906A2 (fr) 2001-06-22 2003-01-03 Syngenta Participations Ag Genes de resistance aux maladies chez les plantes
WO2003015518A1 (fr) 2001-08-13 2003-02-27 E.I. Du Pont De Nemours And Company Procede permettant de lutter contre des insectes nuisibles particuliers par application de composes d'anthranilamide
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2004067528A1 (fr) 2003-01-28 2004-08-12 E.I. Du Pont De Nemours And Company Insecticides a base de cyano-anthranilamide
WO2006013896A1 (fr) 2004-08-04 2006-02-09 Meiji Seika Kaisha, Ltd. Dérivé de quinoline et insecticide contenant celui-ci comme constituant actif
WO2006089633A2 (fr) 2005-02-22 2006-08-31 Bayer Cropscience Ag Cetoenols cycliques substitues par spirocetal
WO2006114400A1 (fr) 2005-04-26 2006-11-02 Neurosearch A/S Nouveaux derives d'oxadiazole et usage medical de ceux-ci
WO2006129714A1 (fr) 2005-06-01 2006-12-07 Meiji Seika Kaisha, Ltd. Agent antiparasitaire
WO2007020986A1 (fr) 2005-08-12 2007-02-22 Nihon Nohyaku Co., Ltd. Dérivé anilide d'acide pyrazolecarboxylique substitué ou son sel, son intermédiaire, agent pour utilisation horticole et agricole, et son utilisation
WO2007026965A1 (fr) 2005-09-02 2007-03-08 Nissan Chemical Industries, Ltd. Composé de benzamide à substitution isoxazoline et agent de lutte contre les organismes nuisibles
WO2007095229A2 (fr) 2006-02-10 2007-08-23 Dow Agrosciences Llc (6-haloalkylpyridin-3-yl)alkyl sulfoximines n-substituees insecticides
DE102006015467A1 (de) 2006-03-31 2007-10-04 Bayer Cropscience Ag Substituierte Enaminocarbonylverbindungen
WO2008005764A2 (fr) 2006-06-30 2008-01-10 Fmc Corporation Nouvelle composition de dzéta-cyperméthrine
WO2009005110A2 (fr) 2007-06-29 2009-01-08 Sumitomo Chemical Company, Limited Composé organosulfurique contenant halogène et son utilisation
WO2010003350A1 (fr) 2008-07-07 2010-01-14 中国中化集团公司 Composés pyridyl-pyrazolylamides 1-substitués et leurs utilisations
WO2010018714A1 (fr) 2008-08-13 2010-02-18 三井化学アグロ株式会社 Dérivé amide, agent antiparasitaire contenant le dérivé amide et utilisation de l’agent antiparasitaire
WO2010060231A1 (fr) 2008-11-25 2010-06-03 Qin Zhaohai Aminonitroguanidines condensées, leur synthèse et leur emploi en tant qu'insecticides botaniques
WO2010069502A2 (fr) 2008-12-18 2010-06-24 Bayer Cropscience Ag Amides d'acide anthranilique substitués par tétrazol, utilisés comme pesticides
WO2010124617A1 (fr) 2009-04-29 2010-11-04 中国中化股份有限公司 Composés de pyrazolylacrylonitrile et leurs utilisations
WO2010129500A2 (fr) 2009-05-04 2010-11-11 E. I. Du Pont De Nemours And Company Sulfonamides nématocides
WO2010139271A1 (fr) 2009-06-05 2010-12-09 中国中化股份有限公司 Composés ester phénylacrylique de type e contenant un groupe anilinopyrimidine substitué et leurs utilisations
WO2011017342A2 (fr) 2009-08-05 2011-02-10 E. I. Du Pont De Nemours And Company Pesticides mésoioniques
WO2011017351A2 (fr) 2009-08-05 2011-02-10 E. I. Du Pont De Nemours And Company Mélanges de pesticides méso-ioniques
WO2011105506A1 (fr) 2010-02-25 2011-09-01 日本曹達株式会社 Composé amine cyclique et acaricide
WO2012029672A1 (fr) 2010-08-31 2012-03-08 Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 Agent de lutte contre des organismes nuisibles
WO2012035011A1 (fr) 2010-09-15 2012-03-22 Bayer Cropscience Ag Arylpyrrolidines pesticides
WO2012034472A1 (fr) 2010-09-13 2012-03-22 中化蓝天集团有限公司 Composés cyanobenzènedicarboxamides, leurs procédés de préparation et leurs utilisations comme insecticides agricoles
WO2012143317A1 (fr) 2011-04-21 2012-10-26 Basf Se Nouveaux composés pesticides à base de pyrazole
WO2013092350A1 (fr) 2011-12-21 2013-06-27 Bayer Cropscience Ag Dérivés de sulfure de trifluoréthyle n-substitué d'arylamidine en tant qu'acaricide et insecticide
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
WO2013157229A1 (fr) 2012-04-20 2013-10-24 クミアイ化学工業株式会社 Dérivé de sulfure d'alkylphényle et agent de lutte contre les organismes nuisibles
WO2013162715A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
WO2014104407A1 (fr) 2012-12-27 2014-07-03 Sumitomo Chemical Company, Limited Composés d'oxazole fusionnés et leur utilisation dans la lutte contre les organismes nuisibles
WO2015038503A1 (fr) 2013-09-13 2015-03-19 E. I. Du Pont De Nemours And Company Pesticides à base d'azole bicyclique substitué par un hétérocycle
WO2015067647A1 (fr) 2013-11-05 2015-05-14 Bayer Cropscience Ag Benzamides substitués pour lutter contre des arthropodes
WO2015133603A1 (fr) 2014-03-07 2015-09-11 住友化学株式会社 Composé hétérocyclique condensé et son utilisation pour lutter contre les ravageurs
EP2952097A1 (fr) 2013-01-31 2015-12-09 Sumitomo Chemical Company, Limited Composition et procédé permettant de lutter contre les animaux nuisibles
WO2016171053A1 (fr) 2015-04-21 2016-10-27 日本化薬株式会社 Composé mésoionique
WO2017065228A1 (fr) 2015-10-16 2017-04-20 住友化学株式会社 Composé pyrazine et agent de lutte contre les arthropodes nuisibles contenant celui-ci
WO2017146226A1 (fr) 2016-02-26 2017-08-31 日本農薬株式会社 Composé de benzoxazole ou sel de celui-ci, insecticide agricole/horticole le contenant, et son procédé d'utilisation
WO2017155103A1 (fr) 2016-03-10 2017-09-14 日産化学工業株式会社 Composé hétérocyclique condensé et agent de lutte antiparasitaire
WO2018011111A1 (fr) 2016-07-12 2018-01-18 Bayer Cropscience Aktiengesellschaft Composés bicycliques utilisés comme pesticides
WO2018177970A1 (fr) 2017-03-31 2018-10-04 Basf Se Procédé de préparation de composés chiraux 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium
WO2019059244A1 (fr) 2017-09-21 2019-03-28 日本農薬株式会社 Composé de benzimidazole ayant un groupe cyclopropylpyridyle ou sel de celui-ci, pesticide agricole et horticole contenant ledit composé, et procédé d'utilisation dudit pesticide
WO2019236274A1 (fr) 2018-06-08 2019-12-12 Dow Agrosciences Llc Molécules à utilité pesticide, compositions et procédés associés
WO2020001067A1 (fr) 2018-06-26 2020-01-02 上海泰禾国际贸易有限公司 Composé m-diamide, son procédé de préparation et son utilisation
WO2020013147A1 (fr) 2018-07-10 2020-01-16 日本農薬株式会社 Composé de benzimidazole ayant un groupe alkylènedioxy qui peut être halogéné ou un sel de celui-ci, pesticide agricole et horticole contenant ledit composé, et procédé d'utilisation associé
WO2020018362A1 (fr) 2018-07-14 2020-01-23 Fmc Corporation Mélanges pesticides comprenant des indazoles

Patent Citations (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2231312A1 (de) 1971-06-29 1973-01-11 Sumitomo Chemical Co Cyclopropancarbonsaeure-alpha-cyanbenzylester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
DE2326077A1 (de) 1972-05-25 1974-01-03 Nat Res Dev Insektizide auf der grundlage von pyrethrinderivaten
DE2335347A1 (de) 1972-07-11 1974-02-14 Sumitomo Chemical Co Substituierte acetatverbindungen, verfahren zu ihrer herstellung und ihre verwendung als pestizide
DE2437882A1 (de) 1973-08-06 1975-04-24 Sumitomo Chemical Co Verfahren zur herstellung von estern des 3-phenoxybenzylalkohols
DE2439177A1 (de) 1973-08-15 1975-02-27 Nat Res Dev Insektizide auf der grundlage von pyrethrinderivaten
DE2737297A1 (de) 1976-08-18 1978-02-23 Sumitomo Chemical Co Insektizide mittel und verwendung von optisch aktiven 2-(4-chlorphenyl)- isovaleriansaeure-alpha-cyan-3-phenoxybenzylestern als insektizide
DE2709264A1 (de) 1977-03-03 1978-09-07 Bayer Ag Substituierte phenoxybenzyloxycarbonylderivate, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
DE2850502A1 (de) 1977-11-24 1979-05-31 Ciba Geigy Ag 2,4,4,4-tetrachlorbuttersaeure-1,2,4, 4,4-pentachlor-but-1-enylester
GB2085005A (en) 1980-10-08 1982-04-21 Fmc Corp Control of Acarids with Biphenylmethyl Perhaloalkylvinylcyclopropanecarboxylates
EP0106469A1 (fr) 1982-10-11 1984-04-25 Imperial Chemical Industries Plc Produit insecticide et sa préparation
US4542142A (en) 1982-11-22 1985-09-17 Roussel Uclaf Insecticidal cyclopropane carboxylic acid derivatives with 3-unsaturated-side chain
GB2143823A (en) 1983-07-22 1985-02-20 Ici Australia Ltd Process for the preparation of -substituted -cyanomethyl alcohol enantiomers
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
EP0192060A1 (fr) 1985-02-04 1986-08-27 Nihon Bayer Agrochem K.K. Composés hétérocycliques
EP0235725A2 (fr) 1986-03-07 1987-09-09 Nihon Bayer Agrochem K.K. Composés hétérocycliques
BR8803788A (pt) 1987-07-29 1989-02-21 American Cyanamid Co Composto pesticida,processo para controlar insetos,processo para proteger plantas em crescimento de ataque de insetos,nematodios e acaros e processo para preparar um novo composto de aril-pirrol
EP0353191A2 (fr) 1988-07-29 1990-01-31 Ciba-Geigy Ag Séquences d'ADN codant des polypeptides avec activité béta-1,3-glucanase
EP0367474A1 (fr) 1988-11-01 1990-05-09 Mycogen Corporation Souche de bacillus thuringiensis appelée b.t. ps81gg, active contre les lépidoptères nuisibles et gène codant une toxine active contre les lépidoptères.
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
EP0392560A2 (fr) 1989-04-14 1990-10-17 Takeda Chemical Industries, Ltd. Composés diaminoéthylènes
WO1990013651A1 (fr) 1989-05-09 1990-11-15 Imperial Chemical Industries Plc Genes bacteriens
EP0401979A2 (fr) 1989-05-18 1990-12-12 Mycogen Corporation Souches de bacillus thuringiensis actives contre les lépidoptères nuisibles, et gènes codant pour des toxines actives contre les lépidoptères
WO1991004965A1 (fr) 1989-10-06 1991-04-18 Nippon Soda Co., Ltd. Derives d'amine
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
EP0580553A2 (fr) 1992-07-22 1994-01-26 Ciba-Geigy Ag Dérivés d'oxadiazine
EP0649845A1 (fr) 1993-10-26 1995-04-26 MITSUI TOATSU CHEMICALS, Inc. Insecticide furanyl
WO1995029171A1 (fr) 1994-04-20 1995-11-02 E.I. Du Pont De Nemours And Company Preparation d'oxadiazines arthropodicides
WO1995033818A2 (fr) 1994-06-08 1995-12-14 Ciba-Geigy Ag Genes pour la synthese des substances antipathogenes
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
WO1996011909A1 (fr) 1994-10-14 1996-04-25 Sumitomo Chemical Company, Limited Composes a base de dihalopropene, agents insecticides/acaricides les contenant et intermediaires servant a les produire
WO1998027074A1 (fr) 1996-12-19 1998-06-25 Novartis Ag Procede destine a la preparation de derives thiazoliques
EP1006107A2 (fr) 1998-11-30 2000-06-07 Nihon Nohyaku Co., Ltd. Dérivés de phtalamide ou leur sels, insecticides pour l'agriculture et l'horticulture et procédé pour leur mise en oeuvre
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003000906A2 (fr) 2001-06-22 2003-01-03 Syngenta Participations Ag Genes de resistance aux maladies chez les plantes
WO2003015518A1 (fr) 2001-08-13 2003-02-27 E.I. Du Pont De Nemours And Company Procede permettant de lutter contre des insectes nuisibles particuliers par application de composes d'anthranilamide
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2004067528A1 (fr) 2003-01-28 2004-08-12 E.I. Du Pont De Nemours And Company Insecticides a base de cyano-anthranilamide
WO2006013896A1 (fr) 2004-08-04 2006-02-09 Meiji Seika Kaisha, Ltd. Dérivé de quinoline et insecticide contenant celui-ci comme constituant actif
WO2006089633A2 (fr) 2005-02-22 2006-08-31 Bayer Cropscience Ag Cetoenols cycliques substitues par spirocetal
WO2006114400A1 (fr) 2005-04-26 2006-11-02 Neurosearch A/S Nouveaux derives d'oxadiazole et usage medical de ceux-ci
WO2006129714A1 (fr) 2005-06-01 2006-12-07 Meiji Seika Kaisha, Ltd. Agent antiparasitaire
WO2007020986A1 (fr) 2005-08-12 2007-02-22 Nihon Nohyaku Co., Ltd. Dérivé anilide d'acide pyrazolecarboxylique substitué ou son sel, son intermédiaire, agent pour utilisation horticole et agricole, et son utilisation
WO2007026965A1 (fr) 2005-09-02 2007-03-08 Nissan Chemical Industries, Ltd. Composé de benzamide à substitution isoxazoline et agent de lutte contre les organismes nuisibles
WO2007095229A2 (fr) 2006-02-10 2007-08-23 Dow Agrosciences Llc (6-haloalkylpyridin-3-yl)alkyl sulfoximines n-substituees insecticides
DE102006015467A1 (de) 2006-03-31 2007-10-04 Bayer Cropscience Ag Substituierte Enaminocarbonylverbindungen
WO2008005764A2 (fr) 2006-06-30 2008-01-10 Fmc Corporation Nouvelle composition de dzéta-cyperméthrine
WO2009005110A2 (fr) 2007-06-29 2009-01-08 Sumitomo Chemical Company, Limited Composé organosulfurique contenant halogène et son utilisation
WO2010003350A1 (fr) 2008-07-07 2010-01-14 中国中化集团公司 Composés pyridyl-pyrazolylamides 1-substitués et leurs utilisations
WO2010018714A1 (fr) 2008-08-13 2010-02-18 三井化学アグロ株式会社 Dérivé amide, agent antiparasitaire contenant le dérivé amide et utilisation de l’agent antiparasitaire
WO2010060231A1 (fr) 2008-11-25 2010-06-03 Qin Zhaohai Aminonitroguanidines condensées, leur synthèse et leur emploi en tant qu'insecticides botaniques
WO2010069502A2 (fr) 2008-12-18 2010-06-24 Bayer Cropscience Ag Amides d'acide anthranilique substitués par tétrazol, utilisés comme pesticides
WO2010124617A1 (fr) 2009-04-29 2010-11-04 中国中化股份有限公司 Composés de pyrazolylacrylonitrile et leurs utilisations
WO2010129500A2 (fr) 2009-05-04 2010-11-11 E. I. Du Pont De Nemours And Company Sulfonamides nématocides
WO2010139271A1 (fr) 2009-06-05 2010-12-09 中国中化股份有限公司 Composés ester phénylacrylique de type e contenant un groupe anilinopyrimidine substitué et leurs utilisations
WO2011017342A2 (fr) 2009-08-05 2011-02-10 E. I. Du Pont De Nemours And Company Pesticides mésoioniques
WO2011017351A2 (fr) 2009-08-05 2011-02-10 E. I. Du Pont De Nemours And Company Mélanges de pesticides méso-ioniques
WO2011105506A1 (fr) 2010-02-25 2011-09-01 日本曹達株式会社 Composé amine cyclique et acaricide
WO2012029672A1 (fr) 2010-08-31 2012-03-08 Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 Agent de lutte contre des organismes nuisibles
WO2012034472A1 (fr) 2010-09-13 2012-03-22 中化蓝天集团有限公司 Composés cyanobenzènedicarboxamides, leurs procédés de préparation et leurs utilisations comme insecticides agricoles
WO2012035011A1 (fr) 2010-09-15 2012-03-22 Bayer Cropscience Ag Arylpyrrolidines pesticides
WO2012143317A1 (fr) 2011-04-21 2012-10-26 Basf Se Nouveaux composés pesticides à base de pyrazole
WO2013092350A1 (fr) 2011-12-21 2013-06-27 Bayer Cropscience Ag Dérivés de sulfure de trifluoréthyle n-substitué d'arylamidine en tant qu'acaricide et insecticide
WO2013115391A1 (fr) 2012-02-01 2013-08-08 日本農薬株式会社 Dérivé d'arylalkyloxy pyrimidine, pesticide à usage agricole et horticole contenant le dérivé d'arylalkyloxy pyrimidine comme ingrédient actif, et son utilisation
WO2013157229A1 (fr) 2012-04-20 2013-10-24 クミアイ化学工業株式会社 Dérivé de sulfure d'alkylphényle et agent de lutte contre les organismes nuisibles
WO2013162715A2 (fr) 2012-04-27 2013-10-31 Dow Agrosciences Llc Compositions pesticides et procédés correspondants
WO2014104407A1 (fr) 2012-12-27 2014-07-03 Sumitomo Chemical Company, Limited Composés d'oxazole fusionnés et leur utilisation dans la lutte contre les organismes nuisibles
EP2952097A1 (fr) 2013-01-31 2015-12-09 Sumitomo Chemical Company, Limited Composition et procédé permettant de lutter contre les animaux nuisibles
WO2015038503A1 (fr) 2013-09-13 2015-03-19 E. I. Du Pont De Nemours And Company Pesticides à base d'azole bicyclique substitué par un hétérocycle
WO2015067647A1 (fr) 2013-11-05 2015-05-14 Bayer Cropscience Ag Benzamides substitués pour lutter contre des arthropodes
WO2015133603A1 (fr) 2014-03-07 2015-09-11 住友化学株式会社 Composé hétérocyclique condensé et son utilisation pour lutter contre les ravageurs
WO2016171053A1 (fr) 2015-04-21 2016-10-27 日本化薬株式会社 Composé mésoionique
WO2017065228A1 (fr) 2015-10-16 2017-04-20 住友化学株式会社 Composé pyrazine et agent de lutte contre les arthropodes nuisibles contenant celui-ci
WO2017146226A1 (fr) 2016-02-26 2017-08-31 日本農薬株式会社 Composé de benzoxazole ou sel de celui-ci, insecticide agricole/horticole le contenant, et son procédé d'utilisation
WO2017155103A1 (fr) 2016-03-10 2017-09-14 日産化学工業株式会社 Composé hétérocyclique condensé et agent de lutte antiparasitaire
WO2018011111A1 (fr) 2016-07-12 2018-01-18 Bayer Cropscience Aktiengesellschaft Composés bicycliques utilisés comme pesticides
WO2018177970A1 (fr) 2017-03-31 2018-10-04 Basf Se Procédé de préparation de composés chiraux 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium
WO2019059244A1 (fr) 2017-09-21 2019-03-28 日本農薬株式会社 Composé de benzimidazole ayant un groupe cyclopropylpyridyle ou sel de celui-ci, pesticide agricole et horticole contenant ledit composé, et procédé d'utilisation dudit pesticide
WO2019236274A1 (fr) 2018-06-08 2019-12-12 Dow Agrosciences Llc Molécules à utilité pesticide, compositions et procédés associés
WO2020001067A1 (fr) 2018-06-26 2020-01-02 上海泰禾国际贸易有限公司 Composé m-diamide, son procédé de préparation et son utilisation
WO2020013147A1 (fr) 2018-07-10 2020-01-16 日本農薬株式会社 Composé de benzimidazole ayant un groupe alkylènedioxy qui peut être halogéné ou un sel de celui-ci, pesticide agricole et horticole contenant ledit composé, et procédé d'utilisation associé
EP3835301A1 (fr) * 2018-07-10 2021-06-16 Nihon Nohyaku Co., Ltd. Composé de benzimidazole ayant un groupe alkylènedioxy qui peut être halogéné ou un sel de celui-ci, pesticide agricole et horticole contenant ledit composé, et procédé d'utilisation associé
WO2020018362A1 (fr) 2018-07-14 2020-01-23 Fmc Corporation Mélanges pesticides comprenant des indazoles

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
"Compendium of Herbicide Adjuvants", 2010, SOUTHERN ILLINOIS UNIVERSITY
"McCutcheon's Detergents and Emulsifiers Annual", 1981, MC PUBLISHING CORP.
CAS , no. 1616678-32-0
CAS, no. 1771741 -86-6
COLBY, S.R.: "Calculating synergistic and antagonistic responses of herbicide combination", WEEDS, vol. 15, 1967, pages 20 - 22, XP001112961

Similar Documents

Publication Publication Date Title
WO2015059039A1 (fr) Procédé de protection d'un matériel de propagation des végétaux
WO2023105064A1 (fr) Lutte contre les insectes, les acariens et les nématodes
EA037365B1 (ru) Пестицидные смеси, включающие спирогетероциклические пирролидиндионы
WO2023105065A1 (fr) Lutte contre les insectes, les acariens et les nématodes
KR20240016326A (ko) 설폭시민 함유 치환체를 갖는 살충 활성 헤테로사이클릭 유도체
EP4294187A1 (fr) Lutte contre les insectes et les acariens nuisibles
WO2023203038A1 (fr) Lutte contre les insectes, les acariens et les nématodes nuisibles
EP4475680A1 (fr) Lutte contre les insectes, les acariens et les nématodes nuisibles
WO2022200364A1 (fr) Lutte contre les insectes, les acariens et les nématodes
CN115633687A (zh) 用于防治螨、昆虫及线虫的组合物及应用
EP4294185A1 (fr) Lutte contre les insectes et les acariens nuisibles
WO2022180096A1 (fr) Compositions pesticides
WO2023280999A1 (fr) Lutte contre les insectes, les acariens et les nématodes
EP4404753A1 (fr) Lutte contre les insectes, les acariens et les nématodes
WO2022268815A1 (fr) Lutte contre les insectes, les acariens et les nématodes nuisibles
WO2022238576A1 (fr) Compositions de traitement de semences
WO2022268813A1 (fr) Lutte contre les insectes, les acariens et les nématodes nuisibles
WO2022238575A1 (fr) Lutte antiparasitaire contre les insectes, les acariens et les nématodes
WO2015078812A1 (fr) Procédé de protection d'un matériau de propagation végétale
CN117320552A (zh) 昆虫、蜱螨目和线虫类有害生物控制
CN116916751A (zh) 昆虫和蜱螨目有害生物控制
US20240147999A1 (en) Pesticidal formulations
WO2022136440A1 (fr) Polypeptides d'hexatoxine pesticides et procédés d'utilisation associés

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 22716955

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 22716955

Country of ref document: EP

Kind code of ref document: A1