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WO2021103852A1 - Spin orbit torque-based differential memory cell and manufacturing method therefor - Google Patents

Spin orbit torque-based differential memory cell and manufacturing method therefor Download PDF

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Publication number
WO2021103852A1
WO2021103852A1 PCT/CN2020/121910 CN2020121910W WO2021103852A1 WO 2021103852 A1 WO2021103852 A1 WO 2021103852A1 CN 2020121910 W CN2020121910 W CN 2020121910W WO 2021103852 A1 WO2021103852 A1 WO 2021103852A1
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layer
magnetic
spin
oxidation
material layer
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PCT/CN2020/121910
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French (fr)
Chinese (zh)
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李州
孟皓
殷标
迟克群
刘波
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浙江驰拓科技有限公司
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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/161Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect details concerning the memory cell structure, e.g. the layers of the ferromagnetic memory cell
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/10Magnetoresistive devices

Definitions

  • the invention relates to the technical field of magnetic memory, in particular to a spin-orbit moment-based differential storage unit and a preparation method thereof.
  • SOT spin Orbit Torque
  • SOT-MRAM memory A new type of magnetic storage device based on spin-orbit moment and MTJ (which can be called SOT-MRAM memory) has the advantages of separation of reading and writing, fast writing speed, and low writing current density, and is considered to be the future development trend.
  • the SOT-MRAM storage unit is a three-terminal device, which occupies a larger area compared to the traditional STT-MRAM storage unit, resulting in lower data storage density. Therefore, how to improve the storage density of SOT-MRAM memory cells is an urgent technical problem to be solved.
  • the present invention provides a spin-orbit moment-based differential storage unit and a preparation method thereof, which can improve the data storage density of the storage unit.
  • the present invention provides a spin-orbit moment-based differential storage unit, including:
  • Two magnetic layers are located on one side surface of the spin orbital moment providing line, and respectively form a combined structure with the spin orbital moment providing line, and the two magnetic layers have opposite signs
  • the two magnetic tunnel junctions are located on the other side surface of the spin-orbit moment providing line opposite to the two magnetic layers, and are located at the same positions as the two magnetic layers.
  • One-to-one correspondence One-to-one correspondence.
  • the magnetization directions of the two magnetic layers are in-plane magnetization.
  • the material of the spin-orbit moment providing line includes one of Ti, Au, and Zr.
  • the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer includes one of NiFe and NiCo.
  • it further includes: two anti-oxidation layers, and the two anti-oxidation layers are respectively located between the two magnetic layers and the spin-orbit moment supply line.
  • the anti-oxidation layer is made of the same material as the spin-orbit moment providing line.
  • the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
  • Two magnetic tunnel junctions are formed on the spin-orbit moment supply line, and the positions of the two magnetic tunnel junctions are in one-to-one correspondence with the two magnetic layers, respectively.
  • the material of the spin-orbit moment providing line includes one of Ti, Au, and Zr.
  • the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer includes one of NiFe and NiCo.
  • the forming two magnetic layers on the barrier layer includes:
  • the first magnetic material layer and the first anti-oxidation material layer are etched according to the first photolithography pattern to form a first magnetic layer and a corresponding first anti-oxidation layer, and the first anti-oxidation layer remains after etching
  • the photoresist on the top
  • the second magnetic material layer and the second anti-oxidation material layer are etched according to the second photolithography pattern to form a second magnetic layer and a corresponding second anti-oxidation layer, and the first anti-oxidation layer is removed after etching The photoresist above and the photoresist above the second anti-oxidation layer.
  • the forming two magnetic layers on the barrier layer includes:
  • the first magnetic material layer, the first anti-oxidation material layer, and the first protective medium material layer are etched according to the first photolithography pattern to form the first magnetic layer and the corresponding first anti-oxidation layer, first Protect the dielectric layer, remove the photoresist after etching;
  • the second magnetic material layer, the second anti-oxidation material layer, and the second protective dielectric material layer are etched according to the second photolithography pattern to form a second magnetic layer and the corresponding second anti-oxidation layer, second Protect the dielectric layer, and remove the photoresist after etching.
  • two magnetic layers form a combined structure with the spin orbit moment supply line respectively.
  • the two magnetic layers have positive and negative effects.
  • the resistance value of the junction is opposite under different direction currents, which can realize differential storage and improve storage density.
  • the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, it reduces the use of gate transistors, source lines, word lines, bit lines, etc., and simplifies The array structure is improved, and the degree of integration is improved.
  • FIG. 1 is a schematic structural diagram of a spin-orbit moment-based differential memory cell according to an embodiment of the present invention
  • FIG. 2 is a simplified schematic diagram of the structure of the storage unit shown in FIG. 1;
  • FIG. 3 is a schematic structural diagram of a complete differential SOT-MRAM memory cell including the memory cell shown in FIG. 2;
  • FIG. 4 is a schematic diagram of a writing process of a differential memory cell based on spin-orbit moments according to an embodiment of the present invention
  • FIG. 5 is a schematic structural diagram of a spin-orbit moment-based differential memory cell according to another embodiment of the present invention.
  • 6A to 6H are schematic diagrams of the cross-sectional structure of each step of a method for fabricating a spin-orbit moment-based differential memory cell according to an embodiment of the present invention
  • FIGS. 7A to 7H are schematic diagrams of the cross-sectional structure of each step of a method for fabricating a spin-orbit moment-based differential memory cell according to an embodiment of the present invention.
  • An embodiment of the present invention provides a spin-orbit moment-based differential storage unit, as shown in FIG. 1, including:
  • It also includes: two magnetic tunnel junctions 102 and 103 with the same structure, and the two magnetic tunnel junctions 102 and 103 are located on the other side of the spin-orbit moment supply line 101 opposite to the two magnetic layers 104 and 105.
  • the side surfaces and positions correspond to the two magnetic layers respectively.
  • the magnetic tunnel junction 102 includes a free layer 1021, a barrier layer 1022, and a reference layer 1023 that are stacked
  • the magnetic tunnel junction 103 includes a free layer 1031, a barrier layer 1032, and a reference layer 1033 that are stacked.
  • the two magnetic tunnel junctions 104 and 105 are perpendicular magnetization structures or in-plane magnetization structures.
  • the spin-orbit moment providing line 101 is close to the free layers 1021 and 1031 of the magnetic tunnel junctions 102 and 103, which are used to flip the free layers of the magnetic tunnel junctions 102 and 103. Provide the required spin-orbit moment.
  • the in-plane magnetization of the two magnetic layers 104, 105 considering that the same magnetization direction is easier to achieve during preparation, in this embodiment, the two magnetic layers 104, 105 have the same in-plane magnetization direction, and the two magnetic layers 104, 105 have the same in-plane magnetization direction. It has an abnormal Hall conductivity with opposite signs, so that the combined structure of the first magnetic layer 104 and the spin-orbital moment providing line 101 is compared with the combined structure of the second magnetic layer 105 and the spin-orbital moment providing line 101. They have different interface characteristics, and the formed spin Hall angle has opposite signs, which in turn makes the free layer flipping of the two magnetic tunnel junctions opposite.
  • the material of the spin-orbit moment providing line 101 includes one of Ti, Au, and Zr.
  • the first magnetic layer 104 uses a magnetic material with an abnormal Hall conductivity of a positive value, such as Co, Fe, CoFe, CoFeB, and the second magnetic layer 105 uses a magnetic material with an abnormal Hall conductivity of a negative value, such as NiFe, NiCo.
  • the spin-orbit moment providing line 101 is made of Ti
  • the first magnetic layer 104 is made of CoFeB
  • the second magnetic layer 105 is made of NiFe
  • the free layer and the reference layer are made of CoFeB
  • the barrier layer is made of MgO.
  • CoFeB /Ti/CoFeB/MgO structure the resistance value changes from negative to positive, a positive current needs to be passed; the resistance value changes from positive to negative, and a negative current needs to be passed; for the NiFe/Ti/CoFeB/MgO structure, the resistance value changes from negative to negative Positive, negative current is required; resistance value changes from positive to negative, and positive current is required.
  • the spin-orbital moment-based differential memory cell shown in Figure 1 is simplified to the form shown in Figure 2, where FM1 represents the first magnetic layer, FM2 represents the second magnetic layer, and FL represents Magnetic tunnel junction free layer, TBL stands for magnetic tunnel junction barrier layer, RL stands for magnetic tunnel junction reference layer, two magnetic tunnel junctions adopt perpendicular magnetization structure, free layer and reference layer are perpendicular magnetization, have the same perpendicular magnetization direction.
  • FIG. 3 is a structural schematic diagram of a complete differential SOT-MRAM memory cell containing a memory cell read-write circuit.
  • SA is a sense amplifier
  • BLW is a write bit line
  • BL/BLB is a pair of complementary bit lines
  • WL is a word line
  • SL It is the source line
  • the write operation is: WL energizes the strobe transistor, BLW is energized, and SL is grounded.
  • the read operation is: WL Power on the strobe transistor, SL is energized, current flows through the two magnetic tunnel junctions, and the sensitive amplifier SA reads the data.
  • the magnetic tunnel junction is magnetized perpendicularly, the anomalous Hall conductivity of FM1 is positive, and the anomalous Hall conductivity of FM2 is negative.
  • Figure 4(a) in the initial state, the free layer and the reference layer are parallel, and the two magnetic tunnel junctions are both in a low resistance state (0); as shown in Figure 4(b), a positive current (+ I), the corresponding unit of FM1 becomes high-impedance state (1), and the resistance of the corresponding unit of FM2 remains unchanged (0); as shown in Figure 4(c), a negative current (-I) is applied, and the corresponding unit of FM1 becomes low Resistance state (0), the corresponding unit of FM2 becomes high resistance state (1).
  • the resistance values of the corresponding units of FM1 and FM2 are opposite, and differential storage can be realized.
  • the differential memory cell based on the spin-orbit moment provided by the embodiment of the present invention
  • two magnetic layers form a combined structure with the spin-orbit moment supply line respectively.
  • the two magnetic layers have For abnormal Hall conductivity with opposite signs, the interface characteristics between the two magnetic layers and the spin-orbital moment supply line are opposite.
  • the spin Hall angles of the two combined structures have opposite signs, which makes the two
  • the resistance value of the magnetic tunnel junction is opposite under different direction currents, which can realize differential storage and improve storage density.
  • the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, it reduces the use of gate transistors, source lines, word lines, bit lines, etc., and simplifies The array structure is improved, and the degree of integration is improved.
  • the shape may be one of a circle, an ellipse, a square, a diamond, and a rectangle.
  • the specific laminated structure can be realized in various forms, for example, the following structures can be adopted, including:
  • a free layer where the free layer is located on a side surface of the spin-orbit moment providing line;
  • a barrier layer, the barrier layer is located on a side surface of the free layer away from the spin-orbit moment providing line;
  • a reference layer where the reference layer is located on a side surface of the barrier layer away from the free layer;
  • a coupling layer where the coupling layer is located on a side surface of the reference layer away from the barrier layer;
  • a pinning layer is located on a side surface of the coupling layer away from the reference layer;
  • the protective layer is located on the side surface of the pinning layer away from the coupling layer.
  • the free layer, the barrier layer, the reference layer, the coupling layer, the pinned layer, and the protective layer are stacked.
  • the materials of the free layer and the reference layer include but are not limited to magnetic materials such as Co, CoFe, CoFeB, or Co/ Mo/CoFeB, CoFe/Mo/CoFeB and other synthetic magnetic materials formed by ferromagnetic or anti-ferromagnetic coupling
  • the material of the barrier layer includes but not limited to MgO, MgAl 2 O 4 and other materials.
  • the material of the coupling layer includes but is not limited to materials such as Ru and Mo.
  • the material of the pinning layer includes, but is not limited to, [Co/Pt]n, [Co/Pd]n, [CoFe/Pt]n and other materials.
  • the material of the protective layer includes, but is not limited to, Ta, Pt and other materials.
  • the free layer, the reference layer, and the pinned layer are perpendicularly magnetized, and the two magnetic layers are in-plane magnetized to generate a bias magnetic field.
  • This structure can achieve magnetic moment flipping without an external magnetic field, and the two memory cells are in The resistance value under different direction currents is opposite, which can realize differential storage.
  • the memory cell further includes a first anti-oxidation layer 106 and a second anti-oxidation layer 106.
  • the second anti-oxidation layer 107, the first anti-oxidation layer 106 is located between the first magnetic layer 104 and the spin-orbit moment supply line 101, and is used to prevent the first magnetic layer 104 from being oxidized during the preparation process;
  • the oxide layer 107 is located between the second magnetic layer 105 and the spin-orbit moment supply line 101 to prevent the second magnetic layer 105 from being oxidized during the manufacturing process.
  • the first anti-oxidation layer 106 and the second anti-oxidation layer 107 use the same material as the spin-orbit moment providing line 101.
  • Another embodiment of the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
  • Two magnetic tunnel junctions are formed on the spin-orbit moment supply line, and the positions of the two magnetic tunnel junctions are in one-to-one correspondence with the two magnetic layers, respectively.
  • the material of the substrate 601 is generally Si, and the barrier layer 602 is first provided on the substrate 601, which is beneficial to reduce the etching of the first magnetic layer and the second magnetic layer of the magnetization in the bottom surface. Roughness, and non-conductive, improve the feasibility of the process.
  • the material of the barrier layer 602 includes, but is not limited to, SiO 2 , Si 3 N 4 and other materials.
  • step S2 includes:
  • S21 sequentially deposit a first magnetic material layer 603 and a first anti-oxidation material layer 604, spin-coating photoresist and perform a photolithography process to obtain a first photolithography pattern;
  • a layer of anti-oxidation material is deposited on the magnetic material, and heavy metals have good oxidation resistance, so a further layer is deposited when the first magnetic material layer is deposited.
  • the spin-orbital moment supply line is also a heavy metal material, the deposited anti-oxidation material and the spin-orbital moment supply line use the same heavy metal material.
  • the first magnetic material layer 603 and the first anti-oxidation material layer 604 are etched according to the first photolithography pattern, and the first magnetic layer 6031 and the corresponding first anti-oxidation layer 6041 are formed by etching. After etching, the photoresist above the first anti-oxidation layer 6041 is retained;
  • S23 sequentially deposit a second magnetic material layer 605 and a second anti-oxidation material layer 606, spin-coating photoresist and perform a photolithography process to obtain a second photolithography pattern;
  • the second magnetic material layer 605 and the second anti-oxidation material layer 606 are etched according to the second photolithography pattern, and the second magnetic layer 6051 and the corresponding second anti-oxidation layer 6061 are formed by etching. After etching, the photoresist above the first anti-oxidation layer 6041 and the photoresist above the second anti-oxidation layer 6061 are removed.
  • the material of the first magnetic layer 6031 formed includes but is not limited to magnetic materials with abnormal Hall conductivity such as Co, Fe, CoFe, CoFeB, etc.
  • the material of the second magnetic layer 6051 formed includes but not Limited to NiFe, NiCo and other magnetic materials with negative Hall conductivity.
  • there is no fixed preparation sequence for the first magnetic layer and the second magnetic layer and materials with low surface roughness requirements are preferentially prepared.
  • the thickness of the first magnetic layer and the second magnetic layer ranges from 3 to 10 nm.
  • the two magnetic planes are magnetized in-plane and have the same in-plane magnetization direction.
  • the first anti-oxidation material layer and the second anti-oxidation material layer have the same material, which can be Ti, Au or Zr.
  • the first anti-oxidation layer 6041 and the second anti-oxidation layer 6061 formed are relatively thin, with a thickness ranging from 0.5 to 2 nm.
  • Step S3 fill the insulating medium 607 to isolate the two magnetic layers.
  • the insulating medium can be SiO 2 , Si 3 N 4 and other materials.
  • the magnetization directions of the two magnetic layers are set through high-temperature magnetic field annealing treatment.
  • the flattening process is performed. Since the anti-oxidation layer is deposited on the surfaces of the two magnetic layers, after flattening, a smooth surface is formed with the anti-oxidation layer exposed.
  • Step S4 as shown in FIG. 6G, a spin orbit moment providing line 608 is formed on the formed smooth surface, and the material of the spin orbit moment providing line 608 is the same as that of the anti-oxidation layers 6041 and 6061.
  • the spin-orbital moment supply line is thicker, with a thickness ranging from 2 to 5 nm.
  • the spin-orbital moment supply line 608 and the anti-oxidation layers 6041 and 6061 can be regarded as the spin-orbital moment supply line as a whole.
  • the combined structure of the first magnetic layer and the spin-orbital moment supply line is compared to The combined structure of the second magnetic layer and the spin-orbital moment providing line, and the signs of the spin Hall angles of the two are opposite.
  • Step S5 includes: depositing various layers of films of the magnetic tunnel junction, and obtaining the magnetic tunnel junction through photolithography and etching.
  • the embodiment of the present invention does not specifically limit the structure of the magnetic tunnel junction, which may include a basic free layer, a barrier layer, and a reference layer, and a coupling layer, a pinning layer, and a protective layer may also be provided above the reference layer.
  • the free layer, the reference layer, and the pinned layer are magnetized perpendicularly, and the first magnetic layer and the second magnetic layer are magnetized to generate a bias magnetic field.
  • the free layer, the reference layer, the pinned layer, the first magnetic layer, and the second magnetic layer are all set to in-plane magnetization.
  • the high-temperature magnetic field annealing sets the bias magnetization direction, or the high-temperature magnetic field annealing and the magnetic tunnel junction annealing are performed simultaneously.
  • another embodiment of the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
  • a substrate 701 is provided, and a barrier layer 702 is deposited on the substrate 701;
  • a first magnetic material layer 703, a first anti-oxidation material layer 704, and a first protective medium layer 705 are sequentially deposited on the barrier layer 702, and photoresist is spin-coated and a photolithography process is performed to obtain the first photoresist. Carved pattern
  • the first magnetic material layer 703, the first anti-oxidation material layer 704, and the first protective dielectric material layer 705 are etched according to the first photolithography pattern to form a first magnetic layer 7031.
  • the layer 7041 and the first protective dielectric layer 7051 are etched to remove the photoresist.
  • the first protective medium layer 7051 effectively protects the first magnetic layer 7031 and the first anti-oxidation layer 7041.
  • a second magnetic material layer 706, a second anti-oxidation material layer 707, and a second protective medium material layer 708 are further deposited in sequence, photoresist is spin-coated and a photolithography process is performed to obtain a second photolithography pattern;
  • the second magnetic material layer 706, the second oxidation resistant material layer 707, and the second protective dielectric material layer 708 are etched according to the second photolithography pattern to form a second magnetic layer 7061, a second oxidation resistant material layer 708 After etching the layer 7071 and the second protective dielectric layer 7081, the photoresist is removed.
  • the second protective medium layer 7081 effectively protects the second magnetic layer 7061 and the second anti-oxidation layer 7071.
  • the insulating medium 709 is filled to fill the gap between the two magnetic layers and the anti-oxidation layer and the protective medium layer above.
  • the material of the dielectric 7081 is the same, which can be SiO 2 , Si 3 N 4 and other materials.
  • the magnetization direction of the two magnetic layers is set by high-temperature magnetic field annealing treatment, and the planarization process is performed. During the planarization process, the first protective dielectric layer 7051 The second protective medium 7081 is removed, forming a smooth surface exposing the anti-oxidation layer 7041 and 7071.
  • a spin orbit moment providing line 710 is formed on the formed smooth surface, and the material of the spin orbit moment providing line 710 is the same as that of the anti-oxidation layer 7041 and 7071.
  • two magnetic tunnel junctions 7111, 7112 are formed above the spin-orbit moment supply line 710, wherein the position of the magnetic tunnel junction 7111 corresponds to the position of the first magnetic layer 7031, and the position of the magnetic tunnel junction 7112 It corresponds to the position of the second magnetic layer 7061.
  • the materials and thicknesses of the various layers involved can refer to the previous embodiment, and will not be repeated here.
  • the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, the use of strobe transistors, source lines, word lines, bit lines, etc. is reduced, simplifying The array structure is improved, and the degree of integration is improved.

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Abstract

The present invention provides a spin orbit torque-based differential memory cell and a manufacturing method therefor. The memory cell comprises a spin orbit torque providing line, two magnetic layers, and two magnetic tunnel junctions having the same structure; the two magnetic layers are located on one side surface of the spin orbit torque providing line, and separately form a combination structure together with the spin orbit torque providing line; the two magnetic layers have anomalous Hall conductivity with opposite positive and negative signs; the two magnetic tunnel junctions are located on the other side surface of the spin orbit torque providing line opposite to the two magnetic layers, and the positions of the two magnetic tunnel junctions have one-to-one correspondence to the two magnetic layers. In the present invention, by using the two magnetic layers having the anomalous Hall conductivity with opposite positive and negative signs to separately form the combination structure together with the spin orbit torque providing line, the spin Hall angles of the two combination structures have opposite positive and negative signs, and the two magnetic tunnel junctions achieve the storage of differential data, and thus, the data storage density of a memory cell can be enhanced.

Description

基于自旋轨道矩的差分存储单元及其制备方法Differential storage unit based on spin orbit moment and preparation method thereof 技术领域Technical field
本发明涉及磁性存储器技术领域,尤其涉及一种基于自旋轨道矩的差分存储单元及其制备方法。The invention relates to the technical field of magnetic memory, in particular to a spin-orbit moment-based differential storage unit and a preparation method thereof.
背景技术Background technique
研究发现,在具有自旋轨道矩效应(Spin Orbit Torque,SOT)的材料中通入电流时,会在材料的界面处产生自旋极化的自旋电流,该自旋电流可以用于翻转纳米磁铁,例如磁性隧道结MTJ中的自由层。基于自旋轨道矩和MTJ的新型磁存储器件(可以称为SOT-MRAM存储器)具有读写分离、写入速度快、写电流密度低等优点,被认为是未来的发展趋势。Studies have found that when a current is applied to a material with a spin-orbit moment effect (Spin Orbit Torque, SOT), a spin-polarized spin current will be generated at the interface of the material, and this spin current can be used to flip the nanometer Magnets, such as the free layer in a magnetic tunnel junction MTJ. A new type of magnetic storage device based on spin-orbit moment and MTJ (which can be called SOT-MRAM memory) has the advantages of separation of reading and writing, fast writing speed, and low writing current density, and is considered to be the future development trend.
但是,SOT-MRAM的存储单元为三端器件,相比于传统的STT-MRAM存储单元,占用的面积较大,从而使得数据存储密度较低。因此,如何提高SOT-MRAM存储单元的存储密度,是一个急需解决的技术难题。However, the SOT-MRAM storage unit is a three-terminal device, which occupies a larger area compared to the traditional STT-MRAM storage unit, resulting in lower data storage density. Therefore, how to improve the storage density of SOT-MRAM memory cells is an urgent technical problem to be solved.
发明内容Summary of the invention
有鉴于此,本发明提供一种基于自旋轨道矩的差分存储单元及其制备方法,能够提高存储单元的数据存储密度。In view of this, the present invention provides a spin-orbit moment-based differential storage unit and a preparation method thereof, which can improve the data storage density of the storage unit.
第一方面,本发明提供一种基于自旋轨道矩的差分存储单元,包括:In the first aspect, the present invention provides a spin-orbit moment-based differential storage unit, including:
自旋轨道矩提供线;Spin orbit moment providing line;
两个磁性层,两个所述磁性层位于所述自旋轨道矩提供线的一侧表面,分别与所述自旋轨道矩提供线形成组合结构,两个所述磁性层具有正负符号相反的反常霍尔电导率;Two magnetic layers, the two magnetic layers are located on one side surface of the spin orbital moment providing line, and respectively form a combined structure with the spin orbital moment providing line, and the two magnetic layers have opposite signs The abnormal Hall conductivity;
两个结构相同的磁性隧道结,两个所述磁性隧道结位于所述自旋轨道矩提供线的与两个所述磁性层相对的另一侧表面,且位置分别和两个所述磁性层一一对应。Two magnetic tunnel junctions with the same structure, the two magnetic tunnel junctions are located on the other side surface of the spin-orbit moment providing line opposite to the two magnetic layers, and are located at the same positions as the two magnetic layers. One-to-one correspondence.
可选地,两个所述磁性层的磁化方向为面内磁化。Optionally, the magnetization directions of the two magnetic layers are in-plane magnetization.
可选地,所述自旋轨道矩提供线的材料包括Ti、Au和Zr中的一种。Optionally, the material of the spin-orbit moment providing line includes one of Ti, Au, and Zr.
可选地,其中一个所述磁性层的的材料包括Co、Fe、CoFe和CoFeB中的一种,另一个所述磁性层的材料包括NiFe和NiCo中的一种。Optionally, the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer includes one of NiFe and NiCo.
可选地,还包括:两个抗氧化层,两个所述抗氧化层分别位于两个所述磁性层与所述自旋轨道矩提供线之间。Optionally, it further includes: two anti-oxidation layers, and the two anti-oxidation layers are respectively located between the two magnetic layers and the spin-orbit moment supply line.
可选地,所述抗氧化层采用与所述自旋轨道矩提供线相同的材料。Optionally, the anti-oxidation layer is made of the same material as the spin-orbit moment providing line.
第二方面,本发明提供一种基于自旋轨道矩的差分存储单元的制备方法,包括:In a second aspect, the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
提供基底,在所述基底上沉积阻挡层;Providing a substrate, and depositing a barrier layer on the substrate;
在所述阻挡层上形成间隔设置的两个磁性层,两个所述磁性层具有正负符号相反的反常霍尔电导率;Forming two magnetic layers spaced apart on the barrier layer, the two magnetic layers having anomalous Hall conductivity with opposite signs;
填充绝缘介质,并进行平坦化处理,形成一暴露出两个所述磁性层的平滑表面;Filling an insulating medium and performing a planarization treatment to form a smooth surface exposing the two magnetic layers;
在所述平滑表面上形成自旋轨道矩提供线;Forming a spin orbit moment supply line on the smooth surface;
在所述自旋轨道矩提供线上形成两个磁性隧道结,两个所述磁性隧道结的位置分别和两个所述磁性层一一对应。Two magnetic tunnel junctions are formed on the spin-orbit moment supply line, and the positions of the two magnetic tunnel junctions are in one-to-one correspondence with the two magnetic layers, respectively.
可选地,所述自旋轨道矩提供线的材料包括Ti、Au和Zr中的一种。Optionally, the material of the spin-orbit moment providing line includes one of Ti, Au, and Zr.
可选地,其中一个所述磁性层的的材料包括Co、Fe、CoFe和CoFeB中的一种,另一个所述磁性层的材料包括NiFe和NiCo中的一种。Optionally, the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer includes one of NiFe and NiCo.
可选地,所述在所述阻挡层上形成两个磁性层,包括:Optionally, the forming two magnetic layers on the barrier layer includes:
依次沉积第一磁性材料层和第一抗氧化材料层,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;Depositing a first magnetic material layer and a first anti-oxidation material layer in sequence, spin-coating photoresist and performing a photolithography process to obtain a first photolithography pattern;
按照第一光刻图案刻蚀所述第一磁性材料层和所述第一抗氧化材料层,形成第一磁性层和对应的第一抗氧化层,刻蚀后保留所述第一抗氧化层上方的光刻胶;The first magnetic material layer and the first anti-oxidation material layer are etched according to the first photolithography pattern to form a first magnetic layer and a corresponding first anti-oxidation layer, and the first anti-oxidation layer remains after etching The photoresist on the top;
依次沉积第二磁性材料层和第二抗氧化材料层,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;Sequentially depositing a second magnetic material layer and a second anti-oxidation material layer, spin-coating photoresist and performing a photolithography process to obtain a second photolithography pattern;
按照第二光刻图案刻蚀所述第二磁性材料层和所述第二抗氧化材料层,形成第二磁性层和对应的第二抗氧化层,刻蚀后去除所述第一抗氧化层上方的光刻胶以及所述第二抗氧化层上方的光刻胶。The second magnetic material layer and the second anti-oxidation material layer are etched according to the second photolithography pattern to form a second magnetic layer and a corresponding second anti-oxidation layer, and the first anti-oxidation layer is removed after etching The photoresist above and the photoresist above the second anti-oxidation layer.
可选地,所述在所述阻挡层上形成两个磁性层,包括:Optionally, the forming two magnetic layers on the barrier layer includes:
依次沉积第一磁性材料层、第一抗氧化材料层和第一保护介质材料层,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;Sequentially depositing a first magnetic material layer, a first anti-oxidation material layer and a first protective medium material layer, spin-coating photoresist and performing a photolithography process to obtain a first photolithography pattern;
按照第一光刻图案刻蚀所述第一磁性材料层、所述第一抗氧化材料层和所述第一保护介质材料层,形成第一磁性层和对应的第一抗氧化层、第一保护介质层,刻蚀后去除光刻胶;The first magnetic material layer, the first anti-oxidation material layer, and the first protective medium material layer are etched according to the first photolithography pattern to form the first magnetic layer and the corresponding first anti-oxidation layer, first Protect the dielectric layer, remove the photoresist after etching;
依次沉积第二磁性材料层、第二抗氧化材料层和第二保护介质材料层,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;Sequentially depositing a second magnetic material layer, a second anti-oxidation material layer and a second protective medium material layer, spin-coating photoresist and performing a photolithography process to obtain a second photolithography pattern;
按照第二光刻图案刻蚀所述第二磁性材料层、所述第二抗氧化材料层和所述第二保护介质材料层,形成第二磁性层和对应的第二抗氧化层、第二保护介质层,刻蚀后去除光刻胶。The second magnetic material layer, the second anti-oxidation material layer, and the second protective dielectric material layer are etched according to the second photolithography pattern to form a second magnetic layer and the corresponding second anti-oxidation layer, second Protect the dielectric layer, and remove the photoresist after etching.
本发明提供的基于自旋轨道矩的差分存储单元,两个磁性层分别与自旋轨道矩提供线形成组合结构,自旋轨道矩提供线中通入电流时,由于两个磁性层具有正负符号相反的反常霍尔电导率,两个磁性层和自旋轨道矩提供线之间的界面特性相反,形成的两种组合结构的自旋霍尔角正负符号相反,进而使得两个磁性隧道结在不同方向电流下的阻值高低状态相反,能够实现差分存储,提高存储密度。同时,该存储单元直接在一个金属层上堆叠两个并联的MTJ实现差分结构,相比于2T2R结构的差分存储单元,减少了选通晶体管、源线、字线、位线等的使用,简化了阵列结构,提高了集成度。In the differential storage unit based on the spin orbit moment provided by the present invention, two magnetic layers form a combined structure with the spin orbit moment supply line respectively. When current is passed through the spin orbit moment supply line, the two magnetic layers have positive and negative effects. Anomalous Hall conductivity with opposite signs, the interface characteristics between the two magnetic layers and the spin-orbital moment supply line are opposite, and the spin Hall angles of the two combined structures have opposite signs, which makes the two magnetic tunnels The resistance value of the junction is opposite under different direction currents, which can realize differential storage and improve storage density. At the same time, the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, it reduces the use of gate transistors, source lines, word lines, bit lines, etc., and simplifies The array structure is improved, and the degree of integration is improved.
附图说明Description of the drawings
图1为本发明一实施例的基于自旋轨道矩的差分存储单元的结构示意图;FIG. 1 is a schematic structural diagram of a spin-orbit moment-based differential memory cell according to an embodiment of the present invention;
图2为图1所示存储单元的简化结构示意图;FIG. 2 is a simplified schematic diagram of the structure of the storage unit shown in FIG. 1;
图3为包括图2所示存储单元的一个完整的差分SOT-MRAM存储单元的结构示意图;3 is a schematic structural diagram of a complete differential SOT-MRAM memory cell including the memory cell shown in FIG. 2;
图4为本发明一实施例的基于自旋轨道矩的差分存储单元的写入过程示意图;4 is a schematic diagram of a writing process of a differential memory cell based on spin-orbit moments according to an embodiment of the present invention;
图5为本发明另一实施例的基于自旋轨道矩的差分存储单元的结构示意图;5 is a schematic structural diagram of a spin-orbit moment-based differential memory cell according to another embodiment of the present invention;
图6A~图6H为本发明一实施例的基于自旋轨道矩的差分存储单元的制备方法的各步骤剖面结构示意图;6A to 6H are schematic diagrams of the cross-sectional structure of each step of a method for fabricating a spin-orbit moment-based differential memory cell according to an embodiment of the present invention;
图7A~图7H为本发明一实施例的基于自旋轨道矩的差分存储单元的制备方法的各步骤剖面结构示意图。7A to 7H are schematic diagrams of the cross-sectional structure of each step of a method for fabricating a spin-orbit moment-based differential memory cell according to an embodiment of the present invention.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the objectives, technical solutions, and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be described clearly and completely in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments It is only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
本发明一实施例提供一种基于自旋轨道矩的差分存储单元,如图1所示,包括:An embodiment of the present invention provides a spin-orbit moment-based differential storage unit, as shown in FIG. 1, including:
自旋轨道矩提供线101以及位于所述自旋轨道矩提供线101的一侧表面的两个磁性层104和105,两个磁性层分别与自旋轨道矩提供线101形成组合结构,两个所述磁性层具有正负符号相反的反常霍尔电导率;The spin orbit moment providing line 101 and the two magnetic layers 104 and 105 on one side surface of the spin orbit moment providing line 101, the two magnetic layers respectively form a combined structure with the spin orbit moment providing line 101, two The magnetic layer has an abnormal Hall conductivity with opposite signs;
还包括:两个结构相同的磁性隧道结102和103,两个所述磁性隧道结102、103位于所述自旋轨道矩提供线101的与两个所述磁性层104、105相对的另一侧表面,且位置分别和两个所述磁性层一一对应。It also includes: two magnetic tunnel junctions 102 and 103 with the same structure, and the two magnetic tunnel junctions 102 and 103 are located on the other side of the spin-orbit moment supply line 101 opposite to the two magnetic layers 104 and 105. The side surfaces and positions correspond to the two magnetic layers respectively.
具体地,图1中,磁性隧道结102包括堆叠设置的自由层1021、势垒层1022和参考层1023,磁性隧道结103包括堆叠设置的自由层1031、势垒层1032和参考层1033,两个磁性隧道结104、105为垂直磁化结构或者面内磁化结构,自旋轨道矩提供线101靠近磁性隧道结102和103的自由层1021、1031,用于为磁性隧道结102和103自由层翻转提供所需的自旋轨道矩。两个磁性层104、105面内磁化,考虑到相同磁化方向在制备时更容易实现,本实施例中两个磁性层104、105具有相同的面内磁化方向,两个磁性层104、105由于具有正负符号相反的反常霍尔电导率,使得第一磁性层104和自旋轨道矩提供线101的组合结构相比于第二磁性层105和自旋轨道矩提供线101的组合结构,二者具有不同的界面特性,形成的自旋霍尔角正负符号相反,进而使得两个磁性隧道结的自由层翻转情况相反。Specifically, in FIG. 1, the magnetic tunnel junction 102 includes a free layer 1021, a barrier layer 1022, and a reference layer 1023 that are stacked, and the magnetic tunnel junction 103 includes a free layer 1031, a barrier layer 1032, and a reference layer 1033 that are stacked. The two magnetic tunnel junctions 104 and 105 are perpendicular magnetization structures or in-plane magnetization structures. The spin-orbit moment providing line 101 is close to the free layers 1021 and 1031 of the magnetic tunnel junctions 102 and 103, which are used to flip the free layers of the magnetic tunnel junctions 102 and 103. Provide the required spin-orbit moment. The in-plane magnetization of the two magnetic layers 104, 105, considering that the same magnetization direction is easier to achieve during preparation, in this embodiment, the two magnetic layers 104, 105 have the same in-plane magnetization direction, and the two magnetic layers 104, 105 have the same in-plane magnetization direction. It has an abnormal Hall conductivity with opposite signs, so that the combined structure of the first magnetic layer 104 and the spin-orbital moment providing line 101 is compared with the combined structure of the second magnetic layer 105 and the spin-orbital moment providing line 101. They have different interface characteristics, and the formed spin Hall angle has opposite signs, which in turn makes the free layer flipping of the two magnetic tunnel junctions opposite.
本实施例中,所述自旋轨道矩提供线101的材料包括Ti、Au和Zr中的一种。所述第一磁性层104使用反常霍尔电导率为正值的磁性材料,如Co、Fe、CoFe、CoFeB,所述第二磁性层105使用反常霍尔电导率为负值的磁性材料,如NiFe、NiCo。In this embodiment, the material of the spin-orbit moment providing line 101 includes one of Ti, Au, and Zr. The first magnetic layer 104 uses a magnetic material with an abnormal Hall conductivity of a positive value, such as Co, Fe, CoFe, CoFeB, and the second magnetic layer 105 uses a magnetic material with an abnormal Hall conductivity of a negative value, such as NiFe, NiCo.
举例说明,如果自旋轨道矩提供线101材料为Ti,第一磁性层104材料为CoFeB,第二磁性层105材料为NiFe,自由层和参考层材料为CoFeB,势垒层为MgO,对于CoFeB/Ti/CoFeB/MgO结构,电阻值由负变为正,需通正电流;电阻值由正变为负,需通负电流;对于NiFe/Ti/CoFeB/MgO结构,电阻值由负变为正,需通负电流;电阻值由正变为负,需通正电流。正是由于CoFeB反常霍尔电导率为正值,NiFe反常霍尔电导率为负值,使得CoFeB/Ti的自旋霍尔角为正值,NiFe/Ti的自旋霍尔角为负值,进一步使两个磁性隧道结的阻值高低状态相反。For example, if the spin-orbit moment providing line 101 is made of Ti, the first magnetic layer 104 is made of CoFeB, the second magnetic layer 105 is made of NiFe, the free layer and the reference layer are made of CoFeB, and the barrier layer is made of MgO. For CoFeB /Ti/CoFeB/MgO structure, the resistance value changes from negative to positive, a positive current needs to be passed; the resistance value changes from positive to negative, and a negative current needs to be passed; for the NiFe/Ti/CoFeB/MgO structure, the resistance value changes from negative to negative Positive, negative current is required; resistance value changes from positive to negative, and positive current is required. It is precisely because the abnormal Hall conductivity of CoFeB is positive and the abnormal Hall conductivity of NiFe is negative, so that the spin Hall angle of CoFeB/Ti is positive, and the spin Hall angle of NiFe/Ti is negative. Furthermore, the resistance values of the two magnetic tunnel junctions are reversed.
为便于分析存储单元的特性,将图1所示的基于自旋轨道矩的差分存储单元简化为图2所示的形式,其中,FM1表示第一磁性层,FM2表示第二磁性层,FL表示磁性隧道结自由层,TBL表示磁性隧道结势垒层,RL表示磁性隧道结参考层,两个磁性隧道结采用垂直磁化结构,自由层和参考层均为垂直磁化,具有相同的垂直磁化方向。To facilitate the analysis of the characteristics of the memory cell, the spin-orbital moment-based differential memory cell shown in Figure 1 is simplified to the form shown in Figure 2, where FM1 represents the first magnetic layer, FM2 represents the second magnetic layer, and FL represents Magnetic tunnel junction free layer, TBL stands for magnetic tunnel junction barrier layer, RL stands for magnetic tunnel junction reference layer, two magnetic tunnel junctions adopt perpendicular magnetization structure, free layer and reference layer are perpendicular magnetization, have the same perpendicular magnetization direction.
图3为包含存储单元读写电路的一个完整的差分SOT-MRAM存储单元的结构示意图,SA为灵敏放大器,BLW为写位线,BL/BLB为一对互补位线,WL为字线,SL为源线,写操作为:WL通电选通晶体管,BLW通电,SL接地,当电流流经自旋轨道矩提供线,FM1和FM2对应的磁性隧道结的电阻高低状态相反;读操作为:WL通电选通晶体管,SL通电,电流流经两个磁性隧道结,灵敏放大器SA读取数据。Figure 3 is a structural schematic diagram of a complete differential SOT-MRAM memory cell containing a memory cell read-write circuit. SA is a sense amplifier, BLW is a write bit line, BL/BLB is a pair of complementary bit lines, WL is a word line, SL It is the source line, and the write operation is: WL energizes the strobe transistor, BLW is energized, and SL is grounded. When the current flows through the spin orbit moment supply line, the resistance of the magnetic tunnel junction corresponding to FM1 and FM2 is opposite; the read operation is: WL Power on the strobe transistor, SL is energized, current flows through the two magnetic tunnel junctions, and the sensitive amplifier SA reads the data.
具体的写入过程如下:The specific writing process is as follows:
如前所述,磁性隧道结垂直磁化,FM1的反常霍尔电导率为正值,FM2的反常霍尔电导率为负值。如图4的(a)所示,初始状态,自由层和参考层平行,两个磁性隧道结均为低阻态(0);如图4的(b)所示,通入正电流(+I),FM1对应单元变为高阻态(1),FM2对应单元电阻不变(0);如图4的(c)所示,通入负电流(-I),FM1对应单元变为低阻态(0),FM2对应单元变为高阻态(1)。由此可知,在不同方向电流情况下,FM1与FM2对应单元的电阻阻值高低状态相反,可以实现差分存储。As mentioned earlier, the magnetic tunnel junction is magnetized perpendicularly, the anomalous Hall conductivity of FM1 is positive, and the anomalous Hall conductivity of FM2 is negative. As shown in Figure 4(a), in the initial state, the free layer and the reference layer are parallel, and the two magnetic tunnel junctions are both in a low resistance state (0); as shown in Figure 4(b), a positive current (+ I), the corresponding unit of FM1 becomes high-impedance state (1), and the resistance of the corresponding unit of FM2 remains unchanged (0); as shown in Figure 4(c), a negative current (-I) is applied, and the corresponding unit of FM1 becomes low Resistance state (0), the corresponding unit of FM2 becomes high resistance state (1). It can be seen that, in the case of currents in different directions, the resistance values of the corresponding units of FM1 and FM2 are opposite, and differential storage can be realized.
本发明实施例提供的基于自旋轨道矩的差分存储单元,两个磁性层分别与自旋轨道矩提供线形成组合结构,自旋轨道矩提供线中通入电流时,由于两个磁性层具有正负符号相反的反常霍尔电导率,两个磁性层和自旋轨道矩提供线之间的界面特性相反,形成的两种组合结构的自旋霍尔角正负符号相反,进而使得两个磁性隧道结在不同方向电流下的阻值高低状态相反,能够实现差分存储,提高存储密度。同时,该存储单元直接在一个金属层上堆叠两个并联的MTJ实现差分结构,相比于2T2R结构的差分存储单元,减少了选通晶体管、源线、字线、位线等的使用,简化了阵列结构,提高了集成度。In the differential memory cell based on the spin-orbit moment provided by the embodiment of the present invention, two magnetic layers form a combined structure with the spin-orbit moment supply line respectively. When the current is passed through the spin-orbit moment supply line, the two magnetic layers have For abnormal Hall conductivity with opposite signs, the interface characteristics between the two magnetic layers and the spin-orbital moment supply line are opposite. The spin Hall angles of the two combined structures have opposite signs, which makes the two The resistance value of the magnetic tunnel junction is opposite under different direction currents, which can realize differential storage and improve storage density. At the same time, the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, it reduces the use of gate transistors, source lines, word lines, bit lines, etc., and simplifies The array structure is improved, and the degree of integration is improved.
另外需要说明的是,关于本发明实施例中用到的两个磁性隧道结,形状可以为圆形、椭圆形、正方形、菱形、长方形中的一种。其具体的叠层结构可以有多种实现形式,例如采用如下结构,包括:In addition, it should be noted that, regarding the two magnetic tunnel junctions used in the embodiment of the present invention, the shape may be one of a circle, an ellipse, a square, a diamond, and a rectangle. The specific laminated structure can be realized in various forms, for example, the following structures can be adopted, including:
自由层,所述自由层位于所述自旋轨道矩提供线的一侧表面;A free layer, where the free layer is located on a side surface of the spin-orbit moment providing line;
势垒层,所述势垒层位于所述自由层远离所述自旋轨道矩提供线的一侧表面;A barrier layer, the barrier layer is located on a side surface of the free layer away from the spin-orbit moment providing line;
参考层,所述参考层位于所述势垒层的远离所述自由层的一侧表面;A reference layer, where the reference layer is located on a side surface of the barrier layer away from the free layer;
耦合层,所述耦合层位于所述参考层的远离所述势垒层的一侧表面;A coupling layer, where the coupling layer is located on a side surface of the reference layer away from the barrier layer;
钉扎层,所述钉扎层位于所述耦合层的远离所述参考层的一侧表面;A pinning layer, the pinning layer is located on a side surface of the coupling layer away from the reference layer;
保护层,所述保护层位于所述钉扎层的远离所述耦合层的一侧表面。The protective layer is located on the side surface of the pinning layer away from the coupling layer.
即包括堆叠设置的自由层、势垒层、参考层、耦合层、钉扎层、保护层,其中,自由层和参考层的材料包括但不限于Co、CoFe、CoFeB等磁性材料,或者Co/Mo/CoFeB、CoFe/Mo/CoFeB等通过铁磁或反铁磁耦合形成的合成磁性材料,势垒层的材料包括但不限于MgO、MgAl 2O 4等材料。耦合层的材料包括但不限于Ru、Mo等材料。钉扎层的材料包括但不限于[Co/Pt]n、[Co/Pd]n、[CoFe/Pt]n等材料。保护层的材料包括但不限于Ta、Pt等材料。 That is, the free layer, the barrier layer, the reference layer, the coupling layer, the pinned layer, and the protective layer are stacked. The materials of the free layer and the reference layer include but are not limited to magnetic materials such as Co, CoFe, CoFeB, or Co/ Mo/CoFeB, CoFe/Mo/CoFeB and other synthetic magnetic materials formed by ferromagnetic or anti-ferromagnetic coupling, the material of the barrier layer includes but not limited to MgO, MgAl 2 O 4 and other materials. The material of the coupling layer includes but is not limited to materials such as Ru and Mo. The material of the pinning layer includes, but is not limited to, [Co/Pt]n, [Co/Pd]n, [CoFe/Pt]n and other materials. The material of the protective layer includes, but is not limited to, Ta, Pt and other materials.
采用上述结构时,自由层、参考层、钉扎层为垂直磁化,两个磁性层为面内磁化,产生偏置磁场,该结构可以实现无需外部磁场的磁矩翻转,且两个存储单元在不同方向电流下的阻值高低状态相反,可实现差分存储。When the above structure is adopted, the free layer, the reference layer, and the pinned layer are perpendicularly magnetized, and the two magnetic layers are in-plane magnetized to generate a bias magnetic field. This structure can achieve magnetic moment flipping without an external magnetic field, and the two memory cells are in The resistance value under different direction currents is opposite, which can realize differential storage.
特别说明的是,将图1所示的存储单元结构上下颠倒,仍然可以取得相同的效果,也在本发明保护范围内。In particular, if the memory cell structure shown in FIG. 1 is turned upside down, the same effect can still be obtained, and it is also within the protection scope of the present invention.
进一步地,在图1所示存储单元结构的基础上,为了防止制备过程中第一磁性层和第二磁性层发生氧化,如图5所示,存储单元还包括第一抗氧化层106和第二抗氧化层107,第一抗氧化层106位于第一磁性层104和所述自旋轨道矩提供线101之间,用于防止制备过程中所述第一磁性层104发生氧化;第二抗氧化层107位于第二磁性层105和所述自旋轨道矩提供线101之间,用于防止制备过程中所述第二磁性层105发生氧化。第一抗氧化层106、第二抗氧化层107使用与所述自旋轨道矩提供线101相同的材料。Further, on the basis of the memory cell structure shown in FIG. 1, in order to prevent oxidation of the first magnetic layer and the second magnetic layer during the manufacturing process, as shown in FIG. 5, the memory cell further includes a first anti-oxidation layer 106 and a second anti-oxidation layer 106. The second anti-oxidation layer 107, the first anti-oxidation layer 106 is located between the first magnetic layer 104 and the spin-orbit moment supply line 101, and is used to prevent the first magnetic layer 104 from being oxidized during the preparation process; The oxide layer 107 is located between the second magnetic layer 105 and the spin-orbit moment supply line 101 to prevent the second magnetic layer 105 from being oxidized during the manufacturing process. The first anti-oxidation layer 106 and the second anti-oxidation layer 107 use the same material as the spin-orbit moment providing line 101.
本发明另一实施例提供一种基于自旋轨道矩的差分存储单元的制备方法,包括:Another embodiment of the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
S1、提供基底,在所述基底上沉积阻挡层;S1, providing a substrate, and depositing a barrier layer on the substrate;
S2、在所述阻挡层上形成间隔设置的两个磁性层,两个所述磁性层具有正负符号相反的反常霍尔电导率;S2, forming two magnetic layers spaced apart on the barrier layer, and the two magnetic layers have anomalous Hall conductivity with opposite positive and negative signs;
S3、填充绝缘介质,并进行平坦化处理,形成一暴露出两个所述磁性层的平滑表面;S3, filling an insulating medium and performing a planarization treatment to form a smooth surface exposing the two magnetic layers;
S4、在所述平滑表面上形成自旋轨道矩提供线;S4, forming a spin orbit moment supply line on the smooth surface;
S5、在所述自旋轨道矩提供线上形成两个磁性隧道结,两个所述磁性隧道结的位置分别和两个所述磁性层一一对应。S5. Two magnetic tunnel junctions are formed on the spin-orbit moment supply line, and the positions of the two magnetic tunnel junctions are in one-to-one correspondence with the two magnetic layers, respectively.
步骤S1中,如图6A所示,基底601的材料一般为Si,在所述基底601上先设置阻挡层602,有利于降低底部面内磁化的第一磁性层和第二磁性层刻蚀的粗糙度,而且不导电,提高工艺可行性。阻挡层602的材料包括但不限于SiO 2、Si 3N 4等材料。 In step S1, as shown in FIG. 6A, the material of the substrate 601 is generally Si, and the barrier layer 602 is first provided on the substrate 601, which is beneficial to reduce the etching of the first magnetic layer and the second magnetic layer of the magnetization in the bottom surface. Roughness, and non-conductive, improve the feasibility of the process. The material of the barrier layer 602 includes, but is not limited to, SiO 2 , Si 3 N 4 and other materials.
具体地,步骤S2包括:Specifically, step S2 includes:
S21、如图6B所示,依次沉积第一磁性材料层603和第一抗氧化材料层604,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;S21, as shown in FIG. 6B, sequentially deposit a first magnetic material layer 603 and a first anti-oxidation material layer 604, spin-coating photoresist and perform a photolithography process to obtain a first photolithography pattern;
一般地,为了防止磁性材料在制备时发生氧化,会在磁性材料上沉积一层抗氧化材料,而重金属就具有很好的抗氧化性,因此在沉积第一磁性材料层时进一步沉积一层很薄的重金属,考虑到制备自旋轨道矩提供线也是重金属材料,沉积的抗氧化材料与自旋轨道矩提供线采用相同的重金属材料。Generally, in order to prevent oxidation of the magnetic material during preparation, a layer of anti-oxidation material is deposited on the magnetic material, and heavy metals have good oxidation resistance, so a further layer is deposited when the first magnetic material layer is deposited. For thin heavy metals, considering that the spin-orbital moment supply line is also a heavy metal material, the deposited anti-oxidation material and the spin-orbital moment supply line use the same heavy metal material.
S22、如图6C所示,按照第一光刻图案刻蚀第一磁性材料层603和第一抗氧化材料层604,通过刻蚀形成第一磁性层6031和对应的第一抗氧化层6041,刻蚀后保留所述第一抗氧化层6041上方的光刻胶;S22. As shown in FIG. 6C, the first magnetic material layer 603 and the first anti-oxidation material layer 604 are etched according to the first photolithography pattern, and the first magnetic layer 6031 and the corresponding first anti-oxidation layer 6041 are formed by etching. After etching, the photoresist above the first anti-oxidation layer 6041 is retained;
S23、如图6D所示,依次沉积第二磁性材料层605和第二抗氧化材料层606,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;S23, as shown in FIG. 6D, sequentially deposit a second magnetic material layer 605 and a second anti-oxidation material layer 606, spin-coating photoresist and perform a photolithography process to obtain a second photolithography pattern;
S24、如图6E所示,按照第二光刻图案刻蚀第二磁性材料层605和第二抗氧化材料层606,通过刻蚀形成第二磁性层6051和对应的第二抗氧化层6061,刻蚀后去除所述第一抗氧化层6041上方的光刻胶以及所述第二抗氧化层6061上方的光刻胶。S24. As shown in FIG. 6E, the second magnetic material layer 605 and the second anti-oxidation material layer 606 are etched according to the second photolithography pattern, and the second magnetic layer 6051 and the corresponding second anti-oxidation layer 6061 are formed by etching. After etching, the photoresist above the first anti-oxidation layer 6041 and the photoresist above the second anti-oxidation layer 6061 are removed.
本实施例中,形成的第一磁性层6031的材料包括但不限于Co、Fe、CoFe、CoFeB等反常霍尔电导率为正值的磁性材料,形成的第二磁性层6051的材料包括但不限于NiFe、NiCo等反常霍尔电导率为负值的磁性材料。原则上第一磁性层和第二磁性层没有固定的制备顺序,优先制备对表面粗糙度要求低的材料,第一磁性层和第二磁性层的厚度范围为3~10nm。两个磁性层面内磁化,并具有相同的面内磁化方向。In this embodiment, the material of the first magnetic layer 6031 formed includes but is not limited to magnetic materials with abnormal Hall conductivity such as Co, Fe, CoFe, CoFeB, etc., and the material of the second magnetic layer 6051 formed includes but not Limited to NiFe, NiCo and other magnetic materials with negative Hall conductivity. In principle, there is no fixed preparation sequence for the first magnetic layer and the second magnetic layer, and materials with low surface roughness requirements are preferentially prepared. The thickness of the first magnetic layer and the second magnetic layer ranges from 3 to 10 nm. The two magnetic planes are magnetized in-plane and have the same in-plane magnetization direction.
第一抗氧化材料层、第二抗氧化材料层材料相同,可以为Ti、Au或者Zr,形成的第一抗氧化层6041、第二抗氧化层6061较薄,厚度范围0.5~2nm。The first anti-oxidation material layer and the second anti-oxidation material layer have the same material, which can be Ti, Au or Zr. The first anti-oxidation layer 6041 and the second anti-oxidation layer 6061 formed are relatively thin, with a thickness ranging from 0.5 to 2 nm.
步骤S3,如图6F所示,填充绝缘介质607,使两个磁性层隔离,绝缘介质可以为SiO 2、Si 3N 4等材料,通过高温磁场退火处理,设置两个磁性层的磁化方向,并进行平坦化处理,由于两个磁性层表面沉积了抗氧化层,平坦化之后形成一暴露出抗氧化层的平滑表面。 Step S3, as shown in FIG. 6F, fill the insulating medium 607 to isolate the two magnetic layers. The insulating medium can be SiO 2 , Si 3 N 4 and other materials. The magnetization directions of the two magnetic layers are set through high-temperature magnetic field annealing treatment. The flattening process is performed. Since the anti-oxidation layer is deposited on the surfaces of the two magnetic layers, after flattening, a smooth surface is formed with the anti-oxidation layer exposed.
步骤S4,如图6G所示,在形成的平滑表面上形成自旋轨道矩提供线608,自旋轨道矩提供线608的材料与抗氧化层6041和6061材料相同。自旋轨道矩提供线较厚,厚度范围2~5nm。Step S4, as shown in FIG. 6G, a spin orbit moment providing line 608 is formed on the formed smooth surface, and the material of the spin orbit moment providing line 608 is the same as that of the anti-oxidation layers 6041 and 6061. The spin-orbital moment supply line is thicker, with a thickness ranging from 2 to 5 nm.
分析时,可以将自旋轨道矩提供线608与抗氧化层6041和6061作为一个整体,都看做自旋轨道矩提供线,第一磁性层与自旋轨道矩提供线的组合结构相比于第二磁性层与自旋轨道矩提供线的组合结构,二者的自旋霍尔角符号相反。In the analysis, the spin-orbital moment supply line 608 and the anti-oxidation layers 6041 and 6061 can be regarded as the spin-orbital moment supply line as a whole. The combined structure of the first magnetic layer and the spin-orbital moment supply line is compared to The combined structure of the second magnetic layer and the spin-orbital moment providing line, and the signs of the spin Hall angles of the two are opposite.
步骤S5,如图6H所示,在自旋轨道矩提供线608上方形成两个磁性隧道结6091、6092,其中磁性隧道结6091的位置与所述第一磁性层6031的位置对应,磁性隧道结6092的位置与所述第二磁性层6051的位置对应。具体地,步骤S5包括:沉积磁性隧道结的各层薄膜,通过光刻和刻蚀,得到磁性隧道结。本发明实施例对磁性隧道结的结构不做具体限定,可以包括基本的自由层、势垒层和参考层,还可以在参考层上方设置耦合层、钉扎层和保护层。自由层、参考层、钉扎层垂直磁化,第一磁性层和第二磁性层面内磁化,产生偏置磁场。或者,自由层、参考层、钉扎层、第一磁性层和第二磁性层均设置为面内磁化。在沉积保护层后,高温磁场退火设置偏置磁化方向,或者高温磁场退火与磁性隧道结退火同步进行。Step S5, as shown in FIG. 6H, two magnetic tunnel junctions 6091 and 6092 are formed above the spin-orbit moment providing line 608, wherein the position of the magnetic tunnel junction 6091 corresponds to the position of the first magnetic layer 6031, and the magnetic tunnel junction The position of 6092 corresponds to the position of the second magnetic layer 6051. Specifically, step S5 includes: depositing various layers of films of the magnetic tunnel junction, and obtaining the magnetic tunnel junction through photolithography and etching. The embodiment of the present invention does not specifically limit the structure of the magnetic tunnel junction, which may include a basic free layer, a barrier layer, and a reference layer, and a coupling layer, a pinning layer, and a protective layer may also be provided above the reference layer. The free layer, the reference layer, and the pinned layer are magnetized perpendicularly, and the first magnetic layer and the second magnetic layer are magnetized to generate a bias magnetic field. Alternatively, the free layer, the reference layer, the pinned layer, the first magnetic layer, and the second magnetic layer are all set to in-plane magnetization. After the protective layer is deposited, the high-temperature magnetic field annealing sets the bias magnetization direction, or the high-temperature magnetic field annealing and the magnetic tunnel junction annealing are performed simultaneously.
参考图7A~图7H,本发明另一实施例提供的基于自旋轨道矩的差分存储单元的制备方法,包括:Referring to FIGS. 7A to 7H, another embodiment of the present invention provides a method for manufacturing a spin-orbit moment-based differential memory cell, including:
如图7A所示,提供基底701,在基底701上沉积阻挡层702;As shown in FIG. 7A, a substrate 701 is provided, and a barrier layer 702 is deposited on the substrate 701;
如图7B所示,在阻挡层702上依次沉积第一磁性材料层703、第一抗氧化材料层704和第一保护介质层705,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;As shown in FIG. 7B, a first magnetic material layer 703, a first anti-oxidation material layer 704, and a first protective medium layer 705 are sequentially deposited on the barrier layer 702, and photoresist is spin-coated and a photolithography process is performed to obtain the first photoresist. Carved pattern
如图7C所示,按照第一光刻图案对第一磁性材料层703、第一抗氧化材料层704和第一保护介质材料层705进行刻蚀,形成第一磁性层7031、第一抗氧化层7041和第一保护介质层7051,刻蚀后去除光刻胶。通过第一保护介质层7051对第一磁性层7031、第一抗氧化层7041形成有效的保护。As shown in FIG. 7C, the first magnetic material layer 703, the first anti-oxidation material layer 704, and the first protective dielectric material layer 705 are etched according to the first photolithography pattern to form a first magnetic layer 7031. The layer 7041 and the first protective dielectric layer 7051 are etched to remove the photoresist. The first protective medium layer 7051 effectively protects the first magnetic layer 7031 and the first anti-oxidation layer 7041.
如图7D所示,进一步依次沉积第二磁性材料层706、第二抗氧化材料层707和第二保护介质材料层708,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;As shown in FIG. 7D, a second magnetic material layer 706, a second anti-oxidation material layer 707, and a second protective medium material layer 708 are further deposited in sequence, photoresist is spin-coated and a photolithography process is performed to obtain a second photolithography pattern;
如图7E所示,按照第二光刻图案对第二磁性材料层706、第二抗氧化材料层707和第二保护介质材料层708进行刻蚀,形成第二磁性层7061、第二抗氧化层7071和第二保护介质层7081,刻蚀后去除光刻胶。通过第二保护介质层7081对第二磁性层7061、第二抗氧化层7071形成有效的保护。As shown in FIG. 7E, the second magnetic material layer 706, the second oxidation resistant material layer 707, and the second protective dielectric material layer 708 are etched according to the second photolithography pattern to form a second magnetic layer 7061, a second oxidation resistant material layer 708 After etching the layer 7071 and the second protective dielectric layer 7081, the photoresist is removed. The second protective medium layer 7081 effectively protects the second magnetic layer 7061 and the second anti-oxidation layer 7071.
如图7F所示,填充绝缘介质709,充满两个磁性层及其上方抗氧化层、保护介质层之间的空隙,本实施例中,绝缘介质709与第一保护介质层7051、第二保护介质7081材料相同,可以为SiO 2、Si 3N 4等材料,通过高温磁场退火处理,设置两个磁性层的磁化方向,并进行平坦化处理,平坦化处理过程中,第一保护介质层7051、第二保护介质7081被去除,形成一暴露出抗氧化层7041、7071的平滑表面。 As shown in FIG. 7F, the insulating medium 709 is filled to fill the gap between the two magnetic layers and the anti-oxidation layer and the protective medium layer above. The material of the dielectric 7081 is the same, which can be SiO 2 , Si 3 N 4 and other materials. The magnetization direction of the two magnetic layers is set by high-temperature magnetic field annealing treatment, and the planarization process is performed. During the planarization process, the first protective dielectric layer 7051 The second protective medium 7081 is removed, forming a smooth surface exposing the anti-oxidation layer 7041 and 7071.
如图7G所示,在形成的平滑表面上形成自旋轨道矩提供线710,自旋轨道矩提供线710的材料与抗氧化层7041、7071材料相同。As shown in FIG. 7G, a spin orbit moment providing line 710 is formed on the formed smooth surface, and the material of the spin orbit moment providing line 710 is the same as that of the anti-oxidation layer 7041 and 7071.
如图7H所示,在自旋轨道矩提供线710上方形成两个磁性隧道结7111、7112,其中磁性隧道结7111的位置与所述第一磁性层7031的位置对应,磁性隧道结7112的位置与所述第二磁性层7061的位置对应。As shown in FIG. 7H, two magnetic tunnel junctions 7111, 7112 are formed above the spin-orbit moment supply line 710, wherein the position of the magnetic tunnel junction 7111 corresponds to the position of the first magnetic layer 7031, and the position of the magnetic tunnel junction 7112 It corresponds to the position of the second magnetic layer 7061.
本实施例中,所涉及各层的材料和厚度可以参考上一实施例,不再赘述。In this embodiment, the materials and thicknesses of the various layers involved can refer to the previous embodiment, and will not be repeated here.
通过上述工艺流程制备的基于自旋轨道矩的差分存储单元,自由层、参考层为垂直磁化,两个磁性层为面内磁化,产生偏置磁场,自旋轨道矩提供线中通入电流时,可以实现无需外部磁场的磁矩翻转,且两个磁性隧道结在不同方向电流下的阻值高低状态相反,能够实现差分存储,提高存储密度。同时,该存储单元直接在一个金属层上堆叠两个并联的MTJ实现差分结构,相比于2T2R结构的差分存储单元,减少了选通晶体管、源线、字线、位线等的使用,简化了阵列结构,提高了集成度。The spin-orbital moment-based differential memory cell prepared by the above process, the free layer and the reference layer are perpendicular magnetization, and the two magnetic layers are in-plane magnetization to generate a bias magnetic field. , Can realize the magnetic moment reversal without external magnetic field, and the resistance value of the two magnetic tunnel junctions under different direction currents is opposite, which can realize differential storage and improve storage density. At the same time, the memory cell directly stacks two parallel MTJs on a metal layer to achieve a differential structure. Compared with the differential memory cell of the 2T2R structure, the use of strobe transistors, source lines, word lines, bit lines, etc. is reduced, simplifying The array structure is improved, and the degree of integration is improved.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited to this. Any person skilled in the art can easily think of changes or substitutions within the technical scope disclosed by the present invention. All should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be subject to the protection scope of the claims.

Claims (11)

  1. 一种基于自旋轨道矩的差分存储单元,其特征在于,包括:A differential storage unit based on spin-orbit moment, which is characterized in that it comprises:
    自旋轨道矩提供线;Spin orbit moment providing line;
    两个磁性层,两个所述磁性层位于所述自旋轨道矩提供线的一侧表面,分别与所述自旋轨道矩提供线形成组合结构,两个所述磁性层具有正负符号相反的反常霍尔电导率;Two magnetic layers, the two magnetic layers are located on one side surface of the spin-orbital moment providing line, and respectively form a combined structure with the spin-orbital moment providing line, and the two magnetic layers have opposite signs The abnormal Hall conductivity;
    两个结构相同的磁性隧道结,两个所述磁性隧道结位于所述自旋轨道矩提供线的与两个所述磁性层相对的另一侧表面,且位置分别和两个所述磁性层一一对应。Two magnetic tunnel junctions with the same structure, the two magnetic tunnel junctions are located on the other side surface of the spin-orbit moment providing line opposite to the two magnetic layers, and are located at the same positions as the two magnetic layers. One-to-one correspondence.
  2. 根据权利要求1所述的基于自旋轨道矩的差分存储单元,其特征在于,两个所述磁性层的磁化方向为面内磁化。The differential memory cell based on the spin-orbit moment of claim 1, wherein the magnetization directions of the two magnetic layers are in-plane magnetization.
  3. 根据权利要求1所述的基于自旋轨道矩的差分存储单元,其特征在于,所述自旋轨道矩提供线的材料包括Ti、Au和Zr中的一种。The differential memory cell based on the spin orbit moment of claim 1, wherein the material of the spin orbit moment providing line includes one of Ti, Au, and Zr.
  4. 根据权利要求1所述的基于自旋轨道矩的差分存储单元,其特征在于,其中一个所述磁性层的的材料包括Co、Fe、CoFe和CoFeB中的一种,另一个所述磁性层的材料包括NiFe和NiCo中的一种。The differential memory cell based on the spin-orbit moment of claim 1, wherein the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer The material includes one of NiFe and NiCo.
  5. 根据权利要求1所述的基于自旋轨道矩的差分存储单元,其特征在于,还包括:两个抗氧化层,两个所述抗氧化层分别位于两个所述磁性层与所述自旋轨道矩提供线之间。The differential memory cell based on the spin-orbit moment of claim 1, further comprising: two anti-oxidation layers, the two anti-oxidation layers are respectively located on the two magnetic layers and the spin-orbital moment. Orbital moments are provided between the lines.
  6. 根据权利要求5所述的基于自旋轨道矩的差分存储单元,其特征在于,所述抗氧化层采用与所述自旋轨道矩提供线相同的材料。The differential memory cell based on the spin orbit moment of claim 5, wherein the anti-oxidation layer is made of the same material as the spin orbit moment supply line.
  7. 一种基于自旋轨道矩的差分存储单元的制备方法,其特征在于,包括:A method for preparing a spin-orbit moment-based differential storage unit, which is characterized in that it comprises:
    提供基底,在所述基底上沉积阻挡层;Providing a substrate, and depositing a barrier layer on the substrate;
    在所述阻挡层上形成间隔设置的两个磁性层,两个所述磁性层具有正负符号相反的反常霍尔电导率;Forming two magnetic layers spaced apart on the barrier layer, the two magnetic layers having anomalous Hall conductivity with opposite signs;
    填充绝缘介质,并进行平坦化处理,形成一暴露出两个所述磁性层的平滑表面;Filling an insulating medium and performing a planarization treatment to form a smooth surface exposing the two magnetic layers;
    在所述平滑表面上形成自旋轨道矩提供线;Forming a spin-orbit moment supply line on the smooth surface;
    在所述自旋轨道矩提供线上形成两个磁性隧道结,两个所述磁性隧道结的位置分别和两个所述磁性层一一对应。Two magnetic tunnel junctions are formed on the spin-orbit moment supply line, and the positions of the two magnetic tunnel junctions are in one-to-one correspondence with the two magnetic layers, respectively.
  8. 根据权利要求7所述的方法,其特征在于,所述自旋轨道矩提供线的材料包括Ti、Au和Zr中的一种。The method according to claim 7, wherein the material of the spin-orbit moment providing line includes one of Ti, Au, and Zr.
  9. 根据权利要求7所述的方法,其特征在于,其中一个所述磁性层的的材料包括Co、Fe、CoFe和CoFeB中的一种,另一个所述磁性层的材料包括NiFe和NiCo中的一种。The method according to claim 7, wherein the material of one of the magnetic layers includes one of Co, Fe, CoFe, and CoFeB, and the material of the other magnetic layer includes one of NiFe and NiCo. Kind.
  10. 根据权利要求7所述的方法,其特征在于,所述在所述阻挡层上形成两个磁性层,包括:8. The method of claim 7, wherein the forming two magnetic layers on the barrier layer comprises:
    依次沉积第一磁性材料层和第一抗氧化材料层,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;Depositing a first magnetic material layer and a first anti-oxidation material layer in sequence, spin-coating photoresist and performing a photolithography process to obtain a first photolithography pattern;
    按照第一光刻图案刻蚀所述第一磁性材料层和所述第一抗氧化材料层,形成第一磁性层和对应的第一抗氧化层,刻蚀后保留所述第一抗氧化层上方的光刻胶;The first magnetic material layer and the first anti-oxidation material layer are etched according to the first photolithography pattern to form a first magnetic layer and a corresponding first anti-oxidation layer, and the first anti-oxidation layer remains after etching The photoresist on the top;
    依次沉积第二磁性材料层和第二抗氧化材料层,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;Sequentially depositing a second magnetic material layer and a second anti-oxidation material layer, spin-coating photoresist and performing a photolithography process to obtain a second photolithography pattern;
    按照第二光刻图案刻蚀所述第二磁性材料层和所述第二抗氧化材料层,形成第二磁性层和对应的第二抗氧化层,刻蚀后去除所述第一抗氧化层上方的光刻胶以及所述第二抗氧化层上方的光刻胶。The second magnetic material layer and the second anti-oxidation material layer are etched according to the second photolithography pattern to form a second magnetic layer and a corresponding second anti-oxidation layer, and the first anti-oxidation layer is removed after etching The photoresist above and the photoresist above the second anti-oxidation layer.
  11. 根据权利要求7所述的方法,其特征在于,所述在所述阻挡层上形成两个磁性层,包括:8. The method of claim 7, wherein the forming two magnetic layers on the barrier layer comprises:
    依次沉积第一磁性材料层、第一抗氧化材料层和第一保护介质材料层,旋涂光刻胶并进行光刻工艺,得到第一光刻图案;Sequentially depositing a first magnetic material layer, a first anti-oxidation material layer and a first protective medium material layer, spin-coating photoresist and performing a photolithography process to obtain a first photolithography pattern;
    按照第一光刻图案刻蚀所述第一磁性材料层、所述第一抗氧化材料层和所述第一保护介质材料层,形成第一磁性层和对应的第一抗氧化层、第一保护介质层,刻蚀后去除光刻胶;The first magnetic material layer, the first anti-oxidation material layer, and the first protective dielectric material layer are etched according to the first photolithography pattern to form a first magnetic layer and corresponding first anti-oxidation layer, first Protect the dielectric layer, remove the photoresist after etching;
    依次沉积第二磁性材料层、第二抗氧化材料层和第二保护介质材料层,旋涂光刻胶并进行光刻工艺,得到第二光刻图案;Sequentially depositing a second magnetic material layer, a second anti-oxidation material layer and a second protective medium material layer, spin-coating photoresist and performing a photolithography process to obtain a second photolithography pattern;
    按照第二光刻图案刻蚀所述第二磁性材料层、所述第二抗氧化材料层和所述第二保护介质材料层,形成第二磁性层和对应的第二抗氧化层、第二保护介质层,刻蚀后去除光刻胶。The second magnetic material layer, the second anti-oxidation material layer, and the second protective medium material layer are etched according to the second photolithography pattern to form a second magnetic layer and the corresponding second anti-oxidation layer, second Protect the dielectric layer, and remove the photoresist after etching.
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