WO2021000336A1 - Battery module - Google Patents
Battery module Download PDFInfo
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- WO2021000336A1 WO2021000336A1 PCT/CN2019/095252 CN2019095252W WO2021000336A1 WO 2021000336 A1 WO2021000336 A1 WO 2021000336A1 CN 2019095252 W CN2019095252 W CN 2019095252W WO 2021000336 A1 WO2021000336 A1 WO 2021000336A1
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- WO
- WIPO (PCT)
- Prior art keywords
- battery
- buffer
- cell
- gap
- buffer portion
- Prior art date
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
- H01M50/291—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by their shape
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/105—Pouches or flexible bags
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/107—Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/131—Primary casings; Jackets or wrappings characterised by physical properties, e.g. gas permeability, size or heat resistance
- H01M50/136—Flexibility or foldability
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/211—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for pouch cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/213—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/289—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs
- H01M50/293—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by spacing elements or positioning means within frames, racks or packs characterised by the material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- This application relates to the field of battery technology, and in particular to a battery module.
- the battery module includes a casing and a plurality of battery cells arranged in the casing.
- Each battery cell includes a battery cell.
- the cell includes an electrode assembly and a packaging bag covering the electrode assembly.
- the battery core has two opposite ends.
- the electrode assembly has a first pole piece and a second pole piece with opposite polarities.
- the electrode assembly may be formed by stacking the first pole piece, the second pole piece, and the separator together or spirally winding around the winding axis.
- the thickness of the first pole piece and the second pole piece near the edge is smaller than the thickness of the central area. Therefore, the gap between the first pole piece and the second pole piece of the electrode assembly at the end of the cell will become larger and larger than the gap between the first pole piece and the second pole piece in the center area of the cell, so that it is easy to Lithium evolution occurs at the end of the cell, which affects the cycle performance of the cell.
- the embodiments of the present application provide a battery module, which can effectively reduce the gap between the first pole piece and the second pole piece through a buffer pad, reduce the possibility of lithium evolution at the end of the battery cell, and improve the improvement The overall cycle performance of the battery module.
- an embodiment of the present application proposes a battery module, which includes:
- the battery cell includes a battery cell, the battery cell has two opposite ends along its own length direction, two or more battery cells are arranged side by side along the thickness direction of the battery cell, in two adjacent battery cells, A first gap is formed between the two cells that are close to each other.
- the first gap extends from one end in the length direction, and from the end to the center of the cell, the size of the first gap in the thickness direction is gradually reduced.
- Small buffer pad; wherein a buffer pad is arranged between two adjacent battery cells, the buffer pad is arranged in the first gap and is in contact with the end of the battery cell.
- the buffer pad includes a first buffer portion and a second buffer portion; along the thickness direction, one of the two ends of the battery is One buffer part is arranged in an arrangement, and the other end part is arranged in an arrangement with the second buffer part.
- the cushion pad further includes an intermediate portion, which is disposed between the first cushion portion and the second cushion portion and is in contact with the battery core.
- the surfaces of the first buffer portion, the second buffer portion, and the middle portion facing the battery core are connected to each other and transition smoothly, and/or the surface of the battery core forming the first gap is an arched surface, The surfaces of the first buffer portion, the second buffer portion and the middle portion facing the battery core are attached to the battery core.
- the first buffer part, the second buffer part and the intermediate part are an integrated structure.
- the end surface of the first buffer portion is aligned with the end surface of the battery cell, and/or, along the length direction, the end surface of the second buffer portion is aligned with the end surface of the battery core.
- the ratio of the size of the first buffer portion to the size of the battery core is 0.06 to 0.15, and/or the ratio of the size of the second buffer portion to the size of the battery core is 0.06 To 0.15;
- the size of the buffer pad and the battery core are equal.
- the battery cell includes an electrode assembly and a packaging bag, the electrode assembly is arranged in the packaging bag, and the electrode assembly includes a first pole piece and a second pole piece with opposite polarities, from the end to the battery core In the direction of the center, the thickness of the first pole piece and the second pole piece gradually increase.
- the battery module further includes a casing, the battery unit is arranged in the casing, and a second gap is formed between the battery cell near the casing and the casing, and the distance from the end to the center of the battery cell In the direction, the size of the second gap along the thickness direction is gradually reduced, and a buffer pad is arranged in the second gap, and the buffer pad is in contact with the end of the battery core.
- the battery unit includes more than two battery cells, and a rigid isolation component is arranged between two adjacent battery cells.
- the battery module according to the embodiment of the present application includes more than two battery units and a buffer pad arranged between two adjacent battery units.
- the buffer pad is arranged between the two battery cells.
- a first gap is formed between two adjacent battery cells.
- the buffer pad is arranged in the first gap and is in contact with the end of the battery core.
- the buffer pad provides support stress for the end of the battery cell, which can effectively reduce the gap between the first pole piece and the second pole piece, reduce the possibility of lithium evolution at the end of the battery cell, and improve the battery The overall cycle performance of the module.
- FIG. 1 is a schematic diagram of the overall structure of a battery module according to an embodiment of the present application
- Figure 2 is a schematic side view of the overall structure of a battery module according to an embodiment of the present application.
- Figure 3 is a schematic sectional view of the structure at A-A in Figure 2;
- FIG. 4 is a schematic side view of the structure of a battery core according to an embodiment of the present application.
- FIG. 5 is a schematic diagram of an axonometric structure of a battery core according to an embodiment of the present application.
- FIG. 6 is a schematic cross-sectional view of the structure of the first pole piece according to an embodiment of the present application.
- FIG. 7 is a schematic cross-sectional view of the structure of a second pole piece according to an embodiment of the present application.
- FIG. 8 is a schematic cross-sectional view of a partially laminated structure of the first pole piece, the diaphragm, and the second pole piece included in the battery cell of an embodiment of the present application;
- FIG. 9 is a partial schematic diagram of the distribution of battery cells in a battery module according to an embodiment of the present application.
- FIG. 10 is a schematic structural diagram of a buffer pad provided between battery cells in a battery module of an embodiment of the present application.
- 11 is a schematic diagram of the relationship between the number of battery cycles and the capacity retention rate of an embodiment of the present application.
- FIG. 12 is a schematic diagram of the relationship between the number of battery cycles and the expansion force of an embodiment of the present application.
- FIG. 13 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application.
- FIG. 14 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application.
- 15 is a partial schematic diagram of battery cell distribution in a battery module according to another embodiment of the present application.
- FIG. 16 is a schematic structural diagram of a buffer pad provided between battery cells in a battery module according to another embodiment of the present application.
- FIG. 17 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application.
- FIG. 18 is a partial schematic diagram of battery cell distribution in a battery module according to another embodiment of the present application.
- FIG. 19 is a schematic diagram of a structure in which a buffer pad is arranged between battery cells in a battery module according to another embodiment of the present application.
- X length direction
- Y thickness direction
- Z width direction
- connection should be understood in a broad sense unless otherwise clearly specified and limited. For example, they may be fixed connections or alternatively. Disassembly connection, or integral connection; it can be directly connected or indirectly connected through an intermediate medium. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in this application can be understood according to the specific circumstances.
- the battery module 10 of the embodiment of the present application includes a casing 20, two or more battery cells 30 arranged in the casing 20 and a buffer pad 40.
- the housing 20 has an accommodation space in which the battery unit 30 is accommodated.
- the casing 20 can protect the battery unit 30.
- the battery unit 30 includes a battery cell 31 and a fixed frame (not shown in the figure).
- the battery core 31 is connected to the fixed frame.
- the fixing frame is beneficial to improve the overall structural strength of the battery module 10.
- the battery core 31 of this embodiment is a flat structure as a whole, which has a predetermined thickness, length, and width.
- the cell 31 has two ends 31a facing each other along the length direction X of the cell. Each end 31a has an end surface 31b.
- the end portion 31a of the battery core 31 is thinner and flatter than the central area of the battery core 31.
- the cell 31 includes an electrode assembly 34 and a packaging bag 35.
- the packaging bag 35 has an accommodation space, and the main body of the electrode assembly 34 is accommodated in the packaging bag 35.
- the packaging bag 35 may be a soft shell.
- the packaging bag 35 can be made of aluminum plastic film or steel plastic film.
- the electrode assembly of this embodiment can be formed by stacking the first pole piece, the second pole piece, and the diaphragm together or spirally winding around the winding axis, wherein the diaphragm is between the first pole piece and the second pole piece. Between the insulators.
- the first pole piece is used as a positive electrode piece and the second pole piece is a negative electrode piece for illustration.
- the first pole piece may also be a negative pole piece, and the second pole piece is a positive pole piece.
- the positive sheet active material is coated on the coating area of the positive sheet
- the negative sheet active material is coated on the coating area of the negative sheet.
- the uncoated area extending from the coated area of the main body is used as the tab.
- the electrode assembly includes two tabs, namely the positive tab and the negative tab. The positive tab extends from the coating area of the positive tab, and the negative tab extends from the negative tab. The coating area extends out.
- the first pole piece 34a includes a first current collector 34aa and a first active material layer 34ab.
- the second pole piece 34c includes a second current collector 34ca and a second active material layer 34cb. Since the first pole piece 34a and the second pole piece 34c need to be cold pressed during the processing, the thickness of the first pole piece 34a and the second pole piece 34c after cold pressing is from the end 31a of the cell 31 to the electric The core 31 gradually increases in the direction of the center, so that the electrode assembly 34 formed by stacking or winding together the first pole piece 34a, the second pole piece 34c, and the diaphragm 34b of this embodiment has a thickness at both ends less than the center thickness.
- the overall battery core 31 also has a structure with a thickness at both ends less than the center thickness (see FIG. 4). As shown in FIG. 8, after the first pole piece 34a and the second pole piece 34c form the electrode assembly 34, the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the cell 31 will become larger. It is also larger than the gap between the first pole piece 34a and the second pole piece 34c in the central area of the cell 31.
- Two or more battery cells 30 are arranged side by side along the thickness direction Y of the battery core 31.
- the battery cell 31 of one battery unit 30 and the battery cell 31 of the other battery unit 30 are close to each other and are arranged opposite to each other.
- a first gap 32 is formed between the two cells 31 that are close to each other.
- the first gap 32 extends along the length direction X from one end portion 31a. From the end 31a of the cell 31 to the center of the cell 31, the size of the first gap 32 in the thickness direction Y gradually decreases, that is, from the end 31a of the cell 31 to the center of the cell 31, The size of a gap 32 in the thickness direction Y is changed from width to narrower.
- a buffer pad 40 is provided between two adjacent battery cells 30.
- the buffer pad 40 is disposed in the first gap 32 and is in contact with the end 31 a of the battery core 31.
- the end 31 a of the battery cell 31 is at least partially covered by the cushion 40.
- the cell 31 has two wide surfaces.
- the width direction Z the cell 31 has two narrow faces.
- the wide surface of one battery core 31 is arranged corresponding to the wide surface of the other battery core 31.
- the area where the wide surface of the cell 31 forms the first gap 32 is curved.
- the cushion 40 has elasticity.
- the material of the cushion pad 40 may be a material with cushioning properties such as silica gel or polyurethane.
- the battery module 10 of the embodiment of the present application includes more than two battery cells 30 and a buffer pad 40 arranged between two adjacent battery cells 30.
- the cushion pad 40 is disposed between the two battery cells 30.
- a first gap 32 is formed between two battery cells 31 close to each other.
- the buffer pad 40 is disposed in the first gap 32 and is in contact with the end 31 a of the battery core 31.
- the buffer pad 40 can provide supporting stress for the end 31a of the cell 31, thereby effectively reducing the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the cell 31, reducing the The possibility of lithium evolution at the end 31a of 31 is improved to improve the overall cycle performance of the battery module 10.
- the entire battery cell 31 may expand, and the end portion 31a of the battery cell 31 expands and exerts a pressing force on the cushion pad 40.
- the buffer pad 40 can exert a reaction force on the cells 31 to prevent the end 31a of the cells 31 from expanding to a large extent, thereby helping to ensure the power
- the degree of expansion of the end portion 31a of the core 31 and the degree of expansion of the central area of the cell 31 tend to coincide.
- the buffer pad 40 is added between the battery cells 30, which can effectively restrain the expansion of the end 31a, which is beneficial to reduce the possibility of lithium evolution caused by the excessive expansion of the end 31a, and reduce the possibility of the occurrence of lithium evolution.
- the possibility of structural damage such as cracks in the first pole piece 34a and/or the second pole piece 34c due to mutual extrusion of the core 31 can effectively improve the overall cycle performance of the battery module 10.
- the thickness of the buffer pad 40 is gradually reduced, so as to fit the first gap 32.
- the battery module 10 includes more than two battery cells 30.
- Each battery unit 30 includes two battery cells 31.
- a first gap 32 is formed between two adjacent battery cells 31 in two adjacent battery cells 30.
- the cushion pad 40 includes a first cushion portion 41 and a second cushion portion 42.
- the thickness direction Y one end 31a of the two end portions 31a of the cell 31 and the first buffer portion 41 are arranged mutually, and the other end 31a and the second buffer portion 42 are arranged mutually.
- a first buffer portion 41 and a second buffer portion 42 are respectively provided at both end portions 31a of the cell 31.
- the first buffer portion 41 and the second buffer portion 42 are spaced apart.
- the first buffer portion 41 and the second buffer portion 42 each provide support stress for the two end portions 31a of the cell 31, thereby effectively reducing the gap between the first pole piece 34a and the second pole piece 34c at the end of the cell 31 Gap at part 31a.
- the first buffer portion 41 and the second buffer portion 42 respectively apply a restraining stress to the two end portions 31a of the battery core 31 and act as a buffer to reduce the expansion of the end portion 31a of the battery core 31
- the degree of deformation is such that the expansion degree of the end portion 31a of the cell 31 and the expansion degree of the central area of the cell 31 tend to be consistent.
- the surface of each of the first buffer portion 41 and the second buffer portion 42 facing the cell 31 matches the shape of the surface of the cell 31.
- both the first buffer portion 41 and the second buffer portion 42 are solid structures.
- the wide surface of the cell 31 is arched.
- the surface of the first buffer portion 41 facing the battery core 31 and the surface of the second buffer portion 42 facing the battery core 31 are also arched, so as to match the shape of the wide surface.
- the first buffer portion 41 has an end surface facing outward and away from the second buffer portion 42
- the second buffer portion 42 has an end surface facing outward and away from the first buffer portion 41.
- the end surface of the first buffer portion 41 and the end surface 31b of the battery cell 31 are aligned with each other, so that the end portion 31a opposite to the first buffer portion 41 does not appear to be suspended, and the end surface of the battery cell 31 can be reduced.
- the portion 31a that is not covered by the first buffer portion 41 causes the possibility that the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the cell 31 cannot be reduced, and can also be reduced
- the portion of the end portion 31a of the battery cell 31 that is not covered by the first buffer portion 41 may cause the portion to expand too much.
- the end surface of the second buffer portion 42 and the end surface 31b of the cell 31 are aligned with each other, so that the end 31a opposite to the second buffer portion 42 does not appear to be suspended, which can reduce the loss of the end 31a of the cell 31.
- the part covered by the second buffering portion 42 causes the possibility that the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the cell 31 cannot be reduced, and can also reduce the risk of the cell 31
- the portion of the end portion 31a that is not covered by the second buffer portion 42 may cause the portion to expand too much.
- the end surface of one of the first buffer portion 41 and the second buffer portion 42 is aligned with the end surface 31 b of the cell 31.
- the ratio of the size of at least one of the first buffer portion 41 and the second buffer portion 42 to the length of the cell 31 is 0.06 to 0.15.
- the first buffer portion 41 and the second buffer portion 42 are both equal to the width dimension of the battery cell 31. In this way, both the first buffer portion 41 and the second buffer portion 42 can effectively cover the end 31a of the battery core 31, so as to provide a good support and buffer effect on the end 31a of the battery core 31, thereby facilitating the improvement of the battery core. The balance of the buffer stress on different areas of the end 31a of 31.
- the abscissa in the figure represents the number of cycles of the cell 31, and the ordinate represents the capacity retention rate of the cell 31.
- the cushion 40 includes a first cushion 41 and a second cushion 42. From the end 31a of the cell 31 to the center of the cell 31, the thickness of the first buffer portion 41 and the second buffer portion 42 gradually decrease, and each fits the first gap 32, so that the thickness direction Y There is no gap between the upper first buffer portion 41 and the second buffer portion 42 and the battery cell 31.
- the first buffer portion 41 and the second buffer portion 42 are both non-equal thickness structures. In the case where the first buffer portion 41 and the second buffer portion 42 are provided between two cells 31 close to each other, as the number of cycles increases, the capacity retention rate also shows a downward trend. However, when the first buffering portion 41 and the second buffering portion 42 are arranged between two cells 31 close to each other, the rate of decrease in the capacity retention rate is less than that when a buffer pad of equal thickness is provided between two cells 31 close to each other. The rate of decrease in capacity retention. When the first buffer portion 41 and the second buffer portion 42 are arranged between two battery cells 31 that are close to each other, the overall cycle performance of the battery cells 31 can be improved.
- the abscissa in the figure represents the number of cycles of the cell 31, and the ordinate represents the expansion force of the cell 31.
- the cushion 40 includes a first cushion 41 and a second cushion 42.
- the thickness of the first buffer portion 41 and the second buffer portion 42 gradually decreases, which is adapted to the first gap 32.
- the first buffer portion 41 and the second buffer portion 42 are both non-equal thickness structures.
- the expansion force of each cell 31 also shows an increasing trend.
- the rate of increase of the expansion force of each cell 31 is less than that between two cells 31 that are close to each other.
- the rising rate of the expansion force of each cell 31 when the cushion is thick.
- the cycle performance is improved, and it is better than the cycle when a buffer pad of equal thickness is set between two cells 31 close to each other performance.
- the arrangement of the first buffer portion 41 and the second buffer portion 42 between the two cells 31 that are close to each other can help reduce the expansion force of the cell 31 after the number of cycles reaches a predetermined value.
- the cushion 40 further includes a middle portion 43.
- the intermediate portion 43 is disposed between the first buffer portion 41 and the second buffer portion 42 and is in contact with the battery core 31.
- the dotted lines in FIGS. 13 and 14 are only used to schematically distinguish the first buffer portion 41, the middle portion 43 and the second buffer portion 42, and do not correspond to the structure of the first buffer portion 41, the middle portion 43 and the second buffer portion 42 or other parts. Form a limit.
- the first buffer portion 41 and the second buffer portion 42 can support and buffer the end 31a of the battery core 31, and the middle portion 43 can support and buffer the end portion 31a of the battery core 31.
- the intermediate area between the end portions 31a plays a supporting and buffering role. In this way, it is possible to ensure that the forces on each area of the entire battery cell 31 are more uniform and balanced, which is beneficial to ensure that the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the battery core 31 and the first pole piece 34a and The gaps of the second pole pieces 34c in the central area of the cell 31 tend to be consistent, which is also beneficial to ensure that the expansion degree of the end 31a of the cell 31 and the expansion degree of the central area of the cell 31 tend to be the same, thereby further improving and Improve the cycle performance of the battery cell 31.
- the surface of the middle portion 43 facing the cell 31 matches the shape of the surface of the cell 31.
- the middle part 43 is a solid structure.
- the surfaces of the first buffer portion 41, the second buffer portion 42 and the intermediate portion 43 each facing the battery core 31 are attached to the surface of the battery core 31, preferably in complete contact.
- the first buffer portion 41, the second buffer portion 42 and the middle portion 43 are connected to each other towards the surface of the cell 31 and transition smoothly, thereby reducing the stress concentration area generated by the buffer portion on the surface of the cell 31 and causing damage to the structure of the cell 31 Possibility.
- the first buffer portion 41, the second buffer portion 42 and the intermediate portion 43 may be split structures.
- the first buffer portion 41, the second buffer portion 42 and the intermediate portion 43 may also be an integrated structure.
- a second gap 33 is formed between the battery cell 31 near the casing 20 and the casing 20 in the battery unit 30.
- the size of the second gap 33 in the thickness direction Y gradually decreases, that is, the direction from the end 31a of the cell 31 to the center of the cell 31 .
- the size of the second gap 33 along the thickness direction Y is narrowed from width.
- a cushion 40 is provided in the second gap 33.
- the cushion pad 40 is in contact with the end 31 a of the battery cell 31.
- the second gap 33 is provided through.
- the cushion 40 includes a first cushion 41 and a second cushion 42.
- the first buffer portion 41 is provided between one end 31 a of the battery core 31 and the housing 20, and the second buffer portion 42 is provided between the other end 31 a of the battery core 31 and the housing 20. Both the first buffer portion 41 and the second buffer portion 42 can support the end 31a of the battery core 31, and are also used to buffer the expansion and deformation of the end 31a of the battery core 31, so as to ensure that the entire battery cell 31 close to the housing 20 is exposed to various areas. The force is more uniform and balanced, which is beneficial to further enhance and improve the cycle performance of the cell 31. Further optionally, referring to FIG. 13 or FIG. 14, the cushion pad 40 includes a first cushion portion 41, a middle portion 43 and a second cushion portion 42.
- the intermediate portion 43 is arranged between the first buffer portion 41 and the second buffer portion 42, which helps to ensure that the gap between the first pole piece 34a and the second pole piece 34c at the end 31a of the cell 31 and the first pole piece
- the gap between each of the 34a and the second pole piece 34c in the central area of the cell 31 tends to be the same, which also helps to ensure that the expansion degree of the end 31a of the cell 31 and the expansion degree of the central area of the cell 31 tend to be consistent, thereby further Enhance and improve the cycle performance of the cell 31.
- the battery unit 30 includes more than two battery cells 31. More than two batteries 31 are arranged in a fixed frame.
- a rigid isolation member 50 is provided between two adjacent battery cells 31.
- the rigid isolation member 50 may be an aluminum plate.
- the rigid isolation member 50 can reduce the adjacent two electric The core 31 may squeeze each other due to expansion and deformation, causing structural damage to the first pole piece 34a and the second pole piece 34c.
- the rigid isolation component 50 can be made of a material with thermal conductivity, which can facilitate the heat dissipation of the battery core 31 through the rigid isolation component 50.
- the number of the first gap 32 is two. Two first gaps 32 are formed between the two end portions 31a of two adjacent cells 31, and the central regions of two adjacent cells 31 are in contact with each other so that the two first gaps 32 are not in the length direction X. Connected. A cushion 40 is provided in each first gap 32.
- each battery unit 30 includes a battery cell 31.
- One battery core 31 is arranged in a fixed frame.
- a first gap 32 is formed between two adjacent cells 31.
- Two adjacent battery cells 31 are provided with buffer pads 40.
- the cushion 40 includes a first cushion 41 and a second cushion 42.
- the first buffer portion 41 and the second buffer portion 42 are arranged at intervals along the longitudinal direction X.
- the cushion pad 40 further includes a middle portion 43.
- the first buffer portion 41, the middle portion 43, and the second buffer portion 42 are sequentially arranged along the length direction X and connected to each other.
- the first buffer portion 41, the intermediate portion 43, and the second buffer portion 42 may have a separate structure or an integrally formed structure.
- the dotted line in FIG. 17 is only used to schematically distinguish the first buffer portion 41, the middle portion 43 and the second buffer portion 42, and does not limit the structure of the first buffer portion 41, the middle portion 43 and the second buffer portion 42 or other components.
- two tabs are led out from one end surface 31 b of the battery core 31.
- a first gap 32 is formed between one end 31a of each of two adjacent battery cells 31, and the other end 31a of each is in contact with each other.
- the number of the first gap 32 is one.
- the first gap 32 does not penetrate in the longitudinal direction X.
- a cushion 40 is provided in the first gap 32. The cushion 40 is in contact with the end 31a of the cell 31
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Abstract
Description
相关申请的交叉引用Cross references to related applications
本申请要求享有于2019年07月04日提交的名称为“电池模组”的中国专利申请201921040744.0的优先权,该申请的全部内容通过引用并入本文中。This application claims the priority of the Chinese patent application 201921040744.0 named "Battery Module" filed on July 4, 2019, the entire content of which is incorporated herein by reference.
本申请涉及电池技术领域,特别是涉及一种电池模组。This application relates to the field of battery technology, and in particular to a battery module.
随着科学技术的发展和进步,二次电池的应用范围越来越广,例如二次电池可以应用于电动车、储能等领域。电池模组包括壳体和设置于壳体内的多个电池单元。每个电池单元包括电芯。电芯包括电极组件以及包覆电极组件的包装袋。电芯具有相对的两个端部。电极组件具有极性相反的第一极片和第二极片。电极组件可通过将第一极片、第二极片以及隔膜一同堆叠或围绕卷绕轴线螺旋卷绕而形成。第一极片和第二极片经过冷压处理后,第一极片和第二极片自身靠近边缘的厚度小于中心区域的厚度。所以电极组件的第一极片和第二极片各自在电芯的端部处的间隙会变大,并且大于第一极片和第二极片各自在电芯的中心区域的间隙,从而容易在电芯的端部处出现析锂现象,影响电芯循环性能。With the development and progress of science and technology, the application range of secondary batteries is becoming wider and wider. For example, secondary batteries can be applied to electric vehicles, energy storage and other fields. The battery module includes a casing and a plurality of battery cells arranged in the casing. Each battery cell includes a battery cell. The cell includes an electrode assembly and a packaging bag covering the electrode assembly. The battery core has two opposite ends. The electrode assembly has a first pole piece and a second pole piece with opposite polarities. The electrode assembly may be formed by stacking the first pole piece, the second pole piece, and the separator together or spirally winding around the winding axis. After the first pole piece and the second pole piece are cold-pressed, the thickness of the first pole piece and the second pole piece near the edge is smaller than the thickness of the central area. Therefore, the gap between the first pole piece and the second pole piece of the electrode assembly at the end of the cell will become larger and larger than the gap between the first pole piece and the second pole piece in the center area of the cell, so that it is easy to Lithium evolution occurs at the end of the cell, which affects the cycle performance of the cell.
发明内容Summary of the invention
本申请实施例提供一种电池模组,能够通过缓冲垫有效减小第一极片和第二极片之间的间隙,降低在电芯的端部处出现析锂现象的可能性,提升改善电池模组整体循环性能。The embodiments of the present application provide a battery module, which can effectively reduce the gap between the first pole piece and the second pole piece through a buffer pad, reduce the possibility of lithium evolution at the end of the battery cell, and improve the improvement The overall cycle performance of the battery module.
一方面,本申请实施例提出了一种电池模组,其包括:On the one hand, an embodiment of the present application proposes a battery module, which includes:
两个以上的电池单元,电池单元包括电芯,电芯具有沿自身长度方向相对的两个端部,两个以上的电池单元沿电芯的厚度方向并排设置,相邻两个电池单元中,相互 靠近的两个电芯之间形成有第一间隙,第一间隙从一个端部起始沿长度方向延伸,从端部至电芯的中心的方向,第一间隙沿厚度方向的尺寸逐渐减小;缓冲垫;其中,相邻两个电池单元之间设有缓冲垫,缓冲垫设置于第一间隙内,并与电芯的端部接触。Two or more battery cells, the battery cell includes a battery cell, the battery cell has two opposite ends along its own length direction, two or more battery cells are arranged side by side along the thickness direction of the battery cell, in two adjacent battery cells, A first gap is formed between the two cells that are close to each other. The first gap extends from one end in the length direction, and from the end to the center of the cell, the size of the first gap in the thickness direction is gradually reduced. Small; buffer pad; wherein a buffer pad is arranged between two adjacent battery cells, the buffer pad is arranged in the first gap and is in contact with the end of the battery cell.
根据本申请实施例的一个方面,沿长度方向,第一间隙贯通设置,缓冲垫包括第一缓冲部和第二缓冲部;沿厚度方向,电芯的两个端部中的一个端部与第一缓冲部排布设置,另一个端部与第二缓冲部排布设置。According to one aspect of the embodiments of the present application, along the length direction, the first gap is penetrated, and the buffer pad includes a first buffer portion and a second buffer portion; along the thickness direction, one of the two ends of the battery is One buffer part is arranged in an arrangement, and the other end part is arranged in an arrangement with the second buffer part.
根据本申请实施例的一个方面,缓冲垫还包括中间部,中间部设置于第一缓冲部和第二缓冲部之间并与电芯接触。According to one aspect of the embodiments of the present application, the cushion pad further includes an intermediate portion, which is disposed between the first cushion portion and the second cushion portion and is in contact with the battery core.
根据本申请实施例的一个方面,第一缓冲部、第二缓冲部和中间部各自朝向电芯的表面相互连接并且光滑过渡,和/或,电芯形成第一间隙的表面为拱形面,第一缓冲部、第二缓冲部和中间部各自朝向电芯的表面与电芯相贴合。According to an aspect of the embodiments of the present application, the surfaces of the first buffer portion, the second buffer portion, and the middle portion facing the battery core are connected to each other and transition smoothly, and/or the surface of the battery core forming the first gap is an arched surface, The surfaces of the first buffer portion, the second buffer portion and the middle portion facing the battery core are attached to the battery core.
根据本申请实施例的一个方面,第一缓冲部、第二缓冲部和中间部为一体式结构。According to one aspect of the embodiments of the present application, the first buffer part, the second buffer part and the intermediate part are an integrated structure.
根据本申请实施例的一个方面,沿长度方向,第一缓冲部的端面和电芯的端面相对齐,和/或,沿长度方向,第二缓冲部的端面和电芯的端面相对齐。According to one aspect of the embodiment of the present application, along the length direction, the end surface of the first buffer portion is aligned with the end surface of the battery cell, and/or, along the length direction, the end surface of the second buffer portion is aligned with the end surface of the battery core.
根据本申请实施例的一个方面,沿长度方向,第一缓冲部的尺寸与电芯的尺寸的比值为0.06至0.15,和/或,第二缓冲部的尺寸与电芯的尺寸的比值为0.06至0.15;According to one aspect of the embodiments of the present application, along the length direction, the ratio of the size of the first buffer portion to the size of the battery core is 0.06 to 0.15, and/or the ratio of the size of the second buffer portion to the size of the battery core is 0.06 To 0.15;
或者,沿电芯的宽度方向,缓冲垫与电芯的尺寸相等。Or, along the width direction of the battery core, the size of the buffer pad and the battery core are equal.
根据本申请实施例的一个方面,电芯包括电极组件和包装袋,电极组件设置于包装袋内,电极组件包括极性相反的第一极片和第二极片,从端部至电芯的中心的方向上,第一极片和第二极片的厚度均逐渐增大。According to one aspect of the embodiments of the present application, the battery cell includes an electrode assembly and a packaging bag, the electrode assembly is arranged in the packaging bag, and the electrode assembly includes a first pole piece and a second pole piece with opposite polarities, from the end to the battery core In the direction of the center, the thickness of the first pole piece and the second pole piece gradually increase.
根据本申请实施例的一个方面,电池模组还包括外壳,电池单元设置于外壳内,电池单元中靠近外壳的电芯与外壳之间形成第二间隙,在从端部至电芯的中心的方向上,第二间隙沿厚度方向的尺寸逐渐减小,第二间隙内设有缓冲垫,缓冲垫与电芯的端部接触。According to one aspect of the embodiments of the present application, the battery module further includes a casing, the battery unit is arranged in the casing, and a second gap is formed between the battery cell near the casing and the casing, and the distance from the end to the center of the battery cell In the direction, the size of the second gap along the thickness direction is gradually reduced, and a buffer pad is arranged in the second gap, and the buffer pad is in contact with the end of the battery core.
根据本申请实施例的一个方面,电池单元包括两个以上的电芯,相邻两个电芯之间设置刚性隔离部件。According to one aspect of the embodiments of the present application, the battery unit includes more than two battery cells, and a rigid isolation component is arranged between two adjacent battery cells.
根据本申请实施例的电池模组,包括两个以上的电池单元以及设置于相邻两个电池单元之间的缓冲垫。沿厚度方向,缓冲垫设置于两个电池单元之间。相邻两个电池 单元中,相互靠近的两个电芯之间形成有第一间隙。缓冲垫设置于第一间隙内并与电芯的端部接触。缓冲垫为电芯的端部提供支承应力,从而可以有效减小第一极片和第二极片之间的间隙,降低在电芯的端部处出现析锂现象的可能性,提升改善电池模组整体循环性能。The battery module according to the embodiment of the present application includes more than two battery units and a buffer pad arranged between two adjacent battery units. Along the thickness direction, the buffer pad is arranged between the two battery cells. In two adjacent battery cells, a first gap is formed between two adjacent battery cells. The buffer pad is arranged in the first gap and is in contact with the end of the battery core. The buffer pad provides support stress for the end of the battery cell, which can effectively reduce the gap between the first pole piece and the second pole piece, reduce the possibility of lithium evolution at the end of the battery cell, and improve the battery The overall cycle performance of the module.
下面将通过参考附图来描述本申请示例性实施例的特征、优点和技术效果。The features, advantages, and technical effects of exemplary embodiments of the present application will be described below with reference to the drawings.
图1是本申请一实施例的电池模组整体结构示意图;FIG. 1 is a schematic diagram of the overall structure of a battery module according to an embodiment of the present application;
图2是本申请一实施例的电池模组整体侧视结构示意图;Figure 2 is a schematic side view of the overall structure of a battery module according to an embodiment of the present application;
图3是图2中A-A处剖视结构示意图;Figure 3 is a schematic sectional view of the structure at A-A in Figure 2;
图4是本申请一实施例的电芯的侧视结构示意图;4 is a schematic side view of the structure of a battery core according to an embodiment of the present application;
图5是本申请一实施例的电芯的轴测结构示意图;FIG. 5 is a schematic diagram of an axonometric structure of a battery core according to an embodiment of the present application;
图6是本申请一实施例的第一极片的结构横截面示意图;6 is a schematic cross-sectional view of the structure of the first pole piece according to an embodiment of the present application;
图7是本申请一实施例的第二极片的结构横截面示意图;7 is a schematic cross-sectional view of the structure of a second pole piece according to an embodiment of the present application;
图8是本申请一实施例的电芯所包括的第一极片、隔膜和第二极片局部层叠结构的横截面示意图;8 is a schematic cross-sectional view of a partially laminated structure of the first pole piece, the diaphragm, and the second pole piece included in the battery cell of an embodiment of the present application;
图9是本申请一实施例的电池模组中电池单元分布的局部示意图;9 is a partial schematic diagram of the distribution of battery cells in a battery module according to an embodiment of the present application;
图10是本申请一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图;FIG. 10 is a schematic structural diagram of a buffer pad provided between battery cells in a battery module of an embodiment of the present application;
图11是本申请一实施例的电芯循环次数与容量保持率关系示意图;11 is a schematic diagram of the relationship between the number of battery cycles and the capacity retention rate of an embodiment of the present application;
图12是本申请一实施例的电芯循环次数与膨胀力关系示意图;FIG. 12 is a schematic diagram of the relationship between the number of battery cycles and the expansion force of an embodiment of the present application;
图13是本申请另一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图;FIG. 13 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application;
图14是本申请又一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图;14 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application;
图15是本申请另一实施例的电池模组中电池单元分布的局部示意图;15 is a partial schematic diagram of battery cell distribution in a battery module according to another embodiment of the present application;
图16是本申请又一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图;FIG. 16 is a schematic structural diagram of a buffer pad provided between battery cells in a battery module according to another embodiment of the present application;
图17是本申请又一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图;FIG. 17 is a schematic structural diagram of a buffer pad disposed between battery cells in a battery module according to another embodiment of the present application;
图18是本申请又一实施例的电池模组中电池单元分布的局部示意图;18 is a partial schematic diagram of battery cell distribution in a battery module according to another embodiment of the present application;
图19是本申请又一实施例的电池模组中电池单元之间设置缓冲垫的结构示意图。FIG. 19 is a schematic diagram of a structure in which a buffer pad is arranged between battery cells in a battery module according to another embodiment of the present application.
在附图中,附图未必按照实际的比例绘制。In the drawings, the drawings may not be drawn to actual scale.
标记说明:Mark description:
10、电池模组;10. Battery module;
20、外壳;20. Shell;
30、电池单元;31、电芯;31a、端部;31b、端面;32、第一间隙;33、第二间隙;34、电极组件;34a、第一极片;34aa、第一集流体;34ab、第一活性物质层;34b、隔膜;34c、第二极片;34ca、第二集流体;34cb、第二活性物质层;35、包装袋;30. Battery cell; 31. Cell; 31a, end; 31b, end face; 32, first gap; 33, second gap; 34, electrode assembly; 34a, first pole piece; 34aa, first current collector; 34ab, the first active material layer; 34b, the diaphragm; 34c, the second pole piece; 34ca, the second current collector; 34cb, the second active material layer; 35, the packaging bag;
40、缓冲垫;41、第一缓冲部;42、第二缓冲部;43、中间部;40. Cushion pad; 41. First buffer part; 42, second buffer part; 43. Middle part;
50、刚性隔离部件;50. Rigid isolation parts;
X、长度方向;Y、厚度方向;Z、宽度方向。X, length direction; Y, thickness direction; Z, width direction.
下面结合附图和实施例对本申请的实施方式作进一步详细描述。以下实施例的详细描述和附图用于示例性地说明本申请的原理,但不能用来限制本申请的范围,即本申请不限于所描述的实施例。The implementation of the present application will be described in further detail below in conjunction with the drawings and embodiments. The detailed description and drawings of the following embodiments are used to exemplarily illustrate the principles of the application, but cannot be used to limit the scope of the application, that is, the application is not limited to the described embodiments.
在本申请的描述中,需要说明的是,除非另有说明,“多个”的含义是两个以上;术语“上”、“下”、“左”、“右”、“内”、“外”等指示的方位或位置关系仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本申请的限制。此外,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性。In the description of this application, it should be noted that, unless otherwise specified, "plurality" means two or more; the terms "upper", "lower", "left", "right", "inner", and " The orientation or positional relationship indicated by “outside” is only for the convenience of describing the application and simplifying the description, and does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a reference to the present application. Application restrictions. In addition, the terms "first", "second", etc. are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance.
在本申请的描述中,还需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连。对于本领域的普通技术人员而言,可视具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that the terms "installation", "connection", and "connection" should be understood in a broad sense unless otherwise clearly specified and limited. For example, they may be fixed connections or alternatively. Disassembly connection, or integral connection; it can be directly connected or indirectly connected through an intermediate medium. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in this application can be understood according to the specific circumstances.
为了更好地理解本申请,下面结合图1至图19对本申请实施例进行描述。In order to better understand the present application, the following describes the embodiments of the present application in conjunction with FIG. 1 to FIG. 19.
参见图1至图3所示,本申请实施例的电池模组10包括外壳20、设置于外壳20内的两个以上的电池单元30和缓冲垫40。As shown in FIGS. 1 to 3, the
外壳20具有容纳电池单元30的容纳空间。外壳20可以对电池单元30起到保护作用。电池单元30包括电芯31和固定框(图中未标出)。电芯31连接于固定框。固定框有利于提高电池模组10的整体结构强度。The
参见图4和图5所示,本实施例的电芯31整体为扁平状结构,其具有预定的厚度、长度和宽度。电芯31具有沿自身长度方向X相对的两个端部31a。各个端部31a具有端面31b。电芯31的端部31a相比于电芯31的中心区域偏薄,更加扁平。电芯31包括电极组件34和包装袋35。包装袋35具有容纳空间,而电极组件34的主体容纳于包装袋35内。包装袋35可以是软壳。可选地,包装袋35可以选用铝塑膜、钢塑膜加工制造而成。本实施例的电极组件可通过将第一极片、第二极片以及隔膜一同堆叠或围绕卷绕轴线螺旋卷绕而形成主体,其中,隔膜是介于第一极片和第二极片之间的绝缘体。在本实施例中,示例性地以第一极片为正极片,第二极片为负极片进行说明。同样地,在其他的实施例中,第一极片还可以为负极片,而第二极片为正极片。另外,正极片活性物质被涂覆在正极片的涂覆区上,而负极片活性物质被涂覆到负极片的涂覆区上。由主体的涂覆区延伸出的未涂覆区则作为极耳,电极组件包括两个极耳,即正极耳和负极耳,正极耳从正极片的涂覆区延伸出,负极耳从负极片的涂覆区延伸出。Referring to FIG. 4 and FIG. 5, the
参见图6和图7所示,第一极片34a包括第一集流体34aa和第一活性物质层34ab。第二极片34c包括第二集流体34ca和第二活性物质层34cb。由于第一极片34a和第二极片34c加工过程中需要经过冷压处理,因此冷压后的第一极片34a和第二极片34c整体的厚度从电芯31的端部31a至电芯31的中心的方向上逐渐增大,从而在使用本实施例的第一极片34a、第二极片34c和隔膜34b共同堆叠或卷绕形成的电极组件34整体呈两端厚度小于中心厚度的结构,进而使得电芯31整体也呈两端厚度小于中心厚度的结构(参见图4所示)。参见图8所示,第一极片34a和第二极片34c形成电极组件34后,第一极片34a和第二极片34c各自在电芯31的端部31a处的间隙会变大,并且大于第一极片34a和第二极片34c各自在电芯31的中心区域的间隙。6 and 7, the
两个以上的电池单元30沿电芯31的厚度方向Y并排设置。相邻两个电池单元30中,一个电池单元30中的电芯31与另一个电池单元30的电芯31相互靠近,彼此相对设置。相互靠近的两个电芯31之间形成有第一间隙32。第一间隙32从一个端部31a起始沿长度方向X延伸。从电芯31的端部31a至电芯31的中心的方向,第一间隙32沿厚度方向Y的尺寸逐渐减小,即从电芯31的端部31a至电芯31的中心的方向,第一间隙32沿厚度方向Y的尺寸由宽变窄。相邻两个电池单元30之间设有缓冲垫40。缓冲垫40设置于第一间隙32内并与电芯31的端部31a接触。电芯31的端部31a 至少部分地被缓冲垫40覆盖。沿厚度方向Y,电芯31具有两个宽面。沿宽度方向Z,电芯31具有两个窄面。相邻两个电芯31中,一个电芯31的宽面与另一个电芯31的宽面相对应设置。电芯31的宽面形成第一间隙32的区域呈曲面。缓冲垫40具有弹性。可选地,缓冲垫40的材料可以是硅胶或聚氨酯等具有缓冲性能的材料。Two or
本申请实施例的电池模组10,包括两个以上的电池单元30以及设置于相邻两个电池单元30之间的缓冲垫40。沿厚度方向Y,缓冲垫40设置于两个电池单元30之间。相邻两个电池单元30中,相互靠近的两个电芯31之间形成有第一间隙32。缓冲垫40设置于第一间隙32内并与电芯31的端部31a接触。缓冲垫40可以为电芯31的端部31a提供支承应力,从而可以有效减小第一极片34a和第二极片34c之间在电芯31的端部31a处的间隙,降低在电芯31的端部31a处出现析锂现象的可能性,提升改善电池模组10整体循环性能。The
另外,在电芯31循环过程中,电芯31整体存在发生膨胀的情况,电芯31的端部31a发生膨胀后会对缓冲垫40施加挤压力。在缓冲垫40被两侧的电芯31共同挤压压缩时,缓冲垫40可以对电芯31施加反作用力,以阻止电芯31的端部31a发生较大程度的膨胀,从而有利于保证电芯31的端部31a的膨胀程度与电芯31的中心区域的膨胀程度趋于一致。这样,在电池单元30之间增加设置缓冲垫40,可以有效约束端部31a膨胀,有利于降低因端部31a产生过大程度膨胀而导致出现析锂现象的可能性,降低相邻两个电芯31因相互挤压而导致第一极片34a和/或第二极片34c出现裂纹等结构性损坏的可能性,有效提升改善电池模组10整体循环性能。In addition, during the cycle of the
在一个实施例中,从电芯31的端部31a至电芯31的中心的方向上,缓冲垫40的厚度逐渐减小,从而与第一间隙32相适配。In one embodiment, in the direction from the
在一个实施例中,参见图9所示,电池模组10包括两个以上的电池单元30。每个电池单元30包括两个电芯31。相邻两个电池单元30中相互靠近的两个电芯31之间间隔形成第一间隙32。沿长度方向X,第一间隙32贯通设置。参见图10所示,缓冲垫40包括第一缓冲部41和第二缓冲部42。沿厚度方向Y,电芯31的两个端部31a中的一个端部31a与第一缓冲部41相互排布设置,另一个端部31a与第二缓冲部42相互排布设置。在电芯31的两个端部31a分别设有第一缓冲部41和第二缓冲部42。第一缓冲部41和第二缓冲部42间隔设置。第一缓冲部41和第二缓冲部42各自为电芯31的两个端部31a提供支承应力,从而可以有效减小第一极片34a和第二极片34c之间 在电芯31的端部31a处的间隙。在电芯31发生膨胀变形时,第一缓冲部41和第二缓冲部42分别对电芯31的两个端部31a施加约束应力并起到缓冲作用,降低电芯31的端部31a的膨胀变形程度,以使电芯31的端部31a的膨胀程度与电芯31中心区域的膨胀程度趋于一致。第一缓冲部41和第二缓冲部42各自朝向电芯31的表面与电芯31的表面形状相匹配。可选地,第一缓冲部41和第二缓冲部42均为实心结构体。In one embodiment, referring to FIG. 9, the
在一个实施例中,电芯31的宽面呈拱形。第一缓冲部41朝向电芯31的表面以及第二缓冲部42朝向电芯31的表面也呈拱形,从而与宽面形状相匹配贴合。沿长度方向X,第一缓冲部41具有朝向外侧且远离第二缓冲部42的端面,而第二缓冲部42具有朝向外侧且远离第一缓冲部41的端面。沿长度方向X,第一缓冲部41的端面与电芯31的端面31b相互对齐,从而使得与第一缓冲部41相对设置的端部31a不会出现悬空情况,可以降低因电芯31的端部31a上未被第一缓冲部41覆盖的部分而导致第一极片34a和第二极片34c之间在电芯31的端部31a处的间隙不能被减小的可能性,也可以降低因电芯31的端部31a上未被第一缓冲部41覆盖的部分而导致该部分膨胀程度过大的可能性。第二缓冲部42的端面与电芯31的端面31b相互对齐,从而使得与第二缓冲部42相对设置的端部31a不会出现悬空情况,可以降低因电芯31的端部31a上未被第二缓冲部42覆盖的部分而导致第一极片34a和第二极片34c之间在电芯31的端部31a处的间隙不能被减小的可能性,也可以降低因电芯31的端部31a上未被第二缓冲部42覆盖的部分而导致该部分膨胀程度过大的可能性。在另一个示例中,第一缓冲部41和第二缓冲部42中的一者的端面与电芯31的端面31b相对齐。In one embodiment, the wide surface of the
在一个实施例中,沿长度方向X,第一缓冲部41和第二缓冲部42中至少一者的尺寸与电芯31的长度尺寸的比值为0.06至0.15。沿电芯31的宽度方向Z,第一缓冲部41和第二缓冲部42均与电芯31的宽度尺寸相等。这样,第一缓冲部41和第二缓冲部42均能够有效覆盖电芯31的端部31a,以对电芯31的端部31a起到良好的支承作用和缓冲作用,从而有利于提升电芯31的端部31a不同区域所受缓冲应力的均衡性。In one embodiment, along the length direction X, the ratio of the size of at least one of the
参见图11所示,图中横坐标表示电芯31循环次数,纵坐标表示电芯31容量保持率。在两个相互靠近的电芯31之间设置一个整体等厚缓冲垫的情况下,随着循环次数的增加,容量保持率呈现下降趋势。在一个实施例中,参见图10所示,缓冲垫40包括第一缓冲部41和第二缓冲部42。从电芯31的端部31a至电芯31的中心的方向上,第一缓冲部41和第二缓冲部42的厚度逐渐减小,各自与第一间隙32相适配,从而在 厚度方向Y上第一缓冲部41和第二缓冲部42和电芯31之间贴合无间隙。第一缓冲部41和第二缓冲部42均为非等厚结构体。在两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42的情况下,随着循环次数的增加,容量保持率也呈现下降趋势。但是,两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42时,容量保持率的下降速率小于两个相互靠近的电芯31之间设置等厚缓冲垫时的容量保持率的下降速率。两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42时,电芯31整体循环性能可以得到改善。Referring to FIG. 11, the abscissa in the figure represents the number of cycles of the
参见图12所示,图中横坐标表示电芯31循环次数,纵坐标表示电芯31的膨胀力。在两个相互靠近的电芯31之间设置一个整体等厚缓冲垫的情况下,随着循环次数的增加,每个电芯31的膨胀力呈现增大趋势。在一个实施例中,参见图10所示,缓冲垫40包括第一缓冲部41和第二缓冲部42。从电芯31的端部31a至电芯31的中心的方向上,第一缓冲部41和第二缓冲部42的厚度逐渐减小,与第一间隙32相适配。第一缓冲部41和第二缓冲部42均为非等厚结构体。在两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42的情况下,随着循环次数的增加,每个电芯31的膨胀力也呈现增大趋势。但是,两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42时,每个电芯31的膨胀力的上升速率小于两个相互靠近的电芯31之间设置等厚缓冲垫时的每个电芯31的膨胀力的上升速率。两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42时,循环性能得到改善,并且优于两个相互靠近的电芯31之间设置等厚缓冲垫时的循环性能。两个相互靠近的电芯31之间设置第一缓冲部41和第二缓冲部42,可以有利于在循环次数达到预定值后降低电芯31的膨胀力。Referring to FIG. 12, the abscissa in the figure represents the number of cycles of the
在一个实施例中,参见图13或图14所示,缓冲垫40还包括中间部43。中间部43设置于第一缓冲部41和第二缓冲部42之间并与电芯31接触。图13和图14中虚线仅用于示意区分第一缓冲部41、中间部43和第二缓冲部42,不对第一缓冲部41、中间部43和第二缓冲部42或其它零部件的结构形成限定。在电芯31循环过程发生膨胀时,第一缓冲部41和第二缓冲部42可以对电芯31的端部31a起到支承和缓冲作用,而中间部43可以对电芯31上处于两个端部31a之间的中间区域起到支承和缓冲作用。这样,可以保证整个电芯31各个区域受力更加均匀、平衡,有利于保证第一极片34a和第二极片34c各自在电芯31的端部31a处的间隙与第一极片34a和第二极片34c各自在电芯31的中心区域的间隙趋于一致,也有利于保证电芯31的端部31a的膨 胀程度与电芯31中心区域的膨胀程度趋于一致,从而进一步提升和改善电芯31循环性能。中间部43朝向电芯31的表面与电芯31的表面形状相匹配。可选地,中间部43为实心结构体。In an embodiment, referring to FIG. 13 or FIG. 14, the
第一缓冲部41、第二缓冲部42和中间部43各自朝向电芯31的表面均与电芯31的表面相互贴合,优选为完全贴合接触。第一缓冲部41、第二缓冲部42和中间部43各自朝向电芯31的表面相互连接并且光滑过渡,从而降低缓冲部对电芯31的表面产生应力集中区域而导致电芯31结构发生损坏的可能性。参见图13所示,第一缓冲部41、第二缓冲部42和中间部43可以为分体式结构。参见图14所示,第一缓冲部41、第二缓冲部42和中间部43也可以为一体式结构。The surfaces of the
参见图9所示,电池单元30中靠近外壳20的电芯31与外壳20之间形成第二间隙33。在从电芯31的端部31a至电芯31的中心的方向上,第二间隙33沿厚度方向Y的尺寸逐渐减小,即从电芯31的端部31a至电芯31的中心的方向,第二间隙33沿厚度方向Y的尺寸由宽变窄。第二间隙33内设有缓冲垫40。缓冲垫40与电芯31的端部31a接触。在一个示例中,沿长度方向X,第二间隙33贯通设置。可选地,参见图10所示,缓冲垫40包括第一缓冲部41和第二缓冲部42。第一缓冲部41设置于电芯31的一个端部31a和外壳20之间,而第二缓冲部42设置于电芯31的另一个端部31a和外壳20之间。第一缓冲部41和第二缓冲部42均可以支承电芯31的端部31a,同时也用于缓冲电芯31的端部31a的膨胀变形,保证靠近外壳20的整个电芯31各个区域受力更加均匀、平衡,有利于进一步提升和改善电芯31循环性能。进一步可选地,参见图13或图14所示,缓冲垫40包括第一缓冲部41、中间部43和第二缓冲部42。中间部43设置于第一缓冲部41和第二缓冲部42之间,有利于保证第一极片34a和第二极片34c各自在电芯31的端部31a处的间隙与第一极片34a和第二极片34c各自在电芯31的中心区域的间隙趋于一致,也有利于保证电芯31的端部31a的膨胀程度与电芯31中心区域的膨胀程度趋于一致,从而进一步提升和改善电芯31循环性能。Referring to FIG. 9, a
在一个实施例中,电池单元30包括两个以上的电芯31。两个以上的电芯31设置于一个固定框。在一个电池单元30中,参见图10、图13或图14所示,相邻两个电芯31之间设置刚性隔离部件50。刚性隔离部件50可以是铝板。在电池单元30中的电芯31发生膨胀时,相邻两个电芯31会受到刚性隔离部件50的约束,从而一方面,刚性隔离部件50可以与缓冲垫40共同对电芯31形成约束,以有效减小电芯31的膨胀变 形,以使电芯31端部31a的膨胀程度与电芯31中心区域的膨胀程度趋于一致;另一方面,刚性隔离部件50可以降低相邻两个电芯31因发生膨胀变形而出现相互挤压致使第一极片34a和第二极片34c发生结构损坏的可能性。刚性隔离部件50可以使用具有导热性能的材料制成,从而可以有利于电芯31通过刚性隔离部件50散热。In one embodiment, the
在一个实施例中,第一间隙32的数量为两个。相邻两个电芯31的两个端部31a之间形成两个第一间隙32,而相邻两个电芯31的中心区域相互接触以使得两个第一间隙32在长度方向X上不连通。每个第一间隙32内设置有一个缓冲垫40。In one embodiment, the number of the
在一个实施例中,参见图15所示,每个电池单元30包括一个电芯31。一个固定框内设置一个电芯31。相邻两个电芯31之间形成第一间隙32。相邻两个电芯31设置缓冲垫40。在一个示例中,参见图16所示,缓冲垫40包括第一缓冲部41和第二缓冲部42。第一缓冲部41和第二缓冲部42沿长度方向X间隔设置。在另一个示例中,参见图17所示,缓冲垫40还包括中间部43。第一缓冲部41、中间部43和第二缓冲部42依次沿长度方向X排布,并且彼此相连接。第一缓冲部41、中间部43和第二缓冲部42可以是分体结构,也可以是一体成型结构。图17中虚线仅用于示意区分第一缓冲部41、中间部43和第二缓冲部42,不对第一缓冲部41、中间部43和第二缓冲部42或其它零部件的结构形成限定。In one embodiment, referring to FIG. 15, each
在一个实施例中,参见图18和图19所示,两个极耳从电芯31的一个端面31b引出。相邻两个电芯31各自的一个端部31a之间形成第一间隙32,各自的另一个端部31a彼此接触。第一间隙32的数量为一个。第一间隙32沿长度方向X不贯通。第一间隙32内设置缓冲垫40。缓冲垫40与电芯31的端部31a接触In one embodiment, as shown in FIGS. 18 and 19, two tabs are led out from one
虽然已经参考优选实施例对本申请进行了描述,但在不脱离本申请的范围的情况下,可以对其进行各种改进并且可以用等效物替换其中的部件。尤其是,只要不存在结构冲突,各个实施例中所提到的各项技术特征均可以任意方式组合起来。本申请并不局限于文中公开的特定实施例,而是包括落入权利要求的范围内的所有技术方案。Although the present application has been described with reference to the preferred embodiments, various modifications can be made to it without departing from the scope of the present application and the components therein can be replaced with equivalents. In particular, as long as there is no structural conflict, the various technical features mentioned in the various embodiments can be combined in any manner. This application is not limited to the specific embodiments disclosed in the text, but includes all technical solutions falling within the scope of the claims.
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CN111354899B (en) * | 2020-05-25 | 2020-10-23 | 比亚迪股份有限公司 | Battery pack, battery module, vehicle and energy storage device |
JP7298550B2 (en) * | 2020-06-02 | 2023-06-27 | トヨタ自動車株式会社 | power storage device |
CN115832540A (en) * | 2021-10-14 | 2023-03-21 | 宁德时代新能源科技股份有限公司 | Battery cell, battery, electric device, and device and method for manufacturing battery cell |
CN118801049A (en) * | 2023-04-13 | 2024-10-18 | 宁德时代新能源科技股份有限公司 | Battery cells, batteries and electrical devices |
CN119921039A (en) * | 2023-10-31 | 2025-05-02 | 比亚迪股份有限公司 | Battery components, battery packs and power systems |
CN117313281B (en) * | 2023-11-30 | 2024-03-19 | 瑞浦兰钧能源股份有限公司 | A method for confirming battery module buffer pad |
CN119601790A (en) * | 2025-02-10 | 2025-03-11 | 宁德时代新能源科技股份有限公司 | Battery cells, battery devices and electrical equipment |
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EP3790097B1 (en) | 2023-01-04 |
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