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WO2018115945A1 - Procédé pour la fabrication d'une tôle d'âcier recuite après galvanisation - Google Patents

Procédé pour la fabrication d'une tôle d'âcier recuite après galvanisation Download PDF

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Publication number
WO2018115945A1
WO2018115945A1 PCT/IB2017/001279 IB2017001279W WO2018115945A1 WO 2018115945 A1 WO2018115945 A1 WO 2018115945A1 IB 2017001279 W IB2017001279 W IB 2017001279W WO 2018115945 A1 WO2018115945 A1 WO 2018115945A1
Authority
WO
WIPO (PCT)
Prior art keywords
steel sheet
anyone
coating
zinc
iron
Prior art date
Application number
PCT/IB2017/001279
Other languages
English (en)
Inventor
Anirban Chakraborty
Hassan GHASSEMI-ARMAKI
Original Assignee
Arcelormittal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arcelormittal filed Critical Arcelormittal
Publication of WO2018115945A1 publication Critical patent/WO2018115945A1/fr
Priority to BR112020006461-0A priority Critical patent/BR112020006461B1/pt
Priority to CA3076464A priority patent/CA3076464C/fr
Priority to PCT/IB2018/058158 priority patent/WO2019082038A1/fr
Priority to JP2020522914A priority patent/JP7062058B2/ja
Priority to US16/754,589 priority patent/US11578378B2/en
Priority to KR1020207011205A priority patent/KR102383618B1/ko
Priority to ES18797150T priority patent/ES2982286T3/es
Priority to CN201880069224.4A priority patent/CN111279007B/zh
Priority to HUE18797150A priority patent/HUE067484T2/hu
Priority to PL18797150.2T priority patent/PL3701058T3/pl
Priority to MX2020004313A priority patent/MX2020004313A/es
Priority to MA50453A priority patent/MA50453B1/fr
Priority to RU2020113209A priority patent/RU2738130C1/ru
Priority to UAA202003016A priority patent/UA125978C2/uk
Priority to FIEP18797150.2T priority patent/FI3701058T3/fi
Priority to EP18797150.2A priority patent/EP3701058B1/fr
Priority to US18/094,503 priority patent/US12091724B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06Zinc or cadmium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment
    • C23C2/28Thermal after-treatment, e.g. treatment in oil bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • C23C28/025Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76Adjusting the composition of the atmosphere

Definitions

  • the present invention relates to a method for the manufacture of a galvannealed steel sheet.
  • the invention is particularly well suited for the manufacture of automotive vehicles.
  • Zinc based coatings are generally used because they allow for a protection against corrosion, thanks to barrier protection and cathodic protection.
  • the barrier effect is obtained by the application of a metallic coating on steel surface.
  • the metallic coating prevents the contact between steel and corrosive atmosphere.
  • the barrier effect is independent from the nature of the coating and the substrate.
  • sacrificial cathodic protection is based on the fact that zinc is a metal less noble that steel. Thus, if corrosion occurs, zinc is consumed preferentially as compared to steel. Cathodic protection is essential in areas where steel is directly exposed to corrosive atmosphere, like cut edges where surrounding zinc will be consumed before steel.
  • zinc coated steel sheets are alloyed at high temperature in order to obtain a galvannealed steel sheet.
  • This steel sheet is more resistance to LME than a zinc coated steel sheet because an alloy comprising Fe and Zn is formed which has higher melting point and forms less liquid during spot welding as compared to pure Zinc.
  • the object of the invention is to provide a galvannealed steel sheet which does not have LME issues. It aims to make available, in particular, an easy to implement method in order to obtain an assembly which does not have LME issues after the forming and/or the welding.
  • the object is achieved by providing a method according to claim 1 .
  • the method can also comprise any characteristics of claims 2 to 18.
  • the steel sheet can also comprise any characteristics of claims 20 to 26.
  • spot welded joint can also comprise characteristics of claim according to claim 30.
  • steel or “steel sheet” means a steel sheet, a coil, a plate having a composition allowing the part to achieve a tensile strength up to 2500 MPa and more preferably up to 2000MPa.
  • the tensile strength is above or equal to 500 MPa, preferably above or equal to 980 MPa, advantageously above or equal to 1180 MPa and even above or equal 1470 MPa.
  • the invention relates to a method for the manufacture of a galvannealed steel sheet comprising the following steps:
  • the first coating comprising iron and nickel is deposited by any deposition method known by the man skilled in the art. It can be deposited by vacuum deposition or electro-plating method. Preferably, it is deposited by electro-plating method.
  • the first coating comprises from 10% to 75%, more preferably between 25 to 65% and advantageously between 40 to 60% by weight of iron.
  • the first coating comprises from 25.0 to 90%, preferably from 35 to 75% and advantageously from 40 to 60% by weight of nickel.
  • the first coating consists of iron and nickel.
  • the first coating has a thickness equal or above 0.5 pm. More preferably, the first coating has a thickness between 0.8 and 5.0pm and advantageously between 1.0 and 2.0pm.
  • the thermal treatment is a continuous annealing.
  • the continuous annealing comprises a heating, a soaking and a cooling step. It can further comprise a pre-heating step.
  • the thermal treatment is performed in an atmosphere comprising from 1 to 30% of H 2 at a dew point between -10 and -60°C.
  • the atmosphere comprises from 1 to 10% of H 2 at a dew point between - 40°C and -60°C.
  • the second layer comprises above 70%, more preferably above 80% of zinc and advantageously above 85% of zinc.
  • the second layer can be deposited by any deposition method known by the man skilled in the art. It can be done by hot-dip coating, by vacuum deposition or by electro- galvanizing.
  • the coating based on zinc comprises between 0.01 and0.18 wt.% Al, optionally 0.2-8.0% Mg, the remainder being Zn.
  • the coating based on zinc is deposited by hot-dip galvanizing method.
  • the molten bath can also comprise unavoidable impurities and residuals elements from feeding ingots or from the passage of the steel sheet in the molten bath.
  • the optionally impurities are chosen from Sr, Sb, Pb, Ti, Ca, Mn, Sn, La, Ce, Cr, Zr or Bi, the content by weight of each additional element being inferior to 0.3% by weight.
  • the residual elements from feeding ingots or from the passage of the steel sheet in the molten bath can be iron with a content up to 5.0%, preferably 3.0%, by weight.
  • the second layer consists of zinc.
  • the percentage of Aluminum is comprised between 0.10 and 0.18 wt.% in the bath.
  • step D) the alloying treatment is performed by heating the coated steel sheet obtained in step C) at a temperature between 460 and 550 °C for 5 to 40 seconds.
  • step D is performed at 500°C for 20 seconds.
  • a galvannealed steel sheet is obtained with a first layer comprising iron and nickel directly topped by a second layer based on zinc, the first and second layers being alloyed through diffusion such that the second alloy layer comprising from 5 to 15wt.% of iron, from 0 to 15wt.% and preferably from 1 to 15wt.% of nickel, the balance being zinc.
  • the steel sheet has a microstructure comprising from 1 to 50% of residual austenite, from 1 to 60% of martensite and optionally at least one element chosen from: bainite, ferrite, cementite and pearlite.
  • the martensite can be tempered or untempered.
  • the steel sheet has a microstructure comprising from 5 to 25 % of residual austenite.
  • the steel sheet has a microstructure comprising from 1 to 60% and more preferably between 10 to 60% of tempered martensite.
  • the steel sheet has a microstructure comprising from 10 to 40% of bainite, such bainite comprising from 10 to 20% of lower bainite, from 0 to 15% of upper bainite and from 0 to 5% of carbide free bainite.
  • the steel sheet has a microstructure comprising from 1 to 25% of ferrite.
  • the steel sheet has a microstructure comprising from 1 to 15% untempered martensite.
  • the welding is performed with an effective intensity is between 3kA and 15kA and the force applied on the electrodes is between 150 and 850 daN with said electrode active face diameter being between 4 and 10mm.
  • a spot welded joint of at least two metal sheets, comprising the coated steel sheet according to the present invention is obtained, such said joint containing less than 3 cracks having a size above 100pm and wherein the longest crack has a length below 400 ⁇ .
  • the second metal sheet is a steel sheet or an aluminum sheet. More preferably, the second metal sheet is a steel sheet according to the present invention.
  • the spot welded joint comprises a third metal sheet being a steel sheet or an aluminum sheet.
  • the third metal sheet is a steel sheet according to the present invention.
  • the steel sheet or the spot welded joint according to the present invention can be used for the manufacture of parts for automotive vehicle.
  • Trial 1 to 4 were prepared by deposited a first coating comprising 55% and
  • Trial 5 was prepared by depositing a zinc coating by electro-galvanizing after the continuous annealing of the above steel sheet.
  • Trials according to the present invention show an excellent resistance to LME compared to Trial 5. Indeed, the number of cracks of Trials according to the present invention is very low, even nonexistent, compared to Trial 5.
  • Trials according to the present invention show an excellent resistance to LME as compared to Trial 5.
  • Trials 1 to 4 were bent at a 90° angle followed. An adhesive tape was then applied and removed to verify the coating adhesion with the substrate steel. The coating adhesion of those Trials was excellent.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

La présente invention concerne un procédé pour la fabrication d'une tôle d'acier recuite après galvanisation.
PCT/IB2017/001279 2016-12-21 2017-10-24 Procédé pour la fabrication d'une tôle d'âcier recuite après galvanisation WO2018115945A1 (fr)

Priority Applications (17)

Application Number Priority Date Filing Date Title
EP18797150.2A EP3701058B1 (fr) 2017-10-24 2018-10-19 Procédé permettant la fabrication d'une tôle d'âcier recuite par galvanisation
ES18797150T ES2982286T3 (es) 2017-10-24 2018-10-19 Un procedimiento para la fabricación de una lámina de acero galvano-recocido
PL18797150.2T PL3701058T3 (pl) 2017-10-24 2018-10-19 Sposób wytwarzania blachy stalowej ocynkowanej z przeżarzaniem
PCT/IB2018/058158 WO2019082038A1 (fr) 2017-10-24 2018-10-19 Procédé permettant la fabrication d'une tôle d'âcier recuite par galvanisation
JP2020522914A JP7062058B2 (ja) 2017-10-24 2018-10-19 合金化溶融亜鉛めっき鋼板の製造方法
US16/754,589 US11578378B2 (en) 2017-10-24 2018-10-19 Method for the manufacture of a galvannealed steel sheet
KR1020207011205A KR102383618B1 (ko) 2017-10-24 2018-10-19 용융아연도금된 강 시트의 제조 방법
BR112020006461-0A BR112020006461B1 (pt) 2017-10-24 2018-10-19 Método para a fabricação de uma chapa de aço galvanizada e recozida
CN201880069224.4A CN111279007B (zh) 2017-10-24 2018-10-19 用于制造镀锌扩散退火钢板的方法
HUE18797150A HUE067484T2 (hu) 2017-10-24 2018-10-19 Eljárás galvanizált acéllemez elõállítására
CA3076464A CA3076464C (fr) 2017-10-24 2018-10-19 Procede permettant la fabrication d'une tole d'acier recuite par galvanisation
MX2020004313A MX2020004313A (es) 2017-10-24 2018-10-19 Un metodo para la fabricacion de una lamina de acero galvanizado.
MA50453A MA50453B1 (fr) 2017-10-24 2018-10-19 Procédé permettant la fabrication d'une tôle d'âcier recuite par galvanisation
RU2020113209A RU2738130C1 (ru) 2017-10-24 2018-10-19 Способ изготовления гальванизированной и отожженной листовой стали
UAA202003016A UA125978C2 (uk) 2017-10-24 2018-10-19 Спосіб виготовлення гальванізованої та відпаленої листової сталі
FIEP18797150.2T FI3701058T3 (fi) 2017-10-24 2018-10-19 Menetelmä galvanoidun-hehkutetun teräslevyn valmistusta varten
US18/094,503 US12091724B2 (en) 2017-10-24 2023-01-09 Galvannealed steel sheet coated with an iron and nickel layer topped by a zinc-based layer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IB2016001802 2016-12-21
IBPCT/IB2016/001802 2016-12-21

Publications (1)

Publication Number Publication Date
WO2018115945A1 true WO2018115945A1 (fr) 2018-06-28

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WO (1) WO2018115945A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004124187A (ja) * 2002-10-03 2004-04-22 Sumitomo Metal Ind Ltd 密着性・溶接性に優れた高強度溶融亜鉛めっき鋼板
KR20120074144A (ko) * 2010-12-27 2012-07-05 주식회사 포스코 내파우더링성이 우수한 고망간 고알루미늄 합금화 용융아연도금강판 및 그 제조방법
EP2631319A1 (fr) * 2010-10-21 2013-08-28 Posco Tôle galvanisée présentant d'excellentes aptitudes au revêtement, adhérence de revêtement et aptitude au soudage par points, ainsi que son procédé de fabrication
US20160082701A1 (en) * 2013-05-20 2016-03-24 Nippon Steel & Sumitomo Metal Corporation Galvannealed steel sheet and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004124187A (ja) * 2002-10-03 2004-04-22 Sumitomo Metal Ind Ltd 密着性・溶接性に優れた高強度溶融亜鉛めっき鋼板
EP2631319A1 (fr) * 2010-10-21 2013-08-28 Posco Tôle galvanisée présentant d'excellentes aptitudes au revêtement, adhérence de revêtement et aptitude au soudage par points, ainsi que son procédé de fabrication
KR20120074144A (ko) * 2010-12-27 2012-07-05 주식회사 포스코 내파우더링성이 우수한 고망간 고알루미늄 합금화 용융아연도금강판 및 그 제조방법
US20160082701A1 (en) * 2013-05-20 2016-03-24 Nippon Steel & Sumitomo Metal Corporation Galvannealed steel sheet and manufacturing method thereof

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