WO2016124441A1 - Composition comprenant un amidon modifié et du silicate de magnésium - Google Patents
Composition comprenant un amidon modifié et du silicate de magnésium Download PDFInfo
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- WO2016124441A1 WO2016124441A1 PCT/EP2016/051534 EP2016051534W WO2016124441A1 WO 2016124441 A1 WO2016124441 A1 WO 2016124441A1 EP 2016051534 W EP2016051534 W EP 2016051534W WO 2016124441 A1 WO2016124441 A1 WO 2016124441A1
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- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- composition
- starch
- weight
- magnesium silicate
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 114
- 239000000391 magnesium silicate Substances 0.000 title claims abstract description 17
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 235000019792 magnesium silicate Nutrition 0.000 title claims abstract description 15
- 229910052919 magnesium silicate Inorganic materials 0.000 title claims abstract description 15
- 229920000881 Modified starch Polymers 0.000 title claims description 20
- 239000004368 Modified starch Substances 0.000 title claims description 19
- 235000019426 modified starch Nutrition 0.000 title claims description 19
- 229920002472 Starch Polymers 0.000 claims abstract description 26
- 239000008107 starch Substances 0.000 claims abstract description 26
- 235000019698 starch Nutrition 0.000 claims abstract description 26
- 239000002537 cosmetic Substances 0.000 claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 32
- -1 fatty acid esters Chemical class 0.000 claims description 26
- 239000001254 oxidized starch Substances 0.000 claims description 16
- 235000013808 oxidized starch Nutrition 0.000 claims description 16
- 229920005862 polyol Polymers 0.000 claims description 16
- 150000003077 polyols Chemical class 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 13
- 239000000194 fatty acid Substances 0.000 claims description 13
- 229930195729 fatty acid Natural products 0.000 claims description 13
- 239000000454 talc Substances 0.000 claims description 13
- 229910052623 talc Inorganic materials 0.000 claims description 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 11
- 230000000699 topical effect Effects 0.000 claims description 10
- 240000003183 Manihot esculenta Species 0.000 claims description 8
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 102000011782 Keratins Human genes 0.000 claims description 6
- 108010076876 Keratins Proteins 0.000 claims description 6
- 239000004909 Moisturizer Substances 0.000 claims description 6
- 230000001333 moisturizer Effects 0.000 claims description 6
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 3
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 3
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 3
- 244000061456 Solanum tuberosum Species 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- 239000007764 o/w emulsion Substances 0.000 claims description 3
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- AWIJRPNMLHPLNC-UHFFFAOYSA-N methanethioic s-acid Chemical compound SC=O AWIJRPNMLHPLNC-UHFFFAOYSA-N 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 238000002560 therapeutic procedure Methods 0.000 claims description 2
- 241000209140 Triticum Species 0.000 claims 1
- 150000003672 ureas Chemical class 0.000 claims 1
- 239000003921 oil Substances 0.000 description 21
- 125000004432 carbon atom Chemical group C* 0.000 description 19
- 235000019198 oils Nutrition 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 18
- 239000000839 emulsion Substances 0.000 description 12
- 235000012222 talc Nutrition 0.000 description 12
- 210000003491 skin Anatomy 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 8
- 229920000856 Amylose Polymers 0.000 description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000008103 glucose Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- 229920000945 Amylopectin Polymers 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000006210 lotion Substances 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 239000013543 active substance Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 5
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 4
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000001073 acetylated oxidized starch Substances 0.000 description 4
- 235000013770 acetylated oxidized starch Nutrition 0.000 description 4
- 239000002671 adjuvant Substances 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 235000014121 butter Nutrition 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 4
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 3
- 241001135917 Vitellaria paradoxa Species 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 3
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- DFPAKSUCGFBDDF-UHFFFAOYSA-N nicotinic acid amide Natural products NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
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- 239000007787 solid Substances 0.000 description 3
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- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 2
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 2
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 2
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
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- 235000019486 Sunflower oil Nutrition 0.000 description 2
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- NDJKXXJCMXVBJW-UHFFFAOYSA-N heptadecane Chemical compound CCCCCCCCCCCCCCCCC NDJKXXJCMXVBJW-UHFFFAOYSA-N 0.000 description 2
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- JYGXADMDTFJGBT-VWUMJDOOSA-N hydrocortisone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 JYGXADMDTFJGBT-VWUMJDOOSA-N 0.000 description 2
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- NRTKYSGFUISGRQ-UHFFFAOYSA-N (3-heptanoyloxy-2,2-dimethylpropyl) heptanoate Chemical compound CCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCC NRTKYSGFUISGRQ-UHFFFAOYSA-N 0.000 description 1
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- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
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- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 229940124091 Keratolytic Drugs 0.000 description 1
- 240000004322 Lens culinaris Species 0.000 description 1
- 235000014647 Lens culinaris subsp culinaris Nutrition 0.000 description 1
- 235000019493 Macadamia oil Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000010804 Maranta arundinacea Nutrition 0.000 description 1
- YJPIGAIKUZMOQA-UHFFFAOYSA-N Melatonin Natural products COC1=CC=C2N(C(C)=O)C=C(CCN)C2=C1 YJPIGAIKUZMOQA-UHFFFAOYSA-N 0.000 description 1
- 241001092142 Molina Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010575 Pueraria lobata Nutrition 0.000 description 1
- 244000046146 Pueraria lobata Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000907903 Shorea Species 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 240000003829 Sorghum propinquum Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 235000012419 Thalia geniculata Nutrition 0.000 description 1
- 244000145580 Thalia geniculata Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 229930003537 Vitamin B3 Natural products 0.000 description 1
- 229930003571 Vitamin B5 Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 229930003448 Vitamin K Natural products 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- FRGAIZLZPOROJH-BKIJVIAGSA-N [(2R,3S,4S,5R,6S)-3,4,5-trihydroxy-6-[2-hydroxy-3-[2-hydroxy-3-(2-hydroxy-3-octadecanoyloxypropoxy)propoxy]propoxy]oxan-2-yl]methyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COCC(O)CO[C@H]1O[C@H](COC(=O)CCCCCCCCCCCCCCCCC)[C@@H](O)[C@H](O)[C@H]1O FRGAIZLZPOROJH-BKIJVIAGSA-N 0.000 description 1
- LPGFSDGXTDNTCB-UHFFFAOYSA-N [3-(16-methylheptadecanoyloxy)-2,2-bis(16-methylheptadecanoyloxymethyl)propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCC(C)C)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C LPGFSDGXTDNTCB-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 230000001153 anti-wrinkle effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000010477 apricot oil Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- OHXVIZBSLGZEFS-UHFFFAOYSA-N benzhydrylsilyloxy-diphenyl-silyloxysilane Chemical class C1(=CC=CC=C1)C(C1=CC=CC=C1)[SiH2]O[Si](O[SiH3])(C1=CC=CC=C1)C1=CC=CC=C1 OHXVIZBSLGZEFS-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 229910052599 brucite Inorganic materials 0.000 description 1
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 description 1
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- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- 239000000470 constituent Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
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- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000005534 decanoate group Chemical class 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000007854 depigmenting agent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- 229940102552 disteardimonium hectorite Drugs 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
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- 239000000284 extract Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
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- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008169 grapeseed oil Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000010468 hazelnut oil Substances 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical class [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229960000890 hydrocortisone Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- LTYSCLBTUYRCBF-UHFFFAOYSA-N icosan-9-yl 2-hydroxyoctadecanoate Chemical compound CCCCCCCCCCCCCCCCC(O)C(=O)OC(CCCCCCCC)CCCCCCCCCCC LTYSCLBTUYRCBF-UHFFFAOYSA-N 0.000 description 1
- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 230000001530 keratinolytic effect Effects 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
- 229940031674 laureth-7 Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000010469 macadamia oil Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- DRLFMBDRBRZALE-UHFFFAOYSA-N melatonin Chemical compound COC1=CC=C2NC=C(CCNC(C)=O)C2=C1 DRLFMBDRBRZALE-UHFFFAOYSA-N 0.000 description 1
- 229960003987 melatonin Drugs 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229960003966 nicotinamide Drugs 0.000 description 1
- 235000005152 nicotinamide Nutrition 0.000 description 1
- 239000011570 nicotinamide Substances 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical class C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 125000005474 octanoate group Chemical class 0.000 description 1
- HRPZGPXWSVHWPB-UHFFFAOYSA-N octyl decanoate Chemical compound CCCCCCCCCC(=O)OCCCCCCCC HRPZGPXWSVHWPB-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- SHUZOJHMOBOZST-UHFFFAOYSA-N phylloquinone Natural products CC(C)CCCCC(C)CCC(C)CCCC(=CCC1=C(C)C(=O)c2ccccc2C1=O)C SHUZOJHMOBOZST-UHFFFAOYSA-N 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229960003471 retinol Drugs 0.000 description 1
- 235000020944 retinol Nutrition 0.000 description 1
- 239000011607 retinol Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- COXJMKGEQAWXNP-UHFFFAOYSA-N tris(14-methylpentadecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(C)CCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCC(C)C)CC(=O)OCCCCCCCCCCCCCC(C)C COXJMKGEQAWXNP-UHFFFAOYSA-N 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000009492 vitamin B5 Nutrition 0.000 description 1
- 239000011675 vitamin B5 Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019168 vitamin K Nutrition 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
- 150000003721 vitamin K derivatives Chemical class 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046010 vitamin k Drugs 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/007—Preparations for dry skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
Definitions
- the present invention relates to compositions, especially non-therapeutic and/or makeup cosmetic compositions, containing a modified starch and a magnesium silicate.
- Urea and glycerol are considered as humectants: I.e. small molecules which penetrate into the stratum corneum and keep it moisturized. In order to have a moisturizing effect throughout the day, it is necessary to introduce into cosmetic compositions large amounts of these molecules.
- urea and glycerol especially have the drawback of making formulations tacky, especially when they are used in high concentration.
- the object of the present invention is, precisely, to propose a solution to this lack of moisturizing topical galenical formulations.
- composition especially a cosmetic composition, comprising:
- the inventors have found, unexpectedly, that the combination of a mixture of particular fillers makes it possible to obtain, on topical application of a composition, a significantly improved quality of deposit.
- the composition may be sprayed easily and without a dragging sensation, and, after drying, the feel turns out to be soft, non-tacky and non-greasy. These properties are obtained while at the same time having good moisturizing power.
- compositions according to the invention thus afford, when they are applied and after application, good sensory properties.
- the present invention relates to a non- therapeutic process for caring for and/or making up a keratin material and especially the skin, comprising the topical application to said keratin material of a composition in accordance with the invention.
- the present invention also relates to the use of an effective amount of modified starch and of magnesium silicate, for giving a topical cosmetic composition a glidant, non- tacky and soft nature during and at the end of application and after application.
- alkyl means a linear or branched, saturated C8-C24, better still C12-C20 and more preferentially C14-C18 hydrocarbon-based chain.
- acyl means a linear or branched saturated C8-C24, better still C12- C20 and more preferentially C14-C18 hydrocarbon-based chain comprising a carboxylic function whose hydroxyl function (-OH) has been substituted.
- the modified starch is preferably an oxidized and esterified starch (or oxidized starch ester).
- oxidized means that at least one hydroxyl of the starch has been oxidized, in particular in position 6 of a glucose unit of the starch: the groups -CH 2 -OH becoming an aldehyde group -C(0)-H or carboxylic group -C(0)-OH.
- esters or “esterified” means that at least one hydroxyl group of the glucose unit A of the starch is esterified with a (thio)carboxylic acid, particularly a (Cl- C8)(thio)carboxylic acid, and preferably with an acetic acid to obtain an ester B, C or D with C and D corresponding, respectively, to the end or the start of the starch, Ra, Rb, Rc, Rd and Re representing a hydrogen atom or an alkyl(thio)carbonyl group such as (Ci- C 8 )alkyl-C(0)- or (Ci-C 8 )alkyl-C(S)-, it being understood that at least one of the radicals Ra, Rb, Rc, Rd and Re represents an alkyl(thio)carbonyl in at least one unit of the starch:
- oxidized ester means that at least one hydroxyl group of the starch is oxidized as defined above and that at least one other hydroxyl group of the starch is esterified as defined above.
- the composition of the invention comprises as esterified oxidized starch a starch which comprises at least one linear glucose polymer, i.e. an amylose derivative of formula (I) and/or at least one branched glucose polymer, i.e. an amylopectin derivative of formula (II), anomers thereof, preferably alpha-anomers, salts thereof and solvates thereof such as hydrates thereof:
- R 1 , R 2 , R 3 , R 4 and R 5 which may be identical or different, represent a hydroxymethyl group -CH 2 -OH or an oxidized form such as -CH 2 -C(0)-H, or - C(0)-OH, it being understood that at least one of the radicals R 1 , R 2 , R 3 , R 4 or R represents an oxidized form, preferably -C(0)-OH, and more particularly R is an oxidized form and R 1 , R 2 , R 3 and R 5 represents a hydroxymethyl group;
- R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 which may be identical or different, represent a hydroxyl group or a group (Ci-Cs)alkylcarbonyloxy, or a group (Ci-C 8 )alkylthiocarbonyloxy, preferably a hydroxyl group or a group (Ci- C 6 )alkylcarbonyloxy such as an acetyl group, it being understood that at least one of the radicals R 7 , R 8 , R 9 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 or R 16 represents a group (Ci-C 8 )alkylcarbonyloxy, or a group (Ci-C 8 )alkylthiocarbonyloxy, preferably a group (Ci-Ce)alkylcarbonyloxy such as an acetyl group, more particularly
- n represents an integer, for example between 50 and 300 000, preferably between 100 and 200 000, more particularly from 200 to 100 000, better still from 400 to 100 000 and even better still from 470 to 95 000.
- the average molecular weight of the modified amylopectin of formula (II) is at least 10 7 and may be greater than 10 9 .
- the oxidized starch ester comprises a mixture of linear and branched glucose polymers, i.e. a mixture of amylose derivatives and of amylopectin derivatives and more particularly in an amount ranging from 10% to 40% by weight of amylose and from 60% to 90% of amylopectin; and preferably from 15% to 20% of amylose and from 80% to 85% of amylopectin.
- the oxidized starch ester comprises a major amount of amylose derivatives, preferably from 60% to 100% and more particularly from 80%> to 85%> by weight.
- the oxidized starch ester preferably oxidized starch acetate, comprises amylose derivatives of formula (I) with an average molecular weight of 10 4 to 10 7 , preferably 10 5 to 10 6 , which means that they have a mean degree of polymerization (DP, number of glucosyl units per molecule) ranging from 50 to 20 000, preferably from 100 to 10 000 and more particularly from 600 to 6000.
- DP mean degree of polymerization
- the oxidized starch ester is derived from any natural starch obtained from plants.
- a natural starch may be found, for example, in arrow-root, tapioca, potato, sweet potato, beans (broad beans and peas), lentils, buckwheat, banana, barley, cassava, corn, kudzu, oca (Oxalis tuberosa Molina), rice, sago, sorghum, coco-yam and wheat, and mixtures thereof.
- tapioca, potato and wheat are used to produce the esterified and in particular acetylated oxidized starch according to the invention. Tapioca starch will preferably be used.
- the oxidized starch ester is an acetylated modified starch.
- acetylated modified starch is a white powder of INS E number 1451, and CAS number 68187-08-6
- the viscosity of the oxidized starch ester, particularly the acetylated starch is in the range from 10 cP to 2000 cP, preferably from 18 cP to 1500 cP, more particularly from 18 cP to 1400 cP at a temperature of at least 25°C, preferably at a temperature of at least 45°C, preferably less than 85°C.
- the viscosity of the oxidized modified starch ester, particularly the acetylated modified starch is evaluated using a Brookfield NDJ-1 viscometer.
- the esterification index is preferably greater than 0.05.
- the amount of ester such as a (Ci-Cs)alkylcarbonyloxy group or a (Ci-C8)alkylthiocarbonyloxy group, preferably a (Ci- Ce)alkylcarbonyloxy group such as acetyl, of an esterified, in particular acetylated, oxidized starch ranges from 0.1% to 2.5% by weight and preferably from 0.5% to 1% by weight relative to the total weight of the starch. It is understood that the percentage corresponds to the number of hydroxyl groups on the starch that have been esterified relative to the molecular weight of the modified starch.
- the oxidized starch ester particularly the acetylated oxidized starch, comprises from 0.25%> to 5% of carboxyl groups, preferably from 0.3%) to 0.75%> of carboxyl groups and more preferably from 0.35%> to 0.5%> of carboxyl groups relative to the total weight of the starch.
- the oxidized starch ester preferably the acetylated oxidized starch
- the esterified oxidized starch is a starch which comprises at least one linear glucose polymer, i.e. an amylose derivative of formula (I) and/or at least one branched glucose polymer, i.e. an amylopectin derivative of formula (II) as defined above, in which n is between 470 and 95 000 and
- R 1 , R 2 , R 3 and R 5 represent a hydroxymethyl group
- R 7 , R 8 , R 9 , R 10 , R 11 , R 13 , R 14 , R 15 and R 16 represent a hydroxyl group; and - R 4 represents a carboxyl group -C(0)-OH or salts thereof; and
- R 12 represents a (Ci-Ce)alkylcarbonyloxy group such as acetyl.
- Such a starch is especially sold under the name "Acetylated oxidized starch” by the company Zhucheng Xingmao Corn Developing Co., Ltd., under the name “OXC-10” by Suzhou Gaofeng Starch Technology Co., Ltd. or under the name “MS#6100” by Asia Modified Starch Co., Ltd, etc.
- the esterified oxidized modified starch may be readily produced in a manner known to those skilled in the art.
- the manufacturing process includes two reaction steps of oxidation and esterification.
- the oxidation step may be performed by dispersing the native starch in water followed by oxidation with sodium hydroxide and sodium hypochlorite. Sodium metabisulfite is then added to stop the reaction, and the medium is then neutralized with hydrochloric acid.
- the esterification step may be performed by esterifying the starch obtained in step 1 with acetic anhydride, followed by neutralization with hydrochloric acid.
- the esterified oxidized starch may be present in the composition according to the invention in a content ranging from 1% to 15% by weight, preferably from 3% to 12% by weight and better still from 5% to 10% by weight, relative to the total weight of the composition.
- the magnesium silicates in accordance with the invention may be of natural or synthetic origin.
- Talc is particularly preferred as a magnesium silicate in accordance with the invention.
- Talcs are hydrated magnesium silicates usually also comprising aluminium silicate.
- the crystal structure of talc consists of repeated layers of a sandwich of brucite between layers of silica.
- the talc has a volume-median particle diameter ranging from 100 nm to 150 microns, better still between 500 nm and 50 microns and even more preferentially between 1 and 20 microns.
- the diameter is measured by laser scattering with a machine of the Malvern Mastersizer type.
- the talc in accordance with the invention may be chosen from those sold under the names Talc SG-2000 ® sold by the company Nippon Talc, Luzenac Pharma M ® sold by the company Luzenac, J-68BC from US Corporation and Micro ACE-P-3 ® sold by the company Nippon Talc.
- Use will preferably be made of the talc sold under the name Luzenac 00 by the company Imerys.
- the magnesium silicate may be present in the composition according to the invention in a content ranging from 0.1% to 5% by weight, better still from 0.1% to 3% and more particularly from 0.5% to 1.5% by weight of talc relative to the total weight of the composition.
- the modified starch and the magnesium silicate are used in a modified starch/magnesium silicate weight ratio ranging from 5 to 10 and preferably from 6 to 8.
- a composition according to the invention is preferably cosmetic and is more particularly intended for topical application. It consequently contains a physiologically acceptable medium, i.e. a medium that is compatible with human keratin materials such as the skin, especially of the face and/or the body.
- a physiologically acceptable medium i.e. a medium that is compatible with human keratin materials such as the skin, especially of the face and/or the body.
- compositions according to the invention may be in the form of aqueous solutions, aqueous-alcoholic solutions, emulsions, especially oil-in-water (O/W) emulsions, water-in-oil (W/O) emulsions or multiple emulsions (triple: W/O/W or 0/W/O), or aqueous gels.
- O/W oil-in-water
- W/O water-in-oil
- aqueous gels emulsions
- the compositions may also be anhydrous. These compositions are prepared according to the usual methods.
- the composition is in the form of an emulsion, in particular an oil-in- water emulsion.
- the physiologically acceptable medium may comprise water, organic solvents such as a C1-C8 alcohol, especially ethanol, isopropanol, tert-butanol or n-butanol; a polyol such as glycerol; a glycol such as butylene glycol, isoprene glycol, propylene glycol or polyethylene glycols such as PEG-8; or polyol ethers.
- the composition according to the invention may comprise an amount of aqueous phase which may range, for example, from 30% to 97% by weight, preferably from 40% to 95% by weight and better still from 50% to 90% by weight, relative to the total weight of the composition.
- the aqueous phase comprises water and any other water-soluble compound optionally present, especially such as water-soluble solvents and additives (for example hydrophilic surfactants and active agents).
- Water-soluble solvents that may especially be mentioned are lower alcohols and polyols.
- the term "lower alcohol” means alcohols comprising from 1 to 8 and more particularly from 1 to 6 carbon atoms, such as ethanol.
- Examples of polyols that may be mentioned include glycerol, propylene glycol, butylene glycol and polyethylene glycols (for example PEG-8). These alcohols and/or polyols may be present in the composition in an amount preferably ranging from 0.1% to 25% and better still from 1% to 15% of the total weight of the composition.
- the fatty phase can represent more than 90% of the total weight of the composition.
- the proportion of the fatty phase may range from 2% to 80% by weight and preferably from 5% to 50% by weight relative to the total weight of the composition.
- the oils, waxes, emulsifiers and co-emulsifiers used in the composition in emulsion form are chosen from those conventionally used in the cosmetics field.
- the emulsifier and the co-emulsifier are present in the composition in a proportion ranging from 0.3% to 30% by weight and preferably from 0.5% to 20% by weight relative to the total weight of the composition.
- the emulsion may also contain lipid vesicles.
- the fatty phase consists of oils and of any other fatty substances and lipophilic constituents that may be present in the composition of the invention. Any cosmetically acceptable oil may be used.
- oil means a fatty substance that is liquid at room temperature (25 °C) and at atmospheric pressure.
- oils examples include: - hydrocarbon-based oils of animal origin, such as perhydrosqualene and squalane;
- oils of plant origin such as liquid fatty acid triglycerides containing from 4 to 10 carbon atoms, for instance heptanoic or octanoic acid triglycerides, or alternatively, for example, sunflower oil, corn oil, soybean oil, marrow oil, grapeseed oil, sesameseed oil, hazelnut oil, apricot oil, macadamia oil, arara oil, sunflower oil, castor oil, avocado oil, caprylic/capric acid triglycerides, for instance those sold by the company Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel, jojoba oil and shea butter oil;
- esters and ethers especially of fatty acids, for instance the oils of formulae R1COOR2 and R10R2 in which Rl represents the residue of a fatty acid containing from 8 to 29 carbon atoms and R2 represents a branched or unbranched hydrocarbon-based chain containing from 3 to 30 carbon atoms, for instance Purcellin oil, isononyl isononanoate, isopropyl myristate, 2-ethylhexyl palmitate, 2-octyldodecyl stearate, 2-octyldodecyl erucate or isostearyl isostearate; hydroxylated esters, for instance isostearyl lactate, octyl hydroxy stearate, octyldodecyl hydroxystearate, diisostearyl malate or triisocetyl citrate; fatty alcohol heptanoates, octanoates or de
- hydrocarbons of mineral or synthetic origin such as volatile or non-volatile liquid paraffins, and derivatives thereof, petroleum jelly, polydecenes, and hydrogenated polyisobutene such as Parleam oil;
- volatile linear alkanes advantageously of plant origin, comprising from 7 to 17 carbon atoms, in particular from 9 to 15 carbon atoms and more particularly from 1 1 to 13 carbon atoms.
- volatile linear alkanes that are suitable for use in the invention, mention may be made of those described in patent application WO 2007/068 371 from the company Cognis.
- n-nonane C9
- n-decane CIO
- CI 1 n-undecane
- CI 2 n-dodecane
- CI 3 n-tridecane
- CI 4 n-tetradecane
- CI 5 n-pentadecane
- CI 6 n-hexadecane
- CI 7 n-heptadecane
- use will be made of a mixture of undecane (CI 1) and of tridecane (C13) as obtained in Examples 1 and 2 of patent application WO 2008/155 059 from the company Cognis.
- n-dodecane (CI 2) and n-tetradecane (CI 4) such as those sold by Sasol under the references, respectively, Parafol 12-97 and Parafol 14-97, and also mixtures thereof.
- silicone oils for instance volatile or non-volatile polymethylsiloxanes (PDMSs) containing a linear or cyclic silicone chain, which are liquid or pasty at room temperature, especially cyclopolydimethylsiloxanes (cyclomethicones) such as cyclohexasiloxane and cyclopentasiloxane; polydimethylsiloxanes (or dimethicones) comprising alkyl, alkoxy or phenyl groups, which are pendent or at the end of a silicone chain, these groups containing from 2 to 24 carbon atoms; phenylsilicones, for instance phenyl trimethicones, phenyl dimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes, 2-phenylethyl trimethylsiloxysilicates and polymethylphenylsi
- - fatty alcohols containing from 8 to 26 carbon atoms for instance cetyl alcohol, stearyl alcohol and a mixture thereof (cetylstearyl alcohol);
- oils chosen from:
- esters derived from the reaction of at least one fatty acid containing at least 6 carbon atoms, preferably from 6 to 26 carbon atoms, better still from 6 to 20 carbon atoms and even better still from 6 to 16 carbon atoms, and of at least one alcohol comprising from 1 to 17 carbon atoms and better still from 3 to 15 carbon atoms; mention may in particular be made of isopropyl myristate, isopropyl palmitate, 2-ethylhexyl caprate/caprylate (or octyl caprate/caprylate), 2-ethylhexyl palmitate, isostearyl neopentanoate, isononyl isononanoate, hexyl laurate, lactic acid esters of fatty alcohols comprising 12 or 13 carbon atoms, and dicaprylyl carbonate, such as the product which is sold under the name Cetiol CC by the company Cognis,
- fatty acid ethers comprising from 6 to 20 carbon atoms, such as dicaprylyl ether (Cetiol OE from Cognis),
- the fatty phase may be present in the composition according to the invention in an amount ranging from 5% to 60%, better still ranging from 5% to 50% and preferably from 10% to 40% by weight relative to the total weight of the composition.
- composition according to the invention may comprise from 5% to 40% and preferably from 10% to 30% by weight of oils relative to the total weight of the composition.
- composition of the invention may contain other fatty substances in the fatty phase, such as fatty acids containing from 8 to 30 carbon atoms, for instance stearic acid; silicone resins such as trifluoromethyl-Cl-4-alkyl dimethicone and trifluoropropyl dimethicone; silicone gums (dimethiconol), non- emulsifying silicone elastomers, for instance the products sold under the names KSG 6 and KSG 16 by the company Shin-Etsu, under the names Trefil, BY29 and EPSX by the company Dow Corning, or under the name Gransil by the company Grant Industries; waxes, for example mineral waxes, waxes of animal origin, for instance beeswax, waxes of plant origin, hydrogenated oils that are solid at 25°C, fatty esters and glycerides that are solid at 25°C, synthetic waxes and silicone waxes; pasty fatty substances such as and also butters such as
- the composition comprises at least one surfactant chosen in particular from nonionic surfactants more particularly such as fatty acid esters of polyols.
- fatty acid esters of polyols means esters of a fatty acid and of a polyol in which the fatty acid comprises a C6-C22 and preferably C16-C20 alkyl chain and the polyol is chosen from glycerol, a polyglycerol, sorbitan and sugars such as glucose, and mixtures thereof.
- the fatty acid ester of a polyol is a CI 6- C20 fatty acid ester of polyglycerol and of glucose and/or sorbitan, and mixtures thereof.
- the surfactant(s) may be present in a content ranging from 0.05% to 5% by weight relative to the total weight of the composition, preferably from 0.1% to 3% by weight relative to the total weight of the composition.
- composition of the invention for topical application may also contain one or more adjuvants that are common in cosmetics or dermatology.
- adjuvants are used in the usual proportions in the cosmetics field, for example from 0.01% to 30% of the total weight of the composition, and, depending on their nature, they are introduced into the aqueous phase of the composition or into the oily phase, or alternatively into vesicles or any other type of vector.
- hydrophilic thickeners examples include modified or unmodified carboxyvinyl polymers, such as the products sold under the names Carbopol (INCI name: carbomer) by the company Noveon; polyacrylamides; polymers and copolymers of 2-acrylamido-2-methylpropanesulfonic acid, which are optionally crosslinked and/or neutralized, such as the poly(2-acrylamido-2- methylpropanesulfonic acid) sold by the company Clariant under the name Hostacerin AMPS (INCI name: ammonium polyacryldimethyltauramide); crosslinked anionic copolymers of acrylamide and AMPS, in the form of a W/O emulsion, such as those sold under the name Sepigel 305 (CTFA name: Polyacrylamide/C13-14 isoparaffin/Laureth-7) and under the name Simulgel 600 (CTFA name
- Lipophilic gelling agents that may especially be mentioned include modified clays such as modified magnesium silicate (Bentone Gel VS38 from Rheox), or hectorite modified with distearyldimethylammonium chloride (INCI name: Disteardimonium hectorite) sold under the name Bentone 38 CE by the company Rheox.
- modified clays such as modified magnesium silicate (Bentone Gel VS38 from Rheox), or hectorite modified with distearyldimethylammonium chloride (INCI name: Disteardimonium hectorite) sold under the name Bentone 38 CE by the company Rheox.
- an optionally crosslinked and/or neutralized 2-acrylamido-2-methylpropanesulfonic acid homopolymer for instance poly(2- acrylamido-2-methylpropanesulfonic acid) sold by the company Clariant under the name Hostacerin AMPS (CTFA name: ammonium polyacryldimethyltauramide).
- vitamins such as vitamin A (retinol), vitamin E
- composition will comprise at least one moisturizer.
- the moisturizers are especially chosen from polyols, for instance glycerol and sugars, urea and derivatives thereof especially such as hydroxyalkyl urea, in particular hydroxyalkyl urea, and mixtures thereof.
- the moisturizers are generally present in the compositions according to the invention in a content ranging from 0.1% to 30% by weight and preferably from 1% to 15% by weight relative to the total weight of the composition.
- the composition may be in the form of an aqueous, alcoholic, aqueous-alcoholic or oily solution; a dispersion of the lotion or serum type; emulsions, especially water-in-oil, oil-in-water or multiple emulsions; a suspension; microcapsules or microparticles; vesicular dispersions of ionic and/or nonionic type; an aqueous or oily lotion or a lotion in serum form; capsules, granules, syrups or tablets; foams, solid preparations; an aerosol composition also comprising a propellant under pressure.
- the composition may be in the form of a protecting, treating or care composition for the face, the hands, the feet, the major anatomical folds or the body (for example, day cream, night cream, makeup-removing cream, antisun composition, protective or care body milk, aftersun milk, lotion, gel or foam for caring for the skin, such as cleansing lotions, or artificial tanning compositions); a composition for making up the body or face, such as a foundation; a deodorizing composition comprising, for example, a bactericidal agent; an aftershave composition.
- a protecting, treating or care composition for the face, the hands, the feet, the major anatomical folds or the body for example, day cream, night cream, makeup-removing cream, antisun composition, protective or care body milk, aftersun milk, lotion, gel or foam for caring for the skin, such as cleansing lotions, or artificial tanning compositions
- a composition for making up the body or face such as a foundation
- a deodorizing composition comprising, for example, a bacterici
- the present invention relates to a non-therapeutic cosmetic process, comprising at least one step of topical application to the skin of a composition according to the invention, in particular to the skin of the face and/or body and most particularly bodily skin.
- the cosmetic process according to the invention may be performed by topical application, for example daily, of at least one composition comprising it, which may be formulated, for example, in the form of a cream, gel, serum, lotion, emulsion, or aftersun composition.
- the application is repeated, for example 1 to 2 times daily, over several weeks, in particular at least 4 weeks, indeed even 4 to 15 weeks, with, if appropriate, one or more periods of interruption.
- composition according to the invention will vary as a function of the nature of the galenical form under consideration and of the desired effect.
- the composition may remain in contact with the skin for between 1 minute and 12 hours; it may or may not be removed, especially by rinsing, on conclusion of this contact time.
- composition according to the invention was prepared conventionally.
- An oil-in-water emulsion thickened with ammonium polyacryldimethyltauramide and xanthan gum was prepared at 30°C, and the starch and talc were then introduced into the composition with stirring.
- This composition was applied to the body twice a day for 4 weeks. Application is quick and easy.
- the skin is moisturized, soft, supple and non-tacky with a soft, powdery, velvety finish.
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Abstract
La présente invention concerne une composition, notamment une composition cosmétique, comprenant : - au moins un amidon modifié, en particulier un amidon oxydé et estérifié, et - au moins un silicate de magnésium.
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FR1550777A FR3032116B1 (fr) | 2015-02-02 | 2015-02-02 | Composition comprenant un amidon modifie et un silicate de magnesium |
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61271207A (ja) * | 1985-05-27 | 1986-12-01 | Shiseido Co Ltd | 化粧料 |
JPH02295912A (ja) | 1989-05-10 | 1990-12-06 | Shiseido Co Ltd | 肌用化粧料 |
WO2007068371A1 (fr) | 2005-12-14 | 2007-06-21 | Cognis Ip Management Gmbh | Procede pour produire des hydrocarbures |
WO2008155059A2 (fr) | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Mélanges d'hydrocarbures et leur utilisation |
DE102009045933A1 (de) * | 2009-10-22 | 2011-04-28 | Henkel Ag & Co. Kgaa | Zusammensetzung zur Formgebung keratinischer Fasern |
EP2389920A1 (fr) * | 2009-01-22 | 2011-11-30 | Shiseido Co., Ltd. | Matériau cosmétique émulsifié |
WO2014059676A1 (fr) * | 2012-10-19 | 2014-04-24 | L'oreal | Composition comprenant un amidon modifié d'ester oxydé |
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2015
- 2015-02-02 FR FR1550777A patent/FR3032116B1/fr active Active
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2016
- 2016-01-26 WO PCT/EP2016/051534 patent/WO2016124441A1/fr active Application Filing
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JPS61271207A (ja) * | 1985-05-27 | 1986-12-01 | Shiseido Co Ltd | 化粧料 |
JPH02295912A (ja) | 1989-05-10 | 1990-12-06 | Shiseido Co Ltd | 肌用化粧料 |
WO2007068371A1 (fr) | 2005-12-14 | 2007-06-21 | Cognis Ip Management Gmbh | Procede pour produire des hydrocarbures |
WO2008155059A2 (fr) | 2007-06-19 | 2008-12-24 | Cognis Ip Management Gmbh | Mélanges d'hydrocarbures et leur utilisation |
EP2389920A1 (fr) * | 2009-01-22 | 2011-11-30 | Shiseido Co., Ltd. | Matériau cosmétique émulsifié |
DE102009045933A1 (de) * | 2009-10-22 | 2011-04-28 | Henkel Ag & Co. Kgaa | Zusammensetzung zur Formgebung keratinischer Fasern |
WO2014059676A1 (fr) * | 2012-10-19 | 2014-04-24 | L'oreal | Composition comprenant un amidon modifié d'ester oxydé |
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DATABASE GNPD [online] MINTEL; 27 July 2012 (2012-07-27), "Fluid Talc", XP002742807, Database accession no. 1822766 * |
DATABASE GNPD [online] MINTEL; 29 October 2010 (2010-10-29), "Whip Body Lotion", XP002742806, Database accession no. 1410165 * |
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