WO2016116303A1 - Amélioration du brillant spéculaire de fibres de viscose - Google Patents
Amélioration du brillant spéculaire de fibres de viscose Download PDFInfo
- Publication number
- WO2016116303A1 WO2016116303A1 PCT/EP2016/050290 EP2016050290W WO2016116303A1 WO 2016116303 A1 WO2016116303 A1 WO 2016116303A1 EP 2016050290 W EP2016050290 W EP 2016050290W WO 2016116303 A1 WO2016116303 A1 WO 2016116303A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- viscose fiber
- fiber material
- viscose
- cellulose
- medium
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Definitions
- the invention relates to imparting, preferably enhancing the gloss of viscose fibers using nanocrystalline cellulose, hereinafter called NCC.
- Viscose is regenerated cellulose, insoluble in water, prepared by treatment with sodium hydroxide and carbon disulfide and made water soluble to form sodium cellulose- xanthate solution.
- the slurry when passed through a spinneret under pressure into sulfuric acid solution bath yields regenerated cellulose material known as viscose.
- the chemistry of cellulose and viscose remains the same with exception of physical properties such as crystallinity and morphology.
- Regeneration of cellulose is a precipitation process carried out in harsh acidic condition which affects significantly physical parameters such as crystallinity of the viscose fiber material.
- Specular gloss is an ability of a surface to reflect light in the specular direction in relation to that of a polished flat glass surface with a well-defined optical property such as refractive index. Gloss is identified as a surface phenomenon or effect and flat surfaces empower gloss effect.
- the industrial process of viscose fiber manufacturing can be divided into two parts, namely the pre-regeneration and the post-regeneration regime by means of which improvements in effective specular gloss value can be achieved.
- Multiple additives in sodium cellulose-xanthate slurry reduce the refractive index of regenerated cellulose and lower the effective gloss. Slurries with pigment dispersions are sometimes not spinnable due to harsh acidic regeneration
- cellulose to viscose cellulose to viscose
- finishing chemicals such as special oils are used to impart gloss or finish to the fiber.
- the use of additives and finish chemicals can impart gloss to the finished fiber to a certain extent.
- Gloss obtained by such treatment can be attributed to adsorbed finishing chemicals such as surfactants or special oils used.
- Viscose fibers lack the crystallinity on fiber contour regions. Precipitation conditions such as temperature and molecular weight of cellulose affects the crystallinity of the viscose fiber.
- the present invention helps to overcome the deficiency in gloss on fiber surface.
- the invention also provides a novel concept of the ability of nano-crystalline cellulose (NCC) to alter physical properties of fiber surfaces such as viscose fiber material leading to an enhancement of specular gloss.
- NCC nano-crystalline cellulose
- the present invention relates to a process for imparting gloss onto the surface of a viscose fiber material, characterized in that
- a viscose fiber material is immersed in a liquid hydrophilic medium to give a swollen viscose fiber material
- said swollen viscose fiber material is treated with a suspension or solution of nanocrystalline cellulose in a liquid hydrophilic medium
- said treated viscose fiber material is washed with water and optionally with aqueous sulfuric acid
- the viscose fiber material used in the present invention can be any kind of regenerated cellulose, e.g. neat viscose or a blend of viscose with other fiber material, such as polyester or any natural or synthetic fibers.
- a colored viscose fiber material e,g. colored with a dye or a pigment as specified hereinafter.
- the viscose fiber material is immersed in a liquid hydrophilic medium for a time sufficient to affect a swelling of the viscose fiber material.
- the liquid hydrophilic medium is advantageously an aqueous medium, an alcoholic medium or an aqueous alcoholic medium.
- the alcoholic medium comprises monovalent or polyvalent alcohols, preferably those which are soluble in water, e.g. methanol, ethanol, iso-propanol, n-propanol, n-butanol, iso-butanol, tert-butanol, glycols, such as ethylene glycol, propylene glycol, or glycerine.
- the aqueous medium can be water alone or comprise water in combination with water soluble organic solvents.
- the aqueous alcoholic medium comprises water or said aqueous medium and one or more of the alcohols mentioned before. Ethylene glycol is the preferred alcohol.
- the swelling time according to step (i) is expediently at least 10 minutes, preferably 10 to 120 min, more preferably 20 to 90 min, most preferably 30 to 60 min. A swelling time of more than 120 min is also possible although usually of no technical advantage.
- an elevated temperature is advantageous, e.g. a temperature between 40 and 130 °C, preferably between 50 and 120 °C, more preferably between 60 and 1 10 °C, even more preferably between 70 and 100 °C.
- Nanocrystalline cellulose can be obtained from native fibers, e.g. wood fibers, by an acidic hydrolysis commonly using sulfuric or hydrochloric acid giving rise to nanoparticles or nanowhiskers which are rod like in shape with an aspect ratio which preferably varies from 1 to 100 depending on the cellulose source.
- Cellulose nanocrystals average 100 to 500 nm, preferably 150 to 300 nm, more preferably 180 to 200 nm, in length with a cross section of 1 to 20 nm, preferably 2 to 10 nm, more preferably 3 to 5 nm.
- NCC suspensions are stabilized in aqueous media by means of sulfate ester groups imparted to the cellulose nanocrystal surfaces. Sulfuric acid is used for said acidic hydrolysis of cellulose regeneration.
- the extent of suspension ability of NCC in aqueous or liquid hydrophilic medium may vary depending on the source and molecular weight of NCC.
- the concentration of NCC in the liquid hydrophilic medium may range from 0.5 to 15 % strength by weight, preferably from 1 to 10 % strength by weight, more preferably from 2 to 7.5 strength % by weight, based on the total weight of the liquid hydrophilic medium and NCC.
- liquid hydrophilic medium in steps (i) and (ii) can be the same or different.
- the liquid hydrophilic medium is the same in step (i) and (ii). It is possible that the whole or a partial amount of the NCC to be used is already present in the swelling step (i).
- the amount by weight of NCC relative to the weight of the viscose fiber material to be treated may range from (0.10 to 10.0) : 1 , preferably from (0.20 to 2.0) : 1 , more preferably from (0.25 to 1 .0) : 1 , most preferably from (0.30 to 0.80) : 1 .
- the treatment time of the viscose fiber material with the aqueous suspension or solution of NCC is expediently at least 10 minutes, and may range from 10 to 120 min, preferably from 20 to 90 min, more preferably from 30 to 60 min. A treatment time of more than 120 min is also possible although usually of no technical advantage.
- the temperature applied during said treatment may range from 40 to 130 °C, preferably from 50 to 120 °C, more preferably from 60 to 1 10 °C.
- step (iii) the treated viscose fiber material is washed with water, preferably several times and preferably with distilled water and preferably with water at a temperature of 20 to 40 °C.
- a further treatment with diluted sulfuric acid e.g. with a 1 to 5 % strength by weight sulfuric acid, is carried out at a temperature of between 20 and 40 °C, preferably while ultrasonifying, followed by washing to neutral with water.
- the drying step (iv) is preferably performed at a temperature of between 45 and 75 °C for preferably 2 to 8 hours.
- the present invention further relates to a viscose fiber material wherein the viscose fibers are coated with nanocrystalline cellulose.
- the present invention further relates to a viscose fiber material wherein the viscose fibers are coated with nanocrystalline cellulose by a process as specified above.
- Said viscose fiber material can be any kind of regenerated cellulose, e.g. neat viscose or a blend of viscose with other fiber material, such as polyester or any natural or synthetic fibers.
- the viscose fiber material can be colorless or can be a colored viscose fiber material.
- the colorant is selected from the group consisting of natural colorants derived from plants or animals and synthetic colorants, preferred synthetic colorants being synthetic organic and inorganic dyes and pigments, preferred synthetic organic pigments being azo or disazo pigments, laked azo or disazo pigments or polycyclic pigments, particularly preferably phthalocyanine, diketopyrroiopyrrole, quinacridone, perylene, dioxazine, anthraquinone, thioindigo, diaryl or quinophthalone pigments.
- preferred synthetic colorants being synthetic organic and inorganic dyes and pigments
- preferred synthetic organic pigments being azo or disazo pigments, laked azo or disazo pigments or polycyclic pigments, particularly preferably phthalocyanine, diketopyrroiopyrrole, quinacridone, perylene, dioxazine, anthraquinone, thioindigo, diaryl or quinophthalone pigments.
- the thickness of the neat viscose fibers can be customary, preferably ranging from 5 to 50 pm, more preferably from 10 to 40 pm, even more preferably from 15 to 30 pm.
- the thickness of the NCC coating layer on the viscose fiber is preferably in the range of from 0.5 to 25 pm, more preferably 1 .0 to 20 pm, even more preferably 1 .5 to 15 pm, most preferably 2.0 to 10 pm, especially 2.5 to 8 pm.
- the coated viscose fiber material of the present invention is characterized by a gloss that is enhanced compared to the gloss of the respective uncoated viscose fiber material.
- gloss value enhancements of at least 5 %, preferably at least 10 %, more preferably at least 15 %, measured with a glossmeter at an angle of 60°.
- NCC material used in the following examples was sourced from CelluForce, Canada. Chemically the material is 100 % cellulose hydrogen sulphate sodium salt. It is easily soluble in water in a concentration of 1 to 2 % by weight. For concentrations above 3 % by weight, the solubility in water was improved by providing ultrasonic energy to the dispersion which results in a semi-translucent dispersion.
- Colored viscose fiber (blue) with 150 denier was obtained from Century rayon Industries Mumbai. Copper-phthalocyanin blue was the colorant used to color the viscose fiber.
- a blue colored viscose fiber was wound on plastic plates and the so prepared swatches (weight: 20 g) were processed with an aqueous NCC solution or dispersion in water of different concentrations (Samples I to IV) or without NCC solution (Sample Blank, as comparative) in a Zeltex ® Dyeing Machine.
- the swatches were first kept in a 100 ml metallic bomb reactor containing distilled water or NCC solution (concentrations as of Samples I - IV) and then immersed in an ethylene glycol bath of 20 Liter for 30 - 45 min at 90 - 120 °C. One of these swatches served as blank and as an internal standard for evaluation.
- the swatches (Samples I - IV) were then treated at 90 - 1 10 °C for 30 to 45 min with varying concentrations of aq. suspensions or solutions of NCC of volume 100 ml (cf. Table 1 ).
- the samples I - IV were then washed once with distilled water at room
- the samples were dried at 40 - 60 °C in a drying oven for 4 - 6 hours.
- the dried samples were measured for the gloss using a Minigloss meter supplied by M/s SDL International Textile testing solution.
- the angle of measurement was 60° and the temperature of the measurements was 24 - 26 °C.
- the results are given in Table 1 below.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
La présente invention concerne l'amélioration du brillant spéculaire de fibres de viscose au moyen de cellulose nanocristalline. L'invention concerne un procédé pour conférer un brillant à la surface d'un matériau de fibres de viscose, caractérisée en ce que (v) un matériau de fibres de viscose est immergé dans un milieu hydrophile liquide pour obtenir un matériau de fibres de viscose gonflé, (vi) ledit matériau de fibres de viscose gonflé est traité au moyen d'une suspension ou une solution de cellulose nanocristalline dans un milieu hydrophile liquide, (vii) ledit matériau de fibres de viscose traité est lavé avec de l'eau et éventuellement avec de l'acide sulfurique aqueux, (viii) ledit matériau de fibres de viscose lavé est séché.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15000175.8A EP3048198A1 (fr) | 2015-01-22 | 2015-01-22 | Amélioration du brillant spéculaire de fibre de viscose |
EP15000175.8 | 2015-01-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016116303A1 true WO2016116303A1 (fr) | 2016-07-28 |
Family
ID=52394084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2016/050290 WO2016116303A1 (fr) | 2015-01-22 | 2016-01-08 | Amélioration du brillant spéculaire de fibres de viscose |
Country Status (2)
Country | Link |
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EP (1) | EP3048198A1 (fr) |
WO (1) | WO2016116303A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109750383B (zh) * | 2019-01-29 | 2021-10-26 | 嘉兴学院 | 一种纳米微晶纤维素复合粘胶纤维及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08302566A (ja) * | 1995-04-28 | 1996-11-19 | Toyo Senshoku Kogyo Kk | 再生セルロース系繊維製品の加工法 |
WO2011075837A1 (fr) * | 2009-12-21 | 2011-06-30 | Fpinnovations | Revêtements contenant de la cellulose nanocristalline, procédés de préparation associés et utilisation associée |
CN103161067A (zh) * | 2011-12-13 | 2013-06-19 | 赵建鹏 | 丝光纱液氨处理方法 |
CN103590282A (zh) * | 2012-08-14 | 2014-02-19 | 金东纸业(江苏)股份有限公司 | 涂料及应用该涂料的涂布纸 |
-
2015
- 2015-01-22 EP EP15000175.8A patent/EP3048198A1/fr not_active Withdrawn
-
2016
- 2016-01-08 WO PCT/EP2016/050290 patent/WO2016116303A1/fr unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08302566A (ja) * | 1995-04-28 | 1996-11-19 | Toyo Senshoku Kogyo Kk | 再生セルロース系繊維製品の加工法 |
WO2011075837A1 (fr) * | 2009-12-21 | 2011-06-30 | Fpinnovations | Revêtements contenant de la cellulose nanocristalline, procédés de préparation associés et utilisation associée |
CN103161067A (zh) * | 2011-12-13 | 2013-06-19 | 赵建鹏 | 丝光纱液氨处理方法 |
CN103590282A (zh) * | 2012-08-14 | 2014-02-19 | 金东纸业(江苏)股份有限公司 | 涂料及应用该涂料的涂布纸 |
Non-Patent Citations (3)
Title |
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BIORESOURCES 2012 NORTH CAROLINA STATE UNIVERSITY USA, vol. 7, no. 4, 2012, pages 5190 - 5199 * |
DATABASE COMPENDEX [online] ENGINEERING INFORMATION, INC., NEW YORK, NY, US; 2012, ZHANG H ET AL: "Improvements of mechanical properties and specular gloss of polyurethane by modified nanocrystalline cellulose", XP002742579, Database accession no. E20130515954548 * |
NELSON DURAN ET AL: "Review of Cellulose Nanocrystals Patents: Preparation, Composites and General Applications", RECENT PATENTS ON NANOTECHNOLOGY, 1 January 2012 (2012-01-01), pages 16 - 28, XP055091208, Retrieved from the Internet <URL:http://www.eurekaselect.com/openurl/content.php?genre=article&issn=18722105&volume=6&issue=1&spage=16> [retrieved on 20150722] * |
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Publication number | Publication date |
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EP3048198A1 (fr) | 2016-07-27 |
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