WO2016065888A1 - 可作为织物柔软剂的环保蔗糖聚酯乳液及其制备方法 - Google Patents
可作为织物柔软剂的环保蔗糖聚酯乳液及其制备方法 Download PDFInfo
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- WO2016065888A1 WO2016065888A1 PCT/CN2015/078858 CN2015078858W WO2016065888A1 WO 2016065888 A1 WO2016065888 A1 WO 2016065888A1 CN 2015078858 W CN2015078858 W CN 2015078858W WO 2016065888 A1 WO2016065888 A1 WO 2016065888A1
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- Prior art keywords
- sucrose polyester
- emulsion
- friendly
- environment
- sucrose
- Prior art date
Links
- 229930006000 Sucrose Natural products 0.000 title claims abstract description 70
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 title claims abstract description 70
- 239000005720 sucrose Substances 0.000 title claims abstract description 70
- 229920000728 polyester Polymers 0.000 title claims abstract description 65
- 239000000839 emulsion Substances 0.000 title claims abstract description 57
- 239000002979 fabric softener Substances 0.000 title claims abstract description 7
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000004744 fabric Substances 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- 239000003995 emulsifying agent Substances 0.000 claims description 29
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- 230000032050 esterification Effects 0.000 claims description 13
- 238000005886 esterification reaction Methods 0.000 claims description 13
- 239000010779 crude oil Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000010008 shearing Methods 0.000 claims description 11
- 239000012875 nonionic emulsifier Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 5
- -1 sorbitan fatty acid ester Chemical class 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 3
- 150000002191 fatty alcohols Chemical group 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 230000008569 process Effects 0.000 abstract description 5
- 239000002562 thickening agent Substances 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- 239000007957 coemulsifier Substances 0.000 abstract 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- 238000004945 emulsification Methods 0.000 description 7
- 230000035699 permeability Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000004925 denaturation Methods 0.000 description 2
- 230000036425 denaturation Effects 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
Definitions
- the invention belongs to the technical field of chemical raw materials, and particularly relates to an environment-friendly sucrose polyester emulsion which can be used as a fabric softener and a preparation method thereof.
- SPE has a variety of functions such as oil solubility, fluidity and thixotropy, and the finished cosmetics are non-irritating, non-toxic, and odor-free to the skin. They have good stretchability after rubbing, no shrinkage and sticky feeling, and physiological physiology. No adverse effects.
- SPE has the appearance and taste of edible oils and fats. It is used as an alternative to edible oils and does not produce heat. It is currently the most ideal oil substitute and is widely used in the food industry.
- sucrose polyester emulsion prepared by the alcohol monooleate emulsifier, glycerin, thickener PTF and water can be stored for more than three months for a long time, but the emulsification temperature needs to reach a high temperature of 90 degrees, and the energy consumption is large.
- the addition of thickener seriously affects the application of physicochemical properties and convenient properties of sucrose polyester emulsion.
- the emulsification technology of sucrose polyester still has some defects: the emulsified formula is complicated, the emulsification temperature is high, and the emulsification system is not stable enough. Although the addition of the auxiliary emulsion and the thickener will improve the stability of the emulsion, the application performance is affected and increased. Cost, industrial application value is not big.
- the environmentally friendly sucrose polyester emulsion is characterized in that the emulsion can be used as a fabric softener.
- the prepared emulsion is diluted with water to obtain a solid content-containing finishing liquid.
- the method for applying the environment-friendly sucrose polyester emulsion is characterized in that the solid content of the finishing liquid obtained in the step 1) is 0.1 to 5%; and the liquid carrying rate of the fabric in the step 2) is 80 ⁇ 100%, baking temperature is 80-110 ° C, baking time is 60-180 s.
- the environment-friendly sucrose polyester emulsion is characterized in that the emulsion is composed of the following mass percentage components: sucrose polyester crude oil: 20-50%; nonionic emulsifier: 5-25%; water: 25-75 %.
- the environment-friendly sucrose polyester emulsion characterized in that the nonionic emulsifier is one of a fatty alcohol polyoxyethylene ether, a sorbitan fatty acid ester, a fatty acid methyl ester ethoxylate or an alkyl glycoside or A variety.
- the preparation method of the environment-friendly sucrose polyester emulsion is characterized in that the emulsion is composed of the following mass percentage components: sucrose polyester crude oil: 20-50%; nonionic emulsifier: 5-25%; Water: 25 to 75%, and the emulsion is prepared by the following steps:
- sucrose polyester crude oil by weight ratio, adding sucrose polyester to the mixed liquid of step 1, stirring and mixing well;
- the preparation method of the environment-friendly sucrose polyester emulsion is characterized in that the sucrose polyester crude oil in the step 2) is slowly added to the mixed liquid in the step 1) under stirring; the step 3) The ionized water is added to the mixed liquid in the step 2) at a constant temperature of 60-90 ° C while the high-speed shearing; the deionized water needs to be added within 1 to 5 minutes, and the high-speed shearing rate is 5000 ⁇ . 15000r/min, the total shear time is 3 to 10 minutes.
- the emulsion prepared by the invention can soften various kinds of fabrics such as chemical fiber and cotton spinning as an environmentally-friendly softener, and has no toxicity, no bad stimulation, and environmental protection when used, and can be used as a softener for underwear fabrics or baby clothes. And the emulsion can be softened and completely non-toxic to the hardening of the fabric caused by various reasons in life.
- the invention Compared with the existing preparation process, the invention has the following advantages: the prepared sucrose polyester emulsion has uniform particle size, low viscosity and good stability; no need to add auxiliary emulsion and thickener, cost saving, convenient application; simple process, required Low equipment and manpower; long-term stable storage and transportation, suitable for industrial production.
- the invention prepares a sucrose polyester emulsion with uniform particle size, low viscosity and high stability by using a nonionic emulsifier, and the emulsification temperature is low and the emulsifier is safe in the formulation of the invention.
- a nonionic emulsifier emulsification temperature is low and the emulsifier is safe in the formulation of the invention.
- sucrose oil degree of esterification 6-8) 30%, isomeric tridecyl ethoxylate (1309) emulsifier 10%, sorbitol fatty acid ester (span80) emulsifier 5%, deionized water 55%;
- sucrose polyester obtained is added to the mixture obtained in the step a, and stirred well;
- sucrose polyester emulsion was prepared after high-speed shearing for 3 minutes.
- sucrose oil degree of esterification 6-8 20%, 1309 emulsifier 3%, APG emulsifier 2%, deionized water 75%;
- sucrose polyester obtained is added to the mixture obtained in the step a, and stirred well;
- sucrose oil degree of esterification 6-8 50%, 1309 emulsifier 10%, span80 emulsifier 5%, APG emulsifier 5%, fatty acid methyl ester ethoxylate (FMEE) 5%, deionized 25% water;
- sucrose polyester obtained is added to the mixture obtained in the step a, and stirred well;
- sucrose oil degree of esterification 6-8 30%, 1309 emulsifier 5.09%, span80 emulsifier 2.91%, deionized water 62%;
- the 1309 emulsifier and span80 emulsifier are mixed, and stirred thoroughly until uniform;
- sucrose polyester taken slowly added to the mixture obtained in the step a, fully stirred and mixed;
- step c At 80 ° C, while cutting at a high speed of 10000 r / min, the deionized water is slowly added to the mixture obtained in step b in 1 min, and the high-speed shearing is performed for 3 minutes. Said product.
- sucrose oil degree of esterification 6-8 30%, 1309 emulsifier 4.45%, span80 emulsifier 2.55%, deionized water 63%;
- the 1309 emulsifier and span80 emulsifier are mixed, and stirred thoroughly until uniform;
- sucrose polyester taken slowly added to the mixture obtained in the step a, fully stirred and mixed;
- step c At 80 ° C, while cutting at a high speed of 10000 r / min, the deionized water is slowly added to the mixture obtained in step b in 1 min, and the high-speed shearing is performed for 3 minutes. Said product.
- sucrose oil degree of esterification 6-8 30%, 1309 emulsifier 5.72%, span80 emulsifier 3.28%, deionized water 61%;
- the 1309 emulsifier and span80 emulsifier are mixed, and stirred thoroughly until uniform;
- sucrose polyester taken slowly added to the mixture obtained in the step a, fully stirred and mixed;
- step c At 80 ° C, while cutting at a high speed of 10000 r / min, the deionized water is slowly added to the mixture obtained in step b in 1 min, and the high-speed shearing is performed for 3 minutes. Said product.
- sucrose polyester emulsion prepared in Examples 1, 2, and 3 were weighed separately, diluted with water, and uniformly stirred to obtain a finishing liquid having a solid content of 2% (mass content).
- the fabric is subjected to post-finishing and soft treatment by padding process.
- the process flow is: padding the fabric, the rolling rate is controlled at 100%, and the baking is controlled at 100 ° C for 120 s.
- test method for fabric properties is as follows:
- the fabric softness test was tested by PhabrOmeter fabric intelligent style instrument.
- the softness was characterized by the integrated area of stress-strain curve during the test. The smaller the integral area, the higher the softness.
- the wrinkle performance test was based on GB/T 3819-1997 standard in laser fabric.
- the cotton fabric finished by the product of the present invention has a significantly improved softness and hand feeling compared with the unfinished cotton fabric;
- the sucrose polyester emulsion treated fabric obtained by the embodiment of the present invention has a wrinkle recovery angle significantly higher than that of the original fabric.
- the sucrose polyester emulsion treated fabric obtained by the embodiment of the present invention has a CIE whiteness of 71 to 72, This finishing agent has an effect of improving the whiteness of the fabric.
- the products of the present invention impart excellent softness and whiteness to fabrics.
- the fabric was improved in softness, wrinkle recovery angle and whiteness after treatment with the sucrose polyester emulsion of the present invention.
- the colored cotton fabric which has been finished by the product of the present invention has less color change than the unfinished colored cotton fabric, indicating that the product of the present invention has less influence on the color light of the colored fabric;
- the sucrose polyester emulsion treated fabric obtained by using the embodiment of the present invention is used for treating the fabric.
- the contact angle of the water droplets on the surface of the fabric is greater than 130°, which indicates that the treated fabric has better water repellency;
- the sucrose polyester emulsion treated with the oxidized polyester emulsion obtained in the embodiment of the invention has a slight decrease in gas permeability, indicating that the finishing agent after treatment is
- the adsorption and aggregation of the fabric surface reduces the permeability of the fabric to some extent.
- the product of the invention can impart better water repellency to the fabric, has less influence on the color light, and has less influence on the gas permeability of the fabric.
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Veterinary Medicine (AREA)
- Dispersion Chemistry (AREA)
- Birds (AREA)
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
一种用于织物柔软剂的环保蔗糖聚酯乳液及其制备方法。所制备的蔗糖聚酯乳液粒度均匀、粘度低、稳定性佳；无需添加助乳剂和增稠剂，节约成本，应用便捷；工艺简单，所需设备和人力少；可长期稳定的储运，适合工业化生产。
Description
本发明属于化工原料技术领域，具体涉及一种可作为织物柔软剂的环保蔗糖聚酯乳液及其制备方法。
高酯化度(即酯化度n＝6～8)的蔗糖聚酯(SPE)多用来作为化妆品的油性基料。SPE有充分的油溶性、流动性及触变性等多种功能，且制成的化妆品对皮肤无刺激、无毒、无异味，涂擦后伸展性好，无收缩发粘的感觉，对人体生理无不良影响。另外，SPE具有食用油脂的表观性能和口感，用来代替食用油不会产生热量，是目前最为理想的油脂替代品，在食品行业里得到广泛利用。
目前，纺织行业多采用有机季铵盐和硅油类物质作为织物柔软剂，但上述两者生物可降解性差。使用SPE作为柔软剂，将有望解决上述问题。但SPE不溶于水、比重较水略小且分子量高达到2400，因此需要研究SPE的乳化性能和乳液制备方法。目前很少有关于SPE乳化方面的研究，且制备的乳液稳定性和应用性能欠佳。王新力(11-5167/TS)等研究了以蔗糖聚酯(酯化度n＝6～8)、MOA-9(脂肪醇与环氧乙烷缩合物)乳化剂、Span80(失水山梨糖醇单油酸酯)乳化剂、丙三醇、增稠剂PTF和水制备的蔗糖聚酯乳液，能够长期保存三个月以上，但其乳化温度需达到90度的高温，耗能较大，另外增稠剂的加入严重影响了蔗糖聚酯乳液的应用理化性能和便捷性能。除此之外很少有其他关于蔗糖聚酯乳化的文献。可见目前蔗糖聚酯的乳化技术仍存在一些缺陷：乳化配方复杂、乳化温度高、乳化体系不够稳定，虽然助乳剂和增稠剂的加入会提高乳液稳定性，但其应用性能受到影响，且增加成本，工业应用价值不大。
发明内容
针对现有技术存在的问题，本发明的目的在于设计提供一种环保蔗糖聚酯乳液，可作为织物柔软剂使用。
所述的一种环保蔗糖聚酯乳液，其特征在于该乳液可作为织物柔软剂使用。
所述的环保型蔗糖聚酯乳液，其特征在于该乳液采用蔗糖聚酯原油制成，所述的蔗糖聚酯原油为高酯化度蔗糖聚酯，酯化度n＝6～8。
所述的环保型蔗糖聚酯乳液的应用方法，其特征在包括以下步骤：
1)将制备得到的乳液加水稀释得到一定含固量的整理液。
2)将织物浸轧，焙烘一定时间。
所述环保型蔗糖聚酯乳液的应用方法，其特征在于所述的步骤1)中所得到的整理液的含固量为0.1～5％；所述的步骤2)中织物带液率为80～100％，焙烘温度为80～110℃，焙烘时间为60～180s。
所述的环保型蔗糖聚酯乳液，其特征在于该乳液由以下质量百分比的组分构成：蔗糖聚酯原油：20～50％；非离子型乳化剂：5～25％；水：25～75％。
所述的环保型蔗糖聚酯乳液，其特征在于所述的非离子型乳化剂为脂肪醇聚氧乙烯醚、山梨醇脂肪酸酯、脂肪酸甲酯乙氧基化物、烷基糖苷的一种或多种。
所述的一种环保型蔗糖聚酯乳液的制备方法，其特征在于该乳液由以下质量百分比的组分构成：蔗糖聚酯原油：20～50％；非离子型乳化剂：5～25％；水：25～75％，并且该乳液通过包括以下步骤制得：
1)按重量比称取一种或多种非离子乳化剂，充分搅拌至均匀；
2)按重量比取蔗糖聚酯原油，将蔗糖聚酯添加到步骤1的混合液中，充分搅拌混合均匀；
3)按重量比取去离子水，将去离子水加入到步骤2的混合液中，高速剪切
后即可制得所述蔗糖聚酯乳液。
所述环保型蔗糖聚酯乳液的制备方法，其特征在于所述的步骤2)中的蔗糖聚酯原油是在搅拌条件下缓慢加入到步骤1)中的混合液中；步骤3)中的去离子水是在一定温度60-90℃下，在高速剪切的同时加入到步骤2)中的混合液中；去离子水需在1～5min中内添加完毕，高速剪切的速率是5000～15000r/min，剪切总时间是3～10min。
本发明制得的乳液作为环保柔软剂时可以对化纤、棉纺等各类布料进行较好的软化，使用时无毒害、无不良刺激、绿色环保，可以作为贴身内衣面料或婴儿服饰的软化剂使用，而且该乳液可以对生活中多种原因造成的布料硬化，进行柔软，完全无毒害。
本发明与现有制备工艺相比有如下优点：所制备的蔗糖聚酯乳液粒度均匀、粘度低、稳定性佳；无需添加助乳剂和增稠剂，节约成本，应用便捷；工艺简单，所需设备和人力少；可长期稳定的储运，适合工业化生产。
本发明通过使用非离子型乳化剂将蔗糖聚酯和去离子水制作出一种粒度均匀、低粘度、稳定性高的蔗糖聚酯乳液，且本发明配方中，乳化温度较低、乳化剂安全无毒、工艺简单、应用方便且能够长期稳定储藏，适合工业化生产。
实施例一
按重量比取蔗糖油脂(酯化度6～8)30％、异构十三醇聚氧乙烯醚(1309)乳化剂10％、山梨醇脂肪酸酯(span80)乳化剂5％、去离子水55％；
a将所取1309乳化剂和span80乳化剂进行混合，充分搅拌至均匀；
b在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c在60℃下，在高速(10000r/min)剪切的同时，将所取去离子水在1min
中内缓慢加入到步骤b所得的混合液中，共高速剪切3分钟后即可制得所述蔗糖聚酯乳液。
实施例二
按重量比取蔗糖油脂(酯化度6～8)20％、1309乳化剂3％、APG乳化剂2％、去离子水75％；
a将所取1309乳化剂和蔗糖聚酯乳化剂进行混合，充分搅拌至均匀；
b在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c在90℃下，在高速(5000r/min)剪切的同时，将所取去离子水在5min中内缓慢加入到步骤b所得的混合液中，共高速剪切10分钟后即可制得所述蔗糖聚酯乳液。
实施例三
按重量比取蔗糖油脂(酯化度6～8)50％、1309乳化剂10％、span80乳化剂5％、APG乳化剂5％、脂肪酸甲酯乙氧基化物(FMEE)5％，去离子水25％；
a将所取乳化剂进行混合，充分搅拌至均匀；
b在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c在80℃下，在高速15000r/min剪切的同时，将所取去离子水在3min中内缓慢加入到步骤b所得的混合液中，共高速剪切8分钟后即可制得所述蔗糖聚酯乳液。
实施例四
按重量比取蔗糖油脂(酯化度6～8)30％、1309乳化剂5.09％、span80乳化剂2.91％、去离子水62％；
a、将所取1309乳化剂和span80乳化剂进行混合，充分搅拌至均匀；
b、在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c、在80℃下，在高速10000r/min剪切的同时，将所取去离子水在1min中内缓慢加入到步骤b所得的混合液中，共高速剪切3分钟后即可制得所述产品。
实施例五
按重量比取蔗糖油脂(酯化度6～8)30％、1309乳化剂4.45％、span80乳化剂2.55％、去离子水63％；
a、将所取1309乳化剂和span80乳化剂进行混合，充分搅拌至均匀；
b、在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c、在80℃下，在高速10000r/min剪切的同时，将所取去离子水在1min中内缓慢加入到步骤b所得的混合液中，共高速剪切3分钟后即可制得所述产品。
实施例六
按重量比取蔗糖油脂(酯化度6～8)30％、1309乳化剂5.72％、span80乳化剂3.28％、去离子水61％；
a、将所取1309乳化剂和span80乳化剂进行混合，充分搅拌至均匀；
b、在搅拌条件下，将所取蔗糖聚酯缓慢加到步骤a中所得混合液中，充分搅拌混合均匀；
c、在80℃下，在高速10000r/min剪切的同时，将所取去离子水在1min中内缓慢加入到步骤b所得的混合液中，共高速剪切3分钟后即可制得所述产品。
实施例七
分别称取实施例一、二、三制备的蔗糖聚酯乳液30g，加水稀释，搅拌均匀，得到含固量为2％(质量含量)的整理液。采用浸轧工艺对织物进行后整理柔顺处理，工艺流程为：将织物浸轧，轧余率控制在100％，100℃焙烘120s。
织物性能的测试方法如下：
织物柔软性测试采用PhabrOmeter织物智能风格仪测试，柔软度以测试过程中应力应变曲线积分面积来表征，积分面积越小，柔软度越高；折皱性能测试参照GB/T 3819-1997标准在激光织物折皱弹性测试仪上测试；色黄变性测试，耐热黄变性采用SC－80轻便色彩色差计测试经柔软处理后织物的白度，色变性采用datacolor测配色仪测试经柔软处理后色布的△E，△E绝对值越小，对色变影响越小；拒水性测试以水滴在织物表面的接触角表征，采用静态接触角测试仪测试；透气性按照国家标准GB/T 5453-1997，在YG461D型数字式织物透气量仪上测试，选定压差为100pa，合适孔板。
在并行比较中测试了TF-449B(对比例1)、TF-442(对比例2)处理过的织物的性能，测试结果见表1和表2。
表1 柔软、折皱回复角、黄变测试数据
由表1可知：经过本发明产物整理后的棉织物较未经整理的棉织物的柔软度、手感有显著提高；应用本发明实施例所得蔗糖聚酯乳液处理织物，折皱回复角较原布显著增大，说明处理后的织物动静摩擦系数降低，引起折皱回复角增大；应用本发明实施例所得蔗糖聚酯乳液处理织物，其CIE白度达到71～72，
说明该整理剂对织物白度具有提升作用。综合来说，本发明产物能赋予织物优异的柔软性、白度。
相较于TF-449B(对比例1)、TF-442(对比例2)，采用本发明所述蔗糖聚酯乳液处理后织物在柔软度、折皱回复角、白度均有所改善。
表2 色变、接触角、透气性测试数据
由表2可知：经过本发明产物整理后的有色棉织物较未整理有色棉织物色变性小，说明本发明产物对色织物的色光影响较小；应用本发明实施例所得蔗糖聚酯乳液处理织物，水滴在织物表面的接触角都大于130°，说明处理后的织物具有较好的拒水性；应用本发明实施例所得蔗糖聚酯乳液处理织物，透气性稍有降低，说明处理后整理剂在织物表面吸附聚集，一定程度降低了织物透气性。综合来说，本发明产物能赋予织物较好拒水性，对色光影响小，对织物透气性影响小。
相较于TF-449B(对比例1)、TF-442(对比例2)，采用本发明所述蔗糖聚酯乳液处理后织物在色光、拒水性、透气性均有所改善。
Claims (8)
- 一种环保蔗糖聚酯乳液，其特征在于该乳液可作为织物柔软剂使用。
- 根据权利要求1所述的环保型蔗糖聚酯乳液，其特征在于该乳液采用蔗糖聚酯原油制成，所述的蔗糖聚酯原油为高酯化度蔗糖聚酯，酯化度n＝6～8。
- 一种如权利要求1-2之一的所述的环保型蔗糖聚酯乳液的应用方法，其特征在包括以下步骤：1)将制备得到的乳液加水稀释得到一定含固量的整理液。2)将织物浸轧，焙烘一定时间。
- 根据权利要求3所述环保型蔗糖聚酯乳液的应用方法，其特征在于所述的步骤1)中所得到的整理液的含固量为0.1～5％；所述的步骤2)中织物带液率为80～100％，焙烘温度为80～110℃，焙烘时间为60～180s。
- 根据权利要求1所述的环保型蔗糖聚酯乳液，其特征在于该乳液由以下质量百分比的组分构成：蔗糖聚酯原油：20～50％；非离子型乳化剂：5～25％；水：25～75％。
- 根据权利要求1所述的环保型蔗糖聚酯乳液，其特征在于所述的非离子型乳化剂为脂肪醇聚氧乙烯醚、山梨醇脂肪酸酯、脂肪酸甲酯乙氧基化物、烷基糖苷的一种或多种。
- 一种环保型蔗糖聚酯乳液的制备方法，其特征在于该乳液由以下质量百分比的组分构成：蔗糖聚酯原油：20～50％；非离子型乳化剂：5～25％；水：25～75％，并且该乳液通过包括以下步骤制得：1)按重量比称取一种或多种非离子乳化剂，充分搅拌至均匀；2)按重量比取蔗糖聚酯原油，将蔗糖聚酯添加到步骤1的混合液中，充分搅拌混合均匀；3)按重量比取去离子水，将去离子水加入到步骤2的混合液中，高速剪切 后即可制得所述蔗糖聚酯乳液。
- 根据权利要求7所述环保型蔗糖聚酯乳液的制备方法，其特征在于所述的步骤2)中的蔗糖聚酯原油是在搅拌条件下缓慢加入到步骤1)中的混合液中；步骤3)中的去离子水是在一定温度60～90℃下，在高速剪切的同时加入到步骤2)中的混合液中；去离子水需在1～5min中内添加完毕，高速剪切的速率是5000～15000r/min，剪切总时间是3～10min。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103340242A (zh) * | 2013-07-18 | 2013-10-09 | 北京中科邦尼国际科技有限责任公司 | 用于奶茶的组合物、奶茶及其制备方法 |
| CN104024392A (zh) * | 2011-06-10 | 2014-09-03 | 宝洁公司 | 个人护理组合物 |
| CN104342931A (zh) * | 2014-10-27 | 2015-02-11 | 浙江理工大学 | 一种适用于贴身织物的环保型柔软剂及其制备方法 |
| CN104356401A (zh) * | 2014-10-27 | 2015-02-18 | 浙江理工大学 | 一种环保型高酯化度蔗糖聚酯乳液及其制备方法 |
-
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104024392A (zh) * | 2011-06-10 | 2014-09-03 | 宝洁公司 | 个人护理组合物 |
| CN103340242A (zh) * | 2013-07-18 | 2013-10-09 | 北京中科邦尼国际科技有限责任公司 | 用于奶茶的组合物、奶茶及其制备方法 |
| CN104342931A (zh) * | 2014-10-27 | 2015-02-11 | 浙江理工大学 | 一种适用于贴身织物的环保型柔软剂及其制备方法 |
| CN104356401A (zh) * | 2014-10-27 | 2015-02-18 | 浙江理工大学 | 一种环保型高酯化度蔗糖聚酯乳液及其制备方法 |
Non-Patent Citations (3)
| Title |
|---|
| SHEN, JINYU ET AL.: "Research and Exploitation of Sucrose Polyesters", JOURNAL OF TSINGHUA UNIVERSITY ( SCIENCE AND TECHNOLOGY, vol. 39, no. 12, 10 December 1999 (1999-12-10), pages 16 - 18 and 22 * |
| WANG, XINLI ET AL.: "Study on Preparation and Soft Application on Cotton of Sucrose Polyester Emulsion", JOURNAL OF TEXTILE RESEARCH, vol. 34, no. 5, 30 May 2013 (2013-05-30), pages 90 - 94 * |
| WANG, XINLI: "Study and Application of Sucrose Polyester in Fabric Finishing", SCIENCE -ENGINEERING (A), CHINA MASTER'S THESES FULL-TEXT DATABASE, 15 December 2013 (2013-12-15), pages 2, 16, 20 and 30 - 32 * |
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