WO2016015112A1 - Pre- and post-emergence, broad-range herbicidal formulation containing triazolinones associated with urea pesticides, and weed-control and harvest yield increasing methods - Google Patents
Pre- and post-emergence, broad-range herbicidal formulation containing triazolinones associated with urea pesticides, and weed-control and harvest yield increasing methods Download PDFInfo
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- WO2016015112A1 WO2016015112A1 PCT/BR2015/000112 BR2015000112W WO2016015112A1 WO 2016015112 A1 WO2016015112 A1 WO 2016015112A1 BR 2015000112 W BR2015000112 W BR 2015000112W WO 2016015112 A1 WO2016015112 A1 WO 2016015112A1
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- poe
- formulation
- formulation according
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- urea
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- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 210000000805 cytoplasm Anatomy 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- MSJMDZAOKORVFC-UAIGNFCESA-L disodium maleate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C/C([O-])=O MSJMDZAOKORVFC-UAIGNFCESA-L 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 230000003859 lipid peroxidation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 229950006238 nadide Drugs 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229950003776 protoporphyrin Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000005478 southern crabgrass Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 244000277848 tiririca Species 0.000 description 1
- 235000012184 tortilla Nutrition 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 229940035893 uracil Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
Definitions
- the present invention relates to a broad spectrum herbicide for application at different sugarcane seasons, namely wet, semi-dry, dry and semi-wet season.
- the present invention also relates to herbicide formulations comprising triazolinones in association with substituted urea pesticides.
- the invention also relates to a method for controlling weeds and their effects on crop development and a method for increasing crop yield.
- REPLACEMENT SHEET decumbens
- marmalade grass Bosset grass
- grasshopper Pieris maximum
- cushiongrass species Digitaria norizontat ⁇ s, Digitaria nuda. Digitaria bicornis, Digitaria ciliares and Digitaria sp
- Brachiaria brizantha Brachiaria grass
- Brachiaria grass Eleusine indica
- tick-like caplm Cenchrus ech ⁇ natus
- weed species are characterized by the presence of broadleaves, such as the different species of caruru (Amaranthus sp) and purslane (Portufaca oleracea), among others, which are often found in areas of sugarcane in soils.
- broadleaves such as the different species of caruru (Amaranthus sp) and purslane (Portufaca oleracea), among others, which are often found in areas of sugarcane in soils.
- filter tortilla is used as part of fertilizer, and plants that have been selected by some commonly used herbicides such as mussambê (Cleom ⁇ s affinis) and dairy (Euphorbia heterophylla) and / or in environments of raw cane, such as bougain (Conyza sp), white worm (Parthenium hysterophorus), milk donkey (Chamaescyce hyssopifol ⁇ a), and * rola grass (Croton lobatus) and red mallow (Croton glandulosus).
- a number of weed species popularly known as ropes de vioia have been prominent in the sugarcane infesting communities, particularly in raw cane harvesting areas.
- Ipomoea and Merremia belong to the genera Ipomoea and Merremia, from the Convolvulaceae family.
- Ipomoea stand out: I. hederifolia, I. quamocl ⁇ t, I. nil, I. grandifotia and 1, purple, while in the genus Merremta stand out M, cissoides and M, aegyptia.
- REPLACEMENT SHEET (RULE 26) entails a significant reduction in crop yield (reductions of 20 to 80% in yield), in addition to providing other negative aspects such as decreases in sugarcane longevity (reduction of 2 to 3 crop cuttings or cycles) »reduction in raw material quality and difficulty in harvesting and transport operations. Thus it is evident the need for efficient strategies to control the weeds of the crop.
- herbicide selectivity is very desirable in agriculture, allowing to eliminate unwanted pests and plants without damaging the main crop.
- the present invention provides a novel pesticide combination which has broad spectrum control for all sugarcane seasons.
- the product of the present invention is the first broad spectrum herbicide for all sugarcane seasons. Inefficient control is now done using the Dinamic tank mix (Amicarbazone 700 g / kg - Arysta UfeScience). more Combine (Tebutiuron 500 g / L - Dow AgroSciences) or Plateau (Imazapic 700 g / kg - BASF) more Combine (Tebutiuron 500 g / L - Dow AgroSciences),
- the formulation of the present invention works by two different modes of action: inhibition of protoporphyrinogen oxidase (PPO) and inhibition of photosynthesis in photosystem II (PS II). Inhibition of protoporphyrinogen oxidase in the presence of light will cause cell membrane rupture and irreversible cell damage while inhibition of photosynthesis causes leaf necrosis.
- PPO protoporphyrinogen oxidase
- PS II photosystem II
- PPO Protoporphyrinogen Oxidase IX
- PPO Protoporphyrinogen Oxidase IX
- PPO is present in the synthesis route of chlorophyll and cytochromes, also called the synthesis route of porphyrins or tetrapyrroles (Merotto & Vidal, 2001).
- the mechanism of action of PPO inhibitor herbicides is based on the inhibition of the transformation reaction of protoporphyrinogen into protoporphyrin. This reaction is catalyzed by
- REPLACEMENT SHEET (RULE 26) PPO. With the inhibition of this enzyme, present in the chloroplast, there is an accumulation of protoporphyrinogen that moves from chloroptasto to the cytoplasm and in contact with oxygen, in the presence of light, forms free radicals (singlet oxygen) causing membrane lipid peroxidation. that causes the damage. To date a weed biotype resistant to these herbicides has been detected in agriculture, so the probability of selection is restricted (Weed Science, 2003).
- suffentrazone After soil applications, suffentrazone is absorbed through the roots. It may remain on the surface of the soil for 10 to 14 days or more, however it requires constant rainfall, irrigation or soil preparation to pass below the surface and activate the herbicide. Weed control may be reduced if sulfentrazorta is not activated in a timely manner. If sutfentrazone is associated with tebutiuron, this need decreases.
- Tebutiuron is a non-selective broad spectrum herbicide. Tebutiuron is absorbed by the roots and transported to the leaves »where it inhibits photosynthesis.
- Herbicides that are currently in use and have a mechanism of action to inhibit photosynthesis belong to three main chemical groups: triazines. Substituted urea and uracil. The site of action of these herbicides is on the chloroplast membrane, where the light phase of photosynthesis occurs, more specifically in the transport of electrons (Christoffoleti, 1997). A plant is susceptible to photosynthesis inhibiting herbicides if the herbicide mates with the photosynthetic system's plastoquinone compound (QB) and thus makes it impossible for electron transport to occur.
- QB photosynthetic system's plastoquinone compound
- Herbicidal combinations are often used to broaden the spectrum of the herbicide, increasing control and synergistic effect on weeds,
- Pi 0417671-5 relates to a method for controlling coniferous plants, in particular naturally seeded coniferous plants (wild conifers ⁇ , wherein an effective amount of at least one herbicide selected from the group consisting of sulfentrazone, Carfentrazone, its agriculturally acceptable salts and its agriculturally acceptable derivatives are applied to the coniferous plants to be controlled or to parts thereof such as roots, leaves or germinations,
- Pi 9704565-9 relates to selective herbicides comprising a carbamoyl triazolinone compound and one or more herbicidal compounds selected from amethrin, tebutfuron, hexazinone, isoxaflutol metribuzin, sulfentrazone and / or diuron.
- Pi 0710376-0 relates to a mixture of diuron with mesotrione, optionally containing other herbicides such as tebutiuron and sulfentrazone. Also described is a herbicidal composition comprising diuron, mesotrione and, optionally, other herbicides such as hexazinone and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents. unwanted vegetation comprising applying on the spot the vegetation of a herbicidally effective amount of the mixture.
- US 2002004457 relates to a synergistic herbicidal composition for controlling broadleaf and grassy weeds in
- REPLACEMENT SHEET (RULE 26) useful plant cultures resistant to protoporphyrinogen inhibitors oxtdase, which comprise, in addition to the usual formulation aids Inert, as active compounds a) a herbicide that inhibits the action of protoporphyrinogen oxidases and b) at least one additional pesticide selected from the group consisting of in co-herbicides, fungicides and insecticides / acaritides.
- the present invention relates to a broad spectrum herbicidal formulation for controlling the most important sugarcane weeds during all seasons.
- the formulation of the present invention provides better control more efficient than all commercial sugarcane herbicides by working through two different modes of action.
- an improved blend of herbicides has been developed, in particular a formulation comprising the combination of two of the most important active ingredients used in sugarcane, ie triazolinones, especially sulfentrazone, and pesticides.
- urea especially tebutiuron, resulting in better and more efficient control, being a broad spectrum herbicide for all sugarcane stations,
- Figure 1 refers to the times of application in sugar cane.
- Figure 2 refers to a graph showing the results obtained in the control of the sugarcane. in the dry season. with the application of the composition of the present invention versus the combination of other herbicides.
- the Flg. 2 shows that the formulation of the present invention has excellent effectiveness in controlling Digitaria sp in the dry season.
- Figure 3 refers to a graph showing the results obtained in the
- REPLACEMENT SHEET (RULE 26) control of sugarcane in the dry season with the application of the composition of the present invention versus the combination of other herbicides.
- the Fig. 3 shows that the formulation of the present invention has a much superior control of Ipomoea nil over the control of the Plateau + Combine herbicide mixture.
- Figure 4 is a graph showing the results obtained in the control of plant cane during the wet season with the application of the composition of the present invention versus the combination of other herbicides.
- Fig. 4 shows that the formulation of the present invention shows excellent control of Amaranthus sp 90 days after application as compared to other herbicide mixtures.
- Figure 5 is a graph showing the results obtained in the control of the sugarcane during the wet season with the application of the composition of the present invention versus the combination of other herbicides.
- Fig. 5 shows that the formulation of the present invention shows excellent control of Digitaria sp. 90 days after being applied as compared to other herbicide mixtures.
- the present invention relates to a broad spectrum herbicidal formulation for all seasons.
- the formulation of the present invention comprises triazolinones in urea pesticide sedimentation, resulting in better and more efficient control than all commercial sugarcane herbicides.
- the present invention relates to a formulation that provides improved handling properties with broad spectrum control for all sugarcane seasons.
- Triazolinone group herbicides particularly suiferrtrazone
- Ural group herbicides particularly tebutiuron
- One of the advantages of the formulation of the present invention is to provide better and more efficient control than all commercial sugarcane herbicides, including Dinamic (Amicarbazone 700 g / kg - Arysta LifeScence) mate.
- REPLACEMENT SHEET Combine (Tebutiuron 500 g / L - Dow AgroSciences) and Plateau (imazapic 700 g / Kg - BASF) plus Combine (Tebutiuron 500 g / L - Dow AgroSciences).
- Another advantage of the formulation of the present invention is related to safety for application in the field, since the farmer is able to apply the formulation of the present invention as a concentrated suspension with better convenience and safety, since the formulation is non flammable, has low toxicity and high concentration of active ingredient.
- Another advantage of the present invention is to work with the association of two herbicidal molecules that act on different mechanisms of action, namely suifentrazone which is a PPO inhibitor and tebutiuron which is a PSII inhibitor in a high performance formulation. control of the main weeds in the sugarcane crop.
- the formulation has high solubility, providing excellent weed control in both cane and cane in humid, semi-humid, semi-dry and dry seasons.
- the herbicide association in the present invention is based mainly on the triazolinone group herbicides, more preferably sulfentrazone and the urea herbicides, more particularly tebutiuron. Both suifentrazone and tebutiuron are highly effective in weed control, and their complementary efficacy when used in combination in the same formulation, which is not observed when applied individually,
- Herbicides from the urea group are selected from the group consisting of tebutiuron, Diuron, Chlrotoluron. Dimefuron, Fluometuron, Isoproturon, Isouron, Karbutylate, Linuron, Metabenzthiazuron, Metobenzuron, Methoxuron, Monolinuron, Neburon, Siduron, and mixtures thereof.
- Herbicides from the triazolinone group are selected from the group consisting of sulfentrazone, amicarbazone, carfentrazone and azafenld ⁇ n.
- the present invention is directed to a formulation comprising:
- the present invention relates to a formulation comprising;
- At least one herbicidal pesticide triazolinone group selected from sulfentrazone. amicarbazone or carfentrazone;
- At least one herbicidal pesticide from the group of urea selected from Tebutiuron, Diuron, Chlrotoluron, Dimefuron, Ruometuron, Isoproturon, Isouron, Karbutylate, Linuron, Methabenzthiazuron, Metobenzuron, Metoxuron, Nebon, Sidonuron, Mebonuron, Monolon
- the present invention is directed to a formulation comprising:
- acrylic polymer which may include acrylic styrene polymer, modified acrylic styrene polymer, acrylic copolymer solution, nonionic random polymer, amphoteric polymeric dispersant, polyester / polyamine condensation polymer, sodium polyacrylate, acrylic acid copolymer sodium salt maleic acid, maleic acid / olefin copolymer sodium salt, polycarboxylate sodium salt, vinylpyrrolidone homopolymer, vinylpyrrolidone / vinylacetate copolymer; and
- lignin such as sodium and calcium isosulfonate
- tristirylphenols which may include: tristiriphenol POE (10); tristirylphenoi POE (16); tristyrilphenol POE (20); tristiriffenol POE (25); tristirylphenyl POE (40); tristiriphenol POE (54); distyrylphenol POE (8); distalphenyl POE (13); distyrylphenol POE (17); tristirilpheno ⁇ POE - POP; POE polyaryl phosphate ester (16); POE polytaryl phosphate ester amine salt (16); POE polyaryl phosphate ester potassium salt (16); polyalkylene oxide copolymer tristirylphenyl; tristirylphenol ethoxylated phosphate ester triethylamine salt-POE 16; and
- REPLACEMENT SHEET (RULE 26) Hl) additives to stabilize the formulation, such as antifreeze (glycol or urea), stabilizing agents (gum or mineral products selected from silicates, silicon oxide and bentonite), preservatives and antifoam agents.
- antifreeze glycol or urea
- stabilizing agents such as silicates, silicon oxide and bentonite
- preservatives and antifoam agents such as sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite, sodium metabisulfite
- the present invention relates to a sulfentrazone-based herbicidal formulation mixed primarily with tebutiuron at a coricentrication of 26.5 g / l to 760 g / l. more preferably 265 g / l sulfentrazone and 31 g / l to 750 g / l, more preferably 310 g / l tebutiuron.
- the formulation is in the form of wettable granules, wettable powder, powder, microencapped, leaf, furrows, concentrated solution, dispersible oil and emulsifiable concentrate.
- the formulation of the present invention is in the form of suspension, wettable powder (WP), oil dispersion (OO), emulsifiable concentrate (EC) or dispersible granule (WDG).
- WP wettable powder
- OO oil dispersion
- EC emulsifiable concentrate
- WDG dispersible granule
- the formulation is an aqueous suspension comprising sulfentrazone and tebutiuron.
- Sulfentrazone and tebutiuron may be present in any desired amount.
- the formulation of the present invention is diluted with water to prepare homogeneous solutions for application to the leaves of a plant to exterminate or control plant growth.
- the present invention is also directed to methods of making and using the formulations of the present invention.
- the formulation of the present invention may be applied by any conventional method, such as powder, in microencapsulated leaf grooves, as a wettable powder, as a wettable granule, as a concentrated solution or dispersible oil.
- the present invention also relates to a method for efficient control of different weeds, such as the grass-mattress complex.
- REPLACEMENT SHEET (RULE 26) (Digitaria hortzontalis, Digitaria nuda and others), colonization grass (Panicum maximum), brachiaria grass (Brachiaria decumbens), viola string (Ipomoea grandifoia, Ipomoea nil ipomoea quamoclit, Ipomoea purpurea, Merremia cissoWes and Merremia aes), black prick (Bidens pilosa), tiririca (Cyperus rotundus and Cyperus spp), chicken grass (Eleusina indica), tick grass (Cenchrus Echinatus), mucuna (Mucuna pruriens), dairy (Euphorbia heterophylia), among others. other weed species as described in the tables below, comprising applying the formula of the present invention to plants.
- the present invention also relates to a method for reducing weed competition for water, light and nutrients with sugarcane cultivation, thereby favoring early crop development, yield and increasing crop yield. harvesting and longevity of sugarcane, comprising applying the formulation of the present invention to weeds.
- the invention also relates to the use of the formulation of the present invention in the control of weeds and unwanted pests, as cited above and detailed in the table below.
- Table 3 illustrates the effective control of each mixture or formulation in the respective culture and time after application.
- the present invention has a superior control (A) than Market (D) imazapic 700 g / kg + Tebutiuron 500 g / L treatment and (H) Diuron 603 g / kg + Hexazinone 170 g / kg.
- A superior control
- D imazapic 700 g / kg + Tebutiuron 500 g / L treatment
- H Diuron 603 g / kg + Hexazinone 170 g / kg.
- the mixture of triazolinone and urea herbicide pesticides showed positive results in the control of both pests in the dry and planting season.
- REPLACEMENT SHEET (RULE 26) List of target weeds in which the formulation containing sulféntrazone and Tebutiuron will be registered for sugarcane crop.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a broad-range herbicidal formulation for controlling weeds (true grasses, broad-leaved weeds, morning glories, inter alia) in sugar cane plantations, with high flexibility and versatility, recommended in all seasons (wet, semi-wet, dry and semi-dry), comprising at least one herbicidal pesticide selected from the group of the triazolinones and at least one herbicidal pesticide selected from the group of the ureas. The present invention further relates to methods for controlling undesirable weeds, comprising the application of the formulation of the present invention to the plants, thus providing a faster initial development of the crop, better production levels and an increase in harvest yield, besides a longer life of the sugar cane plantation.
Description
"FORMULAÇÃO HERBICIDA DE AMPLO ESPECTRO PRE E PÓS EMERGÊNCIA CONTENDO TRIAZOLINONAS EM ASSOCIAÇÃO COM PESTICIDAS DE UREIA E MÉTODOS PARA O CONTROLE DE PLANTAS DANINHAS E PARA AUMENTAR O RENDIMENTO DA COLHEITA". "HERBICIDE FORMULATION OF LARGE PRE AND POST EMERGENCY CONTAINING TRIZOLINONES IN ASSOCIATION WITH UREA PESTICIDES AND METHODS FOR WEED CONTROL AND TO INCREASE HARVEST Yield".
CAMPO DA INVENÇÃO FIELD OF INVENTION
[0001] A presente invenção está relacionada a um herbicida de amplo espectro para aplicação nas diferentes épocas de cana-de-açúcar, a saber, épocas úmida, semí-seca, seca e semi-úrnida. A presente invenção também está relacionada a formulações de herbicidas compreendendo triazolinonas em associação com os pesticidas de ureia substituídas. A invenção também se refere a um método para controlar plantas daninhas e seus reflexos no desenvolvimento da cultura e a um método para aumentar o rendimento da colheita. [0001] The present invention relates to a broad spectrum herbicide for application at different sugarcane seasons, namely wet, semi-dry, dry and semi-wet season. The present invention also relates to herbicide formulations comprising triazolinones in association with substituted urea pesticides. The invention also relates to a method for controlling weeds and their effects on crop development and a method for increasing crop yield.
FUNDAMENTOS DA INVENÇÃO BACKGROUND OF THE INVENTION
[0002] O controle de gramíneas Panicum, Digitaria, Amaranthus e Ipomoeaand em culturas de vaior tem sido um problema continuo. O Brasil é o maior produtor de cana«de-açúcar do mundo, moendo aproximadamente 640 milhões de toneladas de cana-de-açúcar por ano e com área de 9 milhões de hectares* As regiões Sudeste com 60% (somente o Estado de São Paulo contribui com 52% dessa área) e Nordeste com 21% da área total plantada, são as maiores regiões produtoras do País. Nessas duas regiões, a produtividade média é de 78 e 55 t.ha-1, respectivamente, Somente no Brasil, estima-se um mercado anual de 12 milhões de dólares para a caria de açúcar. Control of Panicum, Digitaria, Amaranthus, and Ipomoeaand grasses on cow crops has been an ongoing problem. Brazil is the largest sugarcane producer in the world, grinding approximately 640 million tons of sugarcane per year and with an area of 9 million hectares * The 60% Southeast regions (São Paulo State only) Paulo contributes 52% of this area) and Northeast with 21% of the total planted area, are the largest producing regions of the country. In these two regions, the average productivity is 78 and 55 t.ha-1, respectively. An annual market of $ 12 million is estimated for the sugarcane.
[0003] Há uma clara tendência de aumento da área cultivada com cana-de- açúcar no Brasil que atualmente é de 9 milhões de hectares. Um dos pontos mais críticos no processo produtivo da cana-de-açúcar é a interferência negativa imposta peias plantas daninhas que infestam as áreas cultivadas. Essas plantas competem pelos recursos límitanies do meio, liberam substâncias alelopátícas e podem ainda hospedar pragas e doenças comuns a cultura, além de interferirem no rendimento. Nas regiões Centro-Sul e Nordeste, destacam-se algumas gramíneas em áreas tradicionais de cuítivo de cana-de-açúcar como o capím-braquiária (Brachtaria [0003] There is a clear trend of increasing sugarcane acreage in Brazil, which currently stands at 9 million hectares. One of the most critical points in the sugarcane production process is the negative interference imposed by weeds that infest the cultivated areas. These plants compete for the limiting resources of the environment, release allelopathic substances and may also host pests and diseases common to the crop, and interfere with yield. In the Center-South and Northeast regions, some grasses stand out in traditional areas of sugarcane crops such as Brachyria
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decumbens), capim-marmelada (Brachíaria plantaglnea) capím-colonião (Panicum maximum) e complexo de espécies de capím-colchâo (Digitaria norizontatís, Digitaria nuda. Digitaria bicornis, Digitaria ciliares e Digitaria sp), dentre outras gramíneas em áreas de expansão da cultura da cana-de-açúcar, como capim-braquiarâo (Brachiaria brizantha), capim-pé-de-gafinha (Eleusine indica) e caplm-carrapicho (Cenchrus echínatus), REPLACEMENT SHEET (RULE 26) decumbens), marmalade grass (Brachíaria plantaglnea), grasshopper (Panicum maximum) and cushiongrass species (Digitaria norizontatís, Digitaria nuda. Digitaria bicornis, Digitaria ciliares and Digitaria sp), among other grasses in areas of cultivation of sugarcane, such as Brachiaria brizantha, Brachiaria grass (Eleusine indica), and tick-like caplm (Cenchrus echínatus),
[0004] Com a introdução da colheita mecanizada, sem a queima da palhada, houve alterações significativas nos ambientes de produção da cana-de-açúcar, com reflexos na composição da comunidade de plantas daninhas. Vários pesquisadores se preocuparam em avaliar o comportamento diferencial entre as espécies, quanto á germinação e emergência, em relação à manutenção da camada de palha e as alterações mícroclímáticas resultantes. Verifica-se que algumas das espécies de plantas daninhas sáo caracterizadas pela presença de folhas largas, como as diferentes espécies de caruru (Amaranthus sp) e beldroega (Portufaca oleracea), dentre outras, que são frequentemente achadas em áreas de cana planta em solos de boa fertilidade e alto teor de matéria orgânica, ou nos quais são utilizados torta- de-filtro como parte da adubação, e plantas que foram seleclonadas por alguns herbicidas utilizados com frequência, como mussambê (Cleomís affinis) e leiteiro (Euphorbia heterophylla) e/ou em ambientes de cana-crua, como buva (Conyza sp), losna-branca (Parthenium hysterophorus), burra-leiteira (Chamaescyce hyssopifolía) e erva*de*rola (Croton lobatus) e malva-vermelha (Croton glandulosus). Um conjunto de espécies de plantas daninhas conhecidas popularmente como cordas-de*vioia tem se destacado nas comunidades infestantes da cultura da cana-de-açúcar, particularmente em áreas de colheita de cana-crua. Essas espécies pertencem aos géneros Ipomoea e Merremia, da família Convolvulaceae. Dentro do género Ipomoea destacam-se: I. hederifolia, I. quamoclít, I. nil, I. grandifotia e 1, purpúrea, enquanto no género Merremta destacam-se M, cissoides e M, aegyptia. With the introduction of mechanized harvesting without burning the straw, there were significant changes in sugarcane production environments, with effects on the composition of the weed community. Several researchers have been concerned to evaluate the differential behavior between species regarding germination and emergence in relation to the maintenance of the straw layer and the resulting microclimate changes. Some of the weed species are characterized by the presence of broadleaves, such as the different species of caruru (Amaranthus sp) and purslane (Portufaca oleracea), among others, which are often found in areas of sugarcane in soils. good fertility and high organic matter content, or in which filter tortilla is used as part of fertilizer, and plants that have been selected by some commonly used herbicides such as mussambê (Cleomís affinis) and dairy (Euphorbia heterophylla) and / or in environments of raw cane, such as bougain (Conyza sp), white worm (Parthenium hysterophorus), milk donkey (Chamaescyce hyssopifolía), and * rola grass (Croton lobatus) and red mallow (Croton glandulosus). A number of weed species popularly known as ropes de vioia have been prominent in the sugarcane infesting communities, particularly in raw cane harvesting areas. These species belong to the genera Ipomoea and Merremia, from the Convolvulaceae family. Within the genus Ipomoea stand out: I. hederifolia, I. quamoclít, I. nil, I. grandifotia and 1, purple, while in the genus Merremta stand out M, cissoides and M, aegyptia.
[0005] Na composição do custo de produção da cana-de-açúcar, os gastos com o controle das plantas daninhas sâo de grande importância. Segundo Kuva et ai (2003) o outros autores, a interferência proporcionada pelas plantas daninhas In the composition of the cost of sugarcane production, weed control costs are of great importance. According to Kuva et al (2003) the other authors, the interference provided by weeds
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acarreta redução significativa no rendimento da cultura (reduções de 20 a 80% na produção), além da proporcionar outros aspectos negativos, como decréscimos da longevidade do canavial (redução de 2 a 3 cortes ou ciclos da cultura)» redução da qualidade da matéria-prima e dificuldade nas operações de colheita e transporte. Dessa forma ó evidente a necessidade de estratégias eficientes no controle das comunidades infestantes da cultura. REPLACEMENT SHEET (RULE 26) entails a significant reduction in crop yield (reductions of 20 to 80% in yield), in addition to providing other negative aspects such as decreases in sugarcane longevity (reduction of 2 to 3 crop cuttings or cycles) »reduction in raw material quality and difficulty in harvesting and transport operations. Thus it is evident the need for efficient strategies to control the weeds of the crop.
[0006] Para permitir a eliminação eficiente ou o controle de pragas e plantas indesejáveis, a setetívidade dos herbicidas é muito desejável na agricultura, permitindo eliminar as pragas e plantas indesejáveis sem danificar a cultura principal. A presente invenção fornece uma nova combinação pesticida que possui um controle de amplo espectro para todas as estações da cana-de-açúcar. To enable efficient elimination or control of unwanted pests and plants, herbicide selectivity is very desirable in agriculture, allowing to eliminate unwanted pests and plants without damaging the main crop. The present invention provides a novel pesticide combination which has broad spectrum control for all sugarcane seasons.
[0007] O produto da presente invenção é o primeiro herbicida de amplo espectro para todas as épocas da cana-de-açúcar Na atualidada, é feito um controle ineficiente utilizando a mistura de tanque de Dinamic (Amicarbazona 700 g/Kg - Arysta UfeScience) mais Combine (Tebutiuron 500 g/L - Dow AgroSciences) ou Plateau (Imazapic 700 g/Kg - BASF) mais Combine (Tebutiuron 500 g/L ~ Dow AgroSciences), [0007] The product of the present invention is the first broad spectrum herbicide for all sugarcane seasons. Inefficient control is now done using the Dinamic tank mix (Amicarbazone 700 g / kg - Arysta UfeScience). more Combine (Tebutiuron 500 g / L - Dow AgroSciences) or Plateau (Imazapic 700 g / kg - BASF) more Combine (Tebutiuron 500 g / L - Dow AgroSciences),
[0008] A formulação da presente invenção funciona através de dois diferentes modos de açâo: inibição da Protoporfirinogenio Oxidase (PPO) e inibição da fotossíntese no fotossistema II (PS II). A inibição da Protoporfirinogenio Oxidase na presença de luz Irá causar a ruptura da membrana celular e dano celular irreversível enquanto que a inibição da fotossíntese causa necrose foliar. The formulation of the present invention works by two different modes of action: inhibition of protoporphyrinogen oxidase (PPO) and inhibition of photosynthesis in photosystem II (PS II). Inhibition of protoporphyrinogen oxidase in the presence of light will cause cell membrane rupture and irreversible cell damage while inhibition of photosynthesis causes leaf necrosis.
[0009] A sulfentrazona (2',4'-dicloro-5'-(4-difluorometil-4,5-dildro-3-metil-5-oxo-Sulfentrazone (2 ', 4'-dichloro-5' - (4-difluoromethyl-4,5-dildro-3-methyl-5-oxo)
1 H-1 ,2,4-tríazol-1-il) metanosuifonaniilda) é um herbicida de pré-emergéncia, seletivo condicional com açao sistémica a partir do grupo químico da triazoiinona. A sulfentrazona inibe a enzima Protoporfirinogenio Oxidase IX (PPO). A PPO está presente na rota de sfntese da clorofila e de citocromos, também chamada de rota de síntese de porfirinas ou de tetrapirroles (Merotto & Vidal, 2001 ). O mecanismo de açâo dos herbicidas inibidores da PPO está baseado na inibição da reaçâo de transformação do protoporfirinogono em protoporfirina. Esta reaçâo é catalisada pela 1 H-1,2,4-Triazol-1-yl) methanesifiphanoyl) is a pre-emergence, selective conditional herbicide with systemic action from the triazoiinone chemical group. Sulfentrazone inhibits the enzyme Protoporphyrinogen Oxidase IX (PPO). PPO is present in the synthesis route of chlorophyll and cytochromes, also called the synthesis route of porphyrins or tetrapyrroles (Merotto & Vidal, 2001). The mechanism of action of PPO inhibitor herbicides is based on the inhibition of the transformation reaction of protoporphyrinogen into protoporphyrin. This reaction is catalyzed by
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PPO. Com a inibição desta enzima, presente no cloroplasto, existe um acúmulo de protoporfirinogeno que se desloca do cloroptasto para o citoplasma e em contato com o oxigénio, na presença de luz, forma radicais livres (oxigénio singiete) provocando a peroxidacâo de lipídeos das membranas, que causa o dano. Até o momento foi detectado um biótipo de planta daninha resistente a estes herbicidas na agricultura, portanto, a probabilidade de seleção é restrita (Weed Science, 2003). REPLACEMENT SHEET (RULE 26) PPO. With the inhibition of this enzyme, present in the chloroplast, there is an accumulation of protoporphyrinogen that moves from chloroptasto to the cytoplasm and in contact with oxygen, in the presence of light, forms free radicals (singlet oxygen) causing membrane lipid peroxidation. that causes the damage. To date a weed biotype resistant to these herbicides has been detected in agriculture, so the probability of selection is restricted (Weed Science, 2003).
[0010] Após aplicações no solo, a suffentrazona ó absorvida através das raízes. Pode permanecer na superfície do solo por 10 a 14 dias ou mais, no entanto necessita de chuvas constantes, irrigação ou preparação do solo para passar abaixo da superfície e ativar o herbicida. O controle de plantas daninhas pode diminuir se a sulfentrazorta não for ativada em tempo hábil. Se a sutfentrazona estiver associada ao tebutiuron, essa necessidade diminui. After soil applications, suffentrazone is absorbed through the roots. It may remain on the surface of the soil for 10 to 14 days or more, however it requires constant rainfall, irrigation or soil preparation to pass below the surface and activate the herbicide. Weed control may be reduced if sulfentrazorta is not activated in a timely manner. If sutfentrazone is associated with tebutiuron, this need decreases.
[0011] O composto 1-(5-tert-butil-1.3,4-tiadíazol-2-il)-1,3-dimentilurea (Tebutiuron) é um herbicida de amplo espectro não seletívo. O tebutiuron é absorvido pelas raízes e transportado para as folhas» onde inibe a fotossíntese. 1- (5-tert-Butyl-1,4-thiadiazol-2-yl) -1,3-dimentylurea (Tebutiuron) is a non-selective broad spectrum herbicide. Tebutiuron is absorbed by the roots and transported to the leaves »where it inhibits photosynthesis.
[0012] Os herbicidas atualmente em uso e que apresentam mecanismo de açâo de inibição da fotossíntese são pertencentes a três principais grupos químicos: tríazinas. ureias substituídas e uracilas, O local de açâo destes herbicidas é na membrana do cloroplasto, onde ocorre a fase luminosa da fotossíntese, mais especificamente no transporte de eiétrons (Christoffoleti, 1997). Uma planta é susceptível aos herbicidas inibidores da fotossíntese se o herbicida se acoplar ao composto plastoquinona (QB) do sistema fotossintético e, assim, impossibilitar a ocorrência do transporte do elótron até o mesmo. Dessa forma não existe a produção de trifosfato de adenosina (ATP), pois o transporte de elétrons é interrompido, bem como a produção de Nicotinamída-adenína-dinucleaotido di- hidrogenofosfato (NADPH2). Já numa planta daninha resistente, há um processo de mutação no composto QB de tal maneira que o herbicida não consegue acopiar-se ao composto, impedindo o transporte de eiétrons. Portanto, uma planta resistente aos herbicidas Inibidores da fotossíntese consegue efetuar o transporte de eiétrons na fase luminosa da fotossíntese mesmo na presença do herbicida (Christoffoietí, Herbicides that are currently in use and have a mechanism of action to inhibit photosynthesis belong to three main chemical groups: triazines. Substituted urea and uracil. The site of action of these herbicides is on the chloroplast membrane, where the light phase of photosynthesis occurs, more specifically in the transport of electrons (Christoffoleti, 1997). A plant is susceptible to photosynthesis inhibiting herbicides if the herbicide mates with the photosynthetic system's plastoquinone compound (QB) and thus makes it impossible for electron transport to occur. Thus, there is no production of adenosine triphosphate (ATP), since electron transport is interrupted, as well as the production of Nicotinamide adenine dinucleaotide dihydrogen phosphate (NADPH2). Already in a resistant weed, there is a mutation process in compound QB such that the herbicide cannot couple to the compound, preventing the transport of electrons. Therefore, a plant resistant to photosynthesis inhibitors can transport electrons in the light phase of photosynthesis even in the presence of the herbicide (Christoffoietí,
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1997). No mundo, foram encontrados 64 biótipos resistentes ao grupo Cl (classificação do modo de açâo da HRAC- Herbicida Resista nce Action Commíttee), 20 ao grupo C2 e 1 ao grupo C3 (Weed Science, 2003). O mecanismo de açâo das ureias substituídas é o mesmo do grupo das triazinas/triazinonas, porém o sítio de aedo no composto QB é difemnciado, portanto normalmente não existe resistência cruzada entre eles (Chrtstoffoleti, 2001). REPLACEMENT SHEET (RULE 26) 1997). In the world, 64 resistant biotypes were found for group Cl (HRAC-Resistant Action Committee Action Mode classification), 20 for group C2 and 1 for group C3 (Weed Science, 2003). The mechanism of action of the substituted ureas is the same as that of the triazine / triazinone group, but the oil site in compound QB is differentiated, so there is usually no cross-resistance between them (Chrtstoffoleti, 2001).
[0013] Combinações herbicidas são frequentemente usadas para ampliar o espectro do herbicida, aumentando o controle e o efeito sinérgico sobre as plantas daninhas, Herbicidal combinations are often used to broaden the spectrum of the herbicide, increasing control and synergistic effect on weeds,
[0014] O documento Pi 0417671-5 refere-se a um método para controle de plantas coníferas, em particular plantas coníferas naturalmente semeadas (coníferas selvagens}, em que uma quantidade eficaz de pelo menos um herbicida selecionado dentre o grupo consistindo em sulfentrazona, carfentrazona, os seus sais agrícola mente aceitáveis e os seus derivados agricolamente aceitáveis é aplicada às plantas coníferas a serem controladas ou às suas partes, tais como raízes, fo&ias. sementes ou germinações, Pi 0417671-5 relates to a method for controlling coniferous plants, in particular naturally seeded coniferous plants (wild conifers}, wherein an effective amount of at least one herbicide selected from the group consisting of sulfentrazone, Carfentrazone, its agriculturally acceptable salts and its agriculturally acceptable derivatives are applied to the coniferous plants to be controlled or to parts thereof such as roots, leaves or germinations,
[00153 O documento Pi 9704565-9 refere-se a herbicidas seletivos compreendendo um composto de carbamoiltriazolinona e um ou mais compostos herbicidas selecionados dentre ametrina, tebutfuron, hexazinona, ísoxaflutol metribuzin, sulfentrazona e/ou diuron. Pi 9704565-9 relates to selective herbicides comprising a carbamoyl triazolinone compound and one or more herbicidal compounds selected from amethrin, tebutfuron, hexazinone, isoxaflutol metribuzin, sulfentrazone and / or diuron.
[0016] O documento Pi 0710376-0 refere-se a uma mistura de diuron com mesotriona, contendo opcionalmente outros herbicidas tais como, tebutiuron e sulfentrazone. Também é descrita uma composição herbicida que compreende diuron, mesotriona e, opcionalmente, outros herbicidas tais como hexazinona e peio menos um componente adicionai seiecionado a partir do grupo que consiste em tensoatívos, diluentes sólidos e diluentes líquidos, É adicionalmente descrito um método para o controle de vegetação indesejada compreendendo a aplicação no locai da vegetação de uma quantidade herbicidamente eficaz da mistura. Pi 0710376-0 relates to a mixture of diuron with mesotrione, optionally containing other herbicides such as tebutiuron and sulfentrazone. Also described is a herbicidal composition comprising diuron, mesotrione and, optionally, other herbicides such as hexazinone and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents. unwanted vegetation comprising applying on the spot the vegetation of a herbicidally effective amount of the mixture.
[0017] O documento US 2002004457 refere-se a uma composição herbicida sinérgica par» controlar as plantas daninhas de folhas largas e gramíneas em US 2002004457 relates to a synergistic herbicidal composition for controlling broadleaf and grassy weeds in
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culturas de plantes úteis resistentes aos inibidores da protoporfirinogênio oxtdase, que compreendem, além dos auxiliares usuais de formulação Inertes, como compostos ativos a) um herbicida que Inibe a ação das protoporfirinogênio oxidases e b) pelo menos um pesticida adicional selectonado a partir do grupo que consiste em co-herbicidas, fungicidas e inseticidas/acaritídas. REPLACEMENT SHEET (RULE 26) useful plant cultures resistant to protoporphyrinogen inhibitors oxtdase, which comprise, in addition to the usual formulation aids Inert, as active compounds a) a herbicide that inhibits the action of protoporphyrinogen oxidases and b) at least one additional pesticide selected from the group consisting of in co-herbicides, fungicides and insecticides / acaritides.
SUMARIO DA INVENÇÃO SUMMARY OF THE INVENTION
[0013] A presente invenção refere-se a uma formulação herbicida de amplo espectro para controle das mais importantes plantas daninhas de cana-da-acúcar, durante todas as estações. A formulação da presente invenção proporciona um controle melhor β mais eficiente do que lodos os herbicidas de cana-de-açúcar comerciais, trabalhando através de dois diferentes modos de açâo. The present invention relates to a broad spectrum herbicidal formulation for controlling the most important sugarcane weeds during all seasons. The formulation of the present invention provides better control more efficient than all commercial sugarcane herbicides by working through two different modes of action.
[0019] Devido ao desejo de se ter uma formulação com as propriedades acima mencionadas, é útil utilizar combinações de pesticidas ou formulações de um herbicida com outro herbicida, insecticida ou fungicida, etc, para se obter um melhor controle das numerosas plantas daninhas e pragas com uma única aplicação, independente do tempo e ou clima. Due to the desire to have a formulation with the above mentioned properties, it is useful to use combinations of pesticides or formulations of one herbicide with another herbicide, insecticide or fungicide, etc., for better control of the numerous weeds and pests. with a single application, regardless of weather and or climate.
[0020] Com base neste principio, foi desenvolvida uma mistura melhorada de herbicidas, em particular, uma formulação que compreende a combinação de dois dos mais importantes ingredientes ativos utilizados na cana-da-acúcar, isto é, triazolinonas, especialmente sulfentrazona, e pesticidas de ureia, especialmente tebutiuron, resultando em um controle melhor e mais eficiente, sendo um herbicida de amplo espectro para todas as estações de cana-de-açúcar, Based on this principle, an improved blend of herbicides has been developed, in particular a formulation comprising the combination of two of the most important active ingredients used in sugarcane, ie triazolinones, especially sulfentrazone, and pesticides. urea, especially tebutiuron, resulting in better and more efficient control, being a broad spectrum herbicide for all sugarcane stations,
DESCRIÇÃO DAS FIGURAS DESCRIPTION OF THE FIGURES
[0021] A Figura 1 refere-se às épocas de aplicação em cana-da-acúcar. Figure 1 refers to the times of application in sugar cane.
[0022] A Figura 2 refere-se a um gráfico que mostra os resultados obtidos no controle da cana soca. na época seca. com a aplicação da composição da presente invenção versus a combinação de outros herbicidas. A Flg. 2 mostra que a formulação da presente invenção apresenta uma excelente eficácia no controle da Digitaria sp na época seca. [0022] Figure 2 refers to a graph showing the results obtained in the control of the sugarcane. in the dry season. with the application of the composition of the present invention versus the combination of other herbicides. The Flg. 2 shows that the formulation of the present invention has excellent effectiveness in controlling Digitaria sp in the dry season.
[0023] A Figura 3 refere-se a um gráfico que mostra os resultados obtidos no [0023] Figure 3 refers to a graph showing the results obtained in the
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controle da cana soca, na época seca, com a aplicação da composição da presente invenção versus a combinação de outros herbicidas. A Fíg. 3 mostra que a formulação da presente invenção apresenta um controle bem superior da Ipomoea nil em relação ao controle da mistura de herbicidas Plateau + Combine. REPLACEMENT SHEET (RULE 26) control of sugarcane in the dry season with the application of the composition of the present invention versus the combination of other herbicides. The Fig. 3 shows that the formulation of the present invention has a much superior control of Ipomoea nil over the control of the Plateau + Combine herbicide mixture.
[0024] A Figura 4 refere-se a um gráfico que mostra os resultados obtidos no controle da cana planta, na época úmida, com a aplicação da composição da presente invenção versus a combinação de outros herbicidas. A Fig. 4 mostra que a formulação da presente invenção apresenta um controle excelente da Amaranthus sp, 90 dias após ser aplicada, quando comparada a outras misturas de herbicidas. [0024] Figure 4 is a graph showing the results obtained in the control of plant cane during the wet season with the application of the composition of the present invention versus the combination of other herbicides. Fig. 4 shows that the formulation of the present invention shows excellent control of Amaranthus sp 90 days after application as compared to other herbicide mixtures.
[0025] A Figura 5 refere-se a um gráfico que mostra os resultados obtidos no controle da cana planta, na época úmida, com a aplicação da composição da presente invenção versus a combinação de outros herbicidas. A Fig. 5 mostra que a formulação da presente invenção apresenta um controle excelente da Digitaria sp. 90 dias apôs ser aplicada, quando comparada a outras misturas de herbicidas. [0025] Figure 5 is a graph showing the results obtained in the control of the sugarcane during the wet season with the application of the composition of the present invention versus the combination of other herbicides. Fig. 5 shows that the formulation of the present invention shows excellent control of Digitaria sp. 90 days after being applied as compared to other herbicide mixtures.
DESCRIÇÃO DETALHADA DA INVENÇÃO DETAILED DESCRIPTION OF THE INVENTION
[0020] A presente invenção está relacionada a uma formulação herbicida de amplo espectro para todas as estacões. A formulação da presente invenção compreende triazolinonas em assodaçáo com pesticida de ureia, resultando em um controle melhor e mais eficiente do que de todos os herbicidas comerciais de cena- de-açúcar. The present invention relates to a broad spectrum herbicidal formulation for all seasons. The formulation of the present invention comprises triazolinones in urea pesticide sedimentation, resulting in better and more efficient control than all commercial sugarcane herbicides.
[0027] Em particular, a presente invenção refere-se a uma fomnjlação que fornece propriedades de manuseio melhoradas com um controle de amplo espectro para todas as estações da cana-de-açúcar. Os herbicidas do grupo das tríazolinonas, particularmente a suiferrtrazona, e os herbicidas do grupo das u relas, particularmente tebutiuron, são usualmente aplicados em cana-de-açúcar, entretanto, foi verificado que a ação ou espectro pode ser maximizado se estes compostos forem combinados. In particular, the present invention relates to a formulation that provides improved handling properties with broad spectrum control for all sugarcane seasons. Triazolinone group herbicides, particularly suiferrtrazone, and Ural group herbicides, particularly tebutiuron, are usually applied to sugarcane, however, it has been found that the action or spectrum can be maximized if these compounds are combined. .
[0028] Uma das vantagens da formulação da presente invenção é proporcionar um controle melhor e mais eficiente do que todos os herbicidas comerciais de cana- de-açúcar, incluindo Dinamic (Amicarbazona 700 g/Kg - Arysta LifeScíence) mate One of the advantages of the formulation of the present invention is to provide better and more efficient control than all commercial sugarcane herbicides, including Dinamic (Amicarbazone 700 g / kg - Arysta LifeScence) mate.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
Combine (Tebutiuron 500 g/L - Dow AgroSciences) e Plateau (imazapic 700 g/Kg - BASF) mais Combine (Tebutiuron 500 g/L - Dow AgroSciences). REPLACEMENT SHEET (RULE 26) Combine (Tebutiuron 500 g / L - Dow AgroSciences) and Plateau (imazapic 700 g / Kg - BASF) plus Combine (Tebutiuron 500 g / L - Dow AgroSciences).
[0029] Outra vantagem da formulação da presente invenção está relacionada à segurança para a aplicação no campo, uma vez que o fazendeiro é capaz de aplicar a formulação da presente invenção como uma suspensão concentrada com uma melhor comodidade e segurança, visto que a formulação é náo inflamável, possuí baixa toxicidade e alta concentração do ingrediente ativo. Another advantage of the formulation of the present invention is related to safety for application in the field, since the farmer is able to apply the formulation of the present invention as a concentrated suspension with better convenience and safety, since the formulation is non flammable, has low toxicity and high concentration of active ingredient.
[0030] Outra vantagem da presente invenção é trabalhar com a associação de duas moléculas herbicidas que atuam em diferentes mecanismos de açào, ou seja, suífentrazone que é um inibidor de PPO e o tebutiuron que é inibidor do PSII em uma formulação de alta performance no controle das principais plantas daninhas na cultura da cana~de-açúcar. Além disso, a formulação apresenta alta solubilidade, fornecendo um excelente controle de plantas daninhas tanto em cana planta como em cana soca nas épocas úmidas, semi-úmidas, semi-secas e secas. Another advantage of the present invention is to work with the association of two herbicidal molecules that act on different mechanisms of action, namely suifentrazone which is a PPO inhibitor and tebutiuron which is a PSII inhibitor in a high performance formulation. control of the main weeds in the sugarcane crop. In addition, the formulation has high solubility, providing excellent weed control in both cane and cane in humid, semi-humid, semi-dry and dry seasons.
[0031] A associação de herbicidas na presente invenção é baseada, principalmente, nos herbicidas do grupo das tríazolinonas, mais preferencialmente sulfentrazona e os herbicidas de ureia, mais particularmente tebutiuron. Tanto a suífentrazona quanto o tebutiuron são altamente eficazes no controle de plantas daninhas, sendo que as suas eficácias complementares, quando utilizados em associação na mesma formulação, o que náo é observado quando aplicados individualmente, The herbicide association in the present invention is based mainly on the triazolinone group herbicides, more preferably sulfentrazone and the urea herbicides, more particularly tebutiuron. Both suifentrazone and tebutiuron are highly effective in weed control, and their complementary efficacy when used in combination in the same formulation, which is not observed when applied individually,
[0032] Os herbicidas do grupo das ureias são selecionados do grupo que consiste em tebutiuron, Diuron, Chlrotoluron. Dimefuron, Fluometuron, Isoproturon, Isouron, Karbutílate, Linuron, Metabenztíazuron, Metobenzuron, Metoxuron, Monolinuron, Neburon, Siduron, e suas misturas. Herbicides from the urea group are selected from the group consisting of tebutiuron, Diuron, Chlrotoluron. Dimefuron, Fluometuron, Isoproturon, Isouron, Karbutylate, Linuron, Metabenzthiazuron, Metobenzuron, Methoxuron, Monolinuron, Neburon, Siduron, and mixtures thereof.
[0033] Os herbicidas do grupo das triazolinonas são selecionados do grupo consistindo em sulfentrazona, amicarbazona, carfentrazona e azafenldín. Herbicides from the triazolinone group are selected from the group consisting of sulfentrazone, amicarbazone, carfentrazone and azafenldín.
[0034] Em uma concretização, a presente invenção está direcíonada a uma formulação compreendendo: In one embodiment, the present invention is directed to a formulation comprising:
(a) pela menos um pesticida herbicida selecionado do grupo das (a) at least one herbicidal pesticide selected from the group of
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
tríazolinonas; REPLACEMENT SHEET (RULE 26) triazolinones;
(b) pelo menos um pesticida herbicida selecíonado do grupo das ureias. (b) at least one selected urea group herbicidal pesticide.
[0035] Em uma concretização preferencial, a presente invenção refere-se a uma formulação compreendendo; In a preferred embodiment, the present invention relates to a formulation comprising;
(a) pelo menos um pesticida herbicida grupo das tríazolinonas, selecíonado dentre sulfentrazona. amícarbazona ou carfentrazona; (a) at least one herbicidal pesticide triazolinone group selected from sulfentrazone. amicarbazone or carfentrazone;
(b) peio menos um pesticida herbicida do grupo das ureías selecíonado dentre Tebutiuron, Diuron, Chlrotoluron, Dimefuron, Ruometuron, Isoproturon, Isouron, Karbutílate, Linuron, Methabenzthiazuron, Metobenzuron, Metoxuron, Monolínuron, Neburon, Siduron, e suas misturas. (b) at least one herbicidal pesticide from the group of urea selected from Tebutiuron, Diuron, Chlrotoluron, Dimefuron, Ruometuron, Isoproturon, Isouron, Karbutylate, Linuron, Methabenzthiazuron, Metobenzuron, Metoxuron, Nebon, Sidonuron, Mebonuron, Monolon
[0036] Em uma concretização mats preferida, a presente invenção está dírecionada a uma formulação compreendendo: In a preferred mats embodiment, the present invention is directed to a formulation comprising:
i) (a) peio menos um herbicida selecíonado do grupo das triazoíinonas; e (b) peio menos um pesticida herbicida selecíonado do grupo das uretas; (i) (a) at least one selected triazoinone group herbicide; and (b) at least one selected urethane herbicidal pesticide;
li) uma mistura de dispersantes selecionados do grupo consistindo em: (li) a mixture of dispersants selected from the group consisting of:
(a) polímero acrílico, que pode incluir polímero estireno acrilico, polímero estireno acrílico modificado, solução de copolímero acrílico, polímérico aleatório não íônico, dispersante poiimérico anfotérico, polímero de condensação poííéster/poíiamtna, poliacrilato de sódio, sal de sódio de copolímero ácido acrílico/ácido malétco, sal de sódio de copolímero de ácido maléico/olefina, saí de sódio de poítcarboxílato, homopolimero de vinilpirrolidona, copolímero de vinilpirrolidona/vlnilacetato; e (a) acrylic polymer, which may include acrylic styrene polymer, modified acrylic styrene polymer, acrylic copolymer solution, nonionic random polymer, amphoteric polymeric dispersant, polyester / polyamine condensation polymer, sodium polyacrylate, acrylic acid copolymer sodium salt maleic acid, maleic acid / olefin copolymer sodium salt, polycarboxylate sodium salt, vinylpyrrolidone homopolymer, vinylpyrrolidone / vinylacetate copolymer; and
(b) lignina, como por exemplo, iignosulfonato de sódio e cálcio; (b) lignin, such as sodium and calcium isosulfonate;
(c) tristirilfenóís, que podem incluir: tristíriífenol POE (10); tristirilfenoí POE (16); tristírilfenol POE (20); trístíriffenol POE (25); tristirilfenoí POE (40); tristíriífenol POE (54); distirilfenol POE (8); dístirilfenoi POE (13); distirilfenol POE (17); tristirilfenoí POE - POP; éster de poíiaril fosfato POE (16); sal de amina de éster de poltaril fosfato POE (16); sal de potássio de éster poliaril fosfato POE (16); copolímero em bioco de óxido de políalquileno tristirilfenoí; sal de trietilamina de éster de fosfato do tristirilfenol etoxílados-POE 16; e (c) tristirylphenols, which may include: tristiriphenol POE (10); tristirylphenoi POE (16); tristyrilphenol POE (20); tristiriffenol POE (25); tristirylphenyl POE (40); tristiriphenol POE (54); distyrylphenol POE (8); distalphenyl POE (13); distyrylphenol POE (17); tristirilphenoí POE - POP; POE polyaryl phosphate ester (16); POE polytaryl phosphate ester amine salt (16); POE polyaryl phosphate ester potassium salt (16); polyalkylene oxide copolymer tristirylphenyl; tristirylphenol ethoxylated phosphate ester triethylamine salt-POE 16; and
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
Hl) aditivos para estabilizar a formulação, tais como anticongelantes (glicol ou ureia), agentes estabilizantes (goma xarttana ou produtos minerais selecionados dentre silicatos, óxido de silício e bentonita), conservantes ô agentes antiespuma. REPLACEMENT SHEET (RULE 26) Hl) additives to stabilize the formulation, such as antifreeze (glycol or urea), stabilizing agents (gum or mineral products selected from silicates, silicon oxide and bentonite), preservatives and antifoam agents.
[0037] Mais particularmente, a presente invenção refere-se a uma formulação herbicida com base em sulfentrazona misturada principalmente com tebutiuron em uma coricentraçâo de 26,5 g/L a 760 g/L. mais preferencialmente de 265 g/L de sulfentrazona e de 31 g/L a 750 g/L, mais preferencialmente 310 g/L de tebutiuron. More particularly, the present invention relates to a sulfentrazone-based herbicidal formulation mixed primarily with tebutiuron at a coricentrication of 26.5 g / l to 760 g / l. more preferably 265 g / l sulfentrazone and 31 g / l to 750 g / l, more preferably 310 g / l tebutiuron.
[0038] Em uma concretização preferencial da presente Invenção, a formulação está na fornia de grânulos molháveis, pó moihável, pó, microencapeulada, foliar, sulcos, solução concentrada, óleo dispersivel e concentrado emulsionável. In a preferred embodiment of the present invention, the formulation is in the form of wettable granules, wettable powder, powder, microencapped, leaf, furrows, concentrated solution, dispersible oil and emulsifiable concentrate.
[0030] Mais preferencialmente a formulação da presente invenção está na forma de suspensão, pó molhável (WP), dispersão em óleo (OO), concentrado emulsionavel (EC) ou granulo dispersível (WDG). Most preferably the formulation of the present invention is in the form of suspension, wettable powder (WP), oil dispersion (OO), emulsifiable concentrate (EC) or dispersible granule (WDG).
[00403 Em uma concretização mais preferencial, a formulação é uma suspensão aquosa compreendendo sulfentrazona e tebutiuron. A sulfentrazona e o tebutiuron podem estar presentes em qualquer quantidade desejada. In a more preferred embodiment, the formulation is an aqueous suspension comprising sulfentrazone and tebutiuron. Sulfentrazone and tebutiuron may be present in any desired amount.
[0041] Em uma concretização preferencial da presente invenção» a formulação da presente invenção é diluída em água para preparar soluções homogéneas para aplicação nas folhas de uma planta para exterminar ou controlar o crescimento das plantas. A presente invenção também é direção nada a métodos de fabricação e uso das formulações da presente invenção. In a preferred embodiment of the present invention the formulation of the present invention is diluted with water to prepare homogeneous solutions for application to the leaves of a plant to exterminate or control plant growth. The present invention is also directed to methods of making and using the formulations of the present invention.
[0042] Uma mistura com outros compostos ativos corthecidos, tais como inseticidas, fungicidas ou com fertilizantes e reguladores de crescimento também é possível. Mixing with other active cut compounds such as insecticides, fungicides or with fertilizers and growth regulators is also possible.
[0043] A formulação da presente invenção pode ser aplicada através de qualquer método convencional, tal como, em pó, em sulcos» foliar, microencapsulada, como um pó moihável, como um grânulo molhável, como uma solução concentrada ou óleo dispersíveí. The formulation of the present invention may be applied by any conventional method, such as powder, in microencapsulated leaf grooves, as a wettable powder, as a wettable granule, as a concentrated solution or dispersible oil.
[0044] A presente invenção também se refere a um método para controle eficiente de diferentes piantas daninhas, tais como o complexo capím-colchâo The present invention also relates to a method for efficient control of different weeds, such as the grass-mattress complex.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
(Digitaria hortzontalis, Digitaria nuda e outras), capim-coloníao (Panicum maxímum), capím-braquiárla (Brachiaria decumbens), corda-de-viola (Ipomoea grandifoia, Ipomoea níl ipomoea quamoclit, Ipomoea purpúrea, Merremia cissoWes e Merremia aegypta), picão-preto (Bidens pilosa), tiririca (Cyperus rotundus e Cyperus spp), capim-pe-de~galinha (Eleusina indica), capim-carrapicho (Cenchrus Echinatus), mucuna (Mucuna pruriens), leiteiro (Euphorbia heterophylia), dentre outras espécies de plantas daninhas conforme descrito nas tabelas abaixo, compreendendo a aplicação da fórmula da presente invenção nas plantas. REPLACEMENT SHEET (RULE 26) (Digitaria hortzontalis, Digitaria nuda and others), colonization grass (Panicum maximum), brachiaria grass (Brachiaria decumbens), viola string (Ipomoea grandifoia, Ipomoea nil ipomoea quamoclit, Ipomoea purpurea, Merremia cissoWes and Merremia aes), black prick (Bidens pilosa), tiririca (Cyperus rotundus and Cyperus spp), chicken grass (Eleusina indica), tick grass (Cenchrus Echinatus), mucuna (Mucuna pruriens), dairy (Euphorbia heterophylia), among others. other weed species as described in the tables below, comprising applying the formula of the present invention to plants.
[0045] A presente invenção também se refere a um método para reduzir a competição das plantas daninhas por água, luz e nutrientes com a cultura da cana- de-açúcar, favorecendo assim o desenvolvimento inicial da cultura, a produção e aumentando o rendimento da colheita e a longevidade do canavial, compreendendo a aplicação da formulação da presente invenção nas plantas daninhas. The present invention also relates to a method for reducing weed competition for water, light and nutrients with sugarcane cultivation, thereby favoring early crop development, yield and increasing crop yield. harvesting and longevity of sugarcane, comprising applying the formulation of the present invention to weeds.
[0046] A invenção refere-se também ao uso da formulação da presente invenção no controle de plantas daninhas e pragas indesejáveis, conforme citados anteriormente e descriminadas em tabela abaixo, [0046] The invention also relates to the use of the formulation of the present invention in the control of weeds and unwanted pests, as cited above and detailed in the table below.
[0047] Os conceitos gerais da invenção são descritos a seguir, os quais nâo devem ser considerados como limltantes da presente invenção. The general concepts of the invention are described below, which should not be construed as limiting the present invention.
TABELA 1 TABLE 1
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
REPLACEMENT SHEET (RULE 26)
|0048] As formulações descritas na Tabela 2 abaixo foram aplicadas em cana- de-açucar nas dosagens abaixo. Para o primeiro protótipo foram avaliados o sinergismo de uma formulação do tipo "built-in" e a mistura dos produtos comerciais. The formulations described in Table 2 below were applied to sugar cane at the dosages below. For the first prototype, the synergism of a built-in formulation and the mix of commercial products were evaluated.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
m®A2 REPLACEMENT SHEET (RULE 26) m®A2
[0049] A tabela 3 ilustra o controle efetivo de cada mistura ou formulação nas respectivas cultura e tempo após aplicação. Table 3 illustrates the effective control of each mixture or formulation in the respective culture and time after application.
[0050] Nota: OAA - dias após aplicada Note: OAA - Days After Applied
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
[0031] Época; Seca - Agosto de 2012 REPLACEMENT SHEET (RULE 26) Season; Drought - August 2012
[0052] A presente invenção possui um controle superior (A) ao do tratamento de Mercado (D) imazapic 700 g/Kg + Tebutiuron 500 g/L e (H) Diuron 603 g/Kg + Hexazinona 170 g/Kg. A mistura de triazolinona e pesticidas herbicida a base de ureia mostrou resultados positivos no controle de ambas as pragas tanto na estação seca quanto na estação de plantio. The present invention has a superior control (A) than Market (D) imazapic 700 g / kg + Tebutiuron 500 g / L treatment and (H) Diuron 603 g / kg + Hexazinone 170 g / kg. The mixture of triazolinone and urea herbicide pesticides showed positive results in the control of both pests in the dry and planting season.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
[0053] Relação de plantas daninhas alvo nas quais a formulação contendo sulféntrazona e Tebutiuron será registrado para a cultura da cana-de-açúcar.REPLACEMENT SHEET (RULE 26) List of target weeds in which the formulation containing sulféntrazone and Tebutiuron will be registered for sugarcane crop.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
TABELA 5 REPLACEMENT SHEET (RULE 26) TABLE 5
[0054] Relação de plantas daninhas alvos nas quais a formulação contando suffentrazona está registrada para cana-de-açúcar. List of target weeds in which the formulation containing suffentrazone is registered for sugarcane.
TABELA S TABLE S
[0055] Relação de plantas daninhas alvos nas quais o herbicida Tebutiuron está registrado para cana-de-açucar. [0055] List of target weeds in which the herbicide Tebutiuron is registered for sugarcane.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
REPLACEMENT SHEET (RULE 26)
[0056] Os resultados foram reproduzidos em condições de cana planta β cana soca nas diferentes épocas úmidas, semi úmidas, secas e semi secas, o que faz da presente invenção inovadora peia flexibildade de uso, visto que a formulação pode ser aplicada no para o controle das principais plantas daninhas da cana-de-açúcar tanto em cana planta, como em cana soca, em diferentes texturas de solo, ambientes de produção e épocas do ano (úmida, semi umida, seca e semi seca). [0056] The results have been reproduced under conditions of sugarcane plant β sugarcane at different wet, semi-wet, dry and semi-dry seasons, which makes the present invention innovative for its flexibility as the formulation can be applied to control of the main sugarcane weeds in both sugarcane and soca sugarcane in different soil textures, production environments and times of the year (wet, semi-moist, dry and semi-dry).
[0057] Será apreciado pelos técnicos no assunto que modificações podem ser feitas na presente Invenção sem o afastamento dos conceitos revelados na descrição acima. Consequentemente, as concretizações preferenciais descritas aqui em detalhe são somente ilustrativas e não limitam o escopo da invenção. It will be appreciated by those skilled in the art that modifications may be made to the present invention without departing from the concepts disclosed in the above description. Accordingly, the preferred embodiments described herein in detail are illustrative only and do not limit the scope of the invention.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
REPLACEMENT SHEET (RULE 26)
Claims
1. Formulação herbicida de amplo espectro pró e pós emergência, caracterizada pelo falo de que compreende: 1. Broad and pro-emergence herbicidal formulation characterized by the phallus that comprises:
(a) pelo menos um pesticida herbicida grupo das triazolinonas. selecionado dentre sulfentrazona. amicarbazona. carfentrazona e azafenidln; (a) at least one triazolinone group herbicidal pesticide. selected from sulfentrazone. amicarbazone. carfentrazone and azafenidln;
(b) pelo menos um pesticida herbicida do grupo das ureias selecionado dentre Tebutiuron, Diuron, Chlrotoluron. Dímefuron, Fluometuron. Isoproturon, Isouron, Karbutilate, Linuron, Methabenzthiazuron, Metobenzuron, Metoxuron. MonoNnuron, Neburon, Siduron, e suas misturas. (b) at least one herbicidal pesticide from the urea group selected from Tebutiuron, Diuron, Chlrotoluron. Dimefuron, Fluometuron. Isoproturon, Isouron, Karbutilate, Linuron, Methabenzthiazuron, Metobenzuron, Methoxuron. MonoNnuron, Neburon, Siduron, and their mixtures.
2. Formulação de acordo com a reivindicação 1, caracterizada pelo fato de que a triazolinona é sutfentrazona. Formulation according to claim 1, characterized in that triazolinone is sutfentrazone.
3. Formulação de acordo com a reivindicação 1 ou 2, caracterizada pelo fato de que a ureia é tebutiuron. Formulation according to claim 1 or 2, characterized in that the urea is tebutiuron.
4. Formulação de acordo com qualquer uma das reivindicações 1 a 3. caracterizada pelo fato de que a formulação é uma suspensão aquosa. Formulation according to any one of Claims 1 to 3, characterized in that the formulation is an aqueous suspension.
5. Formulação de acordo com qualquer uma das reivindicações 1 a 4. caracterizada pelo falo de que compreende ainda uma mistura de dispersantes selecionados do grupo que consistem em: Formulation according to any one of claims 1 to 4, characterized in that it further comprises a mixture of dispersants selected from the group consisting of:
(a) polímeros acrílicos, selecionados dentre polímero estireno acrílico, polímero estireno acrílico modificado, solução de copolimero acrílico, polimérico aleatório não iònico. dispersante polimérico anfotértco, polímero de condensação poliéster/poNamina. poliacrilato de sódio, sal de sódio de copolimero ácido acrílico/ácido maléico. sal de sódio de copolimero de ácido maléico/olefina. sal de sódio de policarboxilato, homopolimero de vinilpirrolidona, copolimero de vinilpirrolidone/vinilacetato; (a) acrylic polymers, selected from acrylic styrene polymer, modified acrylic styrene polymer, acrylic copolymer solution, nonionic random polymer. amphoteric polymeric dispersant, polyester / polyamine condensation polymer. sodium polyacrylate, acrylic acid / maleic acid copolymer sodium salt. sodium salt of maleic acid / olefin copolymer. polycarboxylate sodium salt, vinylpyrrolidone homopolymer, vinylpyrrolidone / vinylacetate copolymer;
(b) ligninae. setecionadas dentre lignosuffonato de sódio e cálcio; e (b) ligninae. selected from sodium and calcium lignosuffonate; and
(c) tristirirfenóis, selecionados dentre tristiriffenol POE (10); tristirllfenol POE (16); tristirilfenol POE (20); tristirilfenol POE (25); tristirllfenol POE (40): tristirilfenol POE (54); distirirfenol POE (8); dislirUfenol POE (13); distirilfenol POE (17); tristirilfenol POE - POP; éster de poliaril fosfato POE (16); sal de amlna de éster (c) tristirirphenols, selected from tristiriffenol POE (10); tristirphenol POE (16); tristirylphenol POE (20); tristirylphenol POE (25); tristirylphenol POE (40): tristirylphenol POE (54); distyrphenol POE (8); dislyrphenol POE (13); distyrylphenol POE (17); tristirylphenol POE - POP; POE polyaryl phosphate ester (16); ester amlna salt
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
de poliaril fosfato POE (16); sal de potássio de éster poliam fosfato POE (16); copolimero em bloco de óxido de polialquileno tristirilfenot; sal de trietilamlna de éster de fosfato de trfsiirilfénol etoxilados-POE 16. REPLACEMENT SHEET (RULE 26) polyaryl phosphate POE (16); POE polyam phosphate ester potassium salt (16); polyalkylene oxide block copolymer tristyrylphenot; ethoxylated triphenylphenol phosphate ester triethylamine salt-POE 16.
6. Formulação de acordo com qualquer uma das reivindicações 1 a 5, caracterizada pelo foto de que compreende ainda aditivos setecionados dentre anticongelantes, agentes estabilizantes, conservantes e agentes antfespuma. Formulation according to any one of claims 1 to 5, characterized in that the photo further comprises additives selected from antifreeze, stabilizing agents, preservatives and antifoaming agents.
7. Formulação de acordo com a reivindicação 6, caracterizada pelo fato de que o anticongeiante é seiecionado dentre glicol e ureia. Formulation according to claim 6, characterized in that the antifungal agent is selected from glycol and urea.
8. Formulação de acordo com a reivindicação 6, caracterizada pelo foto de que o agente estabilizante é seiecionado dentre goma xantana, silicatos, óxido de silício e bentonita. Formulation according to claim 6, characterized in that the stabilizing agent is selected from xanthan gum, silicates, silicon oxide and bentonite.
9. Formulação de acordo com qualquer uma das reivindicações 1 a 8, caracterizada pelo fato de que a triazolinona está presente em uma concentração de 26,5 g/L a 750 g/L e a ureia está presente em uma concentração de 31 g/l a 750 g/L Formulation according to any one of claims 1 to 8, characterized in that triazolinone is present at a concentration of 26.5 g / l to 750 g / l and urea is present at a concentration of 31 g / l at 750 g / l
10. Formulação de acordo com a reivindicação 9, caracterizada pelo foto de que a triazolinona está presente em uma concentração de 265 g/L e a ureia está presente em uma concentração de 310 g/L. Formulation according to claim 9, characterized by the photo that triazolinone is present at a concentration of 265 g / l and urea is present at a concentration of 310 g / l.
11. Formulação de acordo com qualquer uma das reivindicações 1 a 10. caracterizada pelo foto de que está na forma de grânulos moináveis, pó molhável, pó, microencapsulada, foliar, sulcos, solução concentrada, óleo disperslvei e concentrado emulstonável. Formulation according to any one of claims 1 to 10, characterized in that it is in the form of grindable granules, wettable powder, powder, microencapsulated, leaf, furrows, concentrated solution, dispersible oil and emulsifiable concentrate.
12. Formulação de acordo com qualquer uma das reivindicações 1 a 11, caracterizada peio foto de que compreende ainda um composto ativo sefockmado do grupo consistindo em inseticidas, fungicidas, fertilizantes e reguladores de crescimento. Formulation according to any one of claims 1 to 11, characterized in that it further comprises a sephocked active compound from the group consisting of insecticides, fungicides, fertilizers and growth regulators.
13. Método para controlar plantas daninhas indesejáveis setedonadas dentre o complexo capim-cotehão (Digitaria borizontaiis, Digitaria nuda e outras), capim-colonlâo (Panicum maximum), capirn-braquiária (Brachiaria decumbens), corda-de- viola (ipomoea grandifola, Ipomoea nll, Ipomoea quamoclit, Ipomoea 13. Method for controlling undesired weeds between the Cotehão-grass complex (Digitaria borizontaiis, Digitaria nuda and others), Colony grass (Panicum maximum), Brachiaria decumbens, Viola rope (ipomoea grandifola, Ipomoea nll, Ipomoea quamoclit, Ipomoea
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
purpúrea, Ipomoea hederífolía, Merremia cissoides e Merremia aegypta), picâo-preto (Bidens pilosa), tiririca (Cyperus rotundus e Cyperus spp), capim-pé-de-galinha (Eleusine indica), capim-carrapicho (Cenchrus Echinatus), mucuna (Mucuna pruriens), leiteiro (Euphorbia heterophylla), Carrapicho-rasteiro {Acanthospermum australe), Caruru-de-mancha (Amaranthus viridis), Capim-marmelada (Brachiaría plantaginea), Trapoeraba (Commelina benghalensis), Fatea-serralha {Emília sonchifolia), Amendoim-bravo (Euphorbia heterophylla), Picão-branco (Galinsoga parviflora), Beldroega {Portuíaca oieracea), Poaia-branca (Richardia brasiliensís), Malva-branca (Sida cordifolia), Guanxuma-branca (Sida glaziovii), Guanxuma (Sida rhombífolía), Erva-quente (Spermacoce latifólia), caracterizado pelo fato de que compreende aplicar uma formulação como definida em qualquer uma das reivindicações 1 a 12 em uma planta. REPLACEMENT SHEET (RULE 26) purpura, Ipomoea hederífolía, Merremia cissoides and Merremia aegypta), black prawn (Bidens pilosa), tiryrica (Cyperus rotundus and Cyperus spp), chicken grass (Eleusine indica), tick grass (Cenchrus Echinatus), mucuna (Mucuna pruriens), Dairy (Euphorbia heterophylla), Creeping Flycatch (Acanthospermum australe), Spotted Caruru (Amaranthus viridis), Marmalade Grass (Brachiaría plantaginea), Trapoeraba (Commelina benghalensis), Fatea-serralif {Emilia) , Wild peanut (Euphorbia heterophylla), White prick (Galinsoga parviflora), Purslane (Portuaca oieracea), White poaia (Richardia brasiliensís), White mallow (Sida cordifolia), White guanxuma (Sida glaziovii), Guanxuma (Sida) rhombífolía), Fennel (Spermacoce latifolia), characterized in that it comprises applying a formulation as defined in any one of claims 1 to 12 in a plant.
14. Método para aumentar o rendimento da colheita, caracterizado pelo fato de que compreende aplicar uma formulação como definida em qualquer uma das reivindicações 1 a 12 em uma planta. A method for increasing crop yield, characterized in that it comprises applying a formulation as defined in any one of claims 1 to 12 on a plant.
FOLHA DE SUBSTITUIÇÃO (REGRA 26)
REPLACEMENT SHEET (RULE 26)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX2017001099A MX2017001099A (en) | 2014-07-30 | 2015-07-28 | Pre- and post-emergence, broad-range herbicidal formulation containing triazolinones associated with urea pesticides, and weed-control and harvest yield increasing methods. |
| AU2015296907A AU2015296907B2 (en) | 2014-07-30 | 2015-07-28 | Pre- and post-emergence broad spectrum herbicidal formulation containing triazolinones in association with urea pesticides and methods for controlling weeds and increasing crop yield |
| BR112017001562-5A BR112017001562B1 (en) | 2014-07-30 | 2015-07-28 | PRE AND POST EMERGENCY BROAD SPECTRUM HERBICIDE FORMULATION CONTAINING TRIAZOLINONES IN ASSOCIATION WITH UREA PESTICIDES AND METHODS FOR WEED CONTROL AND TO INCREASE CROP YIELD |
| CONC2017/0000790A CO2017000790A2 (en) | 2014-07-30 | 2017-01-30 | Broad spectrum pre-emergent and post-emergent herbicidal formulation containing triazolinones in association with urea-derived pesticides and methods for weed control and increased agricultural yield |
| AU2019250235A AU2019250235A1 (en) | 2014-07-30 | 2019-10-18 | Pre- and post-emergence broad spectrum herbicidal formulation containing triazolinones in association with urea pesticides and methods for controlling weeds and increasing crop yield |
| AU2021202169A AU2021202169A1 (en) | 2014-07-30 | 2021-04-09 | Pre- and post-emergence broad spectrum herbicidal formulation containing triazolinones in association with urea pesticides and methods for controlling weeds and increasing crop yield |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRBR102014018731-6 | 2014-07-30 | ||
| BR102014018731A BR102014018731A2 (en) | 2014-07-30 | 2014-07-30 | pre- and post-emergence broad spectrum herbicidal formulation containing triazolinones in combination with urea pesticides and methods for weed control and crop yield |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2016015112A1 true WO2016015112A1 (en) | 2016-02-04 |
| WO2016015112A8 WO2016015112A8 (en) | 2017-03-09 |
Family
ID=55216502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/BR2015/000112 WO2016015112A1 (en) | 2014-07-30 | 2015-07-28 | Pre- and post-emergence, broad-range herbicidal formulation containing triazolinones associated with urea pesticides, and weed-control and harvest yield increasing methods |
Country Status (8)
| Country | Link |
|---|---|
| AR (1) | AR101365A1 (en) |
| AU (3) | AU2015296907B2 (en) |
| BR (2) | BR102014018731A2 (en) |
| CO (1) | CO2017000790A2 (en) |
| GT (1) | GT201700015A (en) |
| MX (1) | MX2017001099A (en) |
| UY (1) | UY36246A (en) |
| WO (1) | WO2016015112A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111406754A (en) * | 2020-04-28 | 2020-07-14 | 浙江禾本科技股份有限公司 | Hexythiazox water suspending agent and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR118686A1 (en) * | 2020-07-30 | 2021-10-27 | Red Surcos Colombia Ltda | COMPOSITION OF SULFENTRAZONE IN MICRO EMULSION FORM |
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| US6040271A (en) * | 1998-02-20 | 2000-03-21 | Bayer Aktiengesellschaft | Selective herbicides for the cultivation of sugar cane |
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| US20110190126A1 (en) * | 2008-06-09 | 2011-08-04 | Syngenta Crop Protection, Inc. | Weed control method and herbicidal composition |
| US20140031222A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and certain ps ii inhibitors |
| WO2015044150A2 (en) * | 2013-09-26 | 2015-04-02 | Basf Agrochemical Products B.V. | Method for controlling weeds in sugar cane plantations |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR071858A1 (en) * | 2008-05-21 | 2010-07-21 | Basf Se | HERBICIDE COMPOSITION THAT INCLUDES GLIFOSATO, GLUFOSINATO OR ITS SALTS AND METHOD TO CONTROL INDESEABLE VEGETATION THROUGH ITS APPLICATION |
-
2014
- 2014-07-30 BR BR102014018731A patent/BR102014018731A2/en not_active Application Discontinuation
-
2015
- 2015-07-28 BR BR112017001562-5A patent/BR112017001562B1/en active IP Right Grant
- 2015-07-28 MX MX2017001099A patent/MX2017001099A/en unknown
- 2015-07-28 AU AU2015296907A patent/AU2015296907B2/en active Active
- 2015-07-28 WO PCT/BR2015/000112 patent/WO2016015112A1/en active Application Filing
- 2015-07-29 AR ARP150102424A patent/AR101365A1/en active IP Right Grant
- 2015-07-30 UY UY0001036246A patent/UY36246A/en not_active Application Discontinuation
-
2017
- 2017-01-27 GT GT201700015A patent/GT201700015A/en unknown
- 2017-01-30 CO CONC2017/0000790A patent/CO2017000790A2/en unknown
-
2019
- 2019-10-18 AU AU2019250235A patent/AU2019250235A1/en not_active Abandoned
-
2021
- 2021-04-09 AU AU2021202169A patent/AU2021202169A1/en not_active Abandoned
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| US6040271A (en) * | 1998-02-20 | 2000-03-21 | Bayer Aktiengesellschaft | Selective herbicides for the cultivation of sugar cane |
| DE19834627A1 (en) * | 1998-07-31 | 1998-12-03 | Novartis Ag | Broad-spectrum pre- or post=emergence herbicidal composition |
| US6444613B1 (en) * | 1999-03-12 | 2002-09-03 | Hoechst Schering Agrevo Gmbh | Defoliant |
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| WO2007133522A2 (en) * | 2006-05-12 | 2007-11-22 | E. I. Du Pont De Nemours And Company | Herbicidal mixture comprising diuron and mesotrione |
| US20110190126A1 (en) * | 2008-06-09 | 2011-08-04 | Syngenta Crop Protection, Inc. | Weed control method and herbicidal composition |
| US20140031222A1 (en) * | 2012-07-24 | 2014-01-30 | Dow Agrosciences Llc | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and certain ps ii inhibitors |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111406754A (en) * | 2020-04-28 | 2020-07-14 | 浙江禾本科技股份有限公司 | Hexythiazox water suspending agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AR101365A1 (en) | 2016-12-14 |
| UY36246A (en) | 2016-01-29 |
| AU2015296907B2 (en) | 2019-07-18 |
| GT201700015A (en) | 2019-08-12 |
| BR112017001562B1 (en) | 2022-06-14 |
| AU2019250235A1 (en) | 2019-11-07 |
| CO2017000790A2 (en) | 2017-05-10 |
| AU2021202169A1 (en) | 2021-05-06 |
| BR112017001562A2 (en) | 2018-01-30 |
| AU2015296907A1 (en) | 2017-03-02 |
| MX2017001099A (en) | 2017-05-03 |
| BR102014018731A2 (en) | 2016-05-31 |
| WO2016015112A8 (en) | 2017-03-09 |
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