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WO2015192321A1 - Composition pigmentaire à faible échauffement par des rayons infrarouges, et matériau à faible échauffement par des rayons infrarouges - Google Patents

Composition pigmentaire à faible échauffement par des rayons infrarouges, et matériau à faible échauffement par des rayons infrarouges Download PDF

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Publication number
WO2015192321A1
WO2015192321A1 PCT/CN2014/080105 CN2014080105W WO2015192321A1 WO 2015192321 A1 WO2015192321 A1 WO 2015192321A1 CN 2014080105 W CN2014080105 W CN 2014080105W WO 2015192321 A1 WO2015192321 A1 WO 2015192321A1
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WO
WIPO (PCT)
Prior art keywords
pigment
component
red
yellow
blue
Prior art date
Application number
PCT/CN2014/080105
Other languages
English (en)
Chinese (zh)
Inventor
苏文渊
Original Assignee
李耀辉
苏文渊
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 李耀辉, 苏文渊 filed Critical 李耀辉
Priority to PCT/CN2014/080105 priority Critical patent/WO2015192321A1/fr
Publication of WO2015192321A1 publication Critical patent/WO2015192321A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes

Definitions

  • the present invention relates to a pigment composition, and more particularly to an infrared low-temperature pigment composition and an infrared low-temperature material. Background technique
  • the vehicle seat is made of plastic material, such as polyvinyl chloride (PVC), polypropylene (PP), etc., and in order to reduce the staininess of the seat and the obvious degree of reflection, it is usually added to the plastic and easily used as a pigment.
  • Carbon black (car bon bl ac k). Although the use of carbon black can avoid dirt, it has the disadvantage of easily absorbing infrared rays and causing the seat to heat up rapidly.
  • various products with low temperature-increasing properties and cool feelings such as cool-feeling clothes, low-heating cushions, etc.
  • the raw material is added or added with a raw material having a cool feeling.
  • Raw materials with low temperature-increasing properties include pigments or other reagents in addition to the polymer materials used to make the substrate.
  • Japanese Patent Laid-Open No. 2002-249676 discloses a near-infrared reflective composite pigment comprising a near-infrared reflective and/or near-infrared penetrating pigment and a white pigment having good near-infrared reflectance, but it is required to be White pigment assisted;
  • Japanese Patent Laid-Open No. 2006- 24941 1 discloses a black pigment for infrared reflection, which is composed of a metal composite oxide such as iron or cobalt, and also has a good infrared reflectance, but the pigment needs to undergo a high-temperature firing process. Moreover, this document does not disclose that the pigment has an application effect of lowering the temperature rise.
  • the inventors attempted to select a plurality of readily available pigment components to be mixed to obtain an infrared low-temperature pigment composition, and the infrared low-temperature pigment composition can be made into an infrared low-temperature material with a substrate.
  • An object of the present invention is to provide an infrared low-temperature-increasing pigment composition which can reduce the temperature increase effect by absorbing infrared rays.
  • the infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component.
  • the red pigment component is selected from the group consisting of Pigment Red 122, Pigment Red 144, Pigment Red 149, Pigment Red 166, Pigment Red 181, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262, or any combination of the foregoing.
  • the yellow pigment component is selected from the group consisting of Pigment Yellow 81 (pi grriEnt yel l ow 81), Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 110, Pigment Yellow 120, Pigment Yellow 128, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Pigment Yellow 214 or any combination of the foregoing.
  • the blue pigment component is selected from the Pigment Blue 15 series (pigrriEnt bl ue 15 seri es, for example: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4. Pigment Blue 15:6), Pigment Blue 16, Pigment Blue 60, Pigment Blue 80 or any combination of the foregoing.
  • the orange pigment component is selected from Pigment Orange 43 (Pigment Orange 43), Pigment Orange 61, Pigment Orange 64, Pigment Orange 68, Pigment Orange 72, or any combination of the foregoing.
  • the violet pigment component is selected from PighoEnt violet 19, Pigment Violet 37, Pigment Violet 23 or any combination of the foregoing.
  • the brown pigment component is Pigment browi 23 (pigment browi 23).
  • the white pigment component is pigment white 6 ( 0 ) These pigments are expressed according to the color index (col or i ndex) generic name.
  • Another object of the present invention is to provide an infrared low temperature heating material comprising the infrared low temperature heating pigment composition and a substrate, which has a low temperature rising effect after absorbing infrared rays, can effectively reduce the heat absorption degree of the material, and further reduce Light user discomfort and reduce unnecessary energy consumption.
  • the beneficial effect of the invention is that the infrared low-temperature pigment composition of the invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the material.
  • the degree of heat absorption does not require the user to reduce the temperature of the material by consuming energy.
  • FIG. 1 is an infrared temperature elevation diagram illustrating the temperature rise of the black PVC film of Application Example 1, Comparative Application Example 1 and Comparative Application Example 2 after infrared irradiation, curve A shows the test result of Comparative Application Example 1, and curve B shows the comparative application example. 2 test results and curves (: indicates the test results of application example 1;
  • FIG. 2 is an infrared heating diagram illustrating the temperature rise of the black PVC film of Application Example 2 after infrared irradiation;
  • Fig. 3 is an infrared radiation diagram showing the temperature rise of the black PVC film of Application Example 3 after infrared irradiation. detailed description
  • the infrared low-temperature pigment composition of the present invention comprises at least two pigment components selected from the group consisting of a red pigment component, a yellow pigment component, a blue pigment component, an orange pigment component, and a purple pigment component. , brown pigment component or white pigment component.
  • the selection of the pigment components is based on the pigments indicated by the color index generic names listed above.
  • the pigment composition of the present invention can be selected according to the subsequent application, and the color of the pigment composition finally obtained can be any color.
  • the infrared low temperature pigment composition comprises a primary pigment component and an auxiliary pigment component.
  • the primary pigment component is selected from the red pigment component, the yellow pigment component, the blue pigment component, or any combination of the foregoing.
  • the auxiliary pigment component is selected from the orange pigment component, the violet pigment component, the brown pigment component, the white pigment component, or any combination of the foregoing.
  • the infrared low temperature pigment composition comprises a red pigment component, a yellow pigment component and a blue pigment component.
  • the red pigment component is selected from the group consisting of Pigment Red 1 22, Pigment Red 144, Pigment Red 149, Pigment Red 1 66, Pigment Red 1 81, Pigment Red 202, Pigment Red 214, Pigment Red 221, Pigment Red 242, Pigment Red 254, Pigment Red 262 or any combination of the foregoing.
  • the yellow pigment component is selected from the group consisting of Pigment Yellow 81, Pigment Yellow 83, Pigment Yellow 109, Pigment Yellow 1 10, Pigment Yellow 1 20, Pigment Yellow 1 28, Pigment Yellow 138, Pigment Yellow 147, Pigment Yellow 1 81 , Pigment Yellow 1 83, Pigment Yellow 214 or any combination of the foregoing.
  • the blue pigment component is selected from Pigment Blue 15 series (eg: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6), Pigment Blue 16, Pigment Blue 60. Pigment Blue 80 or any combination of the foregoing.
  • Pigment Blue 15 series eg: Pigment Blue 15, Pigment Blue 15: 1, Pigment Blue 15: 2, Pigment Blue 15: 3, Pigment Blue 15: 4, Pigment Blue 15: 6
  • Pigment Blue 16 Pigment Blue 60.
  • Pigment Blue 80 or any combination of the foregoing.
  • the total content of the pigment composition is 100 v ⁇ t ⁇ 1 ⁇ 2, the content of the red pigment component ranges from 11 to 50 wt%, and the content of the yellow pigment component ranges from 26 to 67 v ⁇ t. %, the content of the blue pigment component ranges from 13 to 47 wt ° / 3 ⁇ 4
  • the infrared low temperature rising material of the present invention comprises the infrared low temperature rising pigment composition and the substrate as described above.
  • the infrared low temperature heating material is prepared by adding the infrared low temperature pigment composition to a color masterbatch, a color paste or an ink, and then adding it to the substrate in an appropriate addition ratio.
  • the substrate is a polyvinyl chloride based substrate.
  • the infrared low temperature material is tested according to ASTM D803 and has a final stable temperature of 65-70 °C.
  • the infrared low temperature heating material further comprises an existing additive such as a plasticizer, a liquid stabilizer, a UV absorber, an antioxidant, a surfactant, a lubricant, a flame retardant or any combination of the foregoing.
  • an existing additive such as a plasticizer, a liquid stabilizer, a UV absorber, an antioxidant, a surfactant, a lubricant, a flame retardant or any combination of the foregoing.
  • the infrared low temperature heating material is suitable for most materials requiring low temperature increasing effects, for example, in general methods for automotive interior materials (such as plastics, plastic coating, fiber fabrics), automotive paints, baking varnishes, and paints for vehicles. , outdoor insulation paint, plastic building materials or paving materials (such as cement pavement).
  • the infrared low temperature heating material is suitable for use in black, gray or brown materials.
  • the invention is further described in the following examples, but it should be understood that these examples are for illustrative purposes only and are not to be construed as limiting.
  • the pigment compositions of Examples 1-6 were prepared by mixing according to the pigment types and content ratios in Table 1 below.
  • a total weight of the pigment composition of each of the examples is 100 wtQ / ⁇ 10
  • PVQ film Polyvinyl chloride
  • the PVC powder (S-60), the non-phthalate plasticizer, the calcium/zinc liquid stabilizer and the ultraviolet absorber are mixed in a weight ratio of 100:40:1.5:1 to obtain a PVC component.
  • Example 1 The pigment composition of Example 1 and the PVC powder were formulated into a color masterbatch (containing 25-35 v ⁇ t Q / pigment composition, the balance being PVC powder), and the color masterbatch was added to the above PVC component for color development ( containing 7-10 ⁇ t Q / masterbatch), to give a black PVC film E1.
  • a color masterbatch containing 25-35 v ⁇ t Q / pigment composition, the balance being PVC powder
  • the color masterbatch was added to the above PVC component for color development ( containing 7-10 ⁇ t Q / masterbatch), to give a black PVC film E1.
  • Application Example 2-6 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with the pigment composition of Example 2-6, respectively, and the black PVC film E2-E6 was obtained by color development.
  • Comparative Application Example 1 differs from Application Example 1 in that the pigment composition of Example 1 was replaced with carbon black, and a carbon black PVC film C1 was obtained by color development.
  • Comparative Application Example 2 differs from Application Example 1 in that a commercially available pigment (IR bl ack, main The composition was pigment green 1 7 and pigment blue 1 5: 3) Substituting the pigment composition of Example 1 and developing a black PVC film C2.
  • a commercially available pigment IR bl ack, main The composition was pigment green 1 7 and pigment blue 1 5: 3
  • the infrared light (Phi I i ps PAR38 IR Red 1 50W 1 25-130V, wavelength range 600-1400 nn) and PVC film are irradiated for 60 minutes at a distance of 17 cm, and the infrared thermometer is used every 5 minutes.
  • the PVC film temperature of Application Example 1 and the comparative application examples was measured, and the results are shown in Fig. 1.
  • the temperature of the PVC film of Application Example 2-6 was measured, and the results of Application Example 2 and Application Example 3 are shown in Fig. 2 and Fig. 3, respectively.
  • Figure 1 shows a black PVC film E1 using the infrared low-temperature pigment composition of the present invention, which has a temperature of less than 65 ° C after 60 minutes of absorption of infrared rays (curve C of Figure 1);
  • Figure 2 shows the use of the infrared low-temperature pigment of the present invention.
  • the composition of the black PVC film E2, which absorbs infrared rays for 55 minutes, has a temperature of about 70 ° C;
  • Figure 3 shows a black PVC film E3 using the infrared low-temperature pigment composition of the present invention, which absorbs infrared rays for about 55 minutes.
  • the results of the application examples 4-6 are similar to the application examples 2 - 3; the application examples 1 - 6 are significantly more than the temperature of the application of the carbon black PVC film C1 (greater than 100 ° C, as shown in Figure 1 Curve A) and the temperature of the black PVC film C2 prepared by using the commercially available pigment of Comparative Example 2 (higher than 78 ° C, as shown by curve B in FIG. 1 ) are low, which proves that the infrared low-temperature pigment composition of the present invention can reduce the absorption of infrared rays. The resulting warming effect.
  • the infrared low-temperature pigment composition of the present invention can reduce the temperature rising effect caused by absorbing infrared rays, and the infrared low-temperature heating material of the invention has low temperature-raising effect after absorbing infrared rays, and can effectively reduce the heat absorption degree of the material. The user does not need to consume energy to lower the temperature of the material.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention concerne une composition pigmentaire à faible échauffement par des rayons infrarouges, comprenant au moins deux composants pigmentaires choisis dans le groupe consistant en un composant pigment rouge, un composant pigment jaune, un composant pigment bleu, un composant pigment orangé, un composant pigment pourpre, un composant pigment brun et un composant pigment blanc. La composition pigmentaire à faible échauffement par des rayons infrarouges peut efficacement réduire l'effet d'échauffement résultant de l'absorption de rayons infrarouges. L'invention concerne aussi un matériau à faible échauffement par des rayons infrarouges, comprenant la composition pigmentaire à faible échauffement par des rayons infrarouges et un matériau formant substrat. Le matériau à faible échauffement par des rayons infrarouges présente un faible effet d'échauffement après absorption de rayons infrarouges, ce qui peut efficacement réduire le degré d'absorption de chaleur du matériau à faible échauffement par des rayons infrarouges.
PCT/CN2014/080105 2014-06-17 2014-06-17 Composition pigmentaire à faible échauffement par des rayons infrarouges, et matériau à faible échauffement par des rayons infrarouges WO2015192321A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/080105 WO2015192321A1 (fr) 2014-06-17 2014-06-17 Composition pigmentaire à faible échauffement par des rayons infrarouges, et matériau à faible échauffement par des rayons infrarouges

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/080105 WO2015192321A1 (fr) 2014-06-17 2014-06-17 Composition pigmentaire à faible échauffement par des rayons infrarouges, et matériau à faible échauffement par des rayons infrarouges

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WO2015192321A1 true WO2015192321A1 (fr) 2015-12-23

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3587475A4 (fr) * 2017-02-21 2020-12-30 Lee, Yiu Fai Composition de mélange maître de couleur pour textiles foncés ou plastiques techniques et article produit à partir de celle-ci
US11809933B2 (en) 2018-11-13 2023-11-07 Ppg Industries Ohio, Inc. Method of detecting a concealed pattern
US11808833B2 (en) 2016-10-28 2023-11-07 Ppg Industries Ohio, Inc. Coatings for increasing near-infrared detection distances
US12001034B2 (en) 2019-01-07 2024-06-04 Ppg Industries Ohio, Inc. Near infrared control coating, articles formed therefrom, and methods of making the same

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002020647A (ja) * 2000-07-05 2002-01-23 Dainippon Ink & Chem Inc 黒色顔料組成物
JP2011068737A (ja) * 2009-09-25 2011-04-07 Toyo Ink Mfg Co Ltd 太陽熱遮蔽効果を有する水性分散体および水性塗料組成物の製造法
CN102307795A (zh) * 2009-02-09 2012-01-04 威士伯采购公司 在店内可调色的不吸收红外线的漆料和色料系统
CN103502545A (zh) * 2011-05-16 2014-01-08 阿克佐诺贝尔国际涂料股份有限公司 太阳红外反射漆
CN103827231A (zh) * 2011-09-16 2014-05-28 巴斯夫欧洲公司 涂层体系
CN103865294A (zh) * 2012-12-12 2014-06-18 天彩企业有限公司 红外线低升温颜料组成物及红外线低升温材料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002020647A (ja) * 2000-07-05 2002-01-23 Dainippon Ink & Chem Inc 黒色顔料組成物
CN102307795A (zh) * 2009-02-09 2012-01-04 威士伯采购公司 在店内可调色的不吸收红外线的漆料和色料系统
JP2011068737A (ja) * 2009-09-25 2011-04-07 Toyo Ink Mfg Co Ltd 太陽熱遮蔽効果を有する水性分散体および水性塗料組成物の製造法
CN103502545A (zh) * 2011-05-16 2014-01-08 阿克佐诺贝尔国际涂料股份有限公司 太阳红外反射漆
CN103827231A (zh) * 2011-09-16 2014-05-28 巴斯夫欧洲公司 涂层体系
CN103865294A (zh) * 2012-12-12 2014-06-18 天彩企业有限公司 红外线低升温颜料组成物及红外线低升温材料

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11808833B2 (en) 2016-10-28 2023-11-07 Ppg Industries Ohio, Inc. Coatings for increasing near-infrared detection distances
US11977154B2 (en) 2016-10-28 2024-05-07 Ppg Industries Ohio, Inc. Coatings for increasing near-infrared detection distances
EP3587475A4 (fr) * 2017-02-21 2020-12-30 Lee, Yiu Fai Composition de mélange maître de couleur pour textiles foncés ou plastiques techniques et article produit à partir de celle-ci
US11034803B2 (en) * 2017-02-21 2021-06-15 Yiu Fai Lee Color masterbatch composition for dark textiles or engineering plastics and article produced therefrom
US11809933B2 (en) 2018-11-13 2023-11-07 Ppg Industries Ohio, Inc. Method of detecting a concealed pattern
US12050950B2 (en) 2018-11-13 2024-07-30 Ppg Industries Ohio, Inc. Method of detecting a concealed pattern
US12001034B2 (en) 2019-01-07 2024-06-04 Ppg Industries Ohio, Inc. Near infrared control coating, articles formed therefrom, and methods of making the same

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