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WO2011156892A3 - Integrated chemicals complex containing olefins - Google Patents

Integrated chemicals complex containing olefins Download PDF

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Publication number
WO2011156892A3
WO2011156892A3 PCT/CA2011/000676 CA2011000676W WO2011156892A3 WO 2011156892 A3 WO2011156892 A3 WO 2011156892A3 CA 2011000676 W CA2011000676 W CA 2011000676W WO 2011156892 A3 WO2011156892 A3 WO 2011156892A3
Authority
WO
WIPO (PCT)
Prior art keywords
ethylene
complex containing
containing olefins
complex
olefins
Prior art date
Application number
PCT/CA2011/000676
Other languages
French (fr)
Other versions
WO2011156892A2 (en
Inventor
Andrzej Krzywicki
Charles Ashton Garret Carter
Ian Ronald Jobe
Kamal Elias Serhal
Original Assignee
Nova Chemicals (International) S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals (International) S.A. filed Critical Nova Chemicals (International) S.A.
Publication of WO2011156892A2 publication Critical patent/WO2011156892A2/en
Publication of WO2011156892A3 publication Critical patent/WO2011156892A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/34—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts
    • C10G9/36—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by direct contact with inert preheated fluids, e.g. with molten metals or salts with heated gases or vapours
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

The present invention provides an integrated chemical complex comprising one or more unit operations selected from the group consisting of a steam cracker comprising a C2 splitter, a linear alpha olefin plant and a solution or slurry polyethylene plant the improvement comprising integrating into the complex a reactor for the trimerization or tetramerization of ethylene in the presence of a catalyst system comprising: (iv) a source of chromium; (v) a defined P-N-P ligand; and (vi) an activator and a distillation column to separate one or more of ethylene, 1-hexene, 1-octene which olefins containing less than 1.5 weight % of internal olefins. The integration provides savings in terms of capital costs, operating costs or both.
PCT/CA2011/000676 2010-06-18 2011-06-09 Integrated chemicals complex containing olefins WO2011156892A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2708011 2010-06-18
CA2708011A CA2708011C (en) 2010-06-18 2010-06-18 Integrated chemicals complex containing olefins

Publications (2)

Publication Number Publication Date
WO2011156892A2 WO2011156892A2 (en) 2011-12-22
WO2011156892A3 true WO2011156892A3 (en) 2012-02-02

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2011/000676 WO2011156892A2 (en) 2010-06-18 2011-06-09 Integrated chemicals complex containing olefins

Country Status (2)

Country Link
CA (1) CA2708011C (en)
WO (1) WO2011156892A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104511311A (en) * 2013-09-30 2015-04-15 华东理工大学 High-selectivity catalyst system used in trimerization and tetramerization of ethylene and use method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2800268C (en) 2012-12-21 2020-02-25 Nova Chemicals Corporation Continuous ethylene tetramerization process
US9199889B2 (en) * 2013-03-15 2015-12-01 Altex Technologies Corporation Method and apparatus for conversion of carbonaceous materials to liquid fuel
CA2835683C (en) 2013-12-05 2021-07-06 Nova Chemicals Corporation Ethylene oligomerization with mixed ligands
CA2837590C (en) 2013-12-23 2020-12-15 Nova Chemicals Corporation Continuous ethylene oligomerization with in-situ catalyst preparation
CA2847814C (en) 2014-03-27 2021-09-28 Nova Chemicals Corporation Self cleaning reactor system
CN108025996A (en) * 2015-09-16 2018-05-11 沙特基础工业全球技术有限公司 Method for the inactivation of olefin oligomerization catalyst
WO2017187289A1 (en) * 2016-04-25 2017-11-02 Sabic Global Technologies B.V. Process for removing heat from an oligomerization reaction
US11015131B2 (en) 2018-08-22 2021-05-25 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
WO2020041096A1 (en) 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US10889769B2 (en) 2018-08-22 2021-01-12 Exxonmobil Research And Engineering Company Manufacturing a base stock from ethanol
US10858599B2 (en) 2018-08-22 2020-12-08 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US10858600B2 (en) 2018-08-22 2020-12-08 Exxonmobil Research And Engineering Company Manufacturing a base stock
EP3841188A1 (en) 2018-08-22 2021-06-30 ExxonMobil Research and Engineering Company Manufacturing a base stock from ethanol
FR3116738A1 (en) 2020-11-30 2022-06-03 IFP Energies Nouvelles NEW CATALYTIC COMPOSITION BASED ON CHROMIUM COMPRISING AN AROMATIC ETHER ADDITIVE AND ASSOCIATED PROCESS FOR THE OLIGOMERIZATION OF ETHYLENE INTO OCTENE-1
FR3116739A1 (en) 2020-11-30 2022-06-03 IFP Energies Nouvelles NEW CATALYTIC COMPOSITION BASED ON CHROME COMPRISING AN AROMATIC HYDROCARBON ADDITIVE AND ASSOCIATED METHOD FOR THE OLIGOMERIZATION OF ETHYLENE INTO OCTENE-1
FR3140775A1 (en) 2022-10-17 2024-04-19 IFP Energies Nouvelles New catalytic composition based on supported chromium or titanium

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5981818A (en) * 1995-03-21 1999-11-09 Stone & Webster Engineering Corp. Integrated cracking and olefins derivative process utilizing dilute olefins
US6111156A (en) * 1998-11-10 2000-08-29 Nova Chemicals (International) S.A. Integrated high temperature high conversion olefin/polyolefin process
WO2007016993A1 (en) * 2005-07-29 2007-02-15 Saudi Basic Industries Corporation Method for preparing linear alpha-olefins
WO2010034102A1 (en) * 2008-09-29 2010-04-01 Nova Chemicals (International) S. A. Ethylene tetramerization catalysts comprising p-n-p ligands
WO2010034101A1 (en) * 2008-09-29 2010-04-01 Nova Chemicals (International) S.A. Ethylene trimerization catalysts comprising p-n-p ligands and their use

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5981818A (en) * 1995-03-21 1999-11-09 Stone & Webster Engineering Corp. Integrated cracking and olefins derivative process utilizing dilute olefins
US6111156A (en) * 1998-11-10 2000-08-29 Nova Chemicals (International) S.A. Integrated high temperature high conversion olefin/polyolefin process
WO2007016993A1 (en) * 2005-07-29 2007-02-15 Saudi Basic Industries Corporation Method for preparing linear alpha-olefins
WO2010034102A1 (en) * 2008-09-29 2010-04-01 Nova Chemicals (International) S. A. Ethylene tetramerization catalysts comprising p-n-p ligands
WO2010034101A1 (en) * 2008-09-29 2010-04-01 Nova Chemicals (International) S.A. Ethylene trimerization catalysts comprising p-n-p ligands and their use

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104511311A (en) * 2013-09-30 2015-04-15 华东理工大学 High-selectivity catalyst system used in trimerization and tetramerization of ethylene and use method thereof
CN104511311B (en) * 2013-09-30 2017-07-07 华东理工大学 A kind of ethylene trimer of high selectivity, four poly- catalyst systems and its application method

Also Published As

Publication number Publication date
WO2011156892A2 (en) 2011-12-22
CA2708011A1 (en) 2011-12-18
CA2708011C (en) 2016-10-25

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