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WO2011011492A3 - Decarboxylation cell for production of coupled radical products - Google Patents

Decarboxylation cell for production of coupled radical products Download PDF

Info

Publication number
WO2011011492A3
WO2011011492A3 PCT/US2010/042715 US2010042715W WO2011011492A3 WO 2011011492 A3 WO2011011492 A3 WO 2011011492A3 US 2010042715 W US2010042715 W US 2010042715W WO 2011011492 A3 WO2011011492 A3 WO 2011011492A3
Authority
WO
WIPO (PCT)
Prior art keywords
metal salt
radicals
alkali metal
coupled radical
electrolytic cell
Prior art date
Application number
PCT/US2010/042715
Other languages
French (fr)
Other versions
WO2011011492A2 (en
Inventor
Sai Bhavaraju
Mukund Karanjikar
Ashok Joshi
Joel Hunt
Pallavi Chitta
Original Assignee
Ceramatec, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec, Inc. filed Critical Ceramatec, Inc.
Priority to CN201080024541.8A priority Critical patent/CN102471903B/en
Priority to BR112012001505-2A priority patent/BR112012001505A2/en
Publication of WO2011011492A2 publication Critical patent/WO2011011492A2/en
Publication of WO2011011492A3 publication Critical patent/WO2011011492A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/29—Coupling reactions
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.
PCT/US2010/042715 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products WO2011011492A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201080024541.8A CN102471903B (en) 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products
BR112012001505-2A BR112012001505A2 (en) 2009-07-23 2010-07-21 decarboxylation cell for the production of coupled radical products

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US22807809P 2009-07-23 2009-07-23
US61/228,078 2009-07-23
US25855709P 2009-11-05 2009-11-05
US61/258,557 2009-11-05
US26096109P 2009-11-13 2009-11-13
US61/260,961 2009-11-13

Publications (2)

Publication Number Publication Date
WO2011011492A2 WO2011011492A2 (en) 2011-01-27
WO2011011492A3 true WO2011011492A3 (en) 2011-06-16

Family

ID=43499642

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/042715 WO2011011492A2 (en) 2009-07-23 2010-07-21 Decarboxylation cell for production of coupled radical products

Country Status (4)

Country Link
CN (1) CN102471903B (en)
BR (1) BR112012001505A2 (en)
MY (1) MY155642A (en)
WO (1) WO2011011492A2 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8853463B2 (en) 2011-01-25 2014-10-07 Ceramatec, Inc. Decarboxylation of levulinic acid to ketone solvents
WO2013096225A1 (en) * 2011-12-19 2013-06-27 Ceramatec, Inc. Decarboxylation of levulinic acid to ketone solvents
CN104099120A (en) * 2013-04-11 2014-10-15 中国科学院青岛生物能源与过程研究所 Method for preparing aviation liquid fuel by using biodiesel
AU2015318539B2 (en) * 2014-09-15 2020-07-09 Advonex International Corp. Production of hydrocarbons by Kolbe decarboxylation of a mixture of saturated and unsaturated fatty acids
CN110079821B (en) * 2019-04-08 2021-01-15 天津大学 Method for preparing propane by electrolyzing low-concentration adipic acid solution
CN109913891B (en) * 2019-04-08 2021-01-15 天津大学 A kind of method for preparing methane by electrolysis of succinic acid solution
CN110042420B (en) * 2019-04-08 2021-01-15 天津大学 A kind of electrochemical preparation method of methane
CN110029355B (en) * 2019-04-08 2021-01-15 天津大学 Electrochemical preparation method of propane
CN110042418B (en) * 2019-04-08 2021-01-15 天津大学 Electrochemical preparation method of 1,3, 5-hexatriene
CN110042419B (en) * 2019-04-08 2021-01-15 天津大学 A kind of method for preparing propane by itaconic acid electrolysis
CN110004458B (en) * 2019-04-08 2020-11-10 天津大学 Electrochemical preparation method of acrolein
CN110016689B (en) * 2019-04-08 2021-01-15 天津大学 Electrochemical preparation method of allyl alcohol
CN110016688B (en) * 2019-04-08 2020-11-06 天津大学 Electrochemical preparation method of alcohol substance

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290405A (en) * 1991-05-24 1994-03-01 Ceramatec, Inc. NaOH production from ceramic electrolytic cell
US20050177008A1 (en) * 2003-12-11 2005-08-11 Shekar Balagopal Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
US20090074611A1 (en) * 2005-09-15 2009-03-19 Battelle Memorial Institute Photolytic generation of hydrogen peroxide

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7955489B2 (en) * 2006-02-08 2011-06-07 Dynamic Food Ingredients Corporation Methods for the electrolytic production of erythrose or erythritol
CN101089231A (en) * 2007-07-16 2007-12-19 云南大学 Electrolytic oxidation coupling of aryl-1,3-dicarbonyl compound and oxolane type high efficient PAF antagonist (anti)-2-5 II (3,4,5 trimethoxyphenyl) oxolane and synthesis method of its analogue

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290405A (en) * 1991-05-24 1994-03-01 Ceramatec, Inc. NaOH production from ceramic electrolytic cell
US20050177008A1 (en) * 2003-12-11 2005-08-11 Shekar Balagopal Electrolytic method to make alkali alcoholates using ceramic ion conducting solid membranes
US20090074611A1 (en) * 2005-09-15 2009-03-19 Battelle Memorial Institute Photolytic generation of hydrogen peroxide

Also Published As

Publication number Publication date
CN102471903B (en) 2015-03-11
BR112012001505A2 (en) 2020-10-27
MY155642A (en) 2015-11-13
WO2011011492A2 (en) 2011-01-27
CN102471903A (en) 2012-05-23

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