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WO2009051160A1 - Molded article, and method for production thereof - Google Patents

Molded article, and method for production thereof Download PDF

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Publication number
WO2009051160A1
WO2009051160A1 PCT/JP2008/068708 JP2008068708W WO2009051160A1 WO 2009051160 A1 WO2009051160 A1 WO 2009051160A1 JP 2008068708 W JP2008068708 W JP 2008068708W WO 2009051160 A1 WO2009051160 A1 WO 2009051160A1
Authority
WO
WIPO (PCT)
Prior art keywords
copolymer
vinyl alcohol
double bond
epoxy compound
molded article
Prior art date
Application number
PCT/JP2008/068708
Other languages
French (fr)
Japanese (ja)
Inventor
Kazuhiro Kurosaki
Emi Yatagai
Kaoru Ikeda
Tomoyuki Watanabe
Original Assignee
Kuraray Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co., Ltd. filed Critical Kuraray Co., Ltd.
Priority to JP2009538125A priority Critical patent/JP5409376B2/en
Publication of WO2009051160A1 publication Critical patent/WO2009051160A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/08Epoxidation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246Intercrosslinking of at least two polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/28Treatment by wave energy or particle radiation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02Homopolymers or copolymers of unsaturated alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

Disclosed is a molded article which is produced from a resin composition comprising a modified ethylene-(vinyl alcohol) copolymer (C-1) and a modified ethylene-(vinyl alcohol) copolymer (C-2), wherein the at least a part of the resin composition is cross-linked so as to have a gel fraction of 3 mass% or more. The modified ethylene-(vinyl alcohol) copolymer (C-1) is produced by modifying an unmodified ethylene-(vinyl alcohol) copolymer (A-1) with an epoxy compound (B-1) having a double bond, wherein the ratio of modification with the epoxy compound (B-1) having a double bond is 0.1 to 10 mol%. The modified ethylene-(vinyl alcohol) copolymer (C-2) is produced by modifying an unmodified ethylene-(vinyl alcohol) copolymer (A-2) with an epoxy compound (B-2) having no double bond, wherein the ratio of modification with the epoxy compound (B-2) having no double bond is 0.3 to 40 mol%. It becomes possible to provide a molded article which is excellent in hot water resistance, heat resistance, gas barrier properties, heat-sealing properties in a wide temperature range, thermal shrinkability properties and flexibility.
PCT/JP2008/068708 2007-10-17 2008-10-16 Molded article, and method for production thereof WO2009051160A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009538125A JP5409376B2 (en) 2007-10-17 2008-10-16 Molded product and manufacturing method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007269981 2007-10-17
JP2007-269981 2007-10-17

Publications (1)

Publication Number Publication Date
WO2009051160A1 true WO2009051160A1 (en) 2009-04-23

Family

ID=40567422

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068708 WO2009051160A1 (en) 2007-10-17 2008-10-16 Molded article, and method for production thereof

Country Status (2)

Country Link
JP (1) JP5409376B2 (en)
WO (1) WO2009051160A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7628585B2 (en) 2021-12-24 2025-02-10 株式会社クラレ Resin composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03281542A (en) * 1990-03-29 1991-12-12 Kuraray Co Ltd Molded objects and multilayer structures
JP2003327619A (en) * 2002-05-14 2003-11-19 Kuraray Co Ltd Method for producing modified ethylene-vinyl alcohol copolymer
JP2004161895A (en) * 2002-11-13 2004-06-10 Kuraray Co Ltd Injection molding and injection molding method
WO2007123108A1 (en) * 2006-04-17 2007-11-01 Kuraray Co., Ltd. Molded article and method for production thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03281542A (en) * 1990-03-29 1991-12-12 Kuraray Co Ltd Molded objects and multilayer structures
JP2003327619A (en) * 2002-05-14 2003-11-19 Kuraray Co Ltd Method for producing modified ethylene-vinyl alcohol copolymer
JP2004161895A (en) * 2002-11-13 2004-06-10 Kuraray Co Ltd Injection molding and injection molding method
WO2007123108A1 (en) * 2006-04-17 2007-11-01 Kuraray Co., Ltd. Molded article and method for production thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7628585B2 (en) 2021-12-24 2025-02-10 株式会社クラレ Resin composition

Also Published As

Publication number Publication date
JPWO2009051160A1 (en) 2011-03-03
JP5409376B2 (en) 2014-02-05

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