WO2008103021A2 - Device and method for producing a food item of rolled dough - Google Patents
Device and method for producing a food item of rolled dough Download PDFInfo
- Publication number
- WO2008103021A2 WO2008103021A2 PCT/MX2008/000023 MX2008000023W WO2008103021A2 WO 2008103021 A2 WO2008103021 A2 WO 2008103021A2 MX 2008000023 W MX2008000023 W MX 2008000023W WO 2008103021 A2 WO2008103021 A2 WO 2008103021A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dough
- food
- hole
- spiral
- extruder
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J9/00—Apparatus or utensils for shaping or dispensing portions of butter or the like
- A47J9/002—Apparatus or utensils for shaping or dispensing portions of butter or the like by forming, e.g. peeling off or extruding, curls or rings
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21C—MACHINES OR EQUIPMENT FOR MAKING OR PROCESSING DOUGHS; HANDLING BAKED ARTICLES MADE FROM DOUGH
- A21C11/00—Other machines for forming the dough into its final shape before cooking or baking
- A21C11/16—Extruding machines
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/117—Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
- A23L7/13—Snacks or the like obtained by oil frying of a formed cereal dough
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P30/00—Shaping or working of foodstuffs characterised by the process or apparatus
- A23P30/20—Extruding
Definitions
- the present invention relates to an apparatus and method for forming dough tubes that resemble, when cut, a rolled dough product. Specifically, this invention relates to a method and apparatus for producing rolled dough pieces using an extrusion die having a spiral orifice pattern.
- Rolls products are found in many different food industries such as crescent buns, waffle bars, flutes and frozen / stuffed taquitos. Many of the prior art procedures have been developed to address the complexities of winding each of these products.
- the crescent roll industry generally uses a relative speed differential between two bands.
- the crescent roll industry uses relatively thick dough with a high degree of stickiness, which makes it absolutely easy to manipulate.
- the wafer bar industry typically uses a milkshake or pastry mixture that is dried by means of a drum, is wound around a mandrel at an angle of 45 degrees, and then cut into pieces.
- the dough typically used comprises one or more starches and / or flour, said dough is then formed into very thin sheets, cut into pieces, and then roasted, fried and / or baked.
- Typical types of dough include, but are not limited to, the following: potato, rice, corn and wheat based doughs. It is particularly desirable to produce a cylindrical sandwich piece, typically made of a thin sheet dough that is roasted and / or fried, and seasoned.
- the dough used in said snack products unlike the dough used in other food industries, is generally very thin, fragile and difficult to handle. This makes the typical winding technology unacceptable for said application.
- the processing speeds required in the snack food industry are very high in relation to other industries, making rolling the dough even more difficult when using a laminated starting material.
- the '974 patent refers to an apparatus for rolling dough that has a "pre-winding mesh” and a “final winding mesh” and repeatedly emphasizes the need for said meshes to be placed on an "acceleration conveyor belt” that operates faster than the preceding "conveyor belt”.
- the '974 Patent in column 4, lines 53-55 states that "[n] ext towards the conveyor belt 106 it is an acceleration conveyor belt 108 with a cross-sectional area that advances at a speed greater than the output conveyor belt 106 ".
- the patent” 974 continues, "pre meshes are placed. winding 1 19 with a small contact surface and are dragged with the mesh of the acceleration conveyor belt
- Patents '293 and' 583 emphasize that the dough pieces are to be stretched and transferred to an unreduced winding apparatus significantly to the adhesion of the dough pieces
- the methods of the prior art for rolling dough pieces to half-moon sandwich shapes employed the use of flour to make the dough pieces less adhesive and more easily handled
- the '293 Patents and '583 teach that such loss of adhesion is disadvantageous in producing closely wound half-moon sandwiches.
- ' 293 and '583 do not provide a means to Ensure that the mass winding curtain effectively initiates a winding action, nor does it offer solutions to the problems of carrying out a more complete winding and avoiding the clogging of the product along the flat surface of the mass winding conveyor belt.
- it is possible to use a single mass rolling curtain to roll a piece of rolled dough said The device tends to have lower winding efficiency and lower production than is desirable.
- the US attempt No. 4,389,176 (the "Patent '176") granted to Nenci on June 21, 1983 and entitled "Machine for the Production of Tubular Covers of Food Dough".
- the '176 Patent refers to a dough wrapping device where pieces of dough are wrapped around support cores to form cannon tubes.
- the '176 Patent describes the use of a metal mesh sieve as a mass winding device, the metal mesh of the Patent '176 is supported and maintained between two rollers. See Patent '176 in column 6, lines 26-30.
- a flat mesh screen shown may not be suitable for thin and fragile doughs such as corn dough in the form of a thin sheet, since said flat sieve can unduly concentrate winding forces and pressure in the minimum contact area between the flat screen and rolled dough products. This could probably result in the destruction of the fragile mass product. In this way, a flexible chain or mesh curtain is critical for rolling fragile dough pre-forms.
- US Patent No. 7,156,642 (the "patent '642") issued on January 2, 2007, and entitled “Apparatus and Method for Rolling Dough”.
- the apparatus described in the '642 Patent comprises an apparatus for rolling dough having a dough sheeter, a receiving conveyor belt having a ramp section, a roll initiation curtain placed above the ramp section just downstream of the peak of the ramp, and a roll completion curtain placed under the roll initiation curtain.
- a ramp mass winding conveyor belt solves the problem of jamming of pre-forms (rolled and cut dough pieces) and roll fall as they pass through under the first curtain or group of curtains.
- the '642 Patent is an improvement with respect to the prior art in this field, careful attention is required for several of the components of the' 642 Patent apparatus in order to maintain a consistently rolled product. For example, if any mass develops on the winding curtains, the shape of the final product is altered. As with any rolling arrangement, mass development emissions in components are always present, thus requiring frequent cleaning.
- the invention comprises a method and apparatus for producing a rolled dough product.
- This rolled dough product is formed as individual pieces with the appearance of a flute or taquito shape.
- the pieces are formed by extruding a food dough through a spiral shaped hole.
- the extrudate is cut into individual segments, thus forming individual food pieces. These pieces can then be cooked, typically fried.
- Figure 2 is a perspective view of the extruded product leaving an extruder die according to an embodiment of the invention
- Figures 3a and 3b are perspective views of a product made in accordance with an embodiment of the present invention
- Figure 4 is an exploded view of an extruder die insert assembly according to an embodiment of the present invention.
- Figures 5a and 5b are views of the front and rear of a die insert assembly according to an embodiment of the present invention.
- Figure 6 is a side view of an extruder of the prior art and cutting mechanism
- Figure 7 is a plan view of the extruder die face according to an embodiment of the present invention.
- the invention of the applicant produces a snack food type piece, which has a rolled appearance, but is not rolled through the manufacturing, at least not through the methods used in the prior art. Rather, applicants use extrusion technology to produce a food piece that provides the appearance of having been rolled from a lamination process.
- Figures 1 a and 1 b show the front part (exit) and the rear part (entrance), respectively, of an extrusion die insert 102 according to an embodiment of the Applicant's invention.
- the die insert 102 is shown in a plan view from the perspective of the outlet portion of the spiral hole 104 of the Applicant.
- Figure 1b again a plan view, shows the opposite side of the die insert 102, thus revealing the inlet opening towards the hole 106 in a spiral shape. It should be noted that the inlet 106 to the hole is wider than the outlet 104 of the hole.
- the internal width of the hole between the inlet 106 and the outlet 104 gradually and linearly is reduced from the width of the inlet 106 to the width of the outlet 104, in the illustrated mode. This reduction in width allows the introduction of the extruded product into the insert of 08 000023
- the typical width of the outlet portion of the hole 104 is between 0.5 mm and about 3.0 mm, and the width of the inlet 106 about twice the width of the outlet 104.
- the die insert 202 is shown together with an extruded material 208 that emerges from the spiral-shaped hole.
- This extruded material 208 (or extrusion material), when extruded at high speeds, essentially forms an extruded mass or filament, which in its cross section, is spirally shaped.
- the extruded filament is cut through known means in the technique along the surface of the die insert 202. The cutting of the extrudate 208 into individual pieces produces a rolled dough product that can then be cooked, typically, fried, through means known in the art.
- a typical snack-type part 308 formed through the Applicant's method and apparatus is shown.
- the individual piece 308 has a first end 312 and a second end 310.
- the second end 310 is generally a flatter surface, since the second end 310 results from the cutting of the extruded product on the face of the die insert as described above.
- the first end 312 of the piece therefore, is first formed by emerging from the die insert immediately after the previous piece has been cut along the face of the die insert.
- the variations in the axial flow rate of the extruded product through the hole result in a slightly irregular shape of the first end 312 of the piece.
- a slightly open skirt 314 is shown.
- This slightly open skirt 314 may be desirable in order to give the food piece a shape that is more favorable for using the piece 308 as a ladle or hand shovel for various dressings, and sauces.
- the shape of this skirt 314 depends on the mass material used, the various processing parameters through the extruder, and the shape of the hole of the die insert. An additional insert hole mode given that it provides a more open skirt 314 is discussed below with respect to Figures 5a and 5b.
- the piece can vary in length from 1 cm to 40 cm and a width of 0.5 cm to 3.0 cm. Referring to Figure 4, an exploded view of a formation die insert 402 and its separation die insert 420 is illustrated. This particular forming die insert 402 has six individual spiral-shaped holes, 406, over an individual insert.
- the formation die insert 402 coincides with the separation die insert 420 and maintains an appropriate position with it through two posts 424 on the separation die insert 420 which are received by two ports 426 on the die die insert.
- formation 402. The purpose of the separation die insert 420 is to channel the flow of extruded product from the extruder body to the discrete dough channels through corresponding openings 422 that coincide with, and direct the flow into the individual holes 406. Consequently, during operation, a mass of extruded product first flows through the openings 422 of the separation die insert 420 and then through the holes 406 of the formation die insert 402.
- Figures 5a and 5b show an alternative embodiment of a die insert assembly.
- FIG 5a shows, in a plan view, the formation die insert 502 with several individual holes 504 in a spiral shape having a slightly different shape to that shown in Figure 4.
- each hole 504 in the form of a spiral has a tail or extreme Proration 505 which, when viewed from the outside of the spiral, inverts the curvature of the spiral 504 from convex to concave. Consequently, the hole 504 in the embodiment illustrated in Figure 5a is said to have a concave end portion 505.
- the use of the term "concave end portion”, by the Applicants, is intended to describe the portion 505 of the hole 504 illustrated in the figure 5th. A die insert having this concave end portion produces an end product with a block shape.
- Figure 5b shows how the die assembly matches the openings 522 of the separation die insert 520 with the hole 506 of the formation die insert. It should be understood that more than one separation die insert can be used with the Applicants' training die insert, but Applicants have illustrated an individual separation 520 insert 520 as a modality. preferred. The extrudate flows through the openings 522, then into the spiral hole 506.
- Figure 6 shows a side view of an assembly of a tube return extruder 610, bell 612 and die 614 of the prior art.
- the product such as the mass
- An arrow 616 extends through the turn 610, the bell 612. and die 614.
- Mounted on the end of arrow 616 is a cutting mechanism.
- the cutting mechanism comprises a hopper 630, rays 632 extending from the hopper 630, and blade supports 634 attached to the rays. Each blade holder 634 in turn maintains a blade 636 in contact with the die 614.
- Figure 7 shows a plan view of the die face
- the die face 715 will typically exhibit a number of die inserts 702 having at least one hole each, thus allowing product communication from the bell, through the die 714, and on the die face 715. As the product leaves these holes, it is cut into relatively uniform pieces through the blades 736 as the entire cutting mechanism revolves around the arrow in the direction 740 illustrated in Figure 7. Said rotation 740 is typically at speeds ranging from fifty to three hundred rpm, with approximately one hundred and forty rpm generally used to cut the extruded product from dough. It should be understood that the cutting mechanism shown in Figure 7 is, but one of several modalities of the cutting devices of the prior art, which can be used to cut the extruded product as it exits the holes. For example, oscillating blades or cutting cables can also be used.
- any direct low pressure or high pressure extrusion process can be used to push the mass of extruded product through the forming die to form the food pieces according to the invention of the Applicants.
- a vertical extruder is used, such as a vertical extruder through which an individual piston, in an upright position, pushes and advances the mass of extruded product against the forming die and, therefore, forcing its flow through the hole.
- a typical reciprocal pressure in said extruder, using corn-based doughs and the Applicants method is approximately 21.09 kg / cm2 at approximately 84.36 kg / cm2, depending on the flow rate chosen from the extruder.
- the conditions of the procedure can be varied to obtain different textures and flavors of the product.
- Some of these process conditions include the degree of cooking of the base material before extrusion, the temperature of the extruded product, the humidity of the extruded product, the particle size distribution of the extruded product, the length of the piece produced, and the cooking time and temperature
- a corn-based nixtamal flour such as Maseca flour
- water at a mass moisture level of between 45% to 55% by weight, or preferably about 49%. If the dough has too much moisture, it will lose its shape as it leaves the dice. Conversely, if it has very low humidity, it will stick to the extruder, die or other equipment.
- a typical mixing time of the flour with water is about 10 to about 30 minutes in a low shear mixing operation. The purpose of this mixing step is the hydration of the flour.
- This dough is made of a combination of yellow and white corn (typically a 50/50 combination). It is cooked with an addition of 1% by weight of lime until it has a moisture content of approximately 36%, which typically takes 6-8 minutes. It is then soaked until the moisture content is approximately 45%, which normally takes approximately 12 hours. The corn is then drained from the water and washed. This whole corn, cooked, soaked and washed is then transported to a drainage band to a corn mill that has a mill hole set between 0.04318 centimeters and 0.0508 centimeters as the target. Water with the corn is added to the corn mill in order to bring the total moisture level by weight of the resulting corn-based dough to between 45% to about 51%, with the same consideration for shape retention and stickiness of mass as described above.
- the corn-based dough is then extruded as previously detailed.
- the temperature of the dough in the extruder varies from about 18 0 C to about 28 0 C for the mass of corn nixtamal flour and from about 3 0 C to about 4 0 0 C for fresh ground corn dough.
- the filament of the extruded product is cut into individual pieces as it exits the extruder, preferably over a length of approximately 3.0 cm to approximately 7.0 cm.
- these food pieces are then immediately fried in hot oil, typically with a fryer temperature of about 19O 0 C to about 198 0 C.
- the residence time in the fryer for a typical product produced by the preferred mode of Applicants is between 25 seconds to approximately 60 seconds, depending on the size and texture and flavor desired.
- Individual food pieces are typically fried at a humidity level of about 1% to 3%. The pieces are then seasoned and packed through methods previously known in the art.
- the invention of the Applicants can be used to produce a product that has a rolling appearance, made of a number of suitable starting materials, either alone or in combination, such as wheat, rice, oats, sorghum, barley, barley in malt, rye, rye in malt, corn in malt, and other grains or pseudo-cereals such as amaranth, vegetables and legumes such as soybeans, beans, beans, peas, lentils, as well as sources of tuberous starchy starch, such as potatoes, sweet potatoes, cassava, dairy and meat products, such as cheese, cottage cheese, casein / milk caseinates, yogurt , pork and its by-products, beef and its by-products, and chicken meat and its by-products.
- suitable starting materials such as wheat, rice, oats, sorghum, barley, barley in malt, rye, rye in malt, corn in malt, and other grains or pseudo-cereals such as amaranth, vegetables and legumes such
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- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Nutrition Science (AREA)
- Confectionery (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- Manufacturing And Processing Devices For Dough (AREA)
- Formation And Processing Of Food Products (AREA)
- Seeds, Soups, And Other Foods (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2678223A CA2678223C (en) | 2007-02-21 | 2008-02-21 | Device and method for producing a food item of rolled dough |
MX2009008992A MX2009008992A (en) | 2007-02-21 | 2008-02-21 | Device and method for producing a food item of rolled dough. |
EP08723805.1A EP2140997B1 (en) | 2007-02-21 | 2008-02-21 | Device and method for producing a food item of rolled dough |
BRPI0808010-0A BRPI0808010B1 (en) | 2007-02-21 | 2008-02-21 | apparatus and method for producing rolled shaped food piece and rolled shaped food piece |
PL08723805T PL2140997T3 (en) | 2007-02-21 | 2008-02-21 | Device and method for producing a food item of rolled dough |
ES08723805.1T ES2549867T3 (en) | 2007-02-21 | 2008-02-21 | Apparatus and procedure for the production of a rolled-up food product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/677,469 US7585531B2 (en) | 2007-02-21 | 2007-02-21 | Method for production of rolled dough food piece |
US11/677,469 | 2007-02-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008103021A2 true WO2008103021A2 (en) | 2008-08-28 |
WO2008103021A3 WO2008103021A3 (en) | 2009-12-03 |
Family
ID=39706884
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/MX2008/000023 WO2008103021A2 (en) | 2007-02-21 | 2008-02-21 | Device and method for producing a food item of rolled dough |
Country Status (14)
Country | Link |
---|---|
US (2) | US7585531B2 (en) |
EP (1) | EP2140997B1 (en) |
AR (1) | AR065415A1 (en) |
BR (1) | BRPI0808010B1 (en) |
CA (1) | CA2678223C (en) |
CR (1) | CR10972A (en) |
ES (1) | ES2549867T3 (en) |
GT (1) | GT200900232A (en) |
NI (1) | NI200900160A (en) |
PA (1) | PA8865201A1 (en) |
PL (1) | PL2140997T3 (en) |
SV (1) | SV2009003360A (en) |
WO (1) | WO2008103021A2 (en) |
ZA (1) | ZA200905801B (en) |
Families Citing this family (19)
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US20030039728A1 (en) * | 2001-08-21 | 2003-02-27 | Herrick James Peter | Device and method for on-demand dispensing of spoonable or drinkable food products having visual appearance of multi-components |
GB201004902D0 (en) * | 2010-03-23 | 2010-05-05 | Cadbury Uk Ltd | Consumables and methods of production thereof |
USD676245S1 (en) * | 2010-03-30 | 2013-02-19 | Colgate-Palmolive Company | Oral care implement |
US20110256281A1 (en) * | 2010-04-20 | 2011-10-20 | Charles Johnson | Cheese fabricating machine and method |
US8926308B2 (en) | 2010-04-21 | 2015-01-06 | Intercontinental Great Brands Llc | Dough extruders and methods |
CN101856676A (en) * | 2010-06-18 | 2010-10-13 | 上海交通大学 | Sheet Production Method Based on Extruded Helical Strip Expansion |
EP2401926A1 (en) | 2010-06-29 | 2012-01-04 | Nestec S.A. | Method for making a multilayered food product and corresponding product |
US8353742B1 (en) | 2012-04-30 | 2013-01-15 | Choi Young S | Automatic sausage rolling machine |
WO2015139906A1 (en) * | 2014-03-18 | 2015-09-24 | Rustichella D'abruzzo S.P.A. | Spaghetti-like long pasta shape and relative production device |
USD732791S1 (en) * | 2014-07-22 | 2015-06-30 | Hill's Pet Nutrition, Inc. | Pet food piece |
US20190191742A1 (en) * | 2016-03-04 | 2019-06-27 | Xiang Chen | Edible Pet Chew and Method of Manufacture thereof |
US10219529B2 (en) * | 2016-03-04 | 2019-03-05 | DeYu Chen | Edible dog chew with lengthwise extruded interior and method of manufacture |
USD817727S1 (en) * | 2016-11-10 | 2018-05-15 | Frito-Lay North America, Inc. | Food extrusion die |
USD845089S1 (en) * | 2016-11-10 | 2019-04-09 | Frito-Lay North America, Inc. | Food extrusion die |
USD844393S1 (en) * | 2016-11-10 | 2019-04-02 | Frito-Lay North America, Inc. | Food extrusion die |
USD846361S1 (en) * | 2016-11-10 | 2019-04-23 | Frito-Lay North America, Inc. | Food extrusion die |
FR3063873B1 (en) * | 2017-03-15 | 2019-04-19 | Fromageries Bel | PROCESS FOR PRODUCING CHEESE SPIRAL AND WINDING DEVICE FOR SUCH PRODUCTION |
USD897626S1 (en) * | 2018-03-14 | 2020-10-06 | Frito-Lay North America, Inc. | Snack food product |
IT201800007432A1 (en) * | 2018-07-23 | 2020-01-23 | METHOD OF MAKING A FOOD KIT FOR THE PREPARATION OF FRESH FILLED PASTA, FOOD KIT OBTAINED AND METHOD OF USE |
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US4905583A (en) | 1986-06-18 | 1990-03-06 | Rheon Automatic Machinery Co., Ltd. | Apparatus and method for rolling croissant dough pieces |
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2007
- 2007-02-21 US US11/677,469 patent/US7585531B2/en active Active
-
2008
- 2008-02-21 ES ES08723805.1T patent/ES2549867T3/en active Active
- 2008-02-21 PL PL08723805T patent/PL2140997T3/en unknown
- 2008-02-21 EP EP08723805.1A patent/EP2140997B1/en not_active Not-in-force
- 2008-02-21 AR ARP080100710A patent/AR065415A1/en unknown
- 2008-02-21 WO PCT/MX2008/000023 patent/WO2008103021A2/en active Application Filing
- 2008-02-21 CA CA2678223A patent/CA2678223C/en not_active Expired - Fee Related
- 2008-02-21 BR BRPI0808010-0A patent/BRPI0808010B1/en not_active IP Right Cessation
-
2009
- 2009-07-31 US US12/533,527 patent/US7950916B2/en active Active
- 2009-08-10 CR CR10972A patent/CR10972A/en unknown
- 2009-08-17 GT GT200900232A patent/GT200900232A/en unknown
- 2009-08-19 SV SV2009003360A patent/SV2009003360A/en not_active Application Discontinuation
- 2009-08-20 ZA ZA200905801A patent/ZA200905801B/en unknown
- 2009-08-20 NI NI200900160A patent/NI200900160A/en unknown
-
2010
- 2010-03-15 PA PA20108865201A patent/PA8865201A1/en unknown
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US4389176A (en) | 1981-03-20 | 1983-06-21 | Claudio Nenci | Machine for the production of tubular casings of alimentary dough |
US4666391A (en) | 1983-04-08 | 1987-05-19 | Quaker Products Australia Limited | Apparatus for rolling up a pastry layer and a separator sheet |
US4905583A (en) | 1986-06-18 | 1990-03-06 | Rheon Automatic Machinery Co., Ltd. | Apparatus and method for rolling croissant dough pieces |
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Also Published As
Publication number | Publication date |
---|---|
CA2678223A1 (en) | 2008-08-28 |
NI200900160A (en) | 2010-06-30 |
AR065415A1 (en) | 2009-06-03 |
BRPI0808010B1 (en) | 2019-11-05 |
EP2140997A4 (en) | 2011-03-30 |
EP2140997B1 (en) | 2015-08-05 |
ZA200905801B (en) | 2010-05-26 |
CR10972A (en) | 2011-02-04 |
US7585531B2 (en) | 2009-09-08 |
US7950916B2 (en) | 2011-05-31 |
CA2678223C (en) | 2012-05-01 |
PA8865201A1 (en) | 2010-04-21 |
US20080199569A1 (en) | 2008-08-21 |
GT200900232A (en) | 2011-09-23 |
US20090311391A1 (en) | 2009-12-17 |
EP2140997A2 (en) | 2010-01-06 |
BRPI0808010A2 (en) | 2014-06-17 |
ES2549867T3 (en) | 2015-11-02 |
WO2008103021A3 (en) | 2009-12-03 |
PL2140997T3 (en) | 2015-12-31 |
SV2009003360A (en) | 2010-02-17 |
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