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WO2008065629A1 - Emballage pour pain de savon à haute teneur en humidité - Google Patents

Emballage pour pain de savon à haute teneur en humidité Download PDF

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Publication number
WO2008065629A1
WO2008065629A1 PCT/IB2007/054854 IB2007054854W WO2008065629A1 WO 2008065629 A1 WO2008065629 A1 WO 2008065629A1 IB 2007054854 W IB2007054854 W IB 2007054854W WO 2008065629 A1 WO2008065629 A1 WO 2008065629A1
Authority
WO
WIPO (PCT)
Prior art keywords
bar soap
paperboard
fungicide
bar
package
Prior art date
Application number
PCT/IB2007/054854
Other languages
English (en)
Inventor
Grace Zhang
Ji-quan LIU
Charlie Reyes Salvador
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP07827084A priority Critical patent/EP2084083A1/fr
Priority to CN2007800444388A priority patent/CN101547844B/zh
Priority to CA2669936A priority patent/CA2669936C/fr
Priority to MX2009005785A priority patent/MX2009005785A/es
Publication of WO2008065629A1 publication Critical patent/WO2008065629A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/28—Applications of food preservatives, fungicides, pesticides or animal repellants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper

Definitions

  • the present invention relates to packaging for high moisture bar soap compositions for cleansing skin.
  • soaps remain a popular product form for cleansing skin.
  • Those skilled in the art use the term soap to designate the reaction product of a carboxylic acid with a base, typically a metal hydroxide or carbonate.
  • the resulting salt has both a polar hydrophilic end and a non-polar lipophilic end which facilitates the removal of oils and other non-polar materials from the skin or other surface in the presence of water.
  • Bar soaps are customarily prepared either by framing/casting or by milling/plodding.
  • the process of making bar soaps usually requires a drying step to remove the "gummy" texture and excessive pliability of the soap mass which exist typically at higher moisture levels.
  • Finished bar soaps typically will thus have a relatively low level of moisture (i.e. water), usually in the range of from about 10% to about 14% by weight of the bar soap.
  • a relatively low level of moisture i.e. water
  • developments have been made with respect to achieving bar soaps that contain higher moisture levels, e.g. at least about 15% water by weight of the bar soap.
  • Bar soaps having higher levels of moisture can be desirable with respect to formulation and process efficiency.
  • high moisture bar soaps tend to encounter of number of potential problems.
  • the present invention relates packaging for high moisture bar soap compositions to address a number of potential problems associated with high moisture bar soap compositions, such as minimizing moisture loss, inhibiting mold growth on paperboard material used in the packaging, and preventing the development of colored stains on the bar soap and packaging resulting from chemical reaction between the high moisture bar soap and the paperboard, especially recycled paperboard.
  • the bar soap product of the present invention comprises: (a) a bar soap package comprising a laminate material and (b) a bar soap composition comprising at least about 15%, by weight of the bar soap composition, of water.
  • the laminate material of the bar soap package comprises a paperboard material, a thermoplastic material disposed on at least one side of the paperboard material, and a fungicide.
  • the paperboard material can be made of cellulosic fibers, either virgin pulp or recycled pulp. Recycled paperboard material is preferred.
  • the thermoplastic material is preferably a biaxially oriented polypropylene material.
  • the fungicide is preferably selected from the group consisting of carbendazim, chlorothalonil, p-tolyl diiodomethyl sulfone, thiabendazole, and mixtures thereof.
  • the present invention further relates to a method of inhibiting the growth of mold which can result from storage of a high moisture bar soap composition in a paperboard package.
  • the method of inhibiting the growth of mold, especially the mold species aspergillus sydowii and/or penicillium chrysogenum, on a paperboard package containing a high moisture bar soap composition comprises treating the paperboard package with a fungicide comprising chlorothalonil and p-tolyl diiodomethyl sulfone, and then packaging the high moisture bar soap composition in the treated paperboard package.
  • high moisture bar soap refers to a bar soap composition comprising at least about 15%, preferably at least about 20%, by weight of the bar soap composition, of water.
  • the bar soap package of the present invention comprises a laminate material comprising a paperboard material, a thermoplastic material, and a fungicide.
  • the thermoplastic material is disposed, preferably laminated, on at least one side of the paperboard material.
  • the thermoplastic material can be applied, preferably laminated, to a side of the paperboard material via a variety of methods, such as adhesive bonding, thermal bonding, and the like.
  • the fungicide can be disposed on at least one side of the paperboard material and/or incorporated directly into the paperboard material during the process of manufacturing the paperboard material.
  • the paperboard material is folded into a carton or box configuration to contain the high moisture bar soap composition.
  • the paperboard material will have an inner side which faces the interior of the carton or box, and an outer side that faces the external environment surrounding the carton or box.
  • the thermoplastic material is laminated onto the inner side of the paperboard material via an adhesive. If the carton or box includes any graphics on the outside of the carton or box, then such graphics are printed on the outer side of the paperboard material. Then, the fungicide is applied to the outer side of the paperboard material, on top of the printed graphics.
  • Suitable paperboard material includes materials made of fibers, such as cellulosic fibers. Such materials are commonly known in the art and preferably have a weight of from about 200 grams per square meter (“gsm”) to about 500 gsm.
  • thermoplastic materials for use in the present invention include polypropylene (such as biaxially oriented polypropylene (“BOPP”)), polyethylene, polyethylene terephthalate (“PET”), polyester, polyvinyl chloride (“PVC”), and combinations thereof.
  • the thermoplastic materials used are preferably selected to retard the loss of moisture from the bar soap composition upon storage.
  • the thermoplastic material is also preferably impermeable to water or water vapor, thereby retarding the absorption of water by the paperboard.
  • the thermoplastic material is also preferably selected to prevent the development of colored stains on the bar soap and packaging resulting from chemical reaction between the high moisture bar soap and the paperboard, especially recycled paperboard.
  • the thermoplastic material will typically have a thickness of from about 5 ⁇ m to about 100 ⁇ m, preferably from about 10 ⁇ m to about 50 ⁇ m, and more preferably from about 12 ⁇ m to about 25 ⁇ m.
  • the thermoplastic material is biaxially oriented polypropylene ("BOPP") having a thickness of 18 ⁇ m.
  • Suitable fungicides for use in the present invention include chlorothalonil, p-tolyl diiodomethyl sulfone, carbendazim, thiabendazole, and mixtures thereof.
  • a preferred fungicide is carbendazim which is commercially available from Intace S.A. under the trade name INTACE B- 350.
  • Another preferred fungicide comprises a mixture of chlorothalonil and p-tolyl diiodomethyl sulfone, which is commercially available from Intace S.A. under the trade name INTACE B- 6773. It is understood that many other suitable fungicides are known in the art and that the preceding list of fungicides are merely non-limiting examples.
  • Fungicides are typically incorporated onto a side of the paperboard material, or directly into the paperboard material, at a level of from about 500 ppm to about 10,000 ppm, preferably from about 1000 ppm to about 5000 ppm, and more preferably from about 1500 ppm to about 3000 ppm.
  • the bar soap composition of the present invention comprises water, soap and other optional ingredients.
  • the bar soap composition of the present invention comprises at least about 15%, more preferably at least about 20%, and more preferably at least about 25%, by weight of the composition, of water.
  • the level of water can be still higher, e.g. 30%, 35%, or even 40%, but is typically not greater than about 60%, preferably not greater than about 55%, and more preferably not greater than about 50%, by weight of the bar composition.
  • the bar compositions of the present invention will typically comprise from about 40% to about 84%, preferably from about 45% to about 75%, and more preferably from about 50% to about 65%, by weight of the composition, of soap.
  • soap is used herein in its popular sense, i.e., the alkali metal or alkanol ammonium salts of alkane- or alkene monocarboxylic acids.
  • Sodium, magnesium, potassium, calcium, mono-, di- and tri-ethanol ammonium cations, or combinations thereof, are suitable for purposes of the present invention.
  • sodium soaps are used in the compositions of this invention, but from about 1% to about 25% of the soap may be ammonium, potassium, magnesium, calcium or a mixture of these soaps.
  • the soaps useful herein are the well known alkali metal salts of alkanoic or alkenoic acids having about 12 to 22 carbon atoms, preferably about 12 to about 18 carbon atoms. They may also be described as alkali metal carboxylates of alkyl or alkene hydrocarbons having about 12 to about 22 carbon atoms.
  • Soaps having the fatty acid distribution of coconut oil may provide the lower end of the broad molecular weight range.
  • Those soaps having the fatty acid distribution of peanut or rapeseed oil, or their hydrogenated derivatives may provide the upper end of the broad molecular weight range.
  • soaps having the fatty acid distribution of tallow and vegetable oil. More preferably the vegetable oil is selected from the group consisting of palm oil, coconut oil, palm kernel oil, palm oil stearine, and hydrogenated rice bran oil, or mixtures thereof, since these are among the more readily available fats. Especially preferred are palm oil stearine, palm kernel oil, and/or coconut oil.
  • the proportion of fatty acids having at least 12 carbon atoms in coconut oil soap is about 85%. This proportion will be greater when mixtures of coconut oil and fats such as tallow, palm oil, or non-tropical nut oils or fats are used, wherein the principle chain lengths are C 16 and higher.
  • a preferred soap is sodium soap having a mixture of from about 50% to about 80%, more preferably from about 35% to about 40%, tallow; from 0% to about 60%, more preferably from
  • palm stearine 0% to about 50%, palm stearine; from 0% to about 40%, more preferably from 0% to about 35%, palm oil; and from about 10% to about 35%, more preferably from about 15% to about 30%, palm kernel oil or coconut oil.
  • the soaps may contain unsaturation in accordance with commercially acceptable standards. Excessive unsaturation is normally avoided.
  • Soaps may be made by the classic kettle boiling process or modern continuous soap manufacturing processes wherein natural fats and oils such as tallow or coconut oil or their equivalents are saponified with an alkali metal hydroxide using procedures well known to those skilled in the art.
  • the soaps may be made by neutralizing fatty acids, such as lauric (C 12), myristic (C 14), palmitic (C 16), or stearic (C 18) acids with an alkali metal hydroxide or carbonate.
  • the bar composition will comprise soap made by a continuous soap manufacturing process.
  • the soap which comprises approximately 30% water, is then processed into soap noodles via a vacuum flash drying process.
  • the soap noodles preferably comprise about about 85% anhydrous soap (50% tallow/30% palm oil stearine/20% palm kernel oil (or 20% coconut oil)), about 0.2% free citric acid, about 0.2% sodium citrate, about 0.05% tetrasodium
  • Inorganic salts can be optionally utilized in the present bar compositions to help in maintaining the relatively high water content of the present compositions.
  • the inorganic salts help to bind the water in the bar composition thereby preventing water loss by evaporation or other means.
  • the present bar compositions comprise from about 1% to about 15%, preferably from about 2% to about 12%, and more preferably from about 2.5% to about 10.5%, by weight of the composition, of inorganic salt.
  • Suitable inorganic salts include magnesium nitrate, trimagnesium phosphate, calcium chloride, sodium carbonate, sodium aluminum sulfate, disodium phosphate, sodium polymetaphosphate, sodium magnesium succinate, sodium tripolyphosphate, aluminum sulfate, aluminum chloride, aluminum chlorohydrate, aluminum- zirconium trichlorohydrate, aluminum-zirconium trichlorohydrate glycine complex, zinc sulfate, ammonium chloride, ammonium phosphate, calcium acetate, calcium nitrate, calcium phosphate, calcium sulfate, ferric sulfate, magnesium chloride, magnesium sulfate, and the like.
  • Preferred inorganic salts include sodium tripolyphosphate, magnesium salts (such as magnesium sulfate), and/or tetrasodium pyrophosphate.
  • Magnesium salts when used as an ingredient in the present bar compositions comprising soap, tend to be converted to magnesium soap in the finished product.
  • Sodium tripolyphosphate, magnesium salts (and as a result magnesium soap), and/or tetrasodium pyrophosphate are preferred in the present compositions
  • Sodium tripolyphosphate is also preferred as it can tend to promote the generation of lather as the bar composition is used by a consumer for cleansing skin.
  • Carbohyrate structurants can optionally, but preferably, be included as ingredients in the present bar compositions.
  • Carbohydrate structurants tend to assist in maintaining the relatively high level of water in the present compositions.
  • Suitable carbohydrate structurants as ingredients in the present compositions include raw starch (corn, rice, potato, wheat, and the like), pregelatinzed starch, carboxymethyl cellulose, stabylene, carbopol, carregeenan, xanthan gum, polyethylene glycol, polyethylene oxide, and the like.
  • Preferred carbohydrate structurants include raw starch and/or pregelatinized starch.
  • a preferred carbohydrate structurant for incorporating in a bar composition is starch.
  • the starch can be either raw starch or it can be pregelatinized starch. Alternatively, raw starch can be used and modified during the process of making the bar composition such that the starch becomes gelatinized, either partially or fully gelatinized.
  • Pregelatinized starch is starch that has been gelatinized before added as an ingredient in the present bar compositions. Gelatinized starch, either partially or fully gelatinized starch, can be preferred for providing enhanced skin feel benefits, such as providing a soft and smooth skin feel.
  • a preferred pregelatinized starch for use as an ingredient in the present compositions is PREGEL-A M 0300 commercially available from Tianjin Tingfung Starch Development Co., Ltd. of Tianjin, China.
  • the level of carbohydrate structurant in the present compositions is typically from about 1% to about 20%, preferably from about 2% to about 17%, and more preferably from about 4% to about 15%, by weight of the composition.
  • the bar soap compositions of the present invention can further comprise additional optional ingredients such as humectants (e.g. glycerin or sorbitol), free fatty acids, synthetic surfactants, cationic polymers, brighteners, silica, and the like.
  • humectants e.g. glycerin or sorbitol
  • free fatty acids e.g. glycerin or sorbitol
  • synthetic surfactants e.g. glycerin or sorbitol
  • cationic polymers e.glycerin or sorbitol
  • compositions include: perfumes; sequestering agents, such as tetrasodium ethylenediaminetetraacetate (EDTA), EHDP or mixtures thereof typically in an amount of 0.01 to 1%, preferably 0.01 to 0.05%, by weight of the composition; and coloring agents, opacifiers and pearlizers such as titanium dioxide; all of which are useful in enhancing the appearance or cosmetic properties of the product.
  • sequestering agents such as tetrasodium ethylenediaminetetraacetate (EDTA), EHDP or mixtures thereof typically in an amount of 0.01 to 1%, preferably 0.01 to 0.05%, by weight of the composition
  • coloring agents, opacifiers and pearlizers such as titanium dioxide
  • the pH of a 1% solution of the bar composition of the present invention dissolved in water is typically from about 7 to about 12, preferably from about 8 to about 11, and more preferably from about 9 to about 10.
  • the appearance of the bar composition according to the present invention can be transparent, translucent, or opaque. In one embodiment, the bar composition is opaque.
  • Suitable high moisture bar soap compositions that can benefit from being packaged in the bar soap package of the present invention include those bar soap compositions described in detail in co-pending U.S. Application Serial No. 11/453,767, filed June 15, 2006, and U.S. Provisional Application Serial No. 60/811,545, filed June 6, 2006.
  • the cleansing bar compositions of the present invention can be used by consumers to cleanse skin during bathing or washing.
  • the present invention further relates to a method of inhibiting the growth of mold, especially certain species of mold such as aspergillus sydowii and/or penicillium chrysogenum, that can grow on a paperboard package containing a high moisture bar soap composition. It has been found that the mold species aspergillus sydowii and/or penicillium chrysogenum can be especially problematic with respect to growing on paperboard packages containing high moisture bar soaps. Such mold species are typically resistant to commonly-used fungicides on paperboard packaging materials, such as carbendazim.
  • a fungicide that comprises a mixture of chlorothalonil and p-tolyl diiodomethyl sulfone can effectively inhibit the growth of mold on the paperboard packaging, especially certain species of mold such as aspergillus sydowii and/or penicillium chrysogenum.
  • a fungicide material is commercially available from Intace S.A. under the tradename INTACE B-6773.
  • the method comprises treating a paperboard package with a fungicide comprising chlorothalonil and p-tolyl diiodomethyl sulfone and using the package to contain a bar soap composition comprising at least about 15%, by weight of the bar soap composition, of water.
  • Amounts of each ingredient are approximate weight percentages by weight of the bar composition.
  • the Soap Noodle utilized in these examples has the following approximate composition: about 85% Anhydrous Soap (50% Tallow/30% Palm Oil Stearine/20% Palm Kernel Oil (or 20% Coconut Oil)), about 0.2% Free Citric Acid, about 0.2% Sodium Citrate, about 0.05% Tetrasodium DPTA, about 0.05% Tetrasodium HEDP, about 0.6% Sodium Chloride, about 1% Glycerin, and from about 12% to about 18% Water, the balance being unsaponifiables. These percentage amounts are by weight of the Soap Noodle.
  • Pregelatinized starch is available as PREGEL-A M 0300 from Tianjin Tingfung Starch Development Co., Ltd. of Tianjin, China.
  • the Soap Noodles are made via a conventional process involving a crutching step and a vacuum drying step.
  • the Soap Noodles are then added to an amalgamator.
  • the ingredients of perfume, brightener, and titanium dioxide are then added to the amalgamator and mixed for about 10 to 15 seconds.
  • the ingredients such as water, inorganic salts (such as sodium tripolyphosphate, tetrasodium pyrophosphate, and/or magnesium sulfate), free fatty acid (such as palm kernel fatty acid), carbohydrate structurant (such as raw starch or pregelatinized starch), dye solution, and trichlorocarban are then added to the amalgamator and then mixed for about 30 to 45 seconds.

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pest Control & Pesticides (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Detergent Compositions (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)

Abstract

L'invention porte sur un emballage pour compositions de savon en pain à haute teneur en humidité qui permet de résoudre un nombre de problèmes potentiels associés aux compositions de savon en pain à haute teneur en humidité, par exemple en réduisant la perte d'humidité, en inhibant la croissance de moisissures sur le carton utilisé dans l'emballage et en empêchant le développement, sur le pain de savon et sur l'emballage, de taches colorées dues à la réaction chimique entre le savon en pain à haute teneur en humidité et le carton, en particulier le carton recyclé. L'emballage pour pain de savon de l'invention est réalisé dans un matériau stratifié comprenant un carton, un matériau thermoplastique disposé sur au moins un côté du carton, et un fongicide. L'invention se rapporte également à un procédé qui permet d'inhiber la croissance de moisissures sur un emballage en carton, croissance qui peut survenir lorsqu'une composition de savon en pain à haute teneur en humidité est stockée dans l'emballage en carton, en traitant l'emballage en carton avec un fongicide comprenant du chlorothalonil et du p-tolyl diiodométhyle sulfone, et en emballant ensuite la composition de savon en pain à haute teneur en humidité dans l'emballage en carton traité.
PCT/IB2007/054854 2006-12-01 2007-11-29 Emballage pour pain de savon à haute teneur en humidité WO2008065629A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP07827084A EP2084083A1 (fr) 2006-12-01 2007-11-29 Emballage pour pain de savon à haute teneur en humidité
CN2007800444388A CN101547844B (zh) 2006-12-01 2007-11-29 用于高水分条皂的包装
CA2669936A CA2669936C (fr) 2006-12-01 2007-11-29 Emballage pour pain de savon a haute teneur en humidite
MX2009005785A MX2009005785A (es) 2006-12-01 2007-11-29 Empaque para jabon en barra de alta humedad.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87237706P 2006-12-01 2006-12-01
US60/872,377 2006-12-01

Publications (1)

Publication Number Publication Date
WO2008065629A1 true WO2008065629A1 (fr) 2008-06-05

Family

ID=39184955

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2007/054854 WO2008065629A1 (fr) 2006-12-01 2007-11-29 Emballage pour pain de savon à haute teneur en humidité

Country Status (5)

Country Link
EP (1) EP2084083A1 (fr)
CN (1) CN101547844B (fr)
CA (1) CA2669936C (fr)
MX (1) MX2009005785A (fr)
WO (1) WO2008065629A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2202358A1 (fr) * 2008-12-29 2010-06-30 Kompetenzzentrum Holz GmbH Papier imprégné avec des propriétés antimicrobiennes
WO2011037819A1 (fr) * 2009-09-22 2011-03-31 Sonoco Development, Inc. Carton contenant un biocide et son procédé de production

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Publication number Priority date Publication date Assignee Title
EP2202358A1 (fr) * 2008-12-29 2010-06-30 Kompetenzzentrum Holz GmbH Papier imprégné avec des propriétés antimicrobiennes
WO2011037819A1 (fr) * 2009-09-22 2011-03-31 Sonoco Development, Inc. Carton contenant un biocide et son procédé de production
US8419899B2 (en) 2009-09-22 2013-04-16 Sonoco Development Inc. Paperboard containing recycled fibers and method of making the same
US8709206B2 (en) 2009-09-22 2014-04-29 Sonoco Development Inc. Paperboard containing recycled fibers and method of making the same

Also Published As

Publication number Publication date
CN101547844B (zh) 2012-04-25
CA2669936C (fr) 2012-07-10
CN101547844A (zh) 2009-09-30
CA2669936A1 (fr) 2008-06-05
EP2084083A1 (fr) 2009-08-05
MX2009005785A (es) 2009-06-10

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