WO2006132426A3 - Surface treatment liquid and method of forming conversion layer - Google Patents
Surface treatment liquid and method of forming conversion layer Download PDFInfo
- Publication number
- WO2006132426A3 WO2006132426A3 PCT/JP2006/311888 JP2006311888W WO2006132426A3 WO 2006132426 A3 WO2006132426 A3 WO 2006132426A3 JP 2006311888 W JP2006311888 W JP 2006311888W WO 2006132426 A3 WO2006132426 A3 WO 2006132426A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- conversion layer
- surface treatment
- treatment liquid
- coloring material
- forming
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 4
- 238000004381 surface treatment Methods 0.000 title abstract 3
- 239000007788 liquid Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 238000004040 coloring Methods 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910001297 Zn alloy Inorganic materials 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
An object of the present invention is to enhance the stability of a hexavalent chromium-free surface treatment liquid for forming a black conversion layer. According to the present invention, there is provided a hexavalent chromium-free surface treatment solution for forming a black conversion layer on zinc or zinc alloy, containing trivalent chromium, an organic acid, an inorganic acid, and a coloring material which makes the conversion layer black, wherein the coloring material contains metal whose concentration in the solution falls within a range of 0.01 g/L to 3 g/L, wherein a molar ratio of the sum of the metal in the coloring material and trivalent chromium with respect to carboxy group falls within a range of 0.1 to 0.3, and wherein a pH value of the solution is equal to or larger than 3 and smaller than 6.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005167327A JP4429214B2 (en) | 2005-06-07 | 2005-06-07 | Surface treatment liquid and method for forming chemical conversion film |
JP2005-167327 | 2005-06-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006132426A2 WO2006132426A2 (en) | 2006-12-14 |
WO2006132426A3 true WO2006132426A3 (en) | 2007-02-15 |
Family
ID=37057218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2006/311888 WO2006132426A2 (en) | 2005-06-07 | 2006-06-07 | Surface treatment liquid and method of forming conversion layer |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP4429214B2 (en) |
WO (1) | WO2006132426A2 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE431442T1 (en) * | 2006-01-31 | 2009-05-15 | Atotech Deutschland Gmbh | AQUEOUS REACTION SOLUTION AND METHOD FOR PASSIVATION OF ZINC AND ZINC ALLOYS |
ES2361361T3 (en) | 2007-03-05 | 2011-06-16 | Atotech Deutschland Gmbh | PASSIVATION IN BLACK EXEMPT FROM CHROME (VI) FOR SURFACES CONTAINING ZINC. |
JP5110505B2 (en) * | 2007-04-04 | 2012-12-26 | 奥野製薬工業株式会社 | Composition for overcoat for chemical conversion film formed on zinc or zinc alloy |
JP5110504B2 (en) * | 2007-04-04 | 2012-12-26 | 奥野製薬工業株式会社 | Composition for forming black chemical conversion film |
CN102758197A (en) * | 2007-08-03 | 2012-10-31 | 迪普索尔化学株式会社 | Corrosion-resistant trivalent-chromium chemical conversion coating and solution for trivalent-chromium chemical treatment |
ATE544881T1 (en) * | 2008-06-17 | 2012-02-15 | Pangang Group Res Inst Co Ltd | SILICIC ACID SOLE COMPOSITION, METHOD FOR PRODUCING THEREOF AND GALVANIZED SELF-LUBRICATING METAL MATERIAL USING THE COMPOSITION |
CN102011118B (en) * | 2010-12-24 | 2012-09-26 | 杭州东方表面技术有限公司 | Trivalent chromium passivating agent for zinc and zinc alloy coatings |
JP6101921B2 (en) * | 2011-12-22 | 2017-03-29 | 日本表面化学株式会社 | Pretreatment liquid for coating and coating method |
US10400338B2 (en) | 2017-05-12 | 2019-09-03 | Chemeon Surface Technology, Llc | pH stable trivalent chromium coating solutions |
ES2848870T3 (en) | 2018-10-19 | 2021-08-12 | Atotech Deutschland Gmbh | A method of electrolytically passivating a surface of silver, a silver alloy, gold, or a gold alloy |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040156999A1 (en) * | 2003-02-07 | 2004-08-12 | Pavco, Inc. | Black trivalent chromium chromate conversion coating |
EP1484432A1 (en) * | 2002-03-14 | 2004-12-08 | Dipsol Chemicals Co., Ltd. | Treating solution for forming black hexavalent chromium-free chemical coating on zinc or zinc alloy plated substrate, and method for forming black hexavalent chromium-free chemical coating on zinc or zinc alloy plated substrate |
JP2004346360A (en) * | 2003-05-21 | 2004-12-09 | Okuno Chem Ind Co Ltd | Composition for depositing black chemical conversion coating |
-
2005
- 2005-06-07 JP JP2005167327A patent/JP4429214B2/en not_active Expired - Fee Related
-
2006
- 2006-06-07 WO PCT/JP2006/311888 patent/WO2006132426A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1484432A1 (en) * | 2002-03-14 | 2004-12-08 | Dipsol Chemicals Co., Ltd. | Treating solution for forming black hexavalent chromium-free chemical coating on zinc or zinc alloy plated substrate, and method for forming black hexavalent chromium-free chemical coating on zinc or zinc alloy plated substrate |
US20040156999A1 (en) * | 2003-02-07 | 2004-08-12 | Pavco, Inc. | Black trivalent chromium chromate conversion coating |
JP2004346360A (en) * | 2003-05-21 | 2004-12-09 | Okuno Chem Ind Co Ltd | Composition for depositing black chemical conversion coating |
Also Published As
Publication number | Publication date |
---|---|
WO2006132426A2 (en) | 2006-12-14 |
JP4429214B2 (en) | 2010-03-10 |
JP2006342376A (en) | 2006-12-21 |
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