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WO2006120851A1 - Agent destine a communiquer des fonctions a des produits textiles - Google Patents

Agent destine a communiquer des fonctions a des produits textiles Download PDF

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Publication number
WO2006120851A1
WO2006120851A1 PCT/JP2006/308214 JP2006308214W WO2006120851A1 WO 2006120851 A1 WO2006120851 A1 WO 2006120851A1 JP 2006308214 W JP2006308214 W JP 2006308214W WO 2006120851 A1 WO2006120851 A1 WO 2006120851A1
Authority
WO
WIPO (PCT)
Prior art keywords
derivative
hydroxyproline
products
proline
hydroxy
Prior art date
Application number
PCT/JP2006/308214
Other languages
English (en)
Japanese (ja)
Inventor
Kouichi Saito
Yasuhiro Ikari
Original Assignee
Kyowa Hakko Kogyo Co., Ltd.
Ohara Paragium Chemical Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyowa Hakko Kogyo Co., Ltd., Ohara Paragium Chemical Co., Ltd. filed Critical Kyowa Hakko Kogyo Co., Ltd.
Priority to JP2007528169A priority Critical patent/JPWO2006120851A1/ja
Publication of WO2006120851A1 publication Critical patent/WO2006120851A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/33—Heterocyclic compounds
    • A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/40—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having five-membered rings with one nitrogen as the only ring hetero atom, e.g. sulpiride, succinimide, tolmetin, buflomedil
    • A61K31/401—Proline; Derivatives thereof, e.g. captopril
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P17/00—Drugs for dermatological disorders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/002—Tissue paper; Absorbent paper

Definitions

  • the present invention relates to a functional imparting agent for a fiber product, a functional fiber product, and a method for producing the functional fiber product, which contains hydroxyproline or an N-acylated derivative of hydroxyproline or a salt thereof.
  • Hydroxyproline an N-acylated derivative of hydroxyproline, or a salt thereof is known as an amino acid exhibiting a moisturizing effect, and has skin-beautifying effects such as skin aging suppression and skin quality improvement as a cosmetic (for example, patent document 1), prevention of pressure ulcer, and therapeutic effects (for example, patent document 2), prevention and improvement of atopic dermatitis (for example, patent document 3), anti-inflammatory, wound healing effect (For example, Non-Patent Document 1) is known.
  • Patent Document 4 discloses an agent for imparting functionality to a fiber product containing amino acids
  • Patent Document 5 discloses a fiber web.
  • amino acids hydroxyproline or hydroxy is disclosed.
  • Patent Document 1 International Publication No. OOZ51561 Pamphlet
  • Patent Document 2 Pamphlet of International Publication No. 2004Z28531
  • Patent Document 3 International Publication No. 02Z6225 Pamphlet
  • Patent Document 4 Japanese Patent Application Laid-Open No. 2004-324026
  • Patent Document 5 International Publication No. 96Z31644 Pamphlet
  • Non-Patent Document 1 Eurobian Medical Research 3rd, 182-188, 1998 Invention Disclosure
  • the present invention relates to an excellent function of hydroxyproline or an N-acylated derivative of hydroxyproline or a salt thereof for a fiber base material widely used for clothes, bedding, paper omgu, etc. An attempt was made to impart the excellent properties of the wood while keeping it intact, providing superior functional fiber products without drastically changing the conventional fiber manufacturing process and properties. The task is to do.
  • the gist of the present invention is as follows.
  • N-acylated derivative of hydroxyproline is an N-acetylated derivative, an N-propionylated derivative, an N-propylylated derivative or an N-isoptyrylated derivative. Sex imparting agent.
  • N-acylated derivative power of hydroxyproline N-acetylated derivative, N-propionylated derivative, N-propylylated derivative or N-isoptyrylated derivative according to item 6 above ⁇ Bedding materials and products, interior materials and products, automotive interior materials and products, and nursing materials and products.
  • N-acylated derivative of hydroxyproline is an N-acetylated derivative, an N-propionylated derivative, an N-propylylated derivative or an N-isoptyrylated derivative.
  • the fiber product has functions such as moisture retention, skin aging prevention, skin quality improvement and other skin beautifying effects, pressure ulcer prevention, anti-atopic, anti-inflammatory and wound healing effects. It can be granted.
  • the hydroxyproline used in the present invention may be any stereoisomer of hydroxyproline.
  • proline of hydroxyproline has 8 physical isomers depending on whether it is D-strength L-strength or hydroxyl-position 3 or 4-position, and its stereoisomer is cis-force trans. And deviations of mixtures thereof can also be used in the present invention.
  • hydroxyproline examples include cis-4-hydroxy-1-L-proline, cis-1-hydroxy-D-proline, cis-3-hydroxy-L-proline, cis-3-hydroxy-D-proline, trans-4-hydroxy-L-- Examples include proline, trans-4-hydroxy-D-proline, trans-1-hydroxy-L-proline, and trans-3-hydroxy-D phosphorus.
  • Hydroxyproline is a kind of amino acid that exists widely in nature as a major constituent amino acid component in collagen and as a constituent amino acid of elastin.
  • hydroxyproline acid-hydrolyzes collagen derived from animals such as butterfly. It can be produced by purification by a conventional method.
  • Trans-4-hydroxy L-proline is a proline 4-hydroxylase isolated from microorganisms of the genus Amvcolatopsis or Dactvlosporangium (JP-A-7-313179). Can be used.
  • cis-3 hydroxyl L proline can be produced using porphyrin 3-position hydroxylase (Japanese Patent Laid-Open No. 7-322885) isolated from Streptomyces genus cattle. Yes, Bioindustry 1, 14 ⁇ , 31 (1997).
  • Hydroxyproline produced using the above-mentioned microorganism-derived enzyme has excellent quality. It is more preferable as hydroxyproline used in the present invention.
  • Examples of the N-acyl yl derivatives of hydroxyproline used in the present invention include the above-mentioned N-acyl yl derivatives of the various hydroxyproline stereoisomers.
  • Examples of the acyl group of the N-acyl derivative include preferably an acyl group having 1 to 24 carbon atoms, more preferably 1 to 12 carbon atoms, and particularly preferably 1 to 6 carbon atoms.
  • Honoleminole acetinole, propionyl, butyrinole, isobutyryl, norellinore, pivalol, hexanol, heptanol, otatanyl, nonanoyl, decanol, undecanol, dodecanol, etc.
  • Examples of the salt of hydroxyproline or N-acylated derivative of hydroxyproline include alkali metal salts such as sodium, potassium and lithium, alkaline earth metal salts such as calcium and magnesium, ammonium salts, Examples thereof include addition salts of amines such as monoethanolamine, diethanolamine, triethanolamine and triisopropanolamine, and addition salts of basic amino acids such as arginine and lysine.
  • N-acyl derivative of hydroxyproline can be prepared by a known method.
  • N-acyl derivatives of hydroxyproline are linear or branched saturated fatty acids having 1 to 24 carbon atoms, such as chlorides and bromides using halogenating agents such as salt and phosgene.
  • the product can be produced by conversion to a halogenated product such as the above, followed by condensation with hydroxyproline as described above, or conversion of a fatty acid to an acid anhydride followed by reaction with hydroxyproline.
  • fatty acids include formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, pivalic acid, hexanoic acid, heptanoic acid, octanoic acid, nonanoic acid, decanoic acid, and undehydroacid.
  • a fatty acid such as dodecanoic acid is used alone or in combination.
  • the fatty acid is dispersed in a solvent such as methylene chloride, chloroform, carbon tetrachloride, benzene, toluene, xylene, n-hexane, etc., and 1 to 5 times equivalent of a halogenating agent is added thereto to react.
  • a solvent such as methylene chloride, chloroform, carbon tetrachloride, benzene, toluene, xylene, n-hexane, etc.
  • Examples of the solvent used in the acyl chloride reaction include water, methanol, ethanol, isopropanol, isobutanol, acetone, toluene, tetrahydrofuran, ethyl acetate, N, N dimethylformamide, dimethyl sulfoxide, and the like. May be used alone or in combination.
  • hydroxyproline is dissolved or dispersed in a solvent, 0.8 to 2.0 times equivalent of alkaline substance such as sodium hydroxide and potassium hydroxide is dissolved in the solvent as necessary. Alternatively, it may be dispersed.
  • N-acylated derivative of hydroxyproline When it is desired to obtain a salt of an N-acylated derivative of hydroxyproline, if the N-acylated derivative of hydroxyproline is obtained in the form of a salt, it can be purified as it is and obtained in a free form. May be dissolved or suspended in a suitable solvent and a base may be added to form a salt.
  • N-acylated derivatives of hydroxyproline include, for example, N-acetyl-cis-4-hydroxy-1-L-proline, N-acetylenolysis-1-4-hydroxy-1-D-proline, N- 1-hydroxyl L-proline, N-acetylenic 1-hydroxy D-proline, N-acetylenic trans 4-4-hydroxy L-proline, N-acetylin trans 4-hydroxy D-proline, N-acetylinole trans 3-hydroxyl-proline, N-acetylinole -Trans 3-hydroxy D proline, N-propionyl-cis 4-hydroxy-L-proline, N-propionyl-cis-4-hydroxy-D-proline, N-propionyl-cis 3-hydroxy L proline, N propionyl cis 3 —Hydroxy D—proline, N propionyl trans 4-hydroxy L— Proline, N-propioninoletrans 4-hydroxy D pulin, N-propion
  • the function-imparting agent of the present invention preferably contains 0.01 to 30% by weight of hydroxyproline, a hydroxyproline N-acylated derivative or a salt thereof.
  • the functionality-imparting agent of the present invention includes, for example, a stabilizer such as hydroxyproline or a N-calyzed derivative of hydroxyproline or a salt thereof of 0.01 to 30 parts by weight, necessary sorbitol or sorbitol. 0.1 to 10 parts by weight, for example, antiseptic of isothiazoline-based antibacterial agents such as 5-clonal 2-methyl-4-isothiazolin-1-one and 2-methyl-4-isothiazolin-1-one compound (trade name: caisson) Preparation is made with 0.05 to 0. 3 parts by weight of the agent, 0.5 to 25 parts by weight of the binder, and 100 parts by weight of water.
  • a stabilizer such as hydroxyproline or a N-calyzed derivative of hydroxyproline or a salt thereof of 0.01 to 30 parts by weight, necessary sorbitol or sorbitol.
  • 0.1 to 10 parts by weight for example, antiseptic of isothiazoline-based antibacterial agents such as
  • the functionality-imparting agent of the present invention further includes peptides, hydroxyproline or amino acid derivatives other than salts of hydroxyproline or its salts, vitamins, ceramides, glycyrrhizic acids of licorice extract, and raspberries. Extract, lavender extract, jasmine extract, peno mint extract, rosemary extract, roman force fir mono extract, eucalyptus extract, hinokitiol, bamboo extract, aloe extract, catechin, grape funoles extract, lemon extract, jojoba oil, olive oil Citrus oil, seaweed extract, squalene, collagen, and at least one selected from the group power that also has glucose strength may be combined.
  • Examples of the peptide include silk protein, hive mouth-in, and the like, and examples of the amino acids include glutamic acid, aspartic acid, glycine, cystine, serine, histidine, lysine, arginine, leucine and the like. It is not limited to. As the vitamins, vitamin A, vitamin C, vitamin E, etc. can be used effectively. Examples of the glycyrrhizic acid of Kiss include glycyrrhizic acid, glycyrrhetinic acid, sodium glycyrrhizinate, potassium glycyrrhizinate, and ammonium glycyrrhizinate.
  • examples of the raspberries include raspberries and raspberry ketones
  • examples of the squalans include squalans and squalene
  • examples of the glucose include glucose, xylitol, and erythritol.
  • antibacterial agents such as chitin and chitosan may be combined.
  • the combination strength S with silk protein, hive mouth-in, screen lantern, and the like, clothing, etc. is particularly preferable because a very characteristic soft and volumey texture can be obtained.
  • components such as hydroxyproline or a hydroxyproline N-acyl yl derivative or a salt thereof may be used in a normal state. It may be used as a clathrate or vesicle structure with dextrin.
  • the vesicle structure utilizes a surfactant that forms a polymer at a specific concentration.
  • the surfactant molecule aggregate that is, the vesicle bag-like bilayer membrane, has an aqueous phase inside. And has an oil phase. In the oil phase, an oily compound or the like is dissolved in a solvent such as benzyl benzoate and held in the oil phase portion of the vesicle structure.
  • the functionality-imparting agent of the present invention contains a binder, it can be fixed to a fiber product as it is, and when it does not contain a binder, it can be fixed using a separate binder.
  • the binder include acrylic ester-based, for example, Pararesin GH-S manufactured by Ohara Paradum Chemical Co., Ltd., urethane-based binders, for example, Parasol PN-20 manufactured by Ohara Paradum Chemical Co., Ltd., silicone binders such as Toray Silicone Co., Ltd. It is preferable to use Toray Silicone BY22-826 made by the company and other polymers such as fluorine and epoxy.
  • the amount of the binder used is preferably 0.5 to 25 parts by weight relative to 0.01 to 30 parts by weight of hydroxyproline or an N-acylated derivative of hydroxyproline or a salt thereof.
  • such a functionality-imparting agent is fixed to a fiber product, and the fiber product is retained.
  • Functionality such as moisture, skin aging control and skin improvement, anti-atopy, anti-inflammatory, wound healing effect, pressure ulcer prevention, etc. can be added.
  • Use a treatment solution containing a binder attach it to textiles using a known method such as dubbing, padding, coating, spraying, etc., and fix it dry!
  • the fiber product to be treated is not particularly limited in terms of the type of fiber, such as yarn, woven fabric, knitted fabric, non-woven fabric, and fiber web, which may be misaligned.
  • the adhesion amount of the function-imparting agent to the fiber product is not particularly limited, but is usually about 0.05 to 5% by weight, preferably 1 to 3% by weight in terms of solid content.
  • the building materials of the present invention 'bedding materials and products, interior materials and products, automotive interior materials and products, care materials and products are hydroxyproline, N-acylated derivatives of hydroxyproline or salts thereof Indicates fabric, blanket, sheets, chair fabric, carpet, car seat fabric, seat cover, etc., which are bonded to fibers such as cotton ⁇ %, cotton Z polyester blend, hemp Z polyester blend, etc. Any of the hydroxyproline, the N-acylated derivative of hydroxyproline or a salt thereof may be used in the article. It is preferable to use hydroxyproline, acetyl hydroxyproline and the like.
  • the garment of the present invention is hydroxyproline or a hydroxyproline N-acylation derivative or a salt thereof made of 100% cotton, 100% polyester, cotton Z polyester blend, 100% nylon, cotton Z nylon blend.
  • the cloth ommu, paper ommu, wet tissue, and tissue paper of the present invention use hydroxyproline or an N-acylated derivative of hydroxyproline or a salt thereof, and cotton woven paper and paper ommu are usually used for the cloth ommu.
  • the water-absorbent fats and oils (see Japanese Patent Application Laid-Open No. 9-157543) and the wet tissue are those produced by bonding to paper. It may also be used in combination with antibacterial agents and deodorizers that are highly safe and natural products, antibacterial agents such as silver colloids, and deodorants.
  • Cloth, paper, wet tissue, tissue paper Any hydroxyproline or hydroxyproline N-acylated derivative or salt thereof may be used for par, but hydroxyproline, acetyl hydroxyproline, etc. are preferably used.
  • silicone resin as binder Toray Silicone Co., Ltd. manufactured by Toray Silicone BY22-826; the same shall apply hereinafter
  • a cotton plain fabric with a basis weight of 300 gZm 2 was dipped in a solution obtained by diluting the above-mentioned functionality-imparting agent with water so as to be lOOgZL, and then squeezed with a mandala so as to obtain a pickup rate of 100%. And pre-dried. Next, it was heat treated at 170 ° C. for 3 minutes to obtain a nursing sheet. This product has a pressure ulcer prevention effect and is very useful as a nursing sheet.
  • a cotton denim woven fabric with a basis weight of 300 gZm 2 was immersed in a solution obtained by diluting the above-described function-imparting agent with water so as to be lOOgZL, and then squeezed with a mandala to obtain a pickup rate of 100%. Pre-dried with C. Next, it was heat treated at 170 ° C. for 3 minutes and sewed onto jeans. This product has a moisturizing and skin-beautifying effect and is very useful as a functional clothing.
  • Example 3 N-acetyl-trans-1, 4-hydroxy-1, L-proline, 10 parts of squalane silica microcapsule, 15 parts of ethanol, 10 parts of ethylene oxide of lauryl alcohol, 10 parts of an adduct, 20 parts of silicone resin as a binder, The remainder was made up to 100 parts with water to make a functionality imparting agent for fiber webs.
  • Example 3 Instead of N-acetylenotrans 4-hydroxy-L proline in Example 3, the amount of water used was increased to make a total of 100 parts.
  • Example 3 The wet tissue obtained in Example 3 and Comparative Example 1 was applied to the elbow part, covered with a nylon film, and stopped with an adhesive tape for upper skin, allowed to stand for 4 hours, and then the skin was removed with a microscope.
  • the product of Example 3 showed a skin beautifying effect such as improvement in skin quality
  • the product of Comparative Example 1 was powerful without showing a skin beautifying effect.
  • the present invention is used in the field of functional fiber products.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Textile Engineering (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Organic Chemistry (AREA)
  • Birds (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Bedding Items (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Mattresses And Other Support Structures For Chairs And Beds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

La présente invention propose un agent destiné à communiquer à des produits textiles certaines fonctions telles que, par exemple, l'humidification, le ralentissement du vieillissement de la peau, l'amélioration des propriétés de la peau, la prévention des escarres, des effets thérapeutiques, la prévention et le traitement de la dermatite atopique, des effets anti-inflammatoires, la guérison des blessures, etc. L'invention concerne donc un agent destiné à communiquer certaines fonctions à des produits textiles, ledit agent contenant de l'hydroxyproline, un dérivé acylé de l'hydroxyproline ou un sel de celle-ci, et des produits textiles fonctionnels à utiliser avec l'agent destiné à communiquer des fonctions tel que décrit plus haut, en particulier des matériaux et des articles d'architecture, de literie, de décoration domestique, d'aménagement intérieur d'automobiles, de soins infirmiers, des vêtements, des couches en tissu, des couches en papier jetables, des mouchoirs en papier et du papier de soie.
PCT/JP2006/308214 2005-05-02 2006-04-19 Agent destine a communiquer des fonctions a des produits textiles WO2006120851A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007528169A JPWO2006120851A1 (ja) 2005-05-02 2006-04-19 繊維製品への機能性付与剤

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JP2005-134124 2005-05-02
JP2005134124 2005-05-02

Publications (1)

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WO2006120851A1 true WO2006120851A1 (fr) 2006-11-16

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008126782A1 (fr) * 2007-04-06 2008-10-23 Kyowa Hakko Bio Co., Ltd. Agent antiseptique cutané
JP2009270208A (ja) * 2008-05-01 2009-11-19 Ohara Palladium Kagaku Kk 繊維用抗菌防臭加工剤並びに該加工剤で加工処理されてなる繊維製品。
US8338404B2 (en) * 2007-09-11 2012-12-25 Kyowa Hakko Bio Co., Ltd. Composition and method for reducing allergen
ITVR20120104A1 (it) * 2012-05-22 2013-11-23 Paolo Srl O Procedimento di trattamento di tessuti destinati ad andare a contatto col corpo umano
WO2014007290A1 (fr) * 2012-07-03 2014-01-09 味の素株式会社 Hydratant et produit cosmétique le comprenant
JP2018202170A (ja) * 2017-06-02 2018-12-27 三洋化成工業株式会社 吸収性物品
JP2018202165A (ja) * 2017-06-02 2018-12-27 三洋化成工業株式会社 吸収性物品
WO2019012744A1 (fr) 2017-07-14 2019-01-17 信越化学工業株式会社 Fibres comprenant un agent fonctionnel, et procédé de fabrication de celles-ci

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Publication number Priority date Publication date Assignee Title
JPS5598978A (en) * 1979-01-18 1980-07-28 Keizou Ogino Dyeing of polyamide product
JPS58212447A (ja) * 1982-05-26 1983-12-10 シ−トン・カンパニ− 凝集性，多孔質コラ−ゲンシ−ト材料の製造方法
JPS62110977A (ja) * 1985-11-11 1987-05-22 日本油脂株式会社 パ−ル状柔軟剤組成物
JP2000178881A (ja) * 1998-12-15 2000-06-27 Fuji Spinning Co Ltd セルロース系布帛の加工法
WO2000051561A1 (fr) * 1999-03-02 2000-09-08 Kyowa Hakko Kogyo Co., Ltd. Produits cosmetiques
WO2003018073A2 (fr) * 2001-08-24 2003-03-06 The Procter & Gamble Company Article absorbant presentant une region de type film qui contient du chitosane et procede de fabrication associe

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5598978A (en) * 1979-01-18 1980-07-28 Keizou Ogino Dyeing of polyamide product
JPS58212447A (ja) * 1982-05-26 1983-12-10 シ−トン・カンパニ− 凝集性，多孔質コラ−ゲンシ−ト材料の製造方法
JPS62110977A (ja) * 1985-11-11 1987-05-22 日本油脂株式会社 パ−ル状柔軟剤組成物
JP2000178881A (ja) * 1998-12-15 2000-06-27 Fuji Spinning Co Ltd セルロース系布帛の加工法
WO2000051561A1 (fr) * 1999-03-02 2000-09-08 Kyowa Hakko Kogyo Co., Ltd. Produits cosmetiques
WO2003018073A2 (fr) * 2001-08-24 2003-03-06 The Procter & Gamble Company Article absorbant presentant une region de type film qui contient du chitosane et procede de fabrication associe

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008126782A1 (fr) * 2007-04-06 2008-10-23 Kyowa Hakko Bio Co., Ltd. Agent antiseptique cutané
JP5424869B2 (ja) * 2007-04-06 2014-02-26 協和発酵バイオ株式会社 皮膚消毒剤
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