WO2006060517A1 - Pressure regulator with ceramic valve element - Google Patents
Pressure regulator with ceramic valve element Download PDFInfo
- Publication number
- WO2006060517A1 WO2006060517A1 PCT/US2005/043380 US2005043380W WO2006060517A1 WO 2006060517 A1 WO2006060517 A1 WO 2006060517A1 US 2005043380 W US2005043380 W US 2005043380W WO 2006060517 A1 WO2006060517 A1 WO 2006060517A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fuel
- valve
- flow
- biasing member
- pressure regulator
- Prior art date
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 10
- 239000000446 fuel Substances 0.000 claims abstract description 138
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000007246 mechanism Effects 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000005483 Hooke's law Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K25/00—Details relating to contact between valve members and seats
- F16K25/005—Particular materials for seats or closure elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M69/00—Low-pressure fuel-injection apparatus ; Apparatus with both continuous and intermittent injection; Apparatus injecting different types of fuel
- F02M69/46—Details, component parts or accessories not provided for in, or of interest apart from, the apparatus covered by groups F02M69/02 - F02M69/44
- F02M69/54—Arrangement of fuel pressure regulators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M37/00—Apparatus or systems for feeding liquid fuel from storage containers to carburettors or fuel-injection apparatus; Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M69/00—Low-pressure fuel-injection apparatus ; Apparatus with both continuous and intermittent injection; Apparatus injecting different types of fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K15/00—Check valves
- F16K15/02—Check valves with guided rigid valve members
- F16K15/04—Check valves with guided rigid valve members shaped as balls
- F16K15/048—Ball features
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D16/00—Control of fluid pressure
- G05D16/04—Control of fluid pressure without auxiliary power
- G05D16/12—Control of fluid pressure without auxiliary power the sensing element being a float
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/02—Fuel-injection apparatus having means for reducing wear
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/09—Fuel-injection apparatus having means for reducing noise
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/80—Fuel injection apparatus manufacture, repair or assembly
- F02M2200/8053—Fuel injection apparatus manufacture, repair or assembly involving mechanical deformation of the apparatus or parts thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/80—Fuel injection apparatus manufacture, repair or assembly
- F02M2200/8084—Fuel injection apparatus manufacture, repair or assembly involving welding or soldering
Definitions
- This invention relates to pressure control devices in general and more particularly, a pressure control device comprising a valve assembly including a ceramic valve element used in automotive fuel systems.
- valves use an upper valve member made of stainless steel or other metallic material and a lower valve member or valve seat fabricated from a stainless steel or other metallic material.
- the valve element When the valve is open, the valve element lifts off the valve seat and may dither, making contact with the valve seat. When the valve closes, the valve element drops onto the valve seat.
- a high density metallic valve element has the potential to wear the sealing surface of the valve seat, which is also called galling. This wear can be attributed to the valve element impacting the valve seat and galling between the valve element and the valve seat.
- Coining is a preferred method of improving the sealing surface on the valve seat.
- a metallic ball or the valve element is used to coin the metallic valve seat. With this process it is possible for galling to occur during coining.
- the Young's Modulus of the valve element and the valve seat are similar, both parts can deform at a similar rate during the coining operation. The result may lead to poor leak performance.
- Pressure regulators known in the art also use a valve biasing member biased to a valve seat with a longitudinal flow passage. At low fuel pressures, the valve seat is biased to a closed position to prevent the flow of fuel through the pressure regulator. As fuel pressure builds in the system, the pressure against the valve seat overcomes the biasing force of the valve biasing member, allowing fuel to flow through the valve seat, thereby controlling the fuel pressure in the system.
- a flow through pressure regulator comprising: a lower housing having a fuel inlet wherein a flow of fuel through the fuel inlet communicates with a valve assembly through a fuel chamber; the valve assembly regulating the flow of fuel through the lower housing to a fuel outlet wherein a valve element rests on a valve seat in a closed position to prohibit the flow of fuel from the fuel chamber to the fuel outlet; a valve biasing member for biasing the valve element toward the fuel chamber in opposition to pressure exerted on the valve element by the fuel in the fuel chamber; and a fuel cover for directing the flow of fuel from the valve biasing member to the fuel outlet.
- a valve biasing member for a flow through pressure regulator comprising: a flat disk; the flat disk affixed to a lower housing in a fixed relative position; and a flow of fuel in communication with the flat disk for controlling transmitted flow of fuel from a fuel inlet to a fuel outlet.
- a method for reducing noise generation in a flow through pressure regulator comprising: providing a passage for a fuel flow from a fuel inlet to a fuel outlet wherein a valve element prohibits the fuel flow through the passage; and communicating the fuel flow with a valve biasing member during flow through the passage.
- Figure 1 illustrates a perspective view of the valve assembly.
- Figure 2 illustrates is a cross section view of the valve assembly with the upper valve element in the open position.
- Figure 3 illustrates a cross sectional view of the flow through pressure regulator that includes a valve biasing member.
- Figure 4 illustrates a perspective view of the flow through pressure regulator that includes a valve biasing member.
- Figure 5 illustrates a top view of the valve biasing member.
- Figure 6 illustrates a perspective view of a fuel cover.
- Figure 7 illustrates a top view of an alternative 3 point of contact embodiment of the valve biasing member.
- Figure 8 illustrates a top view of an alternative spiral embodiment of the valve biasing
- FIGS 1 , 2, and 3 illustrate a flow through pressure regulator 10 according to the present invention.
- Flow through pressure regulator 10 includes a lower housing 20 that contains a fuel tube 30.
- Fuel tube 30 houses a fuel chamber 40 which is generally cylindrical in shape and which channels the fuel into the pressure regulator 10 from the fuel pump (not shown).
- fuel tube 30 is made from stainless steel.
- Fuel will first pass through a fuel filter 50 into fuel chamber 40.
- Fuel filter 50 generally circular in shape, it is disposed around lower portion of fuel tube 30 and adjacent to an o-ring 60.
- O-ring 60 is positioned below the lower housing 20 to seal and prevent any fuel leakages into other components in the system.
- O- ring 60 is made of an elastomeric material and is generally circular in shape. Others skilled in the art may select not to use an o-ring 60.
- Flow through pressure regulator 10 also includes a valve seat 70 which cooperates with valve element 80 that is movably disposed between a closed and open position. In the closed position, the valve element 80 contacts and seals against the seating surface of the valve seat 70 and prevents fuel flow through the valve seat 70.
- the valve element 80 is biased into the closed position by valve biasing member 90.
- Valve biasing member 90 is held in place by lower housing 20 which crimps over the outer edge of valve biasing member 90. Others skilled in the art may choose to affix the valve biasing member 90 to lower housing 20 with a weld or clip. Pressurized fuel flows through and accumulates in fuel chamber 40 until the pressurized fuel contacts the bottom surface of the valve element 80. The pressurized fuel will then push valve element 80 off of valve seat 70 into an open position. The fuel flows through the valve seat 70. In manufacturing the valve seat 70, the sealing surface is coined to assure smooth sealing between the valve element 80 and the valve seat 70.
- Valve biasing member 90 functions to hold the valve element 70 of the flow through pressure regulator 10 in a closed position at a predetermined amount of pressure that is related to the pressure desired by the flow through pressure regulator 10 specification.
- the valve element 80 is shaped as a sphere and maintains a free floating design.
- the valve element 80 is made of a ceramic consisting of alumina oxide, to prevent galling from occurring during coining and reduce wear on the valve seat.
- the valve element 80 performs in wear, heat, corrosive environments and maintains dimensional stability of temperatures up to 2000 degrees F.
- the valve element 80 is not retained by other components of the flow through pressure regulator 10 and therefore does not share a permanent contact with the valve biasing member 90.
- the valve element 80 is free to move both axially and radially when displaced from the valve seat 70.
- Valve biasing member 90 is positioned on the upper surface of the valve element 80 to assist with movement of the valve element 80 in an axial direction away from the valve seat 70.
- valve element 80 When the pressure of the inlet fuel is greater than the force exerted by the valve biasing member 90, the fuel pushes the valve element 80 in an axial upward direction and the valve element 80 leaves the valve seat 70. Fuel flows through the flow through pressure regulator 10 until the pressure of the valve biasing member 90 is strong enough to return the valve element 80 to the valve seat 70 thus closing the opening in the valve seat 70.
- Others skilled in the art may wish to select different shapes for the valve element 80 including a truncated sphere or cone. Others skilled in the art may also choose to weld the valve element 80 to the valve biasing member 90.
- valve biasing member 90 provides the force to close the valve element 80 and seal the opening of the valve seat 70.
- Valve biasing member 90 also provides the spring rate necessary to regulate the fuel pressure in the system.
- the geometry of valve biasing member 90 consists of at least two co-axial concentric rings 100 and 110 adhered together by at least one bridge 120.
- the preferred shape of the valve biasing member is annular, however, others skilled in the art may select other shapes including oval.
- balanced slot openings 130 are formed. In the preferred embodiment, the balanced slot openings 130 are arc shaped. Others skilled in the art may select a balanced slot opening 130 to be shaped as a circle, tubular, triangular or angled.
- Each concentric ring 110 has a beam length used to calculate the spring rate under Hookes law.
- the effective beam length is defined as the total length of the valve biasing member 90. The effect of changing the length of the beams, with all other factors remaining constant, will result in changes to performance criteria.
- the bridge 120 connects first ring 100 with its adjacent neighbor ring 110 in a reticulated network fashion. Bridge 120 increases the effective length of the beams of valve biasing member 90 which achieves desirable spring rates for the flow through pressure regulator 10.
- the valve biasing member 90 applies a balanced force to the valve element 80 that allows the valve element 80 to lift straight in an upright manner without any bias.
- the balanced openings 130 serve as a homogenous diffuser to direct the flow of fuel from the opening of the valve seat 70 to various directions.
- the balanced openings 130 disperse the fuel flow with improved flow characteristics and less noise.
- the center aperture 140 of the valve biasing member 90 preferably centers on the lower housing 20 and on the central axis of valve seat 70.
- the center aperture 140 provides a three-point contact with the valve element 80.
- Others skilled in the art may contact the valve biasing member 90 with the valve element 80 with less than or more than three reference points. This feature centers the valve element 80 and achieves low flow linearity of the flow through pressure regulator 10 resulting in regulation at a low flow at the right pressure.
- a floating valve element 80 design which typically requires an additional part and that is in common in other regulator designs is not required.
- Others skilled in the art may allow the valve element 80 to float in a radial direction by reducing the diameter of or eliminating entirely the center aperture 140 of the valve biasing member 90.
- flow through pressure regulator 10 also includes a fuel cover 150.
- the fuel cover 150 is made of a plastic molded material and generally houses the flow through pressure regulator 10.
- Fuel cover 150 includes fuel passageway 160 for directing and turning the flow of fuel from the valve biasing member 90 to fuel outlet 170.
- the fuel outlet 170 is generally circular in shape and located on the outer edge of cover 150.
- Fuel cover 150 also includes at least one snap mechanism 180 allowing ease when being affixed to the flow through pressure regulator 10.
- the snap mechanism 180 may be directly molded into the fuel cover 150 as an integral clip. This eliminates the need for separate clip attachments.
- the snap mechanism 180 is a tab acting as a clip to hold the flow through pressure regulator 10 in place.
- Fuel cover 150 also acts to keep the valve biasing member 90 submerged in fuel at all times during fuel flow which enhances durability of the valve biasing member 90 as well as dampen any vibrating noise of the valve biasing member 90.
- the fuel builds in the cover chamber 190 above the valve biasing member 90 and climbs over internal wall 200 and then flows to fuel outlet 170. By this process, the flow of fuel exits in an organized flow and does not discharge in various directions.
- submergence of the valve biasing member 90 in the fuel ensures that the fuel is located on both the top portion and the bottom portion of the valve biasing member 90.
- Submergence of the valve biasing member 90 in fuel also ensures that the fuel is not aerated which consequently lessens noise in the flow through pressure regulator 10.
- the fuel cover 150 protects the valve biasing member 90 during shipping and handling.
- valve biasing member 90 illustrates alternative embodiments of the valve biasing member 90. In these embodiments, all the various elements of the flow through pressure regulator 10 are identical with exception to the valve biasing member 90.
- the geometry of valve biasing member 90 is a flat disk including at least a three point of contact aperture 140 with no concentric ring geometry.
- the geometry of valve biasing member 90 is a flat disk with a spiral shape having center aperture 140.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- General Physics & Mathematics (AREA)
- Automation & Control Theory (AREA)
- Fuel-Injection Apparatus (AREA)
- Safety Valves (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE112005002871T DE112005002871T5 (en) | 2004-12-01 | 2005-12-01 | Pressure regulator with ceramic valve element |
JP2007544482A JP2008522099A (en) | 2004-12-01 | 2005-12-01 | Pressure regulator with ceramic valve element |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63209404P | 2004-12-01 | 2004-12-01 | |
US60/632,094 | 2004-12-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006060517A1 true WO2006060517A1 (en) | 2006-06-08 |
Family
ID=36095776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/043380 WO2006060517A1 (en) | 2004-12-01 | 2005-12-01 | Pressure regulator with ceramic valve element |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP2008522099A (en) |
KR (1) | KR100902449B1 (en) |
DE (1) | DE112005002871T5 (en) |
WO (1) | WO2006060517A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006258191A (en) * | 2005-03-17 | 2006-09-28 | Pacific Ind Co Ltd | Valve, and method for manufacturing valve |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100981086B1 (en) * | 2008-08-13 | 2010-09-08 | 인지컨트롤스 주식회사 | Pressure regulator for vehicle fuel system |
KR101381368B1 (en) * | 2013-12-12 | 2014-04-04 | 유상근 | The hydrostat for portable gas range |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3934612A (en) * | 1974-07-08 | 1976-01-27 | The United States Of America As Represented By The United States National Aeronautics And Space Administration | Fluid valve with wide temperature range |
DE19849849A1 (en) * | 1998-10-29 | 2000-05-04 | Pierburg Ag | Fuel pressure regulator valve for combustion engine has contact surface of valve closure made of ceramic material |
US20030196702A1 (en) * | 2001-02-16 | 2003-10-23 | Robert Bosch Gmbh | Pressure regulator |
EP1477873A1 (en) * | 2003-05-12 | 2004-11-17 | WIKA Alexander Wiegand GmbH & Co.KG | Pressure control sysytem |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5018767Y1 (en) * | 1970-09-21 | 1975-06-07 | ||
JPS5915790Y2 (en) * | 1979-05-30 | 1984-05-10 | 日東工器株式会社 | Valve mechanisms for compressors, etc. |
JPS63125264U (en) * | 1987-02-06 | 1988-08-16 | ||
JPH0562775U (en) * | 1992-01-31 | 1993-08-20 | 株式会社土屋製作所 | Relief valve |
JP3296372B2 (en) * | 1993-03-30 | 2002-06-24 | 三菱電機株式会社 | underwater pump |
DE69414814T2 (en) | 1993-12-13 | 1999-04-15 | Stanadyne Automotive Corp., Windsor, Conn. | Main filtration module for fuel with optional conversion options |
DE19705405A1 (en) * | 1997-02-13 | 1998-08-20 | Bosch Gmbh Robert | Device for a fuel system |
JP3767111B2 (en) * | 1997-08-29 | 2006-04-19 | Nok株式会社 | Injection valve |
US6495032B2 (en) | 1999-05-19 | 2002-12-17 | Dynetek Industries Ltd. | Filter arrangement |
JP2002012470A (en) * | 2000-06-23 | 2002-01-15 | Ngk Spark Plug Co Ltd | High purity alumina sintered body, high purity alumina ball, jig for semiconductor, insulator, ball bearing, check valve and method of manufacturing high purity alumina sintered compact |
US6886590B2 (en) * | 2002-09-20 | 2005-05-03 | Siemens Vdo Automative Corporation | Seal assembly for fuel pressure regulator |
JP2004301120A (en) * | 2003-03-14 | 2004-10-28 | Denso Corp | Fuel pressure adjusting device |
-
2005
- 2005-12-01 DE DE112005002871T patent/DE112005002871T5/en not_active Ceased
- 2005-12-01 JP JP2007544482A patent/JP2008522099A/en active Pending
- 2005-12-01 KR KR1020077013816A patent/KR100902449B1/en not_active Expired - Fee Related
- 2005-12-01 WO PCT/US2005/043380 patent/WO2006060517A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3934612A (en) * | 1974-07-08 | 1976-01-27 | The United States Of America As Represented By The United States National Aeronautics And Space Administration | Fluid valve with wide temperature range |
DE19849849A1 (en) * | 1998-10-29 | 2000-05-04 | Pierburg Ag | Fuel pressure regulator valve for combustion engine has contact surface of valve closure made of ceramic material |
US20030196702A1 (en) * | 2001-02-16 | 2003-10-23 | Robert Bosch Gmbh | Pressure regulator |
EP1477873A1 (en) * | 2003-05-12 | 2004-11-17 | WIKA Alexander Wiegand GmbH & Co.KG | Pressure control sysytem |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006258191A (en) * | 2005-03-17 | 2006-09-28 | Pacific Ind Co Ltd | Valve, and method for manufacturing valve |
Also Published As
Publication number | Publication date |
---|---|
DE112005002871T5 (en) | 2007-10-18 |
KR100902449B1 (en) | 2009-06-11 |
JP2008522099A (en) | 2008-06-26 |
KR20070086392A (en) | 2007-08-27 |
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