WO2006020012A1 - Package with reduced product settling - Google Patents
Package with reduced product settling Download PDFInfo
- Publication number
- WO2006020012A1 WO2006020012A1 PCT/US2005/025148 US2005025148W WO2006020012A1 WO 2006020012 A1 WO2006020012 A1 WO 2006020012A1 US 2005025148 W US2005025148 W US 2005025148W WO 2006020012 A1 WO2006020012 A1 WO 2006020012A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- package
- product
- sealing member
- container
- concave body
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/02—Internal fittings
- B65D25/10—Devices to locate articles in containers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/02—Internal fittings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/02—Internal fittings
- B65D25/04—Partitions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2207/00—Standing packages
Definitions
- the present invention is related to packages and packaged products.
- the present invention is related to packages and packaged products in which the product is formed from a plurality of discrete units.
- air freshener products are well known in the market and may take a variety of forms and shapes.
- natural air freshener products such as potpourri may be derived from leaves, stems, etc of flowers and herbs, and may be sold in a see-through package.
- a solid, waxy, or gel material in the form of beads, blocks, etc. is provided which absorbs odors and/or releases perfume.
- gel-type air fresher products also are often sold in see-through packages.
- Such see-through packages typically include at least one portion and/or surface which is either transparent or translucent.
- the discrete units of the product tend to settle over time so that the package appears to contain less product. Such settling may be especially pronounced if the package is transported and stored in the same orientation. While the performance and actual amount of product contained in such a "settled" package may be equivalent to a non-settled package, the perception is that the amount of product is less. This is especially evident where one or more portions of the package are translucent and/or transparent.
- the package may contain a series of baffles, such as are found in an ice-cube tray, to reduce settling.
- baffles tend to cause problems during the filling of the package, as the discrete units of the product (as opposed to a liquid, which may easily flow around the baffles) may tend to congregate around the filling point, and not spread evenly throughout the package.
- baffles often require a significant amount of package material to form, increasing the cost and weight of the package.
- the need exists for a package which overcomes the settling problems described above.
- the need further exists for a package and product combination which is easier to make and employs less package material.
- the present invention relates to a package containing a container for holding a product, a sealing member, and a product containing a plurality of discrete units therein.
- the container contains a concave body bounded by an edge and at least one post protruding from the concave body member.
- the container also contains a first end and a second end in opposition to each other.
- the sealing member is affixed to the edge to form a seal, which keeps the product between the sealing member and the concave body member.
- the post protrudes from the sealing member, instead of the concave body member, so as to achieve a result similar to that above.
- Such an embodiment is useful if settling is not an issue after the sealing member is removed. For example when the product is quickly used up or emptied from the concave body member after the sealing member is removed, such as may be the case for a unit-dose or an individual serving of cereal.
- the package of the present invention has less settling than a package without such a post, and can be comparable to a package with a baffle.
- the package of the present invention also has advantages over a package with a baffle, in that the package may be filled much easier, and the discrete units will more easily flow around a post than a baffle. This allows significant flexibility in the filling orientation as well as filling speed, and the type, shape, and physical properties of the discrete units to be used.
- Fig. 1 is a top-perspective view of an embodiment of the package with posts;
- Fig. 2 is a top-perspective view of an existing package with baffles;
- Fig. 3 is an exploded- view of an embodiment of the package showing a product and a multi-layer sealing member.
- the figures herein are not necessarily drawn to scale.
- the package herein contains a container, a sealing member, and a product.
- the package may be used for a variety of different products, to significantly reduce or even prevent settling caused by, for example, time, vibrations, placement direction, etc.
- block-type products, granular products, gel-type products, and even, for example, cereal would benefit from the package of the present invention.
- the present invention relates to an air freshener product which may freshen the air by absorbing undesirable odor(s), neutralize undesirable odor(s), and/or covering up undesirable odor(s) by, for example, releasing a perfume.
- FIG. 1 is a top-perspective view of a package, 10, formed of a container, 100, with a concave body member, 102, which is bounded by an edge, 104.
- the concave body member, 102 need not be completely concave, but should have at least a portion thereof which forms a hollow shape in which to hold the product (see Fig. 3 at 124).
- the concave body member, 102 may contain a plurality of both concave and convex shapes.
- a plurality of posts, 106 having the cross-sectional shape of a cross protrude from the concave body member, 102.
- At least 1 post is present and protrudes from the concave body member.
- the exact number of posts useful herein depends upon the physical properties of the product and the package, and may be determined by one skilled in the art. In an embodiment of the present invention, the number of posts is from about 2 to about 20. In another embodiment, the number of posts is from about 3 to about 10.
- the posts are typically evenly dispersed around the concave body member, but may also be clustered around the edge, 104, or around the center of the convex body member, as desired. Without intending to be limited by theory, it is believed that these post configurations provide embodiments which substantially reduce settling of the product over time, and/or when subjected to vibrations, placement, as compared to other post configurations.
- the container, 100 contains a first end, 108, and a second end, 110 opposed to the first end, 108.
- the distance, ⁇ , between two adjacent posts, 106A and 106B, is also shown in Fig. 1.
- the posts, 106 have a cross-sectional shape of a cross, where two opposite points thereof, 112 and 112', form a post line, A-A, which is substantially parallel to a second end line, B-B, formed by the second end, 110.
- A-A which is substantially parallel to a second end line, B-B, formed by the second end, 110.
- the package and/or container may be formed of a variety materials such as a plastic or polymers, rubber, glass, metal, and a combination thereof.
- An embodiment of the package and/or container includes rubber, plastic, polyester, and a combination thereof, and another embodiment includes polyethylene, polypropylene, polyethylene terephthalate, polycarbonate, polystyrene, ethyl vinyl alcohol, thermoplastic elastomer, and a combination thereof.
- Flexible package and/or container parts preferably contain at least a portion of thermoplastic elastomer. Textured surfaces may also be employed so as to enhance gripping, if desired.
- Preferred production processes are blow molding, injection molding, injection blow molding, vacuum forming, thermoforming, and a combination thereof.
- the various individual package and/or container portions may be formed with different materials, and/or by different processes, as desired.
- Optional, but preferred characteristics of the container material include color, tinting, UV blocking agents, translucency, transparency, or opaqueness.
- Examples of the UV blocking agent useful herein include titanium dioxide, benzophenone, hydroxy-benzophenone, benzotriazole, and a mixture thereof.
- Such UV blocking agents are commonly available from, for example, Sumito Chemical, Tokyo Japan; Kyodo Chemical, Tokyo Japan; Asahi Denka, Tokyo Japan; Ciba Giegy, Tokyo Japan; and others.
- An embodiment of the package, container, sealing member see Fig.
- concave body member material is transparent or translucent and optionally contains a UV blocking agent to either absorb, reflect, or otherwise reduce the amount of UV light penetrating the container to reach the product.
- a UV blocking agent to either absorb, reflect, or otherwise reduce the amount of UV light penetrating the container to reach the product.
- Other characteristics include easy formation to the desired shape(s), resistance to the product and the applicable pH ranges, durability, coloration, coatings and/or resiliency.
- the container material should be temperature resistant to temperatures from about -5 °C to about 90 °C.
- the package may be sized to hold whatever volume is desirable. In an embodiment herein, the package holds a volume of from about 0.5 niL to about 10 L, or from about 1 mL to about 5 L. In an embodiment herein the package holds a volume of from about 100 mL to about 500 mL.
- a sealing member, 114 is affixed to the edge, 104, to form a seal, 116, which keeps the product (see Fig. 3 at 124) within the bounds of the concave body member, 102, and the sealing member.
- the sealing member, 114 when the sealing member, 114 is affixed to the concave body member, 102, the package, 10, should be substantially impervious to the product (see Fig. 3 at 124), meaning that the product should not be able to undesirably escape, unless the seal, 116, or the package, 10, is otherwise opened.
- the sealing member, 114 contains a tab, 118, which is pulled to specifically break the seal, 116, and open the package, 10.
- the sealing member, 114 may be formed of any of the package and/or container materials above, but is typically formed of a film, such as formed by a plastic, a polymer, and/or a metal.
- the film is a polypropylene and/or polyethylene film.
- the film is a transparent or translucent film.
- the film may be an opaque film, and/or contain a metal therein, such as an aluminum film and/or a mylar film.
- the sealing member is a transparent or translucent film which further includes a UV blocking agent.
- the sealing member useful herein is commonly available from many suppliers, such as Dow Chemicals, Midland, Michigan, USA; DuPont, Wilmington, Delaware, USA; Mitsui Chemical Co., Tokyo Japan; and Toppan Printing Co., Ltd., Tokyo Japan.
- the seal, 116 may be formed by any process known in the art which is compatible with the edge and the sealing member, such as, for example, heat sealing, ultrasonic sealing, pressure sealing, an adhesive, a hook and loop system such as VELCROTM, tape sealing, and/or covering using a lid.
- the seal, 116 should be of sufficient strength and tightness so as to prevent accidental and unintentional release of the product (see Fig. 3 at 124) from the package.
- the seal is watertight and/or airtight.
- the seal is not airtight or watertight, and yet still keeps the product within the package until the package is specifically opened.
- the sealing member contains at least 2 layers, or from about 2 to about 20 layers. In an embodiment herein, the sealing member contains from about 5 to about 17 layers. In another embodiment, the sealing member contains from about 6 to about 13 layers. Such layers could include, for example, a plastic film, a metal film, an adhesive, a lubricant, varnish, a pigment, and/or printing inks.
- the thickness of the film may be from about 20 to about 300 microns. In an embodiment of the invention, the thickness of the film may be from about 40 to about 200 microns. In another embodiment of the invention, the thickness of the film may be from about 80 to about 150 microns.
- a preferred sealing member may also contain cut-out shapes on one or more layers so that when opened, air may enter the package, and yet the product is kept or held inside (see Fig. 3 at 114A and 114B).
- a sealing member is available as polyethylene, polypropylene, polyolefin, polyethylene-terephthalate, nylon, and/or paper.
- Fig. 2 shows a top-perspective view of an existing package, 10, with baffles, 120, similar to those found in an ice cube tray.
- the baffles, 120 are not continuous and have a space, 122, therebetween and between the baffle, 122 and the edge of the convex body member, 102.
- the spaces, 122 allow the product to flow therebetween, but even though the baffles, 120, reduce or even prevent product settling, it has been found that such an embodiment only works well for a liquid product, or a product which is initially a liquid during the filling process, and then which later solidifies. In fact, it has been found that a package as described in Fig.
- baffles require a significant amount of convex body member material, which leads to higher packaging costs, as compared to the posts, 106.
- Fig. 3 shows an exploded- view of an embodiment of the package, 10, showing a product, 124, contained therein.
- the product, 124 is a plurality of discrete units such as a solid or a gel, and not a continuous single piece, nor a liquid.
- An example of the discrete units useful herein include fruit, cereal, or other foodstuff.
- the product is potpourri.
- the discrete unit is a natural and/or a synthetic gel.
- a natural gel useful herein can be xanthan gum, guar gum, carboxy methyl cellulose or agars.
- a synthetic gel useful herein can be a cross-linked polymer such as an acrylic-based polymer.
- the gel can be chemically cross-linked or physically cross-linked.
- cross-linked polymers are cross-linked acrylic acid, acrylamide, polyethylene oxide, maleic acid, styrene, malic acid, etc., especially block polymers thereof.
- physically cross-linked polymers are polyethylene oxides.
- gel items useful herein includes Aquakeep, Aquacube, Aquacalk TW, and Aquacalk TWB from Sumitomo Seika, Osaka, Japan, Aquapearl from Mitsubishi Chemicals, Tokyo, Japan, and Aqualin, AQUALIC CA, AAULIC CS, ACRYHOPE, and super absorption polymer from Nihon Shyokubai, Osaka, Japan.
- Such a product may contain an active ingredient which absorbs, neutralizes, and/or traps odor(s).
- a product may contain a perfume and release the perfume over time.
- Such a product, especially a gel may disappear and/or shrink over time or as water and/or other ingredients degrade, escape and/or evaporate.
- the shape of the product, 124 may be a cone, ball, cube, block, or other predetermined shape as desired.
- the product possess a predetermined shape rather than an amorphous shape.
- the product possesses a predetermined shape with at least one angled portion, such as a corner or point, as such an angled portion tends to catch on the post, as opposed to a completely round, curved, or amorphous product, which will tend to more easily roll around the post.
- the plurality of discrete units are of substantially the same dimensions; by “substantially the same dimensions", it is meant that when the total volume of the discrete units is measured and graphed as a distribution, 90% of the discrete units are within the range of +/- 50% of the average volume, and preferably 90% of the discrete units are within the range of +/- 33% of the average volume.
- the discrete units have an average length, and the distance, ⁇ , between the posts is less than about 3 times the average length.
- the distance, ⁇ , between the posts is from about 0.25 times to about 3 times the average length.
- the distance, ⁇ , between the posts is from about 0.5 times to about 2 times the average length.
- the distance, ⁇ , between the posts is from about 0.75 times to about 1.5 times the average length.
- the distance between a post and the container edge can be similar to the distance, ⁇ between adjacent posts.
- the average length is defined as the longest straight distance through a discrete unit, whether it be a diagonal, a diameter, or otherwise. Without intending to be limited by theory, it is believed that the above product characteristics significantly contribute to reduced settling.
- the sealing member, 114 is a multi-layer sealing member, 114A and
- the first layer of the sealing member, 114A peels away from the second layer of the sealing member, 114B, exposing film holes, 126.
- the seal between the second sealing member, 114B and the edge, 104 is stronger than the attraction between the first layer of the sealing member, 114A, and the second layer of the sealing member, 114B.
- the second layer of the sealing member, 114B remains sealed to the edge, 104. This in turn, allows air to pass through the film holes, 126, to reach the product, 124.
- the film holes, 126 are designed such that the product, 124, will not easily pass through the film holes, 126, even if the package, 10, is turned so that the product, 124, is resting upon the second layer of the sealing member, 114B. This can be achieved by making width and/or height of the film holes smaller than the average length of the discrete units, or by designing the shape of the film holes so as to otherwise prevent passage of the discrete units.
- the film holes are arranged at a distance from the edge, so as to avoid leakage of water or liquid which may escape from the product and flow towards the second end.
- the container also contains a base, 128, opposite the sealing member, 114.
- the post significantly reduces the settling of the product towards the second end.
- EXAMPLE 1 In an embodiment herein, a package as seen in Fig. 1, except that the center post is removed to provide only 6 cross-shaped posts.
- the package contains a gel material in the form of discrete block-like units as seen in Fig. 3 is stood on a flat surface on the first end for 1 minute and then reversed and stood on the second end for 1 day. After 1 day, the product has settled a little bit in that the bottom 1/5 (near the second end) is touching the sealing member. However at the first end, the product still covers the convex body member and the base can not be seen when viewed from the side of the transparent sealing member. In contrast, when this is attempted with an identical package which lacks the posts, all of the product has settled near the second end, with the product touching the sealing member in the bottom 1 A Furthermore, the top 1/3 (near the first end) of the base can be seen.
- An air freshener product according to Example 1 is produced, which contains a gel product.
- the gel contains a perfume, water, alcohol, an odor-neutralizing polymer, and a hydrotrope.
- the gel itself also absorbs certain undesirable odors, while the odor- neutralizing polymer neutralizes certain undesirable odors due to the reactive functional moieties attached thereto.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Packages (AREA)
- Details Of Rigid Or Semi-Rigid Containers (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005518113A JP4253658B2 (en) | 2004-07-19 | 2005-07-15 | Package with reduced product settling |
CA002573264A CA2573264A1 (en) | 2004-07-19 | 2005-07-15 | Package with reduced product settling |
EP05771323A EP1768912A1 (en) | 2004-07-19 | 2005-07-15 | Package with reduced product settling |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US58904804P | 2004-07-19 | 2004-07-19 | |
US60/589,048 | 2004-07-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006020012A1 true WO2006020012A1 (en) | 2006-02-23 |
Family
ID=35148804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/025148 WO2006020012A1 (en) | 2004-07-19 | 2005-07-15 | Package with reduced product settling |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060010840A1 (en) |
EP (1) | EP1768912A1 (en) |
JP (1) | JP4253658B2 (en) |
KR (1) | KR100704516B1 (en) |
CA (1) | CA2573264A1 (en) |
WO (1) | WO2006020012A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9629937B2 (en) | 2014-03-14 | 2017-04-25 | Protect Plus Industries, Llc | Air scent device |
ITUB20159814A1 (en) * | 2015-12-31 | 2017-07-01 | Zobele Holding Spa | DIFFUSER OF ACTIVE SUBSTANCES, WHICH INSECTICIDES, PERFUMES, DETERGENTS OR DISINFECTANTS, AND PROCEDURE FOR ITS MANUFACTURING |
US20190248534A1 (en) * | 2018-02-09 | 2019-08-15 | Transcontinental Holding Corp (formerly Coveris Holding Corp.) | Standing packages and related methods of use |
KR102246131B1 (en) * | 2018-05-28 | 2021-04-28 | 김주용 | A deodorant using super absorbent polymer |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0316466A1 (en) * | 1986-08-06 | 1989-05-24 | Packaging Corporation Of America | A composite carton |
FR2764806A1 (en) * | 1997-06-18 | 1998-12-24 | Marcel Jean | Perfume diffuser, used in e.g. vehicle or room |
WO2002009779A1 (en) * | 2000-07-27 | 2002-02-07 | The Procter & Gamble Company | Process and device for deodorizing an environment |
WO2002055116A1 (en) * | 2001-01-15 | 2002-07-18 | Reckitt Benckiser (Uk) Limited | Air freshening device |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2981039A (en) * | 1956-01-26 | 1961-04-25 | Ernest F Pohl | Tray package and method of packaging |
US4806718A (en) * | 1987-06-01 | 1989-02-21 | General Mills, Inc. | Ceramic gels with salt for microwave heating susceptor |
US5695060A (en) * | 1993-08-25 | 1997-12-09 | Schoeller-Plast Sa | Tray for receiving containers, in particular yogurt cups |
IT1272598B (en) * | 1993-09-09 | 1997-06-26 | Copan Italia Spa | DEVICE FOR THE COLLECTION AND TRANSPORT OF SAMPLES IN VITRO MAINLY FOR DIAGNOSTIC USE |
US5575992A (en) * | 1994-03-08 | 1996-11-19 | Waterbury Companies, Incorporated | Extended release hot and cold gel fragrance cartridges and method of making the same |
US6230883B1 (en) * | 1998-05-08 | 2001-05-15 | Tres Fresh Llc | Modified atmosphere packaging method |
US6193064B1 (en) * | 1998-11-04 | 2001-02-27 | J. G. Finneran Associates, Inc. | Multi-tier vial plate |
-
2005
- 2005-07-15 WO PCT/US2005/025148 patent/WO2006020012A1/en active Application Filing
- 2005-07-15 EP EP05771323A patent/EP1768912A1/en not_active Withdrawn
- 2005-07-15 KR KR1020057016282A patent/KR100704516B1/en active IP Right Grant
- 2005-07-15 JP JP2005518113A patent/JP4253658B2/en active Active
- 2005-07-15 CA CA002573264A patent/CA2573264A1/en not_active Abandoned
- 2005-08-17 US US11/184,617 patent/US20060010840A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0316466A1 (en) * | 1986-08-06 | 1989-05-24 | Packaging Corporation Of America | A composite carton |
FR2764806A1 (en) * | 1997-06-18 | 1998-12-24 | Marcel Jean | Perfume diffuser, used in e.g. vehicle or room |
WO2002009779A1 (en) * | 2000-07-27 | 2002-02-07 | The Procter & Gamble Company | Process and device for deodorizing an environment |
WO2002055116A1 (en) * | 2001-01-15 | 2002-07-18 | Reckitt Benckiser (Uk) Limited | Air freshening device |
Also Published As
Publication number | Publication date |
---|---|
EP1768912A1 (en) | 2007-04-04 |
KR100704516B1 (en) | 2007-04-09 |
JP2007501166A (en) | 2007-01-25 |
KR20060034626A (en) | 2006-04-24 |
CA2573264A1 (en) | 2006-02-23 |
US20060010840A1 (en) | 2006-01-19 |
JP4253658B2 (en) | 2009-04-15 |
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