WO2005080510A1 - Composition for paint having miror effect, method for its application and products thus obtained - Google Patents
Composition for paint having miror effect, method for its application and products thus obtained Download PDFInfo
- Publication number
- WO2005080510A1 WO2005080510A1 PCT/IB2005/000120 IB2005000120W WO2005080510A1 WO 2005080510 A1 WO2005080510 A1 WO 2005080510A1 IB 2005000120 W IB2005000120 W IB 2005000120W WO 2005080510 A1 WO2005080510 A1 WO 2005080510A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- paint
- percentage comprised
- composition
- reflecting
- Prior art date
Links
- 239000003973 paint Substances 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 18
- 230000000694 effects Effects 0.000 title claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000004411 aluminium Substances 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 28
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 16
- 239000007921 spray Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004761 hexafluorosilicates Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/067—Metallic effect
- B05D5/068—Metallic effect achieved by multilayers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2601/00—Inorganic fillers
- B05D2601/02—Inorganic fillers used for pigmentation effect, e.g. metallic effect
- B05D2601/08—Aluminium flakes or platelets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/58—No clear coat specified
- B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
Definitions
- the invention concerns a composition for paint having reflecting effect, the method for its application and the products thus obtained.
- silver nitrate base paints are used.
- silver nitrate is an expensive product and the known application methods are complicated, require particular equipment and specialised labour. Moreover, the traditional methods to obtain reflecting surfaces are not fit for being used on some kinds of materials, particularly plastic materials.
- Another object of the invention is to provide a composition for paint having the above- mentioned properties that can be easily applied, without needing particular equipment and specialised labour.
- a further object of the invention is to provide a method of applying a paint, to obtain reflecting surfaces, preferably mirror-like, on any kind of material.
- a first formulation of paint composition according to the invention preferably comprises
- a second formulation of paint composition according to the invention preferably comprises (percentages indicated by weight): Al powder in a percentage comprised in the range 0,1 ⁇ 1,5%; ethyl acetate in a percentage comprised in the range between 40 ⁇ 55%; isopropyl alcohol in a percentage comprised in the range between 45 ⁇ 55%.
- a second formulation of paint composition according to the invention preferably comprises (percentages indicated by weight): Al powder in a percentage comprised in the range 0,1 ⁇ 1,5%; ethyl acetate in a percentage comprised in the range 4 ⁇ 8%; propylene glycol monomethyl ether in a percentage comprised in the range 35 ⁇ 45%; n-butyl acetate in a percentage comprised in the range 45 ⁇ 55%.
- the paint composition is spray applied on the product on which the mirror-like reflecting effect is wanted to be obtained.
- the spray application can advantageously take place at room temperature.
- a transparent product for instance slabs of transparent plastics, glass, acrylic materials, etc., to which a reflecting effect to be perceived through the material itself is wanted to be given, for instance when producing a mirror
- the paint application takes place on the opposite face (rear face) with respect to the one through which a reflecting effect is wanted to be obtained (front face).
- mirrors having a reflecting power close to 100% can be produced on materials of any kind and nature, even for instance flexible, provided they are transparent.
- the reflecting material layer can be advantageously covered with a layer of protective material, such as a water base or a solvent base paint, in case even in powder, even itself for instance spray applied.
- a layer of protective material such as a water base or a solvent base paint
- the deterioration and the removal of the reflecting layer which can be caused by abrasions due to the contact against other surfaces, are thus avoided.
- the paint application takes place on the same face on which the reflecting effect is wanted to be obtained.
- silvery ornamental products having a reflecting power of at least 85% and even up to 90% can be produced, starting from mat materials of any kind and nature.
- the same technique can be used on transparent products that are wanted to be made reflecting directly onto the outside surface without exploiting their transparency properties.
- the reflecting paint according to the invention By treating mat materials, prior to the application of the reflecting paint according to the invention, it is preferred to apply on the face that is wanted to be made reflecting a layer of bright primer, for instance by means of powder paints, polyurethane paints, acrylic paints or paints of different kinds provided they are able to give a bright appearance to the surface.
- a first example of such paints for executing a bright primer is given by the following composition: 25% by weight of heavy aromatic solvent naphtha (oil), 12,49% by weight of xylene, 2% by weight of 1,2,4-trimethylbenzene, 2% by weight of solvent naphtha (coal) and 0,25% by weight of hexafluorosilicate; about 20% by weight of catalyst comprising 50% by weight of n-butyl acetate, 50% by weight of isocyanates and 0,25% by weight of hexamethylen-l,6-diisocyanate; and about 10-20% by weight of thinner comprising 50% by weight of n-butyl acetate and 50% by weight of xylene.
- a second example of such paints for executing a bright primer is given by the following composition: 25% by weight of xylene, 12,49% by weight of 4-methyl-pentan-2-one (methylisobutylketone), 9% by weight of n-butyl acetate and 6% by weight of cyclohexanone; 20% by weight of catalyst comprising 60% by weight of isocyanates, 25% by weight of l-methyl-2-methoxyethyl acetate, 20% by weight of n-butyl acetate, 7% by weight of light aromatic solvent naphtha (oil), 0,25% by weight of hexamethylen-1,6- diisocyanate and 0,25% by weight of 3-isocyanatemethyl-3,5,5-trimethylcyclohexyl isocyanate.
- catalyst comprising 60% by weight of isocyanates, 25% by weight of l-methyl-2-methoxyethyl acetate, 20% by weight of n-butyl acetate, 7% by
- the reflecting material layer can be advantageously covered with a layer of protective material, which in this case shall necessarily be transparent, such as that one obtainable with a water base or a solvent base paint, said paint possibly being even in powder, even itself for instance spray applied.
- a layer of protective material which in this case shall necessarily be transparent, such as that one obtainable with a water base or a solvent base paint, said paint possibly being even in powder, even itself for instance spray applied.
- the protective layer will avoid the removal of the reflecting layer caused by abrasions against other surfaces.
- Particular chromatic effects can be given to products on which the layer of reflecting paint has been applied, by incorporating one or more coloured pigments into the transparent protective paint.
- Example 1 In a first embodiment of the invention, a slab of plexiglas shaped in such a manner to reproduce an alphabet letter was painted on the rear face with the paint according to the invention obtained with the following formulation: Isopropyl alcohol 52,5%
- Aluminium powder 0,75%
- the rear face of the slab was painted with the above-mentioned composition by spray gun under conditions of air-rich mixture. Both the application and the drying of the layer of the reflecting paint took place at room temperature.
- the product thus obtained showed a substantially mirror-like reflecting surface visible through the front face, while the rear face appeared metallised and substantially mat.
- the container, made of mat plastics, of an electronic apparatus was first painted with a powder paint so to realise a bright layer on the container. Then, the dried bright layer was covered with the paint according to the invention obtained with the following formulation:
- the container was painted by spray gun under conditions of air-rich mixture.
- the product thus obtained showed a reflecting surface having a reflecting power of about
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO2004A000026 | 2004-01-23 | ||
IT000026A ITTO20040026A1 (en) | 2004-01-23 | 2004-01-23 | COMPOSITION OF PAINT WITH REFLECTIVE EFFECT, METHOD FOR ITS APPLICATION AND PRODUCTS SO OBTAINED. |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005080510A1 true WO2005080510A1 (en) | 2005-09-01 |
Family
ID=34878869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2005/000120 WO2005080510A1 (en) | 2004-01-23 | 2005-01-14 | Composition for paint having miror effect, method for its application and products thus obtained |
Country Status (2)
Country | Link |
---|---|
IT (1) | ITTO20040026A1 (en) |
WO (1) | WO2005080510A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008046567A1 (en) * | 2006-10-13 | 2008-04-24 | Endlendt Sandy | Chrome effect paint, chrome effect paint systems and painting method |
ITBO20100532A1 (en) * | 2010-08-30 | 2012-03-01 | Alimonte Carlo D | MIRROR AND METHOD TO REALIZE THE SAME. |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2941894A (en) * | 1955-03-16 | 1960-06-21 | American Marietta Co | Metallized coating compositions |
US3764067A (en) * | 1972-01-26 | 1973-10-09 | Harris Paint Co | Method for decorating surfaces |
US4287231A (en) * | 1975-01-20 | 1981-09-01 | Westinghouse Electric Corp. | Method of spray-reflectorizing electric lamp envelopes |
EP0401766A2 (en) * | 1989-06-08 | 1990-12-12 | BASF Corporation | Reflective automotive coating compositions + method |
US5422229A (en) * | 1993-08-16 | 1995-06-06 | Fabco Products, Inc. | Liquid foil employing aluminum platelets |
JPH07238242A (en) * | 1994-02-28 | 1995-09-12 | Ichikoh Ind Ltd | Method for manufacturing specular body |
-
2004
- 2004-01-23 IT IT000026A patent/ITTO20040026A1/en unknown
-
2005
- 2005-01-14 WO PCT/IB2005/000120 patent/WO2005080510A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2941894A (en) * | 1955-03-16 | 1960-06-21 | American Marietta Co | Metallized coating compositions |
US3764067A (en) * | 1972-01-26 | 1973-10-09 | Harris Paint Co | Method for decorating surfaces |
US4287231A (en) * | 1975-01-20 | 1981-09-01 | Westinghouse Electric Corp. | Method of spray-reflectorizing electric lamp envelopes |
EP0401766A2 (en) * | 1989-06-08 | 1990-12-12 | BASF Corporation | Reflective automotive coating compositions + method |
US5422229A (en) * | 1993-08-16 | 1995-06-06 | Fabco Products, Inc. | Liquid foil employing aluminum platelets |
JPH07238242A (en) * | 1994-02-28 | 1995-09-12 | Ichikoh Ind Ltd | Method for manufacturing specular body |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 01 31 January 1996 (1996-01-31) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008046567A1 (en) * | 2006-10-13 | 2008-04-24 | Endlendt Sandy | Chrome effect paint, chrome effect paint systems and painting method |
ITBO20100532A1 (en) * | 2010-08-30 | 2012-03-01 | Alimonte Carlo D | MIRROR AND METHOD TO REALIZE THE SAME. |
Also Published As
Publication number | Publication date |
---|---|
ITTO20040026A1 (en) | 2004-04-23 |
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