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WO2005026136A3 - 2, 2’-azino-bis-thiazolines et leurs utilisations en tant que precurseurs de radicaux stables dans l’air et dans l’eau - Google Patents

2, 2’-azino-bis-thiazolines et leurs utilisations en tant que precurseurs de radicaux stables dans l’air et dans l’eau Download PDF

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Publication number
WO2005026136A3
WO2005026136A3 PCT/FR2004/002320 FR2004002320W WO2005026136A3 WO 2005026136 A3 WO2005026136 A3 WO 2005026136A3 FR 2004002320 W FR2004002320 W FR 2004002320W WO 2005026136 A3 WO2005026136 A3 WO 2005026136A3
Authority
WO
WIPO (PCT)
Prior art keywords
organic group
air
water
alkenyl
represent
Prior art date
Application number
PCT/FR2004/002320
Other languages
English (en)
Other versions
WO2005026136A2 (fr
Inventor
Michel Armand
Amer Hammami
Hicham Cavalie-Kosheiry
Original Assignee
Michel Armand
Amer Hammami
Hicham Cavalie-Kosheiry
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michel Armand, Amer Hammami, Hicham Cavalie-Kosheiry filed Critical Michel Armand
Publication of WO2005026136A2 publication Critical patent/WO2005026136A2/fr
Publication of WO2005026136A3 publication Critical patent/WO2005026136A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/08—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D277/12—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/18—Nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/38—Nitrogen atoms
    • C07D277/50—Nitrogen atoms bound to hetero atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

L’invention concerne un composé chimique de formule générale (I) dans laquelle RF et R’F’, identiques ou différents, représentent chacun un atome d’halogène ou un groupe organique choisi parmi un alkyle , un alkényle, un aralkyle, un alkyl-alkényle, un aryl-alkényle, ces groupes étant linéaires ou ramifiés, un cycloalkyle, un aryle, contenant de 1 à 28 atomes de carbone, ledit groupe organique étant halogéné, par exemple au moins 40 % de ses atomes d’hydrogène étant remplacés par un halogène, ledit groupe organique comprenant éventuellement un ou plusieurs hétéroatomes tels que -O-, =N-, -S-, =P-, =(P=O)-, -SO-, -SO2-, et RF et R’F’ sont chacun éventuellement partie d’une chaîne polymérique ou d’un réseau ; R et R’, identiques ou différents, représentent chacun un groupe organique ayant de 1 à 400 atomes de carbone, et sont chacun éventuellement partie d’une chaîne polymérique ou d’un réseau ; R1 et R’1, identiques ou différents, ont chacun l’une des significations de R et peuvent également représenter un atome d’hydrogène. L’invention concerne également les utilisations de tels composés, en tant que précurseurs de radicaux stables dans l’air et dans l’eau.
PCT/FR2004/002320 2003-09-11 2004-09-13 2, 2’-azino-bis-thiazolines et leurs utilisations en tant que precurseurs de radicaux stables dans l’air et dans l’eau WO2005026136A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA 2448618 CA2448618A1 (fr) 2003-09-11 2003-09-11 Nouvelles 2,2'-azino-bisthiazolines comme precurseurs de radicaux stables dans l'air
CA2,448,618 2003-09-11

Publications (2)

Publication Number Publication Date
WO2005026136A2 WO2005026136A2 (fr) 2005-03-24
WO2005026136A3 true WO2005026136A3 (fr) 2005-06-23

Family

ID=34230795

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2004/002320 WO2005026136A2 (fr) 2003-09-11 2004-09-13 2, 2’-azino-bis-thiazolines et leurs utilisations en tant que precurseurs de radicaux stables dans l’air et dans l’eau

Country Status (2)

Country Link
CA (1) CA2448618A1 (fr)
WO (1) WO2005026136A2 (fr)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5328994A (en) * 1992-02-25 1994-07-12 Bayer Aktiengesellschaft Azinoneutromethines
EP0846948A1 (fr) * 1996-12-09 1998-06-10 Bayer Corporation Médiateurs utilisables dans un biocapteur électrochimique

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5328994A (en) * 1992-02-25 1994-07-12 Bayer Aktiengesellschaft Azinoneutromethines
EP0846948A1 (fr) * 1996-12-09 1998-06-10 Bayer Corporation Médiateurs utilisables dans un biocapteur électrochimique

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ARMAND M ET AL: "A New Family of 2(3H)-Thiazolone Azines as Precursors to Air-Stable Radical Cations", BULL. CHEM. SOC. JPN, vol. 77, 2004, pages 165 - 167, XP002323149 *
HÜNIG S ET AL: "Polarographie und Spektroskopie heterocyclischer Azine und ihrer höheren Oxydationsstufen", LIEBIGS ANN. CHEM., vol. 752, 1971, pages 196 - 205, XP009045651 *
HÜNIG S, SAUER G: "Polarographie von Thiazolon-(2)-azinen", LIEBIGS ANN. CHEM., vol. 748, 1971, pages 189 - 200, XP009045724 *
HÜNIG S, SAUER G: "Radikal-Kationen aus substituierten Thiazolon-(2)-azinen", LIEBIGS ANN. CHEM., vol. 748, 1971, pages 173 - 188, XP009045652 *

Also Published As

Publication number Publication date
WO2005026136A2 (fr) 2005-03-24
CA2448618A1 (fr) 2005-03-11

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