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WO2004073436A1 - Materiau d'entoilage fixable, ses procedes de production et son utilisation - Google Patents

Materiau d'entoilage fixable, ses procedes de production et son utilisation Download PDF

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Publication number
WO2004073436A1
WO2004073436A1 PCT/EP2003/001670 EP0301670W WO2004073436A1 WO 2004073436 A1 WO2004073436 A1 WO 2004073436A1 EP 0301670 W EP0301670 W EP 0301670W WO 2004073436 A1 WO2004073436 A1 WO 2004073436A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyamide
coating
copolyamide
powder
sub
Prior art date
Application number
PCT/EP2003/001670
Other languages
German (de)
English (en)
Other versions
WO2004073436A9 (fr
Inventor
Hans-Jürgen Preuss
Gerhard Thoenissen
Original Assignee
Hänsel Textil GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hänsel Textil GmbH filed Critical Hänsel Textil GmbH
Priority to DE10394096T priority Critical patent/DE10394096A5/de
Priority to AU2003208875A priority patent/AU2003208875A1/en
Priority to PCT/EP2003/001670 priority patent/WO2004073436A1/fr
Publication of WO2004073436A1 publication Critical patent/WO2004073436A1/fr
Publication of WO2004073436A9 publication Critical patent/WO2004073436A9/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/08—Polyamides polyimides
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00—Details of garments or of their making
    • A41D27/02—Linings
    • A41D27/06—Stiffening-pieces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/125—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/10—Particulate form, e.g. powder, granule

Definitions

  • the invention relates to a fixable interlining with a coating based on a copolyamide.
  • the invention also relates to a method for producing the interlining and its use.
  • Interlinings consist of a substrate, e.g. a woven fabric, a knitted fabric or a nonwoven fabric.
  • the base material of the substrate can be for a fabric Cv / PES, PES, Co, Co / PES, Co / CV, Co / Wo, as well as for knitwear PES, Cv / PES, PES / Co, PA / Co, PA / CV and for Nonwovens PA, PA / PES, PES, PES / Cv.
  • Heat-sealable thermoplastic adhesives e.g. Copolyester, copolyamides, polyethylene, ethylene vinyl acetate, polyvinyl chloride used.
  • the coating is e.g. applied as powder point, colon, paste point or by scatter coating.
  • An insert is cut from the insert material and fixed with an outer material by gluing.
  • a coating is required to ensure very good adhesion, security against kickback and puncture as well as a soft grip.
  • Fixations can cause problems when maintaining textile products. For this reason too, care labels were created in the form of symbols for washing, bleaching, ironing, chemical cleaning and drying, which inform the consumer about suitable care treatments. Improper care treatments can make a garment unusable. There is currently no known fixer that meets the maximum requirements of all care treatments. The highest requirements are currently:
  • Washing maximum washing temperature 95 ° C.
  • Drying in a tumbler Care process: No restriction regarding the drying temperature after the washing process
  • the object of the invention is to provide universally usable interlinings with coatings that are fixed with a textile Ensure fabric care treatments up to the highest requirements.
  • the coatings of the fixed interlining materials and in particular also the substrates of the interlining materials should be suitable for enabling finishing treatments such as garment dyeing, stone wash, enzyme wash and bleaching.
  • substrates are selected that meet the specified requirements, if necessary. meet the maximum requirements for nursing treatments and the requirements of finishing treatments.
  • Such substrates are e.g. PES, PES / Co, co-woven and PES knitted fabrics and hydroentangled nonwovens.
  • copolyamides are selected as coating agents from the large number of coating agents.
  • Copolyamides are common coating agents for substrates. Nonetheless, only a few guarantee the conditions of the highest requirements which are to be met according to the object of the present invention.
  • copolyamides used according to the invention which meet the highest requirements of care and finishing treatments and can be used with any substrate, essentially have the following components:
  • Polycaprolactam (polyamide 6, PA 6) polyundecanamide (polyamide 11, PA 11) polylaurine lactam (polyamide 12, PA 12) polyhexamethylene adipinamide (polyamide 6, 6, PA 6, 6)
  • the following hatched composition areas in% by weight which can be seen in FIG. 1 and which are selected according to the invention and have the composition gaps, ensure the desired high requirements of the care treatments as well as the requirements of the finishing treatments.
  • polyamide 12 and / or polyamide 11 can be combined alone with one of the other two polyamides.
  • the condition must be met that the melting temperatures are between 110 and 150 ° C, in particular between 120 and 145 ° C. Accordingly, the above composition ranges must be observed and the compositions selected accordingly.
  • Polyamide 12 is preferably used instead of polyamide 11.
  • a pressure roller is designed as an air-filled hose
  • the preferred fixing time is 12 to 20, in particular 13 to 18 seconds.
  • interlining materials according to the invention also in particular also meet all the requirements with regard to back and puncture resistance and a soft textile handle.
  • the selected copolyamides can be used for various known coatings such as paste point, powder point, colon and scatter coating.
  • the paste point or colon coating is preferred.
  • the usual coating processes and the copolyamides with the usual grain sizes and grain size distributions are used for this. For example, grain sizes for pastes between 0 and 90 ⁇ m and for powder points between 0 and 140 ⁇ m and for colons between 60 and 220 ⁇ m are selected.
  • paste compositions are preferably used in% by weight for the purpose according to the invention:
  • Plasticizer 0, 5-3, 0
  • Walking aids B 2, 0-5, 0 additionally 0.001% by weight lithium salt The following example 1 shows a particularly good paste composition in% by weight.
  • Thickener / 4.1 aqueous preparation of dispersant water-soluble polyamides, neutralized polyacrylic acid, little wetting agent and paraffin oil
  • compositions in% by weight are preferably used for the sub-point paste.
  • Copolyamide powder 0 - 80 ⁇ m 25-38 selected composition according to the invention
  • Running and printing aids A 7.0-9.0
  • a copolyamide scattering powder according to the invention is sprinkled onto this sub-point paste, which has a higher melting point than the copolyamide of the sub-point paste.
  • the following example 2 shows a particularly good sub-dot paste composition in% by weight.
  • Thickener / 4.0 aqueous preparation of dispersant, water-soluble polyamides, neutralized polyacrylic acid, little wetting agent and paraffin oil
  • Copolyamide powder 31.0 crosslinker based on iso- with amino group cyanate is built into the copolyamide active crosslinker
  • Adhesion promoter to the 3, 0 dipropylene glycol substrate and to the copolyamide an additional 0.001% by weight lithium salt for detection According to the invention, a copolyamide powder selected in accordance with the invention is sprinkled onto the sub-point paste in a manner known per se, which results in the colon coating. Copolyamide powder with a grain size between 60 and 220 ⁇ m, in particular between 80 and 180 ⁇ m, is used.
  • thermoset paste known per se can also be used, which has a somewhat higher melting point than the copolyamide scattering.
  • the known colon coating is varied or supplemented.
  • the sub-point paste in particular a Duroplastzurung
  • a copolyamide is added ⁇ the preparation, preferably in quantities of 25 microns to 35 wt .-%, and preferably in a fineness from 0 to 80.
  • a copolyamide powder selected according to the invention is expediently used, and in particular the copolyamide which is scattered on is used.
  • the powder can be in the form of the grain belt. of the scattered powder or with grain sizes used to make the paste.
  • the amount added should be selected so that the properties of the sub-point mass are not significantly affected. Amounts of between 5 and 15% by weight, in particular between 6 and 11% by weight, are preferably added.
  • the copolyamide scattering powder for the colon coating is mixed with small amounts of a powder from the sub-point material, and expediently with the same amounts as when the copolyamide powder is added to the sub-point paste.
  • the grain size preferably corresponds to the grain size of the copolyamide powder.
  • Fixable unit based on a copc substrate the high standard guaranteed and finishing, stone wash, enzyme wash and lie coating essentially
  • Polyundecanamide (polyamide XI, PA 11) and / or polylaurine lactam (polyamide 12, PA 12) and / or polyhexamethylene adipinamide (polyamide 6.6, PA 6.6)
  • compositions are preferably selected such that the melting temperatures are between 110 and 150 ° C., in particular 120 and 145 ° C., and polyamide 12 and / or 11 is preferably combined alone with only one of the other two polyamides.
  • Interlining fabric according to claim 1, characterized by the following maximum and minimum compositions of the coating in% by weight: Polyamide 12
  • a pressure roller is designed as an air-filled hose
  • Interlining material according to one or more of claims 1 to 4, d a d u r c h g e k e n n z e i c h n e t, that the coating can be fixed in 12 to 30, in particular 13 to 18 seconds.
  • Running and printing aids A 7.0-9.0
  • a copolyamide scattering powder according to the invention is sprinkled onto this sub-point paste, which has a higher melting point than the copolyamide of the sub-point paste.
  • the following example 2 shows a particularly good sub-point paste composition in% by weight.
  • Thickener / 4.0 aqueous preparation of dispersant, water-soluble polyamides, neutralized polyacrylic acid, little wetting agent and paraffin oil
  • Copolyamide powder 31.0 crosslinker based on iso- with amino group cyanate is built into the copolyamide active crosslinker
  • Copolyamide additionally 0.001% by weight lithium salt for detection
  • a copolyamide powder selected in accordance with the invention is sprinkled onto the sub-point paste in a manner known per se, which results in the colon coating.
  • thermoset paste known per se can also be used, which has a somewhat higher melting point than the copolyamide scattering.
  • the known colon coating is varied or supplemented.
  • a copolyamide powder is added to the preparation of the sub-point paste, in particular a thermoset preparation, preferably in amounts of 25 to 35% by weight and preferably in a fineness of 0 to 80 ⁇ m.
  • a copolyamide powder selected according to the invention is expediently used, and in particular the copolyamide which is scattered on is used.
  • the powder can be in the form of the grain belt. of the scattered powder or with grain sizes used to make the paste.
  • the amount added should be selected so that the properties of the sub-point mass are not significantly affected. Amounts of between 5 and 15% by weight, in particular between 6 and 11% by weight, are preferably added.
  • the copolyamide scattering powder for the colon coating is mixed with small amounts of a powder from the sub-point material, expediently with the same amounts as when the copolyamide powder is added to the sub-point paste.
  • the grain size preferably corresponds to the grain size of the copolyamide powder.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Details Of Garments (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne un matériau d'entoilage fixable comprenant un revêtement à base d'un copolyamide qui répond aux exigences les plus pointues en termes de traitements d'entretien et qui permet d'effectuer des traitements de finition tels que la teinture de vêtements, le délavage à la pierre, le lavage enzymatique et la décoloration, indépendamment du substrat sur lequel il est appliqué. Ledit revêtement comprend essentiellement les composants polycaprolactame (polyamide 6, PA 6) et/ou polyundécanamide (polyamide 11, PA 11) et/ou polyaurinelactame (polyamide 12, PA 12) et/ou polyhexaméthylène adipinamide (polyamide 6.6, PA 6.6), le pourcentage en poids minimal et maximal de chacun desdits composants dans la composition ainsi formée étant défini dans le tableau (I). De préférence, les compositions sont sélectionnées de façon que les températures de fusion soient comprises entre 110 et 150 °C, notamment entre 120 et 145 °C. De préférence, le polyamide 12 et/ou 11 est combiné uniquement avec un seul des deux autres polyamides. La présente invention se rapporte en outre à un procédé de production de ce matériau d'entoilage, ainsi qu'à son utilisation.
PCT/EP2003/001670 2003-02-19 2003-02-19 Materiau d'entoilage fixable, ses procedes de production et son utilisation WO2004073436A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE10394096T DE10394096A5 (de) 2003-02-19 2003-02-19 Fixierbarer Einlagestoff sowie Verfahren zu seiner Herstellung und dessen Verwendung
AU2003208875A AU2003208875A1 (en) 2003-02-19 2003-02-19 Fixable interlining material, method for the production thereof, and use thereof
PCT/EP2003/001670 WO2004073436A1 (fr) 2003-02-19 2003-02-19 Materiau d'entoilage fixable, ses procedes de production et son utilisation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2003/001670 WO2004073436A1 (fr) 2003-02-19 2003-02-19 Materiau d'entoilage fixable, ses procedes de production et son utilisation

Publications (2)

Publication Number Publication Date
WO2004073436A1 true WO2004073436A1 (fr) 2004-09-02
WO2004073436A9 WO2004073436A9 (fr) 2004-11-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/001670 WO2004073436A1 (fr) 2003-02-19 2003-02-19 Materiau d'entoilage fixable, ses procedes de production et son utilisation

Country Status (3)

Country Link
AU (1) AU2003208875A1 (fr)
DE (1) DE10394096A5 (fr)
WO (1) WO2004073436A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006084700A1 (fr) * 2005-02-12 2006-08-17 Carl Freudenberg Kg Produit plat textile comprenant un revetement ameliore, sa production et son utilisation

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1329697A (en) * 1969-11-24 1973-09-12 Courtaulds Ltd Fusible fabric adhesive
FR2241604A1 (en) * 1973-08-21 1975-03-21 Windel Hermann Inner lining adhering to surfacing fabric when heated - impermeable base printed in patterns holds min. thermoplastic adhesive
GB1420497A (en) * 1972-03-23 1976-01-07 Kufner Textilwerke Kg Heat-sealable adhesive inserts for fabrics
US4696850A (en) * 1986-03-25 1987-09-29 Firma Carl Freudenberg Iron-on interlining composite of knit layer and nonwoven layer of similar structure
EP0343341A2 (fr) * 1988-05-25 1989-11-29 Hüls Aktiengesellschaft Doublures textiles thermocollantes
US5153064A (en) * 1990-10-16 1992-10-06 Kufner Textilwerke Gmbh Hot-melt adhesive substance for the raster-pattern coating of fabrics, especially of lining materials
US5290594A (en) * 1991-02-05 1994-03-01 Lainiere De Picardie Method for production of thermoadhesive fabric coverings, thermoadhesive fabric covering
EP0927523A1 (fr) * 1997-10-22 1999-07-07 Hänsel Textil GmbH & Co. Double textile thermocollante ainsi que procédé et dispositif pour sa production
US6300413B1 (en) * 1998-03-03 2001-10-09 Degussa-Huels Aktiengesellschaft Crosslinking base layer for bondable interlinings in accordance with the double dot tech technique
US6344238B1 (en) * 1999-04-13 2002-02-05 Firma Carl Freudenberg Process for the production of fusible interlining fabrics
US20020019185A1 (en) * 2000-06-08 2002-02-14 Peter Grynaeus Fixing liner

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1329697A (en) * 1969-11-24 1973-09-12 Courtaulds Ltd Fusible fabric adhesive
GB1420497A (en) * 1972-03-23 1976-01-07 Kufner Textilwerke Kg Heat-sealable adhesive inserts for fabrics
FR2241604A1 (en) * 1973-08-21 1975-03-21 Windel Hermann Inner lining adhering to surfacing fabric when heated - impermeable base printed in patterns holds min. thermoplastic adhesive
US4696850A (en) * 1986-03-25 1987-09-29 Firma Carl Freudenberg Iron-on interlining composite of knit layer and nonwoven layer of similar structure
EP0343341A2 (fr) * 1988-05-25 1989-11-29 Hüls Aktiengesellschaft Doublures textiles thermocollantes
US5153064A (en) * 1990-10-16 1992-10-06 Kufner Textilwerke Gmbh Hot-melt adhesive substance for the raster-pattern coating of fabrics, especially of lining materials
US5290594A (en) * 1991-02-05 1994-03-01 Lainiere De Picardie Method for production of thermoadhesive fabric coverings, thermoadhesive fabric covering
EP0927523A1 (fr) * 1997-10-22 1999-07-07 Hänsel Textil GmbH & Co. Double textile thermocollante ainsi que procédé et dispositif pour sa production
US6300413B1 (en) * 1998-03-03 2001-10-09 Degussa-Huels Aktiengesellschaft Crosslinking base layer for bondable interlinings in accordance with the double dot tech technique
US6344238B1 (en) * 1999-04-13 2002-02-05 Firma Carl Freudenberg Process for the production of fusible interlining fabrics
US20020019185A1 (en) * 2000-06-08 2002-02-14 Peter Grynaeus Fixing liner

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006084700A1 (fr) * 2005-02-12 2006-08-17 Carl Freudenberg Kg Produit plat textile comprenant un revetement ameliore, sa production et son utilisation
CN101120136B (zh) * 2005-02-12 2012-06-13 卡尔弗罗伊登柏格两合公司 具有改善的涂层的纺织平面构型物及其制造和应用
US8603926B2 (en) 2005-02-12 2013-12-10 Carl Freudenberg Kg Textile fabric with improved finish, production and use thereof

Also Published As

Publication number Publication date
WO2004073436A9 (fr) 2004-11-25
AU2003208875A1 (en) 2004-09-09
DE10394096A5 (de) 2007-08-02

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