WO2004048067A1 - 型内被覆成形方法及び型内被覆成形品 - Google Patents
型内被覆成形方法及び型内被覆成形品 Download PDFInfo
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- WO2004048067A1 WO2004048067A1 PCT/JP2003/015033 JP0315033W WO2004048067A1 WO 2004048067 A1 WO2004048067 A1 WO 2004048067A1 JP 0315033 W JP0315033 W JP 0315033W WO 2004048067 A1 WO2004048067 A1 WO 2004048067A1
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- Prior art keywords
- mold
- clamping force
- coating
- resin
- mold cavity
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 93
- 229920005989 resin Polymers 0.000 claims abstract description 199
- 239000011347 resin Substances 0.000 claims abstract description 199
- 239000011248 coating agent Substances 0.000 claims abstract description 179
- 238000000576 coating method Methods 0.000 claims abstract description 131
- 238000000465 moulding Methods 0.000 claims description 61
- 238000002347 injection Methods 0.000 claims description 54
- 239000007924 injection Substances 0.000 claims description 54
- 238000007493 shaping process Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 abstract description 25
- 239000002184 metal Substances 0.000 abstract 6
- 239000003973 paint Substances 0.000 description 71
- 239000000463 material Substances 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 13
- 238000010586 diagram Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 238000005259 measurement Methods 0.000 description 9
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 8
- 230000006399 behavior Effects 0.000 description 7
- 229920005992 thermoplastic resin Polymers 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 238000003892 spreading Methods 0.000 description 3
- 241000255925 Diptera Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 101001012040 Pseudomonas aeruginosa (strain ATCC 15692 / DSM 22644 / CIP 104116 / JCM 14847 / LMG 12228 / 1C / PRS 101 / PAO1) Immunomodulating metalloprotease Proteins 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/76—Measuring, controlling or regulating
- B29C45/7653—Measuring, controlling or regulating mould clamping forces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1679—Making multilayered or multicoloured articles applying surface layers onto injection-moulded substrates inside the mould cavity, e.g. in-mould coating [IMC]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/46—Means for plasticising or homogenising the moulding material or forcing it into the mould
- B29C45/56—Means for plasticising or homogenising the moulding material or forcing it into the mould using mould parts movable during or after injection, e.g. injection-compression moulding
- B29C45/561—Injection-compression moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76003—Measured parameter
- B29C2945/761—Dimensions, e.g. thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76494—Controlled parameter
- B29C2945/76498—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76494—Controlled parameter
- B29C2945/76505—Force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76494—Controlled parameter
- B29C2945/76568—Position
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76655—Location of control
- B29C2945/76702—Closure or clamping device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76655—Location of control
- B29C2945/76775—Fluids
- B29C2945/76785—Fluids hydraulic fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
- B29C2945/76—Measuring, controlling or regulating
- B29C2945/76822—Phase or stage of control
- B29C2945/76869—Mould clamping, compression of the cavity
Definitions
- a coating agent (sometimes referred to as paint) is injected between the resin molded product and the mold capty surface and cured, whereby the surface is coated with the coating agent.
- the present invention relates to an in-mold coating molding method and an in-mold coating molded product to be coated (sometimes referred to as a coating film), and is particularly suitable for forming a molded product having a uniform appearance with a uniform coating thickness.
- the present invention also relates to an in-mold coating molding method and an in-mold coating molded article formed by the in-mold coating molding method.
- decorating by a painting method has been often used as a method of improving the decorativeness of a resin molded product formed of a thermoplastic resin.
- the conventional coating method is to apply a paint to the surface of a molded product by spraying, dipping, etc., after taking out the molded product from the injection molding in the mold.
- the applied paint is then dried to form a strong coating, which covers the surface of the molded article, and decorates and protects the surface.
- the coating agent is sometimes used as a synonym for paint in the following.
- FIG. 12 shows a flowchart of an example of the in-mold coating forming method.
- a thermoplastic resin as a base material is injection-molded in a mold, the resin is cooled to a certain extent, and then the mold is opened slightly.
- a gap is formed between the resin molded product formed in the mold and the cavity surface of the mold, and the paint is injected into the gap using a paint injector. After that, the mold is formed by clamping the mold again.
- This is an in-mold coating molding method characterized by uniformly spreading the paint on the surface of the product, then curing and coating.
- the cost can be reduced by omitting the process, and at the same time, the floating dust is removed before drying. It is possible to obtain a high quality product with almost no fouling such as adhesion to a coating (sometimes called a coating film) and failure.
- the use of the in-mold coating molding method is being studied particularly for automobile parts that require high quality in appearance, such as bumpers, doors, door mirror covers, and fenders.
- Patent Document 1 Japanese Patent Application Laid-Open No. 11-27757
- Patent Document 2 Japanese Patent Application Laid-Open No. 2000-141407
- Patent Document 3 Japanese Patent Application Laid-Open Publication No. 2000-0-3334800
- Patent Document 4 Japanese Patent Application Laid-Open No. 2001-389737
- One of the causes of non-uniform coating is that the resin molded in the mold has a reduced volume due to thermal shrinkage. If the thickness of the molded product becomes thin due to thermal shrinkage, the resin molded product and the cavity surface in the cavity A gap is formed between the layers, and the gap cannot be filled with the amount of the paint injected corresponding to a desired film thickness. As a result, paint does not spread over the entire coated surface, and the coating is not uniform.
- Another cause of non-uniform coating is the deformation of the mold during molding.
- the mold usually has high rigidity, but when the mold is clamped by the mold clamping device, it is deformed on the order of several / several tens / im level. This degree of deformation is not a problem in ordinary resin molding, but in the in-mold coating molding method, the surface of the resin It is common to apply a coating agent with a certain thickness, and a change in the mold cavity shape due to the deformation of the mold is one of the causes of the non-uniform thickness of the coating agent.
- the resin molded product molded under general injection molding conditions is caused by the heat shrinkage of the molten resin filled in the mold cavity. Even if the mold is not opened, a gap may be formed between the mold cavity surface and the resin molded product. Since the size of the gap varies in various ways depending on the shape of the mold cavity and the thickness of the resin molded product, uniform voids are hardly generated on the entire coated surface. Therefore, when performing the in-mold coating molding method, it is necessary to secure the minimum thickness of the coating agent by opening the mold, but if the mold is opened, the gap due to the heat shrinkage and the opening of the mold The portion where the gap is combined causes a problem that the thickness of the coating becomes extremely large.
- An object of the present invention is to provide an in-mold covering molding method suitable for molding a molded article having a good appearance, and an in-mold covering molded article molded by the in-mold covering molding method.
- the in-mold coating molding method according to the present invention is:
- an in-mold coating forming method for controlling a mold clamper such that deformation of a mold due to mold clamping in the second step and the fourth step is substantially the same This is referred to as a first aspect of the invention.
- the mold clamps used in the second step and the fourth step are substantially the same.
- substantially the same mold clamping force means that the difference between mold pressures obtained by dividing the mold clamp by the projected area of the mold cavity between mold clamps to be compared is preferably 5 MPa or less. Means within 3 Mpa, more preferably within IMpa.
- the mold clamping force for clamping the mold in the fourth step may provide a pressure per unit area applied to the coating agent in a range of 1 to 20 MPa, more preferably 1 to 10 MPa. It is preferable to be in the range of MPa.
- the mold clamping force used in the second step may be smaller than the mold clamping force used in the first step, and more preferably, the mold clamping force used in the first step. It is preferred to use a clamping force of 10 to 50% of the force, even more preferably 10 to 25%.
- a resin molded article is formed in a mold cavity using a mold having a mold cavity formed by a male mold and a female mold, and the surface of the resin molded article is molded.
- a mold clamping force for clamping the mold in the second step an in-mold coating forming method using a mold clamping force smaller than the mold clamping force for clamping the mold in the first step is provided. You.
- the mold clamping force for clamping the mold in the second step is 10 to 50% of the mold clamping force for clamping the mold in the first step, more preferably 10 to 50%. 25%.
- the mold clamper for clamping the mold in the second step has a range of 2 to 15 MPa, more preferably 4.0 when expressed in terms of an in-mold pressure per unit area. MP10 MPa.
- the mold clamp for clamping the mold in the second step is substantially the same as the mold clamp for clamping the mold in the third step.
- This embodiment is referred to as a third embodiment of the present invention.
- the mold clamps used in the second step and the third step are substantially the same.
- the mold clamping force for clamping the mold in the third step increases a pressure per unit area applied to the coating agent in a range of 1 to 20 MPa, more preferably 1 to 10 MPa. It is preferable to be in the range of MPa.
- the mold clamping force used in the second step The mold clamping force used in the first step is smaller than the mold clamping force, more preferably 0.10 to 50% of the mold clamping force used in the first step, and still more preferably It is preferred to use a clamping force of between 10 and 25%.
- a resin molded article is formed in the mold cavity using a mold having a mold cavity formed by a male mold and a female mold, and the resin molded article is molded.
- the in-mold coating molding method of coating the surface In the in-mold coating molding method of coating the surface,
- a third step of injecting the coating agent into the mold is performed. The mold clamping force for clamping the mold in the second step is smaller than the mold clamping force for clamping the mold in the first step.
- the mold clamping force for clamping the mold in the second step is 10 to 50% of the mold clamping force for clamping the mold in the first step, more preferably 10 to 50%. 25%.
- the mold clamper for clamping the mold in the second step has a range of 2 to 15 MPa, more preferably 4.0 when expressed in terms of an in-mold pressure per unit area. MP10 MPa.
- substantially the same mold clamping force means that the difference between the mold pressures obtained by dividing the mold clamp by the projected area of the mold cavity is within 5 MPa, between the mold clamps to be compared. Means within 3 Mpa, more preferably within IMpa.
- the first step includes moving the movable mold to a position where a mold cavity having a predetermined volume is formed, and then operating the injection device to operate the mold cavity.
- the process includes an operation of injecting the molten resin into the mold and further moving the movable mold to a desired position after the completion of the injection.
- the second step includes: After filling the molten resin, the volume of the mold cavity is reduced while adjusting to the thermal shrinkage of the injected molten resin due to cooling, and the operation of forming the resin molded product by injecting and solidifying the resin is performed. Includes steps.
- the third step is a step in which, at the end of the second step, the resin molded article has solidified to a level that can withstand the injection pressure and the flow pressure of the coating agent, This refers to a step of moving the movable mold, slightly opening the mold, and forming a gap between the resin molded product and the mold cavity surface.
- the third step is defined as a stage at the end of the second step, at which the resin molded product has solidified to the extent that it can withstand the injection pressure and the flow pressure of the coating agent.
- This refers to a process including an operation of injecting a covering agent between the resin molded product and the mold cavity surface while maintaining the state.
- the fourth step is to inject a coating material into the void formed in the third step, and then re-clamp the mold. This refers to the process including the operation of curing the coating agent.
- FIG. 1 is a structural diagram showing a schematic structure for explaining a configuration of an in-mold coating forming die according to a first embodiment of the present invention.
- FIGS. 2A to 2D are conceptual diagrams illustrating the behavior of a mold, a resin, and a paint in the in-mold coating forming method according to the first embodiment of the present invention.
- FIG. 3 is an overall configuration diagram illustrating the overall configuration of the in-mold coating forming apparatus used in the present invention.
- FIG. 4 is a structural diagram showing a schematic structure for explaining the configuration of the mold for in-mold coating molding used in the second embodiment according to the present invention.
- 5 (a) to 5 (d) are conceptual diagrams illustrating the behavior of a mold, a resin, and a paint in the in-mold coating forming method according to the second embodiment of the present invention.
- FIG. 6 is a flowchart of the in-mold coating forming method according to the first and second embodiments of the present invention.
- FIG. 7 shows resin moldings obtained in Examples 1 to 3 of the present invention and Comparative Examples 1 to 3.
- FIG. 3 is a drawing showing measurement points of the coating film thickness in the product, and is a projection view when the resin molded product is projected from the opening and closing direction of the mold.
- FIG. 8 is a drawing showing the cross-sectional shapes of the resin molded products molded in Example 8 of the present invention and Comparative Example 6, and the measurement points of the coating film thickness are indicated by arrows, respectively.
- FIG. 9 is a graph showing the variation of the coating film thickness ( ⁇ m) at each measurement point of the resin molded product molded in Example 8 of the present invention and Comparative Example 6.
- 10 (a) to 10 (d) are conceptual diagrams illustrating the behavior of a mold, a resin, and a paint according to the related art.
- FIGS. 11 (a) to 11 (d) are conceptual diagrams illustrating the behavior of a mold, resin, and paint according to another conventional technique.
- FIG. 12 is a flowchart of an in-mold coating forming method according to a conventional method.
- FIG. 1 is a structural diagram showing a schematic structure for explaining a configuration of an in-mold coating forming die used in the present embodiment
- 2 (a) to 2 (d) are conceptual diagrams illustrating the behavior of a mold, a resin, and a coating in the in-mold coating forming method according to the present embodiment
- FIG. 3 is an overall configuration diagram illustrating the overall configuration of the in-mold coating forming apparatus used in the present embodiment.
- FIGS. 4 and 5 (a) to (d) relate to the second embodiment of the present invention
- FIG. 4 is a schematic view for explaining the configuration of the mold for in-mold coating molding used in the second embodiment.
- Fig. 5 is a structural diagram showing the structure, and Figs. 5 (a) to 5 (d) show in-mold coating forming according to the second embodiment.
- FIG. 3 is a conceptual diagram illustrating behaviors of a mold, a resin, and a paint in the method.
- FIG. 6 is a flowchart of the in-mold coating forming method according to the first and second embodiments of the present invention.
- FIG. 4 is a schematic view for explaining the configuration of the mold for in-mold coating molding used in the second embodiment.
- Fig. 5 is a structural diagram showing the structure
- Figs. 5 (a) to 5 (d) show in-mold coating forming according to the second embodiment.
- FIG. 3 is a conceptual diagram illustrating behaviors of a mold, a resin,
- FIG. 7 is a drawing showing measurement points of the coating film thickness in the resin molded products molded in Examples 1 to 3 of the present invention and Comparative Examples 1 to 3, wherein the resin molded product is opened and closed in a mold opening and closing direction.
- FIG. 4 is a projection view when projected from FIG.
- FIG. 8 is a drawing showing a cross-sectional shape of a resin molded product molded in Example 8 of the present invention and Comparative Example 6, and measurement points of the coating film thickness are indicated by arrows, respectively.
- Fig. 9 is a graph showing the variation of the coating film thickness (a) at each measurement point of the resin molded article molded in Example 8 of the present invention and Comparative Example 6.
- Fig. 10 (a) Fig. 11 (a) to Fig. 11 (a) to Fig. 11 (d) are conceptual diagrams illustrating the behavior of the mold, resin and paint according to the conventional technology. It is a flowchart.
- mold apparatus for in-mold coating molding 1 OA (sometimes referred to as mold 1 OA) used in the first embodiment of the present invention will be briefly described below with reference to FIG. I do.
- the mold 1OA includes a movable mold 14A, a fixed mold 12A, and a paint injection machine 50.
- the movable type 14A is a female type
- the fixed type 12A is a male type.
- the shape of the mold cavity 15A is a flat plate as shown in FIG.
- the paint injection machine 50 in the present embodiment is attached to the movable mold 14 A, and has a mold cavity 15 A through a paint inlet 51 provided on the mold cavity surface of the movable mold 14 A. It is configured so that paint can be injected into the interior.
- a valve (not shown) is attached to the paint injection port 51 of the paint injection machine 50. At the time of injection molding of the base material, the valve is closed, so that the mold of the mold 1OA is formed. The resin injected into the cavity 15A is prevented from entering the paint injector 50 through the paint inlet 51.
- the paint injector 50 according to the present embodiment is driven by a drive device (not shown) to accurately and accurately supply the paint supplied into the paint injector 50 by a desired amount.
- the paint pouring machine 50 in the present embodiment is configured to inject paint from the mold cavity surface of the movable mold 14A as described above, the present invention is not limited to this. It is sufficient if the paint can be injected into the gap created between the resin molded product molded in 5 A and the mold cavity surface, and if that condition is satisfied, the paint injector 50 can be used as a fixed mold 12 A It may be attached to, for example.
- the mold 1OA is closed by the mold clamping device 20 to form the mold cavity 15A.
- the volume of the mold cavity 15 A is set to be larger than the dimensional volume of the resin molded product to be described later by an amount corresponding to the heat shrinkage of the molten resin.
- the mold 1OA it is necessary to reduce the volume of the mold cavity 15A by the amount of heat shrinkage of the molten resin in a step described later.
- a configuration arrangement is required. For example, by using a mold having the above-mentioned mating structure shown in Fig. 1, the volume of the mold cavity 15A can be reduced by the amount of heat shrinkage after the injection of the molten resin. It is necessary to arrange the fixed type 12 A and the movable type 14 A so that they can be used.
- the thermoplastic resin as the base material is injected into the mold cavity 15A in a molten state (in the present embodiment, the heat-resistant ABS resin as the base material: UT manufactured by UM GA BS) 20 B was used.)
- the mold cavity 15A is provided in a toggle mold clamping mechanism 23 (not shown) in order to keep the volume of the mold 15A from changing as much as possible.
- the hydraulic pressure of the mold clamping cylinder 22 (not shown) was adjusted, and the position of the movable plate 28 (not shown) was controlled to be constant during injection.
- the surface pressure per unit area divided by MmaX is calculated by the following equation 1. The result was 50 MPa (megapascal).
- the surface pressure ma X depends on many factors such as the shape and size of the molded product, the type of resin, the melting temperature, and the like. Or, excluding the injection press method, it is generally at least 3 OMPa or more.
- the position of the movable platen 28 is controlled so that the volume of the mold cavity 15 A does not change as much as possible.
- the mold clamping control method is not limited to this.
- the mold clamping device When filling the molten resin, the mold clamping device is designed so that the volume of the mold cavity 15 A increases by opening the mold 1 OA by the filling pressure of the molten resin. It may be controlled.
- the process proceeds to the second step, in which the molten resin is cooled and solidified to a degree that can withstand the injection pressure of the coating agent described below.
- the volume of the mold cavity 15 A is, at the time immediately after the completion of the injection of the molten resin, at least as large as the amount of heat shrinkage of the molten resin with respect to the dimensional volume of the resin molded product described later. is there.
- the mold clamper in the second step, the mold clamper is changed from the first step, and the mold clamper is set to 100 KN (kilonewton).
- the surface pressure per unit area divided by the area S (20.0 cm 2 in the first embodiment) was set to 5 MPa.
- the mold 1OA When the mold 1OA is clamped in this state, the mold 1OA is gradually closed in accordance with the heat shrinkage of the molten resin in the mold cavity 15A, and the molten resin is formed.
- the process proceeds to the third step, where the mold is slightly opened as shown in FIG. 2 (c) (in the first embodiment, the movable mold is moved by about l mm in the mold opening direction). As a result, a gap is created between the resin molded product molded in the mold cavity 15A and the mold cavity surface of the movable mold 14A.
- the paint is injected into the mold capacity 15A from the paint inlet 51 by the paint injection machine 50 into the mold cap 2Om. Begins to flow.
- the coating surface area of the molded article molded by the mold used in this embodiment is 2000 cm 2 , and the thickness of the coating film is about 0.1 mm.
- the paint used in the first embodiment is Pledge # 800: white (manufactured by Dainippon Paint Co., Ltd.).
- the fourth step move the movable mold 14 A in the direction of the fixed mold 12 A, close the mold 1 OA again and close the mold as shown in Fig. 2 (d).
- the paint in the gap is made to flow while spreading, and the molded product surface is covered with the paint.
- the surface pressure per unit area obtained by dividing the mold clamp by the projected area S of the resin molded product, with the mold clamp set to 100 KN. ) was set to 5 MPa.
- the advantages of the in-mold coating method according to the first embodiment will be described below.
- the volume of the mold cavity 15 A is reduced in accordance with the heat shrinkage of the molten resin in the second step, most of the surface on which the resin molded product is coated is reduced.
- the mold is always pressed against the mold cavity until immediately before the coating is applied.
- the shape of the mold cavity surface can be transferred with high accuracy, and the conventional problem that the thickness of the coating agent is not uniform can be effectively prevented.
- the mold clamping force in the second step which determines the shape of the resin molded product, is set to be substantially the same as the mold clamping force in the fourth step.
- the reason why the thickness of the coating agent is not uniform is deformation of the mold during molding.
- the mold clamping force is substantially required. Should be the same.
- the shape of the mold cavity 15 is similarly deformed in the fourth step, so that the thickness of the coating agent is uniform. Has an excellent effect.
- the effect can be obtained by bringing the mold clamping force of the second step and the mold clamping force of the fourth step as close as possible, but the closer the distance is, the more the effect is improved.
- the difference between the surface ffi (pressure per unit area obtained by dividing the mold clamper by the projected area S of the resin molded product) in the second and fourth steps is assumed to be within 5 MPa
- the mold clamping force in the step 4 and the mold clamping force in the fourth step should be substantially the same, more preferably the surface pressure should be within 3 MPa, and most preferably the second step.
- the surface pressure in the fourth step is within IMPa.
- the pressure per unit area applied to the coating agent by the mold clamping force is preferably in the range of 1 to 2 OMPa, more preferably in the range of 1 to 1 OMPa. is there.
- in-mold coating forming die apparatus 10 also referred to as a die 10) used in the second embodiment will be briefly described below with reference to FIG.
- the mold 10 includes a movable mold 14, a fixed mold 12, and a paint injection machine 50, similarly to the mold 1 OA used in the first embodiment described above.
- the mold 12 and the movable mold 14 are fitted to each other at a fitting portion having a drilling structure, and a rolling portion is formed around the entire circumference of the mold cavity 15.
- the mold cavity shape of the mold 10 has a side wall portion extending along the mold closing direction on the outer periphery of the mold cavity 15 as shown in a cross section in FIG. It is a box shape.
- the mold 10 is formed by fitting the male fixed mold 12 and the female movable mold 14 at a fitting portion having a swirl structure, and in the fitted state, the mold cavity 15 is provided.
- A is formed, and a fitting portion (sometimes referred to as a drawing portion) of the drawing structure is formed over the entire circumference of the mold cavity 15.
- the resin filled in the mold cavity 15 in the mold 10 at the swirl portion can be prevented from leaking out of the mold 10.
- the in-mold coating forming method according to the second embodiment of the present invention will be described with reference to FIGS. 5 (a) to 5 (d).
- the mold 10 is closed by the mold clamping device 20 to form the mold cavity 15.
- the volume of the mold cavity 15 is made larger than the dimensional volume of the resin molded product by an amount corresponding to the amount of heat shrinkage of the molten resin, as in the first embodiment described above.
- the process proceeds to the second step, and the mold is formed in accordance with the heat shrinkage of the molten resin in the mold cavity 15. Close the mold 10 gradually.
- the clamping force in the second step is greatly reduced compared to the first step, and the surface pressure per unit area obtained by dividing the clamping force by the projected area S of the resin molded product is reduced.
- the mold clamping force in the second step is preferably set to 10 to 50%, more preferably 10 to 25% of the mold clamping force in the first step.
- the surface pressure M2 in the second step was set to 5 MPa corresponding to 10% of the surface pressure M1 in the first step.
- the process proceeds to the third step, and the mold is slightly opened as shown in FIG. 5 (c) (in this embodiment, the movable mold 14 is moved by about l mm in the mold opening direction). As a result, a gap (sometimes referred to as a gap) is generated between the resin molded product molded in the mold cavity 15 and the mold cavity surface of the movable mold 14.
- 25 ml (milliliter) of the coating material is injected into the mold cavity 15 from the paint injection port 51 by the paint injection machine 50, and the gap generated by the mold opening and the side wall portion are formed.
- the coating agent starts flowing into the voids generated in the above.
- the molded article molded in the present embodiment has a coating surface area of 250 cm 2 and a coating thickness of about 0.1 mm. Further, the coating agent used in the present embodiment is Praglas # 800: white (manufactured by Dainippon Paint Co., Ltd.).
- the process proceeds to the fourth step.
- the movable mold 14 is moved in the direction of the fixed mold 12 and the mold 10 is closed again to close the mold.
- the coating agent in the gap is made to flow while spreading, and the surface of the molded product is covered with the coating agent.
- the mold clamp is projected onto the resin molded product.
- the surface pressure per unit area divided by the area S is the surface pressure M 3, preferably such that the deformation of the mold cavities in the second step is substantially the same. Choose to be. In this embodiment, the same 5 MPa as in the second step was employed.
- the volume of the mold cavity 15 is reduced in accordance with the heat shrinkage of the molten resin, so that the resin molded product always has the mold cavity surface until immediately before coating. Is pressed.
- the surface of the resin molded product molded in such a state accurately transfers the shape of the mold cavity surface, so if the surface is clean and the thickness is not thinned partially due to heat shrinkage etc. It has the feature of. Therefore, it is possible to effectively prevent the conventional problem that the coating is not uniform because the thickness of the resin molded product becomes thin due to thermal shrinkage.
- the mold clamping force in the second step which determines the shape of the resin molded product, is significantly reduced as compared with the mold clamping force in the first step.
- another cause of the nonuniform thickness of the coating material is the deformation of the mold during molding.
- the deformation amount of the mold 10 is designed based on the mold clamping force P max in the first step, and therefore, the mold clamping force for clamping the mold in the second step is changed to the first step.
- a preferable range in which the effect can be confirmed in actual molding is that the mold clamping force for clamping the mold in the second step is 50% of the mold clamping force for clamping the mold in the first step.
- the range is as follows.
- the mold clamping force P max in the first step is designed based on the surface pressure, which is the pressure per unit area applied to the resin molded product.
- the surface pressure is designed to be 30 MPa or more.
- the pressure per unit area applied by the mold clamping force to the resin molded product in the second step is preferably 15 MPa or less, and more preferably 10 MPa or less in order to further enhance the effect.
- a more preferable range of the mold clamping force in the second step is a unit area.
- the pressure in the mold per unit is 2 to 15 MPa, more preferably 4 to 10 MPa.
- the pressure per unit area applied to the coating agent by the mold clamping force is preferably in the range of 1 to 2 OMPa, and more preferably in the range of 1 to L OMPa. That is.
- the mold 1OA is closed by a mold clamping device 20 (not shown) to form a mold cavity 15A.
- the volume of the mold cavity 15A is set to be larger than the dimensional volume of the resin molded product by an amount corresponding to the heat shrinkage of the molten resin, as in the above-described embodiment.
- the base material is formed by the injection device 30 (not shown in FIG. 2).
- the thermoplastic resin is injected into the mold cavity 15A (in the third embodiment, a heat-resistant ABS resin as a base material: UT20B manufactured by UMGABS).
- the mold clamping force for resin injection was 3000 KN.
- the process proceeds to the second step, as shown in Fig. 2 (b), until the molten resin is cooled and can withstand the injection pressure of the coating agent described below. Enter the solidification process.
- the volume of the mold cavity 15A is, at the time immediately after the completion of the injection of the molten resin, at least as large as the dimensional volume of the resin molded product described later, which is equivalent to the amount of heat shrinkage of the molten resin.
- the mold clamping force is changed from the first step, the mold clamping force is set to 1000 KN, and the projected area S of the resin molded product (the third embodiment In this case, the surface pressure per unit area divided by 2000 cm 2 was set to 5 MPa.
- the mold 1OA is clamped in this state, the mold 1OA is gradually closed and the molten resin is shaped in accordance with the heat shrinkage of the molten resin in the mold cavity 15A.
- the process proceeds to the third step, and the paint is injected into the mold cavity 15A from the paint inlet 51 by the paint injector 50 at 2 Om1.
- the paint injection pressure was set high, and the mold injection OA slightly opened the mold 1 OA, so that the paint flowed into the mold cavity 15A and the molded product surface was Cover with paint.
- the coating surface area of the molded article formed by the mold used in the third embodiment is 2000 cm 2 , and the thickness of the coating film is about 0.1 mm.
- the paint used in the present embodiment is Pluglas # 8000: white (manufactured by Dainippon Paint Co., Ltd.).
- the mold clamping force is set to 1000 KN, and the surface pressure per unit area obtained by dividing the mold clamping by the projection area S of the resin molded product is set to 5 MPa. I have.
- the mold 1OA is closed by a mold clamping device 20 (not shown) to form a mold cavity 15A.
- the volume of the mold cavity 15A is set to be larger than the dimensional volume of the resin molded product by an amount corresponding to the heat shrinkage of the molten resin, as in the above-described embodiment.
- the injection device 30 After forming a mold cavity that is larger than the dimensional volume of the resin molded product by the amount of heat shrinkage of the molten resin, the injection device 30 (not shown) removes the thermoplastic resin as the base material. Inject into molten mold cavity 15A in the molten state (in the fourth embodiment, heat-resistant ABS resin: UT20B manufactured by UMGAB S as the base material). Was set to 3000 KN. After the injection of the molten resin into the mold cavity 15A is completed, the process proceeds to the second step, as shown in Fig. 2 (b), where the molten resin is cooled to withstand the injection pressure of the coating agent described later. Enter the process of solidifying to the extent.
- the volume of the mold cavity 15 A is, at the time immediately after the completion of injection of the molten resin, at least as large as the amount of heat shrinkage of the molten resin with respect to the dimensional volume of the resin molded product described later. is there.
- the mold clamper in the second step, is changed from the first step, the mold clamper is set to 100 KN, and the projected area S (the in fourth embodiment has a surface pressure per unit area divided by 2 0 0 0 was cm 2) and 5 MP a.
- the mold 1OA is closed in this state, the mold 1OA is gradually closed in accordance with the heat shrinkage of the molten resin in the mold cavity 15A, and the molten resin is molded.
- the pressure when the clamping force is expressed as the in-mold pressure per unit area, it is preferable that the pressure be 15 MPa or less. In order to enhance the effect, it is preferable to set the pressure to 10 MPa or less.
- the mold pressure per unit area is in a range of 2 to 15 MPa.
- the process proceeds to the third step, in which 2 Oml of the paint is injected into the mold cavity 15A from the paint inlet 51 by the paint injector 50.
- the paint injection pressure was set high, and the mold injection OA opened the mold 1OA slightly to allow the paint to flow into the mold cavity 15A to form the molded product.
- the surface is covered with paint.
- the coated surface area of the molded article formed by the mold used in the fourth embodiment is 2000 cm 2 , and the thickness of the coating film is about 0.1 mm.
- the paint used in the present embodiment is Pluglas # 800: white (made by Dainippon Paint Co., Ltd.).
- the surface pressure per unit area obtained by dividing the mold clamp by the projection area S of the resin molded product and setting the mold clamp to 2000 KN is described. It is 10 MPa.
- Comparative Examples 1 and 2 where the mold clamping force in the second step exceeds 50% with respect to the mold clamping force (850 ton) in the first step, the variation in the thickness of the molded product was large, but it was 10%. In Examples 1 to 3, which are within the range of 50% to 50%, the variation in the thickness of the molded product is small. Further, in Comparative Example 3 in which the content was less than 10%, obvious sink marks were observed on the molded product surface.
- Example 4 to 7 and Comparative Examples 4 to 5 Using the same mold, change the mold clamping force in the second step and mold clamping force in the fourth step using heat-resistant ABS resin (UT20B manufactured by UMGABS)) and paint (Praglas # 8000 red manufactured by Dainippon Paint) Then, in-mold coating molding was performed. Table 2 shows the results of measuring the thickness of the coating film at this time.
- Example 8 in which the mold clamping force in the second step was controlled to be lower than the mold clamping force in the first step, the coating film was formed on the both end surfaces of the resin molded product. Although the thickness is close to the thickness of the coating film on the flat part of the resin molded product, in Comparative Example 6 where the mold clamp in the second step was the same as the mold clamp in the first step, the resin molding was performed. The thickness of the coating film on the vertical surfaces at both ends of the product was significantly thinner than the coating film thickness on the flat portion of the resin molded product.
- the resin molded product is constantly pressed against the mold cavity surface until immediately before coating is performed. And the mold surface is transferred well, A uniform coating can be applied to the entire coated surface of the fat molded product.
- the amount of deformation of the mold is reduced by reducing the mold clamping force in the second step, which determines the shape of the resin molded product, to 50% or less compared to the mold clamping force in the first step. And has an excellent effect that the thickness of the coating agent can be made uniform overall. Further, the mold clamping force in the second step, which determines the shape of the resin molded product, is adjusted in both steps so that the deformation of the cavities in the two steps is substantially the same.
- the mold cavities in the second step Even if the shape is slightly deformed by the mold clamper, the shape of the mold cavity is similarly deformed in the fourth step, so that the thickness of the coating agent is uniform, which is an excellent effect.
- the mold clamper in the second step described above is always expressed as the pressure in the mold per unit area because the resin molded product must always be pressed with the mold cavity until immediately before the resin molded product is coated. At this time, it is in the range of 2 to 15 MPa, preferably in the range of 4 to 1 OMPa.
- the pressure per unit area applied to the coating agent by the mold clamping force is preferably in the range of 1 to 2 OMPa, more preferably in the range of 1 to 1 OMPa. That is.
- the present invention is applicable not only to a method of injecting paint with the mold opened in advance, but also to an in-mold coating molding method in which the mold is opened by paint injection pressure. The effect of can be obtained.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003284685A AU2003284685A1 (en) | 2002-11-25 | 2003-11-25 | In-mold coat-forming method and in-mold-coated mold product |
CA002506193A CA2506193A1 (en) | 2002-11-25 | 2003-11-25 | In-mold coating method and in-mold-coated molded product |
US10/535,423 US7862758B2 (en) | 2002-11-25 | 2003-11-25 | In-mold coat-forming method |
JP2004555036A JP4182951B2 (ja) | 2002-11-25 | 2003-11-25 | 型内被覆成形方法 |
Applications Claiming Priority (2)
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JP2002-340369 | 2002-11-25 | ||
JP2002340369 | 2002-11-25 |
Publications (1)
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WO2004048067A1 true WO2004048067A1 (ja) | 2004-06-10 |
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ID=32375819
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PCT/JP2003/015033 WO2004048067A1 (ja) | 2002-11-25 | 2003-11-25 | 型内被覆成形方法及び型内被覆成形品 |
Country Status (7)
Country | Link |
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US (1) | US7862758B2 (ja) |
JP (2) | JP4182951B2 (ja) |
KR (1) | KR100969694B1 (ja) |
CN (1) | CN100475481C (ja) |
AU (1) | AU2003284685A1 (ja) |
CA (1) | CA2506193A1 (ja) |
WO (1) | WO2004048067A1 (ja) |
Cited By (6)
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KR100645728B1 (ko) | 2005-07-20 | 2006-11-14 | 현대모비스 주식회사 | 고광택 인젝션 클리어 코팅 방법 |
JP2008525212A (ja) * | 2004-12-24 | 2008-07-17 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | 基材を成形および被覆する方法 |
JP2008247045A (ja) * | 2002-11-25 | 2008-10-16 | Ube Machinery Corporation Ltd | 樹脂成形品の成形方法、樹脂成形品、型内被覆成形方法、及び型内被覆成形品 |
JP2012006222A (ja) * | 2010-06-24 | 2012-01-12 | Ube Machinery Corporation Ltd | 型内被覆成形用金型及び型内被覆成形方法 |
CN103382324A (zh) * | 2007-06-19 | 2013-11-06 | 赢创罗姆有限责任公司 | 用于利用反应注塑涂覆成型体的反应性混合物和经涂覆的成型体 |
JP2021180327A (ja) * | 2018-10-31 | 2021-11-18 | 日亜化学工業株式会社 | パッケージの製造方法および発光装置の製造方法 |
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CN101279312B (zh) * | 2007-04-05 | 2010-10-13 | 金宇轩 | 一种模内涂装方法及其装置 |
EP2139660B1 (en) * | 2007-04-27 | 2013-12-25 | Exatec, LLC. | Abrasion resistant plastic glazing with in-mold coating |
EP2144958B1 (en) | 2007-05-01 | 2012-01-11 | Exatec, LLC. | Encapsulated plastic panel and method of making the same |
US20080286537A1 (en) * | 2007-05-09 | 2008-11-20 | Christophe Lefaux | Pre-dry treatment of ink in decorative plastic glazing |
JP5565828B2 (ja) * | 2009-12-11 | 2014-08-06 | 株式会社富士精工 | 射出成形方法 |
DE102010023499A1 (de) * | 2010-06-11 | 2011-12-15 | Evonik Röhm Gmbh | Verfahren und Vorrichtung zur Herstellung eines beschichteten Trägerelements |
US9862842B2 (en) | 2012-02-29 | 2018-01-09 | Sabic Global Technologies B.V. | Infrared radiation absorbing articles and method of manufacture |
EP2781328B1 (de) * | 2013-03-21 | 2023-05-24 | SMP Deutschland GmbH | Verfahren zur Herstellung eines Verkleidungsbauteils |
CN108025474A (zh) * | 2015-09-25 | 2018-05-11 | 沙特基础工业全球技术有限公司 | 使用模具插入件进行模塑的方法及用于其的装置 |
CN112713159A (zh) * | 2020-12-24 | 2021-04-27 | 深圳市汇顶科技股份有限公司 | 制作图像传感器的方法、图像传感器、摄像头模组和电子设备 |
US20240261815A1 (en) * | 2023-02-08 | 2024-08-08 | Sonoco Development, Inc. | Coating devices and method for articles |
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- 2003-11-25 AU AU2003284685A patent/AU2003284685A1/en not_active Abandoned
- 2003-11-25 CA CA002506193A patent/CA2506193A1/en not_active Abandoned
- 2003-11-25 CN CNB2003801091671A patent/CN100475481C/zh not_active Expired - Fee Related
- 2003-11-25 WO PCT/JP2003/015033 patent/WO2004048067A1/ja active Application Filing
- 2003-11-25 KR KR1020057009368A patent/KR100969694B1/ko not_active IP Right Cessation
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Cited By (8)
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JP2008247045A (ja) * | 2002-11-25 | 2008-10-16 | Ube Machinery Corporation Ltd | 樹脂成形品の成形方法、樹脂成形品、型内被覆成形方法、及び型内被覆成形品 |
JP2008525212A (ja) * | 2004-12-24 | 2008-07-17 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | 基材を成形および被覆する方法 |
KR100645728B1 (ko) | 2005-07-20 | 2006-11-14 | 현대모비스 주식회사 | 고광택 인젝션 클리어 코팅 방법 |
CN103382324A (zh) * | 2007-06-19 | 2013-11-06 | 赢创罗姆有限责任公司 | 用于利用反应注塑涂覆成型体的反应性混合物和经涂覆的成型体 |
CN103382324B (zh) * | 2007-06-19 | 2017-05-10 | 赢创罗姆有限责任公司 | 用于利用反应注塑涂覆成型体的反应性混合物和经涂覆的成型体 |
JP2012006222A (ja) * | 2010-06-24 | 2012-01-12 | Ube Machinery Corporation Ltd | 型内被覆成形用金型及び型内被覆成形方法 |
JP2021180327A (ja) * | 2018-10-31 | 2021-11-18 | 日亜化学工業株式会社 | パッケージの製造方法および発光装置の製造方法 |
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Also Published As
Publication number | Publication date |
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KR20050086777A (ko) | 2005-08-30 |
CN100475481C (zh) | 2009-04-08 |
JP4992842B2 (ja) | 2012-08-08 |
JP2008247045A (ja) | 2008-10-16 |
US7862758B2 (en) | 2011-01-04 |
US20060097425A1 (en) | 2006-05-11 |
CN1741886A (zh) | 2006-03-01 |
KR100969694B1 (ko) | 2010-07-14 |
JP4182951B2 (ja) | 2008-11-19 |
JPWO2004048067A1 (ja) | 2006-03-23 |
AU2003284685A1 (en) | 2004-06-18 |
CA2506193A1 (en) | 2004-06-10 |
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