WO2004027132A1 - Electrically conductive thread - Google Patents
Electrically conductive thread Download PDFInfo
- Publication number
- WO2004027132A1 WO2004027132A1 PCT/DE2003/003059 DE0303059W WO2004027132A1 WO 2004027132 A1 WO2004027132 A1 WO 2004027132A1 DE 0303059 W DE0303059 W DE 0303059W WO 2004027132 A1 WO2004027132 A1 WO 2004027132A1
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- WO
- WIPO (PCT)
- Prior art keywords
- electrically conductive
- thread
- conductive yarn
- yarn
- elastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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Classifications
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
- D02G3/328—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/12—Threads containing metallic filaments or strips
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
Definitions
- the present invention relates to elastic, electrically conductive yarns, their use and methods for their production.
- EP 250 260 describes how thin wires in the core of a wound yarn are also covered by wrapping parallel wire and textile thread can be used.
- the central textile thread ensures tear resistance, while the thin wire running in parallel ensures the electrical conductivity of the yarn.
- such yarns are not particularly stretchable.
- CH 690 686 describes the production of a composite yarn from a textile fuse and monofilament metal thread.
- the fuse is fed a coated metal wire centrally.
- the melting coating glues the central wire to the spun textile covering.
- US 5 881 547 teaches the manufacture of a highly tear-resistant, electrically conductive yarn for use in fencing clothing. These yarns consist of a non-electrically conductive core thread and a double, cross wrap with stainless steel wire. Due to the large diameter of the stainless steel wires used, they are very stiff in the range between 0.6 mm and 1.2 mm, hardly stretchable and in no way elastic.
- US 4,776,160 and US 5,927,060 mention the use of flexible, stretchable core threads for the production of conductive yarns with good textile properties.
- US 4,776,160 mentions as materials for the core thread thermoplastics such as. B. nylon, polyester, rayon, acrylic, PEEK, PBS, PBI, polyolefins (PE, PP) and liquid crystalline polymers, polycarbonate, polyvinyl alcohol and aramid fibers. None of these materials has rubber-elastic properties.
- the preferably multifilament synthetic yarn described in US Pat. No. 5,927,060 can withstand an elongation of approximately 5% without changing the electrical conductivity.
- the textile core thread used there has no rubber-elastic properties.
- the weak winding with only 200 to 600 turns per meter allows only a small amount of stretch under the given conditions until the wrapping wire breaks.
- the yarns described last also have no rubber-elastic properties. Even if they can withstand small strains in the range of 3% to 5% without loss of electrical conductivity, significant residual strains remain. The yarns described last cannot survive elongations of more than 10% without tearing off or at least without loss of conductivity.
- the object of the invention is to provide yarns which are electrically conductive, which can be significantly stretched at least for a short time without loss of conductivity and which have improved elongation properties.
- the yarns according to the invention are made up of at least one elastic core thread, at least one electrically conductive thread wound around the core thread and at least one winding thread wound around the core thread.
- the elasticity of the entire electrically conductive yarn is limited by the winding thread.
- Such a conductive yarn has a number of improved properties.
- the yarn has elastic properties over a wide range of tensile stress.
- an overload due to tensile stress does not lead to a reduction in the conductivity of a yarn according to the invention. This is achieved by limiting the stretchability of the yarn by the thread. Limiting the elasticity of the wrapping thread also ensures that the yarn retains its elastic properties over its entire load range.
- the restoring force of the yarn increases disproportionately from a certain tensile load.
- the reason for this disproportionate increase in the restoring force lies in the thread. This is because from a certain tensile load this load can no longer yield to a smaller number of turns per unit length of the core thread by spreading its helical shape, but allows further stretching only by stretching in the longitudinal direction.
- the transition from an expansion of the helical structure to an actual stretching of the wrapping thread even in its longitudinal direction leads to a strong increase in the restoring force, which prevents further stretching of the yarn.
- This disproportionate increase in the restoring force takes place in the event of a tensile load in which the electrically conductive thread has not yet broken. So the yarn is still conductive.
- the degree of stretchability of the wrapping thread depends mainly on the material properties and the number of wraps of the wrapping thread around the core thread. A higher number of windings will generally achieved a higher elasticity. In addition, a higher elongation at break of the material leads to increased elasticity.
- the elongation at break of a material is the elongation of the material due to tensile stress until it breaks. It is used to determine the strength of the stressed material. A material with a high elongation at break can therefore be stretched by a large amount before it breaks or breaks in the case of threads.
- the extensibility of the entire electrically conductive yarn is limited by the winding thread.
- core thread, conductive thread and wrapping thread are expediently coordinated with one another with regard to material and with regard to the number of wraps of conductive thread and wrapping thread around the core thread.
- several other parameters known to those skilled in the field of yarn production are advantageously adapted.
- the elasticity also depends on the force with which the core thread is wound.
- the different thread materials also have different coefficients of friction, which means that a different amount of force is required in order to shift the individual threads against one another.
- the core thread consists of a rubber-elastic material.
- rubber-elastic material means that after deformation of the material and subsequent relief, the original state of the material is restored. According to DIN 7724 (February 1972), a distinction is made between two types of elasticity, namely energy elasticity (steel elasticity) and entropy elasticity ( rubber elasticity).
- the elastic core thread has an elongation at break of at least 50%, preferably at least 100%, particularly preferably at least 200%.
- the core thread very particularly preferably has an elongation at break of at least 300%, in particular at least 400%, particularly preferably at least 500%.
- the elastic core thread or threads are responsible for the rubber-elastic properties of the entire yarn unit.
- the market offers a variety of rubber elastic threads from which the material suitable for the respective application can be selected. These include natural and synthetic rubbers, the various types of polyester and polyether elastane, modified polyesters, post-crosslinked thermoplastics etc. Polyester-polyurethane elastomers and / or polyether-polyurethane elastomers are particularly suitable as materials for the rubber-elastic core thread.
- the yarns according to the invention should contract at least approximately again to the original length due to the rubber-elastic properties of the core thread.
- the electrically conductive yarn after elastic stretching by at least 15% in the longitudinal direction, has a maximum residual elongation of 5% without losing its electrical conductivity.
- the electrically conductive yarn has a maximum residual elongation of 5%.
- the core thread can be used in a form suitable for the respective application. Some variants are mentioned as examples: monofilament, multifilament, segmented types and textured types. If necessary, several threads can be used in parallel or twisted in the core. Similar or different threads can be used side by side.
- the elastic core of the composite yarn is equipped with at least one electrically conductive wrap.
- the elastic core can be wound several times with conductive threads. These conductive wraps can also be applied in different winding directions and optionally separated from one another by intermediate layers.
- conductive threads are metallic wires, wire threads or braids, conductively coated synthetic fibers, staple yarns with metal content, yarns made of conductive polymers and conductive filled synthetic fibers.
- the conductive threads can be used one or more times, single or mixed.
- Monofilament metal wires used as conductive threads have a diameter between 0.01 and 0.1 mm, preferably between 0.02 and 0.06 mm, particularly preferably between 0.03 and 0.05 mm.
- multifilament stainless steel yarns are extremely suitable for producing the yarns according to the invention.
- the thickness of a single stainless steel filament ranges between 0.002 mm and 0.02 mm.
- the number of individual filaments contained is between 10 and 200.
- the use of silver-coated synthetic yarns for electrically conductive wrapping around the elastic core is suitable for numerous applications. Wash-resistant, silver-coated nylon yarns are particularly suitable for producing the yarns according to the invention.
- the market offers both monofilament and multifilament games. With multifilament threads as a wrap, higher surface coverage of the core can be achieved with the same yarn diameter compared to monofilament fibers.
- the yarn includes another wrap.
- a winding can perform various functions. Examples include: electrical insulation (outside, inside or between several conductive layers), mechanical abrasion protection, improvement of the processability of the yarn on high-speed machines, color, gloss, optics, handle, haptics, over-stretch protection, tear resistance, compensation of the internal torsional tension of the yarn after winding in one direction. It should be pointed out that this further winding thread will generally not be electrically conductive. However, the present invention also encompasses wrapping threads that have an electrical conductivity of any strength.
- a yarn structure with an internal elastic core, inner wrapping with conductive thread and a textile outer wrapping in the opposite direction is suitable for numerous applications.
- the outer wrapping is designed so that it is fully tensioned in the event of a strong stretch in front of the inner conductive wrapping.
- the outer wrap slows down stretching before the conductive wrap is damaged.
- Further preferred embodiments of the yarn according to the invention include the use of multifilament yarns as a non-conductive wrap.
- multifilament games prefer to lie flat on the core thread, so that with the same outer diameter they provide a significantly higher surface coverage compared to the monofilament.
- all possible threads can be suitable for the further winding described.
- Representative of the possible materials may be mentioned as examples: nylon, polyester, viscose, polyamide, linen, wool, silk, cotton, polypropylene, Kevlar in the various embodiments, mixed yarns of all types and metallized game such as. B. silver coated nylon.
- the yarns according to the invention can be produced in various ways.
- the method of classic yarn winding is preferred.
- the central elastic thread is warped on a drafting system.
- the warped elastic core thread is passed through a rotating hollow spindle.
- the spool of thread with the conductive thread or the winding thread sits on the hollow spindle. This thread is carried along by the uniformly drawn-off elastic core thread, so that the conductive thread or the winding thread is wound in the form of a helix around the core thread. If the warped core thread relaxes again after winding, the individual wraps are much denser than during wrapping.
- Rubber-elastic yarns can be manufactured with a high warp compared to inelastic yarns, which leads to significantly narrower windings under otherwise identical production conditions due to the relaxation of the yarn after winding.
- Elastic yarns can be wrapped more tightly than non-elastic yarns using the method mentioned.
- the electrically conductive thread and the wrapping thread are wound in opposite directions around the elastic core thread. If, for example, the electrically conductive thread is wound around elastic core thread in the S direction, the wrapping thread is wound around the elastic core thread in the Z direction. So it is a cross-wrap.
- the present invention also includes the use of the yarns and fabrics according to the invention for data transmission and the power supply of electrical or electronic components.
- the use of the yarns and fabrics according to the invention as electrically conductive materials is also included, which, like a ribbon cable or a two-dimensional matrix that can be controlled in a spatially resolved manner, can transport different electrical signals next to one another without any appreciable mutual influence.
- yarns according to the invention or products made therefrom can be used to shield electromagnetic fields or to discharge static charges. It is possible to use the yarns according to the invention as a resistance conductor in the context of an electrical heater.
- the present invention also includes the use of the yarns according to the invention as an electrical heating conductor and the fabric made therefrom as an elastic, electrically heatable fabric.
- the present invention also includes the use of the yarns according to the invention as a sensor material, preferably as a moisture sensor or strain sensor. Ways of Carrying Out the Invention
- Lycra 163C manufactured of Lycra 163C (manufacturer: Du pont De Nemours International SA Fibers Department, Du Pont Straße 1, D-61352, Bad Homburg; product name: LYCRA Elastane Yarn; Dtex / type: 1880 Dtex T. 136C) with a thickness of 1880 dtex is pre-stretched on a yarn winding machine.
- the elongation at break of the thread is 500% with a tensile strength of 1300 cN. After a stretch of 100%, the thread relaxes to a residual stretch of 2.4%.
- the pre-stretched Lycra thread is passed through a hollow spindle.
- This hollow spindle carries a conical thread spindle, from which a 0.04 mm thick, hard silver-plated copper wire (manufacturer: Elektro-Feindraht AG in CH-8182 Escholzmatt; product name: Textile Wire silver / copper with varnish type TW-D) is drawn off by the lycra thread becomes.
- the diameter of the wire including its coating is 0.048 mm.
- the wire has an elongation at break of 21.3%.
- the Lycra which is simply wrapped in wire, is guided through a second hollow spindle.
- This hollow spindle carries a commercially available multifilament polyamide yarn made of PA66 with 78 dtex and 34 individual filaments (manufacturer: Radicifil S.p.A. / Synfil GmbH, IT-24126 Bergamo; designation RN01235_78 / 34 / 1S; elongation at break: 28%).
- the PA66 yarn is wound around the core in the opposite direction to the wire.
- the machine parameters are selected so that a balanced yarn is created that is as free as possible from internal torsional stresses.
- the outer PA66 yarn is wound around the core 3200 times per meter of yarn; the inner wire is wound around the core 3600 times per meter of yarn.
- the inside lying wire is almost completely covered by the outside PA66 yarn, so that the yarn has a textile look and feel.
- the yarn has excellent electrical conductivity. With a stretch of approx. 250%, the restoring force of the yarn becomes disproportionately stronger when the PA66 yarn is fully stretched. The yarn only loses its electrical conductivity due to wire breakage after approx. 300% elongation.
- the elastic, electrically conductive composite yarn from Example 1 is used as a weft thread on a commercially available weaving machine.
- the warp beam consists of 0.3 mm thick, simply twisted cotton threads, which are combined in groups of 8 threads.
- a firm fabric is created which has excellent electrical conductivity in the weft direction and does not conduct the electrical current in the direction of the warp thread. These electrical properties are retained even after stretching by more than 120% in the weft direction.
- the poles of a DC voltage source are connected at a distance in the warp thread direction, this voltage can be spaced one meter apart in the weft thread direction for operating an electrical consumer, such as, for. B.
- a light emitting diode can be used.
- the fabric can be stretched in the weft direction without affecting the power supply to the light emitting diode.
- the elastic, electrically conductive composite yarn from Example 1 is used as a weft thread on a commercially available weaving machine.
- the warp beam consists of an electrically conductive, but not rubber-elastic composite yarn.
- a commercially available polyester yarn with 100 dtex and 36 individual filaments is equipped with an inner winding made of 0.041 mm thick, hard silver-plated copper wire and an outer winding made of commercially available polyamide yarn (PA66) with 78 dtex and 34 individual filaments.
- PA66 polyamide yarn
- Weaving creates a strong fabric that has excellent electrical conductivity in the weft direction and an independent electrical conductivity in the direction of the warp thread. These electrical properties are retained even after stretching by more than 120% in the weft direction.
- This fabric which is inexpensive to manufacture, can be used with a corresponding electronic control as a matrix for spatially resolving signal acquisition or for operating a spatially resolving output unit such as, for. B. a screen can be used.
- Lycra 163C Du Pont de Nemours GmbH, Du Pont Straße 1, D-61352, Bad Homburg
- 1880 dtex is pre-stretched on a yarn winding machine.
- the pre-stretched Lycra thread is passed through a hollow spindle.
- This hollow spindle carries a conical thread spindle, from which a silver-coated polyamide thread with 30 denier and 18 individual filaments (X-static, Life SRL, 1-25015 Desenzano, Italy) is pulled off through the lycra thread.
- the Lycra simply wrapped with the silver-coated fiber, is guided through a second hollow spindle.
- This hollow spindle carries a commercially available multifilament polyamide yarn made of PA66 with 33 dtex and 10 individual filaments.
- the PA66 yarn is wound around the core in the opposite direction to the silver-coated fiber.
- the machine parameters are selected so that a balanced yarn is created that is as free as possible from internal torsional stresses.
- the outer PA66 yarn is wound around the core 3200 times per meter of yarn; the silver-coated thread is wound around the core 3600 times per meter of yarn.
- the inside silver-coated thread is not completely covered by the outside PA66 yarn.
- the yarn has excellent electrical conductivity. With a stretch of approx. 250%, the restoring force of the yarn becomes disproportionately stronger when the PA66 yarn is fully stretched.
- the yarns that envelop the Lycra core only tear at about 320% elongation.
- the elastic, electrically conductive composite yarn from Example 4 is used as a weft thread on a commercially available weaving machine.
- the warp beam consists of an electrically conductive, but not rubber-elastic composite yarn.
- a commercially available polyester yarn with 100 dtex and 36 individual filaments with an inner winding is made of a silver-coated polyamide thread with 30 denier and 18 individual filaments (X-static, Life SRL, 1-25015 Desenzano, Italy) and an outer winding commercial polyamide yarn (PA66) with 33 dtex and 10 single filaments.
- Weaving creates a strong fabric that has excellent electrical conductivity. Due to the incomplete insulation of the silver-coated wraps in both the warp and weft threads, all electrically conductive yarns in the fabric are in electrical contact with one another. This direction-independent electrical conductivity is retained even after stretching by more than 100% in the weft direction. Such a fabric has excellent shielding properties against electromagnetic radiation, in particular in the range from 1 to 2000 MHz.
- the elastic, electrically conductive composite yarn from Example 1 is used as a warp thread on a commercially available ribbon loom.
- the warp beam consists of sequences of 8 identical threads each. It is alternated between bundles of eight from the yarns described in Example 1 and those without a conductive portion.
- the threads without a conductive portion largely correspond to the yarns described in Example 1, except for the fact that a multifilament polyamide yarn made of PA66 with 78 dtex and 34 individual filaments is used instead of the wire.
- a commercially available multifilament polyamide yarn is used as the weft thread.
- the elastic band produced in this way has conductive strips which are present next to one another and are electrically insulated from one another.
- An elastic flat cable described in this example is ideal for connecting electrical or electronic components in clothing.
- the tape can be stretched in the warp direction without loss of electrical conductivity.
- the tape is not sensitive to the creases and folds that occur when wearing clothing.
- the elastic fabric which is electrically conductive in the weft direction from Example 2 is electrically contacted in the weft direction to a width of 1.1 cm and a length of 50 cm by means of commercially available ribbon cable plugs. After applying a DC voltage, electrical current flows. In the middle between the connection points, the temperature increase resulting from the current flow is determined using an NTC resistor. With a heating power of 5 W (1.4 A at 3.6 V), the temperature increase reached is already 30 ° C. With a heating current of 13 W (2 A at 6.5 V) the temperature increase is 64.5 ° C.
- the stretchability and the textile feel of the fabric make it ideal for the production of elastic, electrically heatable textiles that are in direct contact with the body.
- Examples of applications are socks, joint warmers, back warmers, gloves, elastic bandages etc.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Non-Insulated Conductors (AREA)
- Resistance Heating (AREA)
- Conductive Materials (AREA)
- Insulated Conductors (AREA)
- Multicomponent Fibers (AREA)
Abstract
Description
Elektrisch leitfähiges Electrically conductive
Technisches GebietTechnical field
Die vorliegende Erfindung betrifft elastische, elektrisch leitfähige Garne, deren Verwendung und Verfahren zu deren Herstellung.The present invention relates to elastic, electrically conductive yarns, their use and methods for their production.
Stand der TechnikState of the art
Es sind einige Verfahren zur Herstellung elektrisch leitfähiger Garne bekannt. So werden z. B. zur Ableitung elektrostatischer Aufladung seit langem Metalldrähte oder Drahtgeflechte bzw. metallisierte Garne direkt in Gewebe eingearbeitet. Diese Gewebe sind oft problematisch am Webstuhl zu fertigen und verfügen aufgrund der offen liegenden Drähte über eine nur eingeschränkt textile Optik und / oder einen metallischen Griff.Some methods for producing electrically conductive yarns are known. So z. B. for the discharge of electrostatic charge for a long time metal wires or wire mesh or metallized yarn incorporated directly into the fabric. These fabrics are often problematic to manufacture on the loom and, due to the exposed wires, have a limited textile appearance and / or a metallic handle.
Ferner sind Verfahren zur Herstellung von so genannten Stapelgarnen bekannt. Dabei werden im Wesentlichen kurze textile Fasern zusammen mit kurzen und sehr feinen Metallfasem zu einem Garn gesponnen. Je nach Metallgehalt besitzen diese Garne mehr oder weniger textile oder metallische Eigenschaften. Stapelgarne mit guter elektrischer Leitfähigkeit weisen eine metallische Optik und Haptik auf.Methods for producing so-called staple yarns are also known. Essentially short textile fibers are spun into a yarn together with short and very fine metal fibers. Depending on the metal content, these yarns have more or less textile or metallic properties. Stacking yarns with good electrical conductivity have a metallic look and feel.
Bekannt sind auch Verfahren, bei denen zentral geführte Metalldrähte einfach oder doppelt textil umwunden werden. Da in diesen Garnen im Wesentlichen der Draht die Reißfestigkeit bestimmt, werden meist relativ dicke Drähte mit Durchmessern größer 0,1 mm eingesetzt. Derartige Garne sind verhältnismäßig steif und deshalb für textile Anwendungen unbrauchbar.Methods are also known in which centrally guided metal wires are wrapped in single or double textiles. Since it is essentially the wire that determines the tensile strength in these yarns, relatively thick wires with diameters greater than 0.1 mm are usually used. Such yarns are relatively stiff and therefore unusable for textile applications.
Die EP 250 260 beschreibt, wie durch die Umwindung von parallel geführtem Draht und textilem Faden auch dünne Drähte im Kern eines umwundenen Garnes eingesetzt werden können. In dieser Anordnung sorgt der zentrale textile Faden für Reißfestigkeit, während der parallel laufende dünne Draht die elektrische Leitfähigkeit des Garns bewirkt. Derartige Garne sind aber nicht besonders gut dehnbar.EP 250 260 describes how thin wires in the core of a wound yarn are also covered by wrapping parallel wire and textile thread can be used. In this arrangement, the central textile thread ensures tear resistance, while the thin wire running in parallel ensures the electrical conductivity of the yarn. However, such yarns are not particularly stretchable.
In der CH 690 686 wird die Herstellung eines Verbundgarnes aus textiler Lunte und monofilem Metallfaden beschrieben. Während des Garnspinnprozesses auf einer Ringspinnmaschine wird der Lunte zentral ein beschichteter Metalldraht zugeführt. In der dem Spinnprozess nachgeschalteten thermischen Behandlung verklebt die schmelzende Beschichtung den zentralen Draht mit der gesponnenen textilen Umhüllung. Auch diese Garne weisen keine gute Dehnbarkeit auf.CH 690 686 describes the production of a composite yarn from a textile fuse and monofilament metal thread. During the yarn spinning process on a ring spinning machine, the fuse is fed a coated metal wire centrally. In the thermal treatment following the spinning process, the melting coating glues the central wire to the spun textile covering. These yarns also do not have good ductility.
Keines der oben beschriebenen Garne kann ohne Verlust der elektrischen Leitfähigkeit in nennenswertem Umfang elastisch gedehnt werden, da die leitfähigen Fäden entweder reißen oder sich plastisch verformen.None of the yarns described above can be elastically stretched to a significant extent without loss of electrical conductivity, since the conductive threads either tear or plastically deform.
In den Schriften US 4 776 160, US 5 881 547 und US 5 927 060 werden jeweils Garne beschrieben, bei denen elektrisch leitfähige Fäden um zentral angeordnete textile Fäden gewunden werden. Diese Anordnung ermöglicht prinzipiell eine gewisse Dehnung der gesamten Garneinheit, ohne ein Reißen des Garnes bzw. einen Bruch der leitfähigen Umwindung zu verursachen.The documents US 4,776,160, US 5,881,547 and US 5,927,060 each describe yarns in which electrically conductive threads are wound around centrally arranged textile threads. In principle, this arrangement allows the entire yarn unit to be stretched to a certain extent without causing the yarn to tear or the conductive wrap to break.
Die US 5 881 547 lehrt die Fertigung eines hochreißfesten, elektrisch leitenden Garns zum Einsatz in Fechtbekleidung. Diese Garne bestehen aus einem nicht elektrisch leitfähigen Kernfaden und einer doppelten, kreuzweisen Umwindung mit Edelstahldraht. Sie sind aufgrund des großen Durchmessers der verwendeten Edelstahldrähte im Bereich zwischen 0,6 mm und 1,2 mm sehr steif, kaum dehnbar und keinesfalls elastisch.US 5 881 547 teaches the manufacture of a highly tear-resistant, electrically conductive yarn for use in fencing clothing. These yarns consist of a non-electrically conductive core thread and a double, cross wrap with stainless steel wire. Due to the large diameter of the stainless steel wires used, they are very stiff in the range between 0.6 mm and 1.2 mm, hardly stretchable and in no way elastic.
Sowohl in der US 4 776 160 als auch in der US 5 927 060 wird die Verwendung flexibler, dehnbarer Kernfäden zur Herstellung leitfähiger Garne mit guten textilen Eigenschaften erwähnt. Die US 4 776 160 erwähnt als Materialien für den Kernfaden Thermoplaste wie z. B. Nylon, Polyester, Rayon, Acryl, PEEK, PBS, PBI, Polyolefine (PE, PP) und flüssigkristalline Polymere, Polycarbonat, Polyvinylalkohol und Aramidfasern. Keines dieser Materialien verfügt über gummielastische Eigenschaften.Both US 4,776,160 and US 5,927,060 mention the use of flexible, stretchable core threads for the production of conductive yarns with good textile properties. US 4,776,160 mentions as materials for the core thread thermoplastics such as. B. nylon, polyester, rayon, acrylic, PEEK, PBS, PBI, polyolefins (PE, PP) and liquid crystalline polymers, polycarbonate, polyvinyl alcohol and aramid fibers. None of these materials has rubber-elastic properties.
Das in der US 5 927 060 beschriebene, bevorzugt multifilamente synthetische Garn kann eine Dehnung um ca. 5% ohne Veränderung der elektrischen Leitfähigkeit ertragen. Der dort verwendete textile Kernfaden besitzt keinerlei gummielastische Eigenschaften. Darüber hinaus erlaubt die schwache Umwicklung mit lediglich 200 bis 600 Umwindungen pro Meter unter den gegebenen Bedingungen eine nur geringe Dehnung bis es zum Bruch des umhüllenden Drahtes kommt.The preferably multifilament synthetic yarn described in US Pat. No. 5,927,060 can withstand an elongation of approximately 5% without changing the electrical conductivity. The textile core thread used there has no rubber-elastic properties. In addition, the weak winding with only 200 to 600 turns per meter allows only a small amount of stretch under the given conditions until the wrapping wire breaks.
Auch die zuletzt beschriebenen Garne verfügen über keine gummielastischen Eigenschaften. Selbst wenn sie geringe Dehnungen im Bereich von 3% bis 5% ohne Verlust der elektrischen Leitfähigkeit überstehen können, so bleiben deutliche Restdehnungen übrig. Dehnungen um mehr als 10% können auch die zuletzt beschriebenen Garne nicht ohne Abriss oder zumindest ohne Verlust der Leitfähigkeit überstehen.The yarns described last also have no rubber-elastic properties. Even if they can withstand small strains in the range of 3% to 5% without loss of electrical conductivity, significant residual strains remain. The yarns described last cannot survive elongations of more than 10% without tearing off or at least without loss of conductivity.
Es besteht daher weiterhin ein Bedarf an Garnen, die neben einer elektrischen Leitfähigkeit eine hohe Elastizität und verbesserte Dehnungseigenschaften aufweisen.There is therefore still a need for yarns which, in addition to having electrical conductivity, have high elasticity and improved elongation properties.
Darstellung der ErfindungPresentation of the invention
Hier setzt die Erfindung an. Der Erfindung, wie sie in den Ansprüchen gekennzeichnet ist, liegt die Aufgabe zugrunde, Garne bereitzustellen, die elektrisch leitfähig sind, die ohne Verlust der Leitfähigkeit zumindest kurzzeitig deutlich gedehnt werden können und die verbesserte Dehnungseigenschaften aufweisen.This is where the invention comes in. The object of the invention, as characterized in the claims, is to provide yarns which are electrically conductive, which can be significantly stretched at least for a short time without loss of conductivity and which have improved elongation properties.
Diese Aufgabe wird erfindungsgemäß durch das Garn gemäß Anspruch 1 gelöst. Weitere vorteilhafte Details, Aspekte und Ausgestaltungen der vorliegenden Erfindung ergeben sich aus den abhängigen Ansprüchen, der Beschreibung und den Beispielen. Die erfindungsgemäßen Garne sind aus zumindest einem elastischen Kernfaden, mindestens einen, um den Kernfaden gewundenen elektrisch leitfähigen Faden und mindestens einen, um den Kernfaden gewundenen Umwindefaden aufgebaut. Die Dehnbarkeit des gesamten elektrisch leitfähigen Garns wird durch den Umwindefaden begrenzt.This object is achieved by the yarn according to claim 1. Further advantageous details, aspects and configurations of the present invention result from the dependent claims, the description and the examples. The yarns according to the invention are made up of at least one elastic core thread, at least one electrically conductive thread wound around the core thread and at least one winding thread wound around the core thread. The elasticity of the entire electrically conductive yarn is limited by the winding thread.
Ein solches leitfähiges Garn besitzt eine ganze Reihe von verbesserten Eigenschaften. Das Garn weist über einen weiten Bereich einer Zugbeanspruchung elastische Eigenschaften auf. Im Gegensatz zu den aus dem Stand der Technik bekannten leitfähigen Garnen führt eine Überbelastung durch Zugbeanspruchung nicht zu einer Verminderung der Leitfähigkeit eines erfindungsgemäßen Garns. Dies wird durch die Begrenzung der Dehnbarkeit des Garns durch den Umwindefaden erreicht. Durch die Begrenzung der Dehnbarkeit durch den Umwindefaden wird zudem erreicht, dass das Garn über seinen ganzen Belastungsbereich seine elastischen Eigenschaften behält.Such a conductive yarn has a number of improved properties. The yarn has elastic properties over a wide range of tensile stress. In contrast to the conductive yarns known from the prior art, an overload due to tensile stress does not lead to a reduction in the conductivity of a yarn according to the invention. This is achieved by limiting the stretchability of the yarn by the thread. Limiting the elasticity of the wrapping thread also ensures that the yarn retains its elastic properties over its entire load range.
Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung nimmt die Rückstellkraft des Garns ab einer bestimmten Zugbelastung überproportional zu. Der Grund für diesen überproportionalen Anstieg der Rückstellkraft liegt in dem Umwindefaden. Dieser kann nämlich ab einer bestimmten Zugbelastung dieser Belastung nicht mehr durch Aufspreizung seiner helikalen Form zu einer geringeren Anzahl an Windungen pro Längeneinheit des Kernfadens nachgeben, sondern erlaubt einer weitere Streckung nur noch durch eine Dehnung in longitudinaler Richtung. Der Übergang von einer Aufspreizung der helikalen Struktur zu einer tatsächlichen Streckung des Umwindefadens selbst in seiner Längsrichtung führt zu einem starken Anstieg der Rückstellkraft, wodurch ein weiteres Dehnen des Garns verhindert wird. Diese überproportionale Zunahme der Rückstellkraft findet bei einer Zugbeanspruchung statt, bei der der elektrisch leitfähige Faden noch nicht gerissen ist. Das Garn ist also immer noch leitfähig.According to a preferred embodiment of the present invention, the restoring force of the yarn increases disproportionately from a certain tensile load. The reason for this disproportionate increase in the restoring force lies in the thread. This is because from a certain tensile load this load can no longer yield to a smaller number of turns per unit length of the core thread by spreading its helical shape, but allows further stretching only by stretching in the longitudinal direction. The transition from an expansion of the helical structure to an actual stretching of the wrapping thread even in its longitudinal direction leads to a strong increase in the restoring force, which prevents further stretching of the yarn. This disproportionate increase in the restoring force takes place in the event of a tensile load in which the electrically conductive thread has not yet broken. So the yarn is still conductive.
Das Ausmaß der Dehnbarkeit des Umwindefadens hängt hauptsächlich von den Materialeigenschaften und von der Anzahl der Wicklungen des Umwindefadens um den Kernfaden ab. Durch eine höhere Anzahl an Wicklungen wird im Allgemeinen eine höhere Dehnbarkeit erreicht. Daneben führt eine höhere Bruchdehnung des Materials zu einer erhöhten Dehnbarkeit.The degree of stretchability of the wrapping thread depends mainly on the material properties and the number of wraps of the wrapping thread around the core thread. A higher number of windings will generally achieved a higher elasticity. In addition, a higher elongation at break of the material leads to increased elasticity.
Unter der Bruchdehnung eines Materials versteht man die Längung des Materials durch Zugbeanspruchung bis zum Bruch. Sie dient zur Ermittlung der Festigkeit des beanspruchten Materials. Ein Material mit hoher Bruchdehnung kann also um einen weiten Betrag gedehnt werden bevor es bricht bzw. im Fall von Fäden reißt.The elongation at break of a material is the elongation of the material due to tensile stress until it breaks. It is used to determine the strength of the stressed material. A material with a high elongation at break can therefore be stretched by a large amount before it breaks or breaks in the case of threads.
Erfindungsgemäß wird die Dehnbarkeit des gesamten elektrisch leitfähigen Garns durch den Umwindefaden begrenzt. Um diese Eigenschaft zu erfüllen, sind Kernfaden, leitfähiger Faden und Umwindefaden im Hinblick auf Material und im Hinblick auf die Anzahl der Umwicklungen von leitfähigem Faden und Umwindefaden um den Kernfaden zweckmäßig aufeinander abgestimmt. Daneben werden vorteilhaft einige weitere, dem Fachmann auf dem Gebiet der Garnherstellung bekannte Parameter angepasst. Die Dehnbarkeit hängt nämlich außerdem von der Kraft, mit der die Umwindung des Kernfadens erfolgt, ab. Auch weisen die verschiedenen Fadenmaterialien verschiedene Reibungskoeffizienten auf, wodurch ein unterschiedlicher Kraftaufwand erforderlich wird, um die einzelnen Fäden gegeneinander zu verschieben.According to the invention, the extensibility of the entire electrically conductive yarn is limited by the winding thread. In order to fulfill this property, core thread, conductive thread and wrapping thread are expediently coordinated with one another with regard to material and with regard to the number of wraps of conductive thread and wrapping thread around the core thread. In addition, several other parameters known to those skilled in the field of yarn production are advantageously adapted. The elasticity also depends on the force with which the core thread is wound. The different thread materials also have different coefficients of friction, which means that a different amount of force is required in order to shift the individual threads against one another.
Für den Fachmann auf dem Gebiet der Garnherstellung stellt eine solche Auswahl kein Problem dar. Für die Auswahl geeigneter Materialien und geeigneter Herstellungsparameter wird der Fachmann üblicherweise einen bestimmten Kernfaden vorlegen, diesen mit einem dünnen Draht umwickeln und dann den Umwindefaden so bestimmen, dass das Garn die geforderten Eigenschaften erfüllt.Such a selection is not a problem for the person skilled in the field of yarn production. For the selection of suitable materials and suitable production parameters, the person skilled in the art will usually present a specific core thread, wrap it with a thin wire and then determine the winding thread in such a way that the yarn has the desired length required properties met.
Zu beachten ist, dass die Anzahl der Umwindungen um den Kernfaden, die in dem resultierenden Garn vorliegen, nicht nur durch die tatsächlich durchgeführte Zahl an Wicklungen beeinflusst wird, sondern auch durch den Grad der Vorstreckung des Kernfadens. Je höher die Kraft ist, mit der der Kernfaden vorgestreckt wird, umso drastischer erhöht sich die Anzahl an Umwindungen, die nach Entlastung des Kernfadens pro Längeneinheit des Kernfadens vorliegen. Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung besteht der Kernfaden aus einem gummielastischen Material. Unter dem Begriff „gummielastisches Material" ist zu verstehen, dass sich nach Deformation des Materials und anschließender Entlastung der ursprüngliche Zustand des Materials wieder einstellt. Nach DIN 7724 (Februar 1972) unterscheidet man zwei Arten von Elastizität, nämlich Energieelastizität (Stahlelastizität) und Entropieelastizität (Gummielastizität).It should be noted that the number of turns around the core thread which are present in the resulting yarn is influenced not only by the number of windings actually carried out, but also by the degree of pre-stretching of the core thread. The higher the force with which the core thread is pre-stretched, the more drastically increases the number of turns that are present per unit length of the core thread after the core thread is relieved. According to a preferred embodiment of the present invention, the core thread consists of a rubber-elastic material. The term "rubber-elastic material" means that after deformation of the material and subsequent relief, the original state of the material is restored. According to DIN 7724 (February 1972), a distinction is made between two types of elasticity, namely energy elasticity (steel elasticity) and entropy elasticity ( rubber elasticity).
Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung weist der elastische Kernfaden eine Bruchdehnung von wenigstens 50%, bevorzugt von wenigstens 100%, besonders bevorzugt von wenigstens 200% auf. Ganz besonders bevorzugt besitzt der Kernfaden eine Bruchdehnung von wenigstens 300%, insbesondere von wenigstens 400%, besonders bevorzugt von wenigstens 500%.According to a preferred embodiment of the present invention, the elastic core thread has an elongation at break of at least 50%, preferably at least 100%, particularly preferably at least 200%. The core thread very particularly preferably has an elongation at break of at least 300%, in particular at least 400%, particularly preferably at least 500%.
Der oder die elastischen Kernfäden sind für die gummielastischen Eigenschaften der gesamten Garneinheit verantwortlich. Der Markt bietet eine Vielfalt von gummielastischen Fäden an, aus der das für die jeweilige Applikation geeignete Material ausgewählt werden kann. Dazu gehören unter anderem Natur- und Synthesegummis, die verschiedenen Polyester- und Polyether-Elastantypen, modifizierte Polyester, nachvernetzte Thermoplaste usw. Ganz besonders geeignet sind Polyester-Polyurethan-Elastomere und/oder Polyether-Polyurethan-Elastomere als Materialien für den gummielastischen Kernfaden.The elastic core thread or threads are responsible for the rubber-elastic properties of the entire yarn unit. The market offers a variety of rubber elastic threads from which the material suitable for the respective application can be selected. These include natural and synthetic rubbers, the various types of polyester and polyether elastane, modified polyesters, post-crosslinked thermoplastics etc. Polyester-polyurethane elastomers and / or polyether-polyurethane elastomers are particularly suitable as materials for the rubber-elastic core thread.
Nach der Dehnung sollen sich die erfindungsgemäßen Garne aufgrund der gummielastischen Eigenschaften des Kernfadens zumindest annähernd wieder auf die ursprüngliche Länge zusammenziehen. Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung weist das elektrisch leitfähige Garn nach einer elastischen Dehnung um mindestens 15% in der Längsrichtung ohne Verlust seiner elektrischen Leitfähigkeit eine maximale Restdehnung von 5% auf. Besonders bevorzugt weist das elektrisch leitfähige Garn nach einer elastischen Dehnung um mindestens 30% in der Längsrichtung ohne Verlust seiner elektrischen Leitfähigkeit eine maximale Restdehnung von 5% auf. Der Kernfaden kann in einer für die jeweilige Applikation geeigneten Form eingesetzt werden. Beispielhaft seien einige Varianten genannt: Monofil, Multifil, segmentierte Typen und texturierte Typen. Falls erforderlich, können auch mehrere Fäden parallel oder verzwirnt im Kern eingesetzt werden. Es können gleichartige oder unterschiedliche Fäden nebeneinander verwendet werden.After stretching, the yarns according to the invention should contract at least approximately again to the original length due to the rubber-elastic properties of the core thread. According to a preferred embodiment of the present invention, after elastic stretching by at least 15% in the longitudinal direction, the electrically conductive yarn has a maximum residual elongation of 5% without losing its electrical conductivity. Particularly preferably, after elastic stretching by at least 30% in the longitudinal direction without loss of its electrical conductivity, the electrically conductive yarn has a maximum residual elongation of 5%. The core thread can be used in a form suitable for the respective application. Some variants are mentioned as examples: monofilament, multifilament, segmented types and textured types. If necessary, several threads can be used in parallel or twisted in the core. Similar or different threads can be used side by side.
Der elastische Kern des Verbundgarns wird mit zumindest einer elektrisch leitfähigen Umwindung ausgestattet. Der elastische Kern kann mehrfach mit leitfähigen Fäden umwunden sein. Diese leitfähigen Umwicklungen können auch in verschiedenen Wickelrichtungen aufgebracht sein und gegebenenfalls durch Zwischenschichten voneinander getrennt sein.The elastic core of the composite yarn is equipped with at least one electrically conductive wrap. The elastic core can be wound several times with conductive threads. These conductive wraps can also be applied in different winding directions and optionally separated from one another by intermediate layers.
Als leitfähige Fäden eignen sich besonders metallische Drähte, Drahtzwirne oder - geflechte, leitend beschichtete Synthesefasern, Stapelgarne mit Metallanteil, Garne aus leitfähigen Polymeren und leitfähig gefüllte Synthesefasern. Die leitfähigen Fäden können einfach oder mehrfach, sortenrein oder gemischt eingesetzt werden. Als leitfähige Fäden verwendete monofile Metalldrähte weisen einen Durchmesser zwischen 0,01 und 0,1 mm, bevorzugt zwischen 0,02 und 0,06 mm, besonders bevorzugt zwischen 0,03 und 0,05 mm auf.Particularly suitable as conductive threads are metallic wires, wire threads or braids, conductively coated synthetic fibers, staple yarns with metal content, yarns made of conductive polymers and conductive filled synthetic fibers. The conductive threads can be used one or more times, single or mixed. Monofilament metal wires used as conductive threads have a diameter between 0.01 and 0.1 mm, preferably between 0.02 and 0.06 mm, particularly preferably between 0.03 and 0.05 mm.
Obwohl sich prinzipiell zahlreiche Metalle und Legierungen, die zusätzlich beschichtet, eloxiert oder gebeizt sein können, als leitfähige Fäden eignen, so sind aufgrund technischer und ökonomischer Faktoren Kupferdrähte, silberbeschichtete Kupferdrähte und Edelstahldrähte besonders bevorzugt. Die Verwendung beschichteter bzw. lackierter Drahttypen verbessert die Korrosionsbeständigkeit und Waschbarkeit der erfindungsgemäßen Game. Solche Game sind nicht nur gut waschbar, sie widerstehen vielmehr sogar einer chemischen Reinigung.Although in principle numerous metals and alloys, which can additionally be coated, anodized or pickled, are suitable as conductive threads, copper wires, silver-coated copper wires and stainless steel wires are particularly preferred due to technical and economic factors. The use of coated or coated wire types improves the corrosion resistance and washability of the game according to the invention. Such games are not only washable, they actually resist chemical cleaning.
Neben monofilen Metalldrähten eignen sich Multifilament Edelstahl Garne ganz hervorragend zur Herstellung der erfindungsgemäßen Garne. Typischerweise bewegt sich die Dicke eines einzelnen Edelstahl-Filaments im Bereich zwischen 0,002 mm und 0,02 mm. Die Zahl der enthaltenen Einzelfilamente liegt zwischen 10 und 200. Für zahlreiche Applikationen bietet sich die Verwendung silberbeschichteter synthetischer Garne zur elektrisch leitfähigen Umwindung des elastischen Kerns an. Besonders eignen sich waschbeständige, silberbeschichtete Nylongarne zur Herstellung der erfindungsgemäßen Garne. Der Markt bietet sowohl Monofilament-, als auch Multifilamentgame an. Mit Multifilamentgamen als Umwindung können im Vergleich zu monofilen Fasern höhere Flächenabdeckungen des Kerns bei gleichem Garndurchmesser erzielt werden.In addition to monofilament metal wires, multifilament stainless steel yarns are extremely suitable for producing the yarns according to the invention. Typically, the thickness of a single stainless steel filament ranges between 0.002 mm and 0.02 mm. The number of individual filaments contained is between 10 and 200. The use of silver-coated synthetic yarns for electrically conductive wrapping around the elastic core is suitable for numerous applications. Wash-resistant, silver-coated nylon yarns are particularly suitable for producing the yarns according to the invention. The market offers both monofilament and multifilament games. With multifilament threads as a wrap, higher surface coverage of the core can be achieved with the same yarn diameter compared to monofilament fibers.
Zusätzlich zur elektrisch leitfähigen Umwindung umfasst das Garn eine weitere Umwindung. Eine derartige Umwindung kann verschiedene Funktionen übernehmen. Beispielhaft seien genannt: Elektrische Isolierung (nach außen, nach innen oder zwischen mehreren leitfähigen Schichten), mechanischer Abriebschutz, Verbesserung der Verarbeitbarkeit des Garns auf schnell laufenden Maschinen, Farbe, Glanz, Optik, Griff, Haptik, Überdehnschutz, Reißfestigkeit, Ausgleich der inneren Torsionsspannung des Garns nach Umwindung in einer Richtung. Es soll darauf hingewiesen werden, dass dieser weitere Umwindefaden in der Regel nicht elektrisch leitfähig sein wird. Von der vorliegenden Erfindung sind aber auch Umwindefäden umfasst, die eine elektrische Leitfähigkeit beliebiger Stärke aufweisen.In addition to the electrically conductive wrap, the yarn includes another wrap. Such a winding can perform various functions. Examples include: electrical insulation (outside, inside or between several conductive layers), mechanical abrasion protection, improvement of the processability of the yarn on high-speed machines, color, gloss, optics, handle, haptics, over-stretch protection, tear resistance, compensation of the internal torsional tension of the yarn after winding in one direction. It should be pointed out that this further winding thread will generally not be electrically conductive. However, the present invention also encompasses wrapping threads that have an electrical conductivity of any strength.
Für zahlreiche Applikationen eignet sich ein Garnaufbau mit innen liegendem elastischen Kern, innerer Umwindung mit leitfähigem Faden und in Gegenrichtung dazu ausgeführter textiler äußerer Umwindung. Die äußere Umwindung ist so beschaffen, dass sie im Fall einer starken Dehnung vor der innen liegenden leitfähigen Umwindung vollständig gespannt wird. So bremst die äußere Umwindung eine Dehnung ab, bevor die leitfähige Umwindung Schaden nimmt.A yarn structure with an internal elastic core, inner wrapping with conductive thread and a textile outer wrapping in the opposite direction is suitable for numerous applications. The outer wrapping is designed so that it is fully tensioned in the event of a strong stretch in front of the inner conductive wrapping. The outer wrap slows down stretching before the conductive wrap is damaged.
Weitere bevorzugte Ausführungsformen des erfindungsgemäßen Garns beinhalten die Verwendung von Multifilamentgamen als nicht leitende Umwindung. Multifilamentgame legen sich bei der Umwindung eines Kerns bevorzugt flächig auf den Kernfaden, so dass sie bei gleichem Außendurchmesser eine im Vergleich zum Monofil deutlich höhere Flächenabdeckung bewirken. Abhängig von der Applikation können sich für die beschriebene weitere Umwindung alle möglichen Fäden eignen. Stellvertretend für die möglichen Materialien seien beispielhaft genannt: Nylon, Polyester, Viskose, Polyamid, Leinen, Wolle, Seide, Baumwolle, Polypropylen, Kevlar in den verschiedenen Ausführungsformen, Mischgarne aller Art sowie metallisierte Game wie z. B. silberbeschichtetes Nylon.Further preferred embodiments of the yarn according to the invention include the use of multifilament yarns as a non-conductive wrap. When wrapping around a core, multifilament games prefer to lie flat on the core thread, so that with the same outer diameter they provide a significantly higher surface coverage compared to the monofilament. Depending on the application, all possible threads can be suitable for the further winding described. Representative of the possible materials may be mentioned as examples: nylon, polyester, viscose, polyamide, linen, wool, silk, cotton, polypropylene, Kevlar in the various embodiments, mixed yarns of all types and metallized game such as. B. silver coated nylon.
Die Herstellung der erfindungsgemäßen Garne kann auf verschiedene Arten erfolgen. Bevorzugt ist das Verfahren der klassischen Garnumwindung. Dabei wird der zentrale elastische Faden auf einem Streckwerk verzogen. Der verzogene elastische Kernfaden wird durch eine rotierende Hohlspindel geführt. Auf der Hohlspindel sitzt die Garnspule mit dem leitfähigen Faden oder dem Umwindefaden. Dieser Faden wird von dem gleichmäßig abgezogenen elastischen Kernfaden mitgenommen, so dass der leitfähige Faden bzw. der Umwindefaden in Form einer Wendel um den Kernfaden gewunden wird. Entspannt sich der verzogene Kernfaden nach dem Umwinden wieder, so liegen die einzelnen Umwindungen wesentlich dichter als während des Umwindens.The yarns according to the invention can be produced in various ways. The method of classic yarn winding is preferred. The central elastic thread is warped on a drafting system. The warped elastic core thread is passed through a rotating hollow spindle. The spool of thread with the conductive thread or the winding thread sits on the hollow spindle. This thread is carried along by the uniformly drawn-off elastic core thread, so that the conductive thread or the winding thread is wound in the form of a helix around the core thread. If the warped core thread relaxes again after winding, the individual wraps are much denser than during wrapping.
Gummielastische Garne können im Vergleich zu unelastischen Garnen mit hohem Verzug gefertigt werden, was bei sonst identischen Produktionsbedingungen durch die beschriebene Relaxation des Garns nach der Umwindung zu deutlich engeren Wicklungen führt. Elastische Garne können mit dem genannten Verfahren enger umwunden werden als nicht elastische Garne.Rubber-elastic yarns can be manufactured with a high warp compared to inelastic yarns, which leads to significantly narrower windings under otherwise identical production conditions due to the relaxation of the yarn after winding. Elastic yarns can be wrapped more tightly than non-elastic yarns using the method mentioned.
Grundsätzlich entstehen durch das Umwinden des Kernfadens mit einem weiteren Faden innere Torsionskräfte, die dazu führen, dass sich das Garn im entlasteten Zustand, also beim Abwickeln von der Spule, um sich selbst verdrillt. Werden zwei Fäden um den Kernfaden gewunden, so ergibt sich die Möglichkeit, diese inneren Torsionskräfte zu eliminieren. Man spricht in diesem Fall von einem „Ausbalanzieren" des Garns. Wird der zweite Faden nämlich gegensinnig zu dem ersten Faden um den Kernfaden gewunden, so ergeben sich Torsionskräfte in entgegengesetzten Richtungen. Material und Anzahl der Umwindungen können nun durch einfache Versuche so aufeinander abgestimmt werden, dass die Beträge der Torsionskräfte ungefähr gleich sind und sich eine resultierende Torsionskraft von nahezu Null ergibt. Als Folge ist gewährleistet, dass sich das Garn im unbelasteten Zustand kaum oder gar nicht um sich selbst verdrillt.Basically, by winding the core thread with another thread, there are internal torsional forces that cause the thread to twist around itself in the unloaded state, i.e. when unwinding from the bobbin. If two threads are wound around the core thread, there is the possibility of eliminating these internal torsional forces. In this case one speaks of a "balancing" of the yarn. If the second thread is wound around the core thread in the opposite direction to the first thread, torsional forces result in opposite directions. The material and the number of turns can now be coordinated with one another by simple tests that the amounts of the torsional forces are approximately the same and that a resulting torsional force of results in almost zero. As a result, it is ensured that the yarn twists itself or not at all in the unloaded state.
Gemäß einer bevorzugten Ausführungsform der vorliegenden Erfindung sind also der elektrisch leitfähige Faden und der Umwindefaden gegensinnig um den elastischen Kernfaden gewickelt. Wenn der elektrisch leitfähige Faden also beispielsweise in S-Richtung um elastischen Kernfaden gewunden vorliegt, so ist der Umwindefaden in Z-Richtung um den elastischen Kernfaden gewickelt. Es handelt sich also um eine kreuzweise Umwindung.According to a preferred embodiment of the present invention, the electrically conductive thread and the wrapping thread are wound in opposite directions around the elastic core thread. If, for example, the electrically conductive thread is wound around elastic core thread in the S direction, the wrapping thread is wound around the elastic core thread in the Z direction. So it is a cross-wrap.
Die vorliegende Erfindung umfasst auch die Verwendung der erfindungsgemäßen Garne und Gewebe zur Datenübertragung und der Stromversorgung elektrischer bzw. elektronischer Bauteile. Daneben ist auch die Verwendung der erfindungsgemäßen Garne und Gewebe als elektrisch leitende Materialien umfasst, die ähnlich einem Flachbandkabel bzw. einer ortsaufgelöst ansteuerbaren zweidimensionalen Matrix verschiedene elektrische Signale ohne nennenswerte gegenseitige Beeinflussung nebeneinander transportieren können.The present invention also includes the use of the yarns and fabrics according to the invention for data transmission and the power supply of electrical or electronic components. In addition, the use of the yarns and fabrics according to the invention as electrically conductive materials is also included, which, like a ribbon cable or a two-dimensional matrix that can be controlled in a spatially resolved manner, can transport different electrical signals next to one another without any appreciable mutual influence.
Ferner können erfindungsgemäße Garne bzw. daraus gefertigte Produkte zur Abschirmung elektromagnetischer Felder oder zur Ableitung statischer Ladungen eingesetzt werden. Eine Nutzung der erfindungsgemäßen Garne als Widerstandsleiter im Rahmen einer elektrischen Heizung ist möglich.Furthermore, yarns according to the invention or products made therefrom can be used to shield electromagnetic fields or to discharge static charges. It is possible to use the yarns according to the invention as a resistance conductor in the context of an electrical heater.
Die vorliegende Erfindung umfasst auch die Verwendung der erfindungsgemäßen Garne als elektrische Heizleiter und der daraus gefertigten Gewebe als elastische, elektrisch heizbare Gewebe.The present invention also includes the use of the yarns according to the invention as an electrical heating conductor and the fabric made therefrom as an elastic, electrically heatable fabric.
Die vorliegende Erfindung umfasst daneben auch die Verwendung der erfindungsgemäßen Garne als Sensormaterial, bevorzugt als Feuchtesensor oder Dehnungssensor. Wege zur Ausführung der ErfindungThe present invention also includes the use of the yarns according to the invention as a sensor material, preferably as a moisture sensor or strain sensor. Ways of Carrying Out the Invention
Nachfolgend soll die Erfindung anhand von Ausführungsbeispielen näher erläutert werden, es wird aber ausdrücklich darauf hingewiesen, dass die Erfindung nicht auf die angegebenen Beispiele beschränkt sein soll.The invention is to be explained in more detail below on the basis of exemplary embodiments, but it is expressly pointed out that the invention is not intended to be limited to the examples given.
Beispiel 1:Example 1:
Ein elastischer Faden aus Lycra 163C (Hersteller: Du pont De Nemours International S.A. Fibres Department, Du Pont Straße 1, D-61352, Bad Homburg; Produktbezeichnung: LYCRA Elastane Yarn; Dtex/Typ: 1880 Dtex T. 136C) mit einer Stärke von 1880 dtex wird auf einer Garnumwindemaschine vorgestreckt. Die Bruchdehnung des Fadens beträgt 500% bei einer Reißkraft von 1300 cN. Der Faden relaxiert nach einer Dehnung von 100% bis auf eine Restdehnung von 2,4%.An elastic thread made of Lycra 163C (manufacturer: Du pont De Nemours International SA Fibers Department, Du Pont Straße 1, D-61352, Bad Homburg; product name: LYCRA Elastane Yarn; Dtex / type: 1880 Dtex T. 136C) with a thickness of 1880 dtex is pre-stretched on a yarn winding machine. The elongation at break of the thread is 500% with a tensile strength of 1300 cN. After a stretch of 100%, the thread relaxes to a residual stretch of 2.4%.
Der vorgestreckte Lycra Faden wird durch eine Hohlspindel geführt. Diese Hohlspindel trägt eine konische Garnspindel, von der über Kopf ein 0,04 mm starker, hartversilberter Kupferdraht (Hersteller: Elektro-Feindraht AG in CH-8182 Escholzmatt; Produktbezeichnung: Textile Wire silver/copper mit Lacktyp TW-D) durch den Lycrafaden abgezogen wird. Der Durchmesser des Drahtes einschließlich seiner Lackbeschichtung beträgt 0,048 mm. Der Draht weist eine Bruchdehnung von 21,3% auf.The pre-stretched Lycra thread is passed through a hollow spindle. This hollow spindle carries a conical thread spindle, from which a 0.04 mm thick, hard silver-plated copper wire (manufacturer: Elektro-Feindraht AG in CH-8182 Escholzmatt; product name: Textile Wire silver / copper with varnish type TW-D) is drawn off by the lycra thread becomes. The diameter of the wire including its coating is 0.048 mm. The wire has an elongation at break of 21.3%.
Das einfach mit Draht umwundene Lycra wird durch eine zweite Hohlspindel geführt. Diese Hohlspindel trägt ein handelsübliches Multifilament-Polyamidgarn aus PA66 mit 78 dtex und 34 Einzelfilamenten (Hersteller: Radicifil S.p.A. / Synfil GmbH, IT-24126 Bergamo; Bezeichnung RN01235_78/34/1S; Bruchdehnung: 28%). Das PA66 Garn wird gegenläufig zum Draht um den Kern gewickelt. Die Maschinenparameter werden so ausgewählt, dass ein ausbalanziert.es Garn entsteht, das möglichst frei von inneren Torsionsspannungen ist.The Lycra, which is simply wrapped in wire, is guided through a second hollow spindle. This hollow spindle carries a commercially available multifilament polyamide yarn made of PA66 with 78 dtex and 34 individual filaments (manufacturer: Radicifil S.p.A. / Synfil GmbH, IT-24126 Bergamo; designation RN01235_78 / 34 / 1S; elongation at break: 28%). The PA66 yarn is wound around the core in the opposite direction to the wire. The machine parameters are selected so that a balanced yarn is created that is as free as possible from internal torsional stresses.
Das äußere PA66 Garn ist 3200-mal pro Meter Garn um den Kern gewunden; der innere Draht ist 3600-mal pro Meter Garn um den Kern gewunden. Der innen liegende Draht ist annähernd vollständig von dem außen liegenden PA66 Garn bedeckt, so dass das Garn über textile Optik und Haptik verfügt. Das Garn verfügt über eine ausgezeichnete elektrische Leitfähigkeit. Bei einer Dehnung um ca. 250% wird die Rückstellkraft des Garns durch vollständige Streckung des PA66 Garns überproportional stärker. Erst bei ca. 300% Dehnung verliert das Garn aufgrund von Drahtbruch seine elektrische Leitfähigkeit.The outer PA66 yarn is wound around the core 3200 times per meter of yarn; the inner wire is wound around the core 3600 times per meter of yarn. The inside lying wire is almost completely covered by the outside PA66 yarn, so that the yarn has a textile look and feel. The yarn has excellent electrical conductivity. With a stretch of approx. 250%, the restoring force of the yarn becomes disproportionately stronger when the PA66 yarn is fully stretched. The yarn only loses its electrical conductivity due to wire breakage after approx. 300% elongation.
Beispiel 2:Example 2:
Das elastische, elektrisch leitende Verbundgarn aus Beispiel 1 wird auf einer handelsüblichen Webmaschine als Schussfaden eingesetzt. Der Kettbaum besteht aus 0,3 mm starken, einfach gezwirnten Baumwollfäden, die in Gruppen zu 8 Fäden zusammengefasst sind. Beim Verweben entsteht ein festes Gewebe, das über eine ausgezeichnete elektrische Leitfähigkeit in Schussfadenrichtung verfügt und in Richtung des Kettfadens den elektrischen Strom nicht leitet. Selbst nach einer Dehnung um mehr als 120% in Schussfadenrichtung bleiben diese elektrischen Eigenschaften erhalten. Werden die Pole einer Gleichspannungsquelle in Kettfadenrichtung beabstandet angeschlossen, so kann diese Spannung im Abstand von einem Meter in Schussfadenrichtung zum Betrieb eines elektrischen Verbrauchers, wie z. B. einer Leuchtdiode verwendet werden. Das Gewebe kann ohne Auswirkung auf die Stromversorgung der Leuchtdiode in Schussfadenrichtung gedehnt werden.The elastic, electrically conductive composite yarn from Example 1 is used as a weft thread on a commercially available weaving machine. The warp beam consists of 0.3 mm thick, simply twisted cotton threads, which are combined in groups of 8 threads. When weaving, a firm fabric is created which has excellent electrical conductivity in the weft direction and does not conduct the electrical current in the direction of the warp thread. These electrical properties are retained even after stretching by more than 120% in the weft direction. If the poles of a DC voltage source are connected at a distance in the warp thread direction, this voltage can be spaced one meter apart in the weft thread direction for operating an electrical consumer, such as, for. B. a light emitting diode can be used. The fabric can be stretched in the weft direction without affecting the power supply to the light emitting diode.
Beispiel 3:Example 3:
Das elastische, elektrisch leitende Verbundgarn aus Beispiel 1 wird auf einer handelsüblichen Webmaschine als Schussfaden eingesetzt. Der Kettbaum besteht aus einem elektrisch leitenden, aber nicht gummielastischen Verbundgarn. Zur Herstellung des Kettfadens wird ein handelsübliches Polyestergarn mit 100 dtex und 36 Einzelfilamenten mit einer inneren Umwindung aus 0,041 mm starkem, hart versilbertem Kupferdraht und einer äußeren Umwindung aus handelsüblichem Polyamidgarn (PA66) mit 78 dtex und 34 Einzelfilamenten ausgestattet. Beim Verweben entsteht ein festes Gewebe, das über eine ausgezeichnete elektrische Leitfähigkeit in Schussfadenrichtung und eine davon unabhängige elektrische Leitfähigkeit in Richtung des Kettfadens verfügt. Selbst nach einer Dehnung um mehr als 120% in Schussfadenrichtung bleiben diese elektrischen Eigenschaften erhalten. Dieses kostengünstig zu fertigende Gewebe kann bei einer entsprechenden elektronischen Ansteuerung als Matrix zur ortsauflösenden Signalerfassung bzw. zum Betrieb einer ortsauflösenden Ausgabeeinheit wie z. B. eines Bildschirms eingesetzt werden.The elastic, electrically conductive composite yarn from Example 1 is used as a weft thread on a commercially available weaving machine. The warp beam consists of an electrically conductive, but not rubber-elastic composite yarn. To produce the warp thread, a commercially available polyester yarn with 100 dtex and 36 individual filaments is equipped with an inner winding made of 0.041 mm thick, hard silver-plated copper wire and an outer winding made of commercially available polyamide yarn (PA66) with 78 dtex and 34 individual filaments. Weaving creates a strong fabric that has excellent electrical conductivity in the weft direction and an independent electrical conductivity in the direction of the warp thread. These electrical properties are retained even after stretching by more than 120% in the weft direction. This fabric, which is inexpensive to manufacture, can be used with a corresponding electronic control as a matrix for spatially resolving signal acquisition or for operating a spatially resolving output unit such as, for. B. a screen can be used.
Beispiel 4:Example 4:
Ein elastischer Faden aus Lycra 163C (Du Pont de Nemours GmbH, Du Pont Straße 1 , D-61352, Bad Homburg) mit 1880 dtex wird auf einer Garnumwindemaschine vorgestreckt. Der vorgestreckte Lycra Faden wird durch eine Hohlspindel geführt. Diese Hohlspindel trägt eine konische Garnspindel, von der über Kopf ein mit Silber beschichteter Polyamidfaden mit 30 denier und 18 Einzelfilamenten (X-static, Life SRL, 1-25015 Desenzano, Italien) durch den Lycrafaden abgezogen wird. Das einfach mit der silberbeschichteten Faser umwundene Lycra wird durch eine zweite Hohlspindel geführt. Diese Hohlspindel trägt ein handelsübliches Multifilament-Polyamidgam aus PA66 mit 33 dtex und 10 Einzelfilamenten. Das PA66 Garn wird gegenläufig zur silberbeschichteten Faser um den Kern gewickelt. Die Maschinenparameter werden so ausgewählt, dass ein ausbalanziertes Garn entsteht, das möglichst frei von inneren Torsionsspannungen ist. Das äußere PA66 Garn ist 3200 Mal pro Meter Garn um den Kern gewunden; der silberbeschichtete Faden ist 3600 Mal pro Meter Garn um den Kern gewunden. Der innen liegende silberbeschichtete Faden ist nicht vollständig von dem außen liegenden PA66 Garn bedeckt. Das Garn verfügt über ausgezeichnete elektrische Leitfähigkeit. Bei einer Dehnung um ca. 250% wird die Rückstellkraft des Garns durch vollständige Streckung des PA66 Garns überproportional stärker. Erst bei ca. 320% Dehnung reißen die den Lycrakern umhüllenden Garne. Beispiel 5:An elastic thread made of Lycra 163C (Du Pont de Nemours GmbH, Du Pont Straße 1, D-61352, Bad Homburg) with 1880 dtex is pre-stretched on a yarn winding machine. The pre-stretched Lycra thread is passed through a hollow spindle. This hollow spindle carries a conical thread spindle, from which a silver-coated polyamide thread with 30 denier and 18 individual filaments (X-static, Life SRL, 1-25015 Desenzano, Italy) is pulled off through the lycra thread. The Lycra, simply wrapped with the silver-coated fiber, is guided through a second hollow spindle. This hollow spindle carries a commercially available multifilament polyamide yarn made of PA66 with 33 dtex and 10 individual filaments. The PA66 yarn is wound around the core in the opposite direction to the silver-coated fiber. The machine parameters are selected so that a balanced yarn is created that is as free as possible from internal torsional stresses. The outer PA66 yarn is wound around the core 3200 times per meter of yarn; the silver-coated thread is wound around the core 3600 times per meter of yarn. The inside silver-coated thread is not completely covered by the outside PA66 yarn. The yarn has excellent electrical conductivity. With a stretch of approx. 250%, the restoring force of the yarn becomes disproportionately stronger when the PA66 yarn is fully stretched. The yarns that envelop the Lycra core only tear at about 320% elongation. Example 5:
Das elastische, elektrisch leitende Verbundgarn aus Beispiel 4 wird auf einer handelsüblichen Webmaschine als Schussfaden eingesetzt. Der Kettbaum besteht aus einem elektrisch leitenden, aber nicht gummielastischen Verbundgarn. Zur Herstellung des Kettfadens wird ein handelsübliches Polyestergarn mit 100 dtex und 36 Einzelfilamenten mit einer inneren Umwindung aus einem mit Silber beschichteten Polyamidfaden mit 30 Denier und 18 Einzelfilamenten (X-static, Life SRL, 1-25015 Desenzano, Italien) und einer äußeren Umwindung aus handelsüblichem Polyamidgarn (PA66) mit 33 dtex und 10 Einzelfilamenten ausgestattet.The elastic, electrically conductive composite yarn from Example 4 is used as a weft thread on a commercially available weaving machine. The warp beam consists of an electrically conductive, but not rubber-elastic composite yarn. To produce the warp thread, a commercially available polyester yarn with 100 dtex and 36 individual filaments with an inner winding is made of a silver-coated polyamide thread with 30 denier and 18 individual filaments (X-static, Life SRL, 1-25015 Desenzano, Italy) and an outer winding commercial polyamide yarn (PA66) with 33 dtex and 10 single filaments.
Beim Verweben entsteht ein festes Gewebe, das über eine ausgezeichnete elektrische Leitfähigkeit verfügt. Aufgrund der nicht vollständigen Isolierung der silberbeschichteten Umwindungen sowohl im Kett-, als auch im Schussfaden stehen in dem Gewebe alle elektrisch leitenden Garne miteinander in elektrischem Kontakt. Selbst nach einer Dehnung um mehr als 100% in Schussfadenrichtung bleibt diese richtungsunabhängige elektrische Leitfähigkeit erhalten. Ein derartiges Gewebe verfügt über ausgezeichnete abschirmende Eigenschaften gegen elektromagnetische Strahlung insbesondere im Bereich von 1 bis 2000 MHz.Weaving creates a strong fabric that has excellent electrical conductivity. Due to the incomplete insulation of the silver-coated wraps in both the warp and weft threads, all electrically conductive yarns in the fabric are in electrical contact with one another. This direction-independent electrical conductivity is retained even after stretching by more than 100% in the weft direction. Such a fabric has excellent shielding properties against electromagnetic radiation, in particular in the range from 1 to 2000 MHz.
Beispiel 6:Example 6:
Das elastische, elektrisch leitende Verbundgarn aus Beispiel 1 wird auf einer handelsüblichen Bandwebmaschine als Kettfaden eingesetzt. Der Kettbaum besteht abwechselnd aus Sequenzen zu je 8 gleichartigen Fäden. Dabei wird zwischen Achterbündeln aus den in Beispiel 1 beschriebenen Garnen und solchen ohne leitfähigen Anteil abgewechselt. Die Fäden ohne leitfähigen Anteil entsprechen weitgehend den in Beispiel 1 beschriebenen Garnen völlig bis auf die Tatsache, dass anstatt des Drahtes ein Multifilament-Polyamidgam aus PA66 mit 78 dtex und 34 Einzelfilamenten eingesetzt wird. Als Schussfaden wird ein handelsübliches Multifilament-Polyamidgam eingesetzt. Das so hergestellte elastische Band besitzt nebeneinander vorliegende, untereinander elektrisch isolierte, leitende Bänder. Um Kurzschlüsse zwischen den leitenden Bändern auch in feuchter Umgebung auszuschließen, ist die Verwendung eines kunststoffbeschichteten Drahtes zur Herstellung des Garnes vorteilhaft. Ein in diesem Beispiel beschriebenes elastisches Flachkabel eignet sich hervorragend zum Anschluss elektrischer bzw. elektronischer Bauteile in Bekleidung. Das Band kann ohne Verlust der elektrischen Leitfähigkeit in Kettrichtung gedehnt werden. Gegen die beim Tragen von Bekleidung entstehenden Knicke und Falten ist das Band nicht empfindlich.The elastic, electrically conductive composite yarn from Example 1 is used as a warp thread on a commercially available ribbon loom. The warp beam consists of sequences of 8 identical threads each. It is alternated between bundles of eight from the yarns described in Example 1 and those without a conductive portion. The threads without a conductive portion largely correspond to the yarns described in Example 1, except for the fact that a multifilament polyamide yarn made of PA66 with 78 dtex and 34 individual filaments is used instead of the wire. A commercially available multifilament polyamide yarn is used as the weft thread. The elastic band produced in this way has conductive strips which are present next to one another and are electrically insulated from one another. In order to rule out short circuits between the conductive tapes even in a damp environment, the use of a plastic-coated wire for the production of the yarn is advantageous. An elastic flat cable described in this example is ideal for connecting electrical or electronic components in clothing. The tape can be stretched in the warp direction without loss of electrical conductivity. The tape is not sensitive to the creases and folds that occur when wearing clothing.
Beispiel 7:Example 7:
Das elastische, elektrisch in Schussfadenrichtung leitende Gewebe aus Beispiel 2 wird mittels handelsüblicher Bandkabelstecker auf einer Breite von 1 ,1 cm und einer Länge von 50 cm elektrisch in Schussfadenrichtung kontaktiert. Nach Anlegen einer Gleichspannung fließt elektrischer Strom. In der Mitte zwischen den Anschlussstellen wird die aus dem Stromfluss resultierende Temperaturerhöhung mittels eines NTC-Widerstandes bestimmt. Bei einer Heizleistung von 5 W (1,4 A bei 3,6 V) beträgt die erreichte Temperaturerhöhung bereits 30 °C. Bei einem Heizstrom von 13 W (2 A bei 6,5 V) beträgt die Temperaturerhöhung 64,5 °C.The elastic fabric which is electrically conductive in the weft direction from Example 2 is electrically contacted in the weft direction to a width of 1.1 cm and a length of 50 cm by means of commercially available ribbon cable plugs. After applying a DC voltage, electrical current flows. In the middle between the connection points, the temperature increase resulting from the current flow is determined using an NTC resistor. With a heating power of 5 W (1.4 A at 3.6 V), the temperature increase reached is already 30 ° C. With a heating current of 13 W (2 A at 6.5 V) the temperature increase is 64.5 ° C.
Durch die Dehnbarkeit und die textile Haptik des Gewebes eignet es sich bestens zur Herstellung von elastischen, elektrisch heizbaren Textilien, die im direkten Körperkontakt stehen. Beispiele für Applikationen sind Socken, Gelenkwärmer, Rückenwärmer, Handschuhe, elastische Binden etc. The stretchability and the textile feel of the fabric make it ideal for the production of elastic, electrically heatable textiles that are in direct contact with the body. Examples of applications are socks, joint warmers, back warmers, gloves, elastic bandages etc.
Claims
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002493145A CA2493145C (en) | 2002-09-14 | 2003-09-15 | Electrically conductive yarn |
| AU2003299049A AU2003299049A1 (en) | 2002-09-14 | 2003-09-15 | Electrically conductive thread |
| EP03756439A EP1537264B1 (en) | 2002-09-14 | 2003-09-15 | Electrically conductive thread |
| JP2004536872A JP2005538270A (en) | 2002-09-14 | 2003-09-15 | Conductive yarn |
| DE50303383T DE50303383D1 (en) | 2002-09-14 | 2003-09-15 | ELECTRICALLY CONDUCTIVE YARN |
| US11/075,198 US20050282009A1 (en) | 2002-09-14 | 2005-03-07 | Electrically conductive yarn |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10242785.2 | 2002-09-14 | ||
| DE2002142785 DE10242785A1 (en) | 2002-09-14 | 2002-09-14 | Electrically conductive yarn has a stretch core filament, with an electrically conductive and a bonding filament wound around it to restrict the core stretch |
| DE10305872 | 2003-02-13 | ||
| DE10305872.9 | 2003-02-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2004027132A1 true WO2004027132A1 (en) | 2004-04-01 |
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|---|---|---|---|
| PCT/DE2003/003059 Ceased WO2004027132A1 (en) | 2002-09-14 | 2003-09-15 | Electrically conductive thread |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20050282009A1 (en) |
| EP (1) | EP1537264B1 (en) |
| JP (1) | JP2005538270A (en) |
| CN (1) | CN100523341C (en) |
| AT (1) | ATE326563T1 (en) |
| AU (1) | AU2003299049A1 (en) |
| CA (1) | CA2493145C (en) |
| DE (2) | DE50303383D1 (en) |
| ES (1) | ES2264771T3 (en) |
| PT (1) | PT1537264E (en) |
| WO (1) | WO2004027132A1 (en) |
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- 2003-09-15 CA CA002493145A patent/CA2493145C/en not_active Expired - Fee Related
- 2003-09-15 ES ES03756439T patent/ES2264771T3/en not_active Expired - Lifetime
- 2003-09-15 JP JP2004536872A patent/JP2005538270A/en active Pending
- 2003-09-15 AT AT03756439T patent/ATE326563T1/en active
- 2003-09-15 CN CNB038182440A patent/CN100523341C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7135227B2 (en) | 2003-04-25 | 2006-11-14 | Textronics, Inc. | Electrically conductive elastic composite yarn, methods for making the same, and articles incorporating the same |
| US7926254B2 (en) | 2003-04-25 | 2011-04-19 | Textronics, Inc. | Electrically conductive elastic composite yarn, methods for making the same, and articles incorporating the same |
| US7504127B2 (en) | 2003-04-25 | 2009-03-17 | Textronics Inc. | Electrically conductive elastic composite yarn, methods for making the same, and articles incorporating the same |
| US7765835B2 (en) | 2004-11-15 | 2010-08-03 | Textronics, Inc. | Elastic composite yarn, methods for making the same, and articles incorporating the same |
| WO2006066773A1 (en) * | 2004-12-20 | 2006-06-29 | Fondazione Don Carlo Gnocchi - Onlus | Elastic conductor, particularly for providing variable-distance electrical connections |
| CN101180423B (en) * | 2005-06-02 | 2011-07-06 | 贝卡尔特股份有限公司 | Electrically conductive elastic composite yarn and its use of products |
| US7849888B2 (en) | 2005-06-10 | 2010-12-14 | Textronics, Inc. | Surface functional electro-textile with functionality modulation capability, methods for making the same, and applications incorporating the same |
| US7413802B2 (en) | 2005-08-16 | 2008-08-19 | Textronics, Inc. | Energy active composite yarn, methods for making the same, and articles incorporating the same |
| US7665288B2 (en) | 2005-08-16 | 2010-02-23 | Textronics, Inc. | Energy active composite yarn, methods for making the same and articles incorporating the same |
| DE102005041297B4 (en) * | 2005-08-31 | 2008-06-26 | Kufner Textilwerke Gmbh | Electrically conductive, elastically extensible hybrid yarn |
| DE102005041297A1 (en) * | 2005-08-31 | 2007-03-08 | Kufner Textilwerke Gmbh | Electrically conductive, elastically extensible hybrid yarn, process for its production, and textile product with such a hybrid yarn |
| DE102006058765A1 (en) * | 2006-12-12 | 2008-06-26 | W. Zimmermann Gmbh & Co. Kg | Method for measuring electrical characteristics of conductive yarn, involves providing electrical circuit having electrically conductive yarn and electrical signal is transmitted into conductive yarn |
| WO2010048948A3 (en) * | 2008-10-28 | 2010-08-05 | W. Zimmermann Gmbh & Co. Kg | Conductive textile fabric having leno weave |
| US9867934B2 (en) | 2010-03-23 | 2018-01-16 | Fresenius Medical Care Deutschland Gmbh | Device for detecting moisture for use with a device for monitoring an access to a patient, in particular for monitoring the vascular access in an extracorporeal blood treatment |
| US9119916B2 (en) | 2010-03-23 | 2015-09-01 | Fresenius Medical Care Deutschland Gmbh | Device for detecting moisture for use with a device for monitoring an access to a patient, in particular for monitoring the vascular access in an extracorporeal blood treatment |
| WO2018104303A1 (en) * | 2016-12-06 | 2018-06-14 | Nv Bekaert Sa | Electromagnetic shielding fabric and yarn for its manufacture |
| CN110023548A (en) * | 2016-12-06 | 2019-07-16 | 贝卡尔特公司 | Electromagnetic shielding fabric and yarn for its manufacture |
| RU2745781C2 (en) * | 2016-12-06 | 2021-03-31 | Нв Бекаэрт Са | Fabric for electromagnetic shielding and thread for manufacture thereof |
| US11248316B2 (en) | 2016-12-06 | 2022-02-15 | Nv Bekaert Sa | Electromagnetic shielding fabric and yarn for its manufacture |
| DE102019132028B3 (en) * | 2019-11-26 | 2021-04-15 | Deutsche Institute Für Textil- Und Faserforschung Denkendorf | Piezoresistive force sensor |
| WO2021104899A1 (en) | 2019-11-26 | 2021-06-03 | Deutsche Institute Für Textil- Und Faserforschung Denkendorf | Piezoresistive force sensor |
| EP4403682A1 (en) * | 2023-01-23 | 2024-07-24 | Helmholtz-Zentrum hereon GmbH | Covered shape-memory polymeric fibers for textile applications |
| WO2024156714A1 (en) | 2023-01-23 | 2024-08-02 | Helmholtz-Zentrum Hereon Gmbh | Covered shape-memory polymeric fibers for textile applications |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1537264A1 (en) | 2005-06-08 |
| DE50303383D1 (en) | 2006-06-22 |
| CN1671901A (en) | 2005-09-21 |
| ES2264771T3 (en) | 2007-01-16 |
| ATE326563T1 (en) | 2006-06-15 |
| CA2493145A1 (en) | 2004-04-01 |
| US20050282009A1 (en) | 2005-12-22 |
| DE10342787A1 (en) | 2004-05-13 |
| PT1537264E (en) | 2006-09-29 |
| AU2003299049A1 (en) | 2004-04-08 |
| EP1537264B1 (en) | 2006-05-17 |
| CN100523341C (en) | 2009-08-05 |
| CA2493145C (en) | 2009-04-07 |
| JP2005538270A (en) | 2005-12-15 |
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