[go: up one dir, main page]

WO2003070669A3 - Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung - Google Patents

Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung Download PDF

Info

Publication number
WO2003070669A3
WO2003070669A3 PCT/EP2003/001668 EP0301668W WO03070669A3 WO 2003070669 A3 WO2003070669 A3 WO 2003070669A3 EP 0301668 W EP0301668 W EP 0301668W WO 03070669 A3 WO03070669 A3 WO 03070669A3
Authority
WO
WIPO (PCT)
Prior art keywords
surfactant
mixture
alcohols
alcohol ethers
producing
Prior art date
Application number
PCT/EP2003/001668
Other languages
English (en)
French (fr)
Other versions
WO2003070669A2 (de
Inventor
Michael Roeper
Juergen Stephan
Goetz-Peter Schindler
Juergen Tropsch
Thomas Heidemann
Martina Prinz
Soeren Zimdahl
Original Assignee
Basf Ag
Michael Roeper
Juergen Stephan
Goetz-Peter Schindler
Juergen Tropsch
Thomas Heidemann
Martina Prinz
Soeren Zimdahl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Michael Roeper, Juergen Stephan, Goetz-Peter Schindler, Juergen Tropsch, Thomas Heidemann, Martina Prinz, Soeren Zimdahl filed Critical Basf Ag
Priority to JP2003569579A priority Critical patent/JP2005517728A/ja
Priority to AU2003208874A priority patent/AU2003208874A1/en
Priority to KR10-2004-7012572A priority patent/KR20040091634A/ko
Priority to EP03706531A priority patent/EP1478609A2/de
Priority to US10/503,213 priority patent/US20050107628A1/en
Publication of WO2003070669A2 publication Critical patent/WO2003070669A2/de
Publication of WO2003070669A3 publication Critical patent/WO2003070669A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

Beschrieben wird ein Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern durch Derivatisierung von Olefinen mit etwa 10 bis 20 C-Atomen oder von Gemischen solcher Olefine und gegebenenfalls anschliessende Alkoxylierung. Das Verfahren weist als Merkmale auf, dass man a) ein C4-Olefin-Gemisch mit einem Verhältnis 1-Buten/2-Buten von ≥ 1,2 einer Metathese unterwirft, b) aus dem Metathesegemisch Olefine mit 5 bis 8 C-Atomen abtrennt, c) die abgetrennten Olefine einzeln oder im Gemisch einer Dimerisierung zu Olefingemischen mit 10 bis 16 C-Atomen unterzieht, d) das erhaltene Olefingemisch, gegebenenfalls nach einer Fraktionierung, der Derivatisierung zu einem Gemisch von Tensidalkoholen unterwirft und e) gegebenenfalls die Tensidalkohole alkoxyliert. Das bei der Dimerisierung erhaltenen Olefingemisch enthält einen hohen Anteil verzweigter Komponenten und weniger als 10 Ges.-% von Verbindungen, die eine Vinylidengruppe enthalten. Beschrieben wird ferner die Verwendung der Tensidalkohole und Tensidalkoholether zu Tensiden durch Glycosidierung oder Polyglycosidierung, Sulfatierung oder Phosphatierung.
PCT/EP2003/001668 2002-02-19 2003-02-19 Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung WO2003070669A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2003569579A JP2005517728A (ja) 2002-02-19 2003-02-19 界面活性剤アルコール及び界面活性剤アルコールエーテルの改変された製造方法、製造された生成物及びその使用
AU2003208874A AU2003208874A1 (en) 2002-02-19 2003-02-19 Modified method for producing surfactant alcohols and surfactant alcohol ethers, the products of said method and use of the same
KR10-2004-7012572A KR20040091634A (ko) 2002-02-19 2003-02-19 변형된 계면활성제 알콜 및 계면활성제 알콜 에테르의제조 방법, 제조 생성물 및 그들의 용도
EP03706531A EP1478609A2 (de) 2002-02-19 2003-02-19 Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung
US10/503,213 US20050107628A1 (en) 2002-02-19 2003-02-19 Modified method for producing surfactant alcohols and surfactant alcohol ethers, the products of said method and use of the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10206845.3 2002-02-19
DE10206845A DE10206845A1 (de) 2002-02-19 2002-02-19 Modifiziertes Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung

Publications (2)

Publication Number Publication Date
WO2003070669A2 WO2003070669A2 (de) 2003-08-28
WO2003070669A3 true WO2003070669A3 (de) 2004-02-05

Family

ID=27635136

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/001668 WO2003070669A2 (de) 2002-02-19 2003-02-19 Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung

Country Status (8)

Country Link
US (1) US20050107628A1 (de)
EP (1) EP1478609A2 (de)
JP (1) JP2005517728A (de)
KR (1) KR20040091634A (de)
CN (1) CN1635984A (de)
AU (1) AU2003208874A1 (de)
DE (1) DE10206845A1 (de)
WO (1) WO2003070669A2 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19859911A1 (de) * 1998-12-23 2000-06-29 Basf Ag Verfahren zur Herstellung von Tensidalkoholen und Tensidalkoholethern, die hergestellten Produkte und ihre Verwendung
DE102004049940A1 (de) * 2004-10-13 2006-04-20 Basf Ag Verfahren zur Herstellung eines C4-Olefin-Gemisches durch Selektivhydrierung und Metatheseverfahren zur Verwendung dieses Stroms
US20060129013A1 (en) * 2004-12-09 2006-06-15 Abazajian Armen N Specific functionalization and scission of linear hydrocarbon chains
WO2007112242A1 (en) * 2006-03-23 2007-10-04 Shell Oil Company Olefin conversion process and olefin recovery process
US8362311B2 (en) 2009-09-30 2013-01-29 Massachusetts Institute Of Technology Highly Z-selective olefins metathesis
US20130172627A1 (en) * 2011-12-28 2013-07-04 Shell Oil Company Process for preparing lower olefins
US9663440B2 (en) 2013-04-09 2017-05-30 Materia, Inc. Cross metathesis of poly-branched poly-olefins
WO2014209711A1 (en) * 2013-06-28 2014-12-31 Dow Global Technologies Llc Process for the preparation of lightly-branched hydrophobes and the corresponding surfactants and applications thereof
WO2019021257A1 (en) * 2017-07-27 2019-01-31 Sabic Global Technologies B.V. PROCESS FOR PRODUCING FUEL ADDITIVE
CN111801404A (zh) 2018-03-19 2020-10-20 沙特基础工业全球技术有限公司 生产燃料添加剂的方法
US11697626B2 (en) 2018-05-18 2023-07-11 Sabic Global Technologies B.V. Method of producing a fuel additive with a hydration unit
CN113544238B (zh) 2019-03-08 2023-02-28 沙特基础工业全球技术有限公司 生产燃料添加剂的方法
EP4157815A2 (de) * 2020-05-29 2023-04-05 Dow Global Technologies LLC Zusammensetzung mit gemischten c8-c18-alkoholen und tensiden daraus
CN118265688A (zh) * 2021-12-06 2024-06-28 陶氏环球技术有限责任公司 包含直链十三烷醇的醇混合物
CN115722238B (zh) * 2022-11-18 2024-08-23 中国科学院长春应用化学研究所 一种生物质糖基化合物催化转化合成烯烃型单体的方法及可逆固化液体橡胶的制备

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000039058A1 (de) * 1998-12-23 2000-07-06 Basf Aktiengesellschaft Verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3317628A (en) * 1963-07-12 1967-05-02 Monsanto Co Polymerization of olefins using ammoniated cobalt salt impregnated carbon catalyst
US4069273A (en) * 1977-01-24 1978-01-17 Chevron Research Company Dimerization of linear alpha-olefins
US4788371A (en) * 1987-12-30 1988-11-29 Uop Inc. Catalytic oxidative steam dehydrogenation process
US5234780A (en) * 1989-02-13 1993-08-10 Kabushiki Kaisha Toshiba Exposure mask, method of manufacturing the same, and exposure method using the same
US5733518A (en) * 1992-04-27 1998-03-31 Sun Company, Inc. (R&M) Process and catalyst for dehydrogenation of organic compounds
NO179131C (no) * 1993-06-14 1996-08-14 Statoil As Katalysator, fremgangsmåte for dens fremstilling og fremgangsmåte for dehydrogenering av lette paraffiner
US5527979A (en) * 1993-08-27 1996-06-18 Mobil Oil Corporation Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen
US5530171A (en) * 1993-08-27 1996-06-25 Mobil Oil Corporation Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen
FR2733978B1 (fr) * 1995-05-11 1997-06-13 Inst Francais Du Petrole Procede et installation pour la conversion de coupes c4 et c5 olefiniques en ether et en propylene
US5731480A (en) * 1995-11-03 1998-03-24 Albemarle Corporation Coproduction of vinylidene alcohols and vinylidene hydrocarbons
US5659100A (en) * 1996-02-05 1997-08-19 Amoco Corporation Production of vinylidene olefins
EG21623A (en) * 1996-04-16 2001-12-31 Procter & Gamble Mid-chain branced surfactants
DE19813720A1 (de) * 1998-03-27 1999-09-30 Basf Ag Verfahren zur Herstellung von Olefinen
DE19932060A1 (de) * 1999-07-12 2001-01-18 Basf Ag Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen
DE10047642A1 (de) * 2000-09-26 2002-04-11 Basf Ag Verfahren zur Dehydrierung von Kohlenwasserstoffen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000039058A1 (de) * 1998-12-23 2000-07-06 Basf Aktiengesellschaft Verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung

Also Published As

Publication number Publication date
KR20040091634A (ko) 2004-10-28
JP2005517728A (ja) 2005-06-16
DE10206845A1 (de) 2003-08-28
EP1478609A2 (de) 2004-11-24
CN1635984A (zh) 2005-07-06
AU2003208874A1 (en) 2003-09-09
WO2003070669A2 (de) 2003-08-28
US20050107628A1 (en) 2005-05-19

Similar Documents

Publication Publication Date Title
AU1865000A (en) Method for producing surfactant alcohols and surfactant alcohol ethers, the resulting products and their use
WO2003070669A3 (de) Modifizierte verfahren zur herstellung von tensidalkoholen und tensidalkoholethern, die hergestellten produkte und ihre verwendung
CA2313850A1 (en) Preparation of c5-/c6 olefins
EP3266757B1 (de) Herstellung von zumindest 1-hexen und octen aus ethen
JP2002533423A5 (de)
AU3813000A (en) Method for producing alcohol surfactants and alcohol ether surfactants, the products obtained and their use
ES2021025B3 (es) Un procedimiento para la obtencion de un producto de alcanolacoxilato.
ZA200602866B (en) Preparation of branched aliphatic alcohols using a process stream from an isomerization unit with recycle to a dehydrogenation unit
PT1159237E (pt) Processo para a preparacao de alcoois tensioactivos e de eteres alcoolicos tensioactivos, produtos assim obtidos e sua utilizacao
ATE402132T1 (de) Verfahren zur herstellung von olefinen mit 8 bis 12 kohlenstoffatomen
WO2001085651A3 (en) Process for preparation of selectively branched detergent products
BR8903961A (pt) Processo para a preparacao de um tenso-ativo biodegradavel e tenso-ativos
DE602004008956D1 (de) Herstellung von verzweigten aliphatischen alkoholen unter verwendung eines verfahrensstroms aus einer dehydrierungs-isomerisierungs-anlage
JP2002540087A5 (de)
CA2604341A1 (en) Process to obtain a highly soluble linear alkylbenzene sulfonate
WO2005037747A3 (en) Preparation of branched aliphatic alcohols using combined process streams from a hydrogenation unit, a dehydrogenation unit and an isomerization unit
TH44571A (th) กรรมวิธีสำหรับการเตรียมของสารลดแรงตึงผิวแอลกอฮอล์และสารลดแรงตึงผิวแอลกอฮอล์ อีเธอร์ ผลิตภัณฑ์สำเร็จรูปและการใช้สารเหล่านั้น
WO2005061447A3 (de) Verfahren zur herstellung von alkylaryl-verbindungen
TH44580A (de)
EP0780467A3 (de) Entfettungszusammensetzungen
WO2005037748A3 (en) Preparation of branched aliphatic alcohols using combined process streams from a dimerization unit and an isomerization unit
MX2024002278A (es) Compuesto solido soluble para aplicacion como vehiculo de agentes activos o recubrimiento multifuncional sobre estructuras vegetales y frutas y su metodo de obtencion.
WO2005037416A3 (en) Preparation of branched aliphatic alcohols using combined process streams from a hydrogenation unit, a dehydrogenation unit, a dimerization unit and an isomerization unit
MX9705174A (es) Procedimiento para la obtencion de oligomeros de buteno a partir de butanos de campo.
JPS557226A (en) Preparation of lower olefin dimer

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 10503213

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 1020047012572

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2003569579

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 2003804210X

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2003706531

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2003706531

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWW Wipo information: withdrawn in national office

Ref document number: 2003706531

Country of ref document: EP