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WO2003051493A3 - Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation - Google Patents

Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation Download PDF

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Publication number
WO2003051493A3
WO2003051493A3 PCT/US2002/035545 US0235545W WO03051493A3 WO 2003051493 A3 WO2003051493 A3 WO 2003051493A3 US 0235545 W US0235545 W US 0235545W WO 03051493 A3 WO03051493 A3 WO 03051493A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon monoxide
platinum group
catalysts
oxidation catalysts
group metal
Prior art date
Application number
PCT/US2002/035545
Other languages
French (fr)
Other versions
WO2003051493A2 (en
Inventor
Lawrence Shore
Wolfang F Ruettinger
Robert J Farrauto
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/035,525 external-priority patent/US6913739B2/en
Application filed by Engelhard Corp filed Critical Engelhard Corp
Priority to AU2002364694A priority Critical patent/AU2002364694A1/en
Publication of WO2003051493A2 publication Critical patent/WO2003051493A2/en
Publication of WO2003051493A3 publication Critical patent/WO2003051493A3/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/044—Selective oxidation of carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

The invention provides copper-based preferential oxidation catalysts containing low concentrations of platinum group metals, and processes that utilize the catalysts for selectively oxidizing carbon monoxide from an input gas stream that contains carbon monoxide, oxygen and hydrogen. Processes that are conducted with the disclosed preferential oxidation catalysts achieve selective oxidization of carbon monoxide with minimal consumption of hydrogen over wide temperature ranges. In some embodiments, the catalysts of the invention have an oxide support on which is dispersed copper or an oxide thereof, a platinum group metal and a reducible metaloxide. In other embodiments, the catalysts have a cerium oxide support on which is dispersed copper or an oxide thereof and a platinum group metal. The invention also provides apparatus, such as fuel processors, that supply hydrogen to a fuel cell, that incorporate the disclosed preferential oxidation catalysts.
PCT/US2002/035545 2001-11-09 2002-11-06 Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation WO2003051493A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002364694A AU2002364694A1 (en) 2001-11-09 2002-11-06 Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/035,525 US6913739B2 (en) 2000-09-25 2001-11-09 Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation
US10/035,575 2001-11-09
US10/035,525 2001-11-09
US10/035,575 US20020131915A1 (en) 2000-09-25 2001-11-09 Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation

Publications (2)

Publication Number Publication Date
WO2003051493A2 WO2003051493A2 (en) 2003-06-26
WO2003051493A3 true WO2003051493A3 (en) 2003-11-13

Family

ID=26712202

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/035545 WO2003051493A2 (en) 2001-11-09 2002-11-06 Platinum group metal promoted copper oxidation catalysts and methods for carbon monoxide remediation

Country Status (2)

Country Link
AU (1) AU2002364694A1 (en)
WO (1) WO2003051493A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006006702A1 (en) 2004-07-15 2006-01-19 Nikki-Universal Co., Ltd. Catalyst for purifying exhaust gas containing organic nitrogen compound and method for purifying such exhaust gas
US20080260607A1 (en) * 2004-11-05 2008-10-23 Maria Flytzani-Stephanopoulos Treatment of Gold-Ceria Catalysts with Oxygen to Improve Stability Thereof in the Water-Gas Shift and Selective Co Oxidation Reactions
US8445402B2 (en) * 2005-06-01 2013-05-21 Basf Corporation Preferential oxidation catalyst containing platinum, copper and iron
HUE039308T2 (en) 2006-02-14 2018-12-28 Basf Se Adsorption composition and process for removal of co from material streams
CN101472665B (en) 2006-06-21 2012-02-01 巴斯夫欧洲公司 Adsorption composition and method of removing CO from streams
JP2010510879A (en) 2006-12-01 2010-04-08 ビーエーエスエフ ソシエタス・ヨーロピア Adsorbent for removing CO from material stream and method for removing the same
DE102008032200A1 (en) * 2008-07-09 2010-01-21 W.C. Heraeus Gmbh oxidation catalyst
US8668890B2 (en) * 2012-04-26 2014-03-11 Basf Corporation Base metal catalyst composition and methods of treating exhaust from a motorcycle
CN108940296B (en) * 2018-08-02 2021-04-30 沈炳龙 Application of Co-Mo-Ni/TiO2-Al2O3 catalyst in CO removal
US11358128B2 (en) 2019-12-30 2022-06-14 Saudi Arabian Oil Company High activity reforming catalyst formulation and process for low temperature steam reforming of hydrocarbons to produce hydrogen

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290530A (en) * 1991-05-31 1994-03-01 Kabushiki Kaisha Riken Method of cleaning exhaust gas
JPH11114423A (en) * 1997-10-16 1999-04-27 Nissan Motor Co Ltd Catalyst for selective oxidation of co in hydrogen gas, its production, and method for removing co in hydrogen gas
EP1136442A2 (en) * 2000-03-21 2001-09-26 dmc2 Degussa Metals Catalysts Cerdec AG Method for the catalytic conversion of carbon monoxide in a hydrogen containing gas mixture with improved cold start and catalyst therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290530A (en) * 1991-05-31 1994-03-01 Kabushiki Kaisha Riken Method of cleaning exhaust gas
JPH11114423A (en) * 1997-10-16 1999-04-27 Nissan Motor Co Ltd Catalyst for selective oxidation of co in hydrogen gas, its production, and method for removing co in hydrogen gas
EP1136442A2 (en) * 2000-03-21 2001-09-26 dmc2 Degussa Metals Catalysts Cerdec AG Method for the catalytic conversion of carbon monoxide in a hydrogen containing gas mixture with improved cold start and catalyst therefor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 09 30 July 1999 (1999-07-30) *

Also Published As

Publication number Publication date
AU2002364694A1 (en) 2003-06-30
WO2003051493A2 (en) 2003-06-26

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