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WO2003050207A8 - Process for sulfur reduction in naphtha streams - Google Patents

Process for sulfur reduction in naphtha streams

Info

Publication number
WO2003050207A8
WO2003050207A8 PCT/US2002/035294 US0235294W WO03050207A8 WO 2003050207 A8 WO2003050207 A8 WO 2003050207A8 US 0235294 W US0235294 W US 0235294W WO 03050207 A8 WO03050207 A8 WO 03050207A8
Authority
WO
WIPO (PCT)
Prior art keywords
boiling range
range naphtha
naphtha
thiophene
light
Prior art date
Application number
PCT/US2002/035294
Other languages
French (fr)
Other versions
WO2003050207A1 (en
Inventor
Willibrord A Groten
Original Assignee
Catalytic Distillation Tech
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytic Distillation Tech filed Critical Catalytic Distillation Tech
Priority to PL02368811A priority Critical patent/PL196032B1/en
Priority to AU2002353999A priority patent/AU2002353999A1/en
Priority to ROA200400523A priority patent/RO121858B1/en
Priority to MXPA04005669A priority patent/MXPA04005669A/en
Publication of WO2003050207A1 publication Critical patent/WO2003050207A1/en
Publication of WO2003050207A8 publication Critical patent/WO2003050207A8/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/16—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural parallel stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
    • C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A process for fractionating and treating of a full range naphtha stream. The full boiling range naphtha stream is first split into a light boiling range naphta, an intermediate boiling range naphtha and a heavy boiling range naphtha. The bottoms are subjected to hydrodesulfurization and the effluent combined with the intermediate boiling range naphtha containing thiophene and thiophene and thiophene mercaptans and subjected to a second hydrodesulfurization. The effluent from the polishing reactor may be combined with the light boiling range naphtha to produce a new full boiling range naphtha containing substantially less total sulfur than the original feed. The mercaptans in the light naphtha may be removed by thioetherification prior to splitting or by wet caustic wash afterwards. The object being to meet higher standards for sulfur removal, by treating the components of the naphta feed with the process that preserves the olefinic while most expediently removing the sulfur compounds.
PCT/US2002/035294 2001-12-12 2002-11-04 Process for sulfur reduction in naphtha streams WO2003050207A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PL02368811A PL196032B1 (en) 2001-12-12 2002-11-04 Process for sulfur reduction in naphtha streams
AU2002353999A AU2002353999A1 (en) 2001-12-12 2002-11-04 Process for sulfur reduction in naphtha streams
ROA200400523A RO121858B1 (en) 2001-12-12 2002-11-04 Process for reducing the content of organic sulphur in a cracked oil flow
MXPA04005669A MXPA04005669A (en) 2001-12-12 2002-11-04 Process for sulfur reduction in naphtha streams.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/015,863 US20040188327A1 (en) 2001-06-20 2001-12-12 Process for sulfur reduction in naphtha streams
US10/015,863 2001-12-12

Publications (2)

Publication Number Publication Date
WO2003050207A1 WO2003050207A1 (en) 2003-06-19
WO2003050207A8 true WO2003050207A8 (en) 2004-10-21

Family

ID=21774060

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/035294 WO2003050207A1 (en) 2001-12-12 2002-11-04 Process for sulfur reduction in naphtha streams

Country Status (8)

Country Link
US (1) US20040188327A1 (en)
CN (1) CN1325611C (en)
MX (1) MXPA04005669A (en)
PL (1) PL196032B1 (en)
RO (1) RO121858B1 (en)
RU (1) RU2285033C2 (en)
WO (1) WO2003050207A1 (en)
ZA (1) ZA200404086B (en)

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US7118151B2 (en) * 2004-05-07 2006-10-10 Ford Global Technologies, Llc Automotive wet trunk with drain
ATE485095T1 (en) 2004-08-02 2010-11-15 Shell Int Research METHOD FOR REMOVAL OF THIOLS FROM AN INERT GAS STREAM
US7638041B2 (en) * 2005-02-14 2009-12-29 Catalytic Distillation Technologies Process for treating cracked naphtha streams
US20070095725A1 (en) * 2005-10-31 2007-05-03 Catalytic Distillation Technologies Processing of FCC naphtha
US7842181B2 (en) * 2006-12-06 2010-11-30 Saudi Arabian Oil Company Composition and process for the removal of sulfur from middle distillate fuels
CN101275084B (en) * 2007-03-30 2012-02-22 中国石油化工股份有限公司 A method for reducing the sulfur content of catalytic cracking gasoline
US20080283445A1 (en) * 2007-05-16 2008-11-20 Powers Donald H Hydrocarbon thermal cracking using atmospheric residuum
US7780847B2 (en) * 2007-10-01 2010-08-24 Saudi Arabian Oil Company Method of producing low sulfur, high octane gasoline
CN101418233B (en) * 2007-10-26 2012-07-18 中国石油化工股份有限公司 Method for reducing sulphur in inferior naphtha
US20090145808A1 (en) * 2007-11-30 2009-06-11 Saudi Arabian Oil Company Catalyst to attain low sulfur diesel
US8142646B2 (en) 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
WO2009105749A2 (en) 2008-02-21 2009-08-27 Saudi Arabian Oil Company Catalyst to attain low sulfur gasoline
US8197674B2 (en) * 2008-09-09 2012-06-12 Lummus Technology Inc. Thioetherification processes for the removal of mercaptans from gas streams
US9005432B2 (en) 2010-06-29 2015-04-14 Saudi Arabian Oil Company Removal of sulfur compounds from petroleum stream
US8597501B2 (en) 2010-06-30 2013-12-03 Uop Llc Process for removing one or more sulfur compounds from a stream
US20120048778A1 (en) * 2010-08-25 2012-03-01 Catalytic Distillation Technologies Selective desulfurization of fcc gasoline
US8535518B2 (en) 2011-01-19 2013-09-17 Saudi Arabian Oil Company Petroleum upgrading and desulfurizing process
CN103059957B (en) * 2011-10-21 2015-10-21 中国石油化工股份有限公司 A kind of Low-energy consumption catalytic gasoline hydrodesulfurizationmethod method
KR101663916B1 (en) * 2012-08-21 2016-10-07 캐털리틱 디스틸레이션 테크놀로지스 Selective hydrodesulfurization of fcc gasoline to below 10 ppm sulfur
CN103789016B (en) * 2012-11-03 2015-07-22 中国石油化工股份有限公司 Combined distillate oil hydroprocessing method
CN103789017B (en) * 2012-11-03 2015-12-02 中国石油化工股份有限公司 A kind of distillate hydrogenation combined technical method
CN103805249B (en) * 2012-11-03 2015-09-30 中国石油化工股份有限公司 A kind of distillate hydrogenation combined method and distillate hydrogenation clustered aggregates
RU2514916C9 (en) * 2012-12-28 2014-05-27 Дженерейшн Инжиниринг Лтд Method for production of commercial-grade diesel fuel of high-sulphur diesel oil cuts and device for its implementation
US20140353209A1 (en) * 2013-05-29 2014-12-04 Uop, Llc Process for treating a naphtha stream
US9822317B2 (en) * 2014-10-10 2017-11-21 Uop Llc Process and apparatus for selectively hydrogenating naphtha
US9393538B2 (en) * 2014-10-10 2016-07-19 Uop Llc Process and apparatus for selectively hydrogenating naphtha
US10308883B2 (en) * 2015-10-07 2019-06-04 Axens Process for desulfurizing cracked naphtha
FR3049955B1 (en) 2016-04-08 2018-04-06 IFP Energies Nouvelles PROCESS FOR TREATING A GASOLINE
WO2017180505A1 (en) 2016-04-14 2017-10-19 Uop Llc Process and apparatus for treating mercaptans
FR3057578B1 (en) * 2016-10-19 2018-11-16 IFP Energies Nouvelles PROCESS FOR HYDRODESULFURING OLEFINIC ESSENCE
US10752847B2 (en) 2017-03-08 2020-08-25 Saudi Arabian Oil Company Integrated hydrothermal process to upgrade heavy oil
US10703999B2 (en) 2017-03-14 2020-07-07 Saudi Arabian Oil Company Integrated supercritical water and steam cracking process
US10526552B1 (en) 2018-10-12 2020-01-07 Saudi Arabian Oil Company Upgrading of heavy oil for steam cracking process

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US4062762A (en) * 1976-09-14 1977-12-13 Howard Kent A Process for desulfurizing and blending naphtha
US5360532A (en) * 1991-08-15 1994-11-01 Mobil Oil Corporation Gasoline upgrading process
US5346609A (en) * 1991-08-15 1994-09-13 Mobil Oil Corporation Hydrocarbon upgrading process
JP3443474B2 (en) * 1995-02-03 2003-09-02 新日本石油株式会社 Desulfurization treatment method for catalytic cracking gasoline
US5597476A (en) * 1995-08-28 1997-01-28 Chemical Research & Licensing Company Gasoline desulfurization process
WO1998014535A1 (en) * 1996-09-30 1998-04-09 Mobil Oil Corporation Alkylation process for desulfurization of gasoline
DK29598A (en) * 1998-03-04 1999-09-05 Haldor Topsoe As Process for desulphurizing FCC heavy gasoline
US6024865A (en) * 1998-09-09 2000-02-15 Bp Amoco Corporation Sulfur removal process
FR2807061B1 (en) * 2000-03-29 2002-05-31 Inst Francais Du Petrole PROCESS FOR FUEL DESULFURIZATION COMPRISING DESULFURIZATION OF HEAVY AND INTERMEDIATE FRACTIONS FROM A FRACTIONATION IN AT LEAST THREE CUT
US6495030B1 (en) * 2000-10-03 2002-12-17 Catalytic Distillation Technologies Process for the desulfurization of FCC naphtha
US6610197B2 (en) * 2000-11-02 2003-08-26 Exxonmobil Research And Engineering Company Low-sulfur fuel and process of making
US6444118B1 (en) * 2001-02-16 2002-09-03 Catalytic Distillation Technologies Process for sulfur reduction in naphtha streams
US6540907B1 (en) * 2001-07-09 2003-04-01 Uop Llc Fractionation for full boiling range gasoline desulfurization

Also Published As

Publication number Publication date
WO2003050207A1 (en) 2003-06-19
RU2004121185A (en) 2006-01-10
PL368811A1 (en) 2005-04-04
MXPA04005669A (en) 2004-12-06
CN1325611C (en) 2007-07-11
RU2285033C2 (en) 2006-10-10
ZA200404086B (en) 2005-08-26
RO121858B1 (en) 2008-06-30
US20040188327A1 (en) 2004-09-30
CN1604956A (en) 2005-04-06
PL196032B1 (en) 2007-11-30

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