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WO2003010346A3 - Wet process and reactor for the recovery of platinum group metals from automobile catalytic converters - Google Patents

Wet process and reactor for the recovery of platinum group metals from automobile catalytic converters Download PDF

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Publication number
WO2003010346A3
WO2003010346A3 PCT/IL2002/000602 IL0200602W WO03010346A3 WO 2003010346 A3 WO2003010346 A3 WO 2003010346A3 IL 0200602 W IL0200602 W IL 0200602W WO 03010346 A3 WO03010346 A3 WO 03010346A3
Authority
WO
WIPO (PCT)
Prior art keywords
platinum group
group metals
reaction chamber
catalytic member
recovery
Prior art date
Application number
PCT/IL2002/000602
Other languages
French (fr)
Other versions
WO2003010346A2 (en
Inventor
Vladimir Shipachev
Original Assignee
Negev Metals Products Ltd
Vladimir Shipachev
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Negev Metals Products Ltd, Vladimir Shipachev filed Critical Negev Metals Products Ltd
Priority to AU2002355201A priority Critical patent/AU2002355201A1/en
Publication of WO2003010346A2 publication Critical patent/WO2003010346A2/en
Publication of WO2003010346A3 publication Critical patent/WO2003010346A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70—Wet oxidation of material submerged in liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/02—Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407—Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/00707—Fouling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00805—Details of the particulate material
    • B01J2208/00814—Details of the particulate material the particulate material being provides in prefilled containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/029—Non-ferrous metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Catalysts (AREA)

Abstract

A process is disclosed for recovering platinum group metals from a spent catalytic member, and in particular, from a catalytic converter from an automobile. The process comprises comprising introducing the catalytic member (10) into a reaction chamber (10), wetting the spent catalytic member with an acidic solution of hydrochloric acid, heating the reaction chamber and adding an oxidizing agent, such as HNO3 and H202, continuing heating such that gaseous vapors are produced and caused to circulate through the reaction chamber, and condensing the gaseous vapors so as to obtain a solution containing platinum group metals from the spent catalytic member. Also disclosed is a reactor adapted for performing the recovery process. The reaction chamber (5) comprises a condenser (2) and is advantageously placed in a heating chamber (4) filled with oil (8). Preferably the catalytic member (10) is disposed in a receptacle (11) having a perforated bottom (7).
PCT/IL2002/000602 2001-06-22 2002-07-21 Wet process and reactor for the recovery of platinum group metals from automobile catalytic converters WO2003010346A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002355201A AU2002355201A1 (en) 2001-06-22 2002-07-21 Wet process and reactor for the recovery of platinum group metals from automobile catalytic converters

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2001117561A RU2209843C2 (en) 2001-06-22 2001-06-22 Method of recovering precipitate metals from automobile catalysts
RU2001117561 2001-07-22

Publications (2)

Publication Number Publication Date
WO2003010346A2 WO2003010346A2 (en) 2003-02-06
WO2003010346A3 true WO2003010346A3 (en) 2003-09-25

Family

ID=20251105

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IL2002/000602 WO2003010346A2 (en) 2001-06-22 2002-07-21 Wet process and reactor for the recovery of platinum group metals from automobile catalytic converters

Country Status (3)

Country Link
AU (1) AU2002355201A1 (en)
RU (1) RU2209843C2 (en)
WO (1) WO2003010346A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2306347C1 (en) * 2005-12-21 2007-09-20 Открытое акционерное общество "Красноярский завод цветных металлов имени В.Н. Гулидова" (ОАО "Красцветмет") Method of processing catalysts containing platinum metals and rhenium on aluminum oxide carriers
RU2363745C1 (en) * 2007-12-21 2009-08-10 Сергей Владимирович Шустов Method of rhenium and platinum concentrates receiving from its cintaining acid liquors
RU2421532C1 (en) * 2010-04-05 2011-06-20 Открытое акционерное общество "Красноярский завод цветных металлов имени В.Н. Гулидова" (ОАО "Красцветмет") Procedure for extraction of rhenium from dead catalyst on supporters out of aluminium oxide containing platinum metals and rhenium
RU2484154C1 (en) * 2012-04-03 2013-06-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный университет" Processing wastes containing nonferrous and platinum metals

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2261284C2 (en) * 2003-09-09 2005-09-27 Открытое акционерное общество "Горно-металлургическая компания "Норильский никель" Method of complex reworking of decontaminated platinum-rhenium catalysts
RU2251582C1 (en) * 2003-10-07 2005-05-10 Общество с ограниченной ответственностью "Интегра Груп. Ру" Method for extracting noble metals from solutions and pulps and reactor for performing the same
BE1017974A3 (en) * 2008-01-30 2010-02-02 Variabel Daniel METHOD FOR THE VALORISATION OF USUAL AND / OR DEFECTIVE CATALYTIC SUPPORT ELEMENTS
RU2364638C1 (en) * 2008-03-24 2009-08-20 Учреждение Российской академии наук Институт неорганической химии им. А.В.Николаева Сибирского отделения РАН Method and device for processing ground scrap produced from dead automobile catalysts
RU2403301C1 (en) * 2009-04-24 2010-11-10 Государственное образовательное учреждение высшего профессионального образования Читинский государственный университет (ЧитГУ) Method of active leaching of metals from ores and concentrates
RU2398899C1 (en) * 2009-12-28 2010-09-10 Общество с ограниченной ответственностью "Промышленная группа "Металлургия благородных металлов" Method of extraxtion of rhenium and/or platinum from deactivated catalysts with aluminium-oxided carrier
RU2464088C1 (en) * 2011-04-18 2012-10-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Юго-Западный государственный университет" (ЮЗГУ) Method of automotive catalyst
RU2563420C2 (en) * 2014-01-29 2015-09-20 Общество с ограниченной ответственностью "Научно-производственное предприятие "Газофторидные Технологии" Dry gas-fluoride technology-based unit for extraction of platinum and other precious metals of platinum group from spent catalysts
PL2985354T3 (en) * 2014-11-10 2017-04-28 Heraeus Deutschland Gmbh & Co Kg Method for removing noble metal from a catalyst support containing noble metals
US11427887B2 (en) 2017-11-27 2022-08-30 The Board Of Trustees Of The University Of Illinois Extraction of selected platinum-group metals from supported catalyst
US11225702B2 (en) 2018-03-15 2022-01-18 The Board Of Regents For Oklahoma State University Platinum group metals recovery
CN110863116B (en) * 2019-10-30 2022-02-15 永兴阳光贵金属有限公司 Noble metal platinum purification device
CN114921651A (en) * 2022-04-25 2022-08-19 江西耐华环保科技有限公司 Waste precious metal recovery treatment method

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Publication number Priority date Publication date Assignee Title
US3985854A (en) * 1974-06-12 1976-10-12 Johnson Matthey & Co., Limited Recovery of PT/RH from car exhaust catalysts
US4069040A (en) * 1973-11-19 1978-01-17 Rhone-Poulenc Industries Method for recovery of platinum and iridium from catalysts
GB2110868A (en) * 1981-11-27 1983-06-22 Alkem Gmbh Dissolution of solids such as solid nuclear reactor fuels
JPS60184043A (en) * 1984-03-01 1985-09-19 Toyobo Co Ltd Preparation of aromatic dicarboxylic acid
US4814021A (en) * 1986-08-01 1989-03-21 Ensr Corporation Apparatus and method for reclassifying electrical apparatus contaminated with PCB
SU1633100A1 (en) * 1988-05-16 1991-03-07 Ленинградский горный институт им.Г.В.Плеханова Method and apparatus for dissolving salt rock
US5417924A (en) * 1991-02-27 1995-05-23 Societe Prolabo Apparatus connectible to a receptacle for condensing fumes generated during chemical reactions
WO1995035160A1 (en) * 1994-06-17 1995-12-28 Chevron U.S.A. Inc. Catalyst support and process for its use

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CS188421B1 (en) * 1975-12-29 1979-03-30 Ivo Peka Method of obtaining platinum from used catalyst
JPS63319054A (en) * 1987-06-19 1988-12-27 Ube Ind Ltd Palladium catalyst recovery method

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US4069040A (en) * 1973-11-19 1978-01-17 Rhone-Poulenc Industries Method for recovery of platinum and iridium from catalysts
US3985854A (en) * 1974-06-12 1976-10-12 Johnson Matthey & Co., Limited Recovery of PT/RH from car exhaust catalysts
GB2110868A (en) * 1981-11-27 1983-06-22 Alkem Gmbh Dissolution of solids such as solid nuclear reactor fuels
JPS60184043A (en) * 1984-03-01 1985-09-19 Toyobo Co Ltd Preparation of aromatic dicarboxylic acid
US4814021A (en) * 1986-08-01 1989-03-21 Ensr Corporation Apparatus and method for reclassifying electrical apparatus contaminated with PCB
SU1633100A1 (en) * 1988-05-16 1991-03-07 Ленинградский горный институт им.Г.В.Плеханова Method and apparatus for dissolving salt rock
US5417924A (en) * 1991-02-27 1995-05-23 Societe Prolabo Apparatus connectible to a receptacle for condensing fumes generated during chemical reactions
WO1995035160A1 (en) * 1994-06-17 1995-12-28 Chevron U.S.A. Inc. Catalyst support and process for its use

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* Cited by examiner, † Cited by third party
Title
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DATABASE WPI Section Ch Week 199205, Derwent World Patents Index; Class H01, AN 1992-040143, XP002231375 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2306347C1 (en) * 2005-12-21 2007-09-20 Открытое акционерное общество "Красноярский завод цветных металлов имени В.Н. Гулидова" (ОАО "Красцветмет") Method of processing catalysts containing platinum metals and rhenium on aluminum oxide carriers
RU2363745C1 (en) * 2007-12-21 2009-08-10 Сергей Владимирович Шустов Method of rhenium and platinum concentrates receiving from its cintaining acid liquors
RU2421532C1 (en) * 2010-04-05 2011-06-20 Открытое акционерное общество "Красноярский завод цветных металлов имени В.Н. Гулидова" (ОАО "Красцветмет") Procedure for extraction of rhenium from dead catalyst on supporters out of aluminium oxide containing platinum metals and rhenium
RU2484154C1 (en) * 2012-04-03 2013-06-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный горный университет" Processing wastes containing nonferrous and platinum metals

Also Published As

Publication number Publication date
RU2209843C2 (en) 2003-08-10
AU2002355201A1 (en) 2003-02-17
WO2003010346A2 (en) 2003-02-06

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