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WO2002080707A1 - Chewable flavor delivery system - Google Patents

Chewable flavor delivery system Download PDF

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Publication number
WO2002080707A1
WO2002080707A1 PCT/US2002/010908 US0210908W WO02080707A1 WO 2002080707 A1 WO2002080707 A1 WO 2002080707A1 US 0210908 W US0210908 W US 0210908W WO 02080707 A1 WO02080707 A1 WO 02080707A1
Authority
WO
WIPO (PCT)
Prior art keywords
delivery system
mesh screen
cellulosic
tobacco substitute
plant material
Prior art date
Application number
PCT/US2002/010908
Other languages
French (fr)
Inventor
John Rizzotto
Eugene Kardelis, Jr.
Original Assignee
Partmers, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Partmers, Inc. filed Critical Partmers, Inc.
Priority to CA002443030A priority Critical patent/CA2443030A1/en
Publication of WO2002080707A1 publication Critical patent/WO2002080707A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B13/00—Tobacco for pipes, for cigars, e.g. cigar inserts, or for cigarettes; Chewing tobacco; Snuff
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10—Chemical features of tobacco products or tobacco substitutes
    • A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes

Definitions

  • the present invention pertains to chewable flavor delivery systems with sustained release of flavorant containing only natural ingredients.
  • Chewing gums as shown by U.S. Patents 5,116,627 and 5,139,787 contain, among other things, a flavoring that the user of the gum desires to have present in the mouth for a period of time.
  • smokeless tobacco In addition to chewing gums, there is a segment of the population that uses what is referred to as smokeless tobacco.
  • the smokeless tobacco is taken orally and can be flavored or unf ⁇ avored.
  • Smokeless tobacco can be chewed much like chewing gum.
  • Chewing tobacco is usually formed in strands or larger pieces of the tobacco leaf.
  • Smokeless tobacco can also be placed loose between the cheek and gum, with this type usually manufactured in small granular form.
  • Another form of smokeless tobacco is finely divided tobacco particles that are packed into porous paper pouches, which are also placed between the cheek and gum.
  • the flavor enjoyment of smokeless tobacco comes partially from the initial flavor burst from any flavors such as peppermint, apple, peach and the like that are added to the tobacco and lastly, the slow release of the tobacco flavor itself.
  • the present invention uses a dried cellulosic material, e.g. cabbage, which is prepared into strand form or relatively coarse granules.
  • the cellulosic material is dried to a moisture content of less than 8% by weight and is prepared in a manner so that at least 30% of the cell walls of the cellulosic material remains in tact.
  • the cellulosic material is combined with flavoring ingredients and a humectant to achieve the final composition which can be chewed or used without chewing in the mouth of a user.
  • one aspect of the present invention is a chewable flavor delivery system comprising in combination; a carrier consisting of an edible cellulosic plant material dried to a moisture content of at or below 8 % by weight, the plant material having at least 30% intact cell walls, a water soluble but not water containing flavoring ingredient in liquid form and capable of entering the intact cell walls in the plant material, and an effective amount of a food safe humectant contained in the delivery system.
  • the present invention is a flavor delivery system comprising in combination; a heat sealable paper pouch adapted to be placed in the mouth of a user, and a mixture comprising an edible cellulosic plant material having at least 30% intact cell walls, a flavoring ingredient, incorporated into the plant material and a humectant, inserted into said paper pouch.
  • the present invention is a tobacco substitute comprising in combination; an edible cellulose plant material dried to a moisture content at or below 8 % by weight, the plant material having at least 30% intact cell walls, a water soluble but not water containing flavoring ingredient in liquid form and capable of entering the intact cell walls in the plant material, and an effective amount of a food safe humectant.
  • the present invention is a tobacco substitute comprising in combination 26 to 46 percent by weight cellulosic plant material having at least about 30% intact cell walls; 29 to 53% by weight humectant; 11 to 14% by weight being one of coffee or caffeine 0.7 to 1 % by weight sweetening agent; and 5 to 10% by weight flavoring ingredient other than tobacco.
  • such an oral tobacco substitute can be manufactured using dried cellulosic material such as freeze dried cabbage.
  • the freeze- dried cabbage is combined with a flavoring, humectant, minor amounts of a sweetener and optionally a coloring ingredient to simulate oral tobacco.
  • the humectant is selected to provide, in the case of smokeless tobacco, like properties of cohesiveness and wetness. In other applications the humectant will act as a lubricant that will not promote microbiological growth while giving the appearance of wetness. In addition to glycerins and propylene glycol vegetable oils can be used.
  • the salient feature of the invention being the use of a cellulosic material dried to a moisture content of 8% or below and having at least 30% of the cell walls in tact.
  • One particular cellulosic material that is found to be particularly effective in the present invention is a freeze dried green cabbage, which is classified as Brassica, oleraeca capitata sold by R. J. Van Drunen & Sons Inc. of Momence, Illinois. Freeze- dried green cabbage granules having a size range from minus twelve (-12) to plus thirty (+30) mesh determined by using a U.S. Standard Sieve Series apparatus are particularly effective for use in the present invention.
  • Table 1 Set forth in Table 1 are a series of compositions that were prepared according to the present invention.
  • Sample 1 in Table 1 was prepared by adding the aspartame and coffee to dry cabbage granules, which were then mixed well. Thereafter, glycerin and flavors were added with further mixing. The composition was then packaged into Dexter No. 11557 heat sealable paper pouches, which are approximately 0.5 inches by 0.8 inches in dimension. Each pouch contained approximately 0.35 grams of the composition. The pouches were pretreated by being dipped into a solution containing, water, Freeze-dried (instant) Colombian Coffee 1A-BBB, natural peppermint flavor 2006, aspartame and Frutarom tobacco flavor 36.210.
  • Colombian Coffee 1A-BBB Colombian Coffee 1A-BBB is the same coffee used in preparing sample 1 and is available from American Instants of Flanders, N.J.
  • the natural peppermint flavor is available from Mother Murphy of Greensboro, N.C. and the tobacco flavoring is available from Frutarom of North Bergen, N.J.
  • the pouches were air dried after dipping and before filling.
  • Sample 2 was prepared using cabbage granules having a particle size of minus
  • Sample 3 was the same as sample 1 except that Irish Creme flavor 867.150/WC supplied by Flavors of North America of Carol Stream, IL was included in addition to the Colombian Instant coffee 1A-BBB.
  • Compositions according to sample 3 were also packaged into pouches similar to those used for samples 1 and 2 with the pouches being pretreated by dipping in a solution containing water, Colombian Instant Coffee Irish Creme flavor 867.150/WC, aspartame and Frutarom tobacco flavor 36.120, followed by drying the dipped pouches prior to filling.
  • Sample 4 was made with cabbage granules having a size of a minus 12 to plus 20 mesh and after mixing were not placed into pouches but were packaged into air tight containers or into film having a good barrier to entry of atmospheric moisture.
  • Sample 5 was produced with 40% by weight cabbage granules having a size of minus 16 to plus 20 mesh and was packaged into an airtight container.
  • Sample 6 was the same as sample 5, except that propylene glycol was substituted for the glycerine.
  • Sample 7 was the same as sample 6 with propylene glycol instead of glycerin with a slight adjustment in the content of the aspartame and the propylene glycol.
  • Sample 8 was a replication of sample 7 using glycerin instead of the propylene glycol.
  • the core of the invention is using a cellulosic plant material in place of gums or synthetic carriers to provide the carrier for the flavor.
  • Maintaining a minimum quantity of the cell walls of the cellulosic material in tact provides a place for the flavoring to be captured and to provide the extended release aspect of the present invention.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Seasonings (AREA)

Abstract

A flavor delivery system, e.g. oral tobacco substitute comprising a cellulosic plant material dried to 8% or less moisture and having at least 30% cell walls intact, coffee or caffeine extract, non-tobacco flavoring, humectant, minor amount of sweetening agent and optional tobacco flavoring. The compositions can be used as prepared or placed in heat sealable paper pouches.

Description

CHEWABLE FLAVOR DELIVERY SYSTEM
BACKGROUND OF THE INVENTION
The present invention pertains to chewable flavor delivery systems with sustained release of flavorant containing only natural ingredients.
Chewing gums, as shown by U.S. Patents 5,116,627 and 5,139,787 contain, among other things, a flavoring that the user of the gum desires to have present in the mouth for a period of time.
Synthetic compositions for providing sustained release of flavorants have been developed. One such composition is illustrated in U.S. Patent 4,992,280.
Even animals have been provided with extended flavor releasing toys, such as shown in U.S. Patent 4,557,219.
In addition to chewing gums, there is a segment of the population that uses what is referred to as smokeless tobacco. The smokeless tobacco is taken orally and can be flavored or unfϊavored. Smokeless tobacco can be chewed much like chewing gum. Chewing tobacco is usually formed in strands or larger pieces of the tobacco leaf. Smokeless tobacco can also be placed loose between the cheek and gum, with this type usually manufactured in small granular form. Another form of smokeless tobacco is finely divided tobacco particles that are packed into porous paper pouches, which are also placed between the cheek and gum.
The flavor enjoyment of smokeless tobacco comes partially from the initial flavor burst from any flavors such as peppermint, apple, peach and the like that are added to the tobacco and lastly, the slow release of the tobacco flavor itself.
In the past, mixing flavors with a substrate such as a cellulose powder has been tried as a tobacco substitute but found to be unsatisfactory. This has been due to the fact that the flavors wash out of the substrate thus, they do not last as long as tobacco based products. Therefore, there is a need to find a tobacco substitute that in essence eliminates the use of the tobacco leaf itself and may use only minor amounts of tobacco flavoring.
BRIEF SUMMARY OF THE INVENTION The present invention uses a dried cellulosic material, e.g. cabbage, which is prepared into strand form or relatively coarse granules. The cellulosic material is dried to a moisture content of less than 8% by weight and is prepared in a manner so that at least 30% of the cell walls of the cellulosic material remains in tact. The cellulosic material is combined with flavoring ingredients and a humectant to achieve the final composition which can be chewed or used without chewing in the mouth of a user.
Therefore, one aspect of the present invention is a chewable flavor delivery system comprising in combination; a carrier consisting of an edible cellulosic plant material dried to a moisture content of at or below 8 % by weight, the plant material having at least 30% intact cell walls, a water soluble but not water containing flavoring ingredient in liquid form and capable of entering the intact cell walls in the plant material, and an effective amount of a food safe humectant contained in the delivery system.
In another aspect the present invention is a flavor delivery system comprising in combination; a heat sealable paper pouch adapted to be placed in the mouth of a user, and a mixture comprising an edible cellulosic plant material having at least 30% intact cell walls, a flavoring ingredient, incorporated into the plant material and a humectant, inserted into said paper pouch.
In yet another aspect the present invention is a tobacco substitute comprising in combination; an edible cellulose plant material dried to a moisture content at or below 8 % by weight, the plant material having at least 30% intact cell walls, a water soluble but not water containing flavoring ingredient in liquid form and capable of entering the intact cell walls in the plant material, and an effective amount of a food safe humectant. In still a further aspect, the present invention is a tobacco substitute comprising in combination 26 to 46 percent by weight cellulosic plant material having at least about 30% intact cell walls; 29 to 53% by weight humectant; 11 to 14% by weight being one of coffee or caffeine 0.7 to 1 % by weight sweetening agent; and 5 to 10% by weight flavoring ingredient other than tobacco.
DETAILED DESCRIPTION OF THE INVENTION
In recent years, much as been written about the oral use of tobacco either as chewing tobacco or what is sometimes referred to as snuff, a finally divided granular tobacco that is placed loosely between the cheek and gum or is packed into porous paper pouches and which can be placed between the cheek and gum of the user.
Confirmed oral tobacco users could attempt to stop the use of conventional oral tobacco products if a chewable flavor delivery system simulating oral tobacco were devised.
According to the present invention, such an oral tobacco substitute can be manufactured using dried cellulosic material such as freeze dried cabbage. The freeze- dried cabbage is combined with a flavoring, humectant, minor amounts of a sweetener and optionally a coloring ingredient to simulate oral tobacco.
The humectant is selected to provide, in the case of smokeless tobacco, like properties of cohesiveness and wetness. In other applications the humectant will act as a lubricant that will not promote microbiological growth while giving the appearance of wetness. In addition to glycerins and propylene glycol vegetable oils can be used.
It is also within the purview of the present invention to achieve other chewable flavor delivery systems, the salient feature of the invention being the use of a cellulosic material dried to a moisture content of 8% or below and having at least 30% of the cell walls in tact.
One particular cellulosic material that is found to be particularly effective in the present invention is a freeze dried green cabbage, which is classified as Brassica, oleraeca capitata sold by R. J. Van Drunen & Sons Inc. of Momence, Illinois. Freeze- dried green cabbage granules having a size range from minus twelve (-12) to plus thirty (+30) mesh determined by using a U.S. Standard Sieve Series apparatus are particularly effective for use in the present invention.
Set forth in Table 1 are a series of compositions that were prepared according to the present invention.
TABLE 1
Figure imgf000005_0001
Sample 1 in Table 1 was prepared by adding the aspartame and coffee to dry cabbage granules, which were then mixed well. Thereafter, glycerin and flavors were added with further mixing. The composition was then packaged into Dexter No. 11557 heat sealable paper pouches, which are approximately 0.5 inches by 0.8 inches in dimension. Each pouch contained approximately 0.35 grams of the composition. The pouches were pretreated by being dipped into a solution containing, water, Freeze-dried (instant) Colombian Coffee 1A-BBB, natural peppermint flavor 2006, aspartame and Frutarom tobacco flavor 36.210. FD (freeze-dried) Colombian Coffee 1A-BBB is the same coffee used in preparing sample 1 and is available from American Instants of Flanders, N.J. The natural peppermint flavor is available from Mother Murphy of Greensboro, N.C. and the tobacco flavoring is available from Frutarom of North Bergen, N.J. The pouches were air dried after dipping and before filling. Sample 2 was prepared using cabbage granules having a particle size of minus
20 plus 30 mesh, natural caffeine anhydrous U.S. P. available from Haglin Flavors of Branchberg, N.J, natural peppermint flavor #2006, caramel color 325 available from Sethness of Clinton, IA, aspartame and Frutarom tobacco flavor 36.210. The pouches into which sample 2 were packed were the same size as the pouches used for sample 1, except that the pouches were dipped into a solution containing water, natural peppermint flavor #2006, caramel color #325, aspartame and Frutarom tobacco flavor 36.210.
Sample 3 was the same as sample 1 except that Irish Creme flavor 867.150/WC supplied by Flavors of North America of Carol Stream, IL was included in addition to the Colombian Instant coffee 1A-BBB. Compositions according to sample 3 were also packaged into pouches similar to those used for samples 1 and 2 with the pouches being pretreated by dipping in a solution containing water, Colombian Instant Coffee Irish Creme flavor 867.150/WC, aspartame and Frutarom tobacco flavor 36.120, followed by drying the dipped pouches prior to filling.
Sample 4 was made with cabbage granules having a size of a minus 12 to plus 20 mesh and after mixing were not placed into pouches but were packaged into air tight containers or into film having a good barrier to entry of atmospheric moisture.
Sample 5 was produced with 40% by weight cabbage granules having a size of minus 16 to plus 20 mesh and was packaged into an airtight container. Sample 6 was the same as sample 5, except that propylene glycol was substituted for the glycerine.
Sample 7 was the same as sample 6 with propylene glycol instead of glycerin with a slight adjustment in the content of the aspartame and the propylene glycol. Sample 8 was a replication of sample 7 using glycerin instead of the propylene glycol.
All of the above samples were tested by users of smokeless tobacco and were found to be acceptable substitutes.
As stated herein before, the core of the invention is using a cellulosic plant material in place of gums or synthetic carriers to provide the carrier for the flavor.
Maintaining a minimum quantity of the cell walls of the cellulosic material in tact provides a place for the flavoring to be captured and to provide the extended release aspect of the present invention.
Having thus described our invention what is desired to be secured by Letters Patent of the United States is set forth in the appended claims.

Claims

What is Claimed: 1. A chewable flavor delivery system comprising in combination: a carrier consisting of an edible cellulosic plant material dried to a moisture content of at or below 8% by weight; said plant material having at least 30% intact cell walls; a water soluble but not water containing flavoring ingredient in liquid form and capable of entering said cell walls of said plant material; and an effective amount of a food safe humectant.
2. A delivery system according to claim 1, wherein said cellulosic plant material is formed into strands.
3. A delivery system according to claim 1, wherein said cellulosic material is in a granular form.
4. A delivery system according to claim 3, wherein said cellulosic material is sized to pass a 16 mesh and be retained on a 30 mesh screen of a U.S. Standard Sieve Series of screens.
5. A delivery system according to claim 4, wherein said cellulosic material is sized to pass a 16 mesh screen and be retained on a 20 mesh screen.
6. A delivery system according to claim 4, wherein said cellulosic material is sized to pass a 20 mesh screen and be retamed on a 30 mesh screen.
7. A delivery system according to claim 1, wherein said humectant is selected from the group consisting of propylene glycol and glycerin.
8. A delivery system according to claim 1, including a minor amount of a sweetening agent.
9. A delivery system according to claim 1, wherein said cellulosic plant material is freeze dried green cabbage classified as Brassica oleracea capitata.
10. A flavor delivery system comprising in combination: a heat sealable paper pouch adapted to be placed in the mouth of a user; and a mixture comprising an edible cellulosic plant material having at least 30% intact cells, a flavoring ingredient, incorporated into said plant material and a humectant, inserted into said paper pouch.
11. A flavor delivery system according to claim 10, wherein said cellulosic material is in a granular form.
12. A flavor delivery system according to claim 11, wherein said cellulosic material is sized to pass a 16 mesh and be retained on a 30 mesh screen of a U.S. Standard Sieve Series of screens.
13. A flavor delivery system according to claim 12, wherein said cellulosic material is sized to pass a 16 mesh screen and be retained on a 20 mesh screen.
14. A flavor delivery system according to claim 12, wherein said cellulosic material is sized to pass a 20 mesh screen and be retained on a 30 mesh screen.
15. A flavor delivery system according to claim 10, wherein said humectant is selected from the group consisting of propylene glycol and glycerin.
16. A flavor delivery system according to claim 10, including a minor amount of a sweetening agent.
17. A flavor delivery system according to claim 10 wherein, said cellulosic plant material is freeze dried green cabbage classified as Brassica oleracea capitata.
18. An oral tobacco substitute comprising in combination: an edible cellulose plant material dried to a moisture content at or below 8 % by weight, said plant material having at least 30% intact cell walls; a water soluble but not water containing flavoring ingredient in liquid form and capable of entering said cell walls of said plant material; and an effective amount of a food safe humectant.
19. A tobacco substitute according to claim 18, wherein said cellulosic plant material is formed into strands.
20. A tobacco substitute according to claim 18, wherein said cellulosic material is in a granular form.
21. A tobacco substitute according to claim 20, wherein said cellulosic material is sized to pass a 16 mesh and be retained on a 30 mesh screen of a U.S. Standard Sieve Series of screens.
22. A tobacco substitute according to claim 21, wherein said cellulosic material is sized to pass a 16 mesh screen and be retained in a 20 mesh screen.
23. A tobacco substitute according to claim 21, wherein said cellulosic material is sized to pass a 20 mesh screen and be retained on a 30 mesh screen.
24. A tobacco substitute according to claim 18, wherein said humectant is selected from the group consisting of propylene glycol and glycerin.
25. A tobacco substitute according to claim 18, including a minor amount of a sweetening agent.
26. A tobacco substitute according to claim 18, wherein said cellulosic plant material is freeze dried green cabbage classified as Brassica oleracea capitata.
27. A tobacco substitute comprising in combination: 26 to 46 percent by weight cellulosic plant material having at least about 30% intact cell walls; 29 to 53 % by weight humectant; 11 to 14% by weight being one of coffee or caffeine 0.7 to 1 % by weight sweetening agent; and 5 to 10% by weight flavoring ingredient other than tobacco.
28. A tobacco substitute according to claim 27, wherein said cellulosic plant material is freeze dried green cabbage classified in Brassica oleracea capituta.
29. A tobacco substitute according to claim 28, wherein said cabbage is in granular form.
30. A tobacco substitute according to claim 29, wherein said cabbage granulars are sized to pass a 16 mesh and be retained on a 30 mesh screen of a U.S. Standard Sieve Series of screens.
31. A tobacco substitute according to claim 30, wherein said cellulosic material is sized to pass a 16 mesh screen and be retained on a 20 mesh screen.
32. A tobacco substitute according to claim 30, wherein said cellulosic material is sized to pass a 20 mesh screen and be retained on a 30 mesh screen.
33. A tobacco substitute according to claim 28, wherein said cabbage is formed into strands.
34. A tobacco substitute according to claim 28, including up to 1 % by weight tobacco flavoring.
35. A tobacco substitute according to claim 28, including an effective amount of a coloring agent to give said cellulosic material to appearance of chewing tobacco.
PCT/US2002/010908 2001-04-06 2002-04-04 Chewable flavor delivery system WO2002080707A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (2)

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US09/827,686 2001-04-06
US09/827,686 US20020170567A1 (en) 2001-04-06 2001-04-06 Chewable flavor delivery system

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Cited By (46)

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WO2007057789A3 (en) * 2005-11-21 2007-10-04 Philip Morris Prod Method of manufacturing flavor pouches
WO2008016520A3 (en) * 2006-08-01 2008-07-24 Reynolds Tobacco Co R Smokeless tobacco
WO2008104891A3 (en) * 2007-02-28 2008-11-06 Philip Morris Prod Oral pouch product with flavored wrapper
WO2009007854A3 (en) * 2007-06-08 2009-03-19 Philip Morris Prod Oral pouch product including soluble dietary fibers
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US7810507B2 (en) 2006-02-10 2010-10-12 R. J. Reynolds Tobacco Company Smokeless tobacco composition
US7861728B2 (en) 2006-02-10 2011-01-04 R.J. Reynolds Tobacco Company Smokeless tobacco composition having an outer and inner pouch
US7950399B2 (en) 2005-04-29 2011-05-31 Philip Morris Usa Inc. Non-tobacco pouch product
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RU2432099C1 (en) * 2010-11-11 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
RU2432101C1 (en) * 2010-11-18 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
RU2432104C1 (en) * 2010-11-23 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
RU2432102C1 (en) * 2010-11-18 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
RU2432100C1 (en) * 2010-11-11 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
RU2432105C1 (en) * 2010-11-23 2011-10-27 Олег Иванович Квасенков Method to make non-smoking product from rustic tobacco
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RU2432868C1 (en) * 2010-10-20 2011-11-10 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
RU2432872C1 (en) * 2010-11-30 2011-11-10 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
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RU2434539C1 (en) * 2010-10-20 2011-11-27 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
RU2438486C1 (en) * 2010-11-23 2012-01-10 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
RU2438484C1 (en) * 2010-11-23 2012-01-10 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
RU2438485C1 (en) * 2010-11-30 2012-01-10 Олег Иванович Квасенков Method for production of non-smoking products of rustic tobacco
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CN103767079A (en) * 2014-01-21 2014-05-07 深圳市凯神科技股份有限公司 Electronic cigarette oil solvent
US8747562B2 (en) 2009-10-09 2014-06-10 Philip Morris Usa Inc. Tobacco-free pouched product containing flavor beads providing immediate and long lasting flavor release
US8863755B2 (en) 2009-02-27 2014-10-21 Philip Morris Usa Inc. Controlled flavor release tobacco pouch products and methods of making
US8950408B2 (en) 2007-07-16 2015-02-10 Philip Morris Usa Inc. Oral pouch product having soft edge
US9027567B2 (en) 2008-12-30 2015-05-12 Philip Morris Usa Inc. Oral pouch product with multi-layered pouch wrapper
US9044049B2 (en) 2005-04-29 2015-06-02 Philip Morris Usa Inc. Tobacco pouch product
US9126704B2 (en) 2010-04-12 2015-09-08 Altria Client Services Inc. Pouch product with improved seal and method
US9888712B2 (en) 2007-06-08 2018-02-13 Philip Morris Usa Inc. Oral pouch products including a liner and tobacco beads
US10039312B2 (en) 2008-11-07 2018-08-07 R. J. Reynolds Tobacco Company Tobacco products and processes
US11793230B2 (en) 2019-12-09 2023-10-24 Nicoventures Trading Limited Oral products with improved binding of active ingredients
US11826462B2 (en) 2019-12-09 2023-11-28 Nicoventures Trading Limited Oral product with sustained flavor release
US11872231B2 (en) 2019-12-09 2024-01-16 Nicoventures Trading Limited Moist oral product comprising an active ingredient
US11969502B2 (en) 2019-12-09 2024-04-30 Nicoventures Trading Limited Oral products
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