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WO2001026806A3 - Possibly dicationic non-metallocene group 4 metal complexes with anionic n, o or p ligands - Google Patents

Possibly dicationic non-metallocene group 4 metal complexes with anionic n, o or p ligands Download PDF

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Publication number
WO2001026806A3
WO2001026806A3 PCT/US2000/028278 US0028278W WO0126806A3 WO 2001026806 A3 WO2001026806 A3 WO 2001026806A3 US 0028278 W US0028278 W US 0028278W WO 0126806 A3 WO0126806 A3 WO 0126806A3
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WO
WIPO (PCT)
Prior art keywords
group
dicationic
possibly
lewis
metal
Prior art date
Application number
PCT/US2000/028278
Other languages
French (fr)
Other versions
WO2001026806A2 (en
Inventor
Eugene Y Chen
William J Kruper Jr
Original Assignee
Dow Chemical Co
Eugene Y Chen
William J Kruper Jr
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co, Eugene Y Chen, William J Kruper Jr filed Critical Dow Chemical Co
Priority to JP2001529859A priority Critical patent/JP2003511427A/en
Priority to EP00975243A priority patent/EP1222025A2/en
Priority to AU13323/01A priority patent/AU1332301A/en
Priority to CA002387258A priority patent/CA2387258A1/en
Priority to US10/088,279 priority patent/US6683199B1/en
Publication of WO2001026806A2 publication Critical patent/WO2001026806A2/en
Publication of WO2001026806A3 publication Critical patent/WO2001026806A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2243—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0252—Nitrogen containing compounds with a metal-nitrogen link, e.g. metal amides, metal guanidides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Possibly dicationic or partially dicationic Group 4 metal compounds having e.g. utility as addition polymerization catalysts, obtainable by contacting a charge-neutral complex having two Lewis basic anionic ligand groups, X, of formula (I), with at least 2 molar equivalents of a charge-neutral, Lewis acidic compound, A, such that ≥2 Lewis basic groups of the Group 4 metal coordination complex are abstracted or partially abstracted, wherein Y?1 and Y2¿ are independently anionic ligand groups that are covalently bonded to M by means of a sigma bond through an oxygen, phosphorus or nitrogen atom, and contain up to 50 atoms, not counting hydrogen, optionally joined through bridging group, J, and further optionally also contain a coordinate/covalent bond to M; J is an optional divalent bridging group having up to 20 atoms not counting hydrogen; j is 0 or 1; M is a Group 4 metal; X1 are independently Lewis bases; x1 is 0, 1, 2.
PCT/US2000/028278 1999-10-12 2000-10-12 Possibly dicationic non-metallocene group 4 metal complexes with anionic n, o or p ligands WO2001026806A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2001529859A JP2003511427A (en) 1999-10-12 2000-10-12 Dicationic non-metallocene group 4 metal complexes
EP00975243A EP1222025A2 (en) 1999-10-12 2000-10-12 Possibly dicationic non-metallocene group 4 metal complexes with anionic n, o or p ligands
AU13323/01A AU1332301A (en) 1999-10-12 2000-10-12 Dicationic non-metallocene group 4 metal complexes
CA002387258A CA2387258A1 (en) 1999-10-12 2000-10-12 Dicationic non-metallocene group 4 metal complexes
US10/088,279 US6683199B1 (en) 1999-10-12 2000-10-12 Dicationic non-metallocene group 4 metal complexes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15902899P 1999-10-12 1999-10-12
US60/159,028 1999-10-12

Publications (2)

Publication Number Publication Date
WO2001026806A2 WO2001026806A2 (en) 2001-04-19
WO2001026806A3 true WO2001026806A3 (en) 2001-12-13

Family

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PCT/US2000/028278 WO2001026806A2 (en) 1999-10-12 2000-10-12 Possibly dicationic non-metallocene group 4 metal complexes with anionic n, o or p ligands

Country Status (5)

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EP (1) EP1222025A2 (en)
JP (1) JP2003511427A (en)
AU (1) AU1332301A (en)
CA (1) CA2387258A1 (en)
WO (1) WO2001026806A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US7910760B2 (en) 2008-04-15 2011-03-22 Exxonmobil Chemical Patents Inc. Semi-rigid linked diamines, precursors therefor, and transition metal diamido complexes as catalysts for olefin polymerization processes

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0694548A1 (en) * 1994-07-29 1996-01-31 ENICHEM ELASTOMERI S.r.l. Organometallic derivatives of group IIIA and process for their preparation
JPH08245713A (en) * 1995-03-08 1996-09-24 Sumitomo Chem Co Ltd Olefin polymerization catalyst and method for producing ethylene-α-olefin copolymer
WO1998046651A2 (en) * 1997-04-11 1998-10-22 Massachusetts Institute Of Technology Living olefin polymerization processes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0694548A1 (en) * 1994-07-29 1996-01-31 ENICHEM ELASTOMERI S.r.l. Organometallic derivatives of group IIIA and process for their preparation
JPH08245713A (en) * 1995-03-08 1996-09-24 Sumitomo Chem Co Ltd Olefin polymerization catalyst and method for producing ethylene-α-olefin copolymer
WO1998046651A2 (en) * 1997-04-11 1998-10-22 Massachusetts Institute Of Technology Living olefin polymerization processes

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
BAUMANN ET AL: "Titanium and Zirconium Complexes That Contain the Tridentate Diamido Ligands [(i-PrN-o-C6H4)2O]2- ([i-PrNON]2-) and [(C6H11N-o-C6H4)2O]2- ([CyNON]2-)", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC,US, vol. 121, no. 34, 1 September 1999 (1999-09-01), pages 7822 - 7836, XP002136125, ISSN: 0002-7863 *
BAUMANN R ET AL: "SYNTHESIS OF TITANIUM AND ZIRCONIUM COMPLEXES THAT CONTAIN THE TRIDENTATE DIAMIDO LIGAND, U((T-BU-D6)N-O-C6H4)2O2- (UNON2-) AND THE LIVING POLYMERIZATION OF 1-HEXENE BY ACTIVATED UNONZRME2", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,US,AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, vol. 119, 2 June 1997 (1997-06-02), pages 3830 - 3831, XP002062057, ISSN: 0002-7863 *
DATABASE CHEMABS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KURIBAYASHI, HIROSHI ET AL: "Catalysts for manufacture of high-molecular-weight ethylene-.alpha.-olefin copolymers", XP002163152, retrieved from STN Database accession no. 126:8814 *
EWEN J A: "PROPYLENE POLYMERIZATIONS WITH METALLOCENE/TEAL/TRITYL TETRAKIS (PENTAFLUOROPHENYL) ALUMINATE MIXTURES", STUDIES IN SURFACE SCIENCE AND CATALYSIS,NL,ELSEVIER SCIENCE B.V., AMSTERDAM, vol. 89, 1994, pages 405 - 410, XP000886125, ISSN: 0167-2991 *
GREEN M L H, ET AL.: "Evidence for zirconocene dications in Kaminsky type catalysts", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS ISSN: 0022-4936, 1999, pages 115 - 116, XP000984763 *
LIANG, LAN-CHANG ET AL: "Synthesis of Titanium, Zirconium, and Hafnium Complexes That Contain the [(MesitylN-o-C6H4)2O]2- Ligand", ORGANOMETALLICS, vol. 19, no. 13, 26 June 2000 (2000-06-26), pages 2526 - 2531, XP000984799 *
SCHROCK, RICHARD R. ET AL: "Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2- and an Evaluation of Activated Versions for the Polymerization of 1-Hexene", ORGANOMETALLICS, vol. 18, no. 18, 30 August 1999 (1999-08-30), pages 3649 - 3670, XP000984798 *
See also references of EP1222025A2 *

Also Published As

Publication number Publication date
EP1222025A2 (en) 2002-07-17
JP2003511427A (en) 2003-03-25
AU1332301A (en) 2001-04-23
WO2001026806A2 (en) 2001-04-19
CA2387258A1 (en) 2001-04-19

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