WO2001000068A1 - Plastic pesticide packing cover or storage unit - Google Patents
Plastic pesticide packing cover or storage unit Download PDFInfo
- Publication number
- WO2001000068A1 WO2001000068A1 PCT/FR2000/001808 FR0001808W WO0100068A1 WO 2001000068 A1 WO2001000068 A1 WO 2001000068A1 FR 0001808 W FR0001808 W FR 0001808W WO 0100068 A1 WO0100068 A1 WO 0100068A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- material according
- packaging material
- packaging
- methyl
- storage unit
- Prior art date
Links
- 238000003860 storage Methods 0.000 title claims abstract description 18
- 239000004033 plastic Substances 0.000 title abstract description 10
- 229920003023 plastic Polymers 0.000 title abstract description 10
- 238000012856 packing Methods 0.000 title abstract 5
- 239000000575 pesticide Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 23
- 230000001681 protective effect Effects 0.000 claims abstract description 14
- 239000002985 plastic film Substances 0.000 claims abstract description 13
- 229920006255 plastic film Polymers 0.000 claims abstract description 13
- 230000000895 acaricidal effect Effects 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000004753 textile Substances 0.000 claims abstract description 7
- 238000004806 packaging method and process Methods 0.000 claims description 17
- 239000003096 antiparasitic agent Substances 0.000 claims description 13
- 229940125687 antiparasitic agent Drugs 0.000 claims description 12
- -1 d-phenothrin Chemical compound 0.000 claims description 11
- 239000000642 acaricide Substances 0.000 claims description 9
- 239000005022 packaging material Substances 0.000 claims description 9
- 239000002728 pyrethroid Substances 0.000 claims description 8
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 4
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 claims description 3
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005770 Eugenol Substances 0.000 claims description 2
- VHVOLFRBFDOUSH-NSCUHMNNSA-N Isosafrole Chemical compound C\C=C\C1=CC=C2OCOC2=C1 VHVOLFRBFDOUSH-NSCUHMNNSA-N 0.000 claims description 2
- VHVOLFRBFDOUSH-UHFFFAOYSA-N Isosafrole Natural products CC=CC1=CC=C2OCOC2=C1 VHVOLFRBFDOUSH-UHFFFAOYSA-N 0.000 claims description 2
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims description 2
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 2
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 235000000484 citronellol Nutrition 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- IITCWRFYJWUUPC-UHFFFAOYSA-N dipropyl pyridine-2,5-dicarboxylate Chemical compound CCCOC(=O)C1=CC=C(C(=O)OCCC)N=C1 IITCWRFYJWUUPC-UHFFFAOYSA-N 0.000 claims description 2
- 229960002217 eugenol Drugs 0.000 claims description 2
- 239000004306 orthophenyl phenol Substances 0.000 claims description 2
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 2
- 229960003536 phenothrin Drugs 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 241000238876 Acari Species 0.000 abstract description 14
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 206010003645 Atopy Diseases 0.000 abstract description 2
- 230000000172 allergic effect Effects 0.000 abstract description 2
- 208000010668 atopic eczema Diseases 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000005871 repellent Substances 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000002141 anti-parasite Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/28—Applications of food preservatives, fungicides, pesticides or animal repellants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G25/00—Household implements used in connection with wearing apparel; Dress, hat or umbrella holders
- A47G25/54—Dust- or moth-proof garment bags, e.g. with suit hangers
- A47G25/58—Moth-proof bags with provisions for pesticides or pest repellants
Definitions
- Plastic packaging or pest control storage unit Plastic packaging or pest control storage unit.
- the present invention relates to a plastic pest protection package which can be used for professional and family storage of wardrobes, wardrobes and all other types of storage packaging for the home or business.
- the invention also relates to the use of this antiparasitic material in the manufacture of hanging cupboards or storage boxes.
- the invention more specifically relates to a material as defined above, characterized in that it contains antiparasitic agents used in particular against bacteria, fungicides, mites and mites.
- antiparasitic agents used in particular against bacteria, fungicides, mites and mites.
- agents consisting of non-polar liquids capable of mixing with the resin at high temperature (between 50 ° C. and 140 ° C. depending on the nature of the material) are used.
- antiparasitic agent is intended to denote a liquid miticide, a liquid repellant and a liquid antimite.
- antiparasitic agents are: synthetic pyrethroids such as 1-ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'- (iichlorovinyl) -cyclopropane- 1 -carboxylate, 1 - ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2'-methyl-l--propenyl) -cyclopropane-1 -carboxylate and 1- ethynyl-2-methyl-2-pentenyl-2, 2,3,3, -tetramethylcyclopropane carboxylate (for example PROFYL AK 14 marketed by the company BREYNER) and chemical compounds such as N, N-diethyl-m-toluamide, 2,3,4,5-bis ( 2-
- the invention more specifically relates to a material as defined above, characterized in that it contains 0.5 mg to 2 g of antiparasitic agent per m2.
- the invention is illustrated by tests carried out on a plastic film material impregnated with pyrethroid, namely l-ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'-dichlorovinyl) - cyclopropane-1 -carboxylate; this example illustrates the invention without limiting it.
- the plastic films according to the invention are impregnated in their bulk by hot addition of pyrethroid either in solution at 10.5 g / liter in acetone with 0.1% acetic acid, or in solution at 75 g liter in xylene, when the plastic is extruded.
- the invention therefore relates to a material as described above, characterized in that the impregnation of the plastic film with the active principle is carried out in the mass.
- the plastic films according to the invention contain from 30 to 650 mg m2 of active principle and more particularly 30 to 370 mg / m2 of pyrethroid, that is to say a pyrethroid concentration of 0.2 to 0.5%.
- the plastic films used for the invention can be of different types. Polyvinyl chloride, polyethylene, polypropylene or polyvinyl ethylene acetate, etc. are used, for example.
- the thickness of the plastic films can vary from 0.02 to 1.5mm.
- the invention relates to the application of the plastic material defined above, characterized in that the protective packaging is endowed with acaricidal and acarifuge properties. Tests carried out on a population of dust mites show the acaricide and repellency activity of the film of plastic material treated with pyrethroids used for protective protective packaging.
- the invention also relates to the application of the plastic material defined above, characterized in that the protective packaging is endowed with a capacity for transferring acaricide properties to the textile material stored inside the cover which it either natural (cotton for example) and / or synthetic (polyesters for example).
- the invention specifically relates to the application of the material as described above for professional or family storage, such as those intended for bedding (mattress cover, pillow cover, cover cover, sheet cover, duvet cover etc.), storage of clothes (suit cover, shirt cover, woolen cover etc.), storage of clothing accessories (laundry bag, shoe bag etc.) etc.
- the invention also relates to the use of this material in the manufacture of storage units, hanging cupboards, storage boxes etc. These examples are given as an indication but not limiting.
- the subject of the invention is therefore a protective packaging material as defined above, characterized in that this packaging is endowed with anti-mite and anti-mite properties.
- the antiparasitic agents thus impregnated on various plastic storage supports constitute an effective response to the development of mites on and in the storage unit; these protective packaging can therefore be particularly recommended for individuals allergic to mites and also to members of families with atopics.
- the following examples illustrate the invention without limiting it.
- a polypropylene film of 2 m2 is produced which is impregnated hot, in the mass at the time of the extrusion of the plastic material by addition of a solution at 10.5 g / liter of pyrethroid of chemical formula 1-ethynyl- 2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'-dichlorovinyl) -cyclopropane-1-carboxylate in acetone with 0.1% acetic acid.
- An amount of antiparasitic agent is used such that the polypropylene film contains 150 mg of antiparasitic agent per m2, ie 0.4% of pyrethroid.
- the study is carried out by depositing mites on polypropylene supports containing 0.4% of antiparasitic agent produced as described above; the same study is carried out on a neutral support as a control. This neutral support is not impregnated in the mass of pest control agent.
- Treated polypropylene is used which is placed in a 5cm diameter enclosure which is tight against mites (no leaks) but which allows ventilation (filter paper) and in which: 0.05 g of nutritive substrate / dust intended to ensure the food survival a piece of polypropylene lining the ground of this arena
- the study is carried out by depositing 25 pairs of mites in these devices. 4 repetitions are performed per experimental factor, including for control batches made up of the same device but with the neutral support.
- Mortality is determined by counting and monitored 2 days, 7 days, 4 weeks and 6 weeks after deposit of the mites on the treated or control supports. The counts give the data in number of surviving mites.
- the treated polypropylene shows a complete elimination of the mite populations after 2 development cycles (6 weeks).
- the treated plastic film is endowed with an interesting acaricide and acarifuge activity.
- the study is carried out on a protective packaging of a pillowcase cover (size: 33 / 33cm) made from a 0.4% pyrethroid polypropylene film treated as described above. A 65/65 cm pillowcase cover made of 100% cotton is placed inside this packaging. The same tests are carried out in comparison with an untreated packaging. After 6 weeks and 12 weeks, the impact of the treatment of the protective packaging on the development of the mite population on the cotton cover stored inside the packaging relative to the control is determined. , by counting the mites present on the cotton cover. 4 repetitions are performed, including for the control batches.
- the protective packaging in treated plastic film is endowed with a capacity to transfer acaricide properties on the textile material stored inside the packaging.
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Mechanical Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
The invention concerns a plastic pesticide protective packing or a storage unit for storing textiles (slip cover) and professional and household textile objects. The invention also concerns the use of said material for making storage units. Said packing can be made of different types of plastic films. The pesticide agent (or combinations thereof) used in the invention is a nonpolar liquid capable of being mixed with resin at high temperature. The inventive protective packing is provided with an acaricidal, mite-repellent and moth-repellent activity. Said protective packing also has the capacity of transferring the acaricidal properties to the contacted textile material stored inside said cover. The invention provides an efficient solution to fight against mites on and inside the storage unit, and is recommended for people allergic to mites and to members of atopic families.
Description
Housse d'emballage ou unité de rangement antiparasitaire en plastique. Plastic packaging or pest control storage unit.
La présente invention concerne un emballage de protection antiparasitaire en plastique qui peut être utilisée pour les rangements professionnels et familiaux de gardes robes, de penderies et tous autres types d'emballages de rangement de la maison ou des entreprises. L'invention concerne également l'utilisation de ce matériau antiparasitaire dans la confection d'armoires suspendues ou de boites de rangement.The present invention relates to a plastic pest protection package which can be used for professional and family storage of wardrobes, wardrobes and all other types of storage packaging for the home or business. The invention also relates to the use of this antiparasitic material in the manufacture of hanging cupboards or storage boxes.
L'invention a plus précisément pour objet un matériau tel que défini précédemment, caractérisé en ce qu'il contient des agents antiparasitaires utilisés en particulier contre les bactéries, les fongicides, les acariens et les mites. Couramment, on utilise des agents constitués par des liquides apolaires aptes à se mélanger à la résine à température élevée (entre 50°C et 140°C selon la nature du matériau).The invention more specifically relates to a material as defined above, characterized in that it contains antiparasitic agents used in particular against bacteria, fungicides, mites and mites. Currently, agents consisting of non-polar liquids capable of mixing with the resin at high temperature (between 50 ° C. and 140 ° C. depending on the nature of the material) are used.
Dans le cadre de l'invention, l'expression «agent antiparasitaire » est destiné à désigner un acaricide liquide, un agent répulsif liquide et un antimite liquide. Couramment les agents antiparasitaires sont : des pyrèthrinoïdes synthétiques tels que l-éthynyl-2-méthyl-2-pentényl-2,2-diméthyl-3-(2', 2'- (iïchlorovinyl)-cyclopropane- 1 -carboxylate, 1 -éthynyl-2-méthyl-2-pentényl- 2,2-diméthyl-3-(2'-méthyl-l '-propényl)-cyclopropane-l -carboxylate et 1- éthynyl-2-méthyl-2-pentényl-2,2,3,3,-tétraméthylcyclopropane carboxylate (par exemple PROFYL AK 14 mis sur le marché par la société BREYNER) et des composés chimiques tels que N,N-diéthyl-m-toluamide, 2,3,4,5-bis (2- butylène)-tétι^ydrofιιrfural, isocinchoméronate di-n-propylique, phtalate dibutylique, d-phénothrine, butoxyde de pipéronyle et orthophénylphénol ainsi que les antimites liquides tel que citronellol, eugènol ou isosafrol. Suivant l'invention ces agents antiparasitaires peuvent être utilisés séparément ou simultanément sous forme de combinaisons.
L'invention a également pour objet un matériau tel que défini précédemment, caractérisé en ce qu'il est constitué par un film de matière plastique.In the context of the invention, the expression “antiparasitic agent” is intended to denote a liquid miticide, a liquid repellant and a liquid antimite. Commonly antiparasitic agents are: synthetic pyrethroids such as 1-ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'- (iichlorovinyl) -cyclopropane- 1 -carboxylate, 1 - ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2'-methyl-l--propenyl) -cyclopropane-1 -carboxylate and 1- ethynyl-2-methyl-2-pentenyl-2, 2,3,3, -tetramethylcyclopropane carboxylate (for example PROFYL AK 14 marketed by the company BREYNER) and chemical compounds such as N, N-diethyl-m-toluamide, 2,3,4,5-bis ( 2- butylene) -tétι ^ ydrofιιrfural, di-n-propyl isocinchomeronate, dibutyl phthalate, d-phenothrin, piperonyl butoxide and orthophenylphenol as well as liquid mites such as citronellol, eugenol or isosafrol. used separately or simultaneously as combinations. The invention also relates to a material as defined above, characterized in that it consists of a plastic film.
L'invention a plus précisément pour objet un matériau tel que défini précédemment, caractérisé en ce qu'il contient 0,5 mg à 2 g d'agent antiparasitaire par m2.The invention more specifically relates to a material as defined above, characterized in that it contains 0.5 mg to 2 g of antiparasitic agent per m2.
L'invention est illustrée par des tests réalisés sur un matériau de film plastique imprégné de pyrèthrinoïde soit le l-éthynyl-2-méthyl-2-pentényl-2,2- diméthyl-3-(2', 2'-dichlorovinyl)-cyclopropane-l -carboxylate ; cet exemple illustre l'invention sans la limiter. Les films de matière plastique selon l'invention sont imprégnés dans leur masse par addition à chaud de pyrèthrinoïde soit en solution à 10,5 g /litre dans l'acétone à 0,1 % d'acide acétique, soit en solution à 75 g litre dans le xylène, au moment de l'extrusion de la matière plastique.The invention is illustrated by tests carried out on a plastic film material impregnated with pyrethroid, namely l-ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'-dichlorovinyl) - cyclopropane-1 -carboxylate; this example illustrates the invention without limiting it. The plastic films according to the invention are impregnated in their bulk by hot addition of pyrethroid either in solution at 10.5 g / liter in acetone with 0.1% acetic acid, or in solution at 75 g liter in xylene, when the plastic is extruded.
L'invention a donc pour objet un matériau tel que décrit précédemment, caractérisé en ce que l'imprégnation du film plastique par le principe actif est effectuée dans la masse.The invention therefore relates to a material as described above, characterized in that the impregnation of the plastic film with the active principle is carried out in the mass.
Les films de matière plastique selon l'invention contiennent de 30 à 650 mg m2 de principe actif et plus particulièrement 30 à 370 mg/m2 de pyrèthrinoïde soit une concentration en pyrèthrinoïde de 0.2 à 0.5 %. Les films plastiques utilisés pour l'invention peuvent être de différentes natures. On utilise, par exemple, du chlorure de polyvinyle, du polyéthylène, du polypropylène ou de l'acétate de polyvinyle éthylène, etc. L'épaisseur des films de matière plastique peut varier de 0.02 à 1.5mm.The plastic films according to the invention contain from 30 to 650 mg m2 of active principle and more particularly 30 to 370 mg / m2 of pyrethroid, that is to say a pyrethroid concentration of 0.2 to 0.5%. The plastic films used for the invention can be of different types. Polyvinyl chloride, polyethylene, polypropylene or polyvinyl ethylene acetate, etc. are used, for example. The thickness of the plastic films can vary from 0.02 to 1.5mm.
L'invention a pour objet l'application du matériau plastique défini précédemment, caractérisé en ce que les emballages de protection sont doués de propriétés acaricides et acarifuges. Des tests réalisés sur une population d'acariens de la poussière montrent l'activité acaricide et acarifuge du film de
matière plastique traité par des pyrèthrinoïdes utilisé pour l'emballage de protection de protection.The invention relates to the application of the plastic material defined above, characterized in that the protective packaging is endowed with acaricidal and acarifuge properties. Tests carried out on a population of dust mites show the acaricide and repellency activity of the film of plastic material treated with pyrethroids used for protective protective packaging.
L'invention a également pour objet l'application du matériau plastique défini précédemment, caractérisé en ce que les emballages de protection sont doués d'une capacité de transfert des propriétés acaricides sur la matière textile rangée à l'intérieur de la housse qu'elle soit naturelle (coton par exemple) et/ou synthétique (polyesters par exemple).The invention also relates to the application of the plastic material defined above, characterized in that the protective packaging is endowed with a capacity for transferring acaricide properties to the textile material stored inside the cover which it either natural (cotton for example) and / or synthetic (polyesters for example).
Des exemples de ces tests sont donnés plus loin dans la partie expérimentale. Le matériau utilisé selon l'invention est également doué de propriétés antimites.Examples of these tests are given later in the experimental part. The material used according to the invention is also endowed with mothproof properties.
L'invention a précisément pour objet l'application du matériau tel que décrit précédemment pour les rangements professionnels ou familiaux, comme ceux destinés à la literie (housse de matelas, housse d'oreiller, housse de couverture, housse de draps, housse de couette etc.), le rangement des vêtements (housse de costume, housse de chemise, housse de lainage etc.), le rangement des accessoires de vêtements (sac à linge, sac à chaussure etc.) etc.The invention specifically relates to the application of the material as described above for professional or family storage, such as those intended for bedding (mattress cover, pillow cover, cover cover, sheet cover, duvet cover etc.), storage of clothes (suit cover, shirt cover, woolen cover etc.), storage of clothing accessories (laundry bag, shoe bag etc.) etc.
L'invention concerne également l'utilisation de ce matériau dans la confection d'unités de stockage, d'armoires suspendues, de boites de rangement etc. Ces exemples sont donnés à titre indicatif mais non limitatif.The invention also relates to the use of this material in the manufacture of storage units, hanging cupboards, storage boxes etc. These examples are given as an indication but not limiting.
L'invention a donc pour objet un matériau d'emballage de protection tel que défini précédemment caractérisé en ce que cet emballage est doué de propriétés antiacariens et antimites. Les agents antiparasitaires ainsi imprégnés sur différents supports de rangement en matière plastique, constituent une réponse efficace au développement des acariens sur et dans l'unité de rangement ; ces emballages de protection peuvent donc être tout particulièrement recommandés aux individus allergiques aux acariens et aussi aux membres des familles d'atopiques.
Les exemples suivants illustrent l'invention sans la limiter.The subject of the invention is therefore a protective packaging material as defined above, characterized in that this packaging is endowed with anti-mite and anti-mite properties. The antiparasitic agents thus impregnated on various plastic storage supports constitute an effective response to the development of mites on and in the storage unit; these protective packaging can therefore be particularly recommended for individuals allergic to mites and also to members of families with atopics. The following examples illustrate the invention without limiting it.
Film de matière plastique imprégné d'agent antiparasitairePlastic film impregnated with pest control agent
On fabrique un film de polypropylène de 2 m2 que l'on imprègne à chaud, dans la masse au moment de l'extrusion de la matière plastique par addition d'une solution à 10.5 g /litre de pyrèthrinoïde de formule chimique 1-éthynyl- 2-méthyl-2-pentényl-2,2-diméthyl-3-(2', 2'-dichlorovinyl)-cyclopropane-l- carboxylate dans l'acétone à 0.1% d'acide acétique. On utilise une quantité d'agent antiparasitaire telle que le film de polypropylène contienne 150 mg d'agent antiparasitaire par m2 soit 0,4 % de pyréthrènoïde. Exemple 1 : étude de l'activité acaricide et acarifuge du matériau traité suivant l'inventionA polypropylene film of 2 m2 is produced which is impregnated hot, in the mass at the time of the extrusion of the plastic material by addition of a solution at 10.5 g / liter of pyrethroid of chemical formula 1-ethynyl- 2-methyl-2-pentenyl-2,2-dimethyl-3- (2 ', 2'-dichlorovinyl) -cyclopropane-1-carboxylate in acetone with 0.1% acetic acid. An amount of antiparasitic agent is used such that the polypropylene film contains 150 mg of antiparasitic agent per m2, ie 0.4% of pyrethroid. Example 1 Study of the Miticide and Miticide Activity of the Material Treated According to the Invention
L'étude est effectuée par dépôt d'acariens sur des supports en polypropylène contenant 0,4 % d'agent antiparasitaire réalisé tel que décrit précédemment ; la même étude est réalisée sur un support neutre comme témoin. Ce support neutre est non imprégné dans la masse d'agent antiparasitaire.The study is carried out by depositing mites on polypropylene supports containing 0.4% of antiparasitic agent produced as described above; the same study is carried out on a neutral support as a control. This neutral support is not impregnated in the mass of pest control agent.
On utilise du polypropylène traité que l'on place dans une enceinte de 5cm de diamètre étanche aux acariens (pas de fuites) mais autorisant une aération (papier filtre) et dans laquelle se trouve : 0.05g de substrat nutritif /poussière destiné à assurer la survie alimentaire un morceau de polypropylène tapissant le sol de cette arèneTreated polypropylene is used which is placed in a 5cm diameter enclosure which is tight against mites (no leaks) but which allows ventilation (filter paper) and in which: 0.05 g of nutritive substrate / dust intended to ensure the food survival a piece of polypropylene lining the ground of this arena
L'étude est effectuée par dépôt de 25 couples d'acariens dans ces dispositifs. 4 répétitions sont réalisées par facteur expérimental, y compris pour les lots témoins constitués du même dispositif mais avec le support neutre.The study is carried out by depositing 25 pairs of mites in these devices. 4 repetitions are performed per experimental factor, including for control batches made up of the same device but with the neutral support.
La mortalité est déterminée par comptage et contrôlée 2 jours, 7 jours, 4 semaines et 6 semaines après dépôt des acariens sur les supports traités ou témoins. Les comptages donnent les données en nombre d'acariens survivants.Mortality is determined by counting and monitored 2 days, 7 days, 4 weeks and 6 weeks after deposit of the mites on the treated or control supports. The counts give the data in number of surviving mites.
Les résultats expérimentaux obtenus sont résumés dans le tableau qui suit :
The experimental results obtained are summarized in the following table:
Conclusion : Aux doses d'imprégnation utilisées, le polypropylène traité montre une élimination complète des populations d'acariens après 2 cycles de développement (6 semaines). Le film de matière plastique traité est doué d'une activité acaricide et acarifuge intéressante.Conclusion: At the impregnation doses used, the treated polypropylene shows a complete elimination of the mite populations after 2 development cycles (6 weeks). The treated plastic film is endowed with an interesting acaricide and acarifuge activity.
Exemple 2 : étude de l'évolution des populations d'acariens sur la matière textile au contact de l'emballage traité suivant l'inventionEXAMPLE 2 Study of the Evolution of Mite Populations on the Textile Material in Contact with the Packaging Treated According to the Invention
L'étude est réalisée sur un emballage de protection de housse de taie d'oreiller (dimension : 33 /33cm) confectionnée à partir d'un film de polypropylène 0,4 % pyrèthrynoïde traité comme décrit précédemment. On place à l'intérieur de cet emballage une housse de taie d'oreiller 65 /65 cm en 100% coton. On effectue les mêmes tests en comparaison avec un emballage non traité. Au bout de 6 semaines et 12 semaines, on détermine l'impact du traitement de l'emballage de protection sur l'évolution de la population d'acariens sur la housse de coton rangée à l'intérieur de l'emballage par rapport au témoin, par comptage des acariens présents sur la housse de coton. 4 répétitions sont réalisées, y compris pour les lots témoins.The study is carried out on a protective packaging of a pillowcase cover (size: 33 / 33cm) made from a 0.4% pyrethroid polypropylene film treated as described above. A 65/65 cm pillowcase cover made of 100% cotton is placed inside this packaging. The same tests are carried out in comparison with an untreated packaging. After 6 weeks and 12 weeks, the impact of the treatment of the protective packaging on the development of the mite population on the cotton cover stored inside the packaging relative to the control is determined. , by counting the mites present on the cotton cover. 4 repetitions are performed, including for the control batches.
Des tests similaires ont été réalisés avec une housse de taie d'oreiller 65 /65 cm en 100% polyesters.Similar tests were carried out with a 65/65 cm pillowcase cover made of 100% polyester.
Les résultats expérimentaux obtenus sont résumés dans le tableau suivant :
The experimental results obtained are summarized in the following table:
Conclusion : Aux doses d'imprégnation utilisées, l'emballage de protection en film de matière plastique traité est doué d'une capacité de transfert des propriétés acaricides sur la matière textile rangée à l'intérieur de l'emballage.
Conclusion: At the impregnation doses used, the protective packaging in treated plastic film is endowed with a capacity to transfer acaricide properties on the textile material stored inside the packaging.
Claims
1. Matériau d'emballage, caractérisé en ce qu'il représente une housse de protection ou une unité de rangement.1. Packaging material, characterized in that it represents a protective cover or a storage unit.
2. Matériau d'emballage selon la revendication 1, caractérisé en ce qu'il est constitué par du film de matière plastique.2. Packaging material according to claim 1, characterized in that it consists of plastic film.
3. Matériau d'emballage selon la revendication 2, caractérisé en ce qu'il contient au moins un agent antiparasitaire choisi parmi les pyrèthrinoïdes de synthèse tel que 1 -éthynyl-2-méthyl-2-ρentényl-2,2-diméthyl-3-(2', 2'-dichlorovinyl)- cyclopropane-1 -carboxylate, 1 -éthynyl-2-méthyl-2-pentényl-2,2-diméthyl-3- (2' -méthyl- 1 '-propényl)-cyclopropane-l -carboxylate et 1 -éthynyl-2-méthyl-2- pentényl-2,2,3,3,-tétraméthylcyclopropane carboxylate.3. Packaging material according to claim 2, characterized in that it contains at least one antiparasitic agent chosen from synthetic pyrethroids such as 1-ethynyl-2-methyl-2-ρentenyl-2,2-dimethyl-3 - (2 ', 2'-dichlorovinyl) - cyclopropane-1 -carboxylate, 1-ethynyl-2-methyl-2-pentenyl-2,2-dimethyl-3- (2' -methyl- 1 '-propenyl) -cyclopropane -l -carboxylate and 1 -ethynyl-2-methyl-2-pentenyl-2,2,3,3, -tetramethylcyclopropane carboxylate.
4. Matériau d'emballage selon l'une quelconque revendication 2 ou 3, caractérisé en ce qu'il contient au moins un agent antiparasitaire choisi parmi les composés chimiques suivant : N,N-diéthyl-m-toluamide, 2,3 ,4, 5 -bis (2- butylène)-tétrahydrofurfural, isocinchoméronate di-n-propylique, phtalate dibutylique, d-phénothrine, butoxyde de pipéronyle et orthophénylphénol.4. Packaging material according to any one of claims 2 or 3, characterized in that it contains at least one antiparasitic agent chosen from the following chemical compounds: N, N-diethyl-m-toluamide, 2,3, 4 , 5 -bis (2-butylene) -tetrahydrofurfural, di-n-propyl isocinchomeronate, dibutyl phthalate, d-phenothrin, piperonyl butoxide and orthophenylphenol.
5. Matériau d'emballage selon l'une quelconque revendication 2 à 4, caractérisé en ce qu'il contient au moins un antimite liquide tel que citronellol, eugènol ou isosafrol.5. Packaging material according to any one of claims 2 to 4, characterized in that it contains at least one liquid moth such as citronellol, eugenol or isosafrol.
6. Matériau d'emballage selon l'une quelconque des revendications 2 à 5, caractérisé en ce qu'il est contient de 0,5 mg à 2 g par m2 dudit agent antiparasitaire ou de leurs combinaisons.6. Packaging material according to any one of claims 2 to 5, characterized in that it contains from 0.5 mg to 2 g per m2 of said antiparasitic agent or their combinations.
7. Matériau d'emballage selon l'une quelconque des revendications 1 à 3 ou 6, caractérisé en ce qu'il est contient de 0,2 à 0,5 % de pyrèthrinoïde de synthèse.7. Packaging material according to any one of claims 1 to 3 or 6, characterized in that it contains 0.2 to 0.5% of synthetic pyrethroid.
8. Matériau d'emballage selon l'une quelconque des revendications 2 à 7, caractérisé en ce que l'imprégnation du film de matière plastique par l'agent antiparasitaire, est effectuée à chaud, dans la masse. 8. Packaging material according to any one of claims 2 to 7, characterized in that the impregnation of the plastic film with the antiparasitic agent, is carried out hot, in the mass.
. Application du matériau selon les revendications 1 à 8, caractérisé en ce que les emballages de protection ou les unités de rangement sont doués de propriétés acaricides, acarifuges et antimites.. Application of the material according to Claims 1 to 8, characterized in that the protective packaging or the storage units are provided with acaricide, acarifuge and mothproof properties.
10. Application du matériau selon les revendications 1 à 9, caractérisé en ce que les emballages ou les unités de rangement sont doués d'une capacité de transfert des propriétés acaricides sur la matière textile protégée. 10. Application of the material according to claims 1 to 9, characterized in that the packaging or the storage units are provided with a capacity for transferring acaricide properties to the protected textile material.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR9908660A FR2795611A1 (en) | 1999-06-29 | 1999-06-29 | PROTECTIVE PACKAGING OR PLASTIC PEST STORAGE UNIT |
FR99/08660 | 1999-06-29 |
Publications (1)
Publication Number | Publication Date |
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WO2001000068A1 true WO2001000068A1 (en) | 2001-01-04 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/FR2000/001808 WO2001000068A1 (en) | 1999-06-29 | 2000-06-28 | Plastic pesticide packing cover or storage unit |
Country Status (2)
Country | Link |
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FR (1) | FR2795611A1 (en) |
WO (1) | WO2001000068A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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BE1017464A3 (en) * | 2007-02-12 | 2008-10-07 | Destrooper Patriek | IMPROVED PACKAGING MATERIAL. |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2084021A (en) * | 1980-09-26 | 1982-04-07 | Roussel Uclaf | Packing and/or lining material containing a pyrethrinoid-type compound |
EP0305641A2 (en) * | 1987-08-29 | 1989-03-08 | Wenko-Wenselaar GmbH | Garment bag |
DE3831403A1 (en) * | 1987-09-18 | 1989-04-06 | Rayen Sa | Garment bag |
US5565208A (en) * | 1994-11-03 | 1996-10-15 | Citra Science Ltd. | Insect repellent aerosol |
US5902595A (en) * | 1996-07-29 | 1999-05-11 | Effcon, Inc. | Pesticidal composition and method of use |
-
1999
- 1999-06-29 FR FR9908660A patent/FR2795611A1/en active Pending
-
2000
- 2000-06-28 WO PCT/FR2000/001808 patent/WO2001000068A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2084021A (en) * | 1980-09-26 | 1982-04-07 | Roussel Uclaf | Packing and/or lining material containing a pyrethrinoid-type compound |
EP0305641A2 (en) * | 1987-08-29 | 1989-03-08 | Wenko-Wenselaar GmbH | Garment bag |
DE3831403A1 (en) * | 1987-09-18 | 1989-04-06 | Rayen Sa | Garment bag |
US5565208A (en) * | 1994-11-03 | 1996-10-15 | Citra Science Ltd. | Insect repellent aerosol |
US5902595A (en) * | 1996-07-29 | 1999-05-11 | Effcon, Inc. | Pesticidal composition and method of use |
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