WO2000078279A1 - Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres - Google Patents
Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres Download PDFInfo
- Publication number
- WO2000078279A1 WO2000078279A1 PCT/FR2000/001616 FR0001616W WO0078279A1 WO 2000078279 A1 WO2000078279 A1 WO 2000078279A1 FR 0001616 W FR0001616 W FR 0001616W WO 0078279 A1 WO0078279 A1 WO 0078279A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gel
- gel according
- weight
- particles
- chosen
- Prior art date
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- 239000003349 gelling agent Substances 0.000 title claims abstract description 24
- 239000000945 filler Substances 0.000 title claims abstract description 23
- 239000007787 solid Substances 0.000 title claims abstract description 14
- 239000002245 particle Substances 0.000 claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 19
- 239000002537 cosmetic Substances 0.000 claims abstract description 12
- 239000008247 solid mixture Substances 0.000 claims abstract description 6
- 239000000499 gel Substances 0.000 claims description 92
- 239000000049 pigment Substances 0.000 claims description 28
- -1 polyethylene Polymers 0.000 claims description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 12
- 229910052791 calcium Inorganic materials 0.000 claims description 12
- 239000011575 calcium Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 239000011777 magnesium Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 229920002148 Gellan gum Polymers 0.000 claims description 9
- 108010076876 Keratins Proteins 0.000 claims description 8
- 102000011782 Keratins Human genes 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
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- 239000005017 polysaccharide Substances 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000004676 glycans Chemical class 0.000 claims description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 6
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- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
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- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
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- 229910052708 sodium Inorganic materials 0.000 claims description 5
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- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
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- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
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- 239000010936 titanium Substances 0.000 claims description 4
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- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
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- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 239000000980 acid dye Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229940073609 bismuth oxychloride Drugs 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
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- 235000010418 carrageenan Nutrition 0.000 claims description 3
- 229920001525 carrageenan Polymers 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001282 iso-butane Substances 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
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- 239000000178 monomer Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 2
- GYDYJUYZBRGMCC-INIZCTEOSA-N (2s)-2-amino-6-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NCCCC[C@H](N)C(O)=O GYDYJUYZBRGMCC-INIZCTEOSA-N 0.000 claims description 2
- 241000251468 Actinopterygii Species 0.000 claims description 2
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- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 229910052582 BN Inorganic materials 0.000 claims description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
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- 235000015278 beef Nutrition 0.000 claims description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Inorganic materials [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 2
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- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
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- 239000008273 gelatin Substances 0.000 claims description 2
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- 235000010492 gellan gum Nutrition 0.000 claims description 2
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 2
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
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- DMRBHZWQMKSQGR-UHFFFAOYSA-L magnesium;tetradecanoate Chemical compound [Mg+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O DMRBHZWQMKSQGR-UHFFFAOYSA-L 0.000 claims description 2
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- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 2
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- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
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- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- KZMRYBLIGYQPPP-UHFFFAOYSA-N 3-[[[4-[(2-chlorophenyl)-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]phenyl]-ethylazaniumyl]methyl]benzenesulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)Cl)C=CC=1[NH+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 KZMRYBLIGYQPPP-UHFFFAOYSA-N 0.000 description 1
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- 239000013543 active substance Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
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- 239000004178 amaranth Substances 0.000 description 1
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- 239000010477 apricot oil Substances 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
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- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000021014 blueberries Nutrition 0.000 description 1
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- 150000001805 chlorine compounds Chemical class 0.000 description 1
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- 229940110456 cocoa butter Drugs 0.000 description 1
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- 238000007796 conventional method Methods 0.000 description 1
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- 125000005534 decanoate group Chemical class 0.000 description 1
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- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 150000002315 glycerophosphates Chemical class 0.000 description 1
- RFDAIACWWDREDC-FRVQLJSFSA-N glycocholic acid Chemical compound C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCC(O)=O)C)[C@@]2(C)[C@@H](O)C1 RFDAIACWWDREDC-FRVQLJSFSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940087559 grape seed Drugs 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 150000003893 lactate salts Chemical class 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229960001078 lithium Drugs 0.000 description 1
- 229960005375 lutein Drugs 0.000 description 1
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 description 1
- 235000001055 magnesium Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000004701 malic acid derivatives Chemical class 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
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- 239000004200 microcrystalline wax Substances 0.000 description 1
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- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 210000000282 nail Anatomy 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 125000005474 octanoate group Chemical class 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
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- 239000012188 paraffin wax Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
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- 235000012756 tartrazine Nutrition 0.000 description 1
- 229960000943 tartrazine Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KBPHJBAIARWVSC-XQIHNALSSA-N trans-lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C KBPHJBAIARWVSC-XQIHNALSSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
- 235000008210 xanthophylls Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0279—Porous; Hollow
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Definitions
- the present invention relates to a solid aqueous gel, a solid composition with an aqueous continuous phase comprising such a gel and their use in the cosmetic field, in particular for making up the skin and / or mucous membranes and / or keratin fibers.
- Products in solid form are known in the cosmetic industry. As products of this type, mention may be made, for example, in the field of make-up, of sticks or “sticks” of lipstick, foundation or eye shadow; in the field of skin or lip care, lip repair pencils, depigmenting, make-up removing or moisturizing sticks or "sticks”; in the field of hygiene, deodorant sticks, sticks or foam bars for shaving or for washing the skin.
- makeup products are fairly generally formulated on the one hand on the basis of an oily phase for reasons of comfort and softness and on the other hand on a pulverulent phase which provides the desired color.
- This pulverulent phase can comprise pigments and / or fillers and / or nacres.
- the fatty phase generally comprises waxes and / or oils and / or pasty compounds.
- the sticks formulated based on waxes have certain disadvantages: they have a fatty character which is not appreciated by the users and they lack freshness on application. In addition, it is difficult to introduce hydrophilic active agents into it.
- a makeup product in particular, that the removal of the product be carried out in an ideal manner, that is to say, allows, in a simple manner, using the finger or a sponge. or even directly on the skin of the body for example, to take not only the quantity of adequate product (not too much not to lose product unnecessarily but enough to ensure a makeup effect) but also to preserve the integrity of the product at the time of its removal: the product must not be broken by a shearing phenomenon, but the entire product must be removed with the pigments and / or pearlescent agents, and / or possibly the fillers, which ensure the function of the makeup. It is only under this condition that the application of the product can be done in a homogeneous manner and that the makeup obtained will be uniform.
- Stable solid aqueous gels comprising pigments are known: but these products are generally impossible to disintegrate; they are often brittle, so it is impossible to take the product on the finger or on a sponge. Such products do not allow the deposition of a homogeneous film on the skin. Breakable products also exist but they are then too soft and end up shearing during repeated applications or even exhibit phenomena of syneresis over time, that is to say that the liquid part ends up exuding and the product has two phases: an indelible solid phase and a liquid phase. The product can no longer ensure its function, namely, make up, since it is impossible to take the pigments on the finger or on a sponge.
- the Applicant has unexpectedly discovered that by associating with a hydrophilic gelling agent a filler of a particular nature, namely a filler with deformable particles, it was possible to produce solid aqueous gels optionally comprising pigments and / or nacres, these gels can be easily disintegrated with a finger or a sponge or directly on the skin of the face or body and having remarkable cosmetic qualities.
- the present invention therefore relates to a solid aqueous gel comprising i) at least one hydrophilic gelling agent and ii) a pulverulent phase comprising at least one filler with deformable particles, the hydrophilic gelling agent being present in the gel at a content less than or equal to 20% by weight, relative to the total weight of the gel.
- the gels of the invention have excellent application and disintegration qualities.
- a level of disintegration higher than that of known sticks is obtained, at equivalent hardness.
- Taking the product is easy, it can be done directly on the body or with the finger or even with a sponge, taking a sufficient amount of product, easy to apply then on the skin evenly, without the need for wetting prior.
- the gel spreads easily on the skin.
- the makeup obtained is uniform and homogeneous.
- the gels according to the invention do not exude, even at low levels of gelling agent, and they do not necessarily require the intervention of a particular preparation technique. They give the application a feeling of great freshness while retaining good cosmetic properties, in particular of softness.
- the present invention also relates to a solid composition with an aqueous continuous phase comprising a gel as defined above.
- the present invention also relates to a product for making up the skin or keratin fibers comprising a gel and / or a composition as defined above.
- the present invention also relates to a process for making up the skin and / or mucous membranes and / or keratin fibers, consisting in applying to the latter, an aqueous gel and / or a solid composition and / or a make-up product such as defined above.
- the term “gel or solid composition” means a gel or composition having a hardness defined by a maximum force before rupture ranging from 5 to 50 grams, at room temperature (20-25 ° C.), after penetration by a 2 mm diameter stainless steel mobile in the gel matrix or composition at a thickness of 1 mm at a speed of 1 mm / s and removal of said mobile from the gel matrix or composition at a speed of 2 mm / s; the maximum force before rupture being measured with a texture analyzer of the "TAXT2" type sold by the company RHEO.
- the maximum force before rupture ranges from 7 to 40 g.
- the gel according to the invention comprises a hydrophilic gelling agent.
- gelling agent is meant a compound which, in the presence of a solvent, creates more or less strong intermacromolecular bonds thus inducing a three-dimensional network which freezes said solvent.
- This hydrophilic gelling agent can be chosen from polysaccharides, protein derivatives, synthetic or semi-synthetic gels of polyester type, polyacrylates or polymethacrylates and their derivatives.
- - seaweed extracts such as agar-agar, carrageenans (iota, kappa, lambda), alginates, in particular Na or Ca;
- - gelling agents of animal origin such as protein derivatives, in particular gelatin, beef or fish, casemates;
- the hydrophilic gelling agent is chosen from polysaccharides, and more preferably, the hydrophilic gelling agent is gellan.
- gellan gum sold under the trade name “Kelcogel F” by the company NUTRASWEET-KELCO or else iota carraghenane sold under the trade names “Seaspen PF 357” or “Viscarin SD 389 "by FMC.
- the hydrophilic gelling agent is present in the gel according to the invention at a concentration of up to 20% by weight, and of . preferably 0.2 to 10%, by weight, relative to the total weight of the gel. This concentration makes it possible to obtain the hardness and consistency suitable for an ideal crumbling.
- the gel according to the invention also comprises a pulverulent phase which comprises at least one filler with deformable particles.
- fillers it is necessary to understand colorless or white particles, mineral or synthetic, spherical or non-spherical, intended to give body or rigidity in composition, and / or softness, matness and uniformity in make-up.
- filler with deformable particles is meant, within the meaning of the present invention, spherical particles or not of sufficiently low hardness to deform when the composition is removed using a finger or a sponge or directly by friction on the skin when it is a stick.
- deformable it should be understood that the particles are flexible and elastic: after crushing, they return to their initial shape.
- These particles can be of any chemical nature. Preferably, they have an average particle size ranging from 0.1 to 500 microns, and preferably from 1 to 100 microns. They can be full or hollow.
- solid deformable particles there may be mentioned particles of crosslinked organosiloxane or “silicone rubber powder” as described in document JP 10 175816, the JIS A hardness of which is equal to or less than 80 and preferably less than 65 These particles can be coated with surfactant or a fine organic powder. They may also contain a non-crosslinked silicone or hydrocarbon oil which may exude "silicone rubber powder".
- the solid deformable particles which can be used according to the present invention preferably have a density ranging from 0.8 to 4, more preferably ranging from 0.8 to 1.5.
- the deformable particles When the deformable particles are hollow or filled with gas or air, they advantageously have a density ranging from 0.015 to 0.2 and better still greater than 0.04 and / or less than 0.1 and in particular ranging from 0.06 to 0.08.
- the acrylic monomer is for example a methyl acrylate or methacrylate and, in particular methacrylate. These particles are present in particular in the dry or hydrated state.
- This copolymer is non-toxic and non-irritating to the skin.
- the hollow particles are in the form of microspheres and have an average size or particle size ranging from 10 ⁇ m to 60 ⁇ m.
- the hollow particles of the invention can be obtained, for example, according to the methods of patents and patent applications EP-56 219, EP-348 372, EP-486 080, EP-320473, EP-112 807 and US-3 615,972.
- the internal cavity of the particles in principle contains a gas which can be air, nitrogen or a hydrocarbon such as isobutane or isopentane.
- the hollow particles which can be used in the invention are in particular those sold under the brand name Expancel by the company Casco Nobel such as the Expancel 551 DE 20 with a particle size of 27 ⁇ m and a density of about 0.052, the Expancel 551 DE 80 with a particle size of 50 ⁇ m and density approximately 0.045, Expancel 051 DE with a particle size of 30 ⁇ m and density approximately 0.056, Expancel 461 DE with a particle size of 30 ⁇ m and density approximately 0.058, Expancel 551 DE 12 with a particle size of 17 ⁇ m and density approximately 0.07, or again the Expancel of the "W" series such as the Expancel 551 W 20 with a particle size of 27 ⁇ m and a density of about 0.033.
- the fillers with deformable particles are present in the gels according to the invention at a content ranging from 0.1 to 50% by weight relative to the weight of the gel.
- This content can vary, in particular depending on the density of the load with deformable particles.
- this filler has a density ranging from 0.015 to 0.2, then it is preferably present at a content ranging from 0.1 to 10% by weight, by weight, relative to the total weight of the gel.
- this filler has a density ranging from 0.8 to 4 then it is preferably present at a content ranging from 1 to 50%, by weight, relative to the total weight of the gel.
- this content generally ranges from 0.1% to 10% by weight of particles and better still from 0.3% to 5% by weight and again from 0.3 % to 2%, based on the total weight of the gel.
- the pulverulent phase can comprise, in addition to the fillers with deformable particles mentioned above, other fillers, which can be mineral or synthetic, lamellar or non-lamellar, as well as pigments and / or nacres.
- talc talc
- mica silica
- silica kaolin
- powders of nylon polyethylene, Teflon, lauroyl-lysine, starch, boron nitride, bismuth oxychloride, powders of tetrafluoroethylene polymers, polymethyl methacrylate powders, polyurethane powders, polystyrene powders, polyester powders, synthetic hollow microspheres, non-deformable silicone resin microbeads, zinc and titanium oxides, zirconium or cerium oxides, precipitated calcium carbonate, magnesium carbonate and hydrocarbon, hydroxyapatite, hollow silica microspheres, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, such as stearate zinc, magnesium or lithium, zinc laurate, magnesium myristate, compounds Si0 2 / TiO 2 / SiO 2 , TiO 2
- the fillers may be present in the composition in an amount of 0.1-60% by weight, relative to the total weight of the composition, preferably in an amount of 0.1 to 40%, more preferably 1-20%,
- pigments should be understood to mean white or colored, mineral or organic particles, insoluble in the medium, that is to say in the gel, intended to color and / or opacify the composition.
- the pigments can be present in an amount of 0-40% by weight, relative to the total weight of the composition, preferably in an amount of 0.1 to 30% and more preferably in an amount of 1-20%. They can be white or colored, mineral and / or organic, of usual size or nanometric. By nanometric size is meant pigments with an average particle size of 5 to 100 nm.
- inorganic pigments and nanopigments there may be mentioned titanium, zirconium or cerium dioxides, as well as oxides of zinc, iron or chromium, nanotitanes, ferric blue.
- organic pigments there may be mentioned carbon black, and the lacquers commonly used to give the lips and the skin a makeup effect, which are calcium, barium, aluminum or zirconium salts, dyes acids such as halo-acid, azo or anthraquinone dyes.
- the pigments can in particular be coated with silicone compounds such as PDMS and / or with polymers, in particular polyethylenes or also with fluorinated compounds.
- silicone compounds such as PDMS and / or with polymers, in particular polyethylenes or also with fluorinated compounds.
- SA pigments from Maprecos or PI pigments from Myoshi. By nacres, it is necessary to understand iridescent particles which reflect light, insoluble in the medium, that is to say in the gel.
- the nacres can be present in the composition in an amount of 0-40% by weight, preferably in an amount of 0.1 to 30% and more preferably in an amount of 1-20% by weight.
- the pulverulent phase comprises sufficient pigments and / or pearlescent agents to ensure the desired makeup effect.
- the pulverulent phase comprises at least one pigment and / or a nacre.
- the aqueous gel according to the invention is not transparent, that is to say that the characters of a newspaper page cannot be seen through the gel. More preferably, it is not translucent, that is to say that it does not allow the passage of light.
- the pulverulent phase preferably comprises from 0.1 to 40%, more preferably from 0.1 to 20% by weight, relative to the total weight of the gel, of pigments and / or nacres.
- the gels of the invention also contain a cosmetically or physiologically acceptable medium, that is to say a medium compatible with all keratin materials such as the skin, the nails, the hair, the eyelashes and eyebrows, the mucous membranes and the semi-mucous membranes, and any other skin area of the body and face.
- a cosmetically or physiologically acceptable medium that is to say a medium compatible with all keratin materials such as the skin, the nails, the hair, the eyelashes and eyebrows, the mucous membranes and the semi-mucous membranes, and any other skin area of the body and face.
- the gels according to the invention can also comprise a floral water such as blueberry water and or a mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a water thermal, dyes water-soluble chosen from the usual dyes of the field considered such as the disodium salt of culvert, the disodium salt of alizarin green, quinoline yellow, the trisodium salt of amaranth, the disodium salt of tartrazine, the monosodium salt of rhodamine, disodium fuchsin salt, xanthophyll.
- a floral water such as blueberry water and or a mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a water thermal, dyes water-soluble chosen from the usual dyes of the field considered such as the disodium salt of culvert, the disodium salt of alizarin green, quinoline yellow, the trisodium salt of amaranth, the disodium
- the gels according to the invention comprise up to 99.8% by weight, preferably from 20 to 99% by weight, relative to the total weight of the gel, of water.
- the gels according to the invention can also comprise solvents other than water, for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C-
- solvents other than water for example primary alcohols such as ethanol and isopropanol, glycols such as propylene glycol, butylene glycol, dipropylene glycol, diethylene glycol, glycol ethers such as alkyl (C-
- primary alcohols such as ethanol and isopropanol
- glycols such as propylene glycol, butylene glycol, dipropylene glycol, di
- salts which will increase this rigidity.
- These salts can be chosen from the mono-, di- or trivalent metal salts, and more particularly the alkali and alkaline-earth metal salts and in particular the sodium, calcium or magnesium salts.
- the ions constituting these salts can be chosen, for example, from carbonates, bicarbonates, sulfates, glycerophosphates, borates, chlorides, nitrates, acetates, hydroxides, persulfates as well as the ⁇ -hydroxy acid salts ( citrates, tartrates, lactates, malates) or fruit acids, or the amino acid salts (aspartate, arginate, glycocholate, fumarate).
- the amount of salt can range from 0.01 to 2% and preferably from 0.1 to 1% of the total weight of the gel.
- the salt is chosen from calcium, magnesium or strontium nitrate, calcium or magnesium borate, calcium, sodium, magnesium, strontium, neodymium or manganese chloride, sodium sulfate. magnesium or calcium, calcium or magnesium acetate, and mixtures thereof. More preferably, the salt is magnesium chloride.
- the gels of the invention can be incorporated into cosmetic compositions and constitute the continuous phase thereof. Such compositions can thus comprise a fatty phase which can for example comprise an oil.
- oils of animal, vegetable or mineral origin such as paraffin oil, petroleum jelly, perhydrosqualene, apricot oil, wheat germ oil, sweet almond, calophyllum, sesame, macadamia, grape seed, rapeseed, coconut, peanut, palm, castor, avocado, jojoba, olive or cereal sprouts; esters of fatty acids and of polyol, in particular liquid triglycerides; alcohols; acetylglycerides; octanoates, decanoates or ricinoleates of alcohols or polyalcohols; fatty acid triglycerides; glycerides, fluorinated and perfluorinated oils; synthetic oils such as fatty esters; silicone oils such as volatile silicone oils, polymethylsiloxanes, polymethylphenylsiloxanes, polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, fluor
- the fatty phase of the compositions according to the invention can also comprise other fatty substances, which can be chosen by a person skilled in the art on the basis of his general knowledge, so as to confer on the final composition the desired properties, for example in consistency, texture and / or transfer.
- additional fatty substances can be waxes, gums and / or pasty fatty substances of animal, vegetable, mineral or synthetic origin, as well as their mixtures.
- - silicone gums - animal, vegetable, mineral or synthetic waxes such as microcrystalline waxes, paraffin, petrolatum, petroleum jelly, ozokerite, montan wax; beeswax, lanolin and its derivatives; candellila, Ouricury, Camauba, Japanese waxes, cocoa butter, cork fiber or sugar cane waxes; hydrogenated oils concrete at 25 ° C, ozokerites, fatty esters and glycerides concrete at 25 ° C; polyethylene waxes and waxes obtained by Fischer-Tropsch synthesis; concrete hydrogenated oils at 25 ° C; lanolines; concrete fatty esters at 25 ° C; silicone waxes; fluorinated waxes; their mixtures.
- microcrystalline waxes paraffin, petrolatum, petroleum jelly, ozokerite, montan wax
- beeswax lanolin and its derivatives
- candellila Ouricury, Camauba, Japanese waxes, cocoa butter, cork fiber or sugar
- the fatty phase can be present in proportions ranging, for example, up to 30%, preferably from 0.1 to 20% and better still from 0.5 to 10% of the total weight of the composition, these proportions varying according to selected application.
- Oils or waxes can be introduced into the aqueous phase in the presence of one or more surfactants to ensure better dispersion.
- compositions according to the invention can therefore also contain one or more O / W surfactants or ionic or nonionic cosurfactants, of HLB (hydrophilic-lipophilic balance) greater than or equal to 8, usually used in the cosmetic field.
- HLB hydrophilic-lipophilic balance
- the amount of surfactant or cosurfactant preferably ranges from 0.05 to 8% of the total weight of the composition.
- the composition can also comprise any additional compound usually used in the cosmetic field.
- These complementary compounds can be chosen from antioxidants, essential oils, preservatives, cosmetic or pharmaceutical active ingredients that are lipophilic or hydrophilic, moisturizers, vitamins, essential fatty acids, sphingoiipids, self-tanning compounds such as DHA, sun filters, perfumes, and mixtures thereof.
- antioxidants can be chosen from antioxidants, essential oils, preservatives, cosmetic or pharmaceutical active ingredients that are lipophilic or hydrophilic, moisturizers, vitamins, essential fatty acids, sphingoiipids, self-tanning compounds such as DHA, sun filters, perfumes, and mixtures thereof.
- the gels and the compositions with an aqueous continuous phase according to the invention can be prepared according to the conventional methods for preparing the sticks, these methods being well known to those skilled in the art.
- the gels and compositions according to the invention may constitute make-up or care products for the skin, in particular the body, the face and / or the scalp, or keratin fibers, in particular the hair, nails, eyelashes and / or eyebrows, or also mucous membranes, in particular the lips. They can thus constitute body makeup products, foundations, eyeshadows, blushes, concealers, lipsticks, lip contour pencils, mascaras, contour pencils eyes, sticks for dyeing or making up locks of hair.
- the amounts are given as a percentage by weight relative to the total weight of the composition.
- the Applicant has produced the aqueous gel in the form of the following stick foundation:
- This gel was prepared as follows: the water and the preservative were heated to 90 ° C., then the gellan was incorporated with stirring. After having waited 15 min, the pigment paste produced beforehand was incorporated by mixing the pigments with propylene glycol. Then we incorporated the silicone powder.
- the mixture was then poured into a cup and then cooled. The whole is left to stand for 24 hours at room temperature.
- a very fresh stick is obtained on application, usable with a dry or wet sponge, good grip and easy and homogeneous application on the skin.
- the hardness of this gel measured as described above is: 10 g
- EXAMPLE 2 The Applicant has produced the following aqueous gel in the form of a stick for eyeshadow:
- the hardness of this stick measured as described above is: 5.54 g
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU56888/00A AU5688800A (en) | 1999-06-18 | 2000-06-09 | Solid aqueous gel comprising a hydrophilic gelling agent and particular fillers |
JP2001504344A JP2003502355A (ja) | 1999-06-18 | 2000-06-09 | 親水性ゲル化剤と特定のフィラーとを含む固形水性ゲル、それを含む組成物及び使用 |
KR1020017002059A KR20010072738A (ko) | 1999-06-18 | 2000-06-09 | 친수성 겔화제 및 특정 충전제를 함유하는 고형 수성겔 |
BR0006830-6A BR0006830A (pt) | 1999-06-18 | 2000-06-09 | Gel aquoso sólido que compreende um gelificante hidrófilo e cargas particulares, composição sólida de fase contìnua aquosa, produto para a maquilagem da pele ou das fibras queratìnicas e processo de maquilagem da pele e/ou das fibras queratìnicas |
CA002340031A CA2340031A1 (fr) | 1999-06-18 | 2000-06-09 | Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres |
MXPA01001685A MXPA01001685A (es) | 1999-06-18 | 2000-06-09 | Gel acuoso solido que comprende un gelificante hidrofilo y cargas particulares, composiciones que lo contienen, y su utilizacion. |
EP00942174A EP1104283A1 (fr) | 1999-06-18 | 2000-06-09 | Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR99/07765 | 1999-06-18 | ||
FR9907765A FR2794999B1 (fr) | 1999-06-18 | 1999-06-18 | Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres, compositions le contenant, utilisations |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000078279A1 true WO2000078279A1 (fr) | 2000-12-28 |
Family
ID=9546992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2000/001616 WO2000078279A1 (fr) | 1999-06-18 | 2000-06-09 | Gel aqueux solide comprenant un gelifiant hydrophile et des charges particulieres |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1104283A1 (fr) |
JP (1) | JP2003502355A (fr) |
KR (1) | KR20010072738A (fr) |
AU (1) | AU5688800A (fr) |
BR (1) | BR0006830A (fr) |
CA (1) | CA2340031A1 (fr) |
FR (1) | FR2794999B1 (fr) |
MX (1) | MXPA01001685A (fr) |
WO (1) | WO2000078279A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6638519B1 (en) | 1999-11-08 | 2003-10-28 | L'oreal | Composition for topical application comprising a sugar and its cosmetic uses |
WO2004085412A2 (fr) | 2003-03-24 | 2004-10-07 | Ciba Specialty Chemicals Holding Inc. | Derives de triazine symetriques |
WO2012046954A3 (fr) * | 2010-10-07 | 2012-06-07 | 주식회사 한국비엔씨 | Appareil et procédé pour la préparation de particules dérivées de l'acide hyaluronique |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3596533B2 (ja) * | 2002-03-14 | 2004-12-02 | 富士ゼロックス株式会社 | 固形粉末化粧料 |
KR100509788B1 (ko) * | 2002-11-14 | 2005-08-24 | 주식회사 나우코스 | 목욕용 마사지 전용 화장료 조성물 |
KR100655112B1 (ko) | 2004-11-30 | 2006-12-08 | 방계룡 | 젤라틴과 알긴산나트륨을 이용한 부직포형 팩(pack)의제조방법 |
JP7221010B2 (ja) * | 2018-08-10 | 2023-02-13 | 株式会社 資生堂 | ゲル粒子及びそれを含む皮膚外用剤 |
FR3091172B1 (fr) | 2018-12-31 | 2021-12-10 | Lvmh Rech | Composition cosmétique solide constituée d’une phase continue aqueuse solide |
FR3091164B1 (fr) * | 2018-12-31 | 2021-12-10 | Lvmh Rech | Composition cosmétique solide comprenant des sphéroïdes anhydres en dispersion dans une phase continue aqueuse solide |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0614656A1 (fr) * | 1993-01-29 | 1994-09-14 | L'oreal | Gels aqueux contenant des microsphères creuses expansées |
WO1995031967A1 (fr) * | 1994-05-19 | 1995-11-30 | Kelco International Limited | Emulsion comprenant une phase externe gelifiee aqueuse, une phase intermediaire non aqueuse et une phase interne aqueuse |
EP0692237A1 (fr) * | 1994-07-11 | 1996-01-17 | L'oreal | Emulsion huile-dans-eau sans tensioactif, stabilisée par des particules thermoplastiques creuses |
FR2740678A1 (fr) * | 1995-11-06 | 1997-05-09 | Oreal | Utilisation en cosmetique d'une composition solide ayant une matrice gelifiee et compositions cosmetiques ou dermatologiques mises en oeuvre |
EP0803245A1 (fr) * | 1996-04-23 | 1997-10-29 | INTERCOS ITALIA S.p.A. | Gel compact solide contenant de l'eau |
-
1999
- 1999-06-18 FR FR9907765A patent/FR2794999B1/fr not_active Expired - Fee Related
-
2000
- 2000-06-09 WO PCT/FR2000/001616 patent/WO2000078279A1/fr not_active Application Discontinuation
- 2000-06-09 BR BR0006830-6A patent/BR0006830A/pt not_active IP Right Cessation
- 2000-06-09 AU AU56888/00A patent/AU5688800A/en not_active Abandoned
- 2000-06-09 MX MXPA01001685A patent/MXPA01001685A/es not_active Application Discontinuation
- 2000-06-09 JP JP2001504344A patent/JP2003502355A/ja active Pending
- 2000-06-09 KR KR1020017002059A patent/KR20010072738A/ko not_active Ceased
- 2000-06-09 EP EP00942174A patent/EP1104283A1/fr not_active Withdrawn
- 2000-06-09 CA CA002340031A patent/CA2340031A1/fr not_active Abandoned
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0614656A1 (fr) * | 1993-01-29 | 1994-09-14 | L'oreal | Gels aqueux contenant des microsphères creuses expansées |
WO1995031967A1 (fr) * | 1994-05-19 | 1995-11-30 | Kelco International Limited | Emulsion comprenant une phase externe gelifiee aqueuse, une phase intermediaire non aqueuse et une phase interne aqueuse |
EP0692237A1 (fr) * | 1994-07-11 | 1996-01-17 | L'oreal | Emulsion huile-dans-eau sans tensioactif, stabilisée par des particules thermoplastiques creuses |
FR2740678A1 (fr) * | 1995-11-06 | 1997-05-09 | Oreal | Utilisation en cosmetique d'une composition solide ayant une matrice gelifiee et compositions cosmetiques ou dermatologiques mises en oeuvre |
EP0803245A1 (fr) * | 1996-04-23 | 1997-10-29 | INTERCOS ITALIA S.p.A. | Gel compact solide contenant de l'eau |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6638519B1 (en) | 1999-11-08 | 2003-10-28 | L'oreal | Composition for topical application comprising a sugar and its cosmetic uses |
WO2004085412A2 (fr) | 2003-03-24 | 2004-10-07 | Ciba Specialty Chemicals Holding Inc. | Derives de triazine symetriques |
WO2012046954A3 (fr) * | 2010-10-07 | 2012-06-07 | 주식회사 한국비엔씨 | Appareil et procédé pour la préparation de particules dérivées de l'acide hyaluronique |
Also Published As
Publication number | Publication date |
---|---|
FR2794999A1 (fr) | 2000-12-22 |
MXPA01001685A (es) | 2002-04-08 |
EP1104283A1 (fr) | 2001-06-06 |
FR2794999B1 (fr) | 2001-07-13 |
KR20010072738A (ko) | 2001-07-31 |
CA2340031A1 (fr) | 2000-12-28 |
AU5688800A (en) | 2001-01-09 |
JP2003502355A (ja) | 2003-01-21 |
BR0006830A (pt) | 2001-08-07 |
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