WO2000016097A1 - Method and device for eliminating impurities from the atmosphere, especially in case of breakdowns - Google Patents
Method and device for eliminating impurities from the atmosphere, especially in case of breakdowns Download PDFInfo
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- WO2000016097A1 WO2000016097A1 PCT/PL1999/000030 PL9900030W WO0016097A1 WO 2000016097 A1 WO2000016097 A1 WO 2000016097A1 PL 9900030 W PL9900030 W PL 9900030W WO 0016097 A1 WO0016097 A1 WO 0016097A1
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- Prior art keywords
- inlet
- air
- cloud
- pollutant
- field
- Prior art date
Links
- 239000012535 impurity Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 15
- 230000015556 catabolic process Effects 0.000 title abstract 2
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 27
- 231100000719 pollutant Toxicity 0.000 claims abstract description 27
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000004064 recycling Methods 0.000 claims abstract description 5
- 230000008929 regeneration Effects 0.000 claims abstract description 4
- 238000011069 regeneration method Methods 0.000 claims abstract description 4
- 239000000356 contaminant Substances 0.000 claims description 12
- 238000011109 contamination Methods 0.000 claims description 7
- 238000009423 ventilation Methods 0.000 claims description 6
- 239000000523 sample Substances 0.000 claims description 4
- 239000002594 sorbent Substances 0.000 claims description 3
- 230000006735 deficit Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 239000000809 air pollutant Substances 0.000 abstract 1
- 231100001243 air pollutant Toxicity 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 239000000428 dust Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 231100000572 poisoning Toxicity 0.000 description 5
- 230000000607 poisoning effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000002808 molecular sieve Substances 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000002285 radioactive effect Effects 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 101100279441 Caenorhabditis elegans egg-5 gene Proteins 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229940126601 medicinal product Drugs 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/42—Auxiliary equipment or operation thereof
- B01D46/44—Auxiliary equipment or operation thereof controlling filtration
- B01D46/442—Auxiliary equipment or operation thereof controlling filtration by measuring the concentration of particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
- B01D46/0036—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/455—Gas separation or purification devices adapted for specific applications for transportable use
- B01D2259/4558—Gas separation or purification devices adapted for specific applications for transportable use for being employed as mobile cleaners for ambient air, i.e. the earth's atmosphere
Definitions
- the invention relates to an evaluation of the removal of impurities from the air atmosphere and also to a device for removing impurities from the air atmosphere, especially in fault situations.
- the task of the process and the device includes cleaning the atmosphere of toxic or radioactive gases, vapors, dusts, aerosols, smoking, mists, etc., which are released into the air as a result of damage to cisterns, containers or failure of the chemical or energy equipment etc as well as unlawful acts.
- Polish patent number 143 741 contains a method of lowering toxicity to the gas substances in air, which consists in carrying out a corresponding chemical reaction and or adsorption.
- Polish patent number 143 742 provides information about the process of burning poisoning substances. It is ⁇ .
- devices which are intended to eliminate Verunreini ⁇ uneen from the air. The methods described above were used in these facilities. For example, patent number 107 761 describes the device for chlorine neutralization.
- patent number 151210 describes an extinguishing neutralizer that has a turbo engine with afterburner and ejector.
- Polish patent number 152 675 an extinguishing neutralization device with the inlet movable to the afterburner was described.
- the pollutant concentration field is defined as a quantity of the current concentration values of pollutants in space, which is limited from the outside by measuring points of the pollutant concentration, a subfield forming a fraction of the pollutant field.
- the first activity is the relocation of the facility for the removal of pollution by land, water or air, depending on needs in the vicinity of the accident, especially to the particularly protected areas or where it is highly likely that the pollution clouds can be expected, according to the calculations, according to the equations, to describe the recognized dispersion models of the pollution.
- Contamination cloud is to be defined as the space in which the pollutant concentration exceeds assumed values. Consequently, according to the experience, in the vicinity of the ventilation duct inlet which brings poisoned air to the neutralizing or separating apparatus, the concentration of the pollutants is measured in many points to determine the pollutant concentration field.
- the inlet of the inlet guide is moved to the new cloud point.
- the removal of the poisoning is carried out until the pollution cloud is liquidated.
- the impurities are recovered as a raw material for recycling.
- the device for removing impurities from air with the aid of the neutralization or probe apparatus, which neutralizes the impurities or removes them from the air.
- the device has at least one movable and one immobile or at least one movable or at least two immobile, during the measurement of the pollutant concentration or the measurement of the pollutant concentration and the removal of contaminants from the air in the environment and in relation to the inlet of the inlet line.
- Pollutant concentration measuring devices, and / or inlets to this measuring device are attached to the means of transport which is provided in the apparatus and the fan, possibly on a motor vehicle with the apparatus and / or on the trailer with the fan and or on another Medicinal products are.
- the measuring devices form the interchangeable elements of the device. They include chromatographs with FLD-TCD-ECD sensors, etc. Explosion measuring devices, analyzers, for gluing electrochemical reactions, ultra-red. Geiger-Müller counter tubes, scintillation counter, etc. They have to be adjusted depending on the poisoning.
- Example I Serve to neutralize and separate the contaminants from the air, forming the equipment of the facility, inserts with activated carbon, molecular sieves, silica gels, dust filters etc., housed depending on poisoning in the neutralization or probe apparatus. Measuring devices and inlets are attached to appropriate holders and the inserts as well as the filters are inserted into the housing of the neutralization or removal apparatus of impurities.
- the decay and the arrangement according to the invention enables performance-dependent and independent of the pollution site to remove these contaminants from the atmosphere as well as the recovery of the sorbent and contaminants as recycling raw materials.
- the following examples explain the decaying and the device for removing impurities from the air.
- the inlet 5 After confirmation of the change in the pollutant concentration field 11, the inlet 5 was shifted in the direction of the maximum concentration of the poisoning. The entire action of eliminating the benzene vapors after successive displacements of the egg 5 has been completed after the confirmation that there is no exceeding of the assumed concentration of the benzene vapors in the vicinity of the accident site.
- a dust filter was previously housed in the apparatus 3 and the suction of the air is insured by the fan 4.
- the telescopically extendable bearing 7, which is immovable against the inlet 5 are during the measurement of the radiation intensity and / or dimensions and sucking in the poisoned air, five measuring devices 8 such as scintillation counters were accommodated (only two were shown in FIG. 2). After arriving in the vicinity of the expected cloud 2, the measuring devices 8 were switched on and after confirming that the radiation intensity had been exceeded, the fan 4 was actuated. Further management of the cleaning and especially the displacement of the inlet 5 is analogous to that in Example I.
- the apparatus 3 was mounted on the motor vehicle 12 and the fan 4 on the trailer 14, the fan 4 being connected to the apparatus 3 via the line 15.
- One of the motor vehicles 12 is located near the disaster and the second one at a housing estate.
- the third vehicle 16, on which the boom 7 with inlets 13 to the measuring device 8 is located, also takes part in the action, in this case it is a gas clomograph with an ECD sensor (in FIG. 3, only one motor vehicle 12 was a vehicle 16 and three inlets 13 shown).
- the task of the movable measuring device 8 relative to the inlets 5, which is assigned to the vehicle 16, is that the measurement of the distribution of contamination is supported so that the measurement of the change in the pollutant concentration field 11 can be determined more quickly and over a larger area.
- the apparatus 3 which is located on the motor vehicle 12, insert with molecular sieves was installed and the suction is ensured by the fan 4.
- openings 13 are attached to the measuring device 8, which forms a chromatograph.
- the fan 4 was actuated. Continuation of the cleanliness of the air and especially the shifting of the egg 5 is analogous to that in Example I. Subsequent during the regeneration of molecular sieves, vinyl chloride is recovered.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention relates to a method consisting in measuring pollutant concentration at several points to determine the pollutant concentration field (11) in the vicinity of the inlet (5) to the neutralization or separation apparatus that eliminates said impurities from the air and displacing said inlet (5) to and inside the cloud (2) with the purpose of efficiently eliminating impurities from the atmosphere, especially after breakdowns. During regeneration by sorption, impurities are then recovered in the form of recycling raw materials. The device comprises at least one movable and one stationary pollutant measuring device (8) ort least one movable or at least two stationary pollutant measuring device (8) to measure pollutants in the vicinity of the inlet (5). The invention provides a solution to the problem of eliminating air pollutants in locations distant from the source of emission, it enhances the efficiency of pollutant purification and makes it possible to recover impurities in the form of recycling raw materials.
Description
Verfahren.und Einrichtung zur Beseitigung von Verunreinigungen aus Luftatmosphäre, besonders in Störungslagen. Process and device for removing impurities from the air atmosphere, especially in fault situations.
Die Erfindung betrifft eines Verfaluens der Beseitigung Verunreinigungen aus der Luftatmosp äre und auch eine Einrichtung zur Beseitigung von Verunreinigungen aus Luftatmosphäre, zumal in Störungslagen. Zu der Aufgabe des Verfahrens und der Einrichtung gehört jeweils die Säuberung der Atmosphäre von der toxischen oder radioaktiven Gasen, Dämpfen, Stäuben, Aerosolen, Rauchen, Nebeln u.s.w., die in die Luft infolge einer Beschädigung von Zisternen, Behältern oder Ausfalles der chemischen oder energetischen Apparatur u.s.w. als auch widerrechtlichen Taten, eingedrungen sind.The invention relates to an evaluation of the removal of impurities from the air atmosphere and also to a device for removing impurities from the air atmosphere, especially in fault situations. The task of the process and the device includes cleaning the atmosphere of toxic or radioactive gases, vapors, dusts, aerosols, smoking, mists, etc., which are released into the air as a result of damage to cisterns, containers or failure of the chemical or energy equipment etc as well as unlawful acts.
Aus dem Stand der Technik sind die Verfahren der Beseitigung der Luftveranreimsuns bekannt. Sie bestehen m dem Ansausen der verunreinigten Luft aus der Atmosphäre, die dann durch eine Neutralisations -oder Absondεrnapparatur durchgepresst ist. zwecks Absonderung der Verunreinisun? von der Luft und Ableiten der gesäuberten Luft in die Atmosphäre oder Ableiten der Luft, die weniger schädlichen Substanzen enthält. In der Beschreibung des polnischen Patents Nummer 143 741 ist einVerfahren der Absenkung von Toxität bei der Gassubstanzen in Luft enthalten, welches in Durchführung einer entsprechender chemischer Reaktion und oder Adsorption besteht. In anderer Lösung aus dem polnischen Patent Nummer 143 742 ist Bescheid über Verfahen der Verbrennung von Vergiftungsubstanzen angegeben. Es ., gibt ■ auch Einrichtungen bekannt, die zur Beseitigung von Verunreiniεuneen aus der Luft bestimmt sind.
In diesen Einrichtungen wurden die oben beschriebenen Methoden eingesetzt. Beispielweise das Patent Nummer 107 761 beschreibt die Einrichtung zur Chlorneutralisierung. Wieder, das Patent Nummer 151210 beschreibt über einer Lösch-Neutralisationseinrichtung, die Turbo-Motor mit Nachbrenner und Ejektor aufweist. In nächster Beschreibung aus dem polnischen Patent Nummer 152 675 wurde eine Lösch- Neutralisationseinrichtung, mit dem zum Nachbrenner beweglichen Einlaß beschrieben.The methods of eliminating air pollution are known from the prior art. They consist in the rushing of the contaminated air from the atmosphere, which is then pressed through a neutralization or absorption apparatus. to separate the contaminants? from the air and discharging the cleaned air into the atmosphere or discharging the air which contains less harmful substances. The description of Polish patent number 143 741 contains a method of lowering toxicity to the gas substances in air, which consists in carrying out a corresponding chemical reaction and or adsorption. Another solution from Polish patent number 143 742 provides information about the process of burning poisoning substances. It is ■. Also devices are known which are intended to eliminate Verunreiniεuneen from the air. The methods described above were used in these facilities. For example, patent number 107 761 describes the device for chlorine neutralization. Again, patent number 151210 describes an extinguishing neutralizer that has a turbo engine with afterburner and ejector. In the next description from Polish patent number 152 675 an extinguishing neutralization device with the inlet movable to the afterburner was described.
Bisherige Beseitigung von Verunreinigungen aus Luft fuhrt man ohne Kenntnisse des Schadstoffkonzentrationfeldes von Verschmutzungen in Umgebung des Einlaßes zur Einrichtung von Beseitigung dieser Verschmutzungen durch.Previous removal of contaminants from air is carried out without knowing the pollutant concentration field of contaminants in the vicinity of the inlet in order to set up the removal of these contaminants.
Infolge dessen haben wir mit nidrigem Wirkungsgrad der Säuberung und zu einige zehn Meter begrentzter Wirkungsbereich ab der Quelle der Emmision von Verunreinigungen zu tun. Deshalb nach den Havarien bilden sich zalreiche Verunreinigungswolken, die sich verlagernd, Tod oder Krüppeihaftigkeit der Menschen veranlassen, beziehungsweise Schaden in Flora und Fauna
Das Schadstoftkonzentrationfeld definiert man als eine Menge der momentanen Konzentrationswerte von Sschadstoffen in Raum, der von außen durch Meßpunkte der Schadstoffkonzentration begrentzt ist, wobei ein Teilfeld einen Bruchteil des Schadstoffeldes bildet.As a result, we have to deal with low-level cleaning efficiency and a range of activity that is limited to a few tens of meters from the source of pollution contamination. Therefore, after the accidents, numerous pollution clouds form, which shift, cause death or crippledness of the people, or damage to flora and fauna The pollutant concentration field is defined as a quantity of the current concentration values of pollutants in space, which is limited from the outside by measuring points of the pollutant concentration, a subfield forming a fraction of the pollutant field.
Die Nachteile der oben erwänten Verfaren sind der Erfindung gemäß, durch das Verfahren der Beseitigung von Verunreinigungen aus der Luft, mittels der Neutralisations -oder Absondernapparatur eliminiert worden. Die erste Tätigkeit ist die Verlagerung der Einrichtung zur Beseitigung von Verunreinigung durch das Land-Wasser- oder Luftverkehrsmittel,
abhängig von Bedürfnisse in die Nähe des Unfalles, zumal zu den besonders - geschützten Gegenden oder dort, wo man mit hoher Wahrscheinlichkeit die Verunreinigungswolken erwarten kann, nach den Berechnungen, der Gleichungen gemäß, die anerkannte Ausbreitungsmodelle der Verunreinigungen zu beschreiben. Verunreinigungswolke ist zu definieren als der Raum, in welchem die Schadstoffkonzentration angenommene Werte überschreitet. Folglich, der Erfingung nach, in Umgebung des Einlaßes der Ventilationleitung, die vergiftete Luft zu der Neutraliations -oder Absondernappararur bringt, mißt man in vielen Punkten die Konzentration der Schadstoffe , um das Schadstoffkonzentrationsfeld festzustellen. Das ist eine unerlässliche Bedingung, solche Aufstellung und Verschiebung dieses Eilaßes im Raum, die das Ansaugen vergiftener Luft, und hohe Leistung der Beseitigung von Verunreinigungen nach den Unfällen garantiert. Dies Verfahren gewährleistet das Ansaugen der Vergiftenen Luft von den Orten, wo sich maximale Konzentration von Schadstoffen befindet, und vermeidet diese Orte , WO die Verunreinigungen nicht vorhanden sind. Nach der Feststellung, daß der Einlaß innen der Wolke ist, betätigt man den Ventilator, damit vergiftete Luft durch die Neutralisations-oder Absondemapparatur pressen kann. Gleichzeitig stellt man den Auslaß der Auslaufleitung, die mittels Ventilator mit Neutralisations-oder Absondemapparatur verbunden ist, so auf, damit die Achse der AuslaufVentilationsleitung nicht in Richtung der Wolke aufgestellt wurde. Nach der Feststellung der Änderung des Schadenstoffl onzentrationsfeldes, verlagert man den Einlaß der Einlaufleitimg zum neuen Wolkenpunkt. Die Beseitigung der Vergiftung führt man bis die Verunreinigungswolke liquidiert wird.
Ferner, während der Sorbensregenerierung gewinnt man die Verunreinigungen als Recyklingrohstoff zurück.According to the invention, the disadvantages of the above-mentioned methods have been eliminated by the method of removing impurities from the air by means of the neutralizing or separating apparatus. The first activity is the relocation of the facility for the removal of pollution by land, water or air, depending on needs in the vicinity of the accident, especially to the particularly protected areas or where it is highly likely that the pollution clouds can be expected, according to the calculations, according to the equations, to describe the recognized dispersion models of the pollution. Contamination cloud is to be defined as the space in which the pollutant concentration exceeds assumed values. Consequently, according to the experience, in the vicinity of the ventilation duct inlet which brings poisoned air to the neutralizing or separating apparatus, the concentration of the pollutants is measured in many points to determine the pollutant concentration field. This is an indispensable condition, such placement and relocation of this egg in the room, which guarantees the sucking in of poisoned air, and high performance of the removal of impurities after the accidents. This procedure ensures that the poisoned air is sucked in from the places where there is maximum concentration of pollutants and avoids those places where the contaminants are not present. After determining that the inlet is inside the cloud, the ventilator is actuated so that poisoned air can be forced through the neutralizing or sensing apparatus. At the same time, the outlet of the outlet line, which is connected by means of a fan to the neutralization or sensing apparatus, is set up so that the axis of the outlet ventilation line has not been set up in the direction of the cloud. After the change in the pollutant concentration field has been determined, the inlet of the inlet guide is moved to the new cloud point. The removal of the poisoning is carried out until the pollution cloud is liquidated. Furthermore, during sorbent regeneration, the impurities are recovered as a raw material for recycling.
Zur Anwendung dieses Verfahrens dient die Einrichtung zur Beseitigung von Veranreinigungen aus Luft, mit Hilfe der Neutralisations-oder Absondemapparatur, die die Verunreinigungen neutralisiert oder aus der Luft entfernt.To use this method, the device for removing impurities from air, with the aid of the neutralization or probe apparatus, which neutralizes the impurities or removes them from the air.
Der Erfindung gemäß, hat die Einrichtung während der Abmessung der Schadstoffkonzentration beziehungsweise der Abmessung der Schadstoffkonzentration und der Beseitigung von Verunreinigungen aus der Luft in Umgebung und im Verhältnis zum Einlaß der Einlaufleitung wenigstens ein beweglichen und ein unbeweglichen oder wenigstens ein beweglichen, beziehungsweise wenigstens zwei unbeweglichen, Schadstoffkonzentrationssmeßgeräte, und/oder Einläße zu diesem Meßgerät, wobei diese Meßgeräte an das Verkehrsmittel angebracht sind, das in die Apparatur und den Ventilator versehen ist, eventuell auf einem Kraftwagen mit der Apparatur und/oder auf dem Anhänger mit dem Ventilator und oder auf einem anderen Vehrkelrrsmittel sind. Die Meßgeräte bilden die austauschbare Elementen der Einrichtung. Es gehören zu ihnen Chromatographen mit FLD- TCD- ECD-Fühler u.s.w. Explosionsmeßgeräte, Analysatoren, wirkende in Anleimung an elektrochemische Reaktionen, Ultrarot. Geiger-Müller-Zählrohren, Szintillationszähler u.s.w. Sie sind in Abhängihkeit von der Vergiftung anzupassen.According to the invention, the device has at least one movable and one immobile or at least one movable or at least two immobile, during the measurement of the pollutant concentration or the measurement of the pollutant concentration and the removal of contaminants from the air in the environment and in relation to the inlet of the inlet line. Pollutant concentration measuring devices, and / or inlets to this measuring device, these measuring devices being attached to the means of transport which is provided in the apparatus and the fan, possibly on a motor vehicle with the apparatus and / or on the trailer with the fan and or on another Medicinal products are. The measuring devices form the interchangeable elements of the device. They include chromatographs with FLD-TCD-ECD sensors, etc. Explosion measuring devices, analyzers, for gluing electrochemical reactions, ultra-red. Geiger-Müller counter tubes, scintillation counter, etc. They have to be adjusted depending on the poisoning.
Zur Neutralisation und Absonderung der Veranreinigungen aus der Luft dienen, die bildende die Ausstattung der Einrichtung, Einsätze mit Aktivkohle, Molekularsieben, Kieselgelen, Staubfilter u.s.w., untergebracht abhähngig von Vergiftung in der Neutralisations-oder Absondemapparatur.
Meßgeräte und Einläße werden an entsprechenden Halter befestigt und die Einsätze sowie die Filter werden in das Gehäuse der Neutralisation-oder Absondemapparatur von Verunreinigungen eingeführt. Das Verfallen und die Eirichtung nach der Erfindung ermöglicht leistungsfällige und unabhängige vom Schmutzemmissionsort eine Beseitigung dieser Verunreinigungen aus der Atmosphäre als auch die Rückgewinnug der Sorbens und Verunreinigungen als Recyklingrohstoffe. Nachstehende Beispiele erläutern nälier das Verfaliren und die Einrichtung zur Beseitigung von Verunreinigungen aus der Luft. Beispiel IServe to neutralize and separate the contaminants from the air, forming the equipment of the facility, inserts with activated carbon, molecular sieves, silica gels, dust filters etc., housed depending on poisoning in the neutralization or probe apparatus. Measuring devices and inlets are attached to appropriate holders and the inserts as well as the filters are inserted into the housing of the neutralization or removal apparatus of impurities. The decay and the arrangement according to the invention enables performance-dependent and independent of the pollution site to remove these contaminants from the atmosphere as well as the recovery of the sorbent and contaminants as recycling raw materials. The following examples explain the decaying and the device for removing impurities from the air. Example I
Infolge des Ausfalles im chemischen Werk ist in die Atmosphäre 10 Mg Benzol eingedrungen. In Entfernung etwa 100 Meter von dem Unfall sind zweie Transportmittel jeweils zwei Kraftwagen 1 angekommen, um die Benzoldämpfe von Vemnreinigungswolke 2 zu beseitigen. Ein von der Kraftwagen ist in Fig.l gezeigt. Es wurde angennomen, daß die Beseitigung der Benzoldämpfe aus der Wolke 2 für höhere als 10 mg/m3 Benzolkonzentration geführt wird. In der Neutralisation-oder Absondemapparatur von Veranreinigungen aus der Luft wurde Einsatz mit Aktivkohle untergebracht, hingegen das Ansaugen der vergiftenen Luft durch die Apparatur 3 versichert der Ventilator 4. Auf den drehbar an dem Einlaß 5 zu der Einlauf entilationsleitung 6 befestigten vier Auslegern 7 (in Fig.l ist nur einen bezeichnet) wurden vier bewegliche rundum des Einlaßes 5 Meßgeräte 8 der Verunreinigungsluft, von Typus wie Explosionmeßgerät angebracht, je zwei auf verschiedenen Niveau (in Fig. l nur einen wurde gezeigt). Meßgeräte 8 wurden betätigt, als sich der Einlaß 5 zwei Meter über dem Boden befand. Es wurde die Überschreitung der angennomenen Konzentrationswerte nicht festgestellt. Deshalb ist der
Kraftwagen 1 näher des Ortes des Ausffales verschieben worden und der Einlaß 5 wurde mit Hilfe vom Aufzug in Höhe fünf Meter aufgehoben. Es wurde die Ubersclireitung der angennomenen Konzentration der Benzoldämpfe festgestellt, was bedeutet, daß der Einlaß 5 sich innen der Wolke 2 befindet, darüber hinaus wurde der Ventilator 4 betätig. Der Auslaß 9 der Auslaufventilationsleitung 10 ist so aufgestellt worden, damit die gesäuberte Luft nicht in die Richtung der Wolke 2 ausfließen konnte. Nach der Bestätigung der Änderung des Schadstoffkonzentrationsfeldes 11, wurde der Einlaß 5 in Richtung der maximalen Konzentration der Vergiftung verschieben. Die ganze Aktion der Beseitigung der Benzoldämpfe nach aufeinanderfolgenden Verschiebungen des Eilaßes 5 ist zu Ende gebracht, nach der Bestätigung, daß in Umgebung des Unfallortes keine Überschreitungen der angennomenen Konzentration der Benzoldämpfe zu vorkommen.As a result of the failure in the chemical plant, 10 mg of benzene has entered the atmosphere. At a distance of about 100 meters from the accident, two means of transport, two motor vehicles 1, each arrived to remove the benzene vapors from the cleaning cloud 2. One of the motor vehicles is shown in Fig.l. It has been assumed that the removal of the benzene vapors from cloud 2 will result in benzene concentrations higher than 10 mg / m 3 . In the neutralization or separation apparatus for air pollution, insert with activated carbon was housed, however, the intake of the poisoned air through the apparatus 3 ensures the fan 4. On the four booms 7 (in Fig.l is only designated one) were four movable around the inlet 5 measuring devices 8 of the contaminated air, of type and explosion measuring device, two each at different levels (only one was shown in Fig. 1). Gauges 8 were operated when inlet 5 was two meters above the floor. The exceeding of the assumed concentration values was not found. That is why Motor vehicle 1 has been moved closer to the location of the dropout and inlet 5 has been lifted five meters using the elevator. It was determined the assumed concentration of the benzene vapors, which means that the inlet 5 is inside the cloud 2, in addition the fan 4 was actuated. The outlet 9 of the outlet ventilation line 10 has been set up so that the cleaned air could not flow out in the direction of the cloud 2. After confirmation of the change in the pollutant concentration field 11, the inlet 5 was shifted in the direction of the maximum concentration of the poisoning. The entire action of eliminating the benzene vapors after successive displacements of the egg 5 has been completed after the confirmation that there is no exceeding of the assumed concentration of the benzene vapors in the vicinity of the accident site.
Beispiel IIExample II
Durch einen Ausfall im Kernkraftwerk sind in die Atmospfäre zwei Kilogramm radioaktiver Staub eingedrungen. Nach der Berechnung eines wahrscheinlichen Ortes und Richtung der Verlagerung der Staubwolke 2, zwecks Beseitigung dieses Staubes, wurde ein Transportmittel 1 jeweils ein Zeppelin geschickt, was in Fig.2 gezeigt wurde. Es ist angennomen, daß die Beseitigung des Staubes von innen der Wolke 2 so lange geführt wird, bis die Stärke der radioaktiven Strahlung fünfmal die Niveau eines naturalen Hintergrundes überschreiten wird.Due to a failure in the nuclear power plant, two kilograms of radioactive dust have entered the atmosphere. After calculating a probable location and direction of the displacement of the dust cloud 2 in order to remove this dust, a means of transport 1 was sent to a zeppelin, which was shown in FIG. It is assumed that the dust is removed from the inside of the cloud 2 until the strength of the radioactive radiation will exceed the level of a natural background five times.
In der Apparatur 3 wurde vorher ein Staubfilter untergebracht und das Ansaugen der Luft wird durch den Ventilator 4 versichert. Auf dem teleskopisch ausziehbaren Auslager 7, der gegen den Einlaß 5 unbeweglich ist, sind während des Abmessens von Strahlungsstärke und/oder Abmessen
und Ansaugen der vergiftener Luft, fünf Meßgeräte 8 wie Szintillationszähler untergebracht wurden (in Fig.2 wurden nur zwei gezeigt). Nach de Ankommen in die Nähe der erwarteten Wolke 2 wurden die Meßgeräte 8 eingeschaltet und nach der Bestätigung, daß die Strahlungsstärke überschrietten worden war, wurde der Ventilator 4 betätigt. Weitere Führung der Säuberung und besonders die Verschiebung des Einlaßes 5, ist analogisch wie im Beispiel I.A dust filter was previously housed in the apparatus 3 and the suction of the air is insured by the fan 4. On the telescopically extendable bearing 7, which is immovable against the inlet 5, are during the measurement of the radiation intensity and / or dimensions and sucking in the poisoned air, five measuring devices 8 such as scintillation counters were accommodated (only two were shown in FIG. 2). After arriving in the vicinity of the expected cloud 2, the measuring devices 8 were switched on and after confirming that the radiation intensity had been exceeded, the fan 4 was actuated. Further management of the cleaning and especially the displacement of the inlet 5 is analogous to that in Example I.
Beispiel IIIExample III
Aus einer beschädigten Zisterne sind in die Atmospfäre 20 Mg Vinylchlorid eingedrungen. Zur Beseitigung der Verunreinigung wurden zwei Kraftwagen 12 mit Anhänger 14 bestimmt. Auf den Kraftwagen 12 wurde die Apparatur 3 und auf dem Anhänger 14 den Ventilator 4 montiert, wobei der Ventilator 4 ist mit der Leitung 15 mit der Apparatur 3 verbunden. Ein vom Kraftwagen 12 ist in der Nähe der Katastrophe und der zweite bei einer Wohnsiedlung lokalisiert. In der Aktion nimmt auch das dritte Fahrzeug 16 teil, auf dem sich der Ausleger 7 mit Einlasse 13 zum Meßgerät 8 befindet, in diesem Fall geht um Gascl romεtograph mit ECD - Fühler, (in Fig. 3 wurde nur einen Kraftwagen 12, ein Fahrzeug 16 und drei Einlasse 13 gezeigt). Die Aufgabe des beweglichen gegenüber der Einlasse 5 Meßgerätes 8, das dem Fahrzeug 16 zugeordnet ist, besteht darin, daß das Abmessen der Verteilung von Verunreinigung unterstützt wird, damit schneller und auf grössere Fläche das Abmessen der Änderung des Schadstoffkonzentrationsfeldes 11 ermitteln werden kann. In der Apparatur 3, die sich auf den Kraftwagen 12 befindet, wurde Einsatz mit Molekularsieben installiert und das Ansaugen versichert der Ventilator 4. Auf dem Ausleger 7 des Kraftwagens 12 sind Eilässe 13 zum Meßgerät 8 befestigt, das ein Chromatograph bildet. Nach der Feststellung der
Überschreitung angenommener Vinylchloridkonzentration (5 mg/m3) in Umgebung der Einlasse 5, was bedeuted, daß sie innen der Wolke 2 sind, wurde der Ventilator 4 betätig. Fortsetzung der Säuberang der Luft und besonders die Verschiebung der Eilässe 5 ist analogisch wie im Beispiel I. Folgend während der Molekularsiebenregeneration, gewinnt man Vinylchlorid zurück.
From a damaged cistern, 20 mg of vinyl chloride have penetrated into the atmosphere. To remove the contamination, two motor vehicles 12 with trailers 14 were determined. The apparatus 3 was mounted on the motor vehicle 12 and the fan 4 on the trailer 14, the fan 4 being connected to the apparatus 3 via the line 15. One of the motor vehicles 12 is located near the disaster and the second one at a housing estate. The third vehicle 16, on which the boom 7 with inlets 13 to the measuring device 8 is located, also takes part in the action, in this case it is a gas clomograph with an ECD sensor (in FIG. 3, only one motor vehicle 12 was a vehicle 16 and three inlets 13 shown). The task of the movable measuring device 8 relative to the inlets 5, which is assigned to the vehicle 16, is that the measurement of the distribution of contamination is supported so that the measurement of the change in the pollutant concentration field 11 can be determined more quickly and over a larger area. In the apparatus 3, which is located on the motor vehicle 12, insert with molecular sieves was installed and the suction is ensured by the fan 4. On the boom 7 of the motor vehicle 12, openings 13 are attached to the measuring device 8, which forms a chromatograph. After finding the Exceeding the assumed vinyl chloride concentration (5 mg / m 3 ) in the vicinity of the inlets 5, which means that they are inside the cloud 2, the fan 4 was actuated. Continuation of the cleanliness of the air and especially the shifting of the egg 5 is analogous to that in Example I. Subsequent during the regeneration of molecular sieves, vinyl chloride is recovered.
Claims
1. Verfaliren zur Beseitigung der Verunreinigung aus atmosfärischer Luft, besonders in Störungsanlagen, mit Hilfe von Neutralisations-oder Absondemapparatur, dadurch gekennzeichnet, daß im Ramn vom Radius weniger als 1000 Meter der von Außen den Einlaß (5), zur Einlaufventilationsleitung (6) umgibt, die von zweiter Seite mit dem Einlaß zur Neutralisations - oder Absondemapparatur (3), die die Verunreinigungen von der Luft trennt, beendet ist, die Konzentration der Verunreinigungen mehrpunktig, vorteilhaft in mehr als fünf Punkten mit Hilfe von den Schadstoffmeßgeräte (8) gemessen wird, zwecks der Feststellung rundum des Einlaßes (5) des1. Failure to remove the contamination from atmospheric air, particularly in fault systems, with the aid of neutralization or probing equipment, characterized in that the radius of less than 1000 meters surrounds the inlet (5) from the outside to the inlet ventilation line (6) , which ends from the second side with the inlet to the neutralization or probe apparatus (3), which separates the contaminants from the air, the concentration of the contaminants is measured in several points, advantageously in more than five points, using the pollutant measuring devices (8) , for the purpose of finding all around the inlet (5) of the
Scliadstoffkonzentrationsfeldes (11) definiert als eine Menge von momentanen Konzentrationswerten der Schadstoffe in einem Raum, der von außen durch Meßpunkte der Schadstoffkonzentration begrentzt ist, wobei das Teilfeld einen Bruchteil des Schadstoffkonzentrationsfeldes (11) bildet, und anschließend saugt man die veranreinigte Luft durch die Apparatur (3) mit Hilfe vom Ventilator (4) an, wenn sich das ganze Feld (11) oder wenigstens ein Teilfeld des Feldes (11) vom Radius weniger als ein Meter, das den Einlaß (5) umgibt, innen der Verunreinigungswolke (2), definiert als ein Raum, in dem die Schadstoffkonzentration angenommene Werte überschreitet, befindet, dagegen, wenn sich sogar das Teilfeld vom Radius weniger als ein Meter, das den Einlaß (5) umgibt, innen der Wolke (2) nicht befindet, verlagert man den Einlaß (5) in Richtung erwarteter Wolkenlage und das Ansaugen der verunreinigten Luft mit dem Ventilator (4) durch die Apparatur (3) wird dann eingeschaltet, wenn wenigstens das Teilfeld
des Feldes (11) vom Radius weniger als ein Meter sich innen der Wolke (2) befindet wird.Scliadstoff concentrationsfeldes (11) defined as a set of instantaneous concentration values of the pollutants in a room that is limited from the outside by measuring points of the pollutant concentration, the subfield forming a fraction of the pollutant concentration field (11), and then the cleaned air is sucked through the apparatus ( 3) with the help of the fan (4) when the entire field (11) or at least a partial field of the field (11) is less than one meter in radius from the radius surrounding the inlet (5), inside the cloud of contamination (2), defined as a room in which the pollutant concentration exceeds assumed values, on the other hand, if even the partial field of radius less than one meter surrounding the inlet (5) is not inside the cloud (2), the inlet is shifted (5) in the direction of the expected cloud position and the suction of the polluted air with the fan (4) through the apparatus (3) is switched on if at least the subfield of the field (11) of the radius is less than one meter inside the cloud (2).
2. Verfahren nach Ansprach 1, dadurch gekennzeichnet, daß man den Auslaß (9) der Auslaufventilationsleitung (10) so einstellt, damit die Achse der Leitung (10) nicht in Richtung der Wolke 2 eingestellt ist.2. The method according spoke 1, characterized in that the outlet (9) of the outlet ventilation line (10) is set so that the axis of the line (10) is not set in the direction of the cloud 2.
3. Verfahren nach Ansprach 1, dadurch gekennzeichnet, daß man den Einlaß (5) nach der Konzentrationsminderang der Verunreinigung innen des Feldes (11) zum neuen Punkt der Wolke (2) verlagert.3. The method according spoke 1, characterized in that the inlet (5) is shifted to the new point of the cloud (2) after the concentration deficit of the contamination inside the field (11).
4. Verfahren nach Ansprach 1, dadurch gekennzeichnet, daß die in Apparatur (4) von der Luft abgesonderte Verunreinigungen (3) anschließend während der Sorbensregeneration als Recyklingrohstoff zurückgewannen sind.4. The method according spoke 1, characterized in that the contaminants (3) separated from the air in the apparatus (4) are subsequently recovered as a recycling raw material during the sorbent regeneration.
5. Einrichtung zur Beseitigung von Veranreinigungen aus Luft, besonders in Störungslagen, mit Hilfe von Neutralisations -oder Absondemapparatur, die in Raum versetzbar ist, dadurch gekennzeichnet, daß sie im Verhältnis zum Einlaß (5) der Einlaufventilationsleitung (6), die verbunden mit dem Einlaß zur Neutralisations - oder Absondemapparatur (3) ist, wenigstens ein beweglichen und ein unbeweglichen oder wenigstens ein beweglichen oder wenigstens zwei unbewegliche Schadstoffkonzentrationsmeßgeräte (8) und oder Einlasse (13) zum Meßgerät (8) hat, die auf einem Transportmittel (1) der Apparatur (3) und Ventilator (4) oder auf einem Kraftwagen (12) mit Apparatur (3) und oder auf einem Anhänger (14) mit Ventilator (4) und oder auf einem andern Verkehrsmittel (16) untergebracht sind.
5. A device for removing impurities from air, especially in fault situations, with the help of neutralization or Absondemapparatur, which can be moved into space, characterized in that it is in relation to the inlet (5) of the inlet ventilation line (6) connected to the The inlet to the neutralization or probe apparatus (3) has at least one movable and one immobile or at least one movable or at least two immobile pollutant concentration measuring devices (8) and or inlets (13) for the measuring device (8), which are placed on a means of transport (1) Apparatus (3) and fan (4) or on a motor vehicle (12) with apparatus (3) and or on a trailer (14) with fan (4) and or on another means of transport (16).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU54552/99A AU5455299A (en) | 1998-09-11 | 1999-09-07 | Method and device for eliminating impurities from the atmosphere, especially in case of breakdowns |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PLP.328523 | 1998-09-11 | ||
| PL32852398A PL188001B1 (en) | 1998-09-11 | 1998-09-11 | Method of removing pollutants from atmospheric air and apparatus therefor especially for use in emergency situations |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000016097A1 true WO2000016097A1 (en) | 2000-03-23 |
Family
ID=20072813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/PL1999/000030 WO2000016097A1 (en) | 1998-09-11 | 1999-09-07 | Method and device for eliminating impurities from the atmosphere, especially in case of breakdowns |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU5455299A (en) |
| PL (1) | PL188001B1 (en) |
| WO (1) | WO2000016097A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10122139A1 (en) * | 2001-05-08 | 2002-11-21 | Daniel Swarovski | Remotely-controlled environmental sampling and pollutant distribution profiling, comprises use of e.g. airship with sampling and analysis equipment |
| DE102005025309B3 (en) * | 2005-06-02 | 2006-12-28 | Eads Deutschland Gmbh | Sampling system, for elucidating of aerosol clouds, comprises two or more units arranged symmetrical to aircraft axle for admission of air sample, whereby units are discarded over base station |
| EP2103340A1 (en) * | 2008-03-18 | 2009-09-23 | Astrium GmbH | Device for removing dangerous gases from the atmosphere |
| US20160290977A1 (en) * | 2015-03-31 | 2016-10-06 | International Business Machines Corporation | System and method for air-pollutant source-localization using parked motor vehicles |
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| US3780566A (en) * | 1972-03-07 | 1973-12-25 | Argus Chem | Apparatus for continuously monitoring air-pollution |
| EP0287929A2 (en) * | 1987-04-24 | 1988-10-26 | Miles Inc. | Remote sensing gas analyzer |
| JPH0199634A (en) * | 1987-10-09 | 1989-04-18 | Hiroshi Mizutani | Method for purifying polluted air |
| US5147429A (en) * | 1990-04-09 | 1992-09-15 | James Bartholomew | Mobile airborne air cleaning station |
| DE4312635A1 (en) * | 1993-04-19 | 1994-10-20 | Klaus Ehrmann | Method and measuring device for the conduct and immediate evaluation of atmospheric pollutant analyses in situ |
-
1998
- 1998-09-11 PL PL32852398A patent/PL188001B1/en unknown
-
1999
- 1999-09-07 AU AU54552/99A patent/AU5455299A/en not_active Abandoned
- 1999-09-07 WO PCT/PL1999/000030 patent/WO2000016097A1/en active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3780566A (en) * | 1972-03-07 | 1973-12-25 | Argus Chem | Apparatus for continuously monitoring air-pollution |
| EP0287929A2 (en) * | 1987-04-24 | 1988-10-26 | Miles Inc. | Remote sensing gas analyzer |
| JPH0199634A (en) * | 1987-10-09 | 1989-04-18 | Hiroshi Mizutani | Method for purifying polluted air |
| US5147429A (en) * | 1990-04-09 | 1992-09-15 | James Bartholomew | Mobile airborne air cleaning station |
| DE4312635A1 (en) * | 1993-04-19 | 1994-10-20 | Klaus Ehrmann | Method and measuring device for the conduct and immediate evaluation of atmospheric pollutant analyses in situ |
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| PATENT ABSTRACTS OF JAPAN vol. 13, no. 315 18 July 1989 (1989-07-18) * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10122139A1 (en) * | 2001-05-08 | 2002-11-21 | Daniel Swarovski | Remotely-controlled environmental sampling and pollutant distribution profiling, comprises use of e.g. airship with sampling and analysis equipment |
| DE102005025309B3 (en) * | 2005-06-02 | 2006-12-28 | Eads Deutschland Gmbh | Sampling system, for elucidating of aerosol clouds, comprises two or more units arranged symmetrical to aircraft axle for admission of air sample, whereby units are discarded over base station |
| EP2103340A1 (en) * | 2008-03-18 | 2009-09-23 | Astrium GmbH | Device for removing dangerous gases from the atmosphere |
| DE102008015080B3 (en) * | 2008-03-18 | 2009-11-26 | Astrium Gmbh | Device for removing harmful gases from the atmosphere |
| US7776295B2 (en) | 2008-03-18 | 2010-08-17 | Astrium Gmbh | Flying apparatus and method for removing harmful gases from the atmosphere |
| RU2410613C2 (en) * | 2008-03-18 | 2011-01-27 | Астриум Гмбх | Device for removing harmful gases from atmosphere |
| US20160290977A1 (en) * | 2015-03-31 | 2016-10-06 | International Business Machines Corporation | System and method for air-pollutant source-localization using parked motor vehicles |
| US9719972B2 (en) * | 2015-03-31 | 2017-08-01 | International Business Machines Corporation | System and method for air-pollutant source-localization using parked motor vehicles |
Also Published As
| Publication number | Publication date |
|---|---|
| PL328523A1 (en) | 2000-03-13 |
| PL188001B1 (en) | 2004-11-30 |
| AU5455299A (en) | 2000-04-03 |
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