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WO1996028033A1 - Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien - Google Patents

Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien Download PDF

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Publication number
WO1996028033A1
WO1996028033A1 PCT/AU1996/000137 AU9600137W WO9628033A1 WO 1996028033 A1 WO1996028033 A1 WO 1996028033A1 AU 9600137 W AU9600137 W AU 9600137W WO 9628033 A1 WO9628033 A1 WO 9628033A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
volume
alcohol
disinfecting
oil
Prior art date
Application number
PCT/AU1996/000137
Other languages
English (en)
Inventor
Neil Tumbers
Original Assignee
Palmrow Pty. Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Palmrow Pty. Ltd. filed Critical Palmrow Pty. Ltd.
Priority to AU48714/96A priority Critical patent/AU4871496A/en
Publication of WO1996028033A1 publication Critical patent/WO1996028033A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • TITLE Disinfectant/Insecticide composition containing Eucalyptus Oil and Australian Tea Tree Oil
  • the present invention relates to a disinfecting and insecticidal composition, and in particular, but not exclusively, to a disinfecting and insecticidal composition which is manufactured at least partially from natural chemical products.
  • the most commonly used disinfecting agent is benzalkonium chloride, and it is feared that because of the extensive use of this compound, various strains of bacteria have developed resistance. This is especially dangerous as it would be expected that after treating with a disinfectant, the object or surface which has been treated would be substantially free of bacterial or fungal growth; however this may not in fact be the case and could lead to the transmission of infection, especially where the disinfection is taking place in hospitals or food preparation areas.
  • compositions which exhibits the dual activity of being a broad spectrum disinfectant and an insecticidal/insect repelling agent, and at least partially containing natural products which have a low toxicity to humans and which can be environmentally friendly. It is a further object of the present invention to provide such a disinfecting and insecticidal composition which will be straightforward and economical to produce.
  • a disinfecting and insecticidal composition which is comprised of:
  • the alcohol is ethanol and the wetting agent is comprised of a mixture of sulphonic acid and caustic soda, or is a sodium lauryl sulfate.
  • a method of manufacturing a disinfecting and insecticidal composition as described above which comprises the steps of:
  • the method referred to above will also comprise the initial step of preparing the wetting agent by mixing sulphonic acid and caustic soda.
  • a composition containing a wetting agent, an alcohol and an amount of tea tree oil and/or eucalyptus oil with water is especially effective as a broad spectrum disinfecting agent, and also shows powerful activity as an insecticide and/or insect repelling agent.
  • This composition is especially suited for large scale commercial applications such as disinfection and insecticide/insect repellent treatment of food preparation areas such as food processing plants or restaurants, kitchens and also in hospitals, but naturally the applications of this composition are far broader and it can be usefully employed as a domestic cleaning agent and direct insecticide or surface applied insecticide.
  • the composition includes between about 5% and about 25% by volume of the total composition of a wetting agent, between about 10% and about 40% by volume of the total composition of an alcohol, between about 0.25% and about 14% by volume of the total composition of a combination of tea tree oil and/or eucalyptus oil, with the balance of the composition being made up of water.
  • concentration ranges of the components of the composition are determined by the activity of the component and its relative miscibility. For example, it has been shown that a total concentration of 0.25% by volume of the total composition of tea tree oil and/or eucalyptus oil is necessary for the composition to function as an effective antibacterial agent.
  • a concentration in excess of about 14% by volume of the total composition of tea tree and/or eucalyptus oil in combination will result in an immiscible mixture rather than a homogenous solution.
  • a wetting agent of between about 5% and about 25% by volume of the total composition is necessary for solubility purposes.
  • wetting agent what is meant is the use of an agent which will act as a surfactant to reduce surface tension of the components of the composition such that the various components of the composition, some of which are immiscible, will be able to mix to form a homogenous solution. This homogeneity is important for the activity of the composition so that when it is applied as a disinfectant/insecticide, the active ingredients will be equally distributed upon the surface or object which is being treated. It is possible to utilise any known wetting agent such as wetting agents which are manufactured from a detergent base, however, the most preferred wetting agent is sodium lauryl sulfate.
  • the alcohol utilised in the composition can be any common alcohol, such as for example an alcohol of a C 1 - C 5 hydrocarbon. This is mentioned by way of example only however and it is to be recognised that a broad range of alcohols will be acceptable in carrying out the present invention. It is expected however, that the most preferable alcohol will be ethanol due to its availability.
  • One preferred source of ethanol which is readily available as a by-product, is by fermentation from sugar cane. Other sources of ethanol, are however equally acceptable.
  • the alcohol component of the composition acts to improve its disinfecting activity, but at the same time also aids drying of the composition. This is useful where, for example, the composition is used to disinfect and insect treat a tiled floor, such that the composition will readily evaporate from the floor so that the floor will not remain wet for long periods of time, which could constitute an occupational health and safety hazard.
  • the key active ingredients in the composition of the present invention are tea tree oil and eucalyptus oil, and these ingredients in combination should be present in the concentration rage of between about 0.25% and about 14% by volume of the total composition.
  • Another aspect of this invention relates to the preparation of the inventive composition.
  • the miscibility problems which are associated with the composition it appears to be quite important as to the order in which the various components of the composition are added during the manufacture process. It has been found that the most preferred method of manufacture is to firstly dilute the wetting agent with the required amount of water and to then add in sequence the alcohol, the eucalyptus oil and finally the tea tree oil. The last stage of the process is to mix the components to a homogenous solution.
  • the wetting agent is made of a mixture of caustic soda and alkylbenzene sulphonic acid, and the alcohol is ethanol. It is to be recognised that it is also possible to form a solid by adsorbing the solution onto a filler block or a powder such as soda ash (by methods well known in the art) . It is also possible to mix the composition with a propellant, as is well established and known in the art, in order to provide a sprayable aerosol composition which is useful for both direct killing of insects and insect repellent treatment of surfaces and/or insect repellent of humans or animals, or indeed for use as a disinfectant.
  • the product formulated as an aerosol spray as referred to above or indeed as a gel or cream when associated with customary pharmaceutical excipients, or in fact it is even possible to simply apply the composition in its natural state by rubbing it on the skin, hair or clothes of a human or animal, or possibly applying it using a roll-on applicator. It is to be recognised that other standard application techniques which are known in the personal insecticide art are also envisaged as being potential application techniques in relation to the present invention.
  • the composition according to the present invention is particularly suited to use as a general multi-purpose type disinfectant/insecticide for a broad range of applications.
  • the composition will be especially useful for applications to walls and floors of areas which must be kept hygienically clean, for example in food preparation areas and in hospitals.
  • the broad range of disinfecting action of this composition and its dual activity as an insecticide/insecticide repellent make it especially useful in these applications.
  • the application of the composition for these purposes can be by any conventional method such as, for example, mopping or spraying. It is also possible that the composition can be diluted further with water in order to be applied using a mop in conventional cleaning practices. It is to be recognised however that further diluting the composition will affect its anti-bacterial, anti-fungal and insecticide activities.
  • composition according to the present invention has been shown to exhibit insecticidal and inset repellent properties in relation to a broad range of insects.
  • composition has been shown to be especially active for killing and repelling cockroaches, ants, flies, mosquitoes, beetles, spiders, silver fish, moths as well as numerous other insect species.
  • Example 1 Formulation of preferred disinfectant/insecticide compositio :
  • wetting agent comprising sodium lauryl sulfate
  • composition percentages referred to above are percentages of each component by volume relative to the total volume of composition.
  • a disinfectant/insecticide composition which was manufactured according to the formulation provided in Example 1 was applied using a mop and undiluted to a restaurant kitchen at the close of the restaurant for the evening. Prior to the treatment the restaurant had been reporting problems with cockroaches. Upon returning in the morning there were numerous dead cockroaches to be observed on the restaurant floor, and no live cockroaches could be found.
  • Example 4 A composition of the formulation of Example 1 was diluted 20:1 with water and then poured into an ants nest on an oval. Ants were observed to be killed directly and inspection after 2 days revealed that no live ants were present in the nest.
  • Example 5 A composition of the formulation of Example 1 was diluted 20:1 with water and then poured into an ants nest on an oval. Ants were observed to be killed directly and inspection after 2 days revealed that no live ants were present in the nest.
  • Example 1 The formulation of Example 1 was sprayed on and adjacent to waste bins, behind a restaurant, where there had been a cockroach problem. The bins were sprayed four afternoons in a row, and then in the evening after the close of the restaurant the lights were switched off and the bin area was inspected using torches. No cockroaches could be observed.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Composition désinfectante et insecticide comprenant: (a) 5 à 25 % en volume d'un agent de mouillage/tensioactif; (b) 10 à 40 % en volume d'alcool; (c) 0,25 à 14 % en volume d'une combinaison d'huile de cajeput australien (huile de mélaleuca) et d'huile d'eucalyptus; (d) de l'eau.
PCT/AU1996/000137 1995-03-14 1996-03-14 Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien WO1996028033A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU48714/96A AU4871496A (en) 1995-03-14 1996-03-14 Disinfectant/insecticide composition containing eucalyptus oil and australian tea tree oil

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPN1704 1995-03-14
AUPN1704A AUPN170495A0 (en) 1995-03-14 1995-03-14 Disinfectant/insecticide composition

Publications (1)

Publication Number Publication Date
WO1996028033A1 true WO1996028033A1 (fr) 1996-09-19

Family

ID=3786059

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/AU1996/000050 WO1996028032A1 (fr) 1995-03-14 1996-02-01 Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien
PCT/AU1996/000137 WO1996028033A1 (fr) 1995-03-14 1996-03-14 Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/AU1996/000050 WO1996028032A1 (fr) 1995-03-14 1996-02-01 Composition desinfectante/insecticide contenant de l'huile d'eucalyptus et de l'huile de cajeput australien

Country Status (2)

Country Link
AU (1) AUPN170495A0 (fr)
WO (2) WO1996028032A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5826546A (en) * 1997-04-23 1998-10-27 Miraclecorp Of Australia Method for shampooing a pet using a foam-dispensed pet shampoo composition
WO1999018802A1 (fr) * 1997-10-09 1999-04-22 Barrier Biotech Limited Composition pesticide
WO1999027793A3 (fr) * 1997-11-28 1999-07-22 Barrier Biotech Limited Composition antimicrobienne
DE19821106A1 (de) * 1998-05-12 1999-11-18 Grewe Helmut F Milbentötendes - Reinigungsmittel für Textilien auf Basis ätherischer Pflanzen- und Baumöle
US6019963A (en) * 1998-11-20 2000-02-01 D.S.C. Products, Inc. Deodorizing composition containing tea tree and eucalyptus oils
US6592813B1 (en) 1998-07-02 2003-07-15 University Of Southampton Malodour counteracting treatment
WO2005084717A1 (fr) * 2004-03-09 2005-09-15 Sunnywipes Pty Ltd Solution de nettoyage et lingettes et procede de nettoyage
EP1964576A1 (fr) * 2007-02-27 2008-09-03 Certmedica International GmbH Préparation en gel désinfectante à l'eau
WO2011046611A1 (fr) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Compositions vertes de désinfection et de nettoyage et leurs procédés de production
WO2011013133A3 (fr) * 2009-07-28 2011-05-05 The Energy And Resources Institute (Teri) Nouvelles compositions biopesticides et leur procédé d'isolement et de caractérisation
CN102834038A (zh) * 2009-11-23 2012-12-19 约翰逊父子公司 水激活环保型多功能抹布
US12291693B2 (en) 2022-06-27 2025-05-06 The Procter & Gamble Company Stable aqueous surfactant compositions
US12310355B2 (en) 2019-12-06 2025-05-27 The Procter & Gamble Company Pest control spray

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69735212T2 (de) * 1996-11-20 2006-08-10 Monopace Pty. Ltd., Tweed Heads Feste zusammensetzungen essentieller öle
DE19729852A1 (de) * 1997-07-11 1999-09-09 Feil Mückenabweisendes hautverträgliches Mittel
AUPP244098A0 (en) * 1998-03-18 1998-04-09 Main Camp Marketing Pty. Ltd. Tea tree oil pesticidal compositions
AU2003281745B2 (en) * 2002-07-29 2008-04-03 George John Orban Insect repellant
AU2002950436A0 (en) * 2002-07-29 2002-09-12 George John Orban Insect repellant
FR2853325B1 (fr) * 2003-04-04 2007-08-31 Teinturerie Leschaeve Composition aqueuse pour nettoyage a sec naturel, procede et appareil de nettoyage a sec
GB0319537D0 (en) * 2003-08-20 2003-09-24 Allied Bio Corp Ltd Improvements in and relating to sanitary compositions
KR102025818B1 (ko) * 2017-09-07 2019-09-25 주식회사 래디안 천연 항균제 및 이의 제조방법
CN114342964A (zh) * 2021-12-21 2022-04-15 广东长康科技有限公司 一种杀菌剂及其制备方法和应用

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US4587123A (en) * 1984-06-28 1986-05-06 Price Jacqueline S Compositions and methods for reducing pest infestation
AU3723589A (en) * 1988-06-30 1990-01-04 Omaryne Proprietary Limited Therapeutic composition

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US4587123A (en) * 1984-06-28 1986-05-06 Price Jacqueline S Compositions and methods for reducing pest infestation
AU3723589A (en) * 1988-06-30 1990-01-04 Omaryne Proprietary Limited Therapeutic composition

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Title
INTERNATIONAL JOURNAL OF AROMATHERAPY, Volume 1, No. 3, 1988, R.L. WILLIAMS et al., "The Composition and Bactericidal Activity of Oil of Melaleuca Alternifolia (Tea Tree Oil)", pages 15-17. *
JOURNAL AND PROCEEDINGS OF THE ROYAL SOCIETY OF NEW SOUTH WALES, Volume 59, 1925, A.R. PENFOLD and R. GRANT, "The Germicidal Values of Some Australian Essential Oils and Their Pure Constituents", pages 346-350. *
JOURNAL OF ANTIMICROBIAL CHEMOTHERAPY, Volume 35, No. 3, 1995, C.F. CARSON et al., "Susceptibility of Methicillin-Resistant Staphylococcus Aureus to the Essential Oil of Melaleuca Alternifolia", pages 421-424. *
JOURNAL OF APPLIED BACTERIOLOGY, Volume 78, No. 3, 1995, C.F. CARSON and T.V. RILEY, "Antimicrobial Activity of the Major Components of the Essential Oil of Malaleuca Alternifolia", pages 264-269. *
LETTERS IN APPLIED MICROBIOLOGY, Volume 16, 1993, C.F. CARSON and T.V. RILEY, "Antimicrobial Activity of the Essential Oil of Melaleuca Alternifolia", pages 49-55. *
LETTERS IN APPLIED MICROBIOLOGY, Volume 21, No. 4, 1995, A. RAMAN et al., "Antimicrobial Effects of Tea-Tree Oil and Its Major Components on Staphylococcus Aureus, Staph. Epidermidis and Propionibacterium Acnes", pages 242-245. *
PLANTA MEDICA, Volume 26, 1974, D. LOW et al., "Antibacterial Action of the Essential Oils of Some Australian Myrtaceae With Special References to the Activity of Chromatographic Fractions of Oil Eucalyptus Citriodora", pages 184-189. *
THE AUSTRALIAN JOURNAL OF EXPERIMENTAL BIOLOGY AND MEDICAL SCIENCE, Volume 33, 1955, N. ATKINSON and H.E. BRICE, "Antibacterial Substances Produced by Flowering Plants", pages 547-554. *
THE INDIAN FORESTER, Volume 114, No. 1, 1988, D.C. CHOUDHARI et al., "In Vitro Antimicrobial Activity of Essential Oil of Newly Evolved Eucalyptus Hybrid FRI-4", pages 35-38. *
THE MEDICAL JOURNAL OF AUSTRALIA, Volume 160, 21 February 1994, C.F. CARSON and T.V. RILEY, "The Antimicrobial Activity of Tea Tree Oil", page 236. *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5826546A (en) * 1997-04-23 1998-10-27 Miraclecorp Of Australia Method for shampooing a pet using a foam-dispensed pet shampoo composition
WO1999018802A1 (fr) * 1997-10-09 1999-04-22 Barrier Biotech Limited Composition pesticide
US6251440B1 (en) 1997-10-09 2001-06-26 Barrier Biotech Limited Pesticidal composition
WO1999027793A3 (fr) * 1997-11-28 1999-07-22 Barrier Biotech Limited Composition antimicrobienne
US6352702B1 (en) 1997-11-28 2002-03-05 Barrier Biotech Limited Antimicrobial composition
DE19821106A1 (de) * 1998-05-12 1999-11-18 Grewe Helmut F Milbentötendes - Reinigungsmittel für Textilien auf Basis ätherischer Pflanzen- und Baumöle
US6592813B1 (en) 1998-07-02 2003-07-15 University Of Southampton Malodour counteracting treatment
US6019963A (en) * 1998-11-20 2000-02-01 D.S.C. Products, Inc. Deodorizing composition containing tea tree and eucalyptus oils
WO2005084717A1 (fr) * 2004-03-09 2005-09-15 Sunnywipes Pty Ltd Solution de nettoyage et lingettes et procede de nettoyage
EP1964576A1 (fr) * 2007-02-27 2008-09-03 Certmedica International GmbH Préparation en gel désinfectante à l'eau
WO2011013133A3 (fr) * 2009-07-28 2011-05-05 The Energy And Resources Institute (Teri) Nouvelles compositions biopesticides et leur procédé d'isolement et de caractérisation
AU2009350416B2 (en) * 2009-07-28 2014-08-14 The Energy And Resources Institute (Teri) Novel biopesticide compositions and method for isolation and characterization of same
WO2011046611A1 (fr) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Compositions vertes de désinfection et de nettoyage et leurs procédés de production
CN102655740A (zh) * 2009-10-14 2012-09-05 约翰逊父子公司 绿色消毒/杀菌合成物及其制备过程
US8778860B2 (en) 2009-10-14 2014-07-15 S.C. Johnson & Son, Inc. Green disinfection/sanitization compositions and processes of making thereof
CN102834038A (zh) * 2009-11-23 2012-12-19 约翰逊父子公司 水激活环保型多功能抹布
US12310355B2 (en) 2019-12-06 2025-05-27 The Procter & Gamble Company Pest control spray
US12291693B2 (en) 2022-06-27 2025-05-06 The Procter & Gamble Company Stable aqueous surfactant compositions

Also Published As

Publication number Publication date
AUPN170495A0 (en) 1995-04-06
WO1996028032A1 (fr) 1996-09-19

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