[go: up one dir, main page]

WO1996022020A1 - Compositions pesticides - Google Patents

Compositions pesticides Download PDF

Info

Publication number
WO1996022020A1
WO1996022020A1 PCT/GB1996/000087 GB9600087W WO9622020A1 WO 1996022020 A1 WO1996022020 A1 WO 1996022020A1 GB 9600087 W GB9600087 W GB 9600087W WO 9622020 A1 WO9622020 A1 WO 9622020A1
Authority
WO
WIPO (PCT)
Prior art keywords
ester
composition
pesticidal
log
value
Prior art date
Application number
PCT/GB1996/000087
Other languages
English (en)
Inventor
Geoffrey Gower Briggs
David Stock
Original Assignee
Agrevo Uk Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agrevo Uk Limited filed Critical Agrevo Uk Limited
Priority to AU43965/96A priority Critical patent/AU4396596A/en
Publication of WO1996022020A1 publication Critical patent/WO1996022020A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A01N37/04—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof polybasic
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids

Definitions

  • This invention concerns pesticidal compositions. Background to the invention
  • Pesticidal compounds particularly those used for crop protection, are commonly used in the form of compositions containing one or more co-formulants, for example surfactants. We have found that a new group of compounds, not previously used in association with pesticidal compounds, can also be used with advantage in association with pesticidal compounds.
  • the invention provides the use in a pesticidal composition of at least one aliphatic mono-, di- or triester, optionally substituted by one or more hydroxy groups, said ester(s) having: i) a log octanol-water partition coefficient (log P) of from 5 to 13.1, ii) an equivalent hydrocarbon (EH) value of from 20 to 42; the EH value being calculated as the number of carbon atoms plus five for any hydroxy group present plus 3 for each ester group, and iii) an alcohol moiety comprising at least 2 carbon atoms.
  • log P log octanol-water partition coefficient
  • EH equivalent hydrocarbon
  • ester of the invention' is used herein to indicate an ester having the above properties.
  • the invention provides a pesticidal composition which comprises a pesticidal compound and at least one ester of the invention.
  • the invention provides a method of combating pests at a locus infested or liable to be infested therewith which comprises applying to said locus an effective amount of a pesticidal composition which comprises a pesticidal compound and at least one ester of the invention.
  • the log P value of an ester as that term is used herein is that calculated from the structure of the compound using the clog P Program, Pomona College Med Chem release 3.54, January 1988, provided by Daylight Chemical Information Systems Inc, Claremont, California.
  • the values generated by this program correlate well in general with those determined experimentally by methods well known to those skilled in the art, but such methods are difficult to apply accurately to compounds having log P values within the scope of this invention, and we therefore use the calculated values.
  • the EH value can be simply calculated from the structure of each compound. Sometimes, however, the esters of the invention occur or are presented as mixtures of individual compounds, and the mixture will therefore include compounds of different EH values.
  • the ratio of EH value to log P value is preferably in the range 2.4:1 to 4.15:1.
  • esters of the invention are succinate diesters, lactic acid carboxylic esters, and esters resulting from esterification of a saturated acid of at least 12 carbon atoms with a branched chain alcohol.
  • esters of the invention which have little or no pesticidal activity in their own right, surprisingly aid the penetration of the pesticidal compound into plant or pest tissue, thereby promoting enhanced activity, particularly of pesticidal compounds whose activity depends on such penetration.
  • the pesticidal compound is especially one disclosed in The Pesticide Manual, 10th edition, published by Crop Protection Publications, and may for example be a herbicide, fungicide, insecticide or acaricide.
  • phytopathogenic fungicide selected from:
  • a conazole steroid demethylation inhibitor (i) a conazole steroid demethylation inhibitor; (ii) a steroid reduction inhibitor based on a l-[3-(4- tert-butylphenyl)-2-methylpropyl] group which is attached via the N-atom to piperidine or 2,6- dimethylmorpholine (iii) a dithiocarbamate fungicide (iv) a phthali ide fungicide in which a chloroalkylthio group is attached via the N-atom to the optionally hydrogenated phthalimide group, (v) an anilide fungicide (vi) an mbc fungicide. (vii) a carbamate fungicide
  • a copper compound fungicide (ix) a tin compound fungicide (x) a strobilurin type fungicide, (xi) a 2-anilinopyrimidine fungicide or (x ⁇ ) a fungicide selected from the group consisting of chlorothalonil, dimethomorph, fenpiclonil, fluazinam, hymexazol, nuarimol, pencycuron, pyrifenox, thicyofen, probenazole, pyroquilon, tricyclazole, quaternary ammonium compounds.
  • Conazoles are as defined in ISO standard 257, ie compounds based on imidazole or 1,2,4-triazole and containing a halogenated phenyl group.
  • Examples include prochloraz (and its metal complexes, especially the manganese or copper complex) , propiconazole, flusilazole, hexaconazole, tebuconazole, difenoconazole, bromuconazole, cyproconazole, diniconazole, fenbuconazole, imibenconazole, furconazole, tetraconazole, myclobutanil, penconazole, fluquinconazole, azaconazole, imazalil, triflumizole, epoxiconazole, triticonazole, metconazole and the fungicide having the code No SSF 109.
  • type (ii) fungicides include fenpropimorph and fenpropidin.
  • type (iii) fungicides include mancozeb and thiram.
  • type (iv) fungicides include folpet, captafol and captan.
  • type (v) fungicides include a) 3' ,5'-dichloroanilide fungicides in which the anilino nitrogen comprises a ring carrying two oxo substituents, in positions adjacent the nitrogen, eg iprodione, vinclozolin or procymidone, or b) acetanilide fungicides, eg metalaxyl or ofurace, c) sulfanilide fungicides, eg dichlofluanid, d) benzanilide fungicides, eg flutolanil, and e) heteroarylanilide fungicides, eg thifluzamide.
  • type (vi) fungicides include carbendazim, benomyl and thiophanate-methyl.
  • type (vii) fungicides include diethofencarb and propamocarb.
  • type (viii) fungicides include Bordeaux mixture, oxine-copper, copper oxychloride and copper naphthenate.
  • type (ix) fungicides include tributyltin oxide and tributyltin naphthenate.
  • Strobilurine type fungicides are methyl esters of arylacetic acid in which the acetic acid also carries a methoxymethylene or methoxyi ino substituent.
  • the aryl group is usually a 2-substituted phenyl group.
  • Examples of such compounds are those disclosed in a wide number of patent applications, including EPS 178826, 203606, 203608, 206523, 229974, 226917, 242070, 242081, 243012, 243014, 251082, 256667, 260794, 260832, 267734, 270252, 273572, 274825, 278595, 291196, 299694, 307101, 307103, 310954, 312221, 312243, 329011 and 336211.
  • Specific compounds are those having the code Nos BAS 490F and ICIA 5504.
  • type (xi) fungicides include pyrimethanil, mepanipyrim and cyprodinil.
  • insecticides examples include amitraz, triazophos and formetanate.
  • acaricides which may be used include clofentezine.
  • the names quoted for these compounds are the non- proprietary common names and the chemical structures can be found for example by reference to The Pesticide Manual.
  • the invention is particularly useful for pesticidal compounds of high melting point and/or low solubility in organic solvents. It is particularly applicable to fluquinconazole.
  • esters of the invention may be incorporated in conventional concentrate formulations of the pesticidal compound (eg suspension concentrates, suspoemulsions or solid formulation types such as water dispersible granules) , which are diluted with water prior to application, or they may be added to the pesticidal composition just prior to use.
  • conventional concentrate formulations of the pesticidal compound eg suspension concentrates, suspoemulsions or solid formulation types such as water dispersible granules
  • the pesticidal composition may include small quantities of solvent and/or surfactant, especially a non-ionic surfactant, and other additives such as fatty acids, to improve the emulsifiability of the esters of the invention.
  • solvent and/or surfactant especially a non-ionic surfactant, and other additives such as fatty acids
  • the esters of the invention preferably comprise from 2 to 90% by weight of a concentrate formulation.
  • the esters of the invention are preferably applied in a diluted formulation at a concentration of 20g to 2000g, preferably 50g to 500g, per 100 litres.
  • the mixtures can be used for those applications where the pesticide would normally be used.
  • fluquinconazole for example, it is preferably used in the direct treatment of growing crops, such as cereals and fruit, or in seed treatments.
  • Clarkamol OHS is a trade name for 2-ethylhexyl 12- hydroxystearate
  • Rodamol PC M is a trade name for propylene glycol diester of coconut fatty acids
  • Crodamol IPP is a trade name for isopropyl palmitate
  • Clarkamol IPM is a trade name for isopropyl myristate
  • Crodamol OHS is a trade name for 2-ethylhexyl 12- hydroxystearate
  • Electrodeamol OSU is a trade name for dioctyl succinate
  • Rodamol OP is a trade name for 2-ethylhexyl palmitate
  • Electromol ML is a trade name for myristyl lactate
  • Clarkamol LL is a trade name for lauryl lactate.
  • EC is epoxiconazole
  • BC is bromuconazole
  • TC is tebuconazole
  • CP is cyprodinil
  • TP is triazophos
  • FM is formetanate.
  • Results are given in the following table: gster ⁇ Mortality % Mort ity with CZ without cz Crodamol IPP 99 0

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Utilisation, dans une composition pesticide, d'au moins un mono-, di- ou triester aliphatique, éventuellement substitué par un ou plusieurs groupes hydroxy, ledit ou lesdits esters ayant: i) un log de coefficient de partage octanol-eau (log P) compris entre 5 et 13,1, ii) une valeur d'équivalent hydrocarbure (EH)comprise entre 20 et 42; la valeur EH étant calculée comme étant le nombre d'atomes de carbone plus cinq pour chaque groupe hydroxy présent, plus 3 pour chaque groupe ester, et iii) une fraction alcool comprenant au moins 2 atomes de carbone.
PCT/GB1996/000087 1995-01-19 1996-01-17 Compositions pesticides WO1996022020A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU43965/96A AU4396596A (en) 1995-01-19 1996-01-17 Pesticidal compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9500983.3 1995-01-19
GBGB9500983.3A GB9500983D0 (en) 1995-01-19 1995-01-19 Pesticidal compositions

Publications (1)

Publication Number Publication Date
WO1996022020A1 true WO1996022020A1 (fr) 1996-07-25

Family

ID=10768208

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1996/000087 WO1996022020A1 (fr) 1995-01-19 1996-01-17 Compositions pesticides

Country Status (3)

Country Link
AU (1) AU4396596A (fr)
GB (1) GB9500983D0 (fr)
WO (1) WO1996022020A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744332A1 (fr) * 1996-02-06 1997-08-08 Basf Ag Melange, produits phytosanitaires contenant ce melange et leur utilisation
FR2756464A1 (fr) * 1996-12-02 1998-06-05 Rhone Poulenc Agrochimie Association fongicide a effet synergique a base d'huile d'origine vegetale transformee
WO2000024253A1 (fr) * 1998-10-22 2000-05-04 Aventis Cropscience S.A. Utilisation de derives d'acide citrique comme adjuvants pesticides
US6184182B1 (en) 1996-10-25 2001-02-06 Monsanto Company Composition and method for treating plants with exogenous chemicals
EP1604570A3 (fr) * 2004-06-11 2006-01-18 Luxan B.V. Inhibiteur de germination pour pommes de terre
WO2007028538A2 (fr) 2005-09-09 2007-03-15 Bayer Cropscience Aktiengesellschaft Utilisation d'esters de lactate pour ameliorer l'action de produits phytosanitaires
US7407979B2 (en) 2001-04-12 2008-08-05 Basf Aktiengesellschaft Bioregulatory active ingredient combination
WO2008128666A3 (fr) * 2007-04-21 2009-09-24 Cognis Ip Management Gmbh Compositions agrochimiques
US8349769B2 (en) 2004-07-09 2013-01-08 The New Zealand Institute For Plant And Food Research Limited Fungicidal compositions
WO2013014126A1 (fr) 2011-07-26 2013-01-31 Bayer Intellectual Property Gmbh Esters de lactate ethérés, procédé de préparation et leur utilisation pour améliorer l'effet d'agents phytoprotecteurs
WO2015145057A1 (fr) * 2014-03-26 2015-10-01 Oleon Utilisation d'ester(s) d'acide(s) gras comme insecticide et /ou arachnicide
US9414593B2 (en) 2006-10-27 2016-08-16 Syngenta Crop Protection, Llc Herbicidal compositions

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2303757A1 (de) * 1973-01-26 1974-08-15 Hoechst Ag Fungizide mittel
FR2347052A1 (fr) * 1976-04-06 1977-11-04 Bayer Ag Nouvelles formulations anthelminthiques a application externe
JPS5692207A (en) * 1979-12-27 1981-07-25 Nisshin Oil Mills Ltd:The Acaricide
EP0045424A1 (fr) * 1980-08-02 1982-02-10 Bayer Ag Formulations "pour-on" actives contre les tiques
DE3247050A1 (de) * 1982-12-20 1984-06-20 Bayer Ag, 5090 Leverkusen Herbizide mittel
EP0128351A1 (fr) * 1983-05-17 1984-12-19 Bayer Ag Agent pesticide
EP0295411A1 (fr) * 1987-05-15 1988-12-21 Sansho Co., Ltd. Préparation pharmaceutique pour l'administration percutanée contenant de l'épérisone ou tolpérisone ou l'un de leurs sels
JPH0565201A (ja) * 1991-04-26 1993-03-19 Dow Eranko Nippon Kk 水田除草用粒剤組成物
JPH05306223A (ja) * 1991-07-03 1993-11-19 Takeda Chem Ind Ltd 抗真菌性外用組成物
EP0579052A2 (fr) * 1992-07-03 1994-01-19 Jörg Prof. Dr. Schönherr Agents pour le traitement de plantes
DE4239181A1 (de) * 1992-11-03 1994-05-05 Hoechst Ag Wirkungsverstärkung von Neophanen, Azaneophanen und anderen Wirkstoffen durch Penetrationsmittel

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2303757A1 (de) * 1973-01-26 1974-08-15 Hoechst Ag Fungizide mittel
DD112891A5 (fr) * 1973-01-26 1975-05-12
FR2347052A1 (fr) * 1976-04-06 1977-11-04 Bayer Ag Nouvelles formulations anthelminthiques a application externe
JPS5692207A (en) * 1979-12-27 1981-07-25 Nisshin Oil Mills Ltd:The Acaricide
EP0045424A1 (fr) * 1980-08-02 1982-02-10 Bayer Ag Formulations "pour-on" actives contre les tiques
DE3247050A1 (de) * 1982-12-20 1984-06-20 Bayer Ag, 5090 Leverkusen Herbizide mittel
EP0128351A1 (fr) * 1983-05-17 1984-12-19 Bayer Ag Agent pesticide
EP0295411A1 (fr) * 1987-05-15 1988-12-21 Sansho Co., Ltd. Préparation pharmaceutique pour l'administration percutanée contenant de l'épérisone ou tolpérisone ou l'un de leurs sels
JPH0565201A (ja) * 1991-04-26 1993-03-19 Dow Eranko Nippon Kk 水田除草用粒剤組成物
JPH05306223A (ja) * 1991-07-03 1993-11-19 Takeda Chem Ind Ltd 抗真菌性外用組成物
EP0579052A2 (fr) * 1992-07-03 1994-01-19 Jörg Prof. Dr. Schönherr Agents pour le traitement de plantes
DE4239181A1 (de) * 1992-11-03 1994-05-05 Hoechst Ag Wirkungsverstärkung von Neophanen, Azaneophanen und anderen Wirkstoffen durch Penetrationsmittel

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
BRIGHTON CROP PROT.CONF.--PESTS DIS., no. 1, 1992, pages 411 - 418 *
CHEMICAL ABSTRACTS, vol. 105, no. 21, 24 November 1986, Columbus, Ohio, US; abstract no. 185721, A.CHAMEL: "Foliar absoprption of herbicides: study of the cuticular penetration using isolated cuticles" XP002003456 *
CHEMICAL ABSTRACTS, vol. 118, no. 19, 10 May 1993, Columbus, Ohio, US; abstract no. 185737, P.E.RUSSELL ET AL.: "Fluquinconazole, a novel broad-spectrum fungicide for foliar application" XP002003455 *
DATABASE WPI Week 7528, Derwent World Patents Index; AN 75-46209W [28], XP002003965 *
DATABASE WPI Week 9316, Derwent World Patents Index; AN 93-129070 [16], XP002003458 *
DATABASE WPI Week 9351, Derwent World Patents Index; AN 93-408837 [51], XP002003457 *
PATENT ABSTRACTS OF JAPAN vol. 5, no. 160 (C - 075) 15 October 1981 (1981-10-15) *
PHYSIOL.VEG., vol. 24, no. 4, 1986, pages 491 - 508 *

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2744332A1 (fr) * 1996-02-06 1997-08-08 Basf Ag Melange, produits phytosanitaires contenant ce melange et leur utilisation
US6479434B1 (en) 1996-10-25 2002-11-12 Monsanto Technology Llc Composition and method for treating plants with exogenous chemicals
US6184182B1 (en) 1996-10-25 2001-02-06 Monsanto Company Composition and method for treating plants with exogenous chemicals
FR2756464A1 (fr) * 1996-12-02 1998-06-05 Rhone Poulenc Agrochimie Association fongicide a effet synergique a base d'huile d'origine vegetale transformee
US6551964B1 (en) 1998-10-22 2003-04-22 Bayer Cropscience S.A. Use of citric acid derivatives as pesticidal adjuvants
JP2002528395A (ja) * 1998-10-22 2002-09-03 アベンティス・クロップサイエンス・エス・アー 農薬補助剤としてのクエン酸誘導体の使用
EP1586238A3 (fr) * 1998-10-22 2010-03-03 Bayer CropScience S.A. Utilisation de derivés d'acide citrique comme adjuvants pour des herbicides
EP1586238A2 (fr) 1998-10-22 2005-10-19 Bayer CropScience S.A. Utilisation de derivés d'acide citrique comme adjuvants pour des herbicides
WO2000024253A1 (fr) * 1998-10-22 2000-05-04 Aventis Cropscience S.A. Utilisation de derives d'acide citrique comme adjuvants pesticides
US7407979B2 (en) 2001-04-12 2008-08-05 Basf Aktiengesellschaft Bioregulatory active ingredient combination
EP1604570A3 (fr) * 2004-06-11 2006-01-18 Luxan B.V. Inhibiteur de germination pour pommes de terre
US9510600B2 (en) 2004-07-09 2016-12-06 The New Zealand Institute For Plant And Food Research Limited Fungicidal compositions
US8349769B2 (en) 2004-07-09 2013-01-08 The New Zealand Institute For Plant And Food Research Limited Fungicidal compositions
EP1926369B1 (fr) 2005-09-09 2015-06-17 Bayer Intellectual Property GmbH Utilisation d'esters de lactate pour ameliorer l'action de produits phytosanitaires
EA014782B1 (ru) * 2005-09-09 2011-02-28 Байер Кропсайенс Аг Сложные эфиры молочной кислоты в качестве агента для улучшения воздействия пестицидов на растения, способ улучшения воздействия пестицидов
AU2006289348B2 (en) * 2005-09-09 2011-04-21 Bayer Intellectual Property Gmbh Use of lactate esters for improving the action of agricultural pesticides
WO2007028538A3 (fr) * 2005-09-09 2007-05-31 Bayer Cropscience Ag Utilisation d'esters de lactate pour ameliorer l'action de produits phytosanitaires
WO2007028538A2 (fr) 2005-09-09 2007-03-15 Bayer Cropscience Aktiengesellschaft Utilisation d'esters de lactate pour ameliorer l'action de produits phytosanitaires
US9414593B2 (en) 2006-10-27 2016-08-16 Syngenta Crop Protection, Llc Herbicidal compositions
WO2008128666A3 (fr) * 2007-04-21 2009-09-24 Cognis Ip Management Gmbh Compositions agrochimiques
WO2013014126A1 (fr) 2011-07-26 2013-01-31 Bayer Intellectual Property Gmbh Esters de lactate ethérés, procédé de préparation et leur utilisation pour améliorer l'effet d'agents phytoprotecteurs
US9826734B2 (en) 2011-07-26 2017-11-28 Clariant International Ltd. Etherified lactate esters, method for the production thereof and use thereof for enhancing the effect of plant protecting agents
WO2015145057A1 (fr) * 2014-03-26 2015-10-01 Oleon Utilisation d'ester(s) d'acide(s) gras comme insecticide et /ou arachnicide
FR3019002A1 (fr) * 2014-03-26 2015-10-02 Novance Utilisation d'ester(s) d'acide(s) gras comme insecticide.
US10045531B2 (en) 2014-03-26 2018-08-14 Oleon Nv Use of one or more fatty acid esters as insecticide and/or arachnicide

Also Published As

Publication number Publication date
AU4396596A (en) 1996-08-07
GB9500983D0 (en) 1995-03-08

Similar Documents

Publication Publication Date Title
EP3240414B1 (fr) Compositions fongicides
RU2242124C2 (ru) Фунгицидная композиция и способ подавления роста грибка в очаге поражения
WO1996022020A1 (fr) Compositions pesticides
EP0556157B1 (fr) Mélanges fongicides à base de fongicides triazoliques et de 4,6-diméthyl-N-phenyl-2-pyrimidinamine
BRPI0807634A2 (pt) Composições biocidas (i)
SK8697A3 (en) Fungicidal composition
DE69821615T3 (de) Ein 4-phenoxychinolin enthaltende fungizide mischungen
EP3162208A1 (fr) Composition fongicide pour contrôler les infections fongiques chez la plante de soja
EP0235082B1 (fr) Microbicides
DE4318372A1 (de) Fungizide Mischungen
EP0818144B1 (fr) Microbicides
SK83898A3 (en) Novel fungicide composition containing a 2-imidazoline-5-one
EP0627164B2 (fr) Compositions microbicides, contenant du prochloraz et du cyprodinil
EP0237483A1 (fr) Microbicides
US20250113825A1 (en) Fungicidal combinations and methods for controlling phytopathogenic fungi
BG61471B1 (bg) Метод за борба с фунги,причинители на мана по растенията,и състав,използван в метода
US6495572B1 (en) Synergistic mixtures of an amino acid
DE69814434T2 (de) Fungizide zusammensetzungen auf der basis von fluquinconazole
WO1998043480A1 (fr) Compositions fongicides comprenant un 3-phenyl-pyrazole
JP2003513989A (ja) 非水性の濃厚展着性オイル組成物
RU2786999C2 (ru) Регулятор роста растений и фунгицид
US20050282841A1 (en) Novel esters as useful broad spectrum fungicidal compounds
US20250017200A1 (en) Dithiocarbamate fungicide combinations and compositions thereof
WO2025151697A1 (fr) Formulations fongicides en suspension concentrée
EA043207B1 (ru) Стабильные жидкие составы протиоконазола

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AU AZ BG BR BY CA CN CZ EE FI GE HU JP KG KR KZ LK LT LV MD MK MX NO NZ PL RO RU SD SG SI SK TR TT UA US UZ VN AZ BY KG KZ RU TJ TM

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA