WO1996005716A2 - Method of removing crude oil or oil products from a surface, a method of regenerating and a method of using the used product - Google Patents

Abstract

The proposed method of removing crude oil or oil products from a surface involves treating the surface in question with a dispersed polymer-containing composite material, specifically, a linear polymer with an unlimited degree of swelling in crude oil or oil products and applied to a light mineral or organic inert filler. Regeneration of the product involves mixing the spent product with an excess of initial crude oil or oil product. The method of using the product involves mixing the spent product with a sand/grit mixture or with road or roofing bitumen used in the construction of roads and buildings. The used product can also be used in the production of clayfiller or as a fuel.

Description

\ УΟ 96/05716 ΡСΤ / Κϋ95 / 00177

CUSTOMS CALCULATIONS

ΗΕΦΤΕПΡΟДАΚΤΟΒ, СПΟСΟБ ΡΕГΕΗΕΡΑΙГИИ and СП0С0Б УУЛИЗΑΙШИ ΟΤΡΑБΟΤΑΗΗΟГΟ ПΡΟДСΡΟ

The area of technology

Izοbρeτenie οτnοsiτsya K χimichesκοy προmyshlennοs- τi and κοnκρeτnee, K οchisτκe ποveρχnοsτi οτ neφτi and neφτeπροduκτοΕ οτκρyτyχ vοdοemοv and vοdοτοκοv, ρezeρvν- aροv and τaκzhe K ρegeneρatsii and isποlzοvaniyu οτρabοτan-

10 nights in the payment process.

BACKGROUND OF THE INVENTION Known at present in the process of calculating and disposing of a fault in the oil and the processing of its base

15 They operate on the physical effect of capillary suction and are ineffective; in this case, they are used as substances, such as pulses. husk of rice, buckwheat, tobacco products, food preparation, vermiculite, product of the industrial product "Utility"

20 Canadian "ΗΙ-ΡοϊηΙ Ιгк-изΙгϊез ϋά", wipes from non-woven materials and other products. Low production efficiency, low aggregate capacities, specified material, high activity, low cost of activity

25 νslοviyam sbορa (vοlnenie mορya, bysτροτeκuschie ρeκi, The presence in ρasτiτelnοsτi όοlοτaχ, οzeρach and dρ. Πρichini for liκvidatsii zagρyazneny not dayuτ zhelaemοgο ρezνlτa- τa. Ηaπρimeρ, οchisτκa ποveρχnοsτi οτ neφτi and neΦτeπρο- DUΚΤΟΕ s νslοviyaχ avaρiynyχ siτνatsy χaρaκτeρizνeτsya

30 significant time for the elimination of pollution with the growing environmental pollution. The conduct of such dispersed materials as the REAL SERVICES may be compared with the performance of a free bet. Sat and more \ θ 96/05716 ΡСΤ / ΚШ5 / 00177

Localization is not very trivial on the external part of the vehicle. In fact, natural degradation of oil is most intensively consumed when it is bottled after it is bottled: monthly 15 l,

5 volumes are sitting at the bottom and 10 are evaporated. Β A further, Shem isπaρeniya not προisχοdiτ, nο ezhesuτοchnο οsedaeτ πο 15% οbema neφτi (Ηοϊtez Ρ.Ο. "011 Zρϊϊϊ Sοηι Ρgοs:.. Ρgeν, Βeϊηaν SοηΙg, Sϊeaηiρ..." Νeν / Οgϊealz 1977

10 Izvesτen sποsοb οchisτκi ΕΟDY οτ προlivοv neφτi with ποmοschyu πρeπaρaτa "ΡΙSZΙΟΟΙ" φiρmy ΒΡ SGιetϊsaΙz Τeχ- nichesκaya inφορmatsiya φiρmy ΒΡ SΙπetιsaΙz πο οchisτκe vοdy οτ neφτi, 1987), vκlyuchayuschy πρimenenie bysτροzagνs- τevayushiχ χimichesκiχ κοmποzitsy. living in polimera

15 and a cross-linking agent, and this is the reason for the fact that the operating error is 40–45% of the total weight of the net.

With this method, a well-known application with a moderate degree of swelling is used. The degree of swelling

20 small thickeners, as well as common conditions, depend on thermodynamic couplers for non-negligible fluid loss and negligence. An increase in speed leads to a decrease in the degree of swelling, which, in turn, will significantly increase

25 material consumption. This product is not recommended for the processing of large-scale use of oil. Working in a stable environment. ρеκаχ and τ.d. Κροме τοгο. a crosslinking agent is a toxic agent. Falling of water on the surface of water, if not in contact with water, causes

30 Remedy with known effects. The contacting service provider has been exposed to severe injuries with this product. Otherwise, this may result in a risk of explosion.

Generation of oil from known sources of potential

^" ' ^s ' on, but not economically profitable, the stabilization of such products is carried out in the main combustion, or disposal. \ УΟ 96/05716 ΡСΤ / ΚШ5 / 00177

Ρasκρyτie izοbρeτeniya Β οsnοvu izοbρeτeniya ποlοzhena task sοzdaτ τa- κοy sποσοb οchisτκi ποveρχnοστi οτ neφτi and neφτeπροduκ- τοv, κοτορy would οbesπechival ποvyshennuyu eφφeκτivnοsτ 5 οchisτκi πρaκτichesκi samοπροizvοlnο without isποlzοvaniya σπetsialny ^χ dοbaBοκ σ vyσοκοy στeπenyu οchiστκi ποveρχnοστi.

In addition, the invention also provided for the task of generating and regenerating and disposing of a 10-year product.

The stated problem solves the fact that it is necessary to calculate the efficiency of the fault and the fault. inclusive of processing of dispersed material that is suitable for use with a commercially available material. On the other hand, on the other hand, 15 uses a linear method with an uninterrupted degree of swelling in an inert product, which is applied directly to an inert mineral or oreganese.

With an ultraparadise of a σ load and a contaminant of a practical instantaneous gel

20 maσσa, causes the “thickening” of the contaminant, resulting in viscosity, which may result in viscosity or viscous congestion.

The development of a viscous agent and the contamination of the contaminant and its separation of the section results in 25 independent use of industrial property. The thickening of oil and the inadequacy of the products results in the malfunctioning of them and the inadequacy of the fault in the process. Failure-free evaluation of the waste after 0: 0.3 mg / l.

For οbesπecheniya πlaνchesτi geleοbρaznοy mass non οόlοdimο isποlzοaτ ineρτny ιne vzaimοdeysτvνyushy χimichesκiι naποlniτel πlοτnοsτyu with less than πlοτ- ^"with - nοsτ οτdelyaemοy zhidκοsτi.

For the exclusion of the comparison of the highest possible limit and \ νθ 96/05716 ΡСΤ / ΚШ5 / 00177

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lightweight filler, for example, is applied to the size of the filler. Particles of the size with an average size of 5x10: 5x10 m from the telescope are waiting for the filling of the particles of the filler. that provides physical

5 unloading the filler with a filler. This product (component is an environmentally friendly product, inert to water, does not dissolve in it and does not affect its quality.

For the task to be solved, a wider range of

10th type of product: polylactyl, ethylene and polypropylene, b-tadiene and styrene, butyl, nitrile, isoprene and others are suitable for them.

Use of an example and without a filler in some cases.

15 The filler only needs to ensure reliable buoyancy with a thickened available oil and food.

The best filer is full spherical materials. for example. glass, silicate, phenolphal- maldehyde. Political, yellow or polished

20 lazy capsules with a smaller area. than the density of the separable fluid.

Otherwise, in order to reduce the cost of the competitive material and reduce its cost-effectiveness. As a rule, you can use lightweight dispersed parts.

25 iy, τaκie κaκ ποlye mineρalnye miκροsφeρy οτlοzhe- Nij of lava zοlnye miκροsφeρy of ΟΤΧΟDΟΕ ZΟLY, οbρazuyu- scheysya πρi ρabοτe τeπlοvyχ eleκτροστantsy, veρmiκuliτ, πeρliτ, ground sheluχa gρechiχi, and ρiσa dρνgie legκie, dοστuπnye and cheap maτeρialy, σποσοbnye dο-

30 Take in absorbable liquid.

Pοluchenny ποροshκοοbρazny κοmποzitsiοnny maτeρi- al (sορbenτ) ποmeschayuτ on ποveρχnοsτ οτdelyaemοy liquid κοsτi where ποlimeρ nabuχaeτ, ποglοschaya ποlnοsτyu οτde- trolled zhidκοsτ, οbρazνya πρi eτοm πρaκτichesκi mgnοven- nο sπlοshnuyu geleοbρaznuyu masσu ( "οbρabοτanny προ- dνκτ") κοτορuyu sοbiρayuτ by any known mechanical means.

The posed problem is solved also. what πρed- \ УΟ 96/05716 ΡСΤ / ΚШ5 / 00177

It is based on the process of regeneration of the processed product, while the processed product is mixed with the pressure of the liquid and the product. and προtseσσ ρegene- ρatsii προvοdyaτ in izbyτκe zhidκοgο προdνκτa.

5 Failure to regenerate is caused by the confusion of "return to food" after the payment of land, for example, in the absence of food. there is either a loss of water to the environment in which the load is negative, where there is a large amount of waste in excess.

10 of the Apartment is in compliance with such a rule, and the thickened net is returned in its original condition. Dispersed particles are removed and used for the purpose of using a commercially available or non-removable product after they are removed.

15 non-sludge composition:

It is also proposed to dispose of it, if it is necessary to mix the processed product with sand and grout for the use of

20 quality is optional.

In the case of sludge treatment, the sludge must be mixed with σ and hazardous sorbent and when disposing of the sludge.

Developed mixes can be mixed σ

25 bits for the construction of buildings and structures or to add it as a part of the additive in the manufacture of equipment.

The manufactured product can also be used as fuel.

30 It has been established that the rate of burning of “gasified” gasoline for this reason decreases by 10 times.

SUMMARY OF THE INVENTION

EXAMPLE 1. TESTING AT A CALCULATION OF BADA

35 petroleum companies were dispensed with 22 petroleum samples of various locations, gas condensate and various petroleum products.

For each sample, take a look.

ΟυЬcmυм шϊ ΜЛ ΗЗЛПΒ-ЗЮΤ ιυυ ml ΒΟдЫ, Ηα ПΟБерΧΗΟСΤЬ ννθ 96/05716 ΡСΤ / ΚШ5 / 00177

- 6 -

Quickly remove 1g of net. Then, on an empty film, a simple, competitive material is applied), noting the change in the weight indication by not paying any attention to it. Ρaε.lichnye navesκi sορbenτa HA nοsyaτsya on neφτyanνyu πlenκu and ydeρzhivayuτsya πρπ κοmnaτ- nοy τemπeρaτνρe 20 ^{^} C, πρi οχlazhdenii ^C 5 and C πρi τeρmοs- τaτiροvanii 50 ^e C. Βρemya vydeρzhκi οbρaεtsa zaviσiτ οτ individνalnyχ svοysτv neφτi or οτ τeρmοdinamichesκοgο sροdsτva πaρy ποlimeρ the distributor. The sample is inaccessible to the sample, if it doesn’t show any visual impairment and is not connected to the device, it doesn’t cause a loss of charge. After processing the proprietary non-ferrous spot on the

1 G-D of the water part of the product is an instantaneous viscous material that is easily removed with a clean part of the water. After removing it from the water inlet, the waste water was analyzed by a method that had been analyzed. Separation was carried out on the unit 0 with a plasma-ion detector and at a temperature of 200 ^e C and a temperature of a separator of 150 ^β -gas, which was connected to a gas separator of 150 ^β . _. , for the filling of the palm was used χ ο ма--ΑΜ ΑΜ-ΑΜ (φρ. 0,200 - 0,250), impregnated with 5 ЗШσοηе ΞΕ-30.

25 Testing on distilled and sea water with the addition of oil of various components with light mildly heavy loads.

Σ As a result of the σοbent, a light carrier was used (τCΟ Α9 glass magnets, σi

30 "Save '', removes, vermiculite, green microprocesses), processed by a linear method from a latent learning (random learning, I got a bit of bother and it’s inactive)

Results of tests

35 - Time for thickening the oil (min): 1 - 40;

- σаσχοд sorbent, y / y: 0.08 - 0.2;

- The residual water content is mg / L: 0 - 0.15. \ νθ 96/05716 ΡСΤ / ΚШ5 / 00177

For the sake of comparison, it must be noted that the acceptable food content in potable water is 0.3 mg / l in Russia.

EXAMPLE 2. Tests are carried out in order to clean the water from an inert product using the same method.

Activities and tests:

Distilled and mineral water;

Products: gasoline, diesel fuel, fuel oil. gas condensate, kerosene, oil, gas, t

10 May)

Sorbent: light carrier, large glass mirrors 16-101, silica “S-Sϊϊϊϊ”), equipped with a linear quick-power lamp,

15 rubber, two-ethyl hydroxyl rubber);

TEST RESULTS:

- thickening time (min): 5;

- release of sorbent y / y: 0.1;

- The residual content of the product in the water is 20 mg / l: 0 - 0.1.

EXAMPLE 3. Tests are made to clean the water in a pool of stainless steel with a size of 1.6 m χ 1.5 m, installed in a clean sky. Fill the bσσain with water σ ΡΗ - 0.8. Τemπeρaτuρa οκρuzhayuschey σρedy 2526 "C. Ηa ποveρχnοστ vοdy vylivayuτ 2.5 l legκοy malο- vyazκοy neφτi. Ηeφτyanοe πyaτnο ποd deyστviem veτρa σοπ- ρiκaσaeτσya σο στenκami baσσeyna and naliπaeτ on niχ. Pοsle οbρabοτκi sορbenτοm neφτyanοgο πyaτna ρasχοdοm πρimeρnο with 0.1 g / g egο maintains the flow of the first hour 30 after which they remove the thickened net from the passage of the water from the front of the blade.

TEST RESULTS:

Large metal conversion of base (a condition of failure with the net) is a clean, unstoppable installation of white paper.

The residual water content is 0.3 mg / l.

4. Pρimeρ Pροvοdyaτ iσπyτaniya πο οchisτκe ποveρ ^χ - nοsτi ποchvy οτ προliτοi neφτi. SECURITY \ νθ 96/05716 ΡСΤ / ΚШ5 / 00177

Pour 50 liters of light petroleum and then process the σ bent σ of 0.1–0.15 g / g. The thickened matter of hand-made mechanical components is easily removed from the soil. The practical, instantaneous thickening of oil on the surface of the soil provides for its penetration into the earth and makes it easy and convenient to remove the noise.

EXAMPLE 5. Tests are carried out to find the best base for a clean aerosol base. Sorbent - the edge of ethylene rubber.

In order to prevent the loss of core, it is possible to install a roller for cylindrical operation. replenished with a bent. A simple commercial roller serves as a prepared drum. Dust 30 litters

_Ι_ "σina and exposes its share. After 5 minutes, the thickened kerosene collects and removes. Clear the whole and clear.

Tests are conducted on the basis of the conversion of metal and non-existent tests of non-productive tests.

: ο of products.

Subject of experiments: acetone, benzene. Toluol, Geokan, Heptane, Octana.

Failure and tests:

- ρаσχοд σορbenta y / y: 0.05 - 0.08: ' ^s - - thickening time (min): 1 - 3;

- Processed by removing the thickened product σνχая and σσσ.

EXAMPLE 6. Tests are carried out on the basis of inactive water. -0'-, which does not require water with a concentration of 0.3 mg / l to 300 mg / l, pump through the ρν-channel filters. where аче The highest quality is used by the student with an underestimated degree of swelling applied from the hospital to the clinic. There was a 35-well water supply at a rate of 25 m / h. The residual oil content in the processed water did not exceed 0.1 mg / l.

Example 7. and θBθ are tested \ νθ 96/05716 ΡСΤ / ΚШ5 / 00177

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The pollution of the coastal zone of the outer basin is not clear.

With a double terrace, 50 liters are poured onto the water area near the coastal zone (beach).

5 easy mistakes. The coastal area of the place of the planned release of the waste is spotted - pebble, which is easy to spread with a good layer of sorbent. After a large bypass, there are a lot of waves on the shore, and the “thickened” net is washed away by the same waves as it is on the other side,

10 either a direct or indirect contact (together with a contact), together with a quick shift. Slows down for a day, and light particles use a commercially available material with a thickened oil float on the turn of the water. After removing the thickened oil from the rest of the water, the rest is

15 a new content of oil in the πDYA σ σ σ σ σ σ σ range of 0.02 mg / l

Thanks to the fact that the active, strong σbPenta has all kinds of services: hell. ab- and chemistries are binding. "thickening" nefti. Β τаκοм сοσ-

20 times, it doesn’t cause any pollution of the load, whether it is tied to the BOTTOM and emptied to the coast, it is either empty or running on shore.

Otherwise, the claimed σποσοοб ensures additional environmental effect. and the name σκοροστ of the genius of the “thickened” gasoline by this means is reduced 10 times.

Indication of applicability

30 The proposed invention can be found to be cleaned up in case of liquidation of accidents with the accidental water leak. on the ground, and on solid grounds for industrial accidents, and also for the purpose of calculating the negligence of the products with the following use

35 οτρabοτannοgο προduκτa πρi sτροiτelsτve avτοmοbilny ^χ dοροg or myagκοy κροli buildings and σοορuzheny.

Claims

\ νθ 96/05716 ΡСΤ / ΚШ5 / 00177-10 -ΦΟΡΜУЛΑ ИБΟБΡΕΤΕΗИЯ 1. The process of calculating the profit from the net and the non-product. inclusive processing of disperse 5 best-selling, commercially-friendly materials, I can tell you that. that, as a rule, they use a linear method of σ and an unlimited degree of swelling in a non-product. 2. The process of reversing the faults and failures of 10 products is π 1, which is different from the fact that the linear method is based on an inadequate mineral or non-solid. 3. The process of regeneration of the product, which is different. that the processed product is mixed with the original liquid 15 product in the storage compartment, in addition to this process for the generation of WATER in excess of liquid product. 4. The method of disposal of the product, which is different. that the processed product is mixed with a sand and gravel mixture and is used for the construction of an inevitable base 20 automobiles. 5. The method of disposal, which is distinguished by the fact that the purchased product is mixed with a good bitumen and the mixture is used as a by-product. 6. The method of disposal, which is characterized by the fact that the sludge 25 is mixed after mixing the waste with the original source for its use. 7. Method of disposal. It differs in that mixed products are mixed with a small bitumen and use a mixture to soften buildings and 20 σοορ constrictions. 8. The method of disposal, which is related to the fact that the purchased product is used as a supplement to the product from the product. 9. Disposal method, which is different from the fact that the 35-by-product is used as a fuel.