WO1993017582A1 - Hydrocolloidal dispersion for foodstuffs, mixture therefor and resulting foodstuff - Google Patents
Hydrocolloidal dispersion for foodstuffs, mixture therefor and resulting foodstuff Download PDFInfo
- Publication number
- WO1993017582A1 WO1993017582A1 PCT/BE1993/000012 BE9300012W WO9317582A1 WO 1993017582 A1 WO1993017582 A1 WO 1993017582A1 BE 9300012 W BE9300012 W BE 9300012W WO 9317582 A1 WO9317582 A1 WO 9317582A1
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- WO
- WIPO (PCT)
- Prior art keywords
- phase
- hydrocolloid
- dispersion
- hydrocooid
- mixture
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 85
- 239000000203 mixture Substances 0.000 title claims description 83
- 239000000416 hydrocolloid Substances 0.000 claims abstract description 63
- 108010010803 Gelatin Proteins 0.000 claims abstract description 58
- 229920000159 gelatin Polymers 0.000 claims abstract description 58
- 235000019322 gelatine Nutrition 0.000 claims abstract description 58
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 58
- 239000008273 gelatin Substances 0.000 claims abstract description 54
- 239000001814 pectin Substances 0.000 claims abstract description 22
- 229920001277 pectin Polymers 0.000 claims abstract description 22
- 235000010987 pectin Nutrition 0.000 claims abstract description 22
- 239000004033 plastic Substances 0.000 claims abstract description 21
- 229920000926 Galactomannan Polymers 0.000 claims abstract description 17
- 229920000161 Locust bean gum Polymers 0.000 claims abstract description 16
- 239000000711 locust bean gum Substances 0.000 claims abstract description 16
- 235000010420 locust bean gum Nutrition 0.000 claims abstract description 16
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims abstract description 14
- 239000000665 guar gum Substances 0.000 claims abstract description 9
- 235000010417 guar gum Nutrition 0.000 claims abstract description 9
- 239000000213 tara gum Substances 0.000 claims abstract description 3
- 235000010491 tara gum Nutrition 0.000 claims abstract description 3
- 235000013305 food Nutrition 0.000 claims description 16
- 239000000787 lecithin Substances 0.000 claims description 11
- 235000010445 lecithin Nutrition 0.000 claims description 11
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical group CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 10
- 229940067606 lecithin Drugs 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 229960002154 guar gum Drugs 0.000 claims description 8
- 229920003086 cellulose ether Polymers 0.000 claims description 7
- 108090000623 proteins and genes Proteins 0.000 claims description 6
- 102000004169 proteins and genes Human genes 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000003778 fat substitute Substances 0.000 claims description 5
- 235000013341 fat substitute Nutrition 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 4
- 239000005017 polysaccharide Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229930182830 galactose Natural products 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920000223 polyglycerol Polymers 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 abstract 1
- 241000388430 Tara Species 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000002245 particle Substances 0.000 description 15
- 235000014121 butter Nutrition 0.000 description 13
- 239000006071 cream Substances 0.000 description 12
- 235000019197 fats Nutrition 0.000 description 12
- 235000013618 yogurt Nutrition 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 11
- 235000015067 sauces Nutrition 0.000 description 11
- 235000014651 chocolate spreads Nutrition 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- 235000013336 milk Nutrition 0.000 description 8
- 239000008267 milk Substances 0.000 description 8
- 210000004080 milk Anatomy 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 235000019198 oils Nutrition 0.000 description 8
- 235000020183 skimmed milk Nutrition 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 229920002774 Maltodextrin Polymers 0.000 description 4
- 239000005913 Maltodextrin Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000013345 egg yolk Nutrition 0.000 description 4
- 210000002969 egg yolk Anatomy 0.000 description 4
- 229940035034 maltodextrin Drugs 0.000 description 4
- 235000013310 margarine Nutrition 0.000 description 4
- 239000003264 margarine Substances 0.000 description 4
- 235000010746 mayonnaise Nutrition 0.000 description 4
- 239000008268 mayonnaise Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 235000015277 pork Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 235000015243 ice cream Nutrition 0.000 description 3
- 210000004185 liver Anatomy 0.000 description 3
- 235000015250 liver sausages Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 108010011485 Aspartame Proteins 0.000 description 2
- 244000056139 Brassica cretica Species 0.000 description 2
- 235000003351 Brassica cretica Nutrition 0.000 description 2
- 235000003343 Brassica rupestris Nutrition 0.000 description 2
- 240000008886 Ceratonia siliqua Species 0.000 description 2
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 2
- 229920002245 Dextrose equivalent Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 2
- 229960003438 aspartame Drugs 0.000 description 2
- 235000010357 aspartame Nutrition 0.000 description 2
- 239000000605 aspartame Substances 0.000 description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000021185 dessert Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000010460 mustard Nutrition 0.000 description 2
- 235000014594 pastries Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 235000014438 salad dressings Nutrition 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 2
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 2
- 235000012141 vanillin Nutrition 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 239000008256 whipped cream Substances 0.000 description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- 208000010470 Ageusia Diseases 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000004283 Sodium sorbate Substances 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000019666 ageusia Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 229940072107 ascorbate Drugs 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 235000021270 cold food Nutrition 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000495 cryogel Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000021189 garnishes Nutrition 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000004213 low-fat Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 description 1
- 235000019250 sodium sorbate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
- A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
- A23G1/40—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C15/00—Butter; Butter preparations; Making thereof
- A23C15/12—Butter preparations
- A23C15/16—Butter having reduced fat content
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/12—Fermented milk preparations; Treatment using microorganisms or enzymes
- A23C9/13—Fermented milk preparations; Treatment using microorganisms or enzymes using additives
- A23C9/137—Thickening substances
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
- A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
- A23G9/34—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds characterised by carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/60—Salad dressings; Mayonnaise; Ketchup
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/238—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seeds, e.g. locust bean gum or guar gum
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/275—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of animal origin, e.g. chitin
- A23L29/281—Proteins, e.g. gelatin or collagen
- A23L29/284—Gelatin; Collagen
Definitions
- Hydrocolloid dispersion for food mixture for such dispersion and food thus obtained.
- Edible dispersions to give texture are plastic dispersions which are used in the food industry to improve the texture of food compositions.
- Such dispersions are known from document EP-A-0298561. These dispersions which can be used as a fat substitute (material used to replace the fat of a food or a part thereof and therefore to reduce the fat content of a food or a food composition) are consisting of two gelled phases, a first being dispersed in the second.
- the first phase contains at least one gelling hydrocolloid of the aggregate forming type, such as a maltodextrin of low DE (Dextrose equivalent), while the second phase contains a gelling hydrocolloid different from starch, such as gelatin.
- the continuous phase contains maltodextrin, an agent which affects the taste of the dispersion.
- plastic dispersion of gelatin and maltodextrin has a white color which can negatively influence the color of the food composition, for example chocolate spread.
- the plastic dispersion according to the invention is transparent or translucent, so that the plastic dispersion, according to this embodiment, will have no negative influence on the color of the food or the food composition .
- the particles which are dispersed or distributed in the continuous phase have a diameter which is more or less constant or identical. In other words, the particle size dispersion of the plastic dispersion according to the invention is very limited.
- the particle size dispersion can be measured by the following formula:
- the 5% -95% particle size dispersion of a preferred embodiment according to the invention is, for example, less than 1.
- the dispersion according to the invention is an edible dispersion for giving texture to a food or a food composition which comprises two phases, namely a continuous non-gelled phase and a gelled phase which is dispersed or distributed in the continuous phase to at least a temperature between 0 and 40 ° C.
- the plastic dispersion comprises at least two different hydrocolloids or hydrocooid systems (mixtures of hydrocoids), the concentration of the first hydrocolloid or hydrocooid system being sufficient to form a continuous phase which is incompatible with the second gelled phase. This is called in the literature as being a thermodynamic incompatibility resulting in a phase separation. The concentration of the first hydrocolloid or hydrocooid system is insufficient to form a continuous gelled phase.
- the concentration of the first hydrocolloid or hydrocooid system is therefore a concentration for which the continuous phase is an ungelled phase.
- the concentration must therefore be lower than the critical concentration of said first hydrocolloid or first hydrocooid system, that is to say the minimum concentration for which the hydrocolloid or hydrocooid system forms a gelled phase.
- the minimum concentration depends on various factors such as hydrocolloids, additives (sugars, salts, emulsifiers, triglycerides).
- the concentration of the first hydrocolloid or of the first hydrocooid system is a concentration for which, at at least a temperature between 5 and 20 ° C., the continuous phase is an ungelled phase in which the second phase is dispersed .
- the first hydrocolloid or hydrocooid system is a hydrocolloid which cannot be gelled or which can form a gel only at very high concentrations.
- the second hydrocolloid or hydrocooid system can form a gel, that is to say that its concentration is sufficient to form a gelled phase at at least a temperature below 40 ° C. This concentration must therefore be greater than the critical concentration. Additional information regarding the determination of the critical concentration is given in EP-A-0298561.-.
- the second phase which is dispersed in the first continuous phase essentially comprises or is essentially consisting of the second hydrocolloid or system of hydrocoids or the second hydrocolloid or system of hydrocoids is essentially present in the second phase.
- the second hydrocolloid or hydrocooid system is advantageously a protein or a mixture of proteins, preferably a gelatin or a mixture of gelatins.
- the gelatins can be gelatins of type A, of type B or a mixture of these.
- gelatin By way of gelatin, it is possible to use a gelatinizing gelatin that is cold soluble, that is to say at a temperature below 30 ° C.
- the second hydrocolloid or hydrocooid system is advantageously a mixture of gelatin (s) and pectin.
- Examples of early hydrocolloids are nonionic polysaccharides consisting essentially of galactose and mannose.
- Preferred polysaccharides are galactomannans, which correspond to the following formula:
- the first hydrocolloid is so, for example, guar gum, tara gum, locust bean gum or a mixture of these.
- the first hydrocolloid or hydrocooid system is a mixture containing galactomannan and an agent for increasing viscosity at high temperature, in particular cellulose ether.
- the first phase of the dispersion contains, predominantly, a system comprising a cold soluble galactomannan and a cellulose ether, while the second phase contains, predominantly, a system comprising a soluble gelling gelatin cold and pectin.
- the invention also relates to a mixture for producing or preparing particular dispersions according to the invention.
- This mixture contains at least two hydrocolloids at least partially dried, preferably in the form of a powder. These hydrocolloids are intended, after adding a determined quantity of water and optionally after a heating and cooling step, to form a first continuous and non-gelled phase at a temperature below 40 ° C, preferably at 20 ° C , in which a second gelled phase is dispersed or distributed.
- Said mixture contains a sufficient quantity of the first hydrocolloid or hydrocooid system to form, after addition of a determined quantity of water and optionally after a heating and cooling step, a continuous phase which, at least at a temperature below 40 ° C, is incompatible with the second phase.
- the amount of said first hydrocolloid or first hydrocooid system is an amount for which, after adding said amount of water, the continuous phase is a non-gelled phase for at least one temperature between 0 and 40 ° C, advantageously for at least one temperature between 5 and 20 ° C, in particular between 10 and 15 ° C and preferably between 5 and 20 ° vs.
- the first and second hydrocolloids or hydrocoid systems of the mixture are advantageously the hydrocolloids mentioned above.
- the mixture for preparing a dispersion according to the invention contains at least two hydrocolloids, a first hydrocolloid or a first system of hydrocoids having a critical temperature below 5 ° C., while a second hydrocolloid or a second system of hydrocoids has a critical temperature greater than 15 ° C., the weight ratio of the first hydrocolloid or first system of hydrocoloids / second hydrocolloid or second system of hydrocoids being greater than 0.1: 1, advantageously between 0, 1: 1 and 1: 1, preferably between 0.3: 1 and 1: 1.
- critical temperature is meant the temperature below which the hydrocolloid in aqueous solution at 2% by weight forms a gel.
- the mixture or dispersion according to the invention advantageously contains one or more elusives.
- the weight ratio of emulsifier / first and second hydrocolloid "or hydrocooid system is less than 1: 1.
- Preferred emulsifiers are lecithins, diacetyltartryl ester of mono-diglycerides (DATEM), ester polyglycerol and fatty acids, calcium and / or sodium stearoyl lactilate.
- a preferred mixture according to the invention comprises gelatin, galactomannan and pectin.
- the mixture contains, for example, from 50 to 80% of gelatin and from 10 to 40% of galactomannan, the remainder being pectin.
- the mixture contains from 1 to 40%, in particular from 5 to 25% of pectin relative to the weight of gelatin, galactomannan and pectin.
- the first hydrocooid system is advantageously a system which, as such, forms a continuous phase for temperatures below 40 ° C. and exhibits an increased viscosity at a temperature above 50 ° C. relative to its viscosity measured at 20 ° C.
- the first hydrocooid system can be:
- a dry mixture of gelatin (71.5%) and locust bean gum (28.5%) was mixed with water to obtain a composition containing 1.5% by weight of gelatin and 0.6 % by weight of locust bean gum. After heating the composition to 85 ° C and cooling it to 10 ° C, a dispersion was obtained which consisted of two phases, namely a first continuous non-gelled phase and a second gelled phase which was dispersed in the first phase.
- Gelatin was mainly present in the second phase, while locust bean gum was mainly present in the continuous phase.
- the diameter of the particles which were dispersed in the first phase is given in the following table.
- the particle diameter distribution was therefore very limited.
- the particle distribution factor (for 90% of these) was equal to: 18 ⁇ m - 6 ⁇ m
- Dispersions of gelatin and guar gum were prepared as follows.
- the gelatin and guar gum were mixed with cold water. After heating the mixture to 85 ° C to ensure dissolution of the gelatin in water, the mixture was cooled to 10 ° C for
- the gel strength G of the dispersions was measured using a Stevens texture measuring device.
- the viscosity of the dispersions was measured at 20 ° C for different speeds of rotation.
- a dispersion was prepared by mixing gelatin, locust bean gum, salt, lecithin and sugar with water and vinegar, by heating the mixture to 85 ° C and cooling the mixture to 15 ° C. This mixture was added to egg yolks, mustard and aromatic preparation. By means of a kitchen mixer, the mixture was thus mixed. Then the oil was gradually added and mixed.
- composition of the sauces which have been prepared is given in the following table.
- a dry mixture of 70% gelatin, 20% locust bean gum and 10% lecithin was mixed with water and milk. After heating the composition to 85 ° C and cooling it in a refrigerator, a plastic dispersion was obtained which was used as a texture agent for butter. After working the butter, the plastic dispersion was gradually incorporated into the butter.
- a buttercream was prepared with starch instead of a gelatin / locust bean / lecithin mixture.
- composition and the texture parameters measured at 20 ° C. of the butter creams are given in the following table:
- Example 13 the mixture according to the invention was used as a fat substitute (butter content of 25% compared to a butter content of 50% in Examples 12 and 14).
- the butter creams 12 and 13 had a greater plasticity than that of the cream.
- Example 14 as well as better adhesion parameters.
- butter creams # 12 and 13 were better than cream # 14.
- Butter creams # 12 and 13 were plastic, creamy and homogeneous and had a slightly white-yellowish color.
- a dry mixture of gelatin (70%), locust bean gum (20%) and lecithin (10%) in powder form, as well as salt and sodium sorbate were mixed with a quantity of water. After heating the mixture to 85 ° C, the pH of the mixture was adjusted to obtain a pH value of 4.6. Then the mixture was placed overnight in the refrigerator. This cooled mixture was then worked with butter and / or margarine. Composition and texture settings
- the spreads 15 and 16 were stored at room temperature for 7 weeks.
- Ice was prepared as follows. Dry ingredients (sugar, gelatin mixture, locust bean gum and lecithin) were dissolved in water and milk by heating the composition to 85 ° C. After cooling, fresh cream was added to this composition. The ice was then prepared in an ice cream maker and kept in a freezer.
- the following table gives the composition and properties of the prepared ice, as well as the melting properties of the prepared ice. These melting properties were measured by placing 25 g of ice on a grid and measuring the weight of melted ice after 10, 15, 30 and 60 minutes.
- ice creams were considered acceptable. However, ice # 19 was considered by tasters to be the best. The size of the ice crystals was better controlled for ice # 18 to 21.
- Chocolate spreads were prepared by mixing suerose, fructose, cocoa, milk powder, salt, starch, lecithin (powder) and / or gelatin 70% / carob gum 20% / lecithin 10% with water, by heating this mixture to 85 ° C to dissolve the ingredients, by adding melted margarine and by forming an emulsion.
- the chocolate spreads had a plastic texture.
- Chocolate spread No. 23 had a very shiny appearance, was homogeneous and had a creamy texture.
- the chocolate spread # 24 had a shiny, but noticeably irregular appearance, and a texture that was less creamy than that of the chocolate spread # 23.
- the chocolate spread n ° 24 actually had more or less the appearance and the texture of the chocolate spread n ° 22 (comparative example).
- the following table gives the composition and properties of the chocolate spreads (measured at 20 ° C).
- a dispersion which contained 2% of gelatin, 0.7% of locust bean gum and 0.5% of an emulsifier diacetyltartryl ester of mono-diglycerides (DATEM) was prepared as in Example 1.
- the dispersion had a texture plastic more creamy and more opaque than the dispersion of Example 1, bringing it closer to the appearance of a solid fat, and had a viscosity curve at 20 ° C as follows:
- a yogurt sauce was prepared as follows.
- Example 25 a plastic dispersion for substitution of fatty substances was prepared as in Example 25.
- the mixture of dry ingredients was dispersed in the mixture of wet ingredients.
- the oil was added slowly and emulsified. Part of the fat substitution dispersion was mixed with part of the emulsion.
- the yogurt salad dressing had the following viscosity curve at 5 ° C, after one week of storage in the refrigerator:
- Plastic dispersions were prepared as in Example 27 from the following dry mixtures:
- EXAMPLE 31 A whipped cream with a reduced fat content was prepared by dispersing the dry mixture of Example 27 at a rate of 10% in skimmed milk at 20 ° C., placing this dispersion overnight in the refrigerator, by mixing a part of this dispersion with a part of fresh cream with 40% fat content, adding 6% sugar and whisking until a volume expansion of 150%.
- the whipped cream had organoleptic characteristics close to the model without reduction in the fat content (undiluted fresh cream) and had excellent volume stability at room temperature and in the refrigerator.
- EXAMPLE 32. A whipped cream with a reduced fat content was prepared by dispersing the dry mixture of Example 27 at a rate of 10% in skimmed milk at 20 ° C., placing this dispersion overnight in the refrigerator, by mixing a part of this dispersion with a part of fresh cream with 40% fat content, adding 6% sugar and whisking until a volume expansion of 150%.
- the whipped cream had organoleptic characteristics close to the model without reduction in the fat content (un
- a low-fat yoghurt dessert has been prepared according to the following formulation:
- the mixture of dry ingredients was dispersed in milk at 85 ° C.
- the solution was cooled to 1 ° C for 1 hour and the plastic dispersion obtained was mixed with the yogurt.
- This dessert had the organoleptic qualities of a product having the fat content of non-skimmed milk (3.5%).
- a yogurt with less than 0.2% fat was prepared in 2 steps according to the following formulation:
- Step 1 Gelatin 2% Carob gum 0.7
- Step 2 Skim milk 88
- step 1 The dry ingredients from step 1 were dispersed in milk at 85 ° C and the solution was cooled to 10 ° C for 30 minutes.
- step 2 a lean yoghurt was prepared by dispersing the milk powder and the starter yoghurt in the milk, and incubating at 37 ° C for 6 hours.
- the final product was prepared by mixing 4 parts of the yogurt obtained in step 2 with 1 part of the plastic dispersion obtained in step l. It was very creamy, creamy and comparable to a 3.5% fat yogurt, and showed no syneresis during storage and transport.
- a virtually sugar-free and fat-free pastry cream that can go in the oven was prepared according to the following formulation:
- a 25% fat spread (minarine) was prepared according to the following formulation:
- the dry ingredients of the aqueous phase were dissolved in water at 85 ° C, the solution was cooled to 45 ° C, the water-soluble flavor was added and the pH was adjusted to 4.6 with the acid lactic.
- the emulsion was prepared by melting the fatty substances and gradually adding the aqueous phase to the fatty phase at 45 ° C., with good stirring.
- the emulsion reversed from water / oil to oil / water. It was treated in a Schroeder pilot installation comprising, in order, a high-pressure positive displacement pump, a first scraped surface heat exchanger, a stick box and a second surface heat exchanger beating.
- the oil / water emulsion reversed again to water / oil at the second exchanger.
- the production parameters were as follows:
- Emulsion temperature after the 1st exchanger 14 ° C
- Emulsion temperature after the stick box 21 ° C
- a liver pâté with reduced fat added by a factor of 4 was prepared according to the following formulation: Pork liver
- the liver, fat and lean pork were removed in the cutter at high speed. Additives and spices were added and mixed at low speed. Hot water, gelatin and guar gum were then added and mixed at low speed until perfectly homogeneous. The emulsion was cooked in a mold, in a humid oven at 100 ° C, up to 72 ° C at its core. A perfectly spreadable pâté with organoleptic characteristics close to a pâté with 40% added fat was thus obtained.
- plastic dispersion according to the invention can thus be used in foods or food compositions as a means for giving texture, means for increasing viscosity, agent thickener, fat substitute.
- the dispersion according to the invention can be used as a thickening agent for an amount of water in a cold food composition. Since the dispersion according to the invention has no unpleasant taste, such a dispersion can advantageously be used as a substitute for thickening agents such as maltodextrin, starch, etc.
- a dispersion which contain as gelled particles gelled gelatin particles, it has been observed that the spreadability properties, the taste in the mouth and the release of the aroma are improved. This seems to be the consequence of the texture, the melting properties of gelatin in the mouth and the restricted particle size distribution of the gelatin particles.
- the dispersion can be used as a fat substitute, in particular when the particles (for example gelatin particles) have melting properties which are identical to those of solid fat.
- pectin exhibits gelatin dispersion properties in an aqueous medium.
- Another object of the invention is therefore the use of pectin as a dispersing agent for gelatin. Relative to the weight of gelatin, the amount of pectin used as a gelatin dispersant is advantageously less than 60%, preferably 50%, and is advantageously greater than 5%.
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Abstract
An esculent dispersion providing a plastic texture and including two or more hydrocolloids or hydrocolloid systems. Said dispersion consists of a first phase and a second, gelled phase, with the first phase forming a continuous phase in which the second phase is dispersed, for at least one temperature of 0-40 DEG C. The first hydrocolloid or hydrocolloid system is in a sufficient concentration to form a continuous phase which is immiscible with the second phase, whereby the second phase is dispersed in the first, said concentration of the first hydrocolloid or hydrocolloid system being a concentration for which the continuous phase is an ungelled phase. For example, the first system comprises galactomannan (guar, tara or locust bean gum), and the second system comprises gelatin optionally with pectin.
Description
Dispersion hydrocolloïde pour aliment, mélange pour une telle dispersion et aliment ainsi obtenu. Hydrocolloid dispersion for food, mixture for such dispersion and food thus obtained.
Des dispersions comestibles pour donner une texture sont des dispersions plastiques qui sont utilisées dans 1'industrie alimentaire pour améliorer la texture de compositions alimentaires.Edible dispersions to give texture are plastic dispersions which are used in the food industry to improve the texture of food compositions.
On connaît de telles dispersions par le document EP-A-0298561. Ces dispersions qui peuvent être utilisées en tant que substitut de graisse (matière utilisée pour remplacer la graisse d'un aliment ou une partie de celle-ci et donc pour réduire la teneur en graisse d'un aliment ou d'une composition alimentaire) sont constituées de deux phases gélifiées, une première étant dispersée dans la seconde.Such dispersions are known from document EP-A-0298561. These dispersions which can be used as a fat substitute (material used to replace the fat of a food or a part thereof and therefore to reduce the fat content of a food or a food composition) are consisting of two gelled phases, a first being dispersed in the second.
La première phase contient au moins un hydrocolloïde gélifiant du type formateur d'aggrégats, tel qu'une maltodextrine de faible DE (Dextrose équivalent) , tandis que la deuxième phase contient un hydrocolloïde gélifiant différent de l'amidon, tel que la gélatine. Dans tous les exemples de EP-A-0298561, la phase continue contient de la maltodextrine, un agent qui affecte le goût de la dispersion.The first phase contains at least one gelling hydrocolloid of the aggregate forming type, such as a maltodextrin of low DE (Dextrose equivalent), while the second phase contains a gelling hydrocolloid different from starch, such as gelatin. In all the examples of EP-A-0298561, the continuous phase contains maltodextrin, an agent which affects the taste of the dispersion.
De plus, une telle dispersion plastique de gélatine et de maltodextrine présente une couleur blanche qui peut influencer négativement la couleur de la composition alimentaire, par exemple de pâte à tartiner au chocolat.In addition, such a plastic dispersion of gelatin and maltodextrin has a white color which can negatively influence the color of the food composition, for example chocolate spread.
Dans une forme de réalisation avantageuse, la dispersion plastique selon l'invention est transparente ou translucide, de sorte que la dispersion plastique, selon cette forme de réalisation, n'aura aucune influence négative sur la couleur de l'aliment ou de la composition alimentaire. Dans une forme de réalisation préférée de la
dispersion plastique selon l'invention, les particules qui sont dispersées ou réparties clans la phase continue ont un diamètre qui est plus ou moins constant ou identique. En d'autres mots, la dispersion granulométrique de la dispersion plastique, suivant l'invention, est très restreinte.In an advantageous embodiment, the plastic dispersion according to the invention is transparent or translucent, so that the plastic dispersion, according to this embodiment, will have no negative influence on the color of the food or the food composition . In a preferred embodiment of the plastic dispersion according to the invention, the particles which are dispersed or distributed in the continuous phase have a diameter which is more or less constant or identical. In other words, the particle size dispersion of the plastic dispersion according to the invention is very limited.
La dispersion granulométrique peut être mesurée par la formule suivante :The particle size dispersion can be measured by the following formula:
095% - 05%095% - 05%
[(095% + 05%)/2][(095% + 05%) / 2]
dans laquelle" 095% est un diamètre déterminé pour lequel 95% en poids des particules de la dispersion ont un diamètre qui est inférieur audit diamètre déterminé, et 05% est un diamètre déterminé pour lequel 5% en poids des particules ont un diamètre qui est inférieur au diamètre déterminé.in which "095% is a determined diameter for which 95% by weight of the particles of the dispersion have a diameter which is less than said determined diameter, and 05% is a determined diameter for which 5% by weight of the particles have a diameter which is less than the determined diameter.
La dispersion granulométrique 5%-95% d'une forme de réalisation préférée selon l'invention est, par exemple, inférieure à 1.The 5% -95% particle size dispersion of a preferred embodiment according to the invention is, for example, less than 1.
La dispersion selon 1'invention est une dispersion comestible pour donner de la texture à un aliment ou une composition alimentaire qui comprend deux phases, à savoir une phase continue non gélifiée et une phase gélifiée qui est dispersée ou répartie dans la phase continue à au moins une température comprise entre 0 et 40°C.The dispersion according to the invention is an edible dispersion for giving texture to a food or a food composition which comprises two phases, namely a continuous non-gelled phase and a gelled phase which is dispersed or distributed in the continuous phase to at least a temperature between 0 and 40 ° C.
La dispersion plastique comprend au moins deux hydrocolloïdes ou systèmes d'hydrocoUoïdes (mélanges d'hydrocoUoïdes) différents, la concentration du premier hydrocolloïde ou système d'hydrocoUoïdes étant suffisante pour former une phase continue qui est incompatible avec la deuxième phase gélifiée. Ceci est
appelé dans la littérature comme étant une incompatibilité thermodynamique entraînant une séparation de phases. La concentration du premier hydrocolloïde ou système d'hydrocoUoïdes est insuffisante pour former une phase continue gélifiée.The plastic dispersion comprises at least two different hydrocolloids or hydrocooid systems (mixtures of hydrocoids), the concentration of the first hydrocolloid or hydrocooid system being sufficient to form a continuous phase which is incompatible with the second gelled phase. this is called in the literature as being a thermodynamic incompatibility resulting in a phase separation. The concentration of the first hydrocolloid or hydrocooid system is insufficient to form a continuous gelled phase.
La concentration du premier hydrocolloïde ou système d'hydrocoUoïdes est donc une concentration pour laquelle la phase continue est une phase non gélifiée. La concentration doit donc être inférieure à la concentration critique dudit premier hydrocolloïde ou premier système d'hydrocoUoïdes, c'est-à-dire la concentration minimale pour laquelle l'hydrocolloïde ou système d'hydrocoUoïdes forme une phase gélifiée. La concentration minimale dépend de divers facteurs tels que hydrocolloïdes, additifs (sucres, sels, émulsifiants, triglycérides) .The concentration of the first hydrocolloid or hydrocooid system is therefore a concentration for which the continuous phase is an ungelled phase. The concentration must therefore be lower than the critical concentration of said first hydrocolloid or first hydrocooid system, that is to say the minimum concentration for which the hydrocolloid or hydrocooid system forms a gelled phase. The minimum concentration depends on various factors such as hydrocolloids, additives (sugars, salts, emulsifiers, triglycerides).
De façon avantageuse, la concentration du premier hydrocolloïde ou du premier système d'hydrocoUoïdes est une concentration pour laquelle, à au moins une température comprise entre 5 et 20°C, la phase continue est une phase non gélifiée dans laquelle la deuxième phase est dispersée.Advantageously, the concentration of the first hydrocolloid or of the first hydrocooid system is a concentration for which, at at least a temperature between 5 and 20 ° C., the continuous phase is an ungelled phase in which the second phase is dispersed .
Le premier hydrocolloïde ou système d'hydrocoUoïdes est un hydrocolloïde qui ne peut être gélifié ou qui ne peut former un gel qu'à de très hautes concentrations. Le deuxième hydrocolloïde ou système d'hydrocoUoïdes peut former un gel, c'est-à-dire que sa concentration est suffisante pour former une phase gélifiée à au moins une température inférieure à 40°C. Cette concentration doit donc être supérieure à la concentration critique. Des informations complémentaires en ce qui concerne la détermination de la concentration critique sont données dans EP-A-0298561.- .The first hydrocolloid or hydrocooid system is a hydrocolloid which cannot be gelled or which can form a gel only at very high concentrations. The second hydrocolloid or hydrocooid system can form a gel, that is to say that its concentration is sufficient to form a gelled phase at at least a temperature below 40 ° C. This concentration must therefore be greater than the critical concentration. Additional information regarding the determination of the critical concentration is given in EP-A-0298561.-.
La deuxième phase qui est dispersée dans la première phase continue comprend essentiellement ou est
essentiellement constituée du deuxième hydrocolloïde ou système d'hydrocoUoïdes ou le deuxième hydrocolloïde ou système d'hydrocoUoïdes est essentiellement présent dans la deuxième phase. Le deuxième hydrocolloïde ou système d'hydrocoUoïdes est avantageusement une protéine ou un mélange de protéines, de préférence une gélatine ou un mélange de gélatines.The second phase which is dispersed in the first continuous phase essentially comprises or is essentially consisting of the second hydrocolloid or system of hydrocoids or the second hydrocolloid or system of hydrocoids is essentially present in the second phase. The second hydrocolloid or hydrocooid system is advantageously a protein or a mixture of proteins, preferably a gelatin or a mixture of gelatins.
Les gélatines peuvent être des gélatines de type A, de type B ou un mélange de celles-ci.The gelatins can be gelatins of type A, of type B or a mixture of these.
A titre de gélatine, on pourra utiliser une gélatine gélifiante soluble à froid c'est-à-dire à une température inférieure à 30°C.By way of gelatin, it is possible to use a gelatinizing gelatin that is cold soluble, that is to say at a temperature below 30 ° C.
Le deuxième hydrocolloïde ou système d'hydrocoUoïdes est avantageusement un mélange de gélatine(s) et de pectine.The second hydrocolloid or hydrocooid system is advantageously a mixture of gelatin (s) and pectin.
Des exemples de premiers hydrocolloïdes sont des polysaccharides non ioniques constitués essentiellement de galactose et de mannose. Des polysaccharides préférés sont les galactomannanes, qui répondent à la formule suivante :Examples of early hydrocolloids are nonionic polysaccharides consisting essentially of galactose and mannose. Preferred polysaccharides are galactomannans, which correspond to the following formula:
dans laquelle m = 1 r 2 ou 3, et n est un nombre entier. Le premier hydrocolloïde est
donc, par exemple, de la gomme de guar, de la gomme de tara, de la gomme de caroube (locust bean gum) ou un mélange de celles-ci.where m = 1 r 2 or 3, and n is an integer. The first hydrocolloid is so, for example, guar gum, tara gum, locust bean gum or a mixture of these.
De façon avantageuse, le premier hydrocolloïde ou système d'hydrocoUoïdes est un mélange contenant du galactomannane et un agent pour accroître la viscosité à haute température, en particulier de l'éther de cellulose.Advantageously, the first hydrocolloid or hydrocooid system is a mixture containing galactomannan and an agent for increasing viscosity at high temperature, in particular cellulose ether.
Dans une forme de réalisation, la première phase de la dispersion contient, de manière prépondérante, un système comprenant un galactomannane soluble à froid et un éther de cellulose, tandis que la deuxième phase contient, de manière prépondérante, un système comprenant une gélatine gélifiante soluble à froid et de la pectine.In one embodiment, the first phase of the dispersion contains, predominantly, a system comprising a cold soluble galactomannan and a cellulose ether, while the second phase contains, predominantly, a system comprising a soluble gelling gelatin cold and pectin.
L'invention a également pour objet un mélange pour réaliser ou préparer des dispersions particulières suivant l'invention. Ce mélange contient au moins deux hydrocolloïdes au moins partiellement séchés, de préférence sous forme de poudre. Ces hydrocolloïdes sont destinés, après ajout d'une quantité déterminée d'eau et éventuellement après une étape de chauffage et de refroidissement, à former une première phase continue et non gélifiée à une température inférieure à 40°C, de préférence à 20°C, dans laquelle une deuxième phase gélifiée est dispersée ou répartie. Ledit mélange contient une quantité suffisante du premier hydrocolloïde ou système d'hydrocoUoïdes pour former, après ajout d'une quantité déterminée d'eau et après éventuellement une étape de chauffage et de refroidissement, une phase continue qui, au moins à une température inférieure à 40°C, est incompatible avec la deuxième phase. La quantité dudit premier hydrocolloïde ou premier système d'hydrocoUoïdes est une quantité pour laquelle, après ajout de ladite quantité d'eau, la
phase continue est une phase non gélifiée pour au moins une température comprise entre 0 et 40°C, avantageusement pour au moins une température comprise entre 5 et 20°C, en particulier entre 10 et 15°C et de préférence entre 5 et 20°C.The invention also relates to a mixture for producing or preparing particular dispersions according to the invention. This mixture contains at least two hydrocolloids at least partially dried, preferably in the form of a powder. These hydrocolloids are intended, after adding a determined quantity of water and optionally after a heating and cooling step, to form a first continuous and non-gelled phase at a temperature below 40 ° C, preferably at 20 ° C , in which a second gelled phase is dispersed or distributed. Said mixture contains a sufficient quantity of the first hydrocolloid or hydrocooid system to form, after addition of a determined quantity of water and optionally after a heating and cooling step, a continuous phase which, at least at a temperature below 40 ° C, is incompatible with the second phase. The amount of said first hydrocolloid or first hydrocooid system is an amount for which, after adding said amount of water, the continuous phase is a non-gelled phase for at least one temperature between 0 and 40 ° C, advantageously for at least one temperature between 5 and 20 ° C, in particular between 10 and 15 ° C and preferably between 5 and 20 ° vs.
Les premier et deuxième hydrocolloïdes ou systèmes d'hydrocoUoïdes du mélange sont avantageusement les hydrocolloïdes mentionnés ci-avant.The first and second hydrocolloids or hydrocoid systems of the mixture are advantageously the hydrocolloids mentioned above.
De façon avantageuse, le mélange pour préparer une dispersion suivant l'invention contient au moins deux hydrocolloïdes, un premier hydrocolloïde ou un premier système d'hydrocoUoïdes présentant une température critique inférieure à 5°C, tandis qu'un deuxième hydrocolloïde ou un deuxième système d'hydrocoUoïdes présente une température critique supérieure à 15°C, le rapport en poids premier hydrocolloïde ou premier système d'hydrocol¬ loïdes/deuxième hydrocolloïde ou deuxième système d'hydrocoUoïdes étant supérieur à 0,1:1, avantageusement compris entre 0,1:1 et 1:1, de préférence entre 0,3:1 et 1:1.Advantageously, the mixture for preparing a dispersion according to the invention contains at least two hydrocolloids, a first hydrocolloid or a first system of hydrocoids having a critical temperature below 5 ° C., while a second hydrocolloid or a second system of hydrocoids has a critical temperature greater than 15 ° C., the weight ratio of the first hydrocolloid or first system of hydrocoloids / second hydrocolloid or second system of hydrocoids being greater than 0.1: 1, advantageously between 0, 1: 1 and 1: 1, preferably between 0.3: 1 and 1: 1.
Par température critique, on entend la température en dessous de laquelle 1*hydrocolloïde en solution aqueuse à 2% en poids forme un gel. Le mélange ou la dispersion suivant 1'invention contient avantageusement un ou des é ulsifiants.By critical temperature is meant the temperature below which the hydrocolloid in aqueous solution at 2% by weight forms a gel. The mixture or dispersion according to the invention advantageously contains one or more elusives.
De façon avantageuse, le rapport en poids émulsifiant/premier et deuxième hydrocolloïdes "ou système d'hydrocoUoïdes est inférieur à 1:1. Des émulsifiants préférés sont les lécithines, l'ester de diacétyltartryl de mono-diglycérides (DATEM) , l'ester de polyglycérol et d'acides gras, le stéaroyl lactilate de calcium et/ou de sodium.Advantageously, the weight ratio of emulsifier / first and second hydrocolloid "or hydrocooid system is less than 1: 1. Preferred emulsifiers are lecithins, diacetyltartryl ester of mono-diglycerides (DATEM), ester polyglycerol and fatty acids, calcium and / or sodium stearoyl lactilate.
Un mélange préféré selon 1'invention comprend de la gélatine, du galactomannane et de la pectine. Par
rapport au poids total de gélatine, galactomannane et de pectine, le mélange contient, par exemple, de 50 à 80% de gélatine et de 10 à 40% de galactomannane, le restant étant de la pectine. De façon avantageuse, le mélange contient de 1 à 40%, en particulier de 5 à 25% de pectine par rapport au poids de gélatine, de galactomannane et de pectine.A preferred mixture according to the invention comprises gelatin, galactomannan and pectin. Through based on the total weight of gelatin, galactomannan and pectin, the mixture contains, for example, from 50 to 80% of gelatin and from 10 to 40% of galactomannan, the remainder being pectin. Advantageously, the mixture contains from 1 to 40%, in particular from 5 to 25% of pectin relative to the weight of gelatin, galactomannan and pectin.
Le premier système d'hydrocoUoïdes est avantageusement un système qui, en tant que tel, forme une phase continue pour des températures inférieures à 40°C et présente une viscosité accrue à une température supérieure a 50°C par rapport à sa viscosité mesurée à 20°C.The first hydrocooid system is advantageously a system which, as such, forms a continuous phase for temperatures below 40 ° C. and exhibits an increased viscosity at a temperature above 50 ° C. relative to its viscosity measured at 20 ° C.
A titre d'exemple, le premier système d'hydrocoUoïdes peut être :As an example, the first hydrocooid system can be:
- un galactomannane- a galactomannan
- un mélange de galactomannanes- a mixture of galactomannans
- galactomannane + éther de cellulose tandis que le deuxième système d'hydrocoUoïdes peut être :- galactomannan + cellulose ether while the second hydrocooid system can be:
- une gélatine- a gelatin
- un mélange de gélatines- a mixture of gelatins
- une gélatine gélifiante soluble à froid- a cold soluble gelatinizing gelatin
- gélatine + pectine - gélatine gélifiante soluble à froid + pectine.- gelatin + pectin - cold soluble gelling gelatin + pectin.
D'autres caractéristiques et détails de l'invention ressortiront de la description détaillée suivante dans laquelle il est fait référence à des exemples de préparation. EXEMPLE 1.-Other characteristics and details of the invention will emerge from the following detailed description in which reference is made to examples of preparation. EXAMPLE 1.-
Un mélange sec de gélatine (71,5%) et de gomme de carouîje (locust bean gum) 28,5% a été mélangé à de l'eau pour obtenir une composition contenant 1,5% en poids de gélatine et 0,6% en poids de gomme de caroube.
Après chauffage de la composition à 85°C et refroidissement de celle-ci à 10°C, une dispersion a été obtenue qui consistait en deux phases, à savoir une première phase continue non gélifiée et une deuxième phase gélifiée qui était dispersée dans la première phase.A dry mixture of gelatin (71.5%) and locust bean gum (28.5%) was mixed with water to obtain a composition containing 1.5% by weight of gelatin and 0.6 % by weight of locust bean gum. After heating the composition to 85 ° C and cooling it to 10 ° C, a dispersion was obtained which consisted of two phases, namely a first continuous non-gelled phase and a second gelled phase which was dispersed in the first phase.
La gélatine était essentiellement présente dans la deuxième phase, tandis que la gomme de caroube était essentiellement présente dans la phase continue.Gelatin was mainly present in the second phase, while locust bean gum was mainly present in the continuous phase.
Le diamètre des particules qui étaient dispersées dans la première phase est donné dans le tableau suivant.The diameter of the particles which were dispersed in the first phase is given in the following table.
La distribution du diamètre des particules était donc très limitée.The particle diameter distribution was therefore very limited.
La facteur de distribution des particules (pour 90% de celles-ci) était égal à :
18 μm - 6 μmThe particle distribution factor (for 90% of these) was equal to: 18 μm - 6 μm
2 x ≈ 12 x ≈ 1
18 μm + 6 μm18 μm + 6 μm
La dispersion ainsi obtenue avait des propriétés plastiques. EXEMPLE 2.-The dispersion thus obtained had plastic properties. EXAMPLE 2.-
Une dispersion qui contenait 2% de gélatine et 0,6% de gomme de caroube a été préparée de la manière décrite dans l'exemple 1. EXEMPLES 3 A 5.-A dispersion which contained 2% gelatin and 0.6% locust bean gum was prepared as described in Example 1. EXAMPLES 3 TO 5.-
Des dispersions de gélatine et de gomme de guar ont été préparées comme suit.Dispersions of gelatin and guar gum were prepared as follows.
La gélatine et la gomme de guar ont été mélangées à de l'eau froide. Après chauffage du mélange jusque 85°C pour assurer la dissolution de la gélatine dans l'eau, le mélange a été refroidi à 10°C pendantThe gelatin and guar gum were mixed with cold water. After heating the mixture to 85 ° C to ensure dissolution of the gelatin in water, the mixture was cooled to 10 ° C for
16 heures.16 hours.
La force de gel G des dispersions a été mesurée au moyen d'un appareil de mesure de texture StevensThe gel strength G of the dispersions was measured using a Stevens texture measuring device.
(élément cylindrique de 2,54 cm de diamètre, déplacement de l'élément dans la dispersion sur une distance de 4 mm avec une vitesse de 1 mm/s) .(cylindrical element 2.54 cm in diameter, displacement of the element in the dispersion over a distance of 4 mm with a speed of 1 mm / s).
La viscosité des dispersions a été mesurée à 20°C pour différentes vitesses de rotation.The viscosity of the dispersions was measured at 20 ° C for different speeds of rotation.
Le tableau suivant donne la force de gel G et la viscosité V des dispersions.
The following table gives the gel strength G and the viscosity V of the dispersions.
EXEMPLES 6 A 11.-EXAMPLES 6 TO 11.-
Des sauces pour salades ont été préparées comme suit.Salad dressings were prepared as follows.
Une dispersion a été préparée par mélange de gélatine, gomme de caroube, sel, lecithine et sucre avec de l'eau et du vinaigre, par chauffage du mélange à 85°C et par refroidissement du mélange à 15°C. Ce mélange a été ajouté à des jaunes d'oeufs, moutarde et préparation aromatique. Au moyen d'un mixer de cuisine, le mélange a été ainsi mixé. Ensuite, l'huile a été progressivement ajoutée et mélangée.A dispersion was prepared by mixing gelatin, locust bean gum, salt, lecithin and sugar with water and vinegar, by heating the mixture to 85 ° C and cooling the mixture to 15 ° C. This mixture was added to egg yolks, mustard and aromatic preparation. By means of a kitchen mixer, the mixture was thus mixed. Then the oil was gradually added and mixed.
La composition des sauces qui ont été préparées est donnée dans le tableau suivant.
The composition of the sauces which have been prepared is given in the following table.
La teneur en graisse des sauces 6 et 7 n'avait pas été abaissée. Pour ces sauces, la dispersion gélatine/gomme de caroube/lecithine a été utilisée exclusivement en tant que moyen pour donner de la texture.The fat content of sauces 6 and 7 had not been lowered. For these sauces, the gelatin / locust bean / lecithin dispersion was used exclusively as a means to give texture.
Aucune transformation dans une forme de gel des sauces 6 à 11 n'a été constatée après le placement des sauces dans un réfrigérateur (5°C) pendant une durée de 1 à 4 semaines. Les sauces ont conservé une texture crémeuse et grasse et un aspect brillant et ont été considérées par des goûteurs pendant cette période comme étant une mayonnaise avec un goût attrayant.No transformation into a gel form of sauces 6 to 11 was observed after placing the sauces in a refrigerator (5 ° C) for a period of 1 to 4 weeks. The sauces retained a creamy and oily texture and a shiny appearance and were considered by tasters during this period to be mayonnaise with an attractive taste.
La viscosité de ces sauces, ainsi que d'une mayonnaise normale avec une teneur en huile de 80% a été mesurée à 20°C. Des paramètres de la texture de ces
sauces et d'une mayonnaise normale ont également été mesurés à 20°C au moyen d'un appareil de mesure de texture Stevens (élément conique avec une inclinaison de 60°, déplacement de 20 mm dans la sauce avec une vitesse de 1 mm/s) .
The viscosity of these sauces, as well as normal mayonnaise with an oil content of 80% was measured at 20 ° C. Texture settings of these sauces and normal mayonnaise were also measured at 20 ° C using a Stevens texture measuring device (conical element with an inclination of 60 °, displacement of 20 mm in the sauce with a speed of 1 mm / s).
* d étration + éner ie d'adhésion
* d erration + energy of adhesion
Ce tableau montre qu'au moyen d'un dosage correct, il est possible d'obtenir des produits qui présentaient différentes solidités ou rigidités, dont, entre autres, la solidité ou rigidité d'une mayonnaise normale. La teneur en graisse des sauces peut être fortement réduite grâce à l'utilisation d'une dispersion suivant l'invention. En particulier, cette teneur en graisse peut être égale à 0. EXEMPLES 12 A 14.- Des crèmes au beurre ont été préparées comme suit.This table shows that by means of a correct dosage, it is possible to obtain products which had different solidities or rigidities, including, among others, the solidity or rigidity of a normal mayonnaise. The fat content of sauces can be greatly reduced by using a dispersion according to the invention. In particular, this fat content can be equal to 0. EXAMPLES 12 TO 14.- Butter creams were prepared as follows.
Un mélange sec de gélatine 70%, gomme de caroube 20% et lecithine 10% a été mélangé à de l'eau et du lait. Après chauffage de la composition à 85°C et refroidissement de celle-ci dans un réfrigérateur, on a obtenu une dispersion plastique qui a été utilisée en tant qu'agent de texture pour du beurre. Après avoir travaillé le beurre, la dispersion plastique a été progessivement incorporée dans le beurre. A titre d'exemple comparatif, on a préparé une crème au beurre avec de l'amidon au lieu d'un mélange gélatine/gomme de caroube/lecithine.A dry mixture of 70% gelatin, 20% locust bean gum and 10% lecithin was mixed with water and milk. After heating the composition to 85 ° C and cooling it in a refrigerator, a plastic dispersion was obtained which was used as a texture agent for butter. After working the butter, the plastic dispersion was gradually incorporated into the butter. As a comparative example, a buttercream was prepared with starch instead of a gelatin / locust bean / lecithin mixture.
La composition et les paramètres de texture mesurés à 20°C des crèmes au beurre sont donnés dans le tableau suivant :
The composition and the texture parameters measured at 20 ° C. of the butter creams are given in the following table:
Dans 1'exemple 13, le mélange selon 1'invention a été utilisé en tant que substitut de graisse (teneur en beurre de 25% par rapport à une teneur en beurre de 50% dans les exemples 12 et 14) .In Example 13, the mixture according to the invention was used as a fat substitute (butter content of 25% compared to a butter content of 50% in Examples 12 and 14).
Les crèmes au beurre 12 et 13 avaient une plasticité supérieure à celle de la crème de
l'exemple 14, ainsi que de meilleurs paramètres d'adhésion.The butter creams 12 and 13 had a greater plasticity than that of the cream. Example 14, as well as better adhesion parameters.
En ce qui concerne l'homogénéité, la couleur et le goût, les crèmes au beurre n° 12 et 13 étaient meilleures que la crème n° 14. Les crèmes au beurre n° 12 et 13 étaient plastiques, crémeuses et homogènes et avaient une couleur légèrement blanc-jaunâtre. EXEMPLES 15 ET 16.-In terms of consistency, color and taste, butter creams # 12 and 13 were better than cream # 14. Butter creams # 12 and 13 were plastic, creamy and homogeneous and had a slightly white-yellowish color. EXAMPLES 15 AND 16.-
Des pâtes à tartiner ont été préparées comme suit.Spreads were prepared as follows.
Un mélange sec de gélatine (70%) , gomme de caroube (20%) et lecithine (10%) sous forme de poudre, ainsi que du sel et du sorbate de sodium ont été mélangés à une quantité d'eau. Après chauffage du mélange à 85°C, le pH du mélange a été ajusté pour obtenir une valeur de pH de 4,6. Ensuite, le mélange a été placé pendant une nuit dans le réfrigérateur. Ce mélange refroidi a ensuite été travaillé avec du beurre et/ou de la margarine. La composition et les paramètres de textureA dry mixture of gelatin (70%), locust bean gum (20%) and lecithin (10%) in powder form, as well as salt and sodium sorbate were mixed with a quantity of water. After heating the mixture to 85 ° C, the pH of the mixture was adjusted to obtain a pH value of 4.6. Then the mixture was placed overnight in the refrigerator. This cooled mixture was then worked with butter and / or margarine. Composition and texture settings
(mesurés à 20°C) des pâtes à tartiner sont donnés dans le tableau suivant.
(measured at 20 ° C) spreads are given in the following table.
Dans ce tableau, il ressort que la pâte à tartiner n° 16 est identique au produit du commerceIn this table, it appears that the spread No. 16 is identical to the commercial product
(minarine) en ce qui concerne les propriétés de texture, tandis que la pâte à tartiner n° 15 était plus solide que ledit produit du marché.(minarine) as regards the texture properties, while the spread No. 15 was more solid than the said product on the market.
Les pâtes à tartiner n° 15 et 16 ont été conservées à température ambiante pendant 7 semaines.The spreads 15 and 16 were stored at room temperature for 7 weeks.
Après cette période, les pâtes à tartiner avaient toujours conservé leurs bonnes propriétés. Le mélange
gélatine/gomme de caroube/lecithine n'avait pas d'influence négative sur le goût. Seule une légère diminution du goût de beurre ou de margarine était perceptible pour les pâtes à tartiner n° 15 et 16. Ceci était la conséquence du fait que les pâtes à tartiner n° 15 et 16 ne contiennent qu'une faible quantité de beurre ou de margarine. Cette faible perte de goût peut aisément être solutionnée par addition d'une faible quantité d'une composition aromatique. EXEMPLES 17 A 21.-After this period, the spreads had always retained their good properties. The mixture gelatin / locust bean gum / lecithin had no negative influence on taste. Only a slight decrease in the taste of butter or margarine was noticeable for spreads 15 and 16. This was the consequence of the fact that spreads 15 and 16 contain only a small amount of butter or of margarine. This low loss of taste can easily be resolved by adding a small amount of an aromatic composition. EXAMPLES 17 TO 21.-
De la glace a été préparée comme suit. Des ingrédients secs (sucre, mélange gélatine, gomme de caroube et lecithine) ont été dissous dans de l'eau et du lait par chauffage de la composition à 85°C. Après refroidissement, de la crème fraîche a été ajoutée à cette composition. La glace a ensuite été préparée dans une sorbetière et conservée dans un congélateur.Ice was prepared as follows. Dry ingredients (sugar, gelatin mixture, locust bean gum and lecithin) were dissolved in water and milk by heating the composition to 85 ° C. After cooling, fresh cream was added to this composition. The ice was then prepared in an ice cream maker and kept in a freezer.
Le tableau suivant donne la composition et les propriétés de la glace préparée, ainsi que les propriétés de fusion de la glace préparée. Ces propriétés de fusion ont été mesurées en plaçant 25 g de glace sur une grille et en mesurant le poids de glace fondue après 10, 15, 30 et 60 minutes.
The following table gives the composition and properties of the prepared ice, as well as the melting properties of the prepared ice. These melting properties were measured by placing 25 g of ice on a grid and measuring the weight of melted ice after 10, 15, 30 and 60 minutes.
En ce qui concerne le goût, toutes les glaces étaient considérées comme acceptables. Toutefois, la glace n° 19 était considérée par les goûteurs comme la meilleure. La grandeur des cristaux de glace était mieux contrôlée pour les glaces n° 18 à 21.Regarding taste, all ice creams were considered acceptable. However, ice # 19 was considered by tasters to be the best. The size of the ice crystals was better controlled for ice # 18 to 21.
La fonte des glaces n° 19 et 21 était très bien contrôlée.Ice melt # 19 and # 21 was very well controlled.
Dans les glaces n° 20 et 21, plus de 70% de la matière grasse ont été remplacés sans influence négative
sur le goût ou sur le caractère gras de la glace. EXEMPLES 22 A 24.-In ice creams 20 and 21, more than 70% of the fat was replaced without negative influence on the taste or the fatty character of the ice. EXAMPLES 22 TO 24.-
Des pâtes à tartiner au chocolat ont été préparées par mélange de suerose, fructose, cacao, lait en poudre, sel, amidon, lecithine (en poudre) et/ou mélange gélatine 70%/gomme de caroube 20%/lécithine 10% avec de l'eau, par chauffage de ce mélange jusqu'à 85°C pour dissoudre les ingrédients, par ajout de margarine fondue et par formation d'une émulsion. Les pâtes à tartiner au chocolat avaient une texture plastique. La pâte à tartiner au chocolat n° 23 avait un aspect très brillant, était homogène et avait une texture crémeuse. La pâte à tartiner au chocolat n° 24 avait un aspect brillant, mais sensiblement irrégulier, et une texture qui était moins crémeuse que celle de la pâte à tartiner au chocolat n° 23.Chocolate spreads were prepared by mixing suerose, fructose, cocoa, milk powder, salt, starch, lecithin (powder) and / or gelatin 70% / carob gum 20% / lecithin 10% with water, by heating this mixture to 85 ° C to dissolve the ingredients, by adding melted margarine and by forming an emulsion. The chocolate spreads had a plastic texture. Chocolate spread No. 23 had a very shiny appearance, was homogeneous and had a creamy texture. The chocolate spread # 24 had a shiny, but noticeably irregular appearance, and a texture that was less creamy than that of the chocolate spread # 23.
La pâte à tartiner au chocolat n° 24 avait en réalité plus ou moins l'aspect et la texture de la pâte à tartiner au chocolat n° 22 (exemple comparatif) . Le tableau suivant donne la composition et les propriétés des pâtes à tartiner au chocolat (mesurées à 20°C) .
The chocolate spread n ° 24 actually had more or less the appearance and the texture of the chocolate spread n ° 22 (comparative example). The following table gives the composition and properties of the chocolate spreads (measured at 20 ° C).
Une dispersion qui contenait 2% de gélatine, 0,7% de gomme de caroube et 0,5% d'un émulsifiant ester diacétyltartryl de mono-diglycérides (DATEM) a été préparée comme dans l'exemple 1. La dispersion avait une texture plastique plus crémeuse et plus d'opacité que la dispersion de l'exemple 1, la rapprochant plus de l'aspect d'une graisse solide, et présentait une courbe de viscosité à 20°C comme suit :A dispersion which contained 2% of gelatin, 0.7% of locust bean gum and 0.5% of an emulsifier diacetyltartryl ester of mono-diglycerides (DATEM) was prepared as in Example 1. The dispersion had a texture plastic more creamy and more opaque than the dispersion of Example 1, bringing it closer to the appearance of a solid fat, and had a viscosity curve at 20 ° C as follows:
Une sauce au yoghourt a été préparée de la façon suivante.A yogurt sauce was prepared as follows.
D'une part, une dispersion plastique pour substitution de corps gras a été préparée comme dans l'exemple 25.On the one hand, a plastic dispersion for substitution of fatty substances was prepared as in Example 25.
D'autre part, une émulsion huile/eau a été préparée selon la formulation suivante :
On the other hand, an oil / water emulsion was prepared according to the following formulation:
Huile de soya 20% Gomme xanthane 0,06Soybean oil 20% Xanthan gum 0.06
Sucre 6Sugar 6
Sel 2 Sorbate de potassium 0,2Salt 2 Potassium sorbate 0.2
Jaune d'oeuf frais 4Fresh egg yolk 4
Moutarde 4Mustard 4
Vinaigre (10%) 6Vinegar (10%) 6
Préparation aromatique 2 Yoghourt de lait écrémé 55,74Aromatic preparation 2 Skim milk yogurt 55.74
Le mélange des ingrédients secs a été dispersé dans le mélange des ingrédients humides. L'huile a été rajoutée lentement et émulsionnée. Une part de la dispersion pour substitution de corps gras a été mélangée avec une part de l'émulsion. La sauce salade au yoghourt avait la courbe de viscosité à 5°C suivante, après une semaine de stockage au réfrigérateur :The mixture of dry ingredients was dispersed in the mixture of wet ingredients. The oil was added slowly and emulsified. Part of the fat substitution dispersion was mixed with part of the emulsion. The yogurt salad dressing had the following viscosity curve at 5 ° C, after one week of storage in the refrigerator:
Taux de cisaillement fl/s) Viscosité (Pa.s) 2,25 16,7Shear rate fl / s) Viscosity (Pa.s) 2.25 16.7
4,5 9,814.5 9.81
9 6,63 18 3,879 6.63 18 3.87
45 1,9845 1.98
90 1,1490 1.14
180 0,685180 0.685
EXEMPLE 27.-EXAMPLE 27.-
Un mélange sec de 15% de gélatine gélifianteA dry mixture of 15% gelling gelatin
® soluble à froid (Cryogel ) , 6% de gomme de guar, 4% de pectine et 75% de sucre a été dispersé à raison de 15% dans de l'eau à 20°C. La solution a été mise une nuit au réfrigérateur. Une dispersion plastique a été obtenue.
EXEMPLES 28 A 30.-® cold soluble (Cryogel), 6% guar gum, 4% pectin and 75% sugar was dispersed at 15% in water at 20 ° C. The solution was put in the refrigerator overnight. A plastic dispersion was obtained. EXAMPLES 28 TO 30.-
Des dispersions plastiques ont été préparées comme dans l'exemple 27 à partir des mélanges secs suivants :Plastic dispersions were prepared as in Example 27 from the following dry mixtures:
EXEMPLE 31.- Une crème chantilly à taux de matières grasses réduit a été préparée en dispersant le mélange sec de l'exemple 27 à raison de 10% dans du lait écrémé à 20°C, en plaçant cette dispersion pendant une nuit au réfrigérateur, en mélangeant une part de cette dispersion avec une part de crème fraîche à 40% de matières grasses, en rajoutant 6% de sucre et en fouettant jusqu'à une expansion de volume de 150%. La crème chantilly avait des caractéristiques organoleptiques proches du modèle sans réduction du taux de matières grasses (crème fraîche non diluée) et présentait une excellente stabilité de volume à température ambiante et au réfrigérateur.
EXEMPLE 32 . -EXAMPLE 31.- A whipped cream with a reduced fat content was prepared by dispersing the dry mixture of Example 27 at a rate of 10% in skimmed milk at 20 ° C., placing this dispersion overnight in the refrigerator, by mixing a part of this dispersion with a part of fresh cream with 40% fat content, adding 6% sugar and whisking until a volume expansion of 150%. The whipped cream had organoleptic characteristics close to the model without reduction in the fat content (undiluted fresh cream) and had excellent volume stability at room temperature and in the refrigerator. EXAMPLE 32. -
Un dessert allégé à base de yoghourt a été préparé selon la formulation suivante :A low-fat yoghurt dessert has been prepared according to the following formulation:
Gélatine 1%1% gelatin
Gomme de caroube 0,4Carob gum 0.4
Emulsifiant DATEM 0,2 Aspartame 0,05Emulsifier DATEM 0.2 Aspartame 0.05
Colorant jaune d'oeuf 0,005 Vanilline 0,1Egg yolk color 0.005 Vanillin 0.1
Lait écrémé 48,245Skim milk 48,245
Yoghourt maigre 50Lean yogurt 50
Le mélange des ingrédients secs a été dispersé dans le lait à 85°C. La solution a été refroidie à lθ°C pendant 1 heure et la dispersion plastique obtenue a été mélangée avec le yoghourt. Ce dessert avait les qualités organoleptiques d'un produit ayant la teneur en matières grasses du lait non écrémé (3,5%).The mixture of dry ingredients was dispersed in milk at 85 ° C. The solution was cooled to 1 ° C for 1 hour and the plastic dispersion obtained was mixed with the yogurt. This dessert had the organoleptic qualities of a product having the fat content of non-skimmed milk (3.5%).
-E_-_X-_--E---M----P---L----E--___3•_«3-___.----— ^ -E _-_ X -_-- E --- M ---- P --- L ---- E --___ 3 • _ "3 -___.----— ^
Un yoghourt à moins de 0,2% de matières grasses a été préparé en 2 étapes selon la formulation suivante :A yogurt with less than 0.2% fat was prepared in 2 steps according to the following formulation:
Etape 1 : Gélatine 2% Gomme de caroube 0,7Step 1: Gelatin 2% Carob gum 0.7
Lait écrémé 97,3Skim milk 97.3
100100
Etape 2 : Lait écrémé 88Step 2: Skim milk 88
Poudre de lait écrémé 2Skim milk powder 2
Yoghourt maigre (starter) 10Lean yogurt (starter) 10
100
Les ingrédients secs de l'étape 1 ont été dispersés dans le lait à 85°C et la solution a été refroidie à 10°C pendant 30 minutes. Lors de l'étape 2, un yoghourt maigre a été préparé en dispersant dans le lait la poudre de lait et le yoghourt starter, et en incubant à 37°C pendant 6 heures. Le produit définitif a été préparé en mélangeant 4 parts du yoghourt obtenu dans l'étape 2 avec 1 part de la dispersion plastique obtenue dans l'étape l. Il était très onctueux, crémeux et comparable à un yoghourt à 3,5% de matières grasses, et ne présentait pas de synérèse au stockage et au transport. EXEMPLE 34.-100 The dry ingredients from step 1 were dispersed in milk at 85 ° C and the solution was cooled to 10 ° C for 30 minutes. In step 2, a lean yoghurt was prepared by dispersing the milk powder and the starter yoghurt in the milk, and incubating at 37 ° C for 6 hours. The final product was prepared by mixing 4 parts of the yogurt obtained in step 2 with 1 part of the plastic dispersion obtained in step l. It was very creamy, creamy and comparable to a 3.5% fat yogurt, and showed no syneresis during storage and transport. EXAMPLE 34.-
Une crème pâtissière virtuellement sans sucre et sans matières grasses et pouvant aller au four a été préparée selon la formulation suivante :A virtually sugar-free and fat-free pastry cream that can go in the oven was prepared according to the following formulation:
Gélatine gélifiante soluble à froid 1,75%Cold soluble gelatinizing gelatin 1.75%
Gomme de guar 0,7 Pectine 0,4Guar gum 0.7 Pectin 0.4
Méthylcellulose 0,4Methylcellulose 0.4
Aspartame 0,1Aspartame 0.1
Colorant jaune d'oeuf 0,01Egg yolk dye 0.01
Vanilline 0,1 Lait écrémé 96,54Vanillin 0.1 Skim milk 96.54
Le mélange des ingrédients secs a été dispersé dans le lait à 20°C pendant 15 minutes et la dispersion a été placée au frigo pendant 30 minutes. La crème pâtissière obtenue a été utilisée comme garniture d'une pâtisserie allant au four. Elle a conservé assez de viscosité à la température du four pour ne pas détremper la pâte, et a conservé ses caractéristiques organoleptiques après refroidissement, à savoir une texture crémeuse et une fusion en bouche.
EXEMPLE 35 . -The mixture of dry ingredients was dispersed in milk at 20 ° C for 15 minutes and the dispersion was placed in the fridge for 30 minutes. The resulting pastry cream was used as a garnish for baking in the oven. It retained enough viscosity at oven temperature not to soak the dough, and retained its organoleptic characteristics after cooling, namely a creamy texture and a fusion on the palate. EXAMPLE 35. -
Une pâte à tartiner (minarine) à 25% de matières grasses a été préparée selon la formulation suivante :A 25% fat spread (minarine) was prepared according to the following formulation:
Acide lactique pour ajuster le pH à 4,6Lactic acid to adjust the pH to 4.6
Les ingrédients secs de la phase aqueuse ont été dissous dans l'eau à 85°C, la solution a été refroidie à 45°C, l'arôme hydrosoluble a été ajouté et le pH a été ajusté à 4,6 avec l'acide lactique.The dry ingredients of the aqueous phase were dissolved in water at 85 ° C, the solution was cooled to 45 ° C, the water-soluble flavor was added and the pH was adjusted to 4.6 with the acid lactic.
L'émulsion a été préparée en fondant les corps gras et en ajoutant progressivement la phase aqueuse à la phase grasse à 45°C, sous bonne agitation. L'émulsion s'inversa de eau/huile à huile/eau. Elle a été traitée dans une installation pilote Schroeder comprenant, dans l'ordre, une pompe volumétrique à haute pression, un premier échangeur de chaleur à surface raclée, une boîte à bâtons et un deuxième échangeur de chaleur à surface
raclée. L'émulsion huile/eau s'inversa de nouveau à eau/huile au niveau du deuxième échangeur. Les paramètres de production étaient les suivants :The emulsion was prepared by melting the fatty substances and gradually adding the aqueous phase to the fatty phase at 45 ° C., with good stirring. The emulsion reversed from water / oil to oil / water. It was treated in a Schroeder pilot installation comprising, in order, a high-pressure positive displacement pump, a first scraped surface heat exchanger, a stick box and a second surface heat exchanger beating. The oil / water emulsion reversed again to water / oil at the second exchanger. The production parameters were as follows:
Température émulsion chaude 45°CHot emulsion temperature 45 ° C
Température émulsion après le 1er échangeur 14°C Température émulsion après la boîte à bâtons 21°CEmulsion temperature after the 1st exchanger 14 ° C Emulsion temperature after the stick box 21 ° C
Température émulsion après le 2ème échangeur 11°CEmulsion temperature after the 2nd exchanger 11 ° C
Vitesse du 1er échangeur 750 tr/minSpeed of the 1st heat exchanger 750 rpm
Vitesse de la boîte à bâtons 800 tr/min Vitesse du 2ème échangeur 800 tr/minStick box speed 800 rpm 2nd heat exchanger speed 800 rpm
Débit 85 kg/hFlow rate 85 kg / h
Un excellent produit a été obtenu offrant une bonne texture et tartinabilité et un très bon profil de fusion en bouche. Les paramètres de texture tels que mesurés suivant la méthode des exemples 6 à 11 étaient les suivants :An excellent product was obtained offering a good texture and spreadability and a very good fusion profile in the mouth. The texture parameters as measured according to the method of Examples 6 to 11 were as follows:
Force de pénétration 446 gPenetration force 446 g
Energie de pénétration 334 g.cmPenetration energy 334 g.cm
Force d'adhésion 133 gAdhesion strength 133 g
Distance d'adhésion 1,23 cm Energie d'adhésion 106 g.cmAdhesion distance 1.23 cm Adhesion energy 106 g.cm
Indice de tartinabilité 2,27Spreadability index 2.27
EXEMPLE 36.-EXAMPLE 36.-
Un pâté de foie avec réduction du gras ajouté d'un facteur 4 a été préparé selon la formulation suivante :
Foie de porcA liver pâté with reduced fat added by a factor of 4 was prepared according to the following formulation: Pork liver
Gras de porcPork fat
Viande maigre de porcLean pork
Sel nitrité GélatineGelatin nitrite salt
Gomme de guarGuar gum
Protéine de bléWheat protein
Caséinate de sodiumSodium caseinate
Amidon de pomme de terre DextroseDextrose potato starch
Acide ascorbiqueAscorbic acid
AscorbateAscorbate
Acide citriqueCitric acid
Tripolyphosphate Protéine de soya hydrolyséeTripolyphosphate Hydrolyzed soy protein
GlutamateGlutamate
Epices et arômesSpices and aromas
Le foie, le gras et le maigre de porc ont été é ulsionnés dans le cutter à haute vitesse. Les additifs et les épices ont été ajoutés et mélangés à vitesse lente. L'eau chaude, la gélatine et la gomme de guar ont alors été ajoutés et mélangés à vitesse lente jusqu'à homogénéité parfaite. L'émulsion a été cuite dans un moule, dans un four humide à 100°C, jusqu'à 72°C à coeur. Un pâté parfaitement tartinable et ayant des caractéristiques organoleptiques proches d'un pâté à 40% de gras ajouté a ainsi été obtenu.The liver, fat and lean pork were removed in the cutter at high speed. Additives and spices were added and mixed at low speed. Hot water, gelatin and guar gum were then added and mixed at low speed until perfectly homogeneous. The emulsion was cooked in a mold, in a humid oven at 100 ° C, up to 72 ° C at its core. A perfectly spreadable pâté with organoleptic characteristics close to a pâté with 40% added fat was thus obtained.
La dispersion plastique suivant l'invention peut ainsi être utilisée dans des aliments ou compositions alimentaires en tant que moyen pour donner de la texture, moyen pour accroître la viscosité, agent
d'épaississement, substitut de graisse.The plastic dispersion according to the invention can thus be used in foods or food compositions as a means for giving texture, means for increasing viscosity, agent thickener, fat substitute.
Par exemple, la dispersion selon l'invention peut être utilisée en tant qu'agent d'épaississement pour une quantité d'eau d'une composition alimentaire froide. Etant donné que la dispersion selon l'invention n'a aucun goût désagréable, une telle dispersion peut avantageusement être utilisée en tant que substitut d'agents d'épaississement tels que maltodextrine, amidon, ... Pour les dispersions suivant l'invention qui contiennent en tant que particules gélifiées des particules de gélatine gélifiée, on a remarqué que les propriétés de tartina'bilité, le goût dans la bouche et la libération de l'arôme sont améliorés. Ceci semble être la conséquence de la texture, des propriétés de fusion de la gélatine dans la bouche et de la distribution granulométrique restreinte des particules de gélatine.For example, the dispersion according to the invention can be used as a thickening agent for an amount of water in a cold food composition. Since the dispersion according to the invention has no unpleasant taste, such a dispersion can advantageously be used as a substitute for thickening agents such as maltodextrin, starch, etc. For the dispersions according to the invention which contain as gelled particles gelled gelatin particles, it has been observed that the spreadability properties, the taste in the mouth and the release of the aroma are improved. This seems to be the consequence of the texture, the melting properties of gelatin in the mouth and the restricted particle size distribution of the gelatin particles.
Etant donné la texture, la plasticité et les propriétés de tartinabilité de la dispersion suivant l'invention, la dispersion peut être utilisée en tant que substitut de graisse, en particulier lorsque les particules (par exemple particules de gélatine) ont des propriétés de fusion qui sont identiques à celles de la graisse solide.Given the texture, plasticity and spreadability properties of the dispersion according to the invention, the dispersion can be used as a fat substitute, in particular when the particles (for example gelatin particles) have melting properties which are identical to those of solid fat.
On a également remarqué que la pectine présentait des propriétés de dispersion de la gélatine dans un milieu aqueux. Un autre objet de l'invention est donc l'utilisation de la pectine en tant qu'agent de dispersion pour la gélatine. Par rapport au poids de gélatine, la quantité de pectine utilisée en tant que dispersant de la gélatine est avantageusement inférieure à 60%, de préférence à 50%, et est avantageusement supérieure à 5%.
It has also been noted that pectin exhibits gelatin dispersion properties in an aqueous medium. Another object of the invention is therefore the use of pectin as a dispersing agent for gelatin. Relative to the weight of gelatin, the amount of pectin used as a gelatin dispersant is advantageously less than 60%, preferably 50%, and is advantageously greater than 5%.
Claims
1.- Dispersion comestible pour donner une texture plastique comprenant au moins deux hydrocolloïdes ou systèmes d'hydrocoUoïdes, ladite dispersion étant constituée d'une première phase et d'une deuxième phase gélifiée, la première phase formant une phase continue dans laquelle la deuxième phase est dispersée, pour au moins une température comprise entre 0 et 40°C, caractérisée en ce que la concentration en premier hydrocolloïde ou premier système d'hydrocoUoïdes est suffisante pour former une phase continue qui n'est pas miscible avec la deuxième phase, de telle sorte que la deuxième phase est dispersée dans la première phase, ladite concentration du premier hydrocolloïde ou du premier système d'hydrocoUoïdes étant une concentration pour laquelle la phase continue est une phase non gélifiée.1.- Edible dispersion to give a plastic texture comprising at least two hydrocolloids or hydrocooid systems, said dispersion consisting of a first phase and a second gelled phase, the first phase forming a continuous phase in which the second phase is dispersed, for at least a temperature between 0 and 40 ° C, characterized in that the concentration of first hydrocolloid or first hydrocooid system is sufficient to form a continuous phase which is not miscible with the second phase, such that the second phase is dispersed in the first phase, said concentration of the first hydrocolloid or of the first hydrocooid system being a concentration for which the continuous phase is an ungelled phase.
2.- Dispersion suivant la revendication 1, caractérisée en ce que la concentration du premier hydrocolloïde ou du premier système d'hydrocoUoïdes est une concentration pour laquelle, à au moins une température comprise entre 5 et 20°C, la phase continue est une phase non gélifiée dans laquelle la deuxième phase est dispersée.2. Dispersion according to Claim 1, characterized in that the concentration of the first hydrocolloid or of the first hydrocooid system is a concentration for which, at at least a temperature between 5 and 20 ° C, the continuous phase is a phase ungelled in which the second phase is dispersed.
3.- Dispersion suivant la revendication 2, caractérisée en ce que la concentration du premier hydrocolloïde ou du premier système d'hydrocoUoïdes est une concentration pour laquelle, au moins entre 10 et 15°C, la phase continue est une phase non gélifiée dans laquelle la deuxième phase est dispersée.3. Dispersion according to claim 2, characterized in that the concentration of the first hydrocolloid or of the first hydrocoUoid system is a concentration for which, at least between 10 and 15 ° C, the continuous phase is an ungelled phase in which the second phase is dispersed.
4.- Dispersion suivant l'une quelconque des revendications 1 à 3, caractérisée en ce que la deuxième phase comprend le deuxième hydrocolloïde ou système d'hydrocoUoïdes, la concentration duquel étant suffisante pour former une phase gélifiée.4.- Dispersion according to any one of claims 1 to 3, characterized in that the second phase comprises the second hydrocolloid or hydrocoUoid system, the concentration of which being sufficient to form a gelled phase.
5.- Dispersion suivant la revendication 4, caractérisée en ce que le deuxième hydrocolloïde ou le deuxième système d'hydrocoUoïdes est une protéine. 5. Dispersion according to claim 4, characterized in that the second hydrocolloid or the second hydrocooid system is a protein.
6.- Dispersion suivant la revendication 5, caractérisée en ce que la protéine est une gélatine.6. Dispersion according to claim 5, characterized in that the protein is a gelatin.
7.- Dispersion suivant la revendication 5, caractérisée en ce que la protéine est une gélatine gélifiante soluble à froid, à une température inférieure à 30°C.7. Dispersion according to claim 5, characterized in that the protein is a gelatinizing gelatin cold soluble at a temperature below 30 ° C.
8.- Dispersion suivant la revendication 5, caractérisée en ce que le deuxième système d'hydrocoUoïdes comprend un mélange de gélatine et de pectine. 8. Dispersion according to claim 5, characterized in that the second hydrocooid system comprises a mixture of gelatin and pectin.
9.- Dispersion suivant l'une quelconque des revendications précédentes, caractérisée en ce que le premier hydrocolloïde ou système d'hydrocoUoïdes, dont la concentration est suffisante pour former une phase continue, comprend un polysaccharide non ionique. 9. Dispersion according to any one of the preceding claims, characterized in that the first hydrocolloid or hydrocooid system, the concentration of which is sufficient to form a continuous phase, comprises a nonionic polysaccharide.
10.- Dispersion suivant la revendication 9, caractérisée en ce que le polysaccharide non ionique comprend du galactose et du mannose.10.- Dispersion according to claim 9, characterized in that the nonionic polysaccharide comprises galactose and mannose.
11.- Dispersion suivant la revendication 9, caractérisée en ce que le premier hydrocolloïde ou système d'hydrocoUoïdes comprend un galactomannane.11.- Dispersion according to claim 9, characterized in that the first hydrocolloid or hydrocoUoid system comprises a galactomannan.
12.- Dispersion suivant l'une quelconque des revendications précédentes, caractérisée en ce que le premier hydrocolloïde ou système d'hydrocoUoïdes, dont la concentration est suffisante pour former une phase continue, comprend un mélange de galactomannane et d'éther de cellulose.12.- Dispersion according to any one of the preceding claims, characterized in that the first hydrocolloid or hydrocooid system, the concentration of which is sufficient to form a continuous phase, comprises a mixture of galactomannan and cellulose ether.
13.- Dispersion suivant la revendication 11, caractérisée en ce que le premier hydrocolloïde ou système d'hydrocoUoïdes comprend une gomme de guar, une gomme de tara, une gomme de caroube (locust bean gum) ou un mélange de celles-ci, éventuellement en mélange avec de 1'éther de cellulose.13.- Dispersion according to claim 11, characterized in that the first hydrocolloid or hydrocoUoid system comprises a guar gum, a tara gum, a locust bean gum or a mixture of these, optionally in admixture with cellulose ether.
14.- Dispersion suivant l'une quelconque des revendications précédentes, caractérisée en ce que le rapport en poids premier hydrocolloïde ou système d*hydrocolloïdes/deuxième hydrocolloïde ou système d'hydrocoUoïdes est supérieur à 1:10.14.- Dispersion according to any one of the preceding claims, characterized in that the weight ratio of first hydrocolloid or system of * hydrocolloids / second hydrocolloid or system of hydrocoUoids is greater than 1:10.
15.- Dispersion suivant la revendication 14, caractérisée en ce que le rapport en poids premier hydrocolloïde ou système d'hydrocolloïdes/deuxième hydrocolloïde ou système d'hydrocoUoïdes est inférieur à 1:1.15.- Dispersion according to claim 14, characterized in that the weight ratio first hydrocolloid or hydrocolloid system / second hydrocolloid or hydrocooid system is less than 1: 1.
16.- Dispersion suivant l'une quelconque des revendications précédentes, caractérisée en ce qu'elle comprend un emulsifiant.16.- Dispersion according to any one of the preceding claims, characterized in that it comprises an emulsifier.
17.- Dispersion suivant la revendication 16, caractérisée en ce que 1'emulsifiant est une lecithine, un ester de diacétyltartryl de mono-diglycérides17.- Dispersion according to claim 16, characterized in that the emulsifier is a lecithin, a diacetyltartryl ester of mono-diglycerides
(DATEM) , l'ester de polyglycérol et d'acides gras, le stéaroyl lactilate de calcium et/ou de sodium.(DATEM), the ester of polyglycerol and fatty acids, calcium and / or sodium stearoyl lactilate.
18.- Dispersion suivant la revendication 16 ou 17, caractérisée en ce que le rapport en poids émulsifiant/premier et deuxième hydrocolloïdes ou systèmes d'hydrocoUoïdes est inférieur à 1:1. 18.- Dispersion according to claim 16 or 17, characterized in that the weight ratio of emulsifier / first and second hydrocolloids or hydrocoUoid systems is less than 1: 1.
19.- Dispersion suivant l'une quelconque des revendications précédentes, caractérisée en ce que le premier système d'hydrocoUoïdes est un système d'hydrocoUoïdes qui, en tant que tel, forme une phase continue pour des températures inférieures à 40°C et présente une viscosité accrue à une température supérieure à 50°C par rapport à celle mesurée à 20°C.19.- Dispersion according to any one of the preceding claims, characterized in that the first hydrocoUoid system is a hydrocoUoid system which, as such, forms a continuous phase for temperatures below 40 ° C and has an increased viscosity at a temperature above 50 ° C compared to that measured at 20 ° C.
20.- Dispersion suivant la revendication 19, caractérisée en ce que le premier système d'hydrocoUoïdes comprend également de l'éther de cellulose. 20.- Dispersion according to claim 19, characterized in that the first hydrocooid system also comprises cellulose ether.
21.- Dispersion suivant la revendication l, caractérisée en ce que la première phase contient de manière prépondérante un système de galactomannane soluble à froid et d'un éther de cellulose et en ce que la deuxième phase contient de manière prépondérante un système de gélatine gélifiante soluble à froid et de la pectine.21. Dispersion according to claim 1, characterized in that the first phase contains predominantly a system of cold soluble galactomannan and of a cellulose ether and in that the second phase contains predominantly a gelling gelatin system cold soluble and pectin.
22.- Mélange pour réaliser des dispersions suivant l'une ou l'autre des revendications précédentes, ledit mélange contenant au moins deux hydrocolloïdes ou système d'hydrocoUoïdes, un premier hydrocolloïde ou un premier système d'hydrocoUoïdes présentant une température critique inférieure à 5°C, tandis qu'un deuxième hydrocolloïde ou un deuxième système d'hydrocoUoïdes présente une température critique supérieure à 15°C, le rapport en poids premier hydrocolloïde ou premier système d'hydrocol¬ loïdes/deuxième hydrocolloïde ou deuxième système d'hydrocoUoïdes étant compris entre 0,1:1 et 0,1:1. 22. Mixture for producing dispersions according to either of the preceding claims, said mixture containing at least two hydrocolloids or hydrocooid system, a first hydrocolloid or a first hydrocooid system having a critical temperature of less than 5 ° C, while a second hydrocolloid or a second hydrocoid system has a critical temperature above 15 ° C, the weight ratio of the first hydrocolloid or first hydrocoloid system / second hydrocolloid or second hydrocoid system being between 0.1: 1 and 0.1: 1.
23.- Mélange suivant la revendication 22, caractérisé en ce que le deuxième système d'hydrocoUoïdes comprend de la pectine.23.- A mixture according to claim 22, characterized in that the second hydrocooid system comprises pectin.
24.- Mélange suivant la revendication 21 ou 22, caractérisé en ce qu'il comprend de la gélatine, du galactomannane et de la pectine.24.- A mixture according to claim 21 or 22, characterized in that it comprises gelatin, galactomannan and pectin.
25.- Mélange suivant la revendication 24, caractérisé en ce que, par rapport au poids total de gélatine, de galactomannane et de pectine, il contient de 50 à 80% de gélatine et de 10 à 40% de ga1actomannane.25.- A mixture according to claim 24, characterized in that, relative to the total weight of gelatin, galactomannan and pectin, it contains 50 to 80% of gelatin and 10 to 40% of ga1actomannan.
26.- Mélange suivant la revendication 25, caractérisé en ce qu'il contient de 1 à 40% en poids de pectine par rapport au poids total de gélatine, galactomannane et de pectine. 26.- Mixture according to claim 25, characterized in that it contains from 1 to 40% by weight of pectin relative to the total weight of gelatin, galactomannan and pectin.
27.- Utilisation d'une dispersion ou d'un mélange suivant l'une quelconque des revendications précédentes pour la réalisation de produits ou compositions alimentaires.27.- Use of a dispersion or a mixture according to any one of the preceding claims for the production of food products or compositions.
28.- Utilisation d'une dispersion ou d'un mélange suivant l'une quelconque des revendications 1 à 26 en tant que substitut de graisse.28. Use of a dispersion or mixture according to any one of claims 1 to 26 as a fat substitute.
29.- Produit ou composition alimentaire contenant une dispersion ou un mélange suivant l'une quelconque des revendications 1 à 26. 29.- Food product or composition containing a dispersion or a mixture according to any one of claims 1 to 26.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9200236A BE1005742A3 (en) | 1992-03-09 | 1992-03-09 | Hydrocolloid DISPERSION FOR POWER. |
BE9200236 | 1992-03-09 |
Publications (1)
Publication Number | Publication Date |
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WO1993017582A1 true WO1993017582A1 (en) | 1993-09-16 |
Family
ID=3886179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/BE1993/000012 WO1993017582A1 (en) | 1992-03-09 | 1993-03-08 | Hydrocolloidal dispersion for foodstuffs, mixture therefor and resulting foodstuff |
Country Status (2)
Country | Link |
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BE (1) | BE1005742A3 (en) |
WO (1) | WO1993017582A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO1996002151A1 (en) * | 1994-07-15 | 1996-02-01 | Unilever N.V. | Pourable salad dressing |
EP0702902A1 (en) * | 1994-09-24 | 1996-03-27 | Societe Des Produits Nestle S.A. | A heat-stable oil-in-water emulsion and a process for its manufacture |
US5773072A (en) * | 1994-12-13 | 1998-06-30 | Nestec S.A. | Method of making a heat-stabilized oil/water emulsion containing egg yolk and DATEM |
WO1999002047A1 (en) * | 1997-07-11 | 1999-01-21 | Unilever N.V. | Pourable edible aqueous-continuous emulsions |
EP0986310A1 (en) * | 1997-06-04 | 2000-03-22 | Mars Incorporated | Confection with multiple juicy regions and methods for making the same |
US6251448B1 (en) | 1999-02-22 | 2001-06-26 | Nestec Sa | Chocolate or compound coating with unique texture |
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EP0345885A2 (en) * | 1988-06-09 | 1989-12-13 | Monsanto Company | Gellan gum/gelatin blends |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996002151A1 (en) * | 1994-07-15 | 1996-02-01 | Unilever N.V. | Pourable salad dressing |
AU702501B2 (en) * | 1994-07-15 | 1999-02-25 | Unilever Plc | Pourable salad dressing |
EP0702902A1 (en) * | 1994-09-24 | 1996-03-27 | Societe Des Produits Nestle S.A. | A heat-stable oil-in-water emulsion and a process for its manufacture |
US5837308A (en) * | 1994-09-24 | 1998-11-17 | Nestec S.A. | Oil/water emulsion heat-stabilized with protein and datem |
US5773072A (en) * | 1994-12-13 | 1998-06-30 | Nestec S.A. | Method of making a heat-stabilized oil/water emulsion containing egg yolk and DATEM |
EP0986310A1 (en) * | 1997-06-04 | 2000-03-22 | Mars Incorporated | Confection with multiple juicy regions and methods for making the same |
EP0986310A4 (en) * | 1997-06-04 | 2001-01-10 | Mars Inc | Confection with multiple juicy regions and methods for making the same |
WO1999002047A1 (en) * | 1997-07-11 | 1999-01-21 | Unilever N.V. | Pourable edible aqueous-continuous emulsions |
US6136363A (en) * | 1997-07-11 | 2000-10-24 | Lipton, Division Of Conopco, Inc. | Pourable edible aqueous-continuous emulsions |
US6251448B1 (en) | 1999-02-22 | 2001-06-26 | Nestec Sa | Chocolate or compound coating with unique texture |
Also Published As
Publication number | Publication date |
---|---|
BE1005742A3 (en) | 1994-01-11 |
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