WO1993003458A1 - Method and apparatus for monitoring equipment - Google Patents
Method and apparatus for monitoring equipment Download PDFInfo
- Publication number
- WO1993003458A1 WO1993003458A1 PCT/CA1991/000278 CA9100278W WO9303458A1 WO 1993003458 A1 WO1993003458 A1 WO 1993003458A1 CA 9100278 W CA9100278 W CA 9100278W WO 9303458 A1 WO9303458 A1 WO 9303458A1
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- WIPO (PCT)
- Prior art keywords
- oil
- concentration
- engine
- additive
- tri
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000012544 monitoring process Methods 0.000 title claims description 7
- 239000000654 additive Substances 0.000 claims abstract description 42
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 38
- 230000000996 additive effect Effects 0.000 claims abstract description 30
- 238000004458 analytical method Methods 0.000 claims description 30
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 5
- 238000011156 evaluation Methods 0.000 claims description 3
- 238000002329 infrared spectrum Methods 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 238000004566 IR spectroscopy Methods 0.000 abstract 1
- 239000010913 used oil Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 71
- 238000001228 spectrum Methods 0.000 description 11
- 239000010705 motor oil Substances 0.000 description 9
- 230000003595 spectral effect Effects 0.000 description 7
- 238000011835 investigation Methods 0.000 description 5
- 239000002923 metal particle Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000011088 calibration curve Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- -1 Phenyl- Chemical group 0.000 description 2
- 239000007866 anti-wear additive Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010338 mechanical breakdown Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 101100494267 Caenorhabditis elegans best-18 gene Proteins 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000001636 atomic emission spectroscopy Methods 0.000 description 1
- 238000000559 atomic spectroscopy Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000010724 circulating oil Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000010735 electrical insulating oil Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2835—Specific substances contained in the oils or fuels
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07C—TIME OR ATTENDANCE REGISTERS; REGISTERING OR INDICATING THE WORKING OF MACHINES; GENERATING RANDOM NUMBERS; VOTING OR LOTTERY APPARATUS; ARRANGEMENTS, SYSTEMS OR APPARATUS FOR CHECKING NOT PROVIDED FOR ELSEWHERE
- G07C3/00—Registering or indicating the condition or the working of machines or other apparatus, other than vehicles
Definitions
- This invention relates to a method and apparatus or system for monitoring oil-operating equipment to identify potential equipment failure and is more especially concerned with such a method and apparatus for predicting gas turbine engine failure.
- Equipment of various types employs oil in its operation, especially circulating oil; such oil may circulate as a result of forced or natural circulation forces.
- equipment of this type includes engines in which the oil serves as a lubri ⁇ cant and electric transformers in which the oil serves as a coolant and as a dielectric medium.
- Such oil operating-equipment is subject to failure for various reasons and such failure can have dire consequences; for example, in the case of aviation engines, engine failure may result in a crash and fatalities; in the case of transformers failure may result in temporary shortage of electri-" city supply which at best results in inconvenience to users and at worst may result in fatalities.
- the method currently used by commercial airlines and military bodies for diagnosing mechanical problems involves the measurement of small metal particles suspended in the oil using atomic emission or atomic absorption spectroscopy and the detection of larger metal particles by filter analysis, chip detector analysis or ferrographic analysis.
- Chip detector warning is characteristi- cally of the order of several hours; filter analysis warning is at best 18 hours; traditional oil analysis using atomic spectroscopy is unreliable since it is limited to very small particle detection.
- Infrared analysis of oil has been used to monitor the quality of the oil in order to determine its ability to effectively lubricate the engine. However, it has not been used as a diagnostic tool to determine the state of health of mechanical com ⁇ ponents of the engine.
- Engine oils employed to lubricate engine parts during use contain a number of chemical additives in relatively small amounts. Common additives include oxidation inhibitors, rust inhibitors, anti-wear agents, detergents, dispersers, pour-point depressants, viscosity index improvers and foam inhibitors. The selection and amount of additive depends on the nature of the engine and the environment in which it will be employed.
- Tri-cresyl phosphate is widely employed as an anti-wear additive in gas turbine engine oils, especially for gas turbine engines employed in aircraft and industry, and functions by forming a protective sacrificial film on contacting mechanical surfaces which are lubricated by the oil.
- Phenyl- ⁇ -naphthylamine and dialkylpheno- thiazine are employed as antioxidants in engine oils; and 2, 6-ditertiary-butyl para cresol and 2,6-di- tertiary-butyl phenol are employed as antioxidants in electrical insulating oils.
- the invention seeks to provide a method and apparatus or system which will provide relatively long term warning of failure in oil-operating equip ⁇ ment.
- a method of monitoring oil-operating equipment to identify potential equipment failure comprising: i) determining the concentration of an identified additive in an oil employed in the operation of equipment, ii) comparing the concentration determined in i) with a reference value to provide a comparison, and iii) evaluating the comparison as an indication of the state of the equipment. Conveniently steps i), ii) and iii) are repeated sequentially during continued operation of the engine.
- an apparatus or system for monitoring oil-operating equipment to identify potential equipment failure comprising: a) means for determining the concentration of an identified additive of an oil employed in the operation of equipment, b) comparator means for comparing a determined concentration with a reference value and providing a comparison, and c) evaluating means for evaluating the comparison as an indication of the state of the equipment.
- the method and apparatus or system of the invention employ determination of the concentration of an additive in the oil, more especially a normal oil additive, for example, tri-cresyl phosphate, and which oil has been used in the operation of an engine under investigation.
- the invention relies on the surprising observation that oil in an engine which is approach ⁇ ing failure, suffers a significant drop in its concentration of an additive, such as tri-cresyl phosphate prior to failure.
- the additive is tri-cresyl phosphate
- the concentration of the tri-cresyl phosphate in the fresh oil rapidly drops. This drop in concentration occurs in a time signifi ⁇ cantly shorter than, and much more dramatically than, the expected drop in concentration of the phosphate which occurs during the normal operation of a pro- perly functioning engine.
- the determination of the additive concent ⁇ ration of the oil may be carried, out by a number of analytical techniques, however, infrared spectro ⁇ scopy, and in particular fourier transform infrared spectroscopy has been found to be especially useful for this purpose.
- the present invention it is possible to predict engine failure based on the analysis of the engine oil, and this prediction can be made within a reasonable warning period. Further ⁇ more, while an additive can be deliberately incor ⁇ porated in the oil for the purposes of this invention, the invention is applicable to additives normally incorporated in such oils based on parti ⁇ cular properties, for example, the anti-wear additive tri-cresyl phosphate.
- oil-operating equipment for example, electrical transformers
- hot spots which degrade or thermally decompose oil-additives
- other additives which might be exploited in accordance with the invention include phenyl-o-naphthylamine, dialkylphenothiazine, 2,6-ditertiary-butyl para cresol and 2,6-ditertiary butyl phenol.
- oil-operating equipment means equipment which employs an oil in its operation and includes mechanical equipment, for example, engines and gear boxes and electrical equipment, for example, transformers.
- FIG. 1 illustrates schematically an apparatus or system of the invention for use in carrying out the method of the invention
- Fig. 2 illustrates in flow chart form an algorithm for use in the invention. MODES FOR CARRYING OUT THE INVENTION
- the levels of tri-cresyl phosphate for normally functioning gas turbine aviation engines can be shown to be relatively stable based on analysis of samples of the oil over an extended period of time; in particular analysis shows a level of about 90% of the original content of tri-cresyl phosphate when the engine functions normally. It has been observed that the levels of tri-cresyl phosphate are abnormally low for an engine which subsequently fails due to mechanical breakdown. An engine employed in the invention failed due to mechanical breakdown several weeks after a consistent drop in concentration of the tri-cresyl phosphate below the 80% level, exhibited between 9,000 and 10,000 hours of use of the oil.
- the early warning of failure provided by the method of the invention provides ample time for more extensive tests and inspection of an engine so that the possibility of a disaster such as an in ⁇ flight failure can be reduced or avoided. This early warning permits a range of more extensive testing for a specific engine for which failure is predicted, which would not be practical on a routine basis for all engines.
- the invention is more particularly des ⁇ cribed by reference to the embodiment in which the additive is a normal additive, particularly tri- cresyl phosphate.
- samples of an engine oil containing tri- cresyl phosphate as an additive are obtained periodi ⁇ cally and preferably at regular intervals throughout the working life of the oil.
- the oil sample is analyzed to determine the concentration of tri-cresyl phosphate and the con ⁇ centration is compared with a reference value.
- the reference value may suitably be a predetermined value based on the normal levels of tri-cresyl phosphate observed in properly functioning engines or the level in unused or fresh oil. It will be recog ⁇ nized that the predetermined reference value may be associated with a particular oil or brand of oil and therefore there may be a number of reference values with the appropriate reference value being selected for the oil under investigation.
- the analysis is suitably carried out using an infrared spectrometer, preferably employing fourier transform infrared spectroscopy and a spect ⁇ rum of the oil is developed.
- the spectrum is decon ⁇ volved using a second derivation spectrum.
- the predetermined reference value involves the similarly deconvolved spectrum derived from oils in properly functioning engines.
- the deconvolved spectrum of the oil sample under investigation is subtracted from that in the reference value and an integration is made of the difference in the spectral region corres- ponding to the tri-cresyl phosphate wave length or wave number.
- This integrated value is compared with a previously prepared calibration curve for the reference value, which calibration curve relates concentration and integrated value in the spectral region under consideration. In this way a comparison is made of the concentration of the tri-cresyl phosphate in the sample of oil under investigation and the normal concentration in use.
- the analysis is conducted so as to identify a statistically significant drop in the concentration of the additive under ban- gation, in the oil.
- This may be achieved by drawing the best line possible through a series of plotted results of additive concentration for normally functioning engines over a period of time; and determining the standard deviation and coefficient of correlation.
- the standard deviation may be deter ⁇ mined by drawing a perpendicular line from the afore-mentioned best line to each plotted value, determining the length of each perpendicular line, taking the square of each length, summing the square values and taking the square root of the summation.
- a drop in the concentration of the additive of statistical significance would be one having a given number of standard deviations, and is valid when the coefficient of correlation is close to unity.
- Aviation oils contain 1 to 5%, usually 2 to 3%, by weight, of tri-cresyl phosphate. A decrease in the concentration of 50 to 80% of the normal value would represent a drop of greater than 2 to 3 times the standard deviation. Determination of such a drop, in accordance with the invention, is an indication of a problem with the engine.
- an engine can be monitored and prediction of engine failure can be obtained well in advance of such failure relying on analysis of levels of normal additives present in the oil.
- the invention avoids the need to introduce foreign materials into the oil or engine parts for the sole purpose of analysis and can rely on deter ⁇ mination of materials routinely employed as additives in commercial oil formulations.
- an apparatus or system 10 of the invention comprises a detector 12, a computer or computer network 14 and an output terminal 16.
- Computer network 14 includes a spectral storage system 18, a relational database 20, a deconvolver 22, a subtracter 24 and a comparator 26.
- Computer network 14 additionally includes an evaluator or expert system 30.
- An oil sample is designated 32; the straight lines with arrows indicate signal flow and the broken lines indicate information access.
- Detector 12 is in particular an infrared spectrometer, more especially a fourier transform infrared spectrometer; the spectral storage system 18 contains infrared spectra of the oil in previously tested engines with identifying parameters for such engines; and relational data base 20 contains the references to the spectra of fresh oil, base oil spectra, data of oil additives and functions, spectral data of additives, including spectral regions, calibration models and historical norms.
- a spectrum 34 of oil under analysis is deconvolved in step 36 and the deconvolved spectrum is subtracted from a known spectrum of unused oil of the same type and an integration is made of the difference in spectral region corresponding to the tri-cresyl phosphate wave length in step 38.
- the integrated value is compared in step 40 with a calibration curve from 42 and the result evaluated in step 44.
- a sample 32 of a known oil containing tri-cresyl phosphate is taken from an engine, and the sample is identified by reference to the specific engine from which it is taken and suitably by reference to other parameters such as the number of flight hours of the engine.
- the sample 32 is introduced into detector 12 which may be, for example, an infrared spectrometer, and a deter ⁇ mination of the tri-cresyl phosphate content of the sample 32 is made.
- detector 12 is an infrared spectrometer
- an infrared spectrum is developed at least for the regions in which the characteristic peaks for tri-cresyl phosphate occur.
- the resulting spectrum is fed into computer i4 where the algorithm of Fig. 2 is employed to successively deconvolve the spectrum, substract and integrate, and compare, as described hereinbefore.
- the data for the comparison as well as for the deconvolution and subtraction and integration is taken from the reference data base 20.
- the reference values in data base 20 for the comparison are representative of a normal or acceptable level of tri-cresyl phosphate in engine oil.
- the comparison is fed to evaluator 30 which issues a signal to ouput terminal 16.
- the evaluator 30 may, for example, be programmed to issue a warning signal if the evaluation shows an unacceptable deviation of greater than, for example, 2 times the standard deviation.
- Oil samples were taken from all the engines at periodic intervals during operation of the engines and an infrared analysis was taken to deter- mine the tri-cresyl phosphate concentration of the oil for each engine, in accordance with the specific procedure described herein.
- Table I sets out the results of the analysis for engine 293 and comparison results for 7 of the other 23 engines. In each case the number of hours of operating time when the sample of oil was taken is indicated, together with a percentage value for the tri-cresyl phosphate remaining in the sample, this percentage value being a percentage of the normal concentration in the oil.
- the seven comparison engines for which results are shown in Table I are representative of the 23 engines and were selected for Table I to demonstrate results for a range of different flight hours.
- engines 550, 555 and 830 weretul ⁇ gated through flight hours similar to engine 293, engine 839 and 850 demonstrate results for flight hours in the 2000 to 4000 hour range; and engines 313 and 323 demonstrate results for flight hours in the 6000 to 8000 hour range.
- Engine 830 additionally shows results first in the 2000 to 3000 and then in the 8000 to 10000 hour range.
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Abstract
A method and apparatus for the prediction of failure in oil-operating equipment, for example, a gas turbine engine employs infrared spectroscopy to measure the amount of an oil additive such as tri-cresyl phosphate in a sample of used oil, the level of additive is compared to the levels in similar mechanical units which are known to be operating normally, a significant lowering of the concentration of additive compared to the normal concentration indicates that the mechanical unit is operating abnormally and should be thoroughly inspected to avoid an in-flight or in-production failure.
Description
METHOD AND APPARATUS FOR MONITORING EQUIPMENT TECHNICAL FIELD
This invention relates to a method and apparatus or system for monitoring oil-operating equipment to identify potential equipment failure and is more especially concerned with such a method and apparatus for predicting gas turbine engine failure. BACKGROUND ART
Equipment of various types employs oil in its operation, especially circulating oil; such oil may circulate as a result of forced or natural circulation forces. Typically equipment of this type includes engines in which the oil serves as a lubri¬ cant and electric transformers in which the oil serves as a coolant and as a dielectric medium. Such oil operating-equipment is subject to failure for various reasons and such failure can have dire consequences; for example, in the case of aviation engines, engine failure may result in a crash and fatalities; in the case of transformers failure may result in temporary shortage of electri-" city supply which at best results in inconvenience to users and at worst may result in fatalities.
Ongoing maintenance of such equipment is routine in attempts to minimize failure. in order to comply with the need for safety in aviation gas turbine engines and to reduce the costs of maintenance, periodic sampling of oil used in the operations of the engine and analysis of the oil is carried out in an attempt to diagnose mechanical and oil related problems.
The method currently used by commercial airlines and military bodies for diagnosing mechanical problems involves the measurement of small
metal particles suspended in the oil using atomic emission or atomic absorption spectroscopy and the detection of larger metal particles by filter analysis, chip detector analysis or ferrographic analysis.
All of these methods rely on the principle that a mechanical component of a particular metallic composition has already begun to fail sufficiently to generate metal particles in the oil, which particles can be detected by one of the aforementioned methods. It is well known that at best these methods provide only a short warning period before failure of the engine. Often, there is no warning period whatsoever. Chip detector warning is characteristi- cally of the order of several hours; filter analysis warning is at best 18 hours; traditional oil analysis using atomic spectroscopy is unreliable since it is limited to very small particle detection.
Infrared analysis of oil has been used to monitor the quality of the oil in order to determine its ability to effectively lubricate the engine. However, it has not been used as a diagnostic tool to determine the state of health of mechanical com¬ ponents of the engine. Engine oils employed to lubricate engine parts during use contain a number of chemical additives in relatively small amounts. Common additives include oxidation inhibitors, rust inhibitors, anti-wear agents, detergents, dispersers, pour-point depressants, viscosity index improvers and foam inhibitors. The selection and amount of additive depends on the nature of the engine and the environment in which it will be employed.
Tri-cresyl phosphate is widely employed as an anti-wear additive in gas turbine engine oils, especially for gas turbine engines employed in aircraft and industry, and functions by forming a protective sacrificial film on contacting mechanical surfaces which are lubricated by the oil.
Phenyl-^-naphthylamine and dialkylpheno- thiazine are employed as antioxidants in engine oils; and 2, 6-ditertiary-butyl para cresol and 2,6-di- tertiary-butyl phenol are employed as antioxidants in electrical insulating oils. DISCLOSURE OF THE INVENTION
The invention seeks to provide a method and apparatus or system which will provide relatively long term warning of failure in oil-operating equip¬ ment.
In accordance with one aspect of the invention there is provided a method of monitoring oil-operating equipment to identify potential equipment failure comprising: i) determining the concentration of an identified additive in an oil employed in the operation of equipment, ii) comparing the concentration determined in i) with a reference value to provide a comparison, and iii) evaluating the comparison as an indication of the state of the equipment. Conveniently steps i), ii) and iii) are repeated sequentially during continued operation of the engine.
In accordance with another aspect of the invention there is provided an apparatus or system for monitoring oil-operating equipment to identify potential equipment failure comprising: a) means for determining the concentration of an identified additive of an oil employed in the operation of equipment, b) comparator means for comparing a
determined concentration with a reference value and providing a comparison, and c) evaluating means for evaluating the comparison as an indication of the state of the equipment. The method and apparatus or system of the invention employ determination of the concentration of an additive in the oil, more especially a normal oil additive, for example, tri-cresyl phosphate, and which oil has been used in the operation of an engine under investigation.
The invention relies on the surprising observation that oil in an engine which is approach¬ ing failure, suffers a significant drop in its concentration of an additive, such as tri-cresyl phosphate prior to failure.
Indeed for the particular case in which the additive is tri-cresyl phosphate, if the oil in an engine which exhibits this drop in concentration, is replaced by fresh oil, the concentration of the tri-cresyl phosphate in the fresh oil rapidly drops. This drop in concentration occurs in a time signifi¬ cantly shorter than, and much more dramatically than, the expected drop in concentration of the phosphate which occurs during the normal operation of a pro- perly functioning engine.
This observed drop in concentration of an additive such as tri-cresyl phosphate has been observed to occur long before actual failure of the engine, and before development of metal particles from the metallic components of the engine, in an amount detectable by the traditional methods described above.
Although the reason for this phenomenon has not been established it is possible that a developed mechanical defect or problem in the engine results in the creation of one or more hot spots in the engine, and that the heat from these hot spots rapidly degrades or destroys the additive thereby reducing its concentration.
The determination of the additive concent¬ ration of the oil may be carried, out by a number of analytical techniques, however, infrared spectro¬ scopy, and in particular fourier transform infrared spectroscopy has been found to be especially useful for this purpose.
By means of the present invention it is possible to predict engine failure based on the analysis of the engine oil, and this prediction can be made within a reasonable warning period. Further¬ more, while an additive can be deliberately incor¬ porated in the oil for the purposes of this invention, the invention is applicable to additives normally incorporated in such oils based on parti¬ cular properties, for example, the anti-wear additive tri-cresyl phosphate.
It is likewise possible to predict failure of other oil-operating equipment, for example, electrical transformers, in which hot spots which degrade or thermally decompose oil-additives, may result from early stage electrical shorts or other electrical failures which forebode a breakdown or failure. By way of example other additives which might be exploited in accordance with the invention include phenyl-o-naphthylamine, dialkylphenothiazine, 2,6-ditertiary-butyl para cresol and 2,6-ditertiary butyl phenol.
In this invention "oil-operating equipment" means equipment which employs an oil in its operation and includes mechanical equipment, for example, engines and gear boxes and electrical equipment, for example, transformers.
BRIEF DESCRIPTION OF DRAWINGS
Fig. 1 illustrates schematically an apparatus or system of the invention for use in carrying out the method of the invention; Fig. 2 illustrates in flow chart form an algorithm for use in the invention. MODES FOR CARRYING OUT THE INVENTION
The levels of tri-cresyl phosphate for normally functioning gas turbine aviation engines can be shown to be relatively stable based on analysis of samples of the oil over an extended period of time; in particular analysis shows a level of about 90% of the original content of tri-cresyl phosphate when the engine functions normally. It has been observed that the levels of tri-cresyl phosphate are abnormally low for an engine which subsequently fails due to mechanical breakdown. An engine employed in the invention failed due to mechanical breakdown several weeks after a consistent drop in concentration of the tri-cresyl phosphate below the 80% level, exhibited between 9,000 and 10,000 hours of use of the oil.
The traditional tests for metal particles failed to give any indication of the imminent f ilure at the stage at which the consistent drop in concent¬ ration of tri-cresyl phosphate was observed.
The early warning of failure provided by the method of the invention provides ample time for more extensive tests and inspection of an engine so
that the possibility of a disaster such as an in¬ flight failure can be reduced or avoided. This early warning permits a range of more extensive testing for a specific engine for which failure is predicted, which would not be practical on a routine basis for all engines.
The invention is more particularly des¬ cribed by reference to the embodiment in which the additive is a normal additive, particularly tri- cresyl phosphate. In carrying out the method of the invention samples of an engine oil containing tri- cresyl phosphate as an additive are obtained periodi¬ cally and preferably at regular intervals throughout the working life of the oil. The oil sample is analyzed to determine the concentration of tri-cresyl phosphate and the con¬ centration is compared with a reference value. The reference value may suitably be a predetermined value based on the normal levels of tri-cresyl phosphate observed in properly functioning engines or the level in unused or fresh oil. It will be recog¬ nized that the predetermined reference value may be associated with a particular oil or brand of oil and therefore there may be a number of reference values with the appropriate reference value being selected for the oil under investigation.
On the other hand, particularly in the field of aviation oils, there is a relatively small selection of oils available and the composition of such oils, including the tri-cresyl phosphate con¬ centration, is established within fairly narrow ranges by standards set by the International Civil
Aviation Organization ( CAO), which standards are followed internationally, similar standards are set by military establishments.
The analysis is suitably carried out using an infrared spectrometer, preferably employing fourier transform infrared spectroscopy and a spect¬ rum of the oil is developed. The spectrum is decon¬ volved using a second derivation spectrum. The predetermined reference value involves the similarly deconvolved spectrum derived from oils in properly functioning engines. The deconvolved spectrum of the oil sample under investigation is subtracted from that in the reference value and an integration is made of the difference in the spectral region corres- ponding to the tri-cresyl phosphate wave length or wave number. This integrated value is compared with a previously prepared calibration curve for the reference value, which calibration curve relates concentration and integrated value in the spectral region under consideration. In this way a comparison is made of the concentration of the tri-cresyl phosphate in the sample of oil under investigation and the normal concentration in use.
These operations can be performed in a computer system for which the algorithm is readily developed by routine experimentation. For example, a drop in the tri-cresyl phosphate concentration to a value of 80% or less, and especially a drop to 50-70%, of the normal value is indicative of potential engine failure, and the computer system produces an evaluation and issues a warning signal when a drop into this region occurs.
It is appropriate to maintain a history or record of the results of determination of tri-cresyl phosphate concentration of oil for each engine so that any change or initiation of drop in such phos- phate concentration can be more readily identified as an early warning of engine failure. This history can be compiled automatically in the computer by appro¬ priate software, so that a history of results for each engine is available to the algorithm programs which have the ability to evaluate significant changes in the additive level.
In particular the analysis is conducted so as to identify a statistically significant drop in the concentration of the additive under investi- gation, in the oil. This may be achieved by drawing the best line possible through a series of plotted results of additive concentration for normally functioning engines over a period of time; and determining the standard deviation and coefficient of correlation. The standard deviation may be deter¬ mined by drawing a perpendicular line from the afore-mentioned best line to each plotted value, determining the length of each perpendicular line, taking the square of each length, summing the square values and taking the square root of the summation. A drop in the concentration of the additive of statistical significance would be one having a given number of standard deviations, and is valid when the coefficient of correlation is close to unity.
Aviation oils contain 1 to 5%, usually 2 to 3%, by weight, of tri-cresyl phosphate. A decrease in the concentration of 50 to 80% of the normal value would represent a drop of greater than 2 to 3 times
the standard deviation. Determination of such a drop, in accordance with the invention, is an indication of a problem with the engine.
Thus by means of the invention an engine can be monitored and prediction of engine failure can be obtained well in advance of such failure relying on analysis of levels of normal additives present in the oil. The invention avoids the need to introduce foreign materials into the oil or engine parts for the sole purpose of analysis and can rely on deter¬ mination of materials routinely employed as additives in commercial oil formulations. On the other hand, it is feasible to practice the invention with inclu¬ sion of special additives in the oil which additives are added solely for the purpose of the invention. This can be achieved by incorporating in the oil a substance which does not interfere with the proper operation of the oil or with the functioning additives of the oil, and which will remain sub- stantially inert in the oil under normal conditions, but which will suffer a drop in concentration, for example, as a result of hot spots causing thermal degradation or decompositon, in the event of a problem developing in the engine, which problem ultimately will result in engine failure.
With further reference to Fig. 1, an apparatus or system 10 of the invention comprises a detector 12, a computer or computer network 14 and an output terminal 16. Computer network 14 includes a spectral storage system 18, a relational database 20, a deconvolver 22, a subtracter 24 and a comparator 26.
Computer network 14 additionally includes an evaluator or expert system 30.
An oil sample is designated 32; the straight lines with arrows indicate signal flow and the broken lines indicate information access.
Detector 12 is in particular an infrared spectrometer, more especially a fourier transform infrared spectrometer; the spectral storage system 18 contains infrared spectra of the oil in previously tested engines with identifying parameters for such engines; and relational data base 20 contains the references to the spectra of fresh oil, base oil spectra, data of oil additives and functions, spectral data of additives, including spectral regions, calibration models and historical norms.
With further reference to Fig. 2, there is illustrated in flow chart form an algorithm 28 for use in the invention.
In algorithm 28 a spectrum 34 of oil under analysis is deconvolved in step 36 and the deconvolved spectrum is subtracted from a known spectrum of unused oil of the same type and an integration is made of the difference in spectral region corresponding to the tri-cresyl phosphate wave length in step 38. The integrated value is compared in step 40 with a calibration curve from 42 and the result evaluated in step 44.
In operation a sample 32 of a known oil containing tri-cresyl phosphate is taken from an engine, and the sample is identified by reference to the specific engine from which it is taken and suitably by reference to other parameters such as the number of flight hours of the engine. The sample 32 is introduced into detector 12 which may be, for example, an infrared spectrometer, and a deter¬ mination of the tri-cresyl phosphate content of the sample 32 is made. In the case in which detector 12
is an infrared spectrometer, an infrared spectrum is developed at least for the regions in which the characteristic peaks for tri-cresyl phosphate occur. The resulting spectrum is fed into computer i4 where the algorithm of Fig. 2 is employed to successively deconvolve the spectrum, substract and integrate, and compare, as described hereinbefore.
The data for the comparison as well as for the deconvolution and subtraction and integration is taken from the reference data base 20.
The reference values in data base 20 for the comparison are representative of a normal or acceptable level of tri-cresyl phosphate in engine oil. The comparison is fed to evaluator 30 which issues a signal to ouput terminal 16. The evaluator 30 may, for example, be programmed to issue a warning signal if the evaluation shows an unacceptable deviation of greater than, for example, 2 times the standard deviation.
EXAMPLES Example 1
In a one case history a PW120 turboprop aircraft engine manufactured by Pratt & Whitney was operated continually using Castrol (Trade Mark) 5000 engine oil. For convenience this engine is identified as engine 293.
A total of 23 similar PW120 turboprop aircraft engines each identified by a similar 3 digit number were operated under similar conditions using the same engine oil.
Oil samples were taken from all the engines at periodic intervals during operation of the engines and an infrared analysis was taken to deter-
mine the tri-cresyl phosphate concentration of the oil for each engine, in accordance with the specific procedure described herein.
Table I below sets out the results of the analysis for engine 293 and comparison results for 7 of the other 23 engines. In each case the number of hours of operating time when the sample of oil was taken is indicated, together with a percentage value for the tri-cresyl phosphate remaining in the sample, this percentage value being a percentage of the normal concentration in the oil.
TABLE I ENGINE NO,
293 313 323 550
I
ENGINE NO.
830 839 850 555
The seven comparison engines for which results are shown in Table I are representative of the 23 engines and were selected for Table I to demonstrate results for a range of different flight hours. Thus engines 550, 555 and 830 were investi¬ gated through flight hours similar to engine 293, engine 839 and 850 demonstrate results for flight hours in the 2000 to 4000 hour range; and engines 313 and 323 demonstrate results for flight hours in the 6000 to 8000 hour range. Engine 830 additionally shows results first in the 2000 to 3000 and then in the 8000 to 10000 hour range.
The results for engine 293 indicated very low % remaining at the 9346 and 9997 flight hours analyses, i.e., 67.31% and 69.14%, respectively so that the oil was replaced by fresh oil. The engine failed following 9 flight hours after the 10254 flight hours oil sample was taken. The analysis after 10263 flight hours was thus carried out after failure of the engine.
During the course of these analyses con¬ ventional spectrometric analyses were conducted for the content in parts per million of iron, copper, lead, tin, aluminum, chromium, nickel, titanium, silver, magnesium, silicon, boron, sodium, barium, calcium, phosphorus, manganese, molybdenum, zinc and vanadium. In no case did the levels measured for these metals indicate abnormal contents such as would indicate approaching engine failure. These results demonstrate that an analysis of the oil for metals such as iron and copper, within nine flight hours of the failure would not have predicted imminent engine failure. On the
other hand the analysis at 9346 flight hours followed by oil replacement and the subsequent analysis hours at 9997 flight hours can be seen as having provided a warning of the approaching failure at 917 and 266 flight hours prior to failure, respectively. In each case a rapid drop can be seen in the concentration of tri-cresyl phosphate.
Upon disassembly of the engine following failure it was found that two lubrication nozzles supplying a bearing and gear assembly in the auxiliary drive unit were partially blocked. The balls and races of the bearing were deformed and scored and the pinion shaft could not be held in place. As a result the gears disengaged from one another and no fuel or oil could be supplied to the engine.
The traditional methods of filter analysis, chip detectors and atomic absorption spectroscopy (by the Strategic Oil Analysis programme SOAP) did not indicate any operating or mechanical abnormalities.
Following repair of the engine it can be seen that normal levels of tri-cresyl phosphate in the engine oil were maintained. As indicated, other engines in Table 1 are indicative of results for the 23 engines which functioned normally, and in all cases the lowest values recorded are still close to 90%.
In this case the detected low levels of tri-cresyl phosphate concentration preceded failure of the engine and thus provided a prediction of the subsequent engine failure.
Claims
1. A method of monitoring oil-operating equipment to identify potential engine failure comprising: i) determining the concentration of an identified additive in an oil employed in the operation of oil-operating equipment, ii) comparing the concentration determined in i) with a reference value to provide a comparison, and iii) evaluating the comparison as an indication of the state of the equipment.
2. A method according to claim 1, including: iv) periodically repeating steps i), ii) and iii) sequentially during continued operation of the engine.
3. A method according to claim 2, which includes a step of obtaining a sample of the oil from said equipment prior to step i) and prior to each periodic repetition of step i) .
4. A method according to claim 1, in which step i) comprises an infrared analysis of said oil and deriving said concentration from the infrared spectrum.
5. A method according to claim 4, in which said analysis is a fourier transform infrared spectroscopy analysis.
6. A method according to claim 5, including: v) issuing a signal in response to step iii) as a value of the indication.
7. A method according to claim 1, in which step i) comprises determining the % of the concent¬ ration of said identified additive relative to a reference concentration value to provide the % of said concentration of said identified additive remaining in said oil relative to said reference concentration value.
8. A method of claim 1, wherein said equip¬ ment is an engine.
9. A method of claim 1, wherein said equip¬ ment is an electrical transformer
10. A method of claim 1, 2, 3, 4, 5, 6, 7, 8 or 9, wherein said additive is a normal additive present in the oil.
11. A method of claim 8, wherein said additive is tri-cresyl phosphate.
12. A method according to claim 11, wherein said reference value in ii) is derived from the normal tri-cresyl phosphate concentration of a tri-cresyl phosphate-containing oil operating in a similar engine under normal operation.
13. An apparatus for monitoring oil-operating equipment to identify potential equipment failure comprising: a) means for determining the concentration of an identified additive of an oil employed in the operation of oil- operating equipment, b) comparator means for comparing a deter¬ mined concentration with a reference value and providing a comparison, and c) evaluating means for evaluating the comparison as an indicator of the state of the equipment.
14. An apparatus according to claim 11, wherein said means a) comprises an infrared spectro¬ meter-
15. An apparatus according to claim 12, wherein said spectrometer is a fourier transform infrared spectrometer.
16. An apparatus according to claim 13, further including: d) signal means for issuing a signal in response to the evaluation developed by said evaluating means.
17. An apparatus according to claim 13, 14, 15 or 16, wherein said means a) consists of means for determining the tri-cresyl phosphate concentration of a tri-cresyl phosphate-containing oil.
18. An apparatus according to claim 13, 14, 15 or 16, wherein means b) and c) comprise a programmed computer.
19. An apparatus according to claim 13, 14, 15 or 16, wherein said means a) comprises means for determining the % concentration of the identified additive relative to a reference concentration value to provide the % of said concentration of said identified additive remaining in said oil relative to said reference concentration value.
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PCT/CA1991/000278 WO1993003458A1 (en) | 1991-08-09 | 1991-08-09 | Method and apparatus for monitoring equipment |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100115952A1 (en) * | 2007-03-30 | 2010-05-13 | Kawasaki Plant Systems Kabushiki Kaisha | Gum substance monitoring apparatus, gum substance detecting method, and gas turbine system |
US10240549B2 (en) | 2017-01-04 | 2019-03-26 | Honeywell International Inc. | System and method for evaluating chip zap data |
US11467143B2 (en) * | 2012-10-26 | 2022-10-11 | Pratt & Whitney Canada Corp. | Method and system for failure prediction using lubricating fluid analysis |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3526127A (en) * | 1969-03-24 | 1970-09-01 | Mobil Oil Corp | Engine oil analysis system |
SU757870A1 (en) * | 1978-09-08 | 1980-08-23 | Inst Yadernoj Energet An Brus | Method of qualitive spectroscopic analysis of chemical structure of liquid substances |
FR2513412A1 (en) * | 1981-09-09 | 1983-03-25 | Autoipari Kutato Intezet | METHOD FOR ANTICIPATED INDICATION OF THE DETERIORATION OF A TRIBOLOGICAL SYSTEM |
US4570069A (en) * | 1982-12-30 | 1986-02-11 | Gager Dennis J | On-board electronic oil contamination detector for vehicle engines |
US4744870A (en) * | 1986-12-23 | 1988-05-17 | University Of Dayton | Method for evaluating the remaining useful life of a lubricant |
US4800279A (en) * | 1985-09-13 | 1989-01-24 | Indiana University Foundation | Methods and devices for near-infrared evaluation of physical properties of samples |
SU1396745A1 (en) * | 1986-08-25 | 1989-07-30 | Предприятие П/Я Г-4671 | Comparison specimen for spectrum analysis of lubricants |
JPH0331746A (en) * | 1989-06-29 | 1991-02-12 | Komatsu Ltd | Method for estimating remaining life of lubricating oil |
-
1991
- 1991-08-09 WO PCT/CA1991/000278 patent/WO1993003458A1/en active Application Filing
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3526127A (en) * | 1969-03-24 | 1970-09-01 | Mobil Oil Corp | Engine oil analysis system |
SU757870A1 (en) * | 1978-09-08 | 1980-08-23 | Inst Yadernoj Energet An Brus | Method of qualitive spectroscopic analysis of chemical structure of liquid substances |
FR2513412A1 (en) * | 1981-09-09 | 1983-03-25 | Autoipari Kutato Intezet | METHOD FOR ANTICIPATED INDICATION OF THE DETERIORATION OF A TRIBOLOGICAL SYSTEM |
US4570069A (en) * | 1982-12-30 | 1986-02-11 | Gager Dennis J | On-board electronic oil contamination detector for vehicle engines |
US4800279A (en) * | 1985-09-13 | 1989-01-24 | Indiana University Foundation | Methods and devices for near-infrared evaluation of physical properties of samples |
US4800279B1 (en) * | 1985-09-13 | 1991-11-19 | Indiana University Foundation | |
SU1396745A1 (en) * | 1986-08-25 | 1989-07-30 | Предприятие П/Я Г-4671 | Comparison specimen for spectrum analysis of lubricants |
US4744870A (en) * | 1986-12-23 | 1988-05-17 | University Of Dayton | Method for evaluating the remaining useful life of a lubricant |
JPH0331746A (en) * | 1989-06-29 | 1991-02-12 | Komatsu Ltd | Method for estimating remaining life of lubricating oil |
Non-Patent Citations (4)
Title |
---|
ANALYTICAL CHEMISTRY. vol. 56, no. 9, August 1984, COLUMBUS US pages 1086 - 1094; EISENTRAUT E.A.: 'SPECTROMETRIC OIL ANALYSIS' * |
PATENT ABSTRACTS OF JAPAN vol. 015, no. 166 (P-1195)25 April 1991 & JP,A,3 031 746 ( KOMATSU ) 12 February 1991 * |
SOVIET PATENTS ABSTRACTS Section EI, Week 9004, Derwent Publications Ltd., London, GB; Class S, Page 10, AN 90-028656 & SU,A,1 396 745 (ZAKHAROV) 30 July 1989 * |
SOVIET PATENTS ABSTRACTS Section EI, Week D26, 5 August 1981 Derwent Publications Ltd., London, GB; Class S, Page 15, AN F9764D & SU,A,757 870 (AS BELO NUCL ENERGY) 8 September 1978 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100115952A1 (en) * | 2007-03-30 | 2010-05-13 | Kawasaki Plant Systems Kabushiki Kaisha | Gum substance monitoring apparatus, gum substance detecting method, and gas turbine system |
US8499620B2 (en) * | 2007-03-30 | 2013-08-06 | Kawasaki Jukogyo Kabushiki Kaisha | Gum substance monitoring apparatus, gum substance detecting method, and gas turbine system |
US11467143B2 (en) * | 2012-10-26 | 2022-10-11 | Pratt & Whitney Canada Corp. | Method and system for failure prediction using lubricating fluid analysis |
US12135317B2 (en) | 2012-10-26 | 2024-11-05 | Pratt & Whitney Canada Corp. | Method and system for failure prediction using lubricating fluid analysis |
US10240549B2 (en) | 2017-01-04 | 2019-03-26 | Honeywell International Inc. | System and method for evaluating chip zap data |
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