WO1985001071A1 - Method for the deposition of a coating - Google Patents
Method for the deposition of a coating Download PDFInfo
- Publication number
- WO1985001071A1 WO1985001071A1 PCT/SU1983/000030 SU8300030W WO8501071A1 WO 1985001071 A1 WO1985001071 A1 WO 1985001071A1 SU 8300030 W SU8300030 W SU 8300030W WO 8501071 A1 WO8501071 A1 WO 8501071A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- сђс
- cutting tool
- temperature
- carbide
- fact
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 18
- 239000011248 coating agent Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 10
- 230000008021 deposition Effects 0.000 title 1
- 239000000463 material Substances 0.000 claims abstract description 52
- 238000005520 cutting process Methods 0.000 claims abstract description 25
- 238000001704 evaporation Methods 0.000 claims abstract description 13
- 238000010891 electric arc Methods 0.000 claims abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 229910045601 alloy Inorganic materials 0.000 claims description 11
- 239000000956 alloy Substances 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000005255 carburizing Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000003082 abrasive agent Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 7
- 150000002500 ions Chemical class 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract 4
- 238000000151 deposition Methods 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 22
- 239000000203 mixture Substances 0.000 description 15
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 238000003763 carbonization Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- QDZRBIRIPNZRSG-UHFFFAOYSA-N titanium nitrate Chemical compound [O-][N+](=O)O[Ti](O[N+]([O-])=O)(O[N+]([O-])=O)O[N+]([O-])=O QDZRBIRIPNZRSG-UHFFFAOYSA-N 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- QIJNJJZPYXGIQM-UHFFFAOYSA-N 1lambda4,2lambda4-dimolybdacyclopropa-1,2,3-triene Chemical compound [Mo]=C=[Mo] QIJNJJZPYXGIQM-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 229910039444 MoC Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910002110 ceramic alloy Inorganic materials 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 210000004180 plasmocyte Anatomy 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000008207 working material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/021—Cleaning or etching treatments
- C23C14/022—Cleaning or etching treatments by means of bombardment with energetic particles or radiation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
- C23C10/06—Solid state diffusion of only metal elements or silicon into metallic material surfaces using gases
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/32—Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
- C23C14/325—Electric arc evaporation
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/54—Controlling or regulating the coating process
- C23C14/541—Heating or cooling of the substrates
Definitions
- the temperature of the reaction of carbidization would be 500-540 ° C, and this as a material for the cutting tool used steel.
- the temperature of the carbidization reaction would be equal to 620-680°C, ⁇ vaya hard alloy.
- titanium nitride as an evaporating carbon base material.
- a titanium alloy be used as a vaporizable carbide base material.
- the resulting invention allows to stabilize the composition of the formation of the thickness, which reduces the technical process of its application. Otherwise, the present invention excludes the risk of an explosion safety situation.
- the best variant of the existence of the invention material consists in evaporating the carbide-bearing material in a vacuum with an arc discharge and applying voltage to the cutting tool. P ⁇ - ⁇ m they clean and warm up the working air of the cutting tool of the ka ⁇ day b ⁇ mbardpr ⁇ v ⁇ y and karbidization reaction temperature running tool. Then we vaporize the ⁇ carbid ⁇ - ⁇ brazcheg ⁇ material ⁇ yadensi ⁇ yu ⁇ at the working ⁇ ve ⁇ - n ⁇ st and ⁇ sya ⁇ vy ⁇ ezhushchego iyas ⁇ rumenta d ⁇ ⁇ braz ⁇ vania ⁇ - shelters.
- ⁇ -5 - carbide of the building material is used titanium.
- Titanium was used as a vaporized carbide-forming material, and as a material, steel of the following composition was used:
- the coating was applied to the cutting inserts.
- a hard alloy of the following composition was used:
- the application of the penetration is similar to example I, with the exception of ⁇ g ⁇ , which is to clean the working surface of the plates of the bottom bombardi ⁇ v ⁇ ⁇ th and ⁇ nage of titanium pr ⁇ v ⁇ dizh with its heating up to a temperature of 620°C.
- Tests were carried out on five slabs for each batch in the following modes: cutting speed V - 160 m/min; ⁇ dacha ⁇ -0.3 mm/ ⁇ b; cutting depth I - I mm.
- Titanium nitrate is used as a vaporizable carbon fiber material
- steel is used as a core material in Example I.
- the working surface of the drills of the cataract b ⁇ mbardi ⁇ v ⁇ y and ⁇ nami nitrida ⁇ ita with ⁇ dn ⁇ temporary and temperature 5 ⁇ 0° ⁇ .
- the voltage was syaizhazh d ⁇ 300 V and in the course of ⁇ réelle ⁇ minutes there was a ⁇ nden ⁇ atshchya and ⁇ n ⁇ v ni ⁇ tita n ⁇ t on the working load drill, s ⁇ pr ⁇ v ⁇ awaiting him by carbidization with carbon steel.
- the thickness of the coating representing titanium carbide (N C) was 2 ⁇ m.
- a titanium alloy of the following composition is used:
- Titanium alloy was used as the vaporized carbide-forming material, with teriala ⁇ sn ⁇ vy ⁇ hard alloy, making up ⁇ g ⁇ privedey in example 2.
- the application of the hole is similar to the example, with the exception of ⁇ g ⁇ , which is to clean the working surface of the drills of the bottom bomber ⁇ with titanium, aluminum and molybdenum pr ⁇ even with a daytime heating up to a temperature of 650 ° ⁇ .
- Example 7 Application of the application on twist drills ⁇ 5 mm.
- Example 8 Coating coating on cutting plates.
- composition ⁇ Example 2 ⁇ stzh plates may exist up to a temperature of 680°C. Testing of plates is also similar to example 2. The test results are shown in Table 8.
- test results given in the example 1,2,3,4,5,6,7,8 st ⁇ - -II- typical characteristics of drills.
- the total invention allows to increase the rate of closure with a rate of 0.1-0.7 m ⁇ m/min, which reduces the time of the technical ⁇ g ⁇ cycle.
- This invention can be successfully used to obtain here the melting of wear and tear on the cutting tool, burnt from any materials containing carbon in its composition, such as experience, hard alloys, ceramic alloys and others.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
- Drilling Tools (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Food-Manufacturing Devices (AREA)
- Materials For Medical Uses (AREA)
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19833390523 DE3390523C2 (de) | 1983-08-25 | 1983-08-25 | Verfahren zum Auftragen einer Beschichtung auf dieOberfl{che eines spanenden Werkzeugs |
CH1660/85A CH666054A5 (de) | 1983-08-25 | 1983-08-25 | Verfahren zum beschichten eines werkzeuges, insbesondere eines spanenden werkzeuges. |
PCT/SU1983/000030 WO1985001071A1 (en) | 1983-08-25 | 1983-08-25 | Method for the deposition of a coating |
AT0908483A AT382892B (de) | 1983-08-25 | 1983-08-25 | Verfahren zum auftragen einer beschichtung |
JP83503277A JPS60502110A (ja) | 1983-08-25 | 1983-08-25 | 被膜塗布方法 |
BR8307748A BR8307748A (pt) | 1983-08-25 | 1983-08-25 | Processo para aplicacao de revestimento predominantemente em ferramentas de corte |
NL8320315A NL8320315A (nl) | 1983-08-25 | 1983-08-25 | Werkwijze voor het aanbrengen van een bekleding. |
GB08508273A GB2155044B (en) | 1983-08-25 | 1983-08-25 | Method for the deposition of a coating |
AU20735/83A AU559857B2 (en) | 1983-08-25 | 1983-08-25 | Method for the deposition of a coating |
FR8321028A FR2557595B1 (fr) | 1983-08-25 | 1983-12-29 | Procede de depot de revetements et revetements obtenus par ledit procede |
CA000444620A CA1216252A (en) | 1983-08-25 | 1984-01-04 | Coating application method |
SE8501521A SE454705B (sv) | 1983-08-25 | 1985-03-27 | Forfarande for paforande av en beleggning medelst ljusbagsforangning i vakuum |
DK159385A DK159385D0 (da) | 1983-08-25 | 1985-04-09 | Fremgangsmaade til paafoering af et overtraek paa et basisemne |
FI851485A FI80296C (fi) | 1983-08-25 | 1985-04-12 | Foerfarande foer paofoerande av ett oeverdrag i synnerhet pao skaerverktyg. |
NO851558A NO851558L (no) | 1983-08-25 | 1985-04-18 | Paafoering av et belegg paa skjaereverktoey. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/SU1983/000030 WO1985001071A1 (en) | 1983-08-25 | 1983-08-25 | Method for the deposition of a coating |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1985001071A1 true WO1985001071A1 (en) | 1985-03-14 |
Family
ID=21616808
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SU1983/000030 WO1985001071A1 (en) | 1983-08-25 | 1983-08-25 | Method for the deposition of a coating |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS60502110A (fi) |
AT (1) | AT382892B (fi) |
AU (1) | AU559857B2 (fi) |
BR (1) | BR8307748A (fi) |
CA (1) | CA1216252A (fi) |
CH (1) | CH666054A5 (fi) |
DE (1) | DE3390523C2 (fi) |
DK (1) | DK159385D0 (fi) |
FI (1) | FI80296C (fi) |
FR (1) | FR2557595B1 (fi) |
GB (1) | GB2155044B (fi) |
NL (1) | NL8320315A (fi) |
NO (1) | NO851558L (fi) |
SE (1) | SE454705B (fi) |
WO (1) | WO1985001071A1 (fi) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002002844A3 (en) * | 2000-06-30 | 2002-05-02 | Saint Gobain Abrasives Inc | Process for coating superabrasive particles with metal |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH669347A5 (fi) * | 1986-05-28 | 1989-03-15 | Vni Instrument Inst | |
CH671238A5 (fi) * | 1986-11-06 | 1989-08-15 | Vni Instrument Inst | |
AT388394B (de) * | 1987-01-09 | 1989-06-12 | Vni Instrument Inst | Verfahren zur herstellung von schneidwerkzeug |
FR2609726B1 (fr) * | 1987-01-20 | 1989-05-26 | Instr I | Procede de fabrication d'outils de coupe |
EP0404973A1 (de) * | 1989-06-27 | 1991-01-02 | Hauzer Holding B.V. | Verfahren und Vorrichtung zur Beschichtung von Substraten |
DE59004614D1 (de) * | 1989-06-27 | 1994-03-24 | Hauzer Holding | Verfahren und vorrichtung zur beschichtung von substraten. |
PL2236641T3 (pl) * | 2009-03-30 | 2012-05-31 | Oerlikon Trading Ag | Sposób wstępnej obróbki podłoży w procesie PVD |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2284408A1 (fr) * | 1974-09-11 | 1976-04-09 | Engel Niels | Outil de coupe en acier et son procede de realisation |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3428546A (en) * | 1966-09-27 | 1969-02-18 | Atomic Energy Commission | Apparatus for vacuum deposition on a negatively biased substrate |
US3882579A (en) * | 1972-03-13 | 1975-05-13 | Granville Phillips Co | Anti-wear thin film coatings and method for making same |
US3912826A (en) * | 1972-08-21 | 1975-10-14 | Airco Inc | Method of physical vapor deposition |
US4163071A (en) * | 1977-07-05 | 1979-07-31 | Union Carbide Corp | Method for forming hard wear-resistant coatings |
JPS5462183A (en) * | 1977-10-26 | 1979-05-18 | Seiko Epson Corp | Outside parts for pocket watch |
DE3030149C3 (de) * | 1979-08-09 | 1996-12-19 | Mitsubishi Materials Corp | Schneidplättchen und Verfahren zu seiner Herstellung |
-
1983
- 1983-08-25 GB GB08508273A patent/GB2155044B/en not_active Expired
- 1983-08-25 DE DE19833390523 patent/DE3390523C2/de not_active Expired - Lifetime
- 1983-08-25 CH CH1660/85A patent/CH666054A5/de not_active IP Right Cessation
- 1983-08-25 JP JP83503277A patent/JPS60502110A/ja active Pending
- 1983-08-25 BR BR8307748A patent/BR8307748A/pt not_active IP Right Cessation
- 1983-08-25 WO PCT/SU1983/000030 patent/WO1985001071A1/ru active IP Right Grant
- 1983-08-25 AT AT0908483A patent/AT382892B/de not_active IP Right Cessation
- 1983-08-25 AU AU20735/83A patent/AU559857B2/en not_active Ceased
- 1983-08-25 NL NL8320315A patent/NL8320315A/nl not_active Application Discontinuation
- 1983-12-29 FR FR8321028A patent/FR2557595B1/fr not_active Expired
-
1984
- 1984-01-04 CA CA000444620A patent/CA1216252A/en not_active Expired
-
1985
- 1985-03-27 SE SE8501521A patent/SE454705B/sv not_active IP Right Cessation
- 1985-04-09 DK DK159385A patent/DK159385D0/da not_active IP Right Cessation
- 1985-04-12 FI FI851485A patent/FI80296C/fi not_active IP Right Cessation
- 1985-04-18 NO NO851558A patent/NO851558L/no unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2284408A1 (fr) * | 1974-09-11 | 1976-04-09 | Engel Niels | Outil de coupe en acier et son procede de realisation |
Non-Patent Citations (2)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002002844A3 (en) * | 2000-06-30 | 2002-05-02 | Saint Gobain Abrasives Inc | Process for coating superabrasive particles with metal |
Also Published As
Publication number | Publication date |
---|---|
ATA908483A (de) | 1986-09-15 |
CA1216252A (en) | 1987-01-06 |
FI80296C (fi) | 1990-05-10 |
FI851485L (fi) | 1985-04-12 |
AU2073583A (en) | 1985-03-29 |
AT382892B (de) | 1987-04-27 |
CH666054A5 (de) | 1988-06-30 |
DE3390523C2 (de) | 1990-01-18 |
SE8501521D0 (sv) | 1985-03-27 |
DK159385A (da) | 1985-04-09 |
JPS60502110A (ja) | 1985-12-05 |
AU559857B2 (en) | 1987-03-19 |
SE8501521L (sv) | 1985-03-27 |
FI80296B (fi) | 1990-01-31 |
GB2155044A (en) | 1985-09-18 |
BR8307748A (pt) | 1985-07-02 |
GB2155044B (en) | 1987-11-18 |
FR2557595A1 (fr) | 1985-07-05 |
DE3390523T1 (de) | 1985-08-08 |
NL8320315A (nl) | 1985-07-01 |
FI851485A0 (fi) | 1985-04-12 |
FR2557595B1 (fr) | 1986-07-11 |
NO851558L (no) | 1985-04-18 |
SE454705B (sv) | 1988-05-24 |
DK159385D0 (da) | 1985-04-09 |
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