UST866035I4 - Defensive publication - Google Patents
Defensive publication Download PDFInfo
- Publication number
- UST866035I4 UST866035I4 US866035DH UST866035I4 US T866035 I4 UST866035 I4 US T866035I4 US 866035D H US866035D H US 866035DH US T866035 I4 UST866035 I4 US T866035I4
- Authority
- US
- United States
- Prior art keywords
- dione
- defensive publication
- cyclobutene
- hydroxy
- alkoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 silver halide Chemical class 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 2
- UCKCITHTMXTYNC-UHFFFAOYSA-N 1,2-diethoxycyclobutane Chemical compound CCOC1CCC1OCC UCKCITHTMXTYNC-UHFFFAOYSA-N 0.000 description 1
- DFSFLZCLKYZYRD-UHFFFAOYSA-N 3,4-diethoxycyclobut-3-ene-1,2-dione Chemical compound CCOC1=C(OCC)C(=O)C1=O DFSFLZCLKYZYRD-UHFFFAOYSA-N 0.000 description 1
- LOXKJXLULTVXGW-UHFFFAOYSA-N 3,4-dihydroxycyclobutane-1,2-dione Chemical compound OC1C(O)C(=O)C1=O LOXKJXLULTVXGW-UHFFFAOYSA-N 0.000 description 1
- MFYCMEJDDNEWSV-UHFFFAOYSA-N 3-bromo-4-phenylcyclobut-3-ene-1,2-dione Chemical compound O=C1C(=O)C(Br)=C1C1=CC=CC=C1 MFYCMEJDDNEWSV-UHFFFAOYSA-N 0.000 description 1
- YSWWAKJDYMKMGU-UHFFFAOYSA-N 3-hydroxy-4-phenylcyclobut-3-ene-1,2-dione Chemical compound O=C1C(=O)C(O)=C1C1=CC=CC=C1 YSWWAKJDYMKMGU-UHFFFAOYSA-N 0.000 description 1
- LCMBLCHIHPQQMN-UHFFFAOYSA-N 3-methoxy-4-phenylcyclobut-3-ene-1,2-dione Chemical compound O=C1C(=O)C(OC)=C1C1=CC=CC=C1 LCMBLCHIHPQQMN-UHFFFAOYSA-N 0.000 description 1
- 241000551547 Dione <red algae> Species 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- PWEBUXCTKOWPCW-UHFFFAOYSA-N squaric acid Chemical compound OC1=C(O)C(=O)C1=O PWEBUXCTKOWPCW-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
Definitions
- each R can be hydroxy, alkoxy or halogen and each R can be hydrogen, alkyl, aryl, hydroxy, alkoxy or halogen.
- a useful range for the concentration of the stabilizer is from about 0.5 gram to about 20 grams per mole of silver halide.
- suitable compounds include 3,4 dihydroxy 3 cyclobutene 1,2 dione, 3 methoxy- 4 phenyl 3 cyclobutene 1,2 dione, 3 hydroxy 4- phenyl 3 cyclobutene 1,2 dione, 3,4 diethoxy 3- cyclobutene 1,2 dione, 3,4 diethoxy cyclobutane 1,2/- dione, 3 bromo 4 phenyl 3 cyclobutene 1,2 dione, and 3,4-dihydroxycyclobutane-1,2-dione.
- Photographic silver halide emulsions and elements stabilized as described can be chemically sensitized, e.g., with noble metal sensitizers alone or in combination with sulfur or selenium sensitizers. They can contain spectral sensitizers, incorporated color forming couplers, incorporated developing agents, other antifoggants, hardeners, plasticizers, coating aids, and other suitable photographic addenda, such as described in US. Patent 3,297,446 (columns 4-9).
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
gt 3y DEFENSIVE PUBLICATION UNITED STATES PATENT OFFICE Published at the request of the applicant or owner in accordance with the Notice of Apr. 11, 1968, 849 0.6. 1221. men tiflcation is by serial number of the application and the heading indicates the number of pages of specification, including claims, and of sheets or drawing contained in the application as originally filed. The file of this application is available to the public for inspection; reproduction may be purchased for 30 cents per sheet.
Applications published under the Defensive Publication Program have not been examined as to the merits of alleged invention. The Patent Oiiice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED SEPTEMBER 30, 1969 866 CG. 1439 A U 4 4 822 017 CYCLIC DIONES AS EMULSION STABILIZERS AND ANTIFOGGANTS Dorothy J. Beavers, Kodak Park Division, Rochester, NY. 14650 Filed May 5, 1969. Published Sept. 30, 1969 Int. Cl. G03c 1/34, 1/86 US. C]. 96-85 No Drawing. 10 Pages Specification The stabilization against fog of photographic silver halide emulsions and elements is obtained through the use of cyclic diones wherein there are four carbon atoms in the ring. The stabilizing compounds contain at least one radical or atom selected from the group consisting of hydroxy, alkoxy and halogen. The useful compounds are represented by the following structural formulas:
wherein each R can be hydroxy, alkoxy or halogen and each R can be hydrogen, alkyl, aryl, hydroxy, alkoxy or halogen. A useful range for the concentration of the stabilizer is from about 0.5 gram to about 20 grams per mole of silver halide. Examples of suitable compounds include 3,4 dihydroxy 3 cyclobutene 1,2 dione, 3 methoxy- 4 phenyl 3 cyclobutene 1,2 dione, 3 hydroxy 4- phenyl 3 cyclobutene 1,2 dione, 3,4 diethoxy 3- cyclobutene 1,2 dione, 3,4 diethoxy cyclobutane 1,2/- dione, 3 bromo 4 phenyl 3 cyclobutene 1,2 dione, and 3,4-dihydroxycyclobutane-1,2-dione.
Photographic silver halide emulsions and elements stabilized as described can be chemically sensitized, e.g., with noble metal sensitizers alone or in combination with sulfur or selenium sensitizers. They can contain spectral sensitizers, incorporated color forming couplers, incorporated developing agents, other antifoggants, hardeners, plasticizers, coating aids, and other suitable photographic addenda, such as described in US. Patent 3,297,446 (columns 4-9).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82201769A | 1969-05-05 | 1969-05-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UST866035I4 true UST866035I4 (en) | 1969-09-30 |
Family
ID=25234890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US866035D Pending UST866035I4 (en) | 1969-05-05 | 1969-05-05 | Defensive publication |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | UST866035I4 (en) |
| BE (1) | BE742944A (en) |
| FR (1) | FR2046068A5 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2855997A1 (en) * | 1978-12-23 | 1980-07-10 | Agfa Gevaert Ag | PHOTOGRAPHIC RECORDING MATERIAL |
| GB9607503D0 (en) * | 1996-04-11 | 1996-06-12 | Merck Frosst Canada Inc | Bisaryl cyclobutenes derivatives as cyclooxygenase inhibitors |
| JP2008544743A (en) | 2005-05-10 | 2008-12-11 | インターミューン インコーポレイテッド | Pyridone derivatives for modulating the stress-activated protein kinase system |
| CA3034994A1 (en) | 2008-06-03 | 2009-12-10 | Intermune, Inc. | Substituted aryl-2 pyridone compounds and use thereof for treating inflammatory and fibrotic disorders |
| AR092742A1 (en) | 2012-10-02 | 2015-04-29 | Intermune Inc | ANTIFIBROTIC PYRIDINONES |
| WO2015153683A1 (en) | 2014-04-02 | 2015-10-08 | Intermune, Inc. | Anti-fibrotic pyridinones |
-
1969
- 1969-05-05 US US866035D patent/UST866035I4/en active Pending
- 1969-12-10 FR FR6942649A patent/FR2046068A5/en not_active Expired
- 1969-12-10 BE BE742944D patent/BE742944A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2046068A5 (en) | 1971-03-05 |
| BE742944A (en) | 1970-05-14 |
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