[go: up one dir, main page]

USRE19889E - Absorption refrigerating system - Google Patents

Absorption refrigerating system Download PDF

Info

Publication number
USRE19889E
USRE19889E US19889DE USRE19889E US RE19889 E USRE19889 E US RE19889E US 19889D E US19889D E US 19889DE US RE19889 E USRE19889 E US RE19889E
Authority
US
United States
Prior art keywords
evaporator
solution
resorber
gas
absorption
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Publication date
Application granted granted Critical
Publication of USRE19889E publication Critical patent/USRE19889E/en
Expired legal-status Critical Current

Links

Images

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B15/00Sorption machines, plants or systems, operating continuously, e.g. absorption type
    • F25B15/12Sorption machines, plants or systems, operating continuously, e.g. absorption type with resorber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/27Relating to heating, ventilation or air conditioning [HVAC] technologies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/62Absorption based systems

Definitions

  • Absorption systems in which inert gas is em- 5 ployed in the evaporator and the absorber are known.
  • One form of such systems is that in which a resorber is employed instead of a condenser.
  • a 10 resorption system is so arranged as to cause inert gas to circulate through parts of the system other than the evaporator and absorber.
  • certain desired results may be brought about by the use of multi-stage devices for carrying out the evaporation, absorption, generation or resorption steps inherent in every resorption refrigeration process.
  • an 4 T absorption refrigerating system may be freed from several limitations to which absorption apparatus which use a neutral. or inert gas are subject. The system can be adaptedreadily to a great variety of requirements in practice.
  • the present arrangement may use an absorption solution of the same concentration range for both steps, provided the temperature range and the refrigerant partial pressure zone are different for the two steps.
  • the presence of neutral gas in the resorber has the effect that the temperature range within which the absorption heat of the resorber is liberated is not only dependent upon the pressure and the change in concentration, as is the case in all resorption systems, but also upon the quantity of the neutral gas circulating through the resorber. Therefore, this temperature range can be varied within very wide limits by correspondingly regulating the amount of the gas circulation.
  • the resorber may be included in the circuit of the neutral gas between the evaporator and the absorber, preferably with the gas mixture discharged from the evaporotor traversing first the resorber and then the absorber.
  • the gas mixture circulation can in such a case be brought about with well known means, so that additional means for effecting the neutral gas circulation through the resorber are not necessary.
  • Fig. 1 schematically illustrates an absorption system in which one absorber and one evaporator are connected by an inert gas circuit, and one resorber and one generator are connected by another inert gas circuit;
  • Fig. 2 shows schematically an absorption refrigerating system in which the refrigerant vapor developed in the generator passes first into a condenser, and the condensate passes into a primary evaporator, and in which this primary evaporator and a resorber on one hand, and the absorber and a secondary evaporator on the other' circuits;
  • Fig. 3' shows schematically an absorption re-- frigerating system having a. generator, an absorber, and two resorbers, and two evaporators, and in which one resorber is connected with the generator, the other resorber-with one of the two lines, and
  • Fig. 4 schematically shows an absorption refrigerating system having a generator, two resorbers, one evaporator and one absorberQand in which the evaporator is connected with the two resorbers in one circuit for the absorption solu-, tion, and the absorber, the evaporator and one of the two resorbers, are connected by an inert gas circuit.
  • Fig. 6 shows the absorption refrigerating system shown in Fig. 4 in an arrangement in which the diiferent vessels'and their connections approach more closely the practical form of such a machine.
  • the sulphuric acid absorption solution extensively freed from the water, in flowing from the generator K to the absorber A, interchanges its heat with the solution enriched by working medium flowing from the absorber to the generator.
  • the evaporator is likewise in heat interchange with the solution returning from the evaporator to the absorber.
  • the indication of the heat .inter-w change in the circulation systems of the gas mixture has been omitted in the drawings for the Such a system operates in the following inan'- ner.
  • the sulphuric acid concentrated by the evaporation then reachesthe absorber 'A.
  • the heat of absorption is discharged by cooling water or air.
  • the total pressure may be different or the same in the two gas mixture circulating systems. If the total pressure is different, this diiference in pressure may be maintained ,by liquid columns.
  • the refrigerant is absorbed from the inert gas by the solution in the resorber R at the partial pressure determined by its temperature and re-evaporated from the solution inthesame concentration range into the inert gas in evaporator E in a zone of low refrigerant partial pressure.
  • the gas generated in the generator K is introduced into inert gas mixture at a refrigerant pressure corresponding with the zone of refrigerant, partial pressure of the resorber R.
  • the scope of utility of the invention is increased, if a third (higher) pressure or partial pressure zone is provided, at which the refrigerant or working medium is evaporated and condensed.
  • the condensation may take place in thiszoneof highest pressure eitherby pure condensation orby absorption in a solution, and this pressure zone may or may not be maintained by inert gas.
  • the resorber solution then performs a cycle, in. which it passes in succession into the temperature range of the production of coldfievaporator E) and into the temperature of the heat discharge to the surroundings (reg men) while coming twice in contact with the neutral gas, and this is a dominant characteristic of the .which'it has already produced cold once, so that v the working medium generated by a definite ex-'
  • the working medium, Figures 2 to 6, is assumed to be ammonia and the solvent water.
  • the ammonia is generated in the generator K by the application of heat and passes into the condenser C. It is there condensed under discharge of heat and then passes (dashed line) into the primary evaporator V, where it evaporates into the gas .mixture circulating (dash-dot line) between the resorber R and the primary evaporator V under production of cold in the latter. From the gas mixture the working medium is again absorbed in the resorber R, under renewed discharge of absorption heat by the resorber. The solution thus enriched circulates between the secondary evaporator E and the resorber R.
  • Figure 2 consists of two stages of evaporation .and accordingly may be referred to as a multl-stage system.
  • evaporators V and E
  • the refrigerant evaporates into inert gas.
  • Two separate independent inert gas circuits balance the diiierences in refrigerant'partial pressure between the high (generator K and condenser C) intermediate (evaporator V and resorber R) and low (evaporator E and absorber A) sides of the system.
  • the cycles of circulation of the liquids may be so combined, that all three partial pressure zones are traversed by the solution which circulates between two temperature ranges.
  • Fig. 3 of the drawings show an example of this system.
  • Fig. 3 also diiiers from Fig. 2 in the use of a second resorber (R), insteadoi' a condenser and in the addition of a third inert gas circuit between the generator and the second resorber.
  • the refrigerant pressure in the boiler K and resorber R is high, that in the evaporator E, and resorber R2 intermediate and that in-the evaporator E2 and absorber A low.
  • Ammonia is assumed to be used as working medium, water as solvent and nitrogen as inert gas in all three gas cycles of circulation.
  • the gas circulation systems may be equalized in pressure by interconnecting means.
  • the solution in thelatter resorber is able to do this, since after traversing the evaporator E1 it first passes into the evaporator 1511', where by means of a gas circulation connebtcd with-the absorber A it is freed of gas to a large extent at a low partial pressure, so that it enters the resorber R2 at a low concentration. From the resorber R2 the solution returns into the resorber R1, where it receives ammonia from the generator K.
  • a pressure may prevail in the entire system considerably lower than that which corresponds with the vapor pressure of the pure ammonia. This pressure may, on the other hand, be substantially exceeded. Particularly when a high pressure prevails it may be necessary to make the quantity of the solution circulating between the resorber R1 and the evaporator E1 smaller than the quantity of solution circulating between the resorber R2 and the evaporator E2.
  • a branch leading from the pipe connecting resorber R2 and R1 to the pipe which connects evaporators E1 and E2, shown 111 Fig. 3
  • this requirement may be met in a simple manner.
  • a portion of the solution then returns into the evaporator Ez immediately after it leaves resorber R2, while the remaining portion of the solution traverses resorber R1 and the evaporator E1.
  • Two of the separate gas cycles in Fig. 3, may be combined into a single gas circuit.
  • a combination of the evaporator E1 with the evaporator E2 is also possible. If the use of inert gas in the high pressure zone is omitted, that is between the generator K and the resorber R1, a particular-ly simple embodiment of my invention is obtained, which is illustrated in Fig. 4 of the drawings. From the solution circulating between the absorber A and the generator K the ammonia is expelled in the generator K by the application of heat, and passes into the resorber R1, (dotted line) where it is absorbed by a solution, which has already absorbed ammonia from gas mixture in the resorber R2.
  • the solution thus further enriched in the resorber R1 passes into the evaporator E which is shown comparativeiy'long in order to indicate the combination of two evaporators.
  • the solution after being extensively freed in this evaporator from ammonia which evaporates into the gas mixture coming fromthe absorber A, now passes into theresorber Ra, where it again absorbs ammonia from the gas mixture, and thence returns into the resorber R1, where the further concentration takes place in the absence of inert gas, and commences its cycle anew.
  • the gas mixture arrives in evaporator E from absorber A with low ammonia partial pressure, assumes in the evaporator E an am-- monia partial pressure, which when the mixture leaves the evaporator corresponds with that of the intermediate partial pressure zone, and then gives oif a portion of its admixed ammonia in the resorber R: to the solution contained therein and loses the remainder in the absorber A in the low ammonia partial pressure zone.
  • the absorber A and the resorbers R1 and R it is necessary to discharge heat.
  • the evaporator E the cold is produced.
  • Fig. 6 The apparatus which is only schematicallyv illustrated in Fig.4 of the drawings, is shown in Fig. 6 in a structural form which approximates, more or'less, its actual execution, so far as the relative location of elements and their general structural character and physical connection are concerned.
  • the ammonia expelled from an aqueous ammonia solution in the generator, boiler or still I by means of a heating element 2, ascends in the pipe 3 in gaseous form together with the weak solution into the gas separator or rectifier 4, which is located at such an elevation that the discharge of the solution through the pipe 5 into the absorber 6 commences before the pressure necessary for operating the nozzle I9 exists.
  • the solution returning from the absorber 6 through the pipe 22 to the generator or boiler l forms, together with the pipe 5, a heat interchanger.
  • the expelled gaseous ammonia separates in the gas separator 4 from the solution and passes through the pipe i into the rising leg of the U-shaped pipe 8 coming from the gas filled resorber 9, terminating in this pipe 8 at a level, which suflices' for creating an appreciable liquid head in pipe 8 above this entry point to raise (by the gas from pipe 'I) the liquid in pipe 8 in the direction or the arrow, from the level of resorber 9. Also the liquid pressure at this level creates the back pressure necessary ior operat-.
  • the gaseous ammonia thus raises the solution coming from the second resorber it (R1 in Fig. 4) 'to the first resorber 23 (R1 in Fig. 4) not participating in the gas mixture circulation, this latter resorber being cooled by cooling jacket 24.
  • the gaseous ammonia thus first raises the solution and is absorbed by this solution when it reachesthe resorber 23.
  • the absorption solution enriched in this way passes into the gas separator III, in which any non-absorbed residues of gas separate from the liquid, and then flows through the pipe ll into the evaporator l2, in
  • the gas mixture partially freed from ammonia in the resorber 9 flows thence through pipe l6 into the absorber 6, in which the absorption solution drips down over the pipe coil I'l traversed by cooling water.
  • the gas mixture ascends in the absorber 6 in counter-flow to the absorption'soiution and gives up further ammonia to the cooled absorp tion solution.
  • the gas mixture now flows through the pipe i3 into the evaporator l2, enters at the bottom, and rises in counterfiowto the rich solution dripping down in the evaporator,
  • the nozzle I9 is located in the pipe I4 leading from the evaporator to the resorber 9, so that .the gas employed for bringing about the gas circulation is not lost for the refrigerating action. Small quantities of the solvent are carried from the absorber system into the resorber system. In order to return these surplus quantities a pipe 2
  • FIG. 5 of the drawings illustrate schematically such a system designed for an increased cold t output without neutral gas admixture in the generator K'and resorber R: of the high partial pressure stage, and with a single gas mixture circulation through the evaporator E, the resorber R1 and the absorber A.
  • the absorption solution flows here from the generator K first to the absorber A, thence into resorber R1, thence into resorber R2, thence into the evaporator E and finally back into the generator K.
  • Refrigerant gas generated in K flows to the resorber R2.
  • the resorber R1 may operate under an intermediate or mean refrigerant partial pressure-while the absorber A operates under a low refrigerant partial pressure.
  • the pressure difterence may be maintained by hydrostatic columns and the pressure diiierence may be utilized tobring about the circulation of the gas combined into a common vessel.
  • the absorber A and the resorber R1 may easily be In order that the intended success of the saving of heat may be realized in the practical execution of this-re- .'conditions it is advantageous to subdivide the 1 solution, which flows through the evaporator E and the resorbers R1 and R: by means of interconnections so thatv a smaller quantity circulates within the range of the stronger concentration of the solution.
  • the gas circulation may 'by transverse connections, be quantitatively adapted to the prevailing demand in the various partial pressure zones. All the necessary sizes and quantities may be calculated from the data further explanations appear unnecessary.
  • the gas circuits may either individually or in groups be united to a common circuit through various absorption or evaporation chambers. If three pressure. zones exist, two inert gas currents are necone portion ofthe evaporator, and the other between the other portion of the evaporator and one pcrtionof the resorber. This case is illustrated in Fig. 2 of the drawings.
  • the two separate gas circuits may be combined into a single circuit, which then has two dfierent partial pressure zones, regardless of whether the cycles of liquid circulation are combined or not. This case is illustrated in Figs. 4, ,5 and 6.-
  • inert gas circulation takes place between a chamber to which heat is supplied at a high temperature and a chamber in which heat is discharged at a medium or intermediate temperature.
  • gas mixture circulate in counter-flow to the solution in all chambers in which the working medium evaporates or is absorbed.
  • the counter-flow brings about a considerable improvement, however, particularlyin cases in which the temperature ranges is not extensive, so that it is advisable to make use of it wherever possible.
  • the gas may be circulated by any known means.
  • the gas circulation and the liquid circulation may simultaneously be caused in a very effective manner, and the latter may be rendered so eflicient, that for the chambers, in which the interchange of the working me- ,dium between gas and solution occurs, a pressure head exists.
  • Two evaporator temperatures are ad vantageous, for example, in refrigerating cabinets, where the cooling of the refrigerating chamher to a temperature between 2 and 4 C. suflices, but 'for the production of ice a temperature of at least -5 C. must be produced in the evaporator.
  • One evaporator may'then operate at --8 C. and the other at 0 C. i v
  • the process which consists in evaporating the working medium from a portion of. an absorption solution of a certan concentration range into an inert gas mixture within a certain temperature range and a first partial pressure zone, and reabsorbing it from said gas mixture by another portion of said absorption solution of the same concentration range as the first portion, but'within another temperature range and a second partial pressure zone, and expelling the working medium from a solution and returning it into its liquid phase in a third pa'rtial pressure zone, the second partial pressure, at which the working medium is absorbed from gas mixture, by
  • the aforementioned solution portion of equal concentration range being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partialpressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture.
  • the second pressure at which the working medium is absorbed from the gas mixture by the'aforementioned solution portion of equal concentration range being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partial pressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture, the two solution portions of equal concentration range performing a cycle of circulation in which they pass successively through the low and the medium temperature range.
  • an absorption solution for said connections with said evaporator and having means for receiving lean solution for absorbing gaseous medium delivered from said'evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting the absorption solution of the first-mentioned concentration range to circulate, additional circulating pipe connections between said resorber and said evaporator permitting circulation of solution of the second named concentration range between said two vessels, the evaporation of gaseous medium from absorption solution oi!
  • an absorption solution for said medium and an inert gas not absorbable by said solution comprising a generator for developing gaseous medium from solution of a certain concentration range, a resorber divided into two separate sections andconnected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber, having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said solution
  • an absorption machine containing a working medium an absorption solution for said medium, an an inert gas not absorbable by said solution, and comprising a generator for developinggaseous medium fromsolution of a certain separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained .therein, an evaporator having a liquid of said resorber to permit evaporation of gaseous medium in the evaporator from the solution de- "livered to it from the first resorber section, a.
  • second resorber section to permit the absorption in the latter of some of the gaseous medium gas connections with said evaporator and hav- -ing means'for receiving lean solution for absorbing the remainder of the gaseous medium de- 75 livered from said evaporator to form a solution of first named concentration range, whereby a closed concentration range, a resorber divided into two circulating conduit connection with both sections a gas connection between said evaporator and the evaporated in the evaporator, an absorber having the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between said second re
  • a generator for developing gaseous medium from solution of a certain concentration range a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connecting with both s ec-' tions of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section,
  • I a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes.
  • an absorption solution for said medium and an inert gas not absorbable by said solution comprising a generator for developing gaseous medium from solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber sectained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous 'medium in the evaporator from the solution delivered to it from the first resorber section, a gas 1 connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range,
  • an absorption solution for said contained therein an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder.
  • an absorption solution for said medium and an inert gas not absorbable by said solution comprising a generator for developing gase'ousmedium from solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorbersece tion for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of'some of the gaseous medium evaporated in the evaporator, an absorber having ga's connections with said evaporator and having meansfor receiving lean solution for absorbing the remainder of gase
  • tioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said'absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between nection having a nozzle terminating in one of said gas mixture conduits for setting the gas mix ture in motion.
  • an absorption machine containing a working medium, an absorption solution for said medium, and an inert gas not absorbable by said solution, and comprising a generator for developing gaseous medium from-solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the'solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some 0!
  • an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and 'the absorber, the evaporation or said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption oi!
  • the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between the resorber section containing inert gas and some of the other vessels, including the evaporator, in which absorption solutions come in contact with said inert gas, for permitting circulation of the inert gas through said resorber section and the evaporator, and a pipe connection for conducting pure gaseous medium developed by said generator, at a pressure and temperature higher than those prevailing in the gas mixture circuit, into said mixture circuit, said pipe connection having a nozzle terminating in the gas mixture conduit at the point where the mixture emanates from the evaporator, whereby the gas mixture is set in motion in the direction toward the second resorber section'and the pure gas supplied by said pipe isadmixed to the gas mixture and returned into the cycle of the,operating medium through the evaporator and the two resorber sections, and the absorber.
  • an absorption solution for said medium and an inert gas not absorbable by said solution comprising a generator for developinggaseous medium from solution of a certain concentration range, a resorber divided into two separate sections connected by liquid conduits and containing in both ,sections a solution of another concentration range.
  • liquid circulating conduit to permit the lifting of said second range solution to said first-named resorber section by means of gas bubbles developed in said generator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the gaseous medium delivered from said evaporator to form a solution of the first-named concentration range, whereby aclosed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in said evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in the second-named resorber section also in the presence 01' inert gas.
  • the process which consists in evaporating the working medium from a portion 01' an absorption solution of a certain concentration range into an inert gas mixture within a certain temperature range and a first partial pressure zone, and reabsorbing it from said gas mixture by another portion of said absorption solution of the same concentration range as the first portion, but within another temperature range and a second'partial pressure zone, and expelling the working medium from a solution and returning it into its liquid phase in a third partial pressure zone and within a third temperature range, the second partial pressure, at which the working medium is absorbed from gas mixture by the aforementioned solution portion of equal concentration range, being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partial pressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture.
  • a continuous absorption refrigerating system using an inert gas the combination of a number of inter-connected vessels, including an-evaporator, an absorber, a'generator and a plurality of devices for changing refrigerant from a gaseous phase to a more dense fluid phase, and means for circulating inert gas through the evap orator, the absorber and one of said devices.
  • connected vessels including a plurality of evaporators forming a low refrigerant pressure side of the system, means for circulating inert gas through the vessels constituting the low pressure side of the system and means for circulating inert gas through the vessels constituting the high pressure side of the system.
  • an evaporator In a continuous absorption refrigerating system, an evaporator, an absorber, a generator, a resorberand means for circulating inert gas between the generator and resorber.
  • an evaporator In a continuous absorption refrigerating system, an evaporator, an absorber, a resorber and means for circulating inert gas in a single circuit through said evaporator, absorber and resorber.
  • an evaporator In a continuous absorption refrigerating/- system, an evaporator, an absorber, two resorbers and means for maintaining inert gas in ones of said resorbers.
  • a multi-stage evaporation system comprising a plurality of evaporators having inert gas therein, an equal number of absorbing devices having inert gas therein for absorbing refrigerant gas evolved in the evaporators, and inert gas and absorption liquid circulating means so connected to said evaporators and devices as to enable refrigerant to pass through said evaporators and devices alternately in series and evaporate into inert gas in each evaporator and be absorbed out of inert gas in each absorbing device.
  • a multi-stage device for carrying out one of the steps of'said cycle and comprising a plurality of inter-connected vessels adapted to operate at different refrigerant pressures and means providing independent inert gas circuits through said vessels for maintaining different refrigerant pressures in said vessels.
  • the absorption process of continuously producing refrigeration which comprises a cycle which includes the steps of heating a solution of absorbent and refrigerant to expel the refrigerant in gaseous phase, cooling the gaseous refrigerant so formed to change it to a more dense fluid phase, conveying the refrigerant in the more dense fluid phase into the presenceof an inert gas to cause it to evaporate to produce.
  • a cooling effect conveying the mixture of inert gas and refrigerant gas into thepresence of an absorbent, cooling the gases and absorbent to cause effect, again conveying the mixture of inert gas and refrigerant gas into the presence of absorbent, cooling the mixture and absorbent to cause therefrigerant to again be absorbed and again heating the solution so formed to complete the cycle.
  • An absorption refrigerating system including a generator, an absorber, a plurality of evaporators and a resorber for each evaporator,
  • An absorption refrigerating system includ- Y ing a resorber, two evaporators, means for circuto permit circulation of indiiferent gas through lating solution through said resorber and said evaporators, two separate inert gas circuits, one for each of said evaporator-s, and means for maintaining a difference in the refrigerant partial pressures in the two evaporators.
  • a generator In a continuous absorption refrigerating system of the type in which an inert gas is employed, a generator, a resorber, an evaporator, an absorber, means for causing a refrigerant to pass throughsaid elements in the order named, means for circulating inert gas through said evaporator and said absorber and means for causing the resorber to operate over a different range of solution concentration than the range in said evaporator.
  • absorber means for causing a. refrigerant to pass 7 through 'said elements in the'order named, means for circulating inert gas through said evaporator and said absorber and means for causing the resorber to operate over a. different range of solution concentration than therangein said evaporator, said last mentioned means including 'a second evaporator, a second resorber and an arrangement [for circulating inert J gas between them.
  • An absorption machine for the production of heat of high temperature containing a generator, an absorber, an evaporator aresorber, connecting pipes between said vessels to permit circulation of absorption solution through them, the gaseous working medium in said vesselshaving an indiiferent gas admixed to it, and further connecting pipes between the said vessels said generator, resorber, absorber and evaporator.
  • a continuous absorption refrigerating system including a generator, an absorber, an evaporator, a device for changing gaseous refrigerant to a more dense fluid phase and means for circulating inert gas between said evaporator and 50 said device.
  • a continuous absorption refrigerating system having a number of interconnected elements including a boiler, a condenser, a flrst evaporator, a resorber, a second evaporator, an absorber, means for causing refrigerant to pass in a cycle through said elements in the order recited and means for circulating inert gas through certain of said elements.
  • a heat transfer process which includes the steps of causing a working medium to pass in a continuous cycle through a number of interconnected vessels, applying heat to certain of said vessels, cooling others of said vessels and circulating inert gas through certain of said vessels to cause the working medium to be evolved from a liquid, as a gas and then changed from its gaseous phase to a more dense fluid phase, successively at least three times.
  • an evaporator In a continuous absorption refrigerating system, an evaporator, a plurality of resorbers, a generator, an absorber, means for circulating inort gas through certain of said vessels and means for circulating absorption solutions in series through two resorbers and said evaporator.
  • a generator for expelling refrigerant from an absorption solution an absorber, means for circulating inert gas through the absorber, means for passing refrigerant expelled in the generator directly to said absorber, means for circulating absorption solution through said absorber to cause the refrigerant delivered thereto from thegenerator tobe absorbed in the absorber and means for causing the generator to operate over a different solution concentrationrange than that over whichthe absorber operates.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Sorption Type Refrigeration Machines (AREA)

Description

March 17, 1936. E, ALTENKIRCH ABSORPTION REFRIGERATING SYSTEM Original Filed June 8, 1929v Edmund iliemfgf h' Gttorncg Reissued Mar. 17, 1936 PATENT OFFICE 19,889 ABSORPTION REFRIGERATING SYSTEM Edmund Altenkirch, Neuenhagen, near Berlin, Germany, assignor, by mesne assignments, to The Hoover Company, North Canton, Ohio, a
corporation of Ohio Original No. 1,887,957, datedNovember 15, 1932, Serial No. 369,358, June 8, 1929. Application for reissue September 28, 1934, Serial No" 745,929. In Germany June 16, 1928 ing systems and more particularly to systems usin inert gas.
Absorption systems in which inert gas is em- 5 ployed in the evaporator and the absorber are known. One form of such systems is that in which a resorber is employed instead of a condenser. In accordance with the present invention, a 10 resorption system is so arranged as to cause inert gas to circulate through parts of the system other than the evaporator and absorber.
In the copending application for the reissue of applicant's Patent No. 1,887,909, resorber sys- 15 tems in which inert gas is circulated through a generator are disclosed and particularly claimed. The present case is more concerned with systems in which inert gas is circulated through a resorber, although certain of the claims are generic to the features of Patent 1,887,909.
Under certain conditions, it is desirable to operate an absorption refrigerating system with the boiler and resorber at a relatively low temperature. This is advantageous where high temperatures may cause corrosion or where a cheap source of low temperature heat is available. It is one object of the invention to provide a system capable of operating under these conditions, although it may result, in certain instances, in a decrease in the thermal operating emciency from that which could be obtained were the boiler and resorber operated at higher tempera tures.
It is another object bf theinventionto provide an arrangement for improving the capacity, efii-' cie'ncy, quantity of heat input or other operating -characteristics of a resorption refrigerating system. As will be explained hereinafter, certain desired results may be brought about by the use of multi-stage devices for carrying out the evaporation, absorption, generation or resorption steps inherent in every resorption refrigeration process. In accordance with the present invention, an 4 T absorption refrigerating system may be freed from several limitations to which absorption apparatus which use a neutral. or inert gas are subject. The system can be adaptedreadily to a great variety of requirements in practice. While in the prior art absorption devices, the absorption= solution from which the operating medium or refrigerant, is evaporated into the neutral gas, has a concentration range difierent from the ab-' sorption solution by which the operating medium is absorbed from the gas mixture, the present arrangement may use an absorption solution of the same concentration range for both steps, provided the temperature range and the refrigerant partial pressure zone are different for the two steps.
The presence of neutral gas in the resorber has the effect that the temperature range within which the absorption heat of the resorber is liberated is not only dependent upon the pressure and the change in concentration, as is the case in all resorption systems, but also upon the quantity of the neutral gas circulating through the resorber. Therefore, this temperature range can be varied within very wide limits by correspondingly regulating the amount of the gas circulation. If the mean temperature of the resorber is not much higher than that of the evaporator in which the absorption colution enriched in the resorber is re-evaporated, and if only a comparatively small amount of absorption solution is allowed to circulate between the resorber and the evaporator, the resorber may be included in the circuit of the neutral gas between the evaporator and the absorber, preferably with the gas mixture discharged from the evaporotor traversing first the resorber and then the absorber. The gas mixture circulation can in such a case be brought about with well known means, so that additional means for effecting the neutral gas circulation through the resorber are not necessary.
The further range of use, the advantages and additional new features involved in the invention will be more fully described in the following specification with reference to the accompanying drawing in which a number of different arrangements according to the invention are shown, partly only schematically, and partly in a form approaching that of a practicalform.
In all figures of the drawings, it is clearly shown how the different vessels involved in the system are connected by liquid and gas conduits.
In the drawings,
Fig. 1 schematically illustrates an absorption system in which one absorber and one evaporator are connected by an inert gas circuit, and one resorber and one generator are connected by another inert gas circuit;
Fig. 2 shows schematically an absorption refrigerating system in which the refrigerant vapor developed in the generator passes first into a condenser, and the condensate passes into a primary evaporator, and in which this primary evaporator and a resorber on one hand, and the absorber and a secondary evaporator on the other' circuits; 1
Fig. 3' shows schematically an absorption re-- frigerating system having a. generator, an absorber, and two resorbers, and two evaporators, and in which one resorber is connected with the generator, the other resorber-with one of the two lines, and
evaporators, and the other evaporator with the .absorber, each of the aforementioned pairs of vessels having separate inert gas circuits;
Fig. 4 schematically shows an absorption refrigerating system having a generator, two resorbers, one evaporator and one absorberQand in which the evaporator is connected with the two resorbers in one circuit for the absorption solu-, tion, and the absorber, the evaporator and one of the two resorbers, are connected by an inert gas circuit.
Fig. 5-schematically shows an absorption refrigerating system which contains the same kind and number -01 vessels as Fig. 4, in which however certain vessels are combined to form one single liquid circulating system, but in which, as in Fig. 4, the absorber, the evaporator and one of the resorbers, are connected by a single inert gas circuit; and
Fig. 6 shows the absorption refrigerating system shown in Fig. 4 in an arrangement in which the diiferent vessels'and their connections approach more closely the practical form of such a machine.
ert gas in the generator and resorber nitrogen and in the evaporator and the absorber hydrogen. The sulphuric acid absorption solution extensively freed from the water, in flowing from the generator K to the absorber A, interchanges its heat with the solution enriched by working medium flowing from the absorber to the generator. The
' enriched solution flowing from the resorber to sake of simplification.
the evaporator is likewise in heat interchange with the solution returning from the evaporator to the absorber. The indication of the heat .inter-w change in the circulation systems of the gas mixture has been omitted in the drawings for the Such a system operates in the following inan'- ner. By the application of' heat to the watery sulphuric acid solution in the generator K stan' f.
is developed and discharged into the admixed nitrogen. The sulphuric acid concentrated by the evaporation then reachesthe absorber 'A. The nitrogen, heated by the contact with the solution in the generator' and having also become lighter by having taken up steam, ascends into the resorber R located at a higher. level. There it gives ofl the steam to the sulphuric acid solution coming from the evaporator. The heat of absorption is discharged by cooling water or air. The
gas mixture more or less freed of steam returns to the generator, andthe sulphuric acid diluted bythe absorption at water vapor passes into the present inventlon.
hand, are combined into two separate inert gas evaporator E, where it gives oil. the steam to the admixed hydrogen under a corresponding produc tion of cold. 'The hydrogen gas mixture thus becomes heavier and sinks down into the absorber A, where the steam is absorbed by the sulphuric acid coming from the generator K, heat'being set free, and discharged to cooling water or air. The hydrogen gas mixture freed of steam and heated in the absorber ascends again to the evaporator. The solutions and the gas mixtures flow in opposite directions in all of the vessels.
The total pressure may be different or the same in the two gas mixture circulating systems. If the total pressure is different, this diiference in pressure may be maintained ,by liquid columns.
For i'nstance, in case a lower pressure in the absorber is desired, it would be placed higher than the generator, and in case a lower pressure is desired in the evaporator, it would be placed higher than the resorber. The entire system may be simplified if the same kind of neutral or inert gas-is used in the t wo gas circuits, and if the total pressure is maintained equal. The gas mixture circulation in each of the two systems may be maintained with well known means and without difliculty.
Systems of the type described are entirely free from any restriction in regard to the choice of .the pressure. Those with sulphuric acid as solvent and water as working medium may be operated with a total pressure of 0.1 or- 0.2 atmosphere absolute, or at atmospheric pressure, or
at a pressure above atmospheric, and without any moving parts or great heights of structures. For the greatest economy an increase in pressure is required.
Thus in Figure 1 the refrigerant is absorbed from the inert gas by the solution in the resorber R at the partial pressure determined by its temperature and re-evaporated from the solution inthesame concentration range into the inert gas in evaporator E in a zone of low refrigerant partial pressure. The gas generated in the generator K is introduced into inert gas mixture at a refrigerant pressure corresponding with the zone of refrigerant, partial pressure of the resorber R. The scope of utility of the invention is increased, if a third (higher) pressure or partial pressure zone is provided, at which the refrigerant or working medium is evaporated and condensed.
The condensation may take place in thiszoneof highest pressure eitherby pure condensation orby absorption in a solution, and this pressure zone may or may not be maintained by inert gas.
- By the addition of the third pressure zone v ari-. ous substantial improvements are attained, which .will now be described with reference to the rediagrams. Referring first to Fig. 2, one
of these improvements consists in deriving the ,wor medium, not from the generator K, but from a" rimary evaporator-V- charged with the condensate of ,the higher pressure sta e and in penditure of heat in the generator produced cold twice. The refrigerating capacity of the ma-'- chine can thus be increased considerably.
The resorber solution then performs a cycle, in. which it passes in succession into the temperature range of the production of coldfievaporator E) and into the temperature of the heat discharge to the surroundings (reg men) while coming twice in contact with the neutral gas, and this is a dominant characteristic of the .which'it has already produced cold once, so that v the working medium generated by a definite ex-' The working medium, Figures 2 to 6, is assumed to be ammonia and the solvent water.
In Figure 2 the ammonia is generated in the generator K by the application of heat and passes into the condenser C. It is there condensed under discharge of heat and then passes (dashed line) into the primary evaporator V, where it evaporates into the gas .mixture circulating (dash-dot line) between the resorber R and the primary evaporator V under production of cold in the latter. From the gas mixture the working medium is again absorbed in the resorber R, under renewed discharge of absorption heat by the resorber. The solution thus enriched circulates between the secondary evaporator E and the resorber R. In evaporator E it is, under renewed production of cold, evaporated into the gas mixture circulating between the evaporator Euand the absorberA. Finally it is again absorbed in the absorber A from the latter gas mixture by the solution circulating between the generator K and the absorber A under discharge of heat from the absorber. 1
Thus the arrangement of Figure 2 consists of two stages of evaporation .and accordingly may be referred to as a multl-stage system. Inboth evaporators, (V and E) the refrigerant evaporates into inert gas. Two separate independent inert gas circuits balance the diiierences in refrigerant'partial pressure between the high (generator K and condenser C) intermediate (evaporator V and resorber R) and low (evaporator E and absorber A) sides of the system.
Compared with a single stage absorption systemhaving a condenser'andusing inert gas in the evaporator and absorber, it may be said that the arrangementof Figure 2 consists of such a system with the addition of the resorber R and the evaporator E. At no additional expense, as regards heat input in the boiler, and without causing the boiler to operate at a higher temperature, the refrigerant generated in the boiler is caused to evaporatetwice and be absorbed twice before returning to the boiler.
It is not necessary that the solution, as assumed in the examples mentioned, return immediately from the chamber, in which'it has. absorbed working'medium from a gas mixture, into the chamber in which the absorbed working medium again evaporates from the same concentration range of thesolution into gas mixture. It is quite possible and assists in the simplification of the circulation of the liquid to pass the liquid from the absorption'or resorption chamber in a medium partial pressure zone into a chamber in which it continues to absorb working medium within the same temperature range, but at highen pressure or partial pressure. The strongly concentrated solution may then passinto the cham her where it.gives up working medium to 'gas' mixture in a range of low temperature and in the medium partial pressure zone, and finally.
pass to the chamber, where it gives off further working medium to inert gas in the concentration-range corresponding with the gas absorption in the first chamber. Moregenerally expressed the cycles of circulation of the liquids may be so combined, that all three partial pressure zones are traversed by the solution which circulates between two temperature ranges.
Fig. 3 of the drawings show an example of this system. Fig. 3 also diiiers from Fig. 2 in the use of a second resorber (R), insteadoi' a condenser and in the addition of a third inert gas circuit between the generator and the second resorber. The refrigerant pressure in the boiler K and resorber R, is high, that in the evaporator E, and resorber R2 intermediate and that in-the evaporator E2 and absorber A low. Ammonia is assumed to be used as working medium, water as solvent and nitrogen as inert gas in all three gas cycles of circulation. The gas circulation systems may be equalized in pressure by interconnecting means. In the drawings these interconnections have again been omitted for the sake of simplicity. The ammonia expelled in the generator K by the application of heat passes by the agency of a gascirculation into the resorber R1. In the latter the working medium is absorbed by a solution, which first passes into the evaporator E1, which by a gas circulation system communicates with the resorber R1. The working medium converted into vapor in the evaporator E1 is again absorbed by the solution flowing through the resorber R2. The solution in thelatter resorber is able to do this, since after traversing the evaporator E1 it first passes into the evaporator 1511', where by means of a gas circulation connebtcd with-the absorber A it is freed of gas to a large extent at a low partial pressure, so that it enters the resorber R2 at a low concentration. From the resorber R2 the solution returns into the resorber R1, where it receives ammonia from the generator K.
A pressure may prevail in the entire system considerably lower than that which corresponds with the vapor pressure of the pure ammonia. This pressure may, on the other hand, be substantially exceeded. Particularly when a high pressure prevails it may be necessary to make the quantity of the solution circulating between the resorber R1 and the evaporator E1 smaller than the quantity of solution circulating between the resorber R2 and the evaporator E2. By a branch leading from the pipe connecting resorber R2 and R1, to the pipe which connects evaporators E1 and E2, shown 111 Fig. 3, this requirement may be met in a simple manner. By this branch a portion of the solution then returns into the evaporator Ez immediately after it leaves resorber R2, while the remaining portion of the solution traverses resorber R1 and the evaporator E1.
-This remaining portion of the solution thus cir-- culates through all three partial pressure ranges. This branch currentmay without diificulty be allowed to participate in theheat interchange of the solutions not shown in these diagrams,
but which is preferably provided between the solutiomwhich flows from the resorber R1 to the evaporator E1 and that which flows from the evaporator E2 to the resorber R2.
Two of the separate gas cycles in Fig. 3, may be combined into a single gas circuit. A combination of the evaporator E1 with the evaporator E2 is also possible. If the use of inert gas in the high pressure zone is omitted, that is between the generator K and the resorber R1, a particular-ly simple embodiment of my invention is obtained, which is illustrated in Fig. 4 of the drawings. From the solution circulating between the absorber A and the generator K the ammonia is expelled in the generator K by the application of heat, and passes into the resorber R1, (dotted line) where it is absorbed by a solution, which has already absorbed ammonia from gas mixture in the resorber R2. The solution thus further enriched in the resorber R1 passes into the evaporator E which is shown comparativeiy'long in order to indicate the combination of two evaporators. The solution, after being extensively freed in this evaporator from ammonia which evaporates into the gas mixture coming fromthe absorber A, now passes into theresorber Ra, where it again absorbs ammonia from the gas mixture, and thence returns into the resorber R1, where the further concentration takes place in the absence of inert gas, and commences its cycle anew. The gas mixture arrives in evaporator E from absorber A with low ammonia partial pressure, assumes in the evaporator E an am-- monia partial pressure, which when the mixture leaves the evaporator corresponds with that of the intermediate partial pressure zone, and then gives oif a portion of its admixed ammonia in the resorber R: to the solution contained therein and loses the remainder in the absorber A in the low ammonia partial pressure zone. In the absorber A and the resorbers R1 and R: it is necessary to discharge heat. In the evaporator E the cold is produced.
The apparatus which is only schematicallyv illustrated in Fig.4 of the drawings, is shown in Fig. 6 in a structural form which approximates, more or'less, its actual execution, so far as the relative location of elements and their general structural character and physical connection are concerned. The ammonia, expelled from an aqueous ammonia solution in the generator, boiler or still I by means of a heating element 2, ascends in the pipe 3 in gaseous form together with the weak solution into the gas separator or rectifier 4, which is located at such an elevation that the discharge of the solution through the pipe 5 into the absorber 6 commences before the pressure necessary for operating the nozzle I9 exists. The solution returning from the absorber 6 through the pipe 22 to the generator or boiler l forms, together with the pipe 5, a heat interchanger. The expelled gaseous ammonia separates in the gas separator 4 from the solution and passes through the pipe i into the rising leg of the U-shaped pipe 8 coming from the gas filled resorber 9, terminating in this pipe 8 at a level, which suflices' for creating an appreciable liquid head in pipe 8 above this entry point to raise (by the gas from pipe 'I) the liquid in pipe 8 in the direction or the arrow, from the level of resorber 9. Also the liquid pressure at this level creates the back pressure necessary ior operat-.
ing nozzle l9.
The gaseous ammonia thus raises the solution coming from the second resorber it (R1 in Fig. 4) 'to the first resorber 23 (R1 in Fig. 4) not participating in the gas mixture circulation, this latter resorber being cooled by cooling jacket 24. The gaseous ammonia thus first raises the solution and is absorbed by this solution when it reachesthe resorber 23. The absorption solution enriched in this way passes into the gas separator III, in which any non-absorbed residues of gas separate from the liquid, and then flows through the pipe ll into the evaporator l2, in
p pe
which the cold is generated, the vapor now passing into the circulating gas mixture supplied through pipe II. The absorption solution, which has been greatly impoverished in the .evaporator I! then flows through a pipe 25, which with the II forms a heat interchanger, into the second resorber 9, imwhih it flows over the pipe coil l5 traversed by cooling water. It is cooled thereby and absorbs ammonia from the circulating-gas mixtpre. This mixture is sup.- plied in counter fiow from the evaporator through pipe II. It iscirculated by the gas Jet II supplied with pure gas through pipe l8 directly from gas separator 4, the jet operating in well known manner. The further concentration of the solution then takes place in the resorber 23, as already described. The gas mixture, partially freed from ammonia in the resorber 9 flows thence through pipe l6 into the absorber 6, in which the absorption solution drips down over the pipe coil I'l traversed by cooling water. The gas mixture. ascends in the absorber 6 in counter-flow to the absorption'soiution and gives up further ammonia to the cooled absorp tion solution. The gas mixture now flows through the pipe i3 into the evaporator l2, enters at the bottom, and rises in counterfiowto the rich solution dripping down in the evaporator,
until it is conveyed 'into the pipe I. and the cycle is renewed. pc 18 which supplies jet IS with fresh gas branches from pipe I. at such a height, that when the machine is stopped and -a vacuum is set up in the gas separator 4 inert gas is able to return through the nozzle rearwards into the gas separator 4. This prevents liquor returns from the resorber system into the absorber system, which would cause an undesirable extension of the starting time of the machine. Gas residues, which have not been absorbed in the resorber 23, are conducted to the gas mixture pipe I4 through the pipe 20.
, This is particularly suitable, because this surplus gaseous working medium can thus be absorbed in the resorber 9 and assist in the output 01' cold. The nozzle I9 is located in the pipe I4 leading from the evaporator to the resorber 9, so that .the gas employed for bringing about the gas circulation is not lost for the refrigerating action. Small quantities of the solvent are carried from the absorber system into the resorber system. In order to return these surplus quantities a pipe 2| is provided leading from the resorber 9 into the absorber 6. It would be of advantage to precool the gas mixture flowing through the pipe I3 by the gas mixture flowing in the pipe I4 and this heat interchanger should preferably be located in front of the point of connection of the nozzle l9. For the sake of simplifying the drawings this heat interchanger has been omitted in Fig. 6. For the same reason other improvements known in the'art of absorption machines have been omitted, such as rectifiers or analyzers.
' The greatest simplification for the liquid circulation occurs, of course, when all cycles of liquid circulation are combined in a single cycle. Fig. 5 of the drawings illustrate schematically such a system designed for an increased cold t output without neutral gas admixture in the generator K'and resorber R: of the high partial pressure stage, and with a single gas mixture circulation through the evaporator E, the resorber R1 and the absorber A. The absorption solution. flows here from the generator K first to the absorber A, thence into resorber R1, thence into resorber R2, thence into the evaporator E and finally back into the generator K. The generator K and the resorber R2 --may without difliculty operate under higher refrigerant pressure than the vessels containing inert gas. Refrigerant gas generated in K flows to the resorber R2. The resorber R1 may operate under an intermediate or mean refrigerant partial pressure-while the absorber A operates under a low refrigerant partial pressure. The pressure difterence may be maintained by hydrostatic columns and the pressure diiierence may be utilized tobring about the circulation of the gas combined into a common vessel.
mixture by introducing a portion of the gas expelled in the generator K into the pipe leading from the evaporator E into the resorber R1. The absorber A and the resorber R1 may easily be In order that the intended success of the saving of heat may be realized in the practical execution of this-re- .'conditions it is advantageous to subdivide the 1 solution, which flows through the evaporator E and the resorbers R1 and R: by means of interconnections so thatv a smaller quantity circulates within the range of the stronger concentration of the solution. Finally the gas circulation may 'by transverse connections, be quantitatively adapted to the prevailing demand in the various partial pressure zones. All the necessary sizes and quantities may be calculated from the data further explanations appear unnecessary.
From the preceding explanations and the examples illustrated it will be understood that the gas circuits may either individually or in groups be united to a common circuit through various absorption or evaporation chambers. If three pressure. zones exist, two inert gas currents are necone portion ofthe evaporator, and the other between the other portion of the evaporator and one pcrtionof the resorber. This case is illustrated in Fig. 2 of the drawings. The two separate gas circuits may be combined into a single circuit, which then has two dfierent partial pressure zones, regardless of whether the cycles of liquid circulation are combined or not. This case is illustrated in Figs. 4, ,5 and 6.-
- In the designs according to Figs. 1 and 3 inert gas circulation takes place between a chamber to which heat is supplied at a high temperature and a chamber in which heat is discharged at a medium or intermediate temperature. For bringing about the desired efiect it is not I absolutely necessary; that the gas mixture circulate in counter-flow to the solution in all chambers in which the working medium evaporates or is absorbed. The counter-flow brings about a considerable improvement, however, particularlyin cases in which the temperature ranges is not extensive, so that it is advisable to make use of it wherever possible.
For satisfactory operation of the system gas circulation is necessary, the amount of circulation being dependent on the. liquid circulation and the capacity. The gas may be circulated by any known means.
For the circulation of the absorption solution known means may be employed. Where the generator and resorber contain inert gas the appliwhat difficult.
of the strong and the weak sclution'may be used 11 the pressure in the chambers where working medium under high pressure is absorbed out o1 the gas mixture, is higher than in the chambers where the working medium againevaporates from frigerating machine it is necessary to fulfill a number ofconditions, disregard of which would essary. One circulates between the absorber and available in the literature of the art, so that' cation of these means is, however, rendered some- Circulation due to the different specific weights I the solution into the inert gas, and if this pressure difference is maintained by columns of liquid. Where, however, common gas cycles exist it is .not possible to maintain such a pressure diiIerence. To cause the desired circulation it is then possible to connect the individual vessels in which the gas interchange takes placewith the solution by a system of pipes, such as U-shaped pipes, which also contain temperature interchangers, and. to cause the circulation by heating the solution in the rising leg of the U-shaped pipe, which conveys the solution, for instance, into the chamber, which forms part of the higher temperature range. The heating of the solution in this leg may cause the development of gas from the solution, and the gas so generated may be employed for the operation of a nozzle for starting the gas circulation. In this manner the gas circulation and the liquid circulation may simultaneously be caused in a very effective manner, and the latter may be rendered so eflicient, that for the chambers, in which the interchange of the working me- ,dium between gas and solution occurs, a pressure head exists.
Although in the examples given three temperature ranges were discussed the improvements described are by no means limited to this number. On the contrary, by maintaining two difierent evaporation temperatures or heat discharge temperature it is possible to add further temperature ranges. Two evaporator temperaturesare ad vantageous, for example, in refrigerating cabinets, where the cooling of the refrigerating chamher to a temperature between 2 and 4 C. suflices, but 'for the production of ice a temperature of at least -5 C. must be produced in the evaporator. One evaporator may'then operate at --8 C. and the other at 0 C. i v
If very slight temperature reductions are to be I obtained or an extreme reduction of the evaporation temperature; the intended effect may beincreasedas desired by the addition of further pressure or partial pressure zones, as far as the properties of the absorption solutions permit this.
Various modifications and changes may be made by those skilled in the art without departing from the spirit and the scope of the invention.
I claim as my invention.
1. In an absorption machine of the character described, the process which consists in evaporating the working medium from a portion of. an absorption solution of a certan concentration range into an inert gas mixture within a certain temperature range and a first partial pressure zone, and reabsorbing it from said gas mixture by another portion of said absorption solution of the same concentration range as the first portion, but'within another temperature range and a second partial pressure zone, and expelling the working medium from a solution and returning it into its liquid phase in a third pa'rtial pressure zone, the second partial pressure, at which the working medium is absorbed from gas mixture, by
the aforementioned solution portion of equal concentration range, being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partialpressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture. e.
2. In an absorption machine of the character described and in which heatis applied to an enriched absorption solution in a high and a low temperature range and discharged within a medium temperature range, the process which consists in evaporating the working medium from a portion of an absorption solution into a neutral gas mixture within a certain temperature range and a first partial pressure zone, and reabsorbing it from said gas mixture by another portion of said absorption solution or the same concentration range but within another temperature range and a second partial pressure zone,
and expelling the workingmedium from a solution and returning it intoits liquid phase in a third partial pressure zone, the second pressure at which the working medium is absorbed from the gas mixture by the'aforementioned solution portion of equal concentration range being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partial pressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture, the two solution portions of equal concentration range performing a cycle of circulation in which they pass successively through the low and the medium temperature range.
3. In an absorption machine involving a cycle of generation, resorption, evaporation into an inert gas and absorption, the method of setting the gas mixture in circulation through the evap-v orator, the'resorber and the absorber, by introducing into it working mediumgenerated at a higher pressure. I
4. In an absorption machine involving a cycle of generation, resorption, evaporation into an inert gas and absorption, the method of setting the gas mixture in circulation through the evaporator, the resorber and the absorber, by introducing working medium developed at a higher pressure into the connecting pipe between the evaporator and the resorber in a direction in which the resulting motion of the gas mixture occurs in the direction from the evaporator to- .ward the resorber.
5. In an absorptionfprocess involving operating stages 01 gas generation, resorption, evaporation into an inert gas and absorption therefrom, two
, separate gas mixture cycles within some of the working medium, an absorption solution for said medium and aninert gas not absorbable by said solution, and comprising a generator for developinggaseolis medium from solution of a certain concentration range, a resorber having a gas.
connection with said generator and containing solution of another concentration range and in which the gaseous medium generated in 'said gennections with said evaporator and having means for receiving lean solution for absorbing. gaseous erator is absorbed, an evaporator having a liquid conduit connection with said resorber to permit the evaporation of gaseous medium in the evaporator irom the solution of the second'named concentration range, an absorber having gas conmedium delivered from said evaporator to form a solution of the first named concentration range. whereby a closed cycle of circulation or the said medium is formed, connecting pipes between said generator and said absorber for permitting the absorption solution of the first-mentioned concentration range to circulate, additional circulating pipe connections between said resorber and said evaporator permitting circulation of solution of the secondnamed concentration range between said two vessels, the evaporation of gaseous medium from absorption solution of the second named concentration range and the absorption of gaseous medium into absorption solution of the first named concentration range occurring in the presence oi the said inert gas into which the medium evaporates in said evaporator and from which it separates in said absorber, whereby the development of gaseous medium from absorption solution of at least a portion of one of the two solutions oi! different con centration range occurs in the presence of inert gas .within a certain temperature range and in a certain zone or the partial pressure of said medium in mixture with said inert gas, and whereby the absorption of the gaseous medium in absorption solution of at least one part of the solution of the same concentration range, following said development of gaseous medium, occurs likewise in the presence of inert gas but within another temperature range and another partial pressure zone of said medium, the gaseous medium developed from absorption solution in the generator being under a vapor pressure higher than the pressure in said two partial pressure zones.
8. In an absorption machine containing a work-- ing medium, an absorption solution for said connections with said evaporator and having means for receiving lean solution for absorbing gaseous medium delivered from said'evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting the absorption solution of the first-mentioned concentration range to circulate, additional circulating pipe connections between said resorber and said evaporator permitting circulation of solution of the second named concentration range between said two vessels, the evaporation of gaseous medium from absorption solution oi! the second named concentration range and the absorption of gaseous medium into absorption solution of the first-mentioned concentration range occurring in the presence of said inert gas into-which the medium evaporates in said evaporator and from which it separates in said absorber, whereby the development of gaseous medium from absorption solution of at least a portion of one of the,two solutions of diiferent concentration range occurs, in the presence of inert 'gas within a certain temperature range and in a certain zone of the partialpressure or said" medium in mixture with said inert gas, and whereby the absorption of the gaseous medium in absorption solution of at least one part of the solution of the same concentration range, following said development of gaseous medium, occurs likewise in the presence of inert gas but within another temperature range an another partial pressure zone of said medium, the development of gaseous medium from absorption solution of the first concentration range and its subsequent return to its liquid phase occurring at temperatures other than those prevailing in said aforementioned, two temperature ranges.
9. In an absorption machine containing a working medium, an absorption solution for said medium and an inert gas not absorbable by said solution, and comprising a generator for developing gaseous medium from solution of a certain concentration range, a resorber divided into two separate sections andconnected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber, having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator -to form a solution of the cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber forpermittin'g solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said absorber occurring respectively into and out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas.
10. Inan absorption machine containing a working medium an absorption solution for said medium, an an inert gas not absorbable by said solution, and comprising a generator for developinggaseous medium fromsolution of a certain separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained .therein, an evaporator having a liquid of said resorber to permit evaporation of gaseous medium in the evaporator from the solution de- "livered to it from the first resorber section, a.
second resorber section to permit the absorption in the latter of some of the gaseous medium gas connections with said evaporator and hav- -ing means'for receiving lean solution for absorbing the remainder of the gaseous medium de- 75 livered from said evaporator to form a solution of first named concentration range, whereby a closed concentration range, a resorber divided into two circulating conduit connection with both sections a gas connection between said evaporator and the evaporated in the evaporator, an absorber having the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between said second resorber section and at least one of the other vessels in which absorption solutionscome in contact with said inert gas, for permitting circulation of the inert gas through said vessels.
11. In an absorption machine containing a working medium, an absorption solution for said.
medium and an inert gas not absorbable by said solution, and comprising a generator for developing gaseous medium from solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connecting with both s ec-' tions of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section,
I a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes. between said generator and said absorber for permitting solution of the firstmentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between the resorber section containing inert gas and some of the other vessels, including the evaporator, in which absorption solutions come in contact with said inert gas, for permitting circulation of the inert gas through said resorber section and the evaporator. v
12. In an absorption machine containing a working medium, an absorption solution for said medium and an inert gas not absorbable by said solution, and comprising a generator for developing gaseous medium from solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber sectained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous 'medium in the evaporator from the solution delivered to it from the first resorber section, a gas 1 connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is .i'o'rmed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evapoation of said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in said second resorber section also in the presence of inert gas, and gas conduit connections between said second resorber section and said evaporator and said absorber for permitting circulation oi? the inert gas through'said vessels, the absorption in the first absorber section by solution of the second named concentration range occurring in g the absenceoi inert gas.
13. In an absorption. machine containing working medium, an absorption solution for said contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder. of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a tion of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between the resorber section containing inert gas and some of the other vessels, including the evaporator, in which absorption solutions come in contact with said inert gas, for permitting, circulation of the inert gas through said resorber .sec-' tion and the evaporator, and means for efiecting the circulation or said inert gas.
14. In an absorption machine containing a working medium, an absorption solution for said medium and an inert gas not absorbable by said solution, and comprising a generator for developing gase'ousmedium from solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorbersece tion for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of'some of the gaseous medium evaporated in the evaporator, an absorber having ga's connections with said evaporator and having meansfor receiving lean solution for absorbing the remainder of gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed,
connecting pipes between said generator and said absorber for permitting solution 01' the firstmentioned concentration range to circulate be-- tween the generator and the absorber, the evapo ration of said medium in the evaporator and its absorption in said absorber occun'ing into, re-
spectively out of said inert gas, and the absorp-' tion of the gaseous medium occurring in at least one of said resorber sections also in the presence.
of inert gas, and gas conduit connections between the resorber section containing inert gas and some of the other vessels, including the evaporator, in which absorptionsolutions come in conworking medium, an absorption solution for said medium and an inert gas not absorbable by said solution, and comprising a generatorfor developing gaseous medium from solution of a certain- .concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in bothsections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator irom the solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some of the gaseous medium evaporated in the evaporator, an absorber having gas connections with said. evaporator and having means for receiving lean solution for absorbing the remainder of the. gaseous medium delivered from. said evaporator to form a solutionv of the first named concentration range, whereby a closed cycle of circulation 01 said medium is formed.
connecting pipes between said generator and said absorber for permitting solution of the first;
tioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in the evaporator and its absorption in said'absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between nection having a nozzle terminating in one of said gas mixture conduits for setting the gas mix ture in motion.
, 16. In an absorption machine containing a working medium, an absorption solution for said medium, and an inert gas not absorbable by said solution, and comprising a generator for developing gaseous medium from-solution of a certain concentration range, a resorber divided into two separate sections and connected by liquid conduits and containing in both sections a solution of another concentration range, a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the'solution delivered to it from the first resorber section, a gas connection between said evaporator and the second resorber section to permit the absorption in the latter of some 0! the gaseous medium evaporated in the evaporator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the remainder of the gaseous medium delivered from said evaporator to form a solution of the first named concentration range, whereby a closed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and 'the absorber, the evaporation or said medium in the evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption oi! the gaseous medium occurring in at least one of said resorber sections also in the presence of inert gas, and gas conduit connections between the resorber section containing inert gas and some of the other vessels, including the evaporator, in which absorption solutions come in contact with said inert gas, for permitting circulation of the inert gas through said resorber section and the evaporator, and a pipe connection for conducting pure gaseous medium developed by said generator, at a pressure and temperature higher than those prevailing in the gas mixture circuit, into said mixture circuit, said pipe connection having a nozzle terminating in the gas mixture conduit at the point where the mixture emanates from the evaporator, whereby the gas mixture is set in motion in the direction toward the second resorber section'and the pure gas supplied by said pipe isadmixed to the gas mixture and returned into the cycle of the,operating medium through the evaporator and the two resorber sections, and the absorber.
17. In an absorption process involving operating stages oil gas generation, resorption, evaporation into an inert gas and absorption thereirom, two separate gas mixturecycles within some of the aforementioned operating stages. one of said mixture cycles including the evaporation stage and the absorption stage, and the other gas mixture cycle including the resorption stage and one of the other operating stages.
18. In an absorption process involving operating stages of gas generation, resorption, evaporation into an inert gas and absorption therefrom, two separate gas mixture cycles within some of the aforementioned operating stages, one oi. said mixture cycles including the evaporation stage and the absorption stage, and the other gas mixture cycle including the resorption stage and one of the other operating stages, each of the mixtures in the two gas mixture cycles containing inert gas.
19. In an absorption machine involving a cycle of the working medium through a generation stage, a resorption stage, an evaporation stage and absorption stage, a cycle of absorption liquid through said resorption stage and said evaporation stage and a cycle of an inert gas through said resorption stage and at least one 01 the working medium developing stages; the stage of the process which consists in circulating the gas mixture during the resorption stage in counterfiow to the absorption liquid.
20. In an absorption machine containing a working medium, an absorption solution for said medium and an inert gas not absorbable by said solution, and comprising a generator for developinggaseous medium from solution of a certain concentration range, a resorber divided into two separate sections connected by liquid conduits and containing in both ,sections a solution of another concentration range. a gas connection between said generator and the first resorber section for delivering the generated gas to the latter to be absorbed by the second range solution contained therein, an evaporator having a liquid circulating conduit connection with both sections of said resorber to permit evaporation of gaseous medium in the evaporator from the solution delivered to it from the first resorber section, a gas connection between said generator and an ascending part 0! .said liquid circulating conduit, to permit the lifting of said second range solution to said first-named resorber section by means of gas bubbles developed in said generator, an absorber having gas connections with said evaporator and having means for receiving lean solution for absorbing the gaseous medium delivered from said evaporator to form a solution of the first-named concentration range, whereby aclosed cycle of circulation of said medium is formed, connecting pipes between said generator and said absorber for permitting solution of the first-mentioned concentration range to circulate between the generator and the absorber, the evaporation of said medium in said evaporator and its absorption in said absorber occurring into, respectively out of said inert gas, and the absorption of the gaseous medium occurring in the second-named resorber section also in the presence 01' inert gas.
21. In an absorption machine of the character described, the process which consists in evaporating the working medium from a portion 01' an absorption solution of a certain concentration range into an inert gas mixture within a certain temperature range and a first partial pressure zone, and reabsorbing it from said gas mixture by another portion of said absorption solution of the same concentration range as the first portion, but within another temperature range and a second'partial pressure zone, and expelling the working medium from a solution and returning it into its liquid phase in a third partial pressure zone and within a third temperature range, the second partial pressure, at which the working medium is absorbed from gas mixture by the aforementioned solution portion of equal concentration range, being lower than the third pressure at which the working medium is expelled and returned to its liquid phase, but higher than the first partial pressure at which the working medium evaporates from the first-mentioned solution portion into the gas mixture.
22. In a continuous absorption refrigerating system using an inert gas, the combination of a number of inter-connected vessels, including an-evaporator, an absorber, a'generator and a plurality of devices for changing refrigerant from a gaseous phase to a more dense fluid phase, and means for circulating inert gas through the evap orator, the absorber and one of said devices.
23. In a continuous absorption refrigerating 7 system, inter-connected vessels forming a high refrigerant pressure side of the system, inter.-
connected vessels including a plurality of evaporators forming a low refrigerant pressure side of the system, means for circulating inert gas through the vessels constituting the low pressure side of the system and means for circulating inert gas through the vessels constituting the high pressure side of the system.
24. In a continuous absorption refrigerating system, an evaporator, an absorber, a generator, a resorberand means for circulating inert gas between the generator and resorber. I
25.- In a continuous absorption refrigerating system, an evaporator, an absorber, a resorber and means for circulating inert gas in a single circuit through said evaporator, absorber and resorber.
26. In a continuous absorption refrigerating/- system, an evaporator, an absorber, two resorbers and means for maintaining inert gas in ones of said resorbers.
27. In a continuous absorption refrigerating system, an evaporator, ,an absorber, two resorbers and means for maintaining inert gas in both of said resorbers.
28. In a multi-stage continuous absorption refrigerating system, the combination of a generator, an absorber, a plurality of evaporators, a plurality of resorbers and means for maintaining inert gas in said evaporators and in at least one of said resorbers.
29. In a multi-stage continuous absorption refrigerating system, the combination of -a first evaporator, a second-evaporator, a resorber, a condenser, an absorber, a generator, means for a circulating inert gas between the first mentioned veying liquid refrigerant from the condenser to the first mentioned evaporator.
30. In continuous absorption refrigerating apparatus using inert gas, a multi-stage evaporation system comprising a plurality of evaporators having inert gas therein, an equal number of absorbing devices having inert gas therein for absorbing refrigerant gas evolved in the evaporators, and inert gas and absorption liquid circulating means so connected to said evaporators and devices as to enable refrigerant to pass through said evaporators and devices alternately in series and evaporate into inert gas in each evaporator and be absorbed out of inert gas in each absorbing device.
31. In a continuous absorption refrigerating system using inert gas and arranged to operate on the usual continuous absorption refrigeration cycle in which a refrigerant passes through the steps of evaporation, absorption, generation and change from a gaseous phase to a more dense fluid phase, a multi-stage device for carrying out one of the steps of'said cycle and comprising a plurality of inter-connected vessels adapted to operate at different refrigerant pressures and means providing independent inert gas circuits through said vessels for maintaining different refrigerant pressures in said vessels.
32. In an absorption process for producing refrigeration, the steps of evaporating refrigerant, absorbing it, generating it from solution and changing it from a gaseous phase to a more dense fluid phase, one of said steps being carried out successively in a plurality of stages at different refrigerant pressures while maintaining the difference in pressure between the stages at least partially by circulating inert gas in a plurality of cycles.
33. In an absorption process for producing refrigeration, the steps of evaporating refrigerant, absorbing it, generating it from solution and changing it from a gaseous phase to a more dense fluid phase, said last mentioned step being carried out-in a plurality of stages in the presence of an inert gas. l
34. The absorption process of continuously producing refrigeration which comprises a cycle which includes the steps of heating a solution of absorbent and refrigerant to expel the refrigerant in gaseous phase, cooling the gaseous refrigerant so formed to change it to a more dense fluid phase, conveying the refrigerant in the more dense fluid phase into the presenceof an inert gas to cause it to evaporate to produce. a cooling effect, conveying the mixture of inert gas and refrigerant gas into thepresence of an absorbent, cooling the gases and absorbent to cause effect, again conveying the mixture of inert gas and refrigerant gas into the presence of absorbent, cooling the mixture and absorbent to cause therefrigerant to again be absorbed and again heating the solution so formed to complete the cycle.
35. An absorption refrigerating system including a generator, an absorber, a plurality of evaporators and a resorber for each evaporator,
means for circulating solution between each evaporator and its resorber and means for circulating inert gas through the evaporators.
36. An absorption refrigerating system includ- Y ing a resorber, two evaporators, means for circuto permit circulation of indiiferent gas through lating solution through said resorber and said evaporators, two separate inert gas circuits, one for each of said evaporator-s, and means for maintaining a difference in the refrigerant partial pressures in the two evaporators.
3'7. In a continuous absorption refrigerating system an evaporator, two resorbers, an absorber,
means for circulating solution through said resorbers and said evaporator in series and means for circulating inert gas through said evaporator, said absorber and one of said resorbers in series;
38. In a continuous absorption refrigerating system of the type in which an inert gas is employed, a generator, a resorber, an evaporator, an absorber, means for causing a refrigerant to pass throughsaid elements in the order named, means for circulating inert gas through said evaporator and said absorber and means for causing the resorber to operate over a different range of solution concentration than the range in said evaporator.
. 39. In a continuous absorption refrigerating system of 'thetype in which an inert gas. is employed, a generator, a resorber, an evaporator, an
absorber, means for causing a. refrigerant to pass 7 through 'said elements in the'order named, means for circulating inert gas through said evaporator and said absorber and means for causing the resorber to operate over a. different range of solution concentration than therangein said evaporator, said last mentioned means including 'a second evaporator, a second resorber and an arrangement [for circulating inert J gas between them.
'40. An absorption machine for the production of heat of high temperature, containing a generator, an absorber, an evaporator aresorber, connecting pipes between said vessels to permit circulation of absorption solution through them, the gaseous working medium in said vesselshaving an indiiferent gas admixed to it, and further connecting pipes between the said vessels said generator, resorber, absorber and evaporator.
41. A continuous absorption refrigerating system including a generator, an absorber, an evaporator, a device for changing gaseous refrigerant to a more dense fluid phase and means for circulating inert gas between said evaporator and 50 said device.
42. A continuous absorption refrigerating system having a number of interconnected elements including a boiler, a condenser, a flrst evaporator, a resorber, a second evaporator, an absorber, means for causing refrigerant to pass in a cycle through said elements in the order recited and means for circulating inert gas through certain of said elements. a
43. 'In a continuous absorption refrigerating system, means for causing refrigerant to pass in a continuous cycle through a number of interconnected vessels and means for causing the refrigerant to be evolved from a liquid as a gas and then changed from its-gaseous phase to a more dense fluid phase, successively, in one vessel after another, at least three times, said last mentioned means using inert gas.
44. A heat transfer process which includes the steps of causing a working medium to pass in a continuous cycle through a number of interconnected vessels, applying heat to certain of said vessels, cooling others of said vessels and circulating inert gas through certain of said vessels to cause the working medium to be evolved from a liquid, as a gas and then changed from its gaseous phase to a more dense fluid phase, successively at least three times.
45. In a continuous -'absorption. refrigerating system, an evaporator, a plurality of resorbers, a
generator, an absorber and means for circulating inert gas through one of said resorbers and said evaporator.
46. In a continuous absorption refrigerating system, an evaporator, a plurality of resorbers, a generator, an absorber, means for circulating inort gas through certain of said vessels and means for circulating absorption solutions in series through two resorbers and said evaporator.
47. In a continuous absorption refrigerating system using inert gas, a generator for expelling refrigerant from an absorption solution, an absorber, means for circulating inert gas through the absorber, means for passing refrigerant expelled in the generator directly to said absorber, means for circulating absorption solution through said absorber to cause the refrigerant delivered thereto from thegenerator tobe absorbed in the absorber and means for causing the generator to operate over a different solution concentrationrange than that over whichthe absorber operates.
US19889D Absorption refrigerating system Expired USRE19889E (en)

Publications (1)

Publication Number Publication Date
USRE19889E true USRE19889E (en) 1936-03-17

Family

ID=2084377

Family Applications (1)

Application Number Title Priority Date Filing Date
US19889D Expired USRE19889E (en) Absorption refrigerating system

Country Status (1)

Country Link
US (1) USRE19889E (en)

Similar Documents

Publication Publication Date Title
US3817050A (en) Two-stage ammonia absorption refrigeration system with at least three evaporation stages
US4551991A (en) Multi-effect absorption refrigerating machine
US1781541A (en) Refrigeration
US3273350A (en) Refrigeration systems and methods of refrigeration
US2284691A (en) Refrigeration
US3495420A (en) Two stage generator absorption unit with condensate heat exchanger
USRE19889E (en) Absorption refrigerating system
US1887909A (en) Absorption machine
US2298029A (en) Refrigeration
US2357612A (en) Refrigeration
US2321113A (en) Refrigeration
US1887957A (en) Absorption refrigerating machine
USRE19888E (en) Absorption apparatus
US1996094A (en) Absorption refrigerating apparatus and method
US2357340A (en) Refrigeration
US3986343A (en) Apparatus and process for deuterium exchange
US2770108A (en) Absorption refrigeration
GB317052A (en) Improvements in or relating to absorption machines for refrigerating or heating
US2587629A (en) Absorption refrigeration
US2321060A (en) Refrigeration
US2257986A (en) Refrigeration
US2561369A (en) Absorption refrigeration system
US2072144A (en) Absorption refrigerating system
US1908277A (en) Absorption machine
US1757578A (en) Refrigeration