[go: up one dir, main page]

US6676780B1 - Radon suppression - Google Patents

Radon suppression Download PDF

Info

Publication number
US6676780B1
US6676780B1 US10/349,900 US34990003A US6676780B1 US 6676780 B1 US6676780 B1 US 6676780B1 US 34990003 A US34990003 A US 34990003A US 6676780 B1 US6676780 B1 US 6676780B1
Authority
US
United States
Prior art keywords
ethylene vinyl
layer
percent
film
building
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US10/349,900
Inventor
Ayal Shahar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cadillac Products Packaging Co
Original Assignee
Cadillac Products Packaging Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cadillac Products Packaging Co filed Critical Cadillac Products Packaging Co
Priority to US10/349,900 priority Critical patent/US6676780B1/en
Assigned to CADILLAC PRODUCTS PACKAGING COMPANY reassignment CADILLAC PRODUCTS PACKAGING COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SHAHAR, AYAL
Application granted granted Critical
Publication of US6676780B1 publication Critical patent/US6676780B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D31/00Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
    • E02D31/008Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution against entry of noxious gases, e.g. Radon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/055 or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • B32B2307/7244Oxygen barrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • B32B2323/046LDPE, i.e. low density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • B32B2471/02Carpets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state

Definitions

  • This invention relates to the suppression of the flow of radon into buildings.
  • Radon is a gaseous element having the atomic number 86, i.e., an atom of radon has 86 protons in its nucleus and 86 electrons. Radon exists in the form of eighteen different isotopes. Isotopes are atoms of an element which contain different numbers of neutrons in their nuclei. All the radon isotopes are radioactive. Radioactivity is a process in which atoms undergo spontaneous nuclear transformations or decay by emitting atomic particles and electromagnetic energy. Radon undergoes alpha particle radiation in which the nuclei emit alpha particles consisting of two protons and two neutrons. The rate of radioactivity of a particular isotope is measured by its half-life.
  • a half-life is the time for one-half of the atoms to undergo radioactive transformation. Seventeen of the radon isotopes have very short half-lives, ranging from a few seconds or less. Radon-222, the radon isotope containing 136 neutrons, is the most stable of the isotopes. It has a half-life of 3.8 days. Radon is known to cause many harmful effects on humans, including lung cancer.
  • Radon is constantly being formed by the radioactive decay of subterranean elements.
  • Uranium (atomic number 92) decays into thorium (atomic number 90), thorium decays into radium (atomic number 88), and radium decays into radon.
  • radon gas is constantly seeping upward through rock and soil toward the surface of the earth. It poses no risk when it reaches the atmosphere because its concentration is so small.
  • radon can enter buildings and concentrate to dangerous levels, particularly in basements and first floors of buildings without basements. Radon levels vary considerably at different sites, and over time at any given site. Many factors cause these variations. For example, low pressure atmospheric conditions which often occur during storms are believed to draw higher levels of radon from the ground.
  • the health risks posed by radon have become more widely recognized in the past decade.
  • the United States Environmental Protection Agency has recommended that homeowners take corrective action if the level of radon in their homes exceeds 4 picocuries per liter.
  • Ventilation can be improved by the use of an air-to-air heat exchanger commonly known as a heat recovery ventilator.
  • ventilation is difficult in basements with few, if any, windows or doors. Ventilation also results in the loss of conditioned air, discomfort, security problems, and increased costs of conditioning outside air.
  • the second basic way of lowering radon levels inside a building is to suppress the flow of radon into the building.
  • the most common technique for suppressing the flow of radon into a building is to seal cracks and other openings in the building foundation. Sealing also reduces the loss of conditioned air, thereby making other radon suppression techniques more efficient.
  • normal settling of buildings creates new openings and reopens old ones.
  • Another common technique for suppressing the flow of radon into a building is to pressurize the inside of the building.
  • Building pressurization typically uses a fan to blow air into the basement or living area from either upstairs or outdoors.
  • the effectiveness of this technique depends on the building construction, climate, other appliances in the building, and occupant lifestyle.
  • a major disadvantage of this method is that doors and windows must be left closed.
  • suction pipes are inserted into the crushed rock or soil underneath.
  • a fan is connected to the suction pipes which draws the gas from under the building to the atmosphere. Drain pipes that carry groundwater are sometimes used as the suction pipes.
  • a further way of suppressing the flow of radon into a building is to place a sheet of plastic film between the soil and the building.
  • the sheet is typically placed over the soil beneath the building.
  • plastic films including polyethylene and polypropylene, do not provide an effective barrier to radon.
  • the plastic sheeting must be laid during building construction and it is difficult to completely cover the ground under the foundation. Plastic sheeting is also incorporated into the floor of the building.
  • the use of radon barriers is disclosed in Doyle et al., U.S. Pat. No. 5,137,764, issued Aug. 11, 1992; and Schwilling et al., U.S. Pat. No. 5,174,800, issued Dec. 29, 1992.
  • the general object of this invention is to provide an improved method of suppressing the flow of radon into buildings.
  • the method comprises: (a) obtaining a sheet of plastic film having an oxygen diffusivity of less than about 10 cubic centimeters per day; and (b) placing the plastic film on or under the lowest floor of the building.
  • the method dramatically reduces the flow of radon into a building when the plastic film completely covers the floor.
  • the method is relatively inexpensive and completely safe. It has no effect on the occupant and there are no operating costs.
  • FIG. 1 is a perspective view of a building having a film layer.
  • FIG. 2 is a cross section of a multilayer film.
  • FIG. 3 is a cross section of a carpet liner having the multilayer film of FIG. 2 .
  • FIG. 1 depicts a building 10 having a floor through which radon may enter.
  • Carpet 18 covers the floor.
  • Under the carpet is a sheet of plastic film 22 .
  • the plastic film is shown covering only part of the floor for illustration purposes. In practice, the plastic film would preferably cover the entire floor. Alternatively, the plastic film is placed under the floor and over the soil.
  • the plastic film is made of a material having a low radon diffusivity.
  • the diffusivity of a plastic film can be quantified by the volume of a particular gas in cubic centimeters which passes in one day (24 hours) through a sheet of the material having a surface area of 100 square inches, a thickness of one mil (one one-thousandths of an inch, 0.001 inches), with a pressure differential of one atmosphere, at zero percent relative humidity, and at a temperature of 70° F. Measurements of radon diffusivity are not available. However, radon diffusivity is believed to correlate with the oxygen diffusivity and the oxygen diffusivity for many plastic films is known. Accordingly, a film's radon diffusivity is quantified indirectly herein by its oxygen diffusivity.
  • the plastic film has an oxygen diffusivity of less than about ten cubic centimeters per day, preferably less than about five cubic centimeters per day.
  • Preferred plastic films having such a low oxygen diffusivity include ethylene vinyl alcohol (EVOH) copolymers which contain repeating units of ethylene [—CH 2 —CH 2 —] and of vinyl alcohol [—CHOH—CH 2 —], polyvinylidene chloride (PVDC) which contains repeating units of vinylidene chloride [—CH 2 —CCl 2 —], nylon which contains repeating units of amides [—CH 2 —CHCONH—], polyethylene terephthalate (PET) which contains repeating units of [—C 10 H 8 O4—], and polyvinyl alcohol (PVOH) which contains repeating units of vinyl alcohol [—CHOH—CH 2 —].
  • EVOH ethylene vinyl alcohol
  • PVDC polyvinylidene chloride
  • nylon which contains repeating units of amides [—CH 2 —CHCONH
  • Suitably low oxygen diffusivities are also obtained by coating high diffusivity plastic films such as polyethylene, polypropylene, or ethylene vinyl acetate with substrates such as aluminum, glass, silicon dioxide, aluminum oxide, and the like.
  • the preferred plastic films are ethylene vinyl alcohol copolymers containing about 20 to 60 mole percent ethylene monomers. These copolymers have a very low oxygen/radon diffusivity.
  • the plastic films with low oxygen/radon diffusivities are generally more expensive than uncoated common polyolefin films, such as polyethylene, polypropylene, and ethylene vinyl acetate, which have oxygen diffusivities greater than ten cubic centimeters per day.
  • the plastic films with low oxygen/radon diffusivities are generally stiffer and a have a poorer resistance to puncture. Accordingly, it is preferred to use a multilayer film having a layer of a plastic with a low oxygen/radon diffusivity sandwiched between layers of polyethylene, polypropylene, or ethylene vinyl acetate.
  • Such a multilayer film combines the advantages of both films, the low radon diffusivity of the inner layer and the desirable physical characteristics of the outer layers.
  • FIG. 2 shows a preferred multilayer film 110 containing five separate layers.
  • the film contains an inner layer 112 of ethylene vinyl alcohol copolymer having a first side 113 and a second side 114 .
  • a first adhesive layer 116 contacts the first side and a second adhesive layer 118 contacts the second side.
  • the adhesive layers preferably comprise extrudable adhesives such as linear low density polyethylene or ethylene vinyl acetate.
  • a first outer layer 122 contacts the first adhesive layer and a second outer layer 124 contacts the second adhesive layer.
  • the outer layers are preferably polyethylene, polypropylene, or ethylene vinyl acetate.
  • the multilayer film is preferably about 0.5 to 20 mils in thickness and is most preferably about 1 to 10 mils in thickness.
  • the ethylene vinyl alcohol copolymer preferably makes up about 5 to 70 percent of the thickness, the adhesive layers preferably make up about 5 to 40 percent of the thickness, and the outer layers preferably make up about 5 to 80 percent of the thickness.
  • the multilayer film is manufactured by a conventional extrusion process in which each layer is formed and extruded separately. The layers are then disposed in a side-by-side relationship to form the multilayer film.
  • the multilayer film is used by itself or is incorporated into a carpet liner as shown in FIG. 3 .
  • the liner 310 comprises a multilayer film 314 and a cushion 318 .
  • the cushion is conventional, such as a layer of foam of the type commonly used in carpet installation.
  • the plastic film is installed in the building in any one of a number of ways to create a barrier between the soil and the lowermost living space in the building. It can be spread across the soil beneath the foundation during construction. It can also be installed after construction by laying it down on the floor of the lowermost living space in the building, as shown in FIG. 1 .

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Health & Medical Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The flow of radon from the ground into a building is suppressed by placing a plastic film on or under the lowest floor of the building. The plastic film is made of a material having an oxygen diffusivity of less than about 10 cubic centimeters per day.

Description

CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of U.S. patent application Ser. No. 09/691,428, filed Oct. 18, 2000, now abandoned.
FIELD OF THE INVENTION
This invention relates to the suppression of the flow of radon into buildings.
BACKGROUND OF THE INVENTION
Radon is a gaseous element having the atomic number 86, i.e., an atom of radon has 86 protons in its nucleus and 86 electrons. Radon exists in the form of eighteen different isotopes. Isotopes are atoms of an element which contain different numbers of neutrons in their nuclei. All the radon isotopes are radioactive. Radioactivity is a process in which atoms undergo spontaneous nuclear transformations or decay by emitting atomic particles and electromagnetic energy. Radon undergoes alpha particle radiation in which the nuclei emit alpha particles consisting of two protons and two neutrons. The rate of radioactivity of a particular isotope is measured by its half-life. A half-life is the time for one-half of the atoms to undergo radioactive transformation. Seventeen of the radon isotopes have very short half-lives, ranging from a few seconds or less. Radon-222, the radon isotope containing 136 neutrons, is the most stable of the isotopes. It has a half-life of 3.8 days. Radon is known to cause many harmful effects on humans, including lung cancer.
Radon is constantly being formed by the radioactive decay of subterranean elements. Uranium (atomic number 92) decays into thorium (atomic number 90), thorium decays into radium (atomic number 88), and radium decays into radon. As a result, radon gas is constantly seeping upward through rock and soil toward the surface of the earth. It poses no risk when it reaches the atmosphere because its concentration is so small. However, radon can enter buildings and concentrate to dangerous levels, particularly in basements and first floors of buildings without basements. Radon levels vary considerably at different sites, and over time at any given site. Many factors cause these variations. For example, low pressure atmospheric conditions which often occur during storms are believed to draw higher levels of radon from the ground.
The health risks posed by radon have become more widely recognized in the past decade. The United States Environmental Protection Agency has recommended that homeowners take corrective action if the level of radon in their homes exceeds 4 picocuries per liter. There are two basic ways to lower radon levels in a building. The first is to remove the radon that is already there and the second is to suppress the flow of radon into the building.
The most common technique for removing existing radon from a building is to increase ventilation. Simply opening doors and windows can lower radon levels. Ventilation can be improved by the use of an air-to-air heat exchanger commonly known as a heat recovery ventilator. However, ventilation is difficult in basements with few, if any, windows or doors. Ventilation also results in the loss of conditioned air, discomfort, security problems, and increased costs of conditioning outside air.
The second basic way of lowering radon levels inside a building is to suppress the flow of radon into the building. The most common technique for suppressing the flow of radon into a building is to seal cracks and other openings in the building foundation. Sealing also reduces the loss of conditioned air, thereby making other radon suppression techniques more efficient. However, it is very difficult to identify and permanently seal every opening. Furthermore, normal settling of buildings creates new openings and reopens old ones.
Another common technique for suppressing the flow of radon into a building is to pressurize the inside of the building. Building pressurization typically uses a fan to blow air into the basement or living area from either upstairs or outdoors. The effectiveness of this technique depends on the building construction, climate, other appliances in the building, and occupant lifestyle. A major disadvantage of this method is that doors and windows must be left closed.
Another way of suppressing the flow of radon into a building is to suction the soil under the building. In buildings having a basement or a slab-on-grade foundation, suction pipes are inserted into the crushed rock or soil underneath. A fan is connected to the suction pipes which draws the gas from under the building to the atmosphere. Drain pipes that carry groundwater are sometimes used as the suction pipes.
A further way of suppressing the flow of radon into a building is to place a sheet of plastic film between the soil and the building. The sheet is typically placed over the soil beneath the building. Commonly used plastic films, including polyethylene and polypropylene, do not provide an effective barrier to radon. Furthermore, the plastic sheeting must be laid during building construction and it is difficult to completely cover the ground under the foundation. Plastic sheeting is also incorporated into the floor of the building. The use of radon barriers is disclosed in Doyle et al., U.S. Pat. No. 5,137,764, issued Aug. 11, 1992; and Schwilling et al., U.S. Pat. No. 5,174,800, issued Dec. 29, 1992.
Accordingly, a demand exists for an improved method of suppressing the flow of radon into buildings.
SUMMARY OF THE INVENTION
The general object of this invention is to provide an improved method of suppressing the flow of radon into buildings.
I have invented a method of suppressing the flow of radon from the ground into a building. The method comprises: (a) obtaining a sheet of plastic film having an oxygen diffusivity of less than about 10 cubic centimeters per day; and (b) placing the plastic film on or under the lowest floor of the building.
The method dramatically reduces the flow of radon into a building when the plastic film completely covers the floor. The method is relatively inexpensive and completely safe. It has no effect on the occupant and there are no operating costs.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of a building having a film layer.
FIG. 2 is a cross section of a multilayer film.
FIG. 3 is a cross section of a carpet liner having the multilayer film of FIG. 2.
DETAILED DESCRIPTION OF THE INVENTION
This invention is best understood by reference to the drawings. FIG. 1 depicts a building 10 having a floor through which radon may enter. Carpet 18 covers the floor. Under the carpet is a sheet of plastic film 22. The plastic film is shown covering only part of the floor for illustration purposes. In practice, the plastic film would preferably cover the entire floor. Alternatively, the plastic film is placed under the floor and over the soil.
The plastic film is made of a material having a low radon diffusivity. The diffusivity of a plastic film can be quantified by the volume of a particular gas in cubic centimeters which passes in one day (24 hours) through a sheet of the material having a surface area of 100 square inches, a thickness of one mil (one one-thousandths of an inch, 0.001 inches), with a pressure differential of one atmosphere, at zero percent relative humidity, and at a temperature of 70° F. Measurements of radon diffusivity are not available. However, radon diffusivity is believed to correlate with the oxygen diffusivity and the oxygen diffusivity for many plastic films is known. Accordingly, a film's radon diffusivity is quantified indirectly herein by its oxygen diffusivity.
The plastic film has an oxygen diffusivity of less than about ten cubic centimeters per day, preferably less than about five cubic centimeters per day. Preferred plastic films having such a low oxygen diffusivity include ethylene vinyl alcohol (EVOH) copolymers which contain repeating units of ethylene [—CH2—CH2—] and of vinyl alcohol [—CHOH—CH2—], polyvinylidene chloride (PVDC) which contains repeating units of vinylidene chloride [—CH2—CCl2—], nylon which contains repeating units of amides [—CH2—CHCONH—], polyethylene terephthalate (PET) which contains repeating units of [—C10H8O4—], and polyvinyl alcohol (PVOH) which contains repeating units of vinyl alcohol [—CHOH—CH2—]. Suitably low oxygen diffusivities are also obtained by coating high diffusivity plastic films such as polyethylene, polypropylene, or ethylene vinyl acetate with substrates such as aluminum, glass, silicon dioxide, aluminum oxide, and the like. The preferred plastic films are ethylene vinyl alcohol copolymers containing about 20 to 60 mole percent ethylene monomers. These copolymers have a very low oxygen/radon diffusivity.
The plastic films with low oxygen/radon diffusivities are generally more expensive than uncoated common polyolefin films, such as polyethylene, polypropylene, and ethylene vinyl acetate, which have oxygen diffusivities greater than ten cubic centimeters per day. In addition, the plastic films with low oxygen/radon diffusivities are generally stiffer and a have a poorer resistance to puncture. Accordingly, it is preferred to use a multilayer film having a layer of a plastic with a low oxygen/radon diffusivity sandwiched between layers of polyethylene, polypropylene, or ethylene vinyl acetate. Such a multilayer film combines the advantages of both films, the low radon diffusivity of the inner layer and the desirable physical characteristics of the outer layers.
FIG. 2 shows a preferred multilayer film 110 containing five separate layers. The film contains an inner layer 112 of ethylene vinyl alcohol copolymer having a first side 113 and a second side 114. A first adhesive layer 116 contacts the first side and a second adhesive layer 118 contacts the second side. The adhesive layers preferably comprise extrudable adhesives such as linear low density polyethylene or ethylene vinyl acetate. A first outer layer 122 contacts the first adhesive layer and a second outer layer 124 contacts the second adhesive layer. The outer layers are preferably polyethylene, polypropylene, or ethylene vinyl acetate.
The multilayer film is preferably about 0.5 to 20 mils in thickness and is most preferably about 1 to 10 mils in thickness. The ethylene vinyl alcohol copolymer preferably makes up about 5 to 70 percent of the thickness, the adhesive layers preferably make up about 5 to 40 percent of the thickness, and the outer layers preferably make up about 5 to 80 percent of the thickness.
The multilayer film is manufactured by a conventional extrusion process in which each layer is formed and extruded separately. The layers are then disposed in a side-by-side relationship to form the multilayer film.
The multilayer film is used by itself or is incorporated into a carpet liner as shown in FIG. 3. The liner 310 comprises a multilayer film 314 and a cushion 318. The cushion is conventional, such as a layer of foam of the type commonly used in carpet installation.
The plastic film is installed in the building in any one of a number of ways to create a barrier between the soil and the lowermost living space in the building. It can be spread across the soil beneath the foundation during construction. It can also be installed after construction by laying it down on the floor of the lowermost living space in the building, as shown in FIG. 1.

Claims (17)

I claim:
1. A method of suppressing the flow of radon from the ground into a building, the method comprising:
(a) obtaining a sheet of multilayer plastic film comprising an inner layer having an oxygen diffusivity of less than about ten cubic centimeters per day and outer layers comprising polyethylene, polypropylene, or ethylene vinyl acetate; and
(b) placing the plastic film on or under the lowest floor of the building.
2. The method of claim 1 wherein the plastic film is placed on the lowest floor of the building.
3. The method of claim 2 wherein the inner layer of the film comprises ethylene vinyl alcohol copolymers, polyvinylidene chloride, nylon, polyethylene terephthalate, or polyvinyl alcohol.
4. The method of claim 3 wherein the inner layer of the film comprises ethylene vinyl alcohol copolymers.
5. The method of claim 4 wherein the inner layer of the film comprises ethylene vinyl alcohol copolymers having about 20 to 60 mole percent ethylene monomers.
6. The method of claim 5 wherein the inner layer of the film has an oxygen diffusivity of less than about five cubic centimeters per day.
7. The method of claim 6 wherein adhesive layers are sandwiched between the inner layer and the outer layers.
8. The method of claim 7 wherein the multilayer film has a thickness of about 0.5 to 20 mils, and wherein the inner layer of ethylene vinyl alcohol copolymer comprises about 5 to 70 percent of the thickness, the adhesive layers comprise about 5 to 40 percent of the thickness, and the outer layers of polyethylene, polypropylene, or ethylene vinyl acetate comprise about 5 to 80 percent of the thickness.
9. A method of suppressing the ingress of radon gas from soil into a building through a floor of the building, the method comprising:
(a) providing a first layer comprising an ethylene vinyl comprising a plastic alcohol copolymer having a predetermined percent mole ethylene;
(b) providing a second layer wherein the plastic is different than ethylene vinyl alcohol copolymer adjacent the ethylene vinyl alcohol copolymer layer to form a multilayer film;
(c) disposing the multilayer film on or under the floor; and
(d) covering the multilayer film.
10. The method of claim 9 wherein the predetermined percent mole of ethylene vinyl alcohol copolymer ranges between 20 to 60 percent of ethylene.
11. The method of claim 10 wherein the second layer comprises an adhesive layer.
12. The method of claim 11 wherein the second layer comprises a polyolefin.
13. The method of claim 12 wherein the ethylene vinyl alcohol copolymer layer is about 5 to 70 percent of a thickness of the multilayer film.
14. The method of claim 13 wherein the adhesive layer is about 5 to 40 percent of a thickness of the multilayer film.
15. The method of claim 14 wherein the plastic layer is about 5 to 80 percent of a thickness of the multilayer film.
16. The method of claim 9 wherein the disposing step further includes disposing the film adjacent the soil.
17. The method of claim 9 wherein the multilayer film has a thickness of between about 0.5 mil and 20 mil.
US10/349,900 2000-10-18 2003-01-22 Radon suppression Expired - Lifetime US6676780B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/349,900 US6676780B1 (en) 2000-10-18 2003-01-22 Radon suppression

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69142800A 2000-10-18 2000-10-18
US10/349,900 US6676780B1 (en) 2000-10-18 2003-01-22 Radon suppression

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US69142800A Continuation-In-Part 2000-10-18 2000-10-18

Publications (1)

Publication Number Publication Date
US6676780B1 true US6676780B1 (en) 2004-01-13

Family

ID=29780716

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/349,900 Expired - Lifetime US6676780B1 (en) 2000-10-18 2003-01-22 Radon suppression

Country Status (1)

Country Link
US (1) US6676780B1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100251638A1 (en) * 2008-10-15 2010-10-07 Proten Services Limited Apparatus and method for radon inhibition
EP2489509A1 (en) 2011-02-17 2012-08-22 Industrial Textiles & Plastics Limited Chemical Resistant Membrane
US20150107451A1 (en) * 2013-10-22 2015-04-23 Colin G. Meyer Radon Removal From Gas
US9539537B1 (en) 2013-10-22 2017-01-10 Radon Scrubber Llc Radon removal apparatus
FR3046287A1 (en) * 2015-12-29 2017-06-30 Agence Nat Pour La Gestion Des Dechets Radioactifs CONFINING STORAGE SYSTEM WITH SCREWS OF RADIOACTIVE GAS, SUCH AS TRITIUM
CN108680467A (en) * 2018-05-21 2018-10-19 南华大学 The method of underground engineering in-site detecting radon diffusion coefficient and the radon production rate that can migrate
US20220056660A1 (en) * 2019-01-18 2022-02-24 Tema Technologies And Materials Srl Multilayer membrane for construction
RU2805441C1 (en) * 2023-02-27 2023-10-17 Евгений Дмитриевич Малафеев Radon metal-bitumen insulation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2236127A (en) * 1989-03-31 1991-03-27 Shillabeer John Louis Gas barriers for buildings
US5137764A (en) * 1990-12-06 1992-08-11 Doyle Dennis J Floor structure incorporating a vapor and gas barrier
US20020061982A1 (en) * 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2236127A (en) * 1989-03-31 1991-03-27 Shillabeer John Louis Gas barriers for buildings
US5137764A (en) * 1990-12-06 1992-08-11 Doyle Dennis J Floor structure incorporating a vapor and gas barrier
US20020061982A1 (en) * 1999-06-11 2002-05-23 Donald Robert J. Compositions comprising hydrogenated block copolymers and end-use applications thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100251638A1 (en) * 2008-10-15 2010-10-07 Proten Services Limited Apparatus and method for radon inhibition
EP2489509A1 (en) 2011-02-17 2012-08-22 Industrial Textiles & Plastics Limited Chemical Resistant Membrane
US20150107451A1 (en) * 2013-10-22 2015-04-23 Colin G. Meyer Radon Removal From Gas
US9230700B2 (en) * 2013-10-22 2016-01-05 Radon Scrubber Llc Radon removal from gas
US9539537B1 (en) 2013-10-22 2017-01-10 Radon Scrubber Llc Radon removal apparatus
FR3046287A1 (en) * 2015-12-29 2017-06-30 Agence Nat Pour La Gestion Des Dechets Radioactifs CONFINING STORAGE SYSTEM WITH SCREWS OF RADIOACTIVE GAS, SUCH AS TRITIUM
CN108680467A (en) * 2018-05-21 2018-10-19 南华大学 The method of underground engineering in-site detecting radon diffusion coefficient and the radon production rate that can migrate
CN108680467B (en) * 2018-05-21 2020-07-10 南华大学 Method for in situ determination of radon diffusion coefficient and transportable radon generation rate in underground engineering
US20220056660A1 (en) * 2019-01-18 2022-02-24 Tema Technologies And Materials Srl Multilayer membrane for construction
RU2805441C1 (en) * 2023-02-27 2023-10-17 Евгений Дмитриевич Малафеев Radon metal-bitumen insulation

Similar Documents

Publication Publication Date Title
KR101245143B1 (en) Finishing materials for discharging radon gas and system for discharging toxic material using the same and constructing method
Akerblom et al. Soil gas radon-a source for indoor radon daughters
US6676780B1 (en) Radon suppression
Doi et al. Characterization of Japanese wooden houses with enhanced radon and thoron concentrations
US8720145B2 (en) Mounting arrangement for a foundation wall vapor barrier
Otoo et al. Seasonal indoor radon studies in buildings of Accra Metropolis of Greater Accra region of Ghana
Yu et al. A study of factors affecting indoor radon properties
Senitkova et al. Seasonal and floor variations of indoor radon concentration
Tataru et al. Determination of the radon concentration in homes depending on the insulation used for the floor
US20030051418A1 (en) Prefabricated structure and method of construction
Tanner Indoor radon and its sources in the ground
Jelle et al. Implementation of radon barriers, model development and calculation of radon concentration in indoor air
Rohmingliana et al. Measurement of indoor concentrations of radon and thoron in Mizoram, India
Ennemoser et al. Mitigation of indoor radon in an area with unusually high radon concentrations
Naismith Durability of radon remedial actions
Pazwash A method of radon reduction for new buildings
Alenazi An Assessment of Various Membrane Barriers for Radon Diffusion
Jiránek Testing and design of radon resisting membranes based on the experience from the Czech Republic
Woolliscroft The principles of radon remediation and protection in UK dwellings
Cucu et al. Radon. methods of measurement and concentration reduction in various spaces
Deka et al. Study of indoor radon and thoron progeny levels in surrounding areas of Nalbari, Assam, India
Najafi et al. Radon entry control in new house construction
Tondeur et al. Indoor radon in the region of Brussels
Aït-Ziane et al. Preliminary study of effect of environmental parameter variations on indoor radon concentrations in Mediterranean climate
Armstrong et al. Improving indoor air quality by reducing radon and vapor intrusion through the use of ethylene vinyl alcohol (EVOH)

Legal Events

Date Code Title Description
AS Assignment

Owner name: CADILLAC PRODUCTS PACKAGING COMPANY, MICHIGAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SHAHAR, AYAL;REEL/FRAME:013953/0547

Effective date: 20030121

FPAY Fee payment

Year of fee payment: 4

REMI Maintenance fee reminder mailed
FEPP Fee payment procedure

Free format text: PETITION RELATED TO MAINTENANCE FEES FILED (ORIGINAL EVENT CODE: PMFP); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

FEPP Fee payment procedure

Free format text: PETITION RELATED TO MAINTENANCE FEES GRANTED (ORIGINAL EVENT CODE: PMFG); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

LAPS Lapse for failure to pay maintenance fees
REIN Reinstatement after maintenance fee payment confirmed
FP Lapsed due to failure to pay maintenance fee

Effective date: 20120113

FPAY Fee payment

Year of fee payment: 8

SULP Surcharge for late payment
PRDP Patent reinstated due to the acceptance of a late maintenance fee

Effective date: 20120608

STCF Information on status: patent grant

Free format text: PATENTED CASE

FEPP Fee payment procedure

Free format text: PAT HOLDER CLAIMS SMALL ENTITY STATUS, ENTITY STATUS SET TO SMALL (ORIGINAL EVENT CODE: LTOS); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

FPAY Fee payment

Year of fee payment: 12