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US5792737A - Mild, aqueous, surfactant preparation for cosmetic purposes and as detergent - Google Patents

Mild, aqueous, surfactant preparation for cosmetic purposes and as detergent Download PDF

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Publication number
US5792737A
US5792737A US08/843,552 US84355297A US5792737A US 5792737 A US5792737 A US 5792737A US 84355297 A US84355297 A US 84355297A US 5792737 A US5792737 A US 5792737A
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betaine
sup
carbon atoms
betaines
mild
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US08/843,552
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Burghard Gruning
Christian Weitemeyer
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Evonik Operations GmbH
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TH Goldschmidt AG
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/74—Biological properties of particular ingredients
    • A61K2800/75—Anti-irritant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention relates to mild, aqueous, surfactant preparations for cosmetic purpose and detergents.
  • Betaines and, particularly amidopropyl betaines are used as amphoteric surfactants especially for hair preparations and in cleansing agent preparations for the skin, such as shampoos, foam gels and shower gels, which are gentle on the skin, and for intimate and body cosmetics. In addition to other desirable properties, they improve the dermatological properties of anionic and nonionic surfactants and cause the skin to feel pleasant. Furthermore, the betaines can also be used to advantage in cleansing agents, such as dish rinsing aids and detergents for delicate fabrics.
  • amidopropyl betaines of the state of the art, particularly fatty acid amidopropyl betaines are used, the fatty acid groups of which generally have 8 to 18 or 12 to 18 carbon atoms in the mixture.
  • the amidopropyl betaines of coconut oil fatty acids with the following composition, has proven to be particularly effective;
  • An object of the present invention is aqueous, surfactant preparation for cosmetic purpose and detergents.
  • surfactant preparations which contain, as surfactants, betaines of the general formula ##STR2## in which R is an alkyl group with 7 to 21 carbon atoms, 20 to 100% by weight of the betaines used as R group being an alkyl group with 7 to 9 carbon atoms, in an amount of 1.0 to 40% by weight of the preparation used.
  • inventive preparations are appreciably milder and less irritant than those of the state of the art and lead to only slight or practically no irritations when used, for example, for face lotions, shampoos or lotions.
  • German patent 30 11 549 teaches that alkyl ether sulfates, which have a larger proportion of alkyl groups with 14 carbon atoms, produce milder formulations than do alkyl ether sulfates, which have a larger proportion of groups with 12 carbon atoms and a smaller proportion of groups with 14 carbon atoms.
  • inventive preparations contain these betaines in an amount of 1.5 to 20% by weight, based on the preparation.
  • compositions in which more than 90% by weight of the betaines used have an alkyl group with 7 to 9 carbon atoms.
  • the inventive preparations may contain anionic surfactants.
  • anionic surfactants particularly alkyl ether sulfate and furthermore monoglyceride sulfates, alkyl ether carboxylic acids and their alkali salts may be mentioned as mild, skin-compatible detergents.
  • Long-chain acyl sarcosinates or their alkali salts, such as sodium lauroyl sarcosinate, are a further preferred class of anionic surfactants.
  • anionic surfactants suitable within the scope of the invention are alpha-olefin sulfonates, alkyl sulfates and their salts and, in particular, alkali salts of half esters of sulfosuccinic acid.
  • inventive preparations can furthermore also contain nonionic surfactants.
  • a preferred nonionic surfactant belongs to the class of alkyl polyglucosides of the general formula
  • R is an alkyl group with 8 to 18 carbon atoms
  • R 1 is an ethylene or propylene group
  • Z is a saccharide group with 5 to 6 carbon atoms
  • n is a number from 0 to 10 and x is a number between 1 and 5.
  • alkyl polyglucosides of the above-named general formula are preferred as nonionic surfactants in the inventive compositions, it is also possible to use other nonionic surfactants instead of the ones mentioned or preferably a mixture thereof.
  • nonionic surfactants are, for example, fatty acid esters of multihydric alcohols, such as glycerin, fatty acid polyglycol esters, fatty alcohol ethoxylates and mixed products of ethylene oxide and propylene oxide.
  • Other nonionic surfactant components may be amine oxides and fatty acid monoalkanolamides and dialkanolamides.
  • inventive, mild, aqueous, surfactant preparations may contain all materials normally used in such agents.
  • stabilizers perfume oils, thickeners, which can originate from the group of associative thickeners or the group of polymeric thickeners, such as polyacrylic acid and its derivatives, cellulose derivatives and alginates, dyes, conditioning and cosmetic components, such as cationic, amphoteric polymers, lanolin derivatives, cholesterol, pentothenic acid, polydimethylsiloxanes or their derivatives, preservatives, with the exception of hinokitiol, etc.
  • associative thickeners such as polyacrylic acid and its derivatives, cellulose derivatives and alginates, dyes, conditioning and cosmetic components, such as cationic, amphoteric polymers, lanolin derivatives, cholesterol, pentothenic acid, polydimethylsiloxanes or their derivatives, preservatives, with the exception of hinokitiol, etc.
  • polymeric thickeners such as polyacrylic acid and its derivatives, cellulose derivatives and alginates, dyes, conditioning and cosmetic components, such as cati
  • a hypoirritant surfactant preparation similar to the one herein disclosed, was taught by Hayakawa, EP 500,946.
  • Hayakawa requires the use of hinokitoil or a salt thereof, as a necessary ingredient.
  • the inventor of the herein disclosed compound has found that a less irritating compound can be made if hinokitoil is excluded. Further, this less irritating compound is better suited for some of the disclosed applications such as cosmetic preparations.
  • the inventive products are prepared by stirring the individual components together in water. Mixtures of different components can also be used.
  • the physiological compatibility of fatty acid amidopropyl betaines, derived from fatty acids of different chain lengths, is investigated with the help of an in vitro method, the erythrocyte test (RBC).
  • RBC test is described by J. W. Pape and U. Hoppe in the journal, Arzneim.-Forsch./Drug Res. 40, 498, (1990) and is carried out as described there.
  • the destruction of blood cells by lysis and the denaturing of the hemoglobin released were measured for characterizing the typical irritative interactions of surfactants with whole cell structure.
  • the result is expressed as L/D, the quotient of lysis (L) and denaturing (D). The smaller the L/D value, the more irritating is the substance or formulation.
  • the Table shows that the irritating action of the betaines on the skin and mucous membrane increases with the length of the alkyl chain.
  • the short-chain fatty acid amidopropyl betaines which are derived from caprylic and capric acids, exert practically no irritating effect.
  • Mild surfactant formulations are produced from C 8 /C 10 betaine and coconut oil fatty acid amidopropyl betaine (coconut oil betaine) and differ with respect to their C 8 /C 10 betaine and coconut oil betaine content.
  • the C 8 /C 10 betaine is composed of equal parts of C 8 and C 10 betaines.
  • the coconut oil betaine is characterized by the following distribution of fatty acids:
  • composition of the formulations and their irritant effect are listed in Table 2.
  • Mild surfactant formulations are produced from C 8 /C 10 betaine and the surfactants described below. These formulations are compared with similar formulations based on C 12 betaine or coconut oil fatty acid amidopropyl betaine. In each case, the formulations contain 10% of active betaine substance and 5% of the active second surfactant substance. Aside from water, the formulations do not contain any other components.
  • the C 8 /C 10 is composed of equal parts of C 8 betaine and C 10 betaine.
  • the composition of the coconut oil fatty acid amidopropyl betaine is identical with that of the product used in Example 2.
  • the surfactants used in addition to the betaines are:
  • LSSDNa lauryl sulfosuccinate
  • NaLSC sodium lauroyl sarcosinate
  • APG lauroyl polyglucoside
  • composition of the formulations and their irritant action determined by the RBC test, are listed in Table 3.
  • Mild surfactant formulations are produced from C 8 /C 10 betaine and three other surfactants, which are described in Example 3.
  • the formulations contain 5 to 10% C 8 /C 10 betaine and 10 to 5% of the disodium salt of lauryl sulfosuccinate (LSSDNa), sodium lauroyl sarcosinate (NaLSC) or sodium lauryl polyglucoside (APG).
  • LSSDNa lauryl sulfosuccinate
  • NaLSC sodium lauroyl sarcosinate
  • APG sodium lauryl polyglucoside

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to mild, aqueous, surfactant preparations for cosmetic purposes and as detergents. These preparations contain, as surfactants, betaines of the general formula <IMAGE> in which R is an alkyl group with 7 to 21 carbon atoms, 20 to 100% by weight of the betaines used as R group having an alkyl group with 7 to 9 carbon atoms, in an amount of 1.0 to 40% by weight of the preparation used. These preparations are distinguished by their exceptionally mild and low irritating properties when used, for example, in face lotions, shampoos or lotions.

Description

This is a continuation-in-part application of Ser. No. 08/549,905, filed Oct. 30, 1995.
FIELD OF THE INVENTION
The invention relates to mild, aqueous, surfactant preparations for cosmetic purpose and detergents.
BACKGROUND INFORMATION AND PRIOR ART
Betaines and, particularly amidopropyl betaines, are used as amphoteric surfactants especially for hair preparations and in cleansing agent preparations for the skin, such as shampoos, foam gels and shower gels, which are gentle on the skin, and for intimate and body cosmetics. In addition to other desirable properties, they improve the dermatological properties of anionic and nonionic surfactants and cause the skin to feel pleasant. Furthermore, the betaines can also be used to advantage in cleansing agents, such as dish rinsing aids and detergents for delicate fabrics.
As betaines of the state of the art, particularly fatty acid amidopropyl betaines are used, the fatty acid groups of which generally have 8 to 18 or 12 to 18 carbon atoms in the mixture. The amidopropyl betaines of coconut oil fatty acids, with the following composition, has proven to be particularly effective;
Fatty acid group with 8 carbon atoms ca. 7%
Fatty acid group with 10 carbon atoms ca. 6%
Fatty acid group with 12 carbon atoms ca. 49%
Fatty acid group with 14 carbon atoms ca. 19%
Fatty acid group with 16 carbon atoms ca. 9%
Fatty acid group with 18 carbon atoms ca. 10%
Even though mild surfactant formulations can be prepared with amidopropyl betaines of coconut oil fatty acids, conventional, commercial, aqueous solutions of the betaine or their dilutions with water have a distinct irritant potential, which can be determined in tests on the skin and mucous membranes, and also by modern in vitro test methods for determining the irritant effect, such as the erythrocyte test.
Aside from this, the constant demands of the consumer for milder cosmetic preparations and cleansing agents make it necessary to have particularly mild surfactants available.
It is therefore an object of the invention to find exceptionally mild, low-irritant preparations, which satisfy the demands of high skin compatibility.
OBJECT OF THE INVENTION
An object of the present invention is aqueous, surfactant preparation for cosmetic purpose and detergents.
SUMMARY OF THE INVENTION
Surprisingly, surfactant preparations were found, which contain, as surfactants, betaines of the general formula ##STR2## in which R is an alkyl group with 7 to 21 carbon atoms, 20 to 100% by weight of the betaines used as R group being an alkyl group with 7 to 9 carbon atoms, in an amount of 1.0 to 40% by weight of the preparation used.
These inventive preparations are appreciably milder and less irritant than those of the state of the art and lead to only slight or practically no irritations when used, for example, for face lotions, shampoos or lotions.
It was surprising that especially betaines with a relatively short-chain fatty acid group show these particularly mild properties, because increased irritating properties were assigned in the technical literature especially to those surfactants, which are distinguished by short-chain fatty acid groups.
For example, it can be inferred from the publication Seifen-Ole-Fette-Wachse, vol. 93, No. 15/1967 of Jul. 19, 1967, on page 521 that the dermatological properties of surfactants with shorter alkyl chains are less satisfactory. It is therefore recommended that surfactants with alkyl chain 12 to 14 or 12 to 18 carbon atoms be used in the cosmetic sector.
In the same sense, the German patent 30 11 549 teaches that alkyl ether sulfates, which have a larger proportion of alkyl groups with 14 carbon atoms, produce milder formulations than do alkyl ether sulfates, which have a larger proportion of groups with 12 carbon atoms and a smaller proportion of groups with 14 carbon atoms.
It is advisable that the inventive preparations contain these betaines in an amount of 1.5 to 20% by weight, based on the preparation.
It is of advantage if 40 to 100% by weight of these betaines have an alkyl group with 7 to 9 carbon atoms.
Particularly preferred are preparations, in which more than 90% by weight of the betaines used have an alkyl group with 7 to 9 carbon atoms.
The inventive preparations may contain anionic surfactants. As suitable anionic surfactants, particularly alkyl ether sulfate and furthermore monoglyceride sulfates, alkyl ether carboxylic acids and their alkali salts may be mentioned as mild, skin-compatible detergents.
Long-chain acyl sarcosinates or their alkali salts, such as sodium lauroyl sarcosinate, are a further preferred class of anionic surfactants.
Other anionic surfactants suitable within the scope of the invention are alpha-olefin sulfonates, alkyl sulfates and their salts and, in particular, alkali salts of half esters of sulfosuccinic acid.
The inventive preparations can furthermore also contain nonionic surfactants. A preferred nonionic surfactant belongs to the class of alkyl polyglucosides of the general formula
R--O(R.sup.1 O).sub.n --Z.sub.x
wherein R is an alkyl group with 8 to 18 carbon atoms, R1 is an ethylene or propylene group, Z is a saccharide group with 5 to 6 carbon atoms, n is a number from 0 to 10 and x is a number between 1 and 5.
Although alkyl polyglucosides of the above-named general formula are preferred as nonionic surfactants in the inventive compositions, it is also possible to use other nonionic surfactants instead of the ones mentioned or preferably a mixture thereof. Such other nonionic surfactants are, for example, fatty acid esters of multihydric alcohols, such as glycerin, fatty acid polyglycol esters, fatty alcohol ethoxylates and mixed products of ethylene oxide and propylene oxide. Other nonionic surfactant components may be amine oxides and fatty acid monoalkanolamides and dialkanolamides.
The inventive, mild, aqueous, surfactant preparations may contain all materials normally used in such agents.
Named as such are stabilizers, perfume oils, thickeners, which can originate from the group of associative thickeners or the group of polymeric thickeners, such as polyacrylic acid and its derivatives, cellulose derivatives and alginates, dyes, conditioning and cosmetic components, such as cationic, amphoteric polymers, lanolin derivatives, cholesterol, pentothenic acid, polydimethylsiloxanes or their derivatives, preservatives, with the exception of hinokitiol, etc.
A hypoirritant surfactant preparation, similar to the one herein disclosed, was taught by Hayakawa, EP 500,946. However, Hayakawa requires the use of hinokitoil or a salt thereof, as a necessary ingredient. The inventor of the herein disclosed compound has found that a less irritating compound can be made if hinokitoil is excluded. Further, this less irritating compound is better suited for some of the disclosed applications such as cosmetic preparations.
The inventive products are prepared by stirring the individual components together in water. Mixtures of different components can also be used.
The surprisingly mild action of the betaines in inventive preparations, the fatty acid groups of which are derived to the extent of more than 20% from C8 /C10 fatty acids, is shown by means of the following comparison examples. The percentages given are percentages by weight. It is understood that the following examples are provided by way of illustration and not by way of limitation.
EXAMPLE 1
The physiological compatibility of fatty acid amidopropyl betaines, derived from fatty acids of different chain lengths, is investigated with the help of an in vitro method, the erythrocyte test (RBC). The RBC test is described by J. W. Pape and U. Hoppe in the journal, Arzneim.-Forsch./Drug Res. 40, 498, (1990) and is carried out as described there.
The destruction of blood cells by lysis and the denaturing of the hemoglobin released were measured for characterizing the typical irritative interactions of surfactants with whole cell structure. The result is expressed as L/D, the quotient of lysis (L) and denaturing (D). The smaller the L/D value, the more irritating is the substance or formulation.
The results are summarized in Table 1. The following abbreviated formulation is used for the fatty acid amidopropyl betaines used: ##STR3##
              TABLE 1                                                     
______________________________________                                    
Betaine    L             D     L/D                                        
______________________________________                                    
C.sub.8 -Betaine                                                          
               no hemolysis                                               
                           >>100                                          
C.sub.10 -Betaine                                                         
               no hemolysis                                               
                           >>100                                          
C.sub.12 -Betaine                                                         
           151           17    8.9                                        
C.sub.14 -Betaine                                                         
            13           9.2   1.4                                        
C.sub.16 -Betaine                                                         
           4.4           4.4   1.0                                        
______________________________________
The Table shows that the irritating action of the betaines on the skin and mucous membrane increases with the length of the alkyl chain. The short-chain fatty acid amidopropyl betaines, which are derived from caprylic and capric acids, exert practically no irritating effect.
EXAMPLE 2
Mild surfactant formulations are produced from C8 /C10 betaine and coconut oil fatty acid amidopropyl betaine (coconut oil betaine) and differ with respect to their C8 /C10 betaine and coconut oil betaine content. The C8 /C10 betaine is composed of equal parts of C8 and C10 betaines. The coconut oil betaine is characterized by the following distribution of fatty acids:
______________________________________                                    
       C.sub.8 -betaine                                                   
               7.2%                                                       
       C.sub.10 -betaine                                                  
               5.8%                                                       
       C.sub.12 -betaine                                                  
               49.0%                                                      
       C.sub.14 -betaine                                                  
               18.6%                                                      
       C.sub.16 -betaine                                                  
               9.1%                                                       
       C.sub.18 -betaine                                                  
               10.3%                                                      
______________________________________
The composition of the formulations and their irritant effect, as determined by the RBC test, are listed in Table 2.
              TABLE 2                                                     
______________________________________                                    
Formula      A         B     C      D   E                                 
______________________________________                                    
C.sub.8 /C.sub.10 -Betaine (%)                                            
             15        --    5      7.5 10                                
Coconut Oil                                                               
Betaine (%)  --        15    10     7.5  5                                
Proportion of                                                             
              100      13    42     57  72                                
C.sub.8 /C.sub.10 in betaine                                              
(%)                                                                       
L            --        24    37     51  75                                
D            --        8.4   3.2    2.2 2.2                               
L/D          >>100     2.9   11     23  34                                
______________________________________
The results show that the irritating effect of the betaine decreases clearly and its compatibility increases clearly as the content of C8 /C10 portions increases.
EXAMPLE 3
Mild surfactant formulations are produced from C8 /C10 betaine and the surfactants described below. These formulations are compared with similar formulations based on C12 betaine or coconut oil fatty acid amidopropyl betaine. In each case, the formulations contain 10% of active betaine substance and 5% of the active second surfactant substance. Aside from water, the formulations do not contain any other components.
As in Example 2, the C8 /C10 is composed of equal parts of C8 betaine and C10 betaine. The composition of the coconut oil fatty acid amidopropyl betaine is identical with that of the product used in Example 2.
The surfactants used in addition to the betaines are:
the disodium salt of lauryl sulfosuccinate (LSSDNa), commercially obtainable under the name of TEGO SULFOSUCCINATE F 30 (Th. Goldschmidt AG);
sodium lauroyl sarcosinate (NaLSC), commercially obtainable under the name of Hamposyl L 30 (Grace); and
lauroyl polyglucoside (APG) commercially obtainable under the name of Plantaren 1200 (Henkel).
The composition of the formulations and their irritant action, determined by the RBC test, are listed in Table 3.
              TABLE 3                                                     
______________________________________                                    
       LSSDNa    NaLSC       APG                                          
       L   D      L/D    L    D   L/D  L   D   L/D                        
______________________________________                                    
C.sub.8 /C.sub.10 -betaine                                                
         *     22     >100 563  20  28   no hem                           
                                               >>100                      
         )                                                                
C.sub.12 -betaine                                                         
         4     13     3.8  84   18  4.7  81  <1  >100                     
         9                                                                
Coconut oil                                      >100                     
betaine  2     4.6    4.8  36   12  3.0  46  <1                           
         2                                                                
______________________________________                                    
 hem = hemolysis, *) = no complete hemolysis
The results make it clear that surfactant formulations, which are based on C8 /C10 betaine, have a distinctly lower irritant effect than do those, which are based on C12 betaine or coconut oil betaine.
EXAMPLE 4
Mild surfactant formulations are produced from C8 /C10 betaine and three other surfactants, which are described in Example 3. The formulations contain 5 to 10% C8 /C10 betaine and 10 to 5% of the disodium salt of lauryl sulfosuccinate (LSSDNa), sodium lauroyl sarcosinate (NaLSC) or sodium lauryl polyglucoside (APG). Those which contain 10% C8 /C10 betaine, are identical with the ones described in Example 3. The formulations are tested with the RBC test for their physiological compatibility. The results are shown in Table 4.
                                  TABLE 4                                 
__________________________________________________________________________
Formulation                                                               
      F   G  H   I  K   L  N   N   O                                      
__________________________________________________________________________
C.sub.8 /C.sub.10                                                         
betaine(%)                                                                
      10  7.5                                                             
             5   10 7.5 5  10  7.5 5                                      
LSSDNa (%)                                                                
      5   7.5                                                             
             10  -- --  -- --  --  --                                     
NaLSC (%)                                                                 
      --  -- --  5  7.5 10 --  --  --                                     
APG (%)                                                                   
      --  -- --  -- --  -- --  7.5 10                                     
L     *   *  *   563                                                      
                    409 307                                               
                           **  **  **                                     
D     22  31 42  20 37  55 --  --  --                                     
L/D   >100                                                                
          >100                                                            
             >100                                                         
                 28.2                                                     
                    11.1                                                  
                        5.6                                               
                           >>100                                          
                               >>100                                      
                                   >>100                                  
__________________________________________________________________________
 * = no complete hemolysis                                                
 ** = no hemolysis
All formulations, shown in Table 4, are very mild. Moreover, it becomes clear that the formulations, which contain the greatest proportion of C8 /C10, are the mildest. For formulations F to H, this is evident from the denaturation values (D) and for formulations I to L, this is evident from the lysis values (L) as well as from, the denaturation values.
EXAMPLE 5 
______________________________________                                    
Formulations                                                              
Face Lotions                                                              
______________________________________                                    
Water                    85.5%                                            
Ethanol                  5.0%                                             
C.sub.8 /C.sub.10 Betaine.sup.1)                                          
                         3.7%                                             
Moisturizer.sup.2)       2.0%                                             
Hamamelis Extract.sup.3) 2.0%                                             
Glycerin-(6)-polyglycol ether caprylate/caprate.sup.4)                    
                         1.5%                                             
Allantoin                0.3%                                             
______________________________________                                    
 .sup.1) 50% aqueous solution                                             
 .sup.2) CTFA name: sodium lactate (and) sodium PCA (and) glycine (and)   
 fructose (and) urea (and) niacinamide (and) inotisotol (and) sodium      
 benzoate (and) lactic acid, commercially obtainable under the name of    
 LACTIL (Th. Goldschmidt, AG)                                             
 .sup.3) Commercially obtainable under the name of Extrapon Hamamelis     
 (Dragoco)                                                                
 .sup.4) CTFA name: PEG6 caprylic/capric glycerides, commercially         
 obtainable under the name of TEGOSOFT GMC6 (Th. Goldschmidt AG)          

______________________________________                                    
Conditioning Shampoo                                                      
______________________________________                                    
Water                   43.1%                                             
Sodium lauryl ether sulfate (28% aqueous                                  
                        32.0%                                             
solution).sup.5)                                                          
C.sub.8 /C.sub.10 betaine.sup.1)                                          
                        22.0%                                             
Polyacrylate-based thickener.sup.6)                                       
                        2.0%                                              
Cationic guar.sup.7)    0.5%                                              
Cationic siloxane (50% solution in propylene                              
                        0.4%                                              
glycol).sup.8)                                                            
Perfume                 0.3%                                              
______________________________________                                    
 .sup.5) CTFA name: Sodium laureth sulfate, commercially obtainable under 
 the name of Texapon N 25 (Henkel)                                        
 .sup.6) CTFA name: Acrylates steareth50 acrylate copolymer (and) laureth3
 (and) propylene glycol, commercially obtainable under the name of ANTIL  
 208 (Th. Goldschmidt AG)                                                 
 .sup.7) CTFA name: Guar hydroxypropyl trimonium chloride, commercially   
 obtainable under the name of Cosmedia Guar C261 (Henkel)                 
 .sup.8) CTFA name: Quaternium 80, commercially obtainable under the name 
 of ABIL Quat 3272 (Th. Goldschmidt AG)                                   

______________________________________                                    
Shower Gel                                                                
______________________________________                                    
Water                   40.0%                                             
Disodium lauryl ether sulfosuccinate.sup.9                                
                        17.3%                                             
C.sub.8 C.sub.10 betaine.sup.1                                            
                        17.0%                                             
Lauryl polyglucoside.sup.10)                                              
                        14.0%                                             
Glycerin-(7)-polyglycol ether coconut oil fatty                           
                        5.0%                                              
acid ester.sup.11)                                                        
Polyacrylate-based thickener.sup.6)                                       
                        4.0%                                              
NaCl                    2.5%                                              
Perfume                 0.2%                                              
______________________________________                                    
 .sup.9 CTFA name: Disodium laurethsulfosuccinate, commercially obtainable
 under the name of TEGO SULFOSUCCINATE F 30 (Th. Goldschmidt)             
 .sup.10) CTFA name: Lauryl polyglucose, commercially obtainable under the
 name of Plantaren 1200 (Henkel)                                          
 .sup.11) CTFA name: PEG7 glyceryl cocoate, commercially obtainable under 
 the name of TEGOSOFT GC (Th. Goldschmidt AG)                             

______________________________________                                    
Baby Shampoo                                                              
______________________________________                                    
Water                   69.5%                                             
Sodium lauryl ether sulfate (28% aqueous                                  
                        15.0%                                             
solution).sup.5)                                                          
Coconut oil fatty acid amidopropyl betaine.sup.12)                        
                        6.0%                                              
Oleic acid/coconut oil fatty acid ester of                                
                        4.0%                                              
glycerin-(18)-polyglycol ether.sup.13)                                    
Tallow fatty acid esters of glycerin (30)-                                
                        3.0%                                              
polyglycol ether.sup.14)                                                  
C8/C10 betaine.sup.1)   1.5%                                              
NaCl                    0.7%                                              
Perfume                 0.3%                                              
______________________________________                                    
 .sup.12) CTFA name: Cocamidopropyl betaine, commercially obtainable under
 the name of Tego Betaine F 50 (Th. Goldschmidt AG).                      
 .sup.13) CTFA name: PEG18 glyceryl oleate/cocoate, commercially obtainabl
 under the name of ANTIL 171 (Th. Goldschmidt AG).                        
 .sup.14) CTFA name: PEG30 glyceryl stearate, commercially obtainable unde
 the name of TAGAT S (Th. Goldschmidt AG)

Claims (5)

What is claimed is:
1. An aqueous, surfactant preparation for cosmetic purposes and detergents, comprising as a surfactant, betaines of a general formula ##STR4## in which R is an alkyl group with 7 to 21 carbon atoms, 20 to 100% by weight of the betaines used having R with an alkyl group with 7 to 9 carbon atoms, in an amount of 1.0 to 40% by weight of the preparation, wherein hinokitiol is not an ingredient.
2. The preparation of claim 1, wherein the betaine is present in an amount of 1.5 to 20% by weight, based on the preparation.
3. The preparation of claims 1 or 2, wherein 40 to 100% by weight of the betaines used have an alkyl group with 7 to 9 carbon atoms as R group.
4. The preparation of claims 1 or 2, wherein more than 90% by weight of the betaines used have an alkyl group with 7 to 9 carbon atoms as R group.
5. The preparation of claims 1 or 2, further comprising anionic, nonionic surfactants or both in an amount of 1.0 to 40% by weight based on the preparation, with the proviso that the total surfactant content does not exceed 60% by weight.
US08/843,552 1994-11-07 1997-04-18 Mild, aqueous, surfactant preparation for cosmetic purposes and as detergent Expired - Lifetime US5792737A (en)

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Application Number Priority Date Filing Date Title
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Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4439642A DE4439642C1 (en) 1994-11-07 1994-11-07 Non irritant aq. surfactant formulations useful as mild shampoos, face lotions or body care prods.
DE4439642.2 1994-11-07
US54990595A 1995-10-30 1995-10-30
US08/843,552 US5792737A (en) 1994-11-07 1997-04-18 Mild, aqueous, surfactant preparation for cosmetic purposes and as detergent

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WO2003007892A3 (en) * 2001-07-07 2003-12-11 Beiersdorf Ag Cosmetic and dermatological preparations containing electrolyte, for the treatment and active prevention of dry skin and other negative changes in the physiological homeostasis of the skin
US20030232135A1 (en) * 2002-05-31 2003-12-18 Kimberly-Clark Worldwide, Inc. Application of foam to tissue products using a liquid permeable partition
US20040079502A1 (en) * 2002-10-28 2004-04-29 Kimberly-Clark Worldwide,Inc. Process for applying a liquid additive to both sides of a tissue web
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US6852196B2 (en) 2000-11-08 2005-02-08 Kimberly-Clark Worldwide, Inc. Foam treatment of tissue products
US6949168B2 (en) 2002-11-27 2005-09-27 Kimberly-Clark Worldwide, Inc. Soft paper product including beneficial agents
US6964725B2 (en) 2002-11-06 2005-11-15 Kimberly-Clark Worldwide, Inc. Soft tissue products containing selectively treated fibers
US6977026B2 (en) 2002-10-16 2005-12-20 Kimberly-Clark Worldwide, Inc. Method for applying softening compositions to a tissue product
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EP1671621A1 (en) * 2004-12-16 2006-06-21 KPSS-Kao Professional Salon Services GmbH Shampoo composition
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US8143205B2 (en) 2008-02-21 2012-03-27 S.C. Johnson & Son, Inc. Cleaning composition having high self-adhesion and providing residual benefits
KR101133254B1 (en) 2006-01-10 2012-04-09 주식회사 서울화장품 Low irritant oil detergent composition for bath
US8980813B2 (en) 2008-02-21 2015-03-17 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion on a vertical hard surface and providing residual benefits
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US9410111B2 (en) 2008-02-21 2016-08-09 S.C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US9481854B2 (en) 2008-02-21 2016-11-01 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US20240065959A1 (en) * 2022-08-31 2024-02-29 Blessing Solutions LLC Odor eliminating composition with morpholinium and alginate compounds

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US6514918B1 (en) 2000-08-18 2003-02-04 Johnson & Johnson Consumer Companies, Inc. Viscous, mild, and effective cleansing compositions
US6607783B1 (en) 2000-08-24 2003-08-19 Kimberly-Clark Worldwide, Inc. Method of applying a foam composition onto a tissue and tissue products formed therefrom
US6852196B2 (en) 2000-11-08 2005-02-08 Kimberly-Clark Worldwide, Inc. Foam treatment of tissue products
US6518229B2 (en) 2000-12-06 2003-02-11 Playtex Products, Inc. Antibacterial composition comprising an amphoteric/anionic surfactant mixture
US20020157943A1 (en) * 2001-04-06 2002-10-31 Oliver Thurmuller Process for the preparation of glycine derivatives and use thereof
US6663764B2 (en) * 2001-04-06 2003-12-16 Goldschmidt Ag Process for the preparation of glycine derivatives and use thereof
WO2003007892A3 (en) * 2001-07-07 2003-12-11 Beiersdorf Ag Cosmetic and dermatological preparations containing electrolyte, for the treatment and active prevention of dry skin and other negative changes in the physiological homeostasis of the skin
US20030118848A1 (en) * 2001-12-21 2003-06-26 Kou-Chang Liu Method for the application of hydrophobic chemicals to tissue webs
US6805965B2 (en) 2001-12-21 2004-10-19 Kimberly-Clark Worldwide, Inc. Method for the application of hydrophobic chemicals to tissue webs
US20030232135A1 (en) * 2002-05-31 2003-12-18 Kimberly-Clark Worldwide, Inc. Application of foam to tissue products using a liquid permeable partition
US6797319B2 (en) 2002-05-31 2004-09-28 Kimberly-Clark Worldwide, Inc. Application of foam to tissue products using a liquid permeable partition
US6797116B2 (en) 2002-05-31 2004-09-28 Kimberly-Clark Worldwide, Inc. Method of applying a foam composition to a tissue product
US6835418B2 (en) 2002-05-31 2004-12-28 Kimberly-Clark Worldwide, Inc. Use of gaseous streams to aid in application of foam to tissue products
US20030224106A1 (en) * 2002-05-31 2003-12-04 Kimberly-Clark Worldwide, Inc. Use of gaseous streams to aid in application of foam to tissue products
US6977026B2 (en) 2002-10-16 2005-12-20 Kimberly-Clark Worldwide, Inc. Method for applying softening compositions to a tissue product
US20040079502A1 (en) * 2002-10-28 2004-04-29 Kimberly-Clark Worldwide,Inc. Process for applying a liquid additive to both sides of a tissue web
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US20080171684A1 (en) * 2002-11-04 2008-07-17 The Procter & Gamble Company Liquid laundry detergent
US7439217B2 (en) * 2002-11-04 2008-10-21 The Procter & Gamble Company Liquid laundry detergent comprising a cationic silicone polymer and a coacervate phase forming cationic polymer
US20040092425A1 (en) * 2002-11-04 2004-05-13 The Procter & Gamble Company Liquid laundry detergent
US7273837B2 (en) * 2002-11-04 2007-09-25 The Procter & Gamble Company Liquid laundry detergent comprising cationic silicone block copolymers
US7029756B2 (en) 2002-11-06 2006-04-18 Kimberly-Clark Worldwide, Inc. Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties
US6964725B2 (en) 2002-11-06 2005-11-15 Kimberly-Clark Worldwide, Inc. Soft tissue products containing selectively treated fibers
US6949168B2 (en) 2002-11-27 2005-09-27 Kimberly-Clark Worldwide, Inc. Soft paper product including beneficial agents
US7101460B2 (en) 2002-11-27 2006-09-05 Kimberly-Clark Worldwide, Inc. Soft paper product including beneficial agents
US7396593B2 (en) 2003-05-19 2008-07-08 Kimberly-Clark Worldwide, Inc. Single ply tissue products surface treated with a softening agent
US20060135382A1 (en) * 2004-12-16 2006-06-22 Kpss-Kao Professional Salon Services Gmbh Shampoo composition
US7268105B2 (en) * 2004-12-16 2007-09-11 Kpss-Kao Professional Salon Services Gmbh Shampoo composition comprising a mixture of glyceryl esters
US20080255014A1 (en) * 2004-12-16 2008-10-16 Georgia-Pacific Consumer Products Lp Antimicrobial foam hand soap
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US20090175761A1 (en) * 2004-12-16 2009-07-09 Luu Phuong V Hand-washing method utilizing antimicrobial liquid hand soap compositions with tactile signal
US7795196B2 (en) 2004-12-16 2010-09-14 Georgia-Pacific Consumer Products Lp Hand-washing method utilizing antimicrobial liquid hand soap compositions with tactile signal
US7803746B2 (en) * 2004-12-16 2010-09-28 Georgia-Pacific Consumer Products Lp Antimicrobial foam hand soap comprising inulin or an inulin surfactant
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US20090054521A1 (en) * 2007-08-23 2009-02-26 Evonik Goldschmidt Gmbh Zwitterionic compounds and use thereof
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