US569722A - Plating apparatus - Google Patents
Plating apparatus Download PDFInfo
- Publication number
- US569722A US569722A US569722DA US569722A US 569722 A US569722 A US 569722A US 569722D A US569722D A US 569722DA US 569722 A US569722 A US 569722A
- Authority
- US
- United States
- Prior art keywords
- copper
- scrap
- shoe
- cage
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007747 plating Methods 0.000 title description 4
- 229910052802 copper Inorganic materials 0.000 description 36
- 239000010949 copper Substances 0.000 description 36
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 20
- 239000004020 conductor Substances 0.000 description 14
- 239000003792 electrolyte Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000006011 modification reaction Methods 0.000 description 6
- 239000003923 scrap metal Substances 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 230000000284 resting Effects 0.000 description 4
- 238000000151 deposition Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000036633 rest Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
- C25D17/12—Shape or form
Definitions
- a very common method of forming and employing the anodes in copper electrolytic tanks for depositing copper and other metals is to make the anodes in the form of a plate having suspendingears through which the current is introduced. After such an anode has been in some time it becomes deeply corroded, and in some instances the upper portion is cut through by the corrosion near the surface of the liquid, so that the bottom part falls away; but in any case the entire anode cannot be utilized, owing to the irregularity of the corrosion and to the fact that the upper portion is usually above the surface of the electrolyte. It is customary to take the remaining portions of the corroded anodes, remelt them, and cast new anodes. This remelting, relinin g, and recastin g of the waste portions of anodes is a considerable item in the ruiming expenses of large clectrolytic plants.
- the object of the present invention is to save this expense. Moreover, anodes such as I have just described frequently corrode at the surface of the solution and permit the main part to break oli? and fall into the tank, shortcircuiting art of the tank and very often cutting a hole in the lead bottom or lining, damaging the apparatus and necessitating stoppage and repairs. By my invention this defect and consequent expense is also remedied.
- FIG. 1 is a sectional view lookingendwise and showing a plating-tank containing my anode-cage.
- Fig. 2 is a plan View of my anodecage and its leading-in strap or terminal connection ior the current.
- Fig. 3 is a view similarto Fig. l, showinga modication; and Fig. shows a further modification.
- Hy anode A is a hasket,hox,cage,or other receptacle,resting upon insulators B, which in turn rest on leadcovered supports B, preferahl y provided with passages or channels b to facilitate the washing out of the tank.
- Mycage as illustrated in the drawings, has quarter-inch perforations through its surface to permit the free circulation of the electrolyte and the passage of current through it.
- the anode shown in Figs. l and 2 is preferably ot' lead and forms the conductor between the strap O and the scrap-copper.
- Fig. 3 shows a modification in which the current is led directly from a copper shoe C into the scrap-copper.
- the cage may he of either conducting or non-conducting material, though it' of non-conductingl material enough copper-scrap must always be kept in the cage to insure the contact of the shoe C' with the scrap.
- the cop ⁇ per-scrap need not necessarily touch the copper shoe C', as, when the scrap has been eaten away beneath the shoe, the shoe descends until it rests upon the upper edge of the anode, and after that the action is 'identical with Fig. l, the current passing first into the wall of the cage and thence to the copper-scrap within the cage.
- the shoe C' is provided with the ears c, which project or rest upon the edge of the cage when the scrap has been eaten away, allowing the shoe to descend, By this means the shoe is prevented from sinking into the electrolyte and being corroded; but the cage should be kept so full of scrap that the shoes at no time come in contact with-the edge of the tank, as the purpose of this construction is to transmit. the current directly from the shoe G to the scrap-copper.
- the shoe C is connected with the positive conductor by means of short iexible connection E', which permits the fall of the shoe as the scrap is eaten away, and also facilitates the refilling, it being only necessary to lift up the shoe and throw in some more scrap and then replace the shoe.
- Fig. 4 my most preferred construction is Shown.
- the cage A is in the form of a hollow plate, and the copper strap or band C is provided with copper bails E', by which the cage is suspended from the combined support and conducting-bar F.
- This bar may either rest upon or be secured to the common terminal connection which supplies current to all the anodes.
- the bar F is raised, lifting the anode from the bath and permitting it to be conveniently filled and replaced.
- the anode consisting of a perforated receptacle A filled with broken or scrap metal, the conducting-shoe C resting upon and above the said scrap metal, and the flexible conductor leading to the said shoe, whereby, as the scrap metal is corroded, the
- said shoe may descend by its own weight, substantially as set forth.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Description
(NnMoaex.)
J. T. MORROW.
, PLATIN@ APPARATUS. No. 569,722. Patented 001:. 20,` 1896.
,F251 A j@ 5. 50W.
""'fooopooo 00000000 "0040000000 0000000000 :00000000000 0000000000 0000000000 oooooooooool, 100000000000 0000000000 'z' 0000.000000 200000000000. 00000000000 1;;/0000000000 000000000@ '000000000001?@ lT I 00000000000 2 0000000000 :jjj 0000000000 -pft ooooooooooouj'r 'nu norms #aus oo.. woraufwn.. weulucnnu. n c
PATENTA Prien.
JOHN T. MORROlV, OF GREAT FALLS, MONTANA.
PLATlNG APPARATUS.
SPECIFICATION forming part of Letters Patent No. 569,722, dated October 20, 1896.
Application filed April 5, 1895. Serial No. 544,591. (No model.)
Be it known that I, JOHN T. MORROW, of Great Falls, Montana, have invented a new and useful Improvementin Plating Apparatus, of which the following is a description, re ferring to the accompanying drawings, which form a part of this specieation.
The purpose of my invent-ion is to improve and cheapen the present prevailing methods of employing anodes in platin g-tanks and other apparatus.
A very common method of forming and employing the anodes in copper electrolytic tanks for depositing copper and other metals is to make the anodes in the form of a plate having suspendingears through which the current is introduced. After such an anode has been in some time it becomes deeply corroded, and in some instances the upper portion is cut through by the corrosion near the surface of the liquid, so that the bottom part falls away; but in any case the entire anode cannot be utilized, owing to the irregularity of the corrosion and to the fact that the upper portion is usually above the surface of the electrolyte. It is customary to take the remaining portions of the corroded anodes, remelt them, and cast new anodes. This remelting, relinin g, and recastin g of the waste portions of anodes is a considerable item in the ruiming expenses of large clectrolytic plants.
The object of the present invention is to save this expense. Moreover, anodes such as I have just described frequently corrode at the surface of the solution and permit the main part to break oli? and fall into the tank, shortcircuiting art of the tank and very often cutting a hole in the lead bottom or lining, damaging the apparatus and necessitating stoppage and repairs. By my invention this defect and consequent expense is also remedied.
My invention is of such a nature that it will be readily understood from the accompanyihg` drawings, wherein Figure 1 is a sectional view lookingendwise and showing a plating-tank containing my anode-cage. Fig. 2 is a plan View of my anodecage and its leading-in strap or terminal connection ior the current. Fig. 3 is a view similarto Fig. l, showinga modication; and Fig. shows a further modification.
Throughout the drawings like letters ot' reference indicate like parts.
The tank is shown. at T, containing the electrolytic solution S. The leaden lining of the tank is indicated at t. Hy anode A is a hasket,hox,cage,or other receptacle,resting upon insulators B, which in turn rest on leadcovered supports B, preferahl y provided with passages or channels b to facilitate the washing out of the tank. Mycage, as illustrated in the drawings, has quarter-inch perforations through its surface to permit the free circulation of the electrolyte and the passage of current through it. Into this cage or receptacle l throw the small pieces of metal or scraps from the partially-corroded anodeplates, filling it well up, and I connect this mass with the positive conductor of the plant by means of a copper rim or strap C, running around the upper edge ot the tank, asV shown in Figs. l and 2, and provided with the ear or terminal projection E, which is secured directly to the positive conductor.
lVhen the plant is in operation, the current is led in through the ear E and strap C, passing directly through the walls ot' the anodeeage A into the scrap-copper, and passing from the surface of the scrap-copper into the electrolyte, causing the oxidation of the copper and the enrichment ot' the electrolyte. It is clear that so long as the material ot the cage is less oxidizable than the.scrapeopper in the electrolyte only the scrap-copper will be attacked by the solution, and, with the copper solution used, no local electrolytie action will take place, the scrap-copper serving, therefore, only to enrich the solution as the copper is taken from it and deposited upon the cathode.
The anode shown in Figs. l and 2 is preferably ot' lead and forms the conductor between the strap O and the scrap-copper. In Fig. 3, however, I show a modification in which the current is led directly from a copper shoe C into the scrap-copper. In this case the cage may he of either conducting or non-conducting material, though it' of non-conductingl material enough copper-scrap must always be kept in the cage to insure the contact of the shoe C' with the scrap. If the anode is of conducting material, however, the cop` per-scrap need not necessarily touch the copper shoe C', as, when the scrap has been eaten away beneath the shoe, the shoe descends until it rests upon the upper edge of the anode, and after that the action is 'identical with Fig. l, the current passing first into the wall of the cage and thence to the copper-scrap within the cage. The shoe C' is provided with the ears c, which project or rest upon the edge of the cage when the scrap has been eaten away, allowing the shoe to descend, By this means the shoe is prevented from sinking into the electrolyte and being corroded; but the cage should be kept so full of scrap that the shoes at no time come in contact with-the edge of the tank, as the purpose of this construction is to transmit. the current directly from the shoe G to the scrap-copper. The shoe C is connected with the positive conductor by means of short iexible connection E', which permits the fall of the shoe as the scrap is eaten away, and also facilitates the refilling, it being only necessary to lift up the shoe and throw in some more scrap and then replace the shoe.
In Fig. 4 my most preferred construction is Shown. The cage A is in the form of a hollow plate, and the copper strap or band C is provided with copper bails E', by which the cage is suspended from the combined support and conducting-bar F. This bar may either rest upon or be secured to the common terminal connection which supplies current to all the anodes. To refill this form of my cage, the bar F is raised, lifting the anode from the bath and permitting it to be conveniently filled and replaced. n
From the foregoing it is clear that by my invention I may utilize the scrap-copper directly without necessitating the remelting, refining, and recasting into eectrodes. It is also clear that, so far as nay-invention is con'- cerned, in the place of a perforated cage or receptacle any open -Work construction or other form having passages permitting the ready access of the electrolyte may be employed.
I will not attempt to enumerate the various modifications which may be made Without departing from the principles of my invention, because so to do would obscure rather than make clear the more essential features.
I claim, however, and desire to secure by these Letters Patent, with such limitations as are expressed or by law implied in View of the related arts, as follows:
In combination, the anode consisting of a perforated receptacle A filled with broken or scrap metal, the conducting-shoe C resting upon and above the said scrap metal, and the flexible conductor leading to the said shoe, whereby, as the scrap metal is corroded, the
said shoe may descend by its own weight, substantially as set forth.
In testimony whereof I have hereunto set my hand, at Great Falls, Montana, this 14th day of March, A. D. 1895.
JOHN T. MORROVV.
XVitnesses:
W. H. Goonwvn, M. S. BURNS.
Publications (1)
Publication Number | Publication Date |
---|---|
US569722A true US569722A (en) | 1896-10-20 |
Family
ID=2638427
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US569722D Expired - Lifetime US569722A (en) | Plating apparatus |
Country Status (1)
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US (1) | US569722A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2472796A (en) * | 1944-09-06 | 1949-06-14 | Glenn L Martin Co | Anode rod for plating tanks |
US2943984A (en) * | 1958-10-22 | 1960-07-05 | Chicago Dev Corp | Control of oxygen in metals of groups iv-b, v-b, vi-b, and their alloys |
US3782144A (en) * | 1972-09-28 | 1974-01-01 | Globe Union Inc | Security lid for plating container |
US3907659A (en) * | 1974-04-04 | 1975-09-23 | Holmers & Narver Inc | Composite electrode and method of making same |
-
0
- US US569722D patent/US569722A/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2472796A (en) * | 1944-09-06 | 1949-06-14 | Glenn L Martin Co | Anode rod for plating tanks |
US2943984A (en) * | 1958-10-22 | 1960-07-05 | Chicago Dev Corp | Control of oxygen in metals of groups iv-b, v-b, vi-b, and their alloys |
US3782144A (en) * | 1972-09-28 | 1974-01-01 | Globe Union Inc | Security lid for plating container |
US3907659A (en) * | 1974-04-04 | 1975-09-23 | Holmers & Narver Inc | Composite electrode and method of making same |
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