US5611838A - Process for producing an iron melt - Google Patents
Process for producing an iron melt Download PDFInfo
- Publication number
- US5611838A US5611838A US08/350,952 US35095294A US5611838A US 5611838 A US5611838 A US 5611838A US 35095294 A US35095294 A US 35095294A US 5611838 A US5611838 A US 5611838A
- Authority
- US
- United States
- Prior art keywords
- fine
- set forth
- grained
- iron
- carriers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 131
- 238000000034 method Methods 0.000 title claims abstract description 78
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 64
- 239000002893 slag Substances 0.000 claims abstract description 58
- 239000000969 carrier Substances 0.000 claims abstract description 54
- 239000007789 gas Substances 0.000 claims abstract description 51
- 238000010891 electric arc Methods 0.000 claims abstract description 50
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 36
- 239000003245 coal Substances 0.000 claims abstract description 22
- 239000000428 dust Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 239000000571 coke Substances 0.000 claims abstract description 5
- 229910001567 cementite Inorganic materials 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims abstract description 4
- 239000002023 wood Substances 0.000 claims abstract description 4
- 239000007787 solid Substances 0.000 claims description 27
- 229910000831 Steel Inorganic materials 0.000 claims description 21
- 239000010959 steel Substances 0.000 claims description 21
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 15
- 238000007664 blowing Methods 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 7
- 239000012159 carrier gas Substances 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 7
- 239000003345 natural gas Substances 0.000 claims description 7
- 239000003570 air Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 230000001133 acceleration Effects 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims description 2
- 230000002093 peripheral effect Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 abstract description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 13
- 239000000292 calcium oxide Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000010439 graphite Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000000161 steel melt Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 229910018404 Al2 O3 Inorganic materials 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910001341 Crude steel Inorganic materials 0.000 description 1
- 229910005347 FeSi Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000002817 coal dust Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- -1 iron metals Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010891 toxic waste Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
- C21B13/0013—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/12—Making spongy iron or liquid steel, by direct processes in electric furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/527—Charging of the electric furnace
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/08—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces heated electrically, with or without any other source of heat
- F27B3/085—Arc furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/36—Processes yielding slags of special composition
- C21C2005/366—Foam slags
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
- F27D2003/161—Introducing a fluid jet or current into the charge through a porous element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
- F27D21/02—Observation or illuminating devices
- F27D2021/026—Observation or illuminating devices using a video installation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D21/00—Arrangement of monitoring devices; Arrangement of safety devices
- F27D21/0035—Devices for monitoring the weight of quantities added to the charge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/0025—Charging or loading melting furnaces with material in the solid state
- F27D3/0026—Introducing additives into the melt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
- Y02A40/924—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation using renewable energies
- Y02A40/928—Cooking stoves using biomass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to a process for producing an iron melt, in particular a steel melt, in a reactor with current supply, such as, e.g., an electric arc furnace, as well as a plant for carrying out the process.
- a reactor with current supply such as, e.g., an electric arc furnace
- the gas emerges from the first lance at a speed lying in the ultrasonic range, the solids, thus, being conveyed not only towards the surface of the metal melt, but into the metal melt.
- the invention has as its object to avoid these disadvantages and difficulties and has as its object to provide a process of the initially defined kind as well as a plant for carrying out the process, which render feasible a particularly economical utilization of fine-grained iron carriers, in particular, metallurgical dusts, even at large charging amounts while minimizing the energy input, wherein losses due to the fine-grained iron carriers migrating out of the electric furnace in an unchanged form are largely avoided such that the utilization of filter dusts is feasible without causing any load on the environment.
- this object is achieved by the combination of the following characteristic features:
- fine-grained iron carriers such as metallurgical dusts, fine ores, iron carbide, dust from the production of directly reduced iron, scales, dried metallurgical slurries, etc. are introduced into the foamed slag continuously or discontinuously,
- fine-grained carbon-containing reducing agents such as coal, coke, wood, graphite, synthetic materials, etc. are supplied into the foamed slag continuously or discontinuously and
- fine-grained carbon-containing energy carriers additionally are introduced into the foamed slag continuously or discontinuously for furnishing the required process heat
- the iron melt either constitutes a residual steel amount of the previous melting period or is previously produced by melting lumpy iron carriers (if desired under supply of liquid iron carriers).
- Carbon-containing charging materials also may comprise synthetic materials and graphite.
- the optimum process course may be achieved by supplying the fine-grained iron carriers in locally limited regions and the fine grained carbon-containing reducing agents also in these regions, wherein suitably also the fine-grained carbon-containing energy carriers are supplied in the locally limited regions in which the fine-grained iron carriers are charged.
- inert and/or reducing and/or oxidizing gas preferably are directly injected into the iron melt, preferably from below.
- An efficient process course may be achieved by introducing the fine-grained iron carriers, the fine-grained carbon-containing reducing agents and energy carriers in several locally limited peripheral regions of the reactor.
- the layer height of the foamed slag advantageously is maintained at a predetermined minimum value, preferably is controlled to keep this minimum value, wherein suitably level measuring of the layer height of the foamed slag is carried out several times or continuously during a furnace heat and a foamed slag enveloping an electric arc produced by at least one electrode is formed by blowing solids, gases or a mixture of solids and gases into and/or onto the foamed slag or the iron melt, the layer height of which foamed slag is dimensioned such that the foamed slag extends at least over the entire electric arc.
- the process according to the invention renders feasible the utilization of large amounts of fine-grained iron carriers.
- the blowing rate per minute for the fine-grained iron carriers suitably ranges between one thousandth and some hundredths of the tap weight of the reactor, i.e., advantageously between 20 kg/min and 2000 kg/min.
- By the process according to the invention it is possible to introduce fine-grained iron carriers at an amount of up to 80% of the weight of the overall charge of the reactor.
- the total tap may derive from said fine-grained iron carriers.
- the fine-grained materials are supplied pneumatically, wherein oxygen, air, nitrogen, argon, hydrocarbons, such as natural gas, water vapor, carbon dioxide or mixtures of these gases are used as conveying gases.
- fine-grained iron carriers and, if desired, fine-grained carbon-containing materials are blown in through at least one hollow electrode by means of a carrier gas.
- fine-grained iron carriers and fine-grained carbon-containing materials are blown into the foamed slag formed on the surface of the iron melt through at least one lateral lance and/or pair of tuyeres passing through the side wall of the reactor, by means of a carrier gas, wherein oxygen or oxygen-containing gases is (are) blown into the foamed slag through at least one lateral lance and/or tuyere passing through the side wall of the reactor.
- Lumpy materials likewise may be utilized by the process according to the invention.
- these are introduced through an opening or several openings provided in the furnace lid.
- the sensible heat of hot offgases escaping from the electric arc furnace are used for preheating at least part of the solids introduced, and/or gases injected, into the electric arc furnace.
- the production of molten steel is effected continuously or semi-continuously by using a plant comprising a reactor optionally including a melt-reduction part.
- a reactor with current supply such as an electric arc furnace, comprising at least one electrode
- the mouths of the gas supply means advantageously each lying above the mouths of the solids supply means.
- the supplied gas and the supplied solids are feedable by means of at least one lateral lance passing through the side wall of the reactor, said lateral lance having separate flow cross sections for the gas and the solids as far as to its mouth.
- Another preferred embodiment is characterized in that at least one electrode having a central longitudinal recess is provided, into which a duct supplying fine-grained solids and/or gas enters.
- tuyeres or flushing bricks are provided in the bottom of the reactor.
- the tuyeres are protected by natural gas.
- a level measuring means including a control loop advantageously is provided for measuring the layer height of the foamed slag present on the iron melt, which level measuring means is coupled with the supply means for the solids and/or gases and/or solids-gas mixtures.
- the mouths of the gas supply means and the mouths of the supply means for the fine-grained iron carriers, reducing agents and energy carriers are directed obliquely downwards towards the bottom tuyeres.
- FIG. 1 is a vertical section through an electric arc furnace according to the invention along line I--I of FIG. 2, and
- FIG. 2 is a horizontal section of the same along line II--II of FIG. 1.
- a self-consuming graphite electrode 3 centrally projects into an electric arc furnace 1 from above through the lid 2 of the same, its electric arc 4 burning towards a steel melt 6 that covers the bottom 5 of the electric arc furnace 1.
- a counter electrode 7 is arranged in the bottom 5.
- the embodiment illustrated represents a direct current electric arc furnace having but one electrode. However, there might also be provided several self-consuming graphite electrodes 3--as is indicated by dot-and-dash lines--, which may be operated with alternating or rotary current.
- a layer of foamed slag 9 having a predetermined layer height 10 is present on the steel bath surface 8.
- the self-consuming graphite electrode 3 is designed as a hollow electrode. Through its internal central longitudinal recess 11, which suitably is provided with an internal lining of Al 2 O 3 -containing tubes (corundum, sillimanite, etc.) or steel, fine-grained solids and/or gases or mixtures of solids and gases may be supplied via a duct 12, thus immediately getting into the electric arc furnace 4.
- the lid 2 of the electric arc furnace furthermore, comprises a lid opening 13, through which lumpy solids, lump coal or coke, lump ores, filter dust pellets or briquets and/or fluxes supplied by a supply duct 14 may be introduced into the interior 15 of the electric arc furnace 1.
- a supply duct 14 may be introduced into the interior 15 of the electric arc furnace 1.
- lances 17 which are movably or rigidly arranged relative to the same and either are protected by cooling water or cooling gas or--if not protected--are self-consuming, project into the interior 15 of the electric arc furnace 1.
- the lances 17 are directed obliquely towards the bottom 5. They may be movably arranged in the side wall 16, i.e., capable of being inclined, pivoted and displaced and retracted. Stationary installation in the side wall 16 also is conceivable.
- the mouths 20 of the lances 17 are located on a height level above which the foamed slag 9 extends.
- the electric arc furnace 1 comprises pairs of tuyeres 21, 22 passing through its side wall 16, the mouths 23, 24 of the pairs of tuyeres 21, 22 likewise being located on a height level above which the foamed slag 9 extends.
- Each pair of tuyeres 21, 22 is formed by an upper tuyere 22 and a further tuyere 21 located approximately vertical below this tuyere 22.
- the tuyeres 21, 22 are arranged in the side wall 16 also in a movable manner (inclinable as well as extractable and retractable).
- pairs of tuyeres 21, 22 could again be provided, or, vice versa, the tuyeres 21, 22 also could be replaced with lances 17.
- tuyeres 25 preferably protected by natural gas, or flushing bricks are provided, through which reducing or oxidizing or inert gases that serve to accelerate the steel production process by intensifying the movement of the bath may be injected.
- reducing or oxidizing or inert gases that serve to accelerate the steel production process by intensifying the movement of the bath may be injected.
- the electric arc furnace 1 comprises a bottom tap 26; however, there could also be provided a skimmer tap.
- the slag tap is denoted by 27.
- the offgas forming in the interior 15 of the electric arc furnace 1 is fed to a filtering plant (not illustrated) via an offgas duct 28.
- the sensible heat of the offgases subsequently may be used for preheating at least part of the solids charged, and/or gases injected, into the electric arc furnace 1, either without or with partial after-burning of the offgases.
- Preheating is effected by conducting the offgases through suitable preheating means, such as, e.g., a preheating shaft and/or whirling bed or rotary tubular reactors and/or other heat exchangers.
- the height of the foamed slag 9 may be detected by aid of a level measuring means 29, which, for instance, is designed as a sound measuring means, a high-temperature measuring means or a high-temperature video camera or as a high-temperature radar, wherein the measured signal of the level measuring means is used for controlling the height 10 of the foamed slag 9, for instance, by feeding it to a control loop 30 whose output signals are transmitted to automatic control devices for controlling the solids and/or gases and/or mixtures of solids and gases introduced.
- a level measuring means 29 which, for instance, is designed as a sound measuring means, a high-temperature measuring means or a high-temperature video camera or as a high-temperature radar, wherein the measured signal of the level measuring means is used for controlling the height 10 of the foamed slag 9, for instance, by feeding it to a control loop 30 whose output signals are transmitted to automatic control devices for controlling the solids and/or gases and/or mixtures of solids and gases introduced.
- metallurgical filter dust (grain size ⁇ 1 mm) having the following composition is processed:
- the fine-grained charging substances (filter dust and coal) were supplied into the bath pneumatically up to 100%.
- FIGS. 1 und 2 a 125 ton DC electric arc furnace 1 as illustrated in FIGS. 1 und 2 was used, which, in detail, was equipped as follows:
- steel scrap one cage was charged into the empty furnace and melted down by means of the electrode while top-blowing fine-grained coal and O 2 .
- the coal was introduced through the lances 17 as well as through the tuyeres 21 of the lower plane, the oxygen was injected through the lances 17 and the tuyeres 22 of the upper plane.
- the temperature of the steel sump formed (about 60 tons) was increased to 1620° C., its C-content amounting to 0.15%.
- a filter dust--coal mixture was blown in by aid of N 2 carrier gas below the surface 31 of the foamed slag 9, yet above the surface 8 of the steel bath 6.
- the blow-in rate was 500 kg filter dust/rain so that a total of 20 tons of filter dust was blown in within 40 min.
- O 2 also was blown into the foamed slag 9 through the lances 17 and the tuyeres 22 of the upper tuyere plane.
- N 2 +CH 4 was injected through the bottom tuyeres 25 as a bottom flushing gas.
- Lump lime was added through the lid opening 13. During the total dust blow-in period, a well foaming slag 9 was obtained, completely surrounding the electric arc 4 almost throughout the total dust blow-in period. The following bath conditions were attained:
- Thickness of foamed slag layer 600-900 mm
- DC electric arc length (at approximately 600 V and 100 kA): about 700 mm
- the amount of steel within the furnace was about 73 tons.
- the amount of slag was about 7.5 tons.
- the melt reduction of the iron carriers supplied preferably runs continuously at a temperature ranging between about 1500° and 1650° C.
- the foamed slag 9 via slag tap 27, and the produced steel melt 6 via bottom tap 26 are partially tapped from time to time (while interrupting the supply of current and fine-grained solids because of the discontinuous process course caused by the electric arc furnace) such that a certain amount of residual slag and/or a certain steel sump will remain in the furnace as the minimum amount for a troublefree continuation of the melt reduction.
- a steel sump may also be built up by melting (even lumpy) iron carriers.
- a discontinuous process course is suitable.
- a plant comprising an electric arc furnace or a melt or melt reduction section similar to an electric arc furnace for the production of molten steel
- a continuous or semi-continuous process course is feasible, too.
- the process also may be applied in combination with common electric arc furnace operation--as an additional process step or parallel to smelting (e.g., scrap and/or sponge iron) and/or refining and/or overheating of the melt in the flat bath operation.
- the fine-grained iron carriers--in particular, metallurgical dusts (filter dusts from converters, electric arc furnaces, blast furnaces, melt reduction plants, etc.), fine ores with or without prereduction, iron carbide, DRE fines, scales, dried and comminuted slurry, etc.--according to the invention may be supplied to the electric arc furnace up to a portion of 80% of the total iron charge and may partially or completely be replaced with compounds of non-iron metals (e.g., Ni, Cr, Mo, Mn, etc.).
- non-iron metals e.g., Ni, Cr, Mo, Mn, etc.
- the fine-grained C-containing reducing agents preferably comprise coal, coke, graphite, synthetic materials, wood, etc. or mixtures thereof.
- Low-priced fine-grained FeSi, Al or other reducing agents may also be used.
- the gases fed essentially consist of O 2 , air, N 2 , Ar, natural gas or other hydrocarbons, H 2 O (vapor), CO 2 or mixtures thereof. Hydrocarbon also may be fed in the liquid state. In particular, air, and also the inert gases may be preheated.
- fossile energy carriers and electric energy may be combined to furnish the process heat required for carrying out the process.
- the overall coal consumption results from the socalled “reduction coal” (reaction coal) and the socalled “heating coal” (substitute for electric energy).
- energy may be introduced by aid of afterburning lances operated by O 2 and/or air and blowing onto or into the slag.
- a substantial advantage of the process according to the invention is to be seen in that the working up, and hence disposal, of metallurgical dusts incurring is feasible under simultaneous recovery and/or enrichment of their components (enrichment to concentrations at which the further disposal of waste products can be realized in an economic manner).
- a field of application of the process according to the invention is the disposal of toxic wastes or wastes that constitute a load on the environment, such as shredding waste, synthetic granulates, dried sewage, etc., including the recovery of their valuable components while utilizing their energy content.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Abstract
Description
______________________________________ Component % by weight ______________________________________ Fe.sub.tot (95% oxidic) 66.0 C 6.0 Cl 0.5 Ni 0.04 Alkali (Na, K) 0.5 Cu 0.1 Cr.sub.2 O.sub.3 0.3 CaO 1.5 SiO.sub.2 1.2 TiO.sub.2 0.1 ZnO 1.5 PbO 0.5 H.sub.2 O 1.0 ______________________________________
______________________________________ fine-grained coal (anthracite coal, grain size <1.5 mm) having the composition (in % by weight): 87.8% C 0.13% CaO 0.1% MgO 3.5% SiO.sub.2 2.5% A1.sub.2 O.sub.3 1.4% H.sub.2 O 0.4% S Balance: volatile components soft-burnt lime (piece size 15 to 40 mm) having the composition (in % by weight): 92.5% CaO 1.5% MgO 1.3% SiO.sub.2 1.8% A1.sub.2 O.sub.3 0.2% Fe.sub.2 O.sub.3 1.5% CO.sub.2 1.0% H.sub.2 O 0.04% S Fluor spar (piece size 10 to 40 mm) having the composition (in % by weight): 87.5% CaF.sub.2 3.0% CaO 5.0% SiO.sub.2 1.0% A1.sub.2 O.sub.3 2.0% CO.sub.2 1.1% H.sub.2 O 0.27% S ______________________________________ Gases: O.sub.2, air (dry), N.sub.2, Ar, CH.sub.4
______________________________________ Transfo performance 100 MVA (800 kVA/t liquid) Electrode design 1 hollow electrode 3 of graphite having an internal lining of corundum tube Blow-in lances and 2 water-cooled movable tuyereslateral lances 17 through furnace wall for dust and coal and/or O.sub.2 4 tangentially and firmly installedtuyeres 21 protrcted by natural gas inside wall 16 for dust + coal (lower tuyere plane in FIG. 1) 4 tangentially and firmly installedtuyeres 22 protected by natural gas inside wall 16 for O.sub.2 (upper tuyere plane in FIG. 1) 6bottom tuyeres 25 for N.sub.2 /Ar changeover (to improve the tuyere lives a bit of CH.sub.4 was admixed). ______________________________________
______________________________________ Consumption per ton per min Operational parameters filter dust blow-in-time ______________________________________ A) Charging substances (all at 25° C.) 1) Filter dust 1000 kg 500 kg 2) Coal dust 85 kg 42.5 kg 3) O.sub.2 25 Nm.sup.3 12.5 Nm.sup.3 4) N.sub.2 (carrier gas/bottom flushing) 110/3 Nm.sup.3 55/1.5 Nm.sup.3 5)Lime 20kg 10 kg B) Products (all at 1600° C.) 1) Molten steel (0.07% C) 654 kg 327 kg 2) Slag (% FeO.sub.n = 20%, 73 kg 36.5 kg % CaO/% SiO.sub.2 = 2.2) 3) Offgas (CO-afterburning 384 Nm.sup.3 192 Nm.sup.3 degree = 20%) C) Electric energy consumption 1420 kWh 710 kWh ______________________________________
Claims (35)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT2495/93 | 1993-12-10 | ||
AT249593A AT400245B (en) | 1993-12-10 | 1993-12-10 | METHOD AND SYSTEM FOR PRODUCING A MELTING IRON |
Publications (1)
Publication Number | Publication Date |
---|---|
US5611838A true US5611838A (en) | 1997-03-18 |
Family
ID=3535314
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/350,952 Expired - Fee Related US5611838A (en) | 1993-12-10 | 1994-12-07 | Process for producing an iron melt |
Country Status (5)
Country | Link |
---|---|
US (1) | US5611838A (en) |
EP (1) | EP0657549B1 (en) |
AT (1) | AT400245B (en) |
CA (1) | CA2137766A1 (en) |
DE (1) | DE59410379D1 (en) |
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5885325A (en) * | 1994-12-20 | 1999-03-23 | Usx Corporation | Process and apparatus for the manufacture of steel |
US5961688A (en) * | 1994-09-15 | 1999-10-05 | Mannesmann Aktiengesellschaft | Process and device for making liquid iron by non-electric and electric smelting |
WO2000014287A1 (en) * | 1998-09-03 | 2000-03-16 | Uddeholm Technology Aktiebolag | Method for the production of a bulk of molten metal, a metallurgical product, and use of such a product |
WO2000036161A2 (en) * | 1998-12-16 | 2000-06-22 | Paul Wurth S.A. | Method for feeding fines in a light-arc furnace |
EP1087022A1 (en) * | 1999-09-27 | 2001-03-28 | Technological Resources Pty. Ltd. | A direct smelting process |
EP1114192A1 (en) * | 1998-08-28 | 2001-07-11 | Technological Resources Pty. Ltd. | A process and an apparatus for producing metals and metal alloys |
WO2001061056A1 (en) * | 2000-02-17 | 2001-08-23 | Uddeholm Technology Aktiebolag | Method relating to manufacturing of steel |
US6524362B1 (en) | 1997-10-07 | 2003-02-25 | Metallgesellschaft Ag | Method of melting fine grained direct reduced iron in an electric arc furnace |
US6635096B1 (en) * | 1999-06-25 | 2003-10-21 | Paul Wurth S.A. | Method for optimizing the operating conditions of a submerged arc furnace |
AU769631B2 (en) * | 1999-04-22 | 2004-01-29 | Voest-Alpine Industrieanlagenbau Gmbh | Method and device for melting down finely particulate material containing metal, such as sponge iron |
US20040050210A1 (en) * | 2000-01-28 | 2004-03-18 | Alfred Edlinger | Method for reprocessing dust or dust mixtures |
US20040060389A1 (en) * | 2001-02-23 | 2004-04-01 | Jean-Luc Roth | Method for producing a melt iron in an electric furnace |
WO2005014868A1 (en) * | 2003-07-23 | 2005-02-17 | Outokumpu Technology Oy | Method of charging fine-grained metals into an electric-arc furnace |
US20070215249A1 (en) * | 2004-04-07 | 2007-09-20 | Outokumpus Stainless Akteibolag | Method in Connection with Steel Production |
US20070256516A1 (en) * | 2001-07-20 | 2007-11-08 | Mcclintock Willard K | Steel making material recycling system |
US20100288078A1 (en) * | 2007-10-23 | 2010-11-18 | Johann Reichel | Process for producing stainless steel using direct reduction furnaces for ferrochrome and ferronickel on the primary side of a converter |
US20100315098A1 (en) * | 2005-07-22 | 2010-12-16 | Dieter Fink | Method for determining at least one state variable of an electric arc furnace, and electric arc furnace |
US7858021B2 (en) | 2005-12-07 | 2010-12-28 | Siemens Vai Metals Technologies Gmbh & Co. | Conveyor system, composite system and method for coupling metallurgical methods |
US20100327233A1 (en) * | 2009-06-24 | 2010-12-30 | Shugart Jason V | Copper-Carbon Composition |
US20110007773A1 (en) * | 2008-01-31 | 2011-01-13 | Doebbeler Arno | Method for operating an arc furnace comprising at least one electrode, regulating and/or control device, machine-readable program code, data carrier and arc furnace for carrying out said method |
CN102042763A (en) * | 2010-12-01 | 2011-05-04 | 张昭贵 | Sleeve coal spraying gun with viewing function |
US20110146447A1 (en) * | 2008-08-26 | 2011-06-23 | Sms Siemag Ag | Method for Controlling Foamed Slag in a Stainless Melt in an Electronic Arc Furnace |
US20110154946A1 (en) * | 1999-06-02 | 2011-06-30 | Djamschid Amirzadeh-Asl | Method for producing foamed slag |
US20110272866A1 (en) * | 2010-04-26 | 2011-11-10 | Ehsan Shameli | Measurement of charge bank level in a metallurgical furnace |
US8349759B2 (en) | 2010-02-04 | 2013-01-08 | Third Millennium Metals, Llc | Metal-carbon compositions |
CN103602877A (en) * | 2004-09-03 | 2014-02-26 | 纽索思创新有限公司 | Production of ferro-alloys |
CN104630411A (en) * | 2015-03-10 | 2015-05-20 | 中冶南方工程技术有限公司 | QDF electric steelmaking process |
US9273380B2 (en) | 2011-03-04 | 2016-03-01 | Third Millennium Materials, Llc | Aluminum-carbon compositions |
US20160326606A1 (en) * | 2014-01-31 | 2016-11-10 | Saudi Basic Industries Corporation | Methods for producing improved steels by injecting iron containing by-products of an iron ore production process into liquid steel |
WO2017136679A1 (en) * | 2016-02-04 | 2017-08-10 | Liquid Minerals Group Ltd. | A system and method for disrupting slag deposits and the compositions used |
WO2017165802A1 (en) * | 2016-03-25 | 2017-09-28 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Inert gas blanketing of electrodes in an electric arc furnace |
JP2019525112A (en) * | 2016-07-01 | 2019-09-05 | ペキン チョンカイホンド テクノロジー カンパニー リミテッドBeijing Zhongkaihongde Technology Co., Ltd | Metallurgical electric furnace and melting method |
CN112595093A (en) * | 2020-11-26 | 2021-04-02 | 天津水泥工业设计研究院有限公司 | Electrode heating process and device capable of blowing powder for electric arc furnace |
US11390926B2 (en) | 2018-03-30 | 2022-07-19 | Tata Steel Nederland Technology B.V. | Method for off-gas composition control in a metal smelting apparatus |
WO2022154680A1 (en) * | 2021-01-18 | 2022-07-21 | Sieć Badawcza Łukasiewicz Instytut Metalurgii Żelaza Im. Stanisława Staszica W Gliwicach | Method of steel smelting directly from iron ore |
CN115652089A (en) * | 2022-09-16 | 2023-01-31 | 汤海军 | Hollow electrode metallurgical production process |
CN115976333A (en) * | 2022-11-22 | 2023-04-18 | 云南驰宏锌锗股份有限公司 | Smelting method of hot slag side-blown reduction furnace |
CN116907204A (en) * | 2023-09-08 | 2023-10-20 | 山西吕梁山矿产品有限公司 | Device and method for smelting brown fused alumina |
WO2024126200A1 (en) * | 2022-12-12 | 2024-06-20 | Thyssenkrupp Steel Europe Ag | Process for producing an iron melt and liquid slag in an electric smelter |
WO2024236508A1 (en) | 2023-05-15 | 2024-11-21 | Metix (Proprietary) Limited | Novel process for the smelting of a blend of hot and cold metalliferous feedstock material yielding reduced carbon emissions |
WO2024236503A1 (en) | 2023-05-15 | 2024-11-21 | Metix (Proprietary) Limited | Novel process for the smelting of a metalliferous feedstock material yielding reduced carbon emissions |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1009828A3 (en) * | 1995-07-13 | 1997-10-07 | Centre Rech Metallurgique | Method of recovering iron-rich iron and steel manufacturing residues |
SE505602C2 (en) * | 1995-11-14 | 1997-09-22 | Interproject Service Ab | Method of destroying rubber-based material and plastic material |
AUPO426396A0 (en) * | 1996-12-18 | 1997-01-23 | Technological Resources Pty Limited | A method of producing iron |
AT405054B (en) | 1997-06-18 | 1999-05-25 | Voest Alpine Ind Anlagen | METHOD AND PLANT FOR PRODUCING AN IRON MEL WITH THE USE OF IRON-CONTAINING RESIDUAL MATERIALS |
AU2005279678B2 (en) * | 2004-09-03 | 2011-06-23 | Newsouth Innovations Pty Limited | Production of ferro-alloys |
DE102006023259A1 (en) * | 2006-05-18 | 2007-11-22 | Alzchem Hart Gmbh | Use of residual and / or waste materials in electric low-shaft kilns |
RU2476601C1 (en) * | 2011-07-14 | 2013-02-27 | Учреждение Российской академии наук Институт металлургии и материаловедения им. А.А. Байкова РАН | Method for electric-arc carbon-thermal reduction of iron from titanomagnetite so that metal product is obtained in form of powder and granules, and device for its implementation |
RU2567424C1 (en) * | 2014-04-11 | 2015-11-10 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Method of steel melting out of iron-ore iron-rich pellets in electric arc furnace |
RU2567425C1 (en) * | 2014-04-11 | 2015-11-10 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Method of steel making in arc-type steel-making furnace |
CN104492599B (en) * | 2014-12-08 | 2017-01-11 | 沈阳航空航天大学 | Treatment method of graphite dust |
DE102017127626A1 (en) * | 2017-11-22 | 2019-05-23 | Sms Group Gmbh | Method for controlling the afterburning of waste gases resulting from the production of steel and non-ferrous metals |
DE102020116425A1 (en) | 2020-06-22 | 2021-12-23 | Salzgitter Flachstahl Gmbh | Process for the production of crude steel with a low N content |
EP4012311A1 (en) * | 2020-12-10 | 2022-06-15 | Linde GmbH | Electrode for an electric arc furnace |
LU102322B1 (en) * | 2020-12-17 | 2022-06-21 | Wurth Paul Sa | Green production route for low carbon, low nitrogen steel |
DE102023100464A1 (en) | 2023-01-11 | 2024-07-11 | Thyssenkrupp Steel Europe Ag | Method for operating a direct current electric furnace for producing molten iron and liquid slag |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE228831C (en) * | 1909-08-16 | |||
EP0087405A1 (en) * | 1982-01-19 | 1983-08-31 | VOEST-ALPINE Aktiengesellschaft | Process and device for the reduction of particle-sized ores containing oxide |
EP0115756A1 (en) * | 1982-12-07 | 1984-08-15 | VOEST-ALPINE Aktiengesellschaft | A method and arrangement for producing metals, in particular molten pig iron, steel pre-material or ferroalloys |
FR2634787A1 (en) * | 1988-08-01 | 1990-02-02 | Siderurgie Fse Inst Rech | Process for obtaining a foaming slag in an electrical furnace for steel manufacture |
EP0418656A1 (en) * | 1989-09-20 | 1991-03-27 | Fuchs Systemtechnik Gmbh | Process and installation for intermittant simultaneous addition of gases and fine-grained solids into a melt |
EP0579591A1 (en) * | 1992-07-16 | 1994-01-19 | Voest-Alpine Industrieanlagenbau Gmbh | Process for the production of a metal melt |
US5378261A (en) * | 1992-05-26 | 1995-01-03 | Zaptech Corporation | Method for producing steel |
EP0637634A1 (en) * | 1993-08-04 | 1995-02-08 | Voest-Alpine Industrieanlagenbau Gmbh | Process for producing a metal melt |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD228831A1 (en) * | 1984-10-26 | 1985-10-23 | Brandenburg Stahl Walzwerk | METHOD FOR ILLUMINATING THE ARC FLASH |
-
1993
- 1993-12-10 AT AT249593A patent/AT400245B/en not_active IP Right Cessation
-
1994
- 1994-12-05 DE DE59410379T patent/DE59410379D1/en not_active Expired - Lifetime
- 1994-12-05 EP EP94890201A patent/EP0657549B1/en not_active Expired - Lifetime
- 1994-12-07 US US08/350,952 patent/US5611838A/en not_active Expired - Fee Related
- 1994-12-09 CA CA 2137766 patent/CA2137766A1/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE228831C (en) * | 1909-08-16 | |||
EP0087405A1 (en) * | 1982-01-19 | 1983-08-31 | VOEST-ALPINE Aktiengesellschaft | Process and device for the reduction of particle-sized ores containing oxide |
EP0115756A1 (en) * | 1982-12-07 | 1984-08-15 | VOEST-ALPINE Aktiengesellschaft | A method and arrangement for producing metals, in particular molten pig iron, steel pre-material or ferroalloys |
FR2634787A1 (en) * | 1988-08-01 | 1990-02-02 | Siderurgie Fse Inst Rech | Process for obtaining a foaming slag in an electrical furnace for steel manufacture |
EP0418656A1 (en) * | 1989-09-20 | 1991-03-27 | Fuchs Systemtechnik Gmbh | Process and installation for intermittant simultaneous addition of gases and fine-grained solids into a melt |
US5378261A (en) * | 1992-05-26 | 1995-01-03 | Zaptech Corporation | Method for producing steel |
EP0579591A1 (en) * | 1992-07-16 | 1994-01-19 | Voest-Alpine Industrieanlagenbau Gmbh | Process for the production of a metal melt |
US5366538A (en) * | 1992-07-16 | 1994-11-22 | Voest-Alpine Industrieanlagenbau Gmbh | Process for the production of a metal melt |
EP0637634A1 (en) * | 1993-08-04 | 1995-02-08 | Voest-Alpine Industrieanlagenbau Gmbh | Process for producing a metal melt |
Cited By (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5961688A (en) * | 1994-09-15 | 1999-10-05 | Mannesmann Aktiengesellschaft | Process and device for making liquid iron by non-electric and electric smelting |
US5885325A (en) * | 1994-12-20 | 1999-03-23 | Usx Corporation | Process and apparatus for the manufacture of steel |
US6524362B1 (en) | 1997-10-07 | 2003-02-25 | Metallgesellschaft Ag | Method of melting fine grained direct reduced iron in an electric arc furnace |
EP1114192A1 (en) * | 1998-08-28 | 2001-07-11 | Technological Resources Pty. Ltd. | A process and an apparatus for producing metals and metal alloys |
EP1114192A4 (en) * | 1998-08-28 | 2003-06-25 | Tech Resources Pty Ltd | A process and an apparatus for producing metals and metal alloys |
WO2000014287A1 (en) * | 1998-09-03 | 2000-03-16 | Uddeholm Technology Aktiebolag | Method for the production of a bulk of molten metal, a metallurgical product, and use of such a product |
US6689189B1 (en) | 1998-09-03 | 2004-02-10 | Uddeholm Technology Aktiebolag | Metallurgical product |
WO2000036161A2 (en) * | 1998-12-16 | 2000-06-22 | Paul Wurth S.A. | Method for feeding fines in a light-arc furnace |
LU90327B1 (en) * | 1998-12-16 | 2000-07-18 | Wurth Paul Sa | Proc-d- for placing fines in a furnace - arc |
WO2000036161A3 (en) * | 1998-12-16 | 2000-08-31 | Wurth Paul Sa | Method for feeding fines in a light-arc furnace |
AU769631B2 (en) * | 1999-04-22 | 2004-01-29 | Voest-Alpine Industrieanlagenbau Gmbh | Method and device for melting down finely particulate material containing metal, such as sponge iron |
US20110154946A1 (en) * | 1999-06-02 | 2011-06-30 | Djamschid Amirzadeh-Asl | Method for producing foamed slag |
US6635096B1 (en) * | 1999-06-25 | 2003-10-21 | Paul Wurth S.A. | Method for optimizing the operating conditions of a submerged arc furnace |
EP1087022A1 (en) * | 1999-09-27 | 2001-03-28 | Technological Resources Pty. Ltd. | A direct smelting process |
US20040050210A1 (en) * | 2000-01-28 | 2004-03-18 | Alfred Edlinger | Method for reprocessing dust or dust mixtures |
US20030164062A1 (en) * | 2000-02-17 | 2003-09-04 | Per-Ake Lundstrom | Method relating to manufacturing of steel |
WO2001061056A1 (en) * | 2000-02-17 | 2001-08-23 | Uddeholm Technology Aktiebolag | Method relating to manufacturing of steel |
US20040060389A1 (en) * | 2001-02-23 | 2004-04-01 | Jean-Luc Roth | Method for producing a melt iron in an electric furnace |
US7169205B2 (en) * | 2001-02-23 | 2007-01-30 | Paul Wurth S.A. | Method for producing a melt iron in an electric furnace |
US20070256516A1 (en) * | 2001-07-20 | 2007-11-08 | Mcclintock Willard K | Steel making material recycling system |
US8391331B2 (en) | 2003-07-23 | 2013-03-05 | Outotec Oyj | Method of charging fine-grained metals into an electric-arc furnace |
US20070082312A1 (en) * | 2003-07-23 | 2007-04-12 | Heinz Eichberger | Method of charging fine-grained metals into an electric-arc furnace |
EA008735B1 (en) * | 2003-07-23 | 2007-08-31 | Оутокумпу Текнолоджи Ой | Method of charging fine-grained metals into an electric-arc furnace |
WO2005014868A1 (en) * | 2003-07-23 | 2005-02-17 | Outokumpu Technology Oy | Method of charging fine-grained metals into an electric-arc furnace |
US20100275728A1 (en) * | 2004-04-07 | 2010-11-04 | Outokumpu Oyj | Method in connection with steel production |
US20070215249A1 (en) * | 2004-04-07 | 2007-09-20 | Outokumpus Stainless Akteibolag | Method in Connection with Steel Production |
US8246716B2 (en) | 2004-04-07 | 2012-08-21 | Outokumpu Oyj | Method in connection with steel production |
US7744674B2 (en) * | 2004-04-07 | 2010-06-29 | Outokumpu Oyj | Method in connection with steel production |
CN103911539A (en) * | 2004-09-03 | 2014-07-09 | 纽索思创新有限公司 | Production of ferro-alloys |
CN103602877A (en) * | 2004-09-03 | 2014-02-26 | 纽索思创新有限公司 | Production of ferro-alloys |
US9255303B2 (en) * | 2005-07-22 | 2016-02-09 | Siemens Aktiengesellschaft | Method for determining at least one state variable of an electric arc furnace, and electric arc furnace |
US20100315098A1 (en) * | 2005-07-22 | 2010-12-16 | Dieter Fink | Method for determining at least one state variable of an electric arc furnace, and electric arc furnace |
US7858021B2 (en) | 2005-12-07 | 2010-12-28 | Siemens Vai Metals Technologies Gmbh & Co. | Conveyor system, composite system and method for coupling metallurgical methods |
US20110101577A1 (en) * | 2005-12-07 | 2011-05-05 | Siemens Vai Metals Technologies Gmbh & Co. | Conveyor system, composite system and method for coupling metallurgical methods |
US8202474B2 (en) | 2005-12-07 | 2012-06-19 | Siemens Vai Metals Technologies Gmbh | Conveyor system, composite system and method for coupling metallurgical methods |
US8133296B2 (en) | 2007-10-23 | 2012-03-13 | Sms Siemag Aktiengesellschaft | Process for producing stainless steel using direct reduction furnaces for ferrochrome and ferronickel on the primary side of a converter |
US20100288078A1 (en) * | 2007-10-23 | 2010-11-18 | Johann Reichel | Process for producing stainless steel using direct reduction furnaces for ferrochrome and ferronickel on the primary side of a converter |
US9175359B2 (en) * | 2008-01-31 | 2015-11-03 | Siemens Aktiengesellschaft | Method for operating an arc furnace comprising at least one electrode, regulating and/or control device, machine-readable program code, data carrier and arc furnace for carrying out said method |
US20110007773A1 (en) * | 2008-01-31 | 2011-01-13 | Doebbeler Arno | Method for operating an arc furnace comprising at least one electrode, regulating and/or control device, machine-readable program code, data carrier and arc furnace for carrying out said method |
US8728194B2 (en) * | 2008-08-26 | 2014-05-20 | Sms Siemag Ag | Method for controlling foamed slag in a stainless melt in an electronic arc furnace |
US20110146447A1 (en) * | 2008-08-26 | 2011-06-23 | Sms Siemag Ag | Method for Controlling Foamed Slag in a Stainless Melt in an Electronic Arc Furnace |
US20100327233A1 (en) * | 2009-06-24 | 2010-12-30 | Shugart Jason V | Copper-Carbon Composition |
US8647534B2 (en) | 2009-06-24 | 2014-02-11 | Third Millennium Materials, Llc | Copper-carbon composition |
US8349759B2 (en) | 2010-02-04 | 2013-01-08 | Third Millennium Metals, Llc | Metal-carbon compositions |
US8541335B2 (en) | 2010-02-04 | 2013-09-24 | Third Millennium Metals, Llc | Metal-carbon compositions |
US8541336B2 (en) | 2010-02-04 | 2013-09-24 | Third Millennium Metals, Llc | Metal-carbon compositions |
US8546292B2 (en) | 2010-02-04 | 2013-10-01 | Third Millennium Metals, Llc | Metal-carbon compositions |
US8551905B2 (en) | 2010-02-04 | 2013-10-08 | Third Millennium Metals, Llc | Metal-carbon compositions |
CN102884388B (en) * | 2010-04-26 | 2016-03-09 | 哈茨有限公司 | The measurement of the bed of material level in metallurgical furnace |
CN102884388A (en) * | 2010-04-26 | 2013-01-16 | 哈茨有限公司 | Measurement of charge bank level in a metallurgical furnace |
US20110272866A1 (en) * | 2010-04-26 | 2011-11-10 | Ehsan Shameli | Measurement of charge bank level in a metallurgical furnace |
US20110272865A1 (en) * | 2010-04-26 | 2011-11-10 | Ehsan Shameli | Measurement of charge bank level in a metallurgical furnace |
US9417322B2 (en) * | 2010-04-26 | 2016-08-16 | Hatch Ltd. | Measurement of charge bank level in a metallurgical furnace |
US9417321B2 (en) * | 2010-04-26 | 2016-08-16 | Hatch Ltd. | Measurement of charge bank level in a metallurgical furnace |
CN102042763A (en) * | 2010-12-01 | 2011-05-04 | 张昭贵 | Sleeve coal spraying gun with viewing function |
US9273380B2 (en) | 2011-03-04 | 2016-03-01 | Third Millennium Materials, Llc | Aluminum-carbon compositions |
US20160326606A1 (en) * | 2014-01-31 | 2016-11-10 | Saudi Basic Industries Corporation | Methods for producing improved steels by injecting iron containing by-products of an iron ore production process into liquid steel |
CN104630411A (en) * | 2015-03-10 | 2015-05-20 | 中冶南方工程技术有限公司 | QDF electric steelmaking process |
WO2017136679A1 (en) * | 2016-02-04 | 2017-08-10 | Liquid Minerals Group Ltd. | A system and method for disrupting slag deposits and the compositions used |
WO2017165802A1 (en) * | 2016-03-25 | 2017-09-28 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Inert gas blanketing of electrodes in an electric arc furnace |
EP3480325A4 (en) * | 2016-07-01 | 2019-12-04 | Beijing Zhongkaihongde Technology Co., Ltd. | Smelting method for metallurgical electric-furnace |
JP2019525112A (en) * | 2016-07-01 | 2019-09-05 | ペキン チョンカイホンド テクノロジー カンパニー リミテッドBeijing Zhongkaihongde Technology Co., Ltd | Metallurgical electric furnace and melting method |
US11390926B2 (en) | 2018-03-30 | 2022-07-19 | Tata Steel Nederland Technology B.V. | Method for off-gas composition control in a metal smelting apparatus |
CN112595093A (en) * | 2020-11-26 | 2021-04-02 | 天津水泥工业设计研究院有限公司 | Electrode heating process and device capable of blowing powder for electric arc furnace |
CN112595093B (en) * | 2020-11-26 | 2022-05-27 | 天津水泥工业设计研究院有限公司 | Electrode heating process and device capable of blowing powder for electric arc furnace |
WO2022154680A1 (en) * | 2021-01-18 | 2022-07-21 | Sieć Badawcza Łukasiewicz Instytut Metalurgii Żelaza Im. Stanisława Staszica W Gliwicach | Method of steel smelting directly from iron ore |
CN115652089A (en) * | 2022-09-16 | 2023-01-31 | 汤海军 | Hollow electrode metallurgical production process |
CN115976333A (en) * | 2022-11-22 | 2023-04-18 | 云南驰宏锌锗股份有限公司 | Smelting method of hot slag side-blown reduction furnace |
WO2024126200A1 (en) * | 2022-12-12 | 2024-06-20 | Thyssenkrupp Steel Europe Ag | Process for producing an iron melt and liquid slag in an electric smelter |
WO2024236508A1 (en) | 2023-05-15 | 2024-11-21 | Metix (Proprietary) Limited | Novel process for the smelting of a blend of hot and cold metalliferous feedstock material yielding reduced carbon emissions |
WO2024236503A1 (en) | 2023-05-15 | 2024-11-21 | Metix (Proprietary) Limited | Novel process for the smelting of a metalliferous feedstock material yielding reduced carbon emissions |
NL2034822B1 (en) * | 2023-05-15 | 2024-12-02 | Metix Pty Limited | Novel process for the smelting of a metalliferous feedstock material yielding reduced carbon emissions |
NL2034821B1 (en) * | 2023-05-15 | 2024-12-02 | Metix Pty Limited | Novel process for the smelting of a blend of hot and cold metalliferous feedstock material yielding reduced carbon emissions |
CN116907204A (en) * | 2023-09-08 | 2023-10-20 | 山西吕梁山矿产品有限公司 | Device and method for smelting brown fused alumina |
CN116907204B (en) * | 2023-09-08 | 2023-11-28 | 山西吕梁山矿产品有限公司 | Device and method for smelting brown fused alumina |
Also Published As
Publication number | Publication date |
---|---|
CA2137766A1 (en) | 1995-06-11 |
DE59410379D1 (en) | 2004-08-05 |
EP0657549A1 (en) | 1995-06-14 |
AT400245B (en) | 1995-11-27 |
EP0657549B1 (en) | 2004-06-30 |
ATA249593A (en) | 1995-03-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5611838A (en) | Process for producing an iron melt | |
KR0131266B1 (en) | Manufacturing method of iron using converter | |
US6264883B1 (en) | Plant for the production of metal melts | |
EP0190313B1 (en) | Method and apparatus for continuous steelmaking | |
AU734802B2 (en) | Process of melting fine grained, direct reduced iron in an electric arc furnace | |
JPH0433841B2 (en) | ||
KR940008926B1 (en) | Mill arrangement and a process of operating the same using off gases to refine pig iron | |
JPH0442452B2 (en) | ||
US3912501A (en) | Method for the production of iron and steel | |
RU2147039C1 (en) | Plant and process of winning of iron melt | |
US6685761B1 (en) | Method for producing beneficiated titanium oxides | |
JPS6294792A (en) | Continuous preheating method and device for charging raw materials for steelmaking furnaces | |
US4756748A (en) | Processes for the smelting reduction of smeltable materials | |
US4540432A (en) | Continuous process of melting sponge iron | |
US5885325A (en) | Process and apparatus for the manufacture of steel | |
US3832158A (en) | Process for producing metal from metal oxide pellets in a cupola type vessel | |
US6364929B1 (en) | Method for reprocessing steel slags and ferriferous materials | |
US5733358A (en) | Process and apparatus for the manufacture of steel from iron carbide | |
JP2690732B2 (en) | Steel manufacturing method | |
JP7518455B2 (en) | Molten iron production method | |
Bengtsson et al. | Ironmaking in the Stora rotary furnace | |
JPS62116712A (en) | Melting and smelting vessel having splash lance | |
JPH07207313A (en) | Method for melting tin-plated steel scrap | |
JPH0873916A (en) | Method for melting iron scrap by using vertical furnace | |
MXPA00004699A (en) | Method for reprocessing steel slags and ferriferous materials |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: VOEST-ALPINE, A CORP. OF AUSTRIA, AUSTRIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:FRITZ, ERNST;DIMITROV, STEFAN;REEL/FRAME:007283/0375 Effective date: 19941003 Owner name: VOEST-ALPINE INDUSTRIEANLAGENBAU GMBH, AUSTRIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:FRITZ, ERNST;DIMITROV, STEFAN;REEL/FRAME:007283/0375 Effective date: 19941003 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
REMI | Maintenance fee reminder mailed | ||
LAPS | Lapse for failure to pay maintenance fees | ||
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20090318 |