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US522619A - Electrolytic-decomposition tank - Google Patents

Electrolytic-decomposition tank Download PDF

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US522619A
US522619A US522619DA US522619A US 522619 A US522619 A US 522619A US 522619D A US522619D A US 522619DA US 522619 A US522619 A US 522619A
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tank
electrolytic
anode
cathode
decomposition tank
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells

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  • This invention is an improvement in tanks for the electrolytic decomposition of metallic salts, but more particularly for use in connectlon with a particular apparatus designed by me for this purpose, the character of which maybe thus generally described.
  • the vat or receptacle for containing the solution to be decomposed is made of iron or like metal,in order that it may serve also as the cathode of the couple.
  • a carbon anode separated from the cathode by a mass Of pulverized anthracite coal contained in a bag or other receptacle and packed in around the anode, the purpose of the coal being to form an electrolytic diaphragm or partition between the two electrodes.
  • Figure 1 is a plan View of the apparatus.
  • Fig. 2 is avertical section on line ale-00, of Fig. 1.
  • A is the usual cathode tank or vat of iron or suitable material.
  • B, B are angle plates of the same material placed on end in any desired manner to divide the main tank or vat up into small compartments or cells. These plates are independent and preferably placed in the tank without connections-at least no permanent connections.
  • the main vat A forms,in part, the walls, while the walls of the inner compartmentsare composed en tirely of the angle plates.
  • O, O are the anodes or bags containing the same. These are connected to one of the main wires D, while a binding post E, on the tank A, serves to connect all the'cathode surfaces to the other wire F.
  • This arrangement effects a great saving in material and cost, and makes available large rectangular tanks which are the easiest and cheapest to make 'andmost economical to use.
  • Wlfat I claim is- 1.
  • a cathode or conducting vat or tank of sheets or plates of conducting material placed therein in electrical connection with the tank and dividing said tank into vertical communicating compartments, and an anode supported in each cathode compartment, as set forth.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Description

(No Model.) I
I. L. ROBERTS.
ELECTROLYTIC DECOMPOSITION TANK. No. 522,619, Patented July 10, 1894.
Wwzmsafiz [said Z. 153060175 fave/dwfmu Q K M 4y UNIT D STATES PATENT OF ICE.-
ISAIAH L. ROBERTS, OEBROOK LYN, NEW YORK.
ELECTROLYTtC-DECOMPOSITION TANK.
SPECIFICATION forming part of Letters Patent NO. 522,61 9, dated July 10, 1894.
Applicationfiled November 25, 1891. Renewed January 29; 1894- Serial No. 498,399- (No model.)
To all whom, it may concern:
Be it known that I, ISAIAH L. ROBERTS, a
citizen of theUnited States, residing at Brooklyn, in the county of Kings and State of New York, have invented certain new and useful Improvements in Electrolytic-Decomposition Tanks, of which the following is a specification, reference being had tothe drawings accompanying and forming apart of the same.
This invention is an improvement in tanks for the electrolytic decomposition of metallic salts, but more particularly for use in connectlon with a particular apparatus designed by me for this purpose, the character of which maybe thus generally described. The vat or receptacle for containing the solution to be decomposed is made of iron or like metal,in order that it may serve also as the cathode of the couple. Within this vat is suspended a carbon anode separated from the cathode by a mass Of pulverized anthracite coal contained in a bag or other receptacle and packed in around the anode, the purpose of the coal being to form an electrolytic diaphragm or partition between the two electrodes. Various other electrodes and many forms of electrolytic partitionsmay be used and difierent appliances and constructions adopted for carryingoff the gases generated at the anode or acids resulting from impuritiesand chemical combinations inthe coal dust, but the essential feature, so far as this invention is concerned, is the use in an apparatus of this kind of an anode in an iron cathode tank.
In practice it has been found convenient to employ a number of anodes in one large cathode tank, as the construction of a separate iron tank for each anode involves great expense and waste of material, but when a number of anodes are suspended or supported in one tank, the distance between some of them and the walls of the tank increases the internal resistance of these couples to such an extent as to impair their efficiency. This I avoid by dividing up the interior space in the main tank into a number of vertical compartments by means of angle iron plates set on end.- Each of such compartments contains an anode, and communication for the circulation of solution is maintained between all of them through the joints or spaces left between the several plates.
This improvement is shown in detail in the accompanying drawings.
Figure 1 is a plan View of the apparatus.
Fig. 2 is avertical section on line ale-00, of Fig. 1.
A is the usual cathode tank or vat of iron or suitable material.
B, B, are angle plates of the same material placed on end in any desired manner to divide the main tank or vat up into small compartments or cells. These plates are independent and preferably placed in the tank without connections-at least no permanent connections. For the outer compartments the main vat A forms,in part, the walls, while the walls of the inner compartmentsare composed en tirely of the angle plates.
O, O, are the anodes or bags containing the same. These are connected to one of the main wires D, while a binding post E, on the tank A, serves to connect all the'cathode surfaces to the other wire F. This arrangement effects a great saving in material and cost, and makes available large rectangular tanks which are the easiest and cheapest to make 'andmost economical to use.-
Wlfat I claim is- 1. In an electrolytic apparatus, the combination with a cathode or conducting vat or tank, of sheets or plates of conducting material placed therein in electrical connection with the tank and dividing said tank into vertical communicating compartments, and an anode supported in each cathode compartment, as set forth.
2. The combination, with a cathode or iron Vat or tank, of iron angle plates set on end therein in electrical connection with the tank, and dividing said tank into a number of small communicating anode compartments, and an anode contained in each of said compartments, as set'forth.
ISAIAH L. ROBERTS.
Witnesses:
RO T. F. GAYLORD, H PARKER W. PAGE. I v, w.
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