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US4309189A - Method and means for producing sustained colored flames - Google Patents

Method and means for producing sustained colored flames Download PDF

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Publication number
US4309189A
US4309189A US06/174,006 US17400680A US4309189A US 4309189 A US4309189 A US 4309189A US 17400680 A US17400680 A US 17400680A US 4309189 A US4309189 A US 4309189A
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matrix
flame
color
metallic compound
mixture
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US06/174,006
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Bruce J. Oberhardt
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives

Definitions

  • This invention relates to a method for producing prolonged coloration of the flames in a fire, and to a flame coloration compound used in said method.
  • Prior attempts to enhance colored flame production have produced only short-lived results. The color production often was not great as well as lasting only a short time.
  • Previous compounds have, generally, been one of four types.
  • the first type includes powders which are sprinkled, poured or placed upon logs in a fire. These powders have usually been metallic salts.
  • the second type is cakes or pellets formed of a combination of metallic salts and paraffin. These cakes increase the intensity of the yellow flame due to the combustion of paraffin, but the length of the burn and the colored flame propogation is short.
  • Pre-treating of logs is a third type of treatment to produce colored flame. Logs are soaked either overnight or for several days in a metallic salt solution.
  • Synthetic logs have been treated with color producing material.
  • the synthetic logs are used primarily for fuel and burning thereof lacks the color brilliance of the aforementioned, pre-treated logs.
  • Synthetic logs are produced from a composition of sawdust, wood chips and paraffin. Some metallic salts may be used in synthetic logs. This is usually done to tone down the intense yellow color resulting from the combustion of paraffin.
  • the present invention consists of the use of an optimized mixture of two constituents, (1) a specific chemical or mixture of chemicals in solid or powdered form which produces flames of desired color when placed in an open fire, usually a metallic salt; and (2) a non-combustible or slow-burning non-volatile second substance or matrix material or mixture thereof.
  • the color producing chemical is either absorbed into the matrix before being placed into the fire or becomes absorbed with the matrix upon an interaction occurring within the fire.
  • the compound contains no oxidizing agent and thus is unable to sustain a flame by itself.
  • the matrix material e.g. boric acid, etc.
  • the matrix prolongs flame color by physically and/or chemically holding or entrapping the color compound.
  • the relatively low volatility of the matrix provides adherence of matrix on burning wood and logs, and this, in turn, keeps the color compound in flame contact for a substantial period of time. In the absence of the matrix, the effect of the color compound would be rapidly lost incident to vaporization of the compound or to its falling from the flames.
  • Another object of this invention is to provide a novel method of prolonging desired flame coloration in a fire.
  • FIG. 1 is a perspective view of one form of package of the color producing chemical.
  • FIG. 2 is a cross sectional view taken on line 2--2 of FIG. 1.
  • the compound of this invention is used to increase flame color in a fire, thereby creating a more aesthetic and colorful effect and increasing the observer's enjoyment of a fire.
  • the compound may be used in powdered form packaged in a combustible container or shaped into a solid form by use of a binder.
  • the container 10 consists of a series of individual packets 12, each separately sealed by seal lines 14 and each containing a selected quantity of powdered color producing material.
  • FIG. 2 depicts the separation of individual packets 12 created by sealing along seal lines 14. Color compound 16 is evenly distributed throughout each packet 12.
  • a container 10 of selected size containing a selected number of packets 12 is laid atop a log for burning.
  • Each packet 12 may contain the same or differing compounds 16.
  • the separation of individual packets 12 by seal lines 14 assures even distribution of compound 16 or compounds along the length or surface of the firewood or log.
  • the compound can also be formed into solid shapes with the addition of a binding agent.
  • a binding agent allows for the production of sheets, slabs and cakes which are more readily adaptable to a gas fire.
  • Binding agents used are of three kinds: (1) high molecular weight polyglycols, such as mono-methoxypolyethylene glycol of a molecular weight approaching 6,000, (2) paraffin and (3) acacia gums, (i.e., gum arabic).
  • the color compound is a mixture of a metallic salt, such as copper chloride or copper sulfate, and a matrix material or mixture thereof, such as boric acid and charcoal.
  • the metallic salts can be used either separately or in a mixture to produce any of a multiplicity of colors.
  • the color producing substances which may be utilized include copper compounds, e.g. copper sulfate and copper chloride, which produce flame coloration, as well as potassium halides, sodium halides, lithium sulfate, strontium chloride, barium chloride, a combination of copper sulfate and ammonium chloride, and a combination of copper chloride and ammonium chloride.
  • the matrices which may be used include boric acid, boric acid forming matrices, barium chloride, sucrose or carbon forming matrices, or carbon, e.g. powdered wood charcoal, magnesium chloride, lithium sulfate and aluminum sulfate.
  • Barium chloride is a matrix substance when mixed with certain color producing substances, and when mixed with other matrix substances it may be a color producing substance. The same is true for lithium sulfate.
  • ingredients which could be utilized for color producing substances include the metallic salts listed, as well as salts for barium and calcium. However, not all such metallic salts are suitable for use with the same matrix, and not all are advantageous for use in a wood fueled fire.
  • a mixture of 50 percent, by weight, ammonium chloride and 50 percent, by weight, copper sulfate (both constituents in powdered form) was prepared and labelled Component A.
  • Component A two parts, by weight, of boric acid (labelled Component B) was added.
  • Component B boric acid
  • the resulting mixture was compared with Component A alone and Component B alone in a flame.
  • a propane torch was utilized to provide the flame.
  • Each test batch was weighed out into a 30 mg. portion and poured onto an iron spatula. Each iron spatula was held in the flame for ten minutes, and progress of color development was observed.
  • Component A alone blue and green flames resulted with many in-between hues, combinations and variations.
  • Example 1 The experiment performed in Example 1 was performed with copper sulfate as Component A and boric acid as B. In this case, one part, by weight, of Component A was added to one part, by weight, of Component B. Component A produced a bright green flame for about 40 seconds. Component B provides dull green flames for about 30 seconds. The mixture of A and B, as in Example 1, was still producing green flame coloration after ten minutes.
  • a quantity of mixture consisting of 50 percent powdered boric acid, 25 percent powdered copper chloride and 25 percent powdered ammonium chloride was weighed out to 14 g. This mixture was placed in an average size fire fueled with natural wood logs. Flame colors (greens, blues, yellow greens) appeared after a few minutes in some areas of the fire. The flame colors reached a peak intensity after about 25 minutes and persisted for more than an hour.
  • Strontium chloride was applied to a flame, as in Example 1, and crimson colors were observed. After about 10 seconds the color ceased. Magnesium chloride was similarly applied to a flame and no color propogation was observed, except for the original propane color. A mixture of 50 percent strontium chloride and 50 percent magnesium chloride, both in granular form, was introduced to the flame. A 30 mg. sample of this mixture produced intense crimson flames for more than 10 minutes.
  • a mixture of 10 mg. powdered magnesium chloride, 10 mg. ammonium chloride, 10 mg. copper sulfate and 10 mg. lithium sulfate was held in a propane torch flame on an iron spatula and colors of blue, green, and intense magenta were observed.
  • the compound is copper borate (Cu(BO 2 ) 2 ). Copper borate is produced by the interaction of copper hydroxide and boric acid. Therefore, when using copper borate in a fire, i.e., a color producing copper compound (copper hydroxide) and a matrix are interacted prior to application to a fire, the result of use of the copper borate is the same as the result of applying to a fire separately the aforementioned components thereof.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

A chemical compound and the method for using it to produce and prolong colored flames. The compound contains a metallic salt and a matrix. The metallic salt produces the color and the matrix prolongs the life of that color.

Description

SUMMARY OF THE INVENTION
This invention relates to a method for producing prolonged coloration of the flames in a fire, and to a flame coloration compound used in said method.
Prior attempts to enhance colored flame production have produced only short-lived results. The color production often was not great as well as lasting only a short time. Previous compounds have, generally, been one of four types. The first type includes powders which are sprinkled, poured or placed upon logs in a fire. These powders have usually been metallic salts. The second type is cakes or pellets formed of a combination of metallic salts and paraffin. These cakes increase the intensity of the yellow flame due to the combustion of paraffin, but the length of the burn and the colored flame propogation is short. Pre-treating of logs is a third type of treatment to produce colored flame. Logs are soaked either overnight or for several days in a metallic salt solution. The soaked log, when dry, will burn and produce long-lasting, brilliant colors, provided sufficient chemicals have been used in the treatment. This method is very time consuming and inconvenient. Finally, synthetic logs have been treated with color producing material. The synthetic logs are used primarily for fuel and burning thereof lacks the color brilliance of the aforementioned, pre-treated logs. Synthetic logs are produced from a composition of sawdust, wood chips and paraffin. Some metallic salts may be used in synthetic logs. This is usually done to tone down the intense yellow color resulting from the combustion of paraffin.
The present invention consists of the use of an optimized mixture of two constituents, (1) a specific chemical or mixture of chemicals in solid or powdered form which produces flames of desired color when placed in an open fire, usually a metallic salt; and (2) a non-combustible or slow-burning non-volatile second substance or matrix material or mixture thereof. The color producing chemical is either absorbed into the matrix before being placed into the fire or becomes absorbed with the matrix upon an interaction occurring within the fire. The compound contains no oxidizing agent and thus is unable to sustain a flame by itself.
The matrix material, e.g. boric acid, etc., serves several purposes. The matrix prolongs flame color by physically and/or chemically holding or entrapping the color compound. The relatively low volatility of the matrix provides adherence of matrix on burning wood and logs, and this, in turn, keeps the color compound in flame contact for a substantial period of time. In the absence of the matrix, the effect of the color compound would be rapidly lost incident to vaporization of the compound or to its falling from the flames.
The addition of a second metallic salt has been used to increase color propogation produced by another metallic salt. However, the use of boric acid or barium chloride as a matrix to enhance the life of the color of flames has not been known heretofore.
Accordingly, it is an object of this invention to provide a novel material for producing prolonged colored flames in a fire.
Another object of this invention is to provide a novel method of prolonging desired flame coloration in a fire.
Other objects will become obvious upon a reading of the following description.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of one form of package of the color producing chemical.
FIG. 2 is a cross sectional view taken on line 2--2 of FIG. 1.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The preferred embodiments illustrated and described are not intended to be exhaustive or to limit the invention to the precise form disclosed. They are chosen and described in order to best explain the principles of the invention and its application and practical use to thereby enable others skilled in the art to best utilize the invention.
The compound of this invention is used to increase flame color in a fire, thereby creating a more aesthetic and colorful effect and increasing the observer's enjoyment of a fire. The compound may be used in powdered form packaged in a combustible container or shaped into a solid form by use of a binder. As shown in FIG. 1, the container 10 consists of a series of individual packets 12, each separately sealed by seal lines 14 and each containing a selected quantity of powdered color producing material. FIG. 2 depicts the separation of individual packets 12 created by sealing along seal lines 14. Color compound 16 is evenly distributed throughout each packet 12. In use, a container 10 of selected size containing a selected number of packets 12 is laid atop a log for burning. Each packet 12 may contain the same or differing compounds 16. The separation of individual packets 12 by seal lines 14 assures even distribution of compound 16 or compounds along the length or surface of the firewood or log.
The compound can also be formed into solid shapes with the addition of a binding agent. The use of a binding agent allows for the production of sheets, slabs and cakes which are more readily adaptable to a gas fire. Binding agents used are of three kinds: (1) high molecular weight polyglycols, such as mono-methoxypolyethylene glycol of a molecular weight approaching 6,000, (2) paraffin and (3) acacia gums, (i.e., gum arabic).
The color compound is a mixture of a metallic salt, such as copper chloride or copper sulfate, and a matrix material or mixture thereof, such as boric acid and charcoal. The metallic salts can be used either separately or in a mixture to produce any of a multiplicity of colors. The color producing substances which may be utilized include copper compounds, e.g. copper sulfate and copper chloride, which produce flame coloration, as well as potassium halides, sodium halides, lithium sulfate, strontium chloride, barium chloride, a combination of copper sulfate and ammonium chloride, and a combination of copper chloride and ammonium chloride. The matrices which may be used include boric acid, boric acid forming matrices, barium chloride, sucrose or carbon forming matrices, or carbon, e.g. powdered wood charcoal, magnesium chloride, lithium sulfate and aluminum sulfate. Barium chloride is a matrix substance when mixed with certain color producing substances, and when mixed with other matrix substances it may be a color producing substance. The same is true for lithium sulfate. As may be found in the pyrotechnic literature, ingredients which could be utilized for color producing substances include the metallic salts listed, as well as salts for barium and calcium. However, not all such metallic salts are suitable for use with the same matrix, and not all are advantageous for use in a wood fueled fire. A detailed description of the interaction of matrices and color producing substances is set out in Table One. All of the tests performed which are recorded in Table One have been carried out with wood fires. As shown with the asterisk (*) under the column for the final three matrices (magnesium chloride, lithium sulfate, aluminum sulfate) a propane flame, as found in gas fireplaces, as opposed to wood fireplaces, does produce excellent quality with the aforementioned matrices.
EXAMPLES EXAMPLE 1
A mixture of 50 percent, by weight, ammonium chloride and 50 percent, by weight, copper sulfate (both constituents in powdered form) was prepared and labelled Component A. To one part Component A, two parts, by weight, of boric acid (labelled Component B) was added. The resulting mixture was compared with Component A alone and Component B alone in a flame. For this experiment, a propane torch was utilized to provide the flame. Each test batch was weighed out into a 30 mg. portion and poured onto an iron spatula. Each iron spatula was held in the flame for ten minutes, and progress of color development was observed. For Component A alone, blue and green flames resulted with many in-between hues, combinations and variations. The color began as an intense blue, became greener and ceased to produce color after 45 seconds. Component B, alone, produced a green color of less intensity than Component A, the color fading to an imperceptible level in about 30 seconds. With the mixture of A and B, as described, colors similar to those obtained by A alone were produced. However, the flame coloration was observed for the duration of the experiment. At ten minutes when the experiment was terminated, a moderate level of green color persisted.
EXAMPLE 2
The experiment performed in Example 1 was performed with copper sulfate as Component A and boric acid as B. In this case, one part, by weight, of Component A was added to one part, by weight, of Component B. Component A produced a bright green flame for about 40 seconds. Component B provides dull green flames for about 30 seconds. The mixture of A and B, as in Example 1, was still producing green flame coloration after ten minutes.
EXAMPLE 3
A quantity of mixture consisting of 50 percent powdered boric acid, 25 percent powdered copper chloride and 25 percent powdered ammonium chloride was weighed out to 14 g. This mixture was placed in an average size fire fueled with natural wood logs. Flame colors (greens, blues, yellow greens) appeared after a few minutes in some areas of the fire. The flame colors reached a peak intensity after about 25 minutes and persisted for more than an hour.
EXAMPLE 4
Strontium chloride was applied to a flame, as in Example 1, and crimson colors were observed. After about 10 seconds the color ceased. Magnesium chloride was similarly applied to a flame and no color propogation was observed, except for the original propane color. A mixture of 50 percent strontium chloride and 50 percent magnesium chloride, both in granular form, was introduced to the flame. A 30 mg. sample of this mixture produced intense crimson flames for more than 10 minutes.
EXAMPLE 5
A mixture of 10 mg. powdered magnesium chloride, 10 mg. ammonium chloride, 10 mg. copper sulfate and 10 mg. lithium sulfate was held in a propane torch flame on an iron spatula and colors of blue, green, and intense magenta were observed.
It is noted that one compound has been found that is capable of acting as both color producing agent and matrix. The compound is copper borate (Cu(BO2)2). Copper borate is produced by the interaction of copper hydroxide and boric acid. Therefore, when using copper borate in a fire, i.e., a color producing copper compound (copper hydroxide) and a matrix are interacted prior to application to a fire, the result of use of the copper borate is the same as the result of applying to a fire separately the aforementioned components thereof.
It is understood that the invention is not to be limited by the preceding description but may be practiced within the scope of the appended claims.
                                  TABLE ONE                               
__________________________________________________________________________
COLOR                                                                     
PRODUCING                                                                 
        BORIC                                                             
             BARIUM       POWDERED                                        
                                  MAGNESIUM                               
                                          LITHIUM                         
                                                 ALUMINUM                 
AGENT   ACID CHLORIDE                                                     
                    SUCROSE                                               
                          CHARCOAL                                        
                                  CHLORIDE                                
                                          SULFATE                         
                                                 SULFATE                  
__________________________________________________________________________
Cu.sub.2 SO.sub.4                                                         
             Green/       Bright                                          
        Greens                                                            
             Yellow-                                                      
                    Green Green     --      --     --     Color           
             Green                                                        
                    Fair/ Fair/                                           
        Excel.                                                            
             Excel. Good  Good                            Quality         
KCl     Blue-             Dull    Dull    Dull   Dull                     
        Purple/                                                           
               --   Blue- Blue-   Blue-   Blue/Red                        
                                                 Blue-    Color           
        Green       Purple                                                
                          Purple  Purple  Purple Purple                   
                                  Fair-   Fair-  Fair-                    
        Good        Good  Good    Poor*   Poor*  Poor*    Quality         
NaCl    Yellow                                                            
        Green       Yellow                                                
                          Yellow                                          
        Good        Good  Good                                            
Cu.sub.2 SO.sub.4                                                         
             Blue & Blue/ Blue/                                           
  +     Blue/                                                             
             Yellow-                                                      
                    Green Green                           Color           
NH.sub.4 Cl                                                               
        Green                                                             
             Green                                                        
                    Fair/ Fair/                                           
        Excel.                                                            
             Excel. Good  Good                            Quality         
Cucl.sub.2   Blue &                                                       
 +      Blue/                                                             
             Yellow-                                                      
                    Blue/ Blue/                                           
NH.sub.4 Cl                                                               
        Green                                                             
             Green  Green Green                                           
                    Fair/ Fair/                                           
        Excel.                                                            
             Excel. Good  Good                                            
CuCl.sub.2   Green/                                                       
        Green                                                             
             Yellow-                                                      
                    Green Green                                           
             Green                                                        
                    Fair/ Fair/                                           
        Excel.                                                            
             Excel. Good  Good                                            
Li.sub.2 SO.sub.4                                                         
             Green                                                        
             to                   Magenta        Magenta                  
             Magenta                                                      
                                  Fair-          Fair-                    
             Fair                 Poor*          Poor*                    
SrCl.sub.2                                Crimson                         
                                  Crimson &      Crimson  Color           
                                          Magenta                         
                                  Fair-   Fair-  Fair-                    
                                  Poor*   Poor*  Poor*    Quality         
BaCl                              Yellow-        Yellow-                  
                                  Green          Green    Color           
                                  Fair-          Fair-                    
                                  Poor*          Poor*    Quality         
__________________________________________________________________________

Claims (3)

What I claim is:
1. A flame colorant consisting of a mixture of a color producing agent and a matrix, said color producing agent including at least one metallic compound, said matrix being a substantially low-volatile, non-combustible substance capable of prolonging the duration of flame coloration over that achieved by either of said agent or said matrix alone, and said matrix is a material of low volatility selected from a group of the class consisting essentially of boric acid or a source thereof, barium chloride, magnesium chloride, lithium sulfate and aluminum sulfate.
2. The method of producing sustained colored flames of a fire consisting of applying to a flame a mixture consisting of at least one color producing metallic compound and at least one matrix, said matrix consisting of a substantially non-combustible substance, wherein said metallic compound and said matrix are mixed and interact prior to application thereof to produce a mixture capable of prolonging the duration of flame coloration over that achieved by either said metallic compound or said matrix used along, said matrix being a material which consists of at least one of the following: boric acid or a source thereof, barium chloride, magnesium chloride, lithium sulfate, and aluminum sulfate.
3. The method of producing sustained colored flames of a fire consisting of applying to a flame a mixture consisting of at least one color producing metallic compound and at least one matrix, said matrix consisting of a substantially non-combustible substance, wherein said metallic compound and said matrix are mixed and interact prior to application thereof to produce a mixture capable of prolonging the duration of flame coloration over that achieved by either said metallic compound or said matrix used alone, said metallic compound being copper hydroxide and said matrix being boric acid which have interacted to form copper borate.
US06/174,006 1980-07-31 1980-07-31 Method and means for producing sustained colored flames Expired - Lifetime US4309189A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6203586B1 (en) * 2000-01-12 2001-03-20 John W. Davis Fire enhancement system
EP1111300A3 (en) * 1999-12-20 2002-07-24 Lerchner, Leonhard Lighting device
US6752622B2 (en) 2001-06-06 2004-06-22 John Sherman Lesesne Lamp and candle with a colored flame
US20060016123A1 (en) * 2004-07-23 2006-01-26 Ashok Chandaria Firelog that crackles and has a colored flame
US20080271365A1 (en) * 2007-05-03 2008-11-06 Jonathan Goldfarb Long-Lasting Flame Colorant Composition, Device, And Method Of Production
US20090269711A1 (en) * 2008-04-28 2009-10-29 Sandra Haugen Color enhancement system for fires
US7878796B1 (en) 2007-11-10 2011-02-01 La Torre Innovations LLC Colored flame candle
US20130118057A1 (en) * 2011-06-26 2013-05-16 Jon Ross Method for Manufacturing a Gelled Fuel Heat Source
US8894409B1 (en) 2007-11-10 2014-11-25 La Torre Innovation LLC Colored flame candle

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1617996A (en) * 1925-12-22 1927-02-15 Chadeloid Chemical Co Flame-coloring agent
US1705020A (en) * 1925-09-25 1929-03-12 Koppers Co Inc Coke treatment and product
US2398571A (en) * 1941-11-26 1946-04-16 Clarence B F Young Fuel unit for producing colored flames
US3107511A (en) * 1960-06-17 1963-10-22 Hamsag-Garshanin Xenia Colored flame candle
US3150510A (en) * 1961-12-07 1964-09-29 Emmett P Klopfenstein Candle
US3370932A (en) * 1963-11-27 1968-02-27 Johnson Coal Cubing Co Flame coloring product and method of manufacturing same
US4042313A (en) * 1976-03-19 1977-08-16 Philadelphia Quartz Company Method of imparting color to fires
US4202669A (en) * 1975-04-30 1980-05-13 Ball Andrew C Fire-lighters

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1705020A (en) * 1925-09-25 1929-03-12 Koppers Co Inc Coke treatment and product
US1617996A (en) * 1925-12-22 1927-02-15 Chadeloid Chemical Co Flame-coloring agent
US2398571A (en) * 1941-11-26 1946-04-16 Clarence B F Young Fuel unit for producing colored flames
US3107511A (en) * 1960-06-17 1963-10-22 Hamsag-Garshanin Xenia Colored flame candle
US3150510A (en) * 1961-12-07 1964-09-29 Emmett P Klopfenstein Candle
US3370932A (en) * 1963-11-27 1968-02-27 Johnson Coal Cubing Co Flame coloring product and method of manufacturing same
US4202669A (en) * 1975-04-30 1980-05-13 Ball Andrew C Fire-lighters
US4042313A (en) * 1976-03-19 1977-08-16 Philadelphia Quartz Company Method of imparting color to fires

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1111300A3 (en) * 1999-12-20 2002-07-24 Lerchner, Leonhard Lighting device
US6203586B1 (en) * 2000-01-12 2001-03-20 John W. Davis Fire enhancement system
US6752622B2 (en) 2001-06-06 2004-06-22 John Sherman Lesesne Lamp and candle with a colored flame
US20060016123A1 (en) * 2004-07-23 2006-01-26 Ashok Chandaria Firelog that crackles and has a colored flame
US20080271365A1 (en) * 2007-05-03 2008-11-06 Jonathan Goldfarb Long-Lasting Flame Colorant Composition, Device, And Method Of Production
US7878796B1 (en) 2007-11-10 2011-02-01 La Torre Innovations LLC Colored flame candle
US20110086320A1 (en) * 2007-11-10 2011-04-14 La Torre Justin S Colored flame candle
US8894409B1 (en) 2007-11-10 2014-11-25 La Torre Innovation LLC Colored flame candle
US20090269711A1 (en) * 2008-04-28 2009-10-29 Sandra Haugen Color enhancement system for fires
US8118589B2 (en) 2008-04-28 2012-02-21 Sandra Haugen Color enhancement system for fires
US20130118057A1 (en) * 2011-06-26 2013-05-16 Jon Ross Method for Manufacturing a Gelled Fuel Heat Source

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