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US3862018A - Rigidizing process for screens with aluminum frames - Google Patents

Rigidizing process for screens with aluminum frames Download PDF

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Publication number
US3862018A
US3862018A US370326A US37032673A US3862018A US 3862018 A US3862018 A US 3862018A US 370326 A US370326 A US 370326A US 37032673 A US37032673 A US 37032673A US 3862018 A US3862018 A US 3862018A
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US
United States
Prior art keywords
screen
frame
aluminum
nickel
stainless steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US370326A
Inventor
Pat F Mentone
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Individual
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Priority to US370326A priority Critical patent/US3862018A/en
Application granted granted Critical
Publication of US3862018A publication Critical patent/US3862018A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00Electroforming
    • C25D1/08Perforated or foraminous objects, e.g. sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/14Forme preparation for stencil-printing or silk-screen printing
    • B41C1/142Forme preparation for stencil-printing or silk-screen printing using a galvanic or electroless metal deposition processing step
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/12Electroplating: Baths therefor from solutions of nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/36Pretreatment of metallic surfaces to be electroplated of iron or steel
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/42Pretreatment of metallic surfaces to be electroplated of light metals
    • C25D5/44Aluminium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated

Definitions

  • This invention relates generally to printing screens and methods of making printing screens and, more particularly, to rigidized self-supporting printing screens.
  • problems occur when it is desired to use a lightweight frame such as aluminum to support a screen to be rigidized. While other frames such as stainless steel are suitable, it is oftentimes preferred to use an aluminum frame for various reasons.
  • the aluminum frame has good strength, good dimensional stability, good corrosion resistance besides being light, easy to cast, and generally less expensive than other types of frames.
  • the use of an aluminum frame to support a screen to be encapsulated in nickel creates a problem because the aluminum is not passive in the nickel plating solution. Consequently, to plate nickel onto a screen with an aluminum frame produces a secondary reaction in the nickel plating solution that affects the encapsulating properties of the nickel.
  • the present invention eliminates the problem of plating on an active metal frame such as aluminum by using two plating solutions, a first zincating solution to plate onto the aluminum frame but not onto the stainless steel screen and a second nickel plating solution to encapsulate and rigidize the screen.
  • the invention comprises a process and a method for producing an improved rigidized screen with an aluminum frame for use in the printing industry.
  • the invention includes an improved apparatus or screen for use in the printing industry.
  • the frame and screen are subjected to a spray rinse to remove any impurities or particles on the screen and frame.
  • the screen and frame are then immersed in a nitric acid bath for approximately 30 seconds to remove any remaining impurities on the screen and frame.
  • the screen and frame are subjected to a rinse of normal tap water to remove any nitric acid and thus prepare the frame and screen for the zincation step.
  • the screen and frame are zincated for 1 minute in a zincating solution by immersing the aluminum frame and screen in the zincating solution which typically comprises sodium hydroxide and zinc hydroxide.
  • the zincating solution typically comprises sodium hydroxide and zinc hydroxide.
  • sodium hydroxide and zinc hydroxide are described, other zincating solutions could also be used.
  • the outer layer of aluminum oxide is dissolved and replaced with a fine layer of zinc while the stainless steel screen remains unaffected by the zincating solution, i.e., the zinc does not plate onto the stainless steel. Care must be taken in zincating the aluminum frame to ensure that enough zinc is plated onto the aluminum frame to cover all the exposed areas of the frame.
  • the screen and frame are removed and washed with a deionized water spray to remove any zincating solution on the frame and screen.
  • the final step to rigidize the screen requires plating nickel onto the flexible but taut screen to encapsulate the screen to thereby produce a rigid screen.
  • nickel sulfamate bath with a PH of approximately 5.
  • the higher PI-I is desirable and preferred as it does not readily attack the zinc layer on the aluminum frame.
  • the nickel forms a harder and stronger deposit around the stainless steel wires which produces a substantially stronger screen.
  • the thickness of the nickel layer need only be on the order of 0.1 mil to 0.2 mil to produce a rigidized screen.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

An improved process for rigidized screen for printing and the like in which the frame is zincated prior to rigidizing the screen by encapsulating the screen in nickel.

Description

United States Patent Mentone Jan. 21, 975
[ RIGIDIZING PROCESS FOR SCREENS 2,640,789 6/1953 Hausner 204/24 WITH ALUMINUM FRAMES 2,978,389 4/1961 Tumbull Inventor: Pat F. Mentone, 1756 Eleanor St.,
St. Paul, Minn. 55116 Filed: June 15, 1973 Appl. No.: 370,326
Related US. Application Data Division of Ser. No. 198,396, Nov. 12, 1971, Pat. No.
References Cited UNITED STATES PATENTS 11/1933 Rafton 204/21 3,482,300 12/1969 Reinke 204/16 OTHER PUBLICATIONS Metal Finishing Guidebook Directory, 1968, pgs. 222-224.
Primary ExaminerR. L. Andrews Attorney, Agent, or Firm-Jacobson and Johnson ABSTRACT 1 Claim, N0 Drawings RIGIDIZING PROCESS FOR SCREENS WITH ALUMINUM FRAMES This is a division, of application Ser. No. 198,396, filed Nov. 12, 1971, now U.S. Pat. No. 3,752,187.
BACKGROUND OF THE INVENTION Field of the Invention This invention relates generally to printing screens and methods of making printing screens and, more particularly, to rigidized self-supporting printing screens.
Description of the Prior Art There are numerous printing screens and methods of rigidizing flexible printing screens as evidenced by the Rafton U.S. Pat. No. 1,934,643, and the Reinke U.S. Pat. No. 3,482,300. Basically, these patents teach the coating of a screen to rigidize it by electrolytically coating the screen with a suitable material. For example, the Reinke patent shows a screen which is rigidized by electrolytically depositing nickel on a stainless steel screen. Reinke indicates that a uniform deposit of A to 1 mil of nickel on both faces of the screen is sufficient to rigidize the screen. While prior art processes of this type work relatively well, with screens having stainless steel frames, they are not suitable for all applications. For example, problems occur when it is desired to use a lightweight frame such as aluminum to support a screen to be rigidized. While other frames such as stainless steel are suitable, it is oftentimes preferred to use an aluminum frame for various reasons. Generally, the aluminum frame has good strength, good dimensional stability, good corrosion resistance besides being light, easy to cast, and generally less expensive than other types of frames. The use of an aluminum frame to support a screen to be encapsulated in nickel creates a problem because the aluminum is not passive in the nickel plating solution. Consequently, to plate nickel onto a screen with an aluminum frame produces a secondary reaction in the nickel plating solution that affects the encapsulating properties of the nickel. Although other encapsulating materials have been tried, it is preferred to use a final nickel finish on the screen because of its strength and corrosion resistance. Furthermore, an alternate method of using two plating materials, i.e., a first plating solution to plate onto both the aluminum and stainless steel and a second nickel plating solution to encapsulate the screen, is undesirable because the two layers of plating would substantially reduce the openings in the screen.
The present invention eliminates the problem of plating on an active metal frame such as aluminum by using two plating solutions, a first zincating solution to plate onto the aluminum frame but not onto the stainless steel screen and a second nickel plating solution to encapsulate and rigidize the screen.
SUMMARY OF THE INVENTION Briefly, the invention comprises a process and a method for producing an improved rigidized screen with an aluminum frame for use in the printing industry. In its further embodiment the invention includes an improved apparatus or screen for use in the printing industry.
DESCRIPTION OF THE PREFERRED EMBODIMENT In the preferred embodiment of my invention, one prepares an aluminum frame with a stainless steel screen for rigidizing by first cleaning the screen and frame. In the first step, one generally cleans the aluminum frame with a stainless steel screen in an aluminum etch cleaner. Next, the frame and screen are subjected to a spray rinse to remove any impurities or particles on the screen and frame. The screen and frame are then immersed in a nitric acid bath for approximately 30 seconds to remove any remaining impurities on the screen and frame. After the nitric acid bath, the screen and frame are subjected to a rinse of normal tap water to remove any nitric acid and thus prepare the frame and screen for the zincation step.
In the zincation step, the screen and frame are zincated for 1 minute in a zincating solution by immersing the aluminum frame and screen in the zincating solution which typically comprises sodium hydroxide and zinc hydroxide. Although sodium hydroxide and zinc hydroxide are described, other zincating solutions could also be used. During the zincating process, the outer layer of aluminum oxide is dissolved and replaced with a fine layer of zinc while the stainless steel screen remains unaffected by the zincating solution, i.e., the zinc does not plate onto the stainless steel. Care must be taken in zincating the aluminum frame to ensure that enough zinc is plated onto the aluminum frame to cover all the exposed areas of the frame. However, too long exposure to the zincating solution causes the zinc to form flakes and ridges that fall off when the aluminum frame is immersed in the nickel plating solution. Typically, l have found for a zincating solution at room temperature about one minute is sufficient time to produce a zinc coating of proper thickness.
After zincating, the screen and frame are removed and washed with a deionized water spray to remove any zincating solution on the frame and screen.
As the zincating process does not plate any zinc onto the stainless steel screen, it is apparent that at this stage the screen is uncovered while the aluminum frame is covered with a layer of zinc.
The final step to rigidize the screen requires plating nickel onto the flexible but taut screen to encapsulate the screen to thereby produce a rigid screen. In order to properly plate the nickel it is preferred to use a nickel sulfamate bath with a PH of approximately 5. The higher PI-I is desirable and preferred as it does not readily attack the zinc layer on the aluminum frame. Furthermore, with a higher PH the nickel forms a harder and stronger deposit around the stainless steel wires which produces a substantially stronger screen.
While my process is described with respect to aluminum frames, it is apparent that my process will work equally well with aluminum alloy frames and other active metal frames such as magnesium.
With my process it has also been found that the thickness of the nickel layer need only be on the order of 0.1 mil to 0.2 mil to produce a rigidized screen.
I claim:
1. The method of rigidizing a flexible printing screen mounted on a metal frame where the metal frame contains aluminum and the flexible printing screen is stainless steel comprising:
a. cleaning the aluminum frame and the stainless steel screen;
b. immersing both the aluminum frame and the stainless steel screen in a zincating solution for approximately one minute to thereby ensure that enough zinc is plated onto the aluminum frame to cover the exposed area of the frame while the stainless steel mately 5 until a nickel layer of 0.1 mil to 0.2 mil screen remains uncovered; and
c. electroplating nickel on both the stainless steel screen and the zinc coated aluminum frame in a nickel sulfamate bath having a pH of approxi- 5 thickness is obtained on the screen to thereby produce a rigidized screen.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent 3,862,018 Dated January 21, 1975 O Inventor-( F. It is certified that error appears in the above-identified patent and that said Letters Patentare hereby corrected as shown below:
In the Related U.S. Application Data on page 1, column 1, line 9., "3,752,187" should be changed to --3,749,0l0
Signcd and Scalcd this Twenty-first Day of Aprill98l [SEAL] Anm:
. RENE D. TEGTMEYER Arresting Oflicer Acting Commissioner of Patents and Trademarks
US370326A 1971-11-12 1973-06-15 Rigidizing process for screens with aluminum frames Expired - Lifetime US3862018A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US370326A US3862018A (en) 1971-11-12 1973-06-15 Rigidizing process for screens with aluminum frames

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19839671A 1971-11-12 1971-11-12
US370326A US3862018A (en) 1971-11-12 1973-06-15 Rigidizing process for screens with aluminum frames

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4197359A (en) * 1975-10-21 1980-04-08 Rager Edgar A Hub for a disk storage medium
EP0029348A2 (en) * 1979-11-15 1981-05-27 Institute For Industrial Research And Standards Metal printing screen for flat screen printing
US4543803A (en) * 1983-11-30 1985-10-01 Mark Keyasko Lightweight, rigid, metal product and process for producing same
US4705608A (en) * 1984-11-14 1987-11-10 Ferd Ruesch Ag Process for making screen printing fabrics for screen printing cylinders
US5268068A (en) * 1992-12-08 1993-12-07 International Business Machines Corporation High aspect ratio molybdenum composite mask method
EP0924320A2 (en) * 1997-12-16 1999-06-23 Totoku Electric Co., Ltd. Method of fabricating a copper plated aluminium wire, a plated aluminium wire, an insulating plated aluminium wire, methods of fabricating thereof, and a composite lightweighted plated aluminium wire
US6364247B1 (en) 2000-01-31 2002-04-02 David T. Polkinghorne Pneumatic flotation device for continuous web processing and method of making the pneumatic flotation device
WO2002086197A1 (en) * 2001-04-20 2002-10-31 Corus Aluminium Walzprodukte Gmbh Method of plating and pretreating aluminium workpieces
US20040115468A1 (en) * 2002-01-31 2004-06-17 Joseph Wijenberg Jacques Hubert Olga Brazing product and method of manufacturing a brazing product
US20040121180A1 (en) * 2002-12-13 2004-06-24 Wittebrood Adrianus Jacobus Brazing sheet product and method of its manufacture
US20040131879A1 (en) * 2002-12-13 2004-07-08 Wittebrood Adrianus Jacobus Brazing sheet product and method of its manufacture
US20060121306A1 (en) * 2002-01-31 2006-06-08 Jacques Hubert Olga Wijenberg Brazing product and method of its manufacture
US20060157352A1 (en) * 2005-01-19 2006-07-20 Corus Aluminium Walzprodukte Gmbh Method of electroplating and pre-treating aluminium workpieces
US20090229989A1 (en) * 2006-09-22 2009-09-17 Istanbul Teknik Universitesi Method for the preparation of nanostructures and nanowires

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1934643A (en) * 1930-01-14 1933-11-07 Rafton Engineering Corp Wire cloth and method of producing the same
US2640789A (en) * 1948-12-04 1953-06-02 Hausner Joseph Method of producing reinforced wire netting
US2978389A (en) * 1958-03-07 1961-04-04 Philips Corp Method of tensioning thin meshes of metal
US3482300A (en) * 1966-10-31 1969-12-09 Screen Printing Systems Inc Printing screen and method of making same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1934643A (en) * 1930-01-14 1933-11-07 Rafton Engineering Corp Wire cloth and method of producing the same
US2640789A (en) * 1948-12-04 1953-06-02 Hausner Joseph Method of producing reinforced wire netting
US2978389A (en) * 1958-03-07 1961-04-04 Philips Corp Method of tensioning thin meshes of metal
US3482300A (en) * 1966-10-31 1969-12-09 Screen Printing Systems Inc Printing screen and method of making same

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4197359A (en) * 1975-10-21 1980-04-08 Rager Edgar A Hub for a disk storage medium
EP0029348A2 (en) * 1979-11-15 1981-05-27 Institute For Industrial Research And Standards Metal printing screen for flat screen printing
EP0029348A3 (en) * 1979-11-15 1982-01-20 Institute For Industrial Research And Standards Metal printing screen for flat screen printing
US4543803A (en) * 1983-11-30 1985-10-01 Mark Keyasko Lightweight, rigid, metal product and process for producing same
US4705608A (en) * 1984-11-14 1987-11-10 Ferd Ruesch Ag Process for making screen printing fabrics for screen printing cylinders
US5268068A (en) * 1992-12-08 1993-12-07 International Business Machines Corporation High aspect ratio molybdenum composite mask method
EP0924320A2 (en) * 1997-12-16 1999-06-23 Totoku Electric Co., Ltd. Method of fabricating a copper plated aluminium wire, a plated aluminium wire, an insulating plated aluminium wire, methods of fabricating thereof, and a composite lightweighted plated aluminium wire
EP0924320A3 (en) * 1997-12-16 2001-09-12 Totoku Electric Co., Ltd. Method of fabricating a copper plated aluminium wire, a plated aluminium wire, an insulating plated aluminium wire, methods of fabricating thereof, and a composite lightweighted plated aluminium wire
US6364247B1 (en) 2000-01-31 2002-04-02 David T. Polkinghorne Pneumatic flotation device for continuous web processing and method of making the pneumatic flotation device
US6846401B2 (en) 2001-04-20 2005-01-25 Corus Aluminium Walzprodukte Gmbh Method of plating and pretreating aluminium workpieces
WO2002086197A1 (en) * 2001-04-20 2002-10-31 Corus Aluminium Walzprodukte Gmbh Method of plating and pretreating aluminium workpieces
AU2002316865B2 (en) * 2001-04-20 2006-07-20 Corus Aluminium Walzprodukte Gmbh Method of plating and pretreating aluminium workpieces
US20040115468A1 (en) * 2002-01-31 2004-06-17 Joseph Wijenberg Jacques Hubert Olga Brazing product and method of manufacturing a brazing product
US6994919B2 (en) 2002-01-31 2006-02-07 Corus Aluminium Walzprodukte Gmbh Brazing product and method of manufacturing a brazing product
US20060121306A1 (en) * 2002-01-31 2006-06-08 Jacques Hubert Olga Wijenberg Brazing product and method of its manufacture
US7294411B2 (en) 2002-01-31 2007-11-13 Aleris Aluminum Koblenz Gmbh Brazing product and method of its manufacture
US20040131879A1 (en) * 2002-12-13 2004-07-08 Wittebrood Adrianus Jacobus Brazing sheet product and method of its manufacture
US7056597B2 (en) 2002-12-13 2006-06-06 Corus Aluminium Walzprodukte Gmbh Brazing sheet product and method of its manufacture
US7078111B2 (en) 2002-12-13 2006-07-18 Corus Aluminium Walzprodukte Gmbh Brazing sheet product and method of its manufacture
US20040121180A1 (en) * 2002-12-13 2004-06-24 Wittebrood Adrianus Jacobus Brazing sheet product and method of its manufacture
US20060157352A1 (en) * 2005-01-19 2006-07-20 Corus Aluminium Walzprodukte Gmbh Method of electroplating and pre-treating aluminium workpieces
US20090229989A1 (en) * 2006-09-22 2009-09-17 Istanbul Teknik Universitesi Method for the preparation of nanostructures and nanowires

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