US3661572A - Manufacturing process for manufacturing electrophotographic sensitive material - Google Patents
Manufacturing process for manufacturing electrophotographic sensitive material Download PDFInfo
- Publication number
- US3661572A US3661572A US60118A US3661572DA US3661572A US 3661572 A US3661572 A US 3661572A US 60118 A US60118 A US 60118A US 3661572D A US3661572D A US 3661572DA US 3661572 A US3661572 A US 3661572A
- Authority
- US
- United States
- Prior art keywords
- zinc oxide
- water
- dye
- powder
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/09—Sensitisors or activators, e.g. dyestuffs
Definitions
- This invention relates to a novel electrophotographic sensitive layer.
- the electrophotographic sensitive layer In obtaining a print by the electrofax process from the original of a color slide produced by using a silver halide photographic film, for example, the electrophotographic sensitive layer is required to have, as its property, photosensitivity over the whole visible range and gradation reproducibility of low contrast.
- the photosensitivity extending over the whole visible range is generally conferred upon by causing more than one kind of sensitizing dye to be adsorbed on the photoconductive material. Where zinc oxide is used as the photoconductive material, the resulting gradation reproducibility is generally of high contrast.
- the gradation is accomplished by controlling the particle size distribution of silver halides to be used.
- the electrophotographic process which uses a photoconductive material, however, it has been difficult to employ such means of gradation control.
- gradation control by regulating the distribution of the amount of sensitizing dye to be adsorbed on the photoconductive element, uniform adsorption tends to occur as a consequence of desorption and resorption of sensitizing dye in the course of sensitive layer production, making it difficult to achieve desired results.
- an object of this invention resides in providing a manufacturing process for a zinc oxide insulative resin type electrophotographic sensitive material having excellent gradation reproducibility.
- Another object of the present invention consists in providing a satisfactory process for depositing a sensitizing dye fast onto zinc oxide particles.
- the aforementioned objects of this invention have been accomplished by the discovery of a manufacturing process for an electrophotographic sensitive material, characterized by adding a lead compound soluble in water and capable of generating lead ions upon dissolution in water and a water-soluble dye possessed of carboxyl group to a slurry prepared by dispersing a finely divided photoconductive zinc oxide in water thereby allowing the said dye to be deposited fast on the surface of zinc oxide so as to give rise to a colored zinc oxide powder, washing the said powder with water, subsequently blending the colored powder (which may be mixed with untreated zinc oxide powder as occasion demands) with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface.
- the aforementioned colored zinc oxide powder is such that the dye on zinc oxide is deposited with sufficient strength, separation of the deposited dye or re-adsorption to other zinc oxide occurs very seldom even when it is mixed with untreated zinc oxide. Therefore, there can be obtained an electrophotographic sensitive layer having low contrast of gradation reproducibility by mixing the aforementioned colored zinc oxide powder with untreated zinc oxide.
- the dye to be used for the present invention contains carboxyl group and is easy to be deposited on zinc oxide.
- the dye which contains sulfonyl group is generally difficult to be deposited.
- the lead ion which is utilized for the present invention has been found to have a higher capacity to deposit dye than other heavy metal ions.
- As compounds which donate such lead on there are used water-soluble salts of lead nitrate, lead acetate, etc.
- the reaction for depositing dye onto zinc oxide is carried out within a water dispersion.
- this is accomplished by preparing a slurry having zinc oxide sufficiently dispersed in water in advance and then adding into this dispersion of zinc oxide an aqueous solution containing therein a dye solution and lead ion.
- the dye is insolubilized through combination with lead ion and consequently deposited fast on the surface of zinc oxide.
- the water slurry may be heated.
- the combination of dye and zinc oxide thus obtained is then washed sufficiently with water. This treatment of washing with water is aimed at removing water-soluble ion and therefore is important.
- the colored, finely divided zinc oxide powder thus obtained is mixed with untreated zinc oxide as required and added into an insulative resin.
- an electrophotographic sensitive material By spreading the resultant mixture in the form of a layer on an electroconductive base, there can be obtained an electrophotographic sensitive material.
- the zinc oxide to be used for the purpose of this invention is manufactured generally by French process and has photoconductivity.
- the amount of dye to be used for this invention is in the range of from 0.000 1 to 2 parts by weight based on parts by weight of zinc oxide.
- a dye which is not adsorbed on zinc oxide in water can be used. That is to say, the dye to be used has only to satisfy the requirement that it should be deposited fast onto zinc oxide in the presence of lead ion.
- Eorsin, eriochrome cyanin R (color index 43,820), Chromazurol S (color index 43,825), alizarin violet (color index 45,445), phloxine (color index (acid red 98) 45,405), fluorescein, chrome pure blue (color index 43,830), chrome brilliant violet (color index 43,865), mordant brilliant red B (color index 45,305 chrome yellow GG (color index 14,025), chrome yellow M (color index 14,095 mordant blue 47 (color index 43,855).
- the dyes have invariably been observed to be deposited fast on zinc oxide and to manifest sensitizing activity.
- a sensitive layer with good gradation reproducibility can be produced by using the colored zinc oxide of this invention alone.
- the colored zinc oxide to be obtained as mentioned above in combination with untreated zinc oxide, there can be obtained a sensitive layer having still better gradation reproducibility of low contrast.
- the colored zinc oxide is mixed at a ratio of 0.1 5 parts by weight with 1 part by weight of untreated zinc oxide. 1
- EXAMPLE I In a glass beaker, 10 g. I of photoconductive zinc oxide (made by Sakai Chemical Co., Ltd.) was placed and stirred with 200 ml. of distilled water added thereto. Then the mixture was subjected to ultrasonic waves at 29 KHz. to afford a water dispersion of sufficiently distributed zinc oxide. To this dispersion was added 5 ml. of 0.1 percent aqueous solution of eosin. Eosin was not appreciably adsorbed out of the aqueous solution onto zinc oxide. When 5 ml. of 1 percent aqueous solution of lead acetate was added to thereto, however, eosin was observed to be adsorbed abruptly onto zinc oxide.
- the resultant paste in peach color was spread on an aluminum plate.
- the dry thickness of the layer was 6.5;4.
- the layer was dried and thereafter allowed to stand for 10 hours in a dark room kept at 40 C.
- the sensitive layer thus obtained was found to acquire an electric potential of 360 V upon negative corona discharge. It was exposed to light projected through an optical wedge and subsequently developed with a liquid developing agent containing therein a positively charged toner.
- the value -y" indicating gradation was 1.1.
- Test of spectroscopic sensitivity showed that the sensitive layerhad been sensitized in the spectrum range of EXAMPLEZ By using 2.5 g. of the zinc oxide in peach color obtained in Example 1 and 7.5 g. of untreated zinc oxide and following the procedure of Example 1, there was prepared a sensitive layer.
- the value y indicating the gradation of this sensitive layer was 0.7.
- EXAMPLE 3 A sensitive layer was prepared by following the procedure of Example 1, except lead nitrate was used in the place of lead acetate. The layer gave virtually the same results.
- a process for manufacturing an electrophotographic sensitive layer which comprises adding a lead compound soluble in water and capable of generating lead ions upon dissolution in water and a water-soluble sensitizing dye having a carboxyl group to a slurry prepared by dispersing a finely divided photoconductive zinc oxide in water thereby allowing the said dye to be deposited fast on the surface of zinc oxide so as to give rise to a colored zinc oxide powder, washing the said powder with water, subsequently blending the colored powder with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface.
- said dye is Eosine, Eriochrome cyanine R, Chromazural S, Alizarin violet, Phloxine, Fluorescein, Chrome pure blue, Chrome brilliant violet, Mordant brilliant red B, Chrome yellow 66, Chrome yellow M or Mordant blue 47.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
A process for manufacturing an electrophotographic sensitive layer which comprises adding a lead compound soluble in water and capable of generating lead ions upon dissolution in water and a water-soluble, sensitizing dye having a carboxyl group to a slurry prepared by dispersing a finely divided photoconductive zinc oxide in water thereby allowing the dye to be deposited fast on the surface of the zinc oxide so as to give rise to a colored zinc oxide powder, washing the powder with water, subsequently blending the colored powder which may be optionally mixed with untreated zinc oxide powder with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface.
Description
O United States Patent [151 3,661,572 Tamai et al. 1 May 9, 1972 [54] MANUFACTURING PROCESS FOR 1 References Cited MANUFACTURING UNITED STATES PATENTS ELECTROPHOTOGRAPHIC SENSITIVE 3,123,474 3/1964 Byrne ..96/l08 MATERIAL 3,260,605 7/1966 Sutherns.. .....96/l08 428,45 2 9 9 G ..96 1.7 [72] Inventors: Yasun Tamai; Masaaki Takimoto; Hajime 2 ll 6 lalmo of Asaka* Japan Primary E.\'aminerGeorge F. Lesmes 731 Assignee: Fuji Photo Film c6., 1211., Kanagawa, Amman winenberg Japan Attorney-Addams & Ferguson [22] Filed: July 31, 1970 [57] ABSTRACT [21 Appl. No.: 60,118 A process for manufacturing an electrophotographic sensitive layer which comprises adding a lead compound soluble in water and capable of generating lead ions upon dissolution in [30] Fore'gn Apphcatmn Pnomy Data water and a water-soluble, sensitizing dye having a carboxyl Aug. 4, 1969 Japan ..44/6l018 group to a Slurry P p y dispersing finely divided photoconductive zinc oxide in water thereby allowing the dye 52 us. c1 ..96/1.7,96/l.5,96/1.8, to be deposited fast the swim of the Zinc Oxide as to 252/501 give rise to a colored zinc oxide powder, washing the powder [5 1 Int CL Gosg 5/00 603g 7/00 with water, subsequently blending the colored powder which [58] l1 5 1 6 1 8 may be optionally mixed with untreated zinc oxide powder 5 with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface.
7 Claims, No Drawings MANUFACTURING PROCESS FOR MANUFACTURING ELECTROPHOTOGRAPHIC SENSITIVE MATERIAL This invention relates to a novel electrophotographic sensitive layer. In obtaining a print by the electrofax process from the original of a color slide produced by using a silver halide photographic film, for example, the electrophotographic sensitive layer is required to have, as its property, photosensitivity over the whole visible range and gradation reproducibility of low contrast. The photosensitivity extending over the whole visible range is generally conferred upon by causing more than one kind of sensitizing dye to be adsorbed on the photoconductive material. Where zinc oxide is used as the photoconductive material, the resulting gradation reproducibility is generally of high contrast. In the case of a silver halide film, the gradation is accomplished by controlling the particle size distribution of silver halides to be used. In the electrophotographic process which uses a photoconductive material, however, it has been difficult to employ such means of gradation control. To be more specific, while it is possible to control gradation by regulating the distribution of the amount of sensitizing dye to be adsorbed on the photoconductive element, uniform adsorption tends to occur as a consequence of desorption and resorption of sensitizing dye in the course of sensitive layer production, making it difficult to achieve desired results.
Thus, an object of this invention resides in providing a manufacturing process for a zinc oxide insulative resin type electrophotographic sensitive material having excellent gradation reproducibility. Another object of the present invention consists in providing a satisfactory process for depositing a sensitizing dye fast onto zinc oxide particles.
The aforementioned objects of this invention have been accomplished by the discovery of a manufacturing process for an electrophotographic sensitive material, characterized by adding a lead compound soluble in water and capable of generating lead ions upon dissolution in water and a water-soluble dye possessed of carboxyl group to a slurry prepared by dispersing a finely divided photoconductive zinc oxide in water thereby allowing the said dye to be deposited fast on the surface of zinc oxide so as to give rise to a colored zinc oxide powder, washing the said powder with water, subsequently blending the colored powder (which may be mixed with untreated zinc oxide powder as occasion demands) with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface. Since the aforementioned colored zinc oxide powder is such that the dye on zinc oxide is deposited with sufficient strength, separation of the deposited dye or re-adsorption to other zinc oxide occurs very seldom even when it is mixed with untreated zinc oxide. Therefore, there can be obtained an electrophotographic sensitive layer having low contrast of gradation reproducibility by mixing the aforementioned colored zinc oxide powder with untreated zinc oxide.
The dye to be used for the present invention contains carboxyl group and is easy to be deposited on zinc oxide. The dye which contains sulfonyl group is generally difficult to be deposited. Further, the lead ion which is utilized for the present invention has been found to have a higher capacity to deposit dye than other heavy metal ions. As compounds which donate such lead on, there are used water-soluble salts of lead nitrate, lead acetate, etc.
In the present invention, the reaction for depositing dye onto zinc oxide is carried out within a water dispersion. To be concrete, this is accomplished by preparing a slurry having zinc oxide sufficiently dispersed in water in advance and then adding into this dispersion of zinc oxide an aqueous solution containing therein a dye solution and lead ion. As a result of this treatment, the dye is insolubilized through combination with lead ion and consequently deposited fast on the surface of zinc oxide. At this time, the water slurry may be heated. The combination of dye and zinc oxide thus obtained is then washed sufficiently with water. This treatment of washing with water is aimed at removing water-soluble ion and therefore is important. In this treatment of washing with water, no removal of dye is observed at all so far as the procedure of this invention is concerned. Generally, a dye adsorbed onto zinc oxide is liable to come off upon washing. In the procedure of the present invention, however, the dye is deposited so fast that virtually no removal of dye occurs.
The colored, finely divided zinc oxide powder thus obtained is mixed with untreated zinc oxide as required and added into an insulative resin. By spreading the resultant mixture in the form of a layer on an electroconductive base, there can be obtained an electrophotographic sensitive material. The zinc oxide to be used for the purpose of this invention is manufactured generally by French process and has photoconductivity. The amount of dye to be used for this invention is in the range of from 0.000 1 to 2 parts by weight based on parts by weight of zinc oxide. In the case of this invention, a dye which is not adsorbed on zinc oxide in water can be used. That is to say, the dye to be used has only to satisfy the requirement that it should be deposited fast onto zinc oxide in the presence of lead ion.
In the following are given concrete examples of dye to be used for the present invention. It should be understood, however, that this invention is not-lirnited thereto.
Eorsin, eriochrome cyanin R (color index 43,820), Chromazurol S (color index 43,825), alizarin violet (color index 45,445), phloxine (color index (acid red 98) 45,405), fluorescein, chrome pure blue (color index 43,830), chrome brilliant violet (color index 43,865), mordant brilliant red B (color index 45,305 chrome yellow GG (color index 14,025), chrome yellow M (color index 14,095 mordant blue 47 (color index 43,855). The dyes have invariably been observed to be deposited fast on zinc oxide and to manifest sensitizing activity. A sensitive layer with good gradation reproducibility can be produced by using the colored zinc oxide of this invention alone. By using the colored zinc oxide to be obtained as mentioned above in combination with untreated zinc oxide, there can be obtained a sensitive layer having still better gradation reproducibility of low contrast. In this case, the colored zinc oxide is mixed at a ratio of 0.1 5 parts by weight with 1 part by weight of untreated zinc oxide. 1
The present invention is described in further detail below by referring to working embodiments thereof.
EXAMPLE I In a glass beaker, 10 g. I of photoconductive zinc oxide (made by Sakai Chemical Co., Ltd.) was placed and stirred with 200 ml. of distilled water added thereto. Then the mixture was subjected to ultrasonic waves at 29 KHz. to afford a water dispersion of sufficiently distributed zinc oxide. To this dispersion was added 5 ml. of 0.1 percent aqueous solution of eosin. Eosin was not appreciably adsorbed out of the aqueous solution onto zinc oxide. When 5 ml. of 1 percent aqueous solution of lead acetate was added to thereto, however, eosin was observed to be adsorbed abruptly onto zinc oxide. When zinc oxide was separated from the mother liquor by means of a centrifugal separator, the mother liquor became substantially colorless and clear, suggesting that eosin had been adsorbed completely onto zinc oxide. The zinc oxide now in peach color was again dispersed in 100 ml. of distilled water. Eosin was not observed to separate from the surface of zinc oxide. Again, zinc oxide was collected. When the zinc oxide in peach color was washed sufficiently with methanol, eosin was not observed to separate into the mother liquor. The zinc oxide was dried and then combined with 2 g. of vinyl chloride-vinyl acetate copolymer and 13 g. of butyl acetate and sufficiently blended in a small ball mill. The resultant paste in peach color was spread on an aluminum plate. The dry thickness of the layer was 6.5;4. The layer was dried and thereafter allowed to stand for 10 hours in a dark room kept at 40 C. The sensitive layer thus obtained was found to acquire an electric potential of 360 V upon negative corona discharge. It was exposed to light projected through an optical wedge and subsequently developed with a liquid developing agent containing therein a positively charged toner. The value -y" indicating gradation was 1.1. Test of spectroscopic sensitivity showed that the sensitive layerhad been sensitized in the spectrum range of EXAMPLEZ By using 2.5 g. of the zinc oxide in peach color obtained in Example 1 and 7.5 g. of untreated zinc oxide and following the procedure of Example 1, there was prepared a sensitive layer. The value y indicating the gradation of this sensitive layer was 0.7.
EXAMPLE 3 EXAMPLE 4 A sensitive layer was prepared by following the procedure of Example 1, except lead nitrate was used in the place of lead acetate. The layer gave virtually the same results.
What is claimed is:
l. A process for manufacturing an electrophotographic sensitive layer which comprises adding a lead compound soluble in water and capable of generating lead ions upon dissolution in water and a water-soluble sensitizing dye having a carboxyl group to a slurry prepared by dispersing a finely divided photoconductive zinc oxide in water thereby allowing the said dye to be deposited fast on the surface of zinc oxide so as to give rise to a colored zinc oxide powder, washing the said powder with water, subsequently blending the colored powder with an insulative resin, and spreading the resultant mixture in the form of a layer on a base having an electroconductive surface.
2. The process as claimed in claim 1 wherein the lead compound is lead acetate or lead nitrate.
3. The process as claimed in claim 1 wherein the amount of the dye to be used is in the range of from 0.0001 to 2 parts by weight based on parts by weight of zinc oxide.
4. The process as claimed in claim 1 wherein the amount of the lead compound to be used is in the range of from 0.0005 to 5 parts by weight based on 100 parts by weight of zinc oxide.
5. The electrophotographic sensitive layer manufactured by the process as claimed in claim 1.
6. The process as claimed in claim 1 wherein said dye is Eosine, Eriochrome cyanine R, Chromazural S, Alizarin violet, Phloxine, Fluorescein, Chrome pure blue, Chrome brilliant violet, Mordant brilliant red B, Chrome yellow 66, Chrome yellow M or Mordant blue 47.
7. A process as in claim 1 where said colored zinc oxide powder is mixed with untreated zinc oxide powder.
Claims (6)
- 2. The process as claimed in claim 1 wherein the lead compound is lead acetate or lead nitrate.
- 3. The procesS as claimed in claim 1 wherein the amount of the dye to be used is in the range of from 0.0001 to 2 parts by weight based on 100 parts by weight of zinc oxide.
- 4. The process as claimed in claim 1 wherein the amount of the lead compound to be used is in the range of from 0.0005 to 5 parts by weight based on 100 parts by weight of zinc oxide.
- 5. The electrophotographic sensitive layer manufactured by the process as claimed in claim 1.
- 6. The process as claimed in claim 1 wherein said dye is Eosine, Eriochrome cyanine R, Chromazural S, Alizarin violet, Phloxine, Fluorescein, Chrome pure blue, Chrome brilliant violet, Mordant brilliant red B, Chrome yellow GG, Chrome yellow M or Mordant blue 47.
- 7. A process as in claim 1 where said colored zinc oxide powder is mixed with untreated zinc oxide powder.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP44061018A JPS51452B1 (en) | 1969-08-04 | 1969-08-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3661572A true US3661572A (en) | 1972-05-09 |
Family
ID=13159145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US60118A Expired - Lifetime US3661572A (en) | 1969-08-04 | 1970-07-31 | Manufacturing process for manufacturing electrophotographic sensitive material |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3661572A (en) |
| JP (1) | JPS51452B1 (en) |
| BE (1) | BE754323A (en) |
| DE (1) | DE2038762B2 (en) |
| FR (1) | FR2056500A5 (en) |
| GB (1) | GB1305298A (en) |
| NL (1) | NL7011489A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5573879A (en) | 1991-05-02 | 1996-11-12 | Fuji Photo Film Co., Ltd. | Electrophotographic light-sensitive material |
| CN109799197B (en) * | 2017-11-17 | 2021-06-25 | 中国科学院化学研究所 | Use of cyanine dyes in the detection of lead ions, lead ion detection kit and method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3123474A (en) * | 1958-05-26 | 1964-03-03 | byrne | |
| US3260605A (en) * | 1962-01-05 | 1966-07-12 | Eastman Kodak Co | Method for preparing light-sensitive silver halide emulsions suitable for print-out recording materials |
| US3428452A (en) * | 1965-01-18 | 1969-02-18 | Rca Corp | Photoconductive compositions and electrophotographic recording elements made therefrom |
-
0
- BE BE754323D patent/BE754323A/en unknown
-
1969
- 1969-08-04 JP JP44061018A patent/JPS51452B1/ja active Pending
-
1970
- 1970-07-31 US US60118A patent/US3661572A/en not_active Expired - Lifetime
- 1970-08-03 GB GB3741770A patent/GB1305298A/en not_active Expired
- 1970-08-03 FR FR7028557A patent/FR2056500A5/fr not_active Expired
- 1970-08-04 DE DE2038762A patent/DE2038762B2/en active Granted
- 1970-08-04 NL NL7011489A patent/NL7011489A/xx unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3123474A (en) * | 1958-05-26 | 1964-03-03 | byrne | |
| US3260605A (en) * | 1962-01-05 | 1966-07-12 | Eastman Kodak Co | Method for preparing light-sensitive silver halide emulsions suitable for print-out recording materials |
| US3428452A (en) * | 1965-01-18 | 1969-02-18 | Rca Corp | Photoconductive compositions and electrophotographic recording elements made therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2038762C3 (en) | 1974-10-31 |
| JPS51452B1 (en) | 1976-01-08 |
| NL7011489A (en) | 1971-02-08 |
| GB1305298A (en) | 1973-01-31 |
| BE754323A (en) | 1971-01-18 |
| FR2056500A5 (en) | 1971-05-14 |
| DE2038762A1 (en) | 1971-10-28 |
| DE2038762B2 (en) | 1974-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3189447A (en) | Electrophotographic material and method | |
| US3052540A (en) | Dye sensitization of electrophotographic materials | |
| US3197307A (en) | Surface modification of zinc oxide and electrophotographic member therefrom | |
| GB2084605A (en) | Phthalocyanine pigments | |
| US3212887A (en) | Laterally disposed coterminously adjacent multicolor area containing graphic reproduction receptor and electrophotographic process of using same | |
| US2987395A (en) | Electrophotographic printing element | |
| US3661572A (en) | Manufacturing process for manufacturing electrophotographic sensitive material | |
| US3163530A (en) | Material for electrophotographic purposes | |
| US3654865A (en) | Method for forming dye image using an electrophotographic developer containing a gelatin toner | |
| GB1603277A (en) | Electrophotographic materials | |
| US3642470A (en) | Method of improving the color tone of a recording layer containing photoconductive lead (ii) oxide | |
| US3625747A (en) | Photoconductive powders and a method for producing the same | |
| US3460963A (en) | Process for the manufacture of an electrophotographic material | |
| US4160666A (en) | Polymeric chemical sensitizers for organic photoconductive compositions | |
| US3682825A (en) | Process for the production of electrophotographic liquid developer containing gelatin | |
| US3681067A (en) | Cds-chalcogen ternary compound mixture as photoconductive material in an electrophotographic member | |
| US3345161A (en) | Photoconductive material and process for its preparation | |
| US3806339A (en) | Liquid developer composition | |
| US3541028A (en) | Photoconductive insulating materials | |
| US3864125A (en) | Electrophotographic method of making an imaging master | |
| US3692522A (en) | Electrophotographic material of zinc oxide treated with guanazole | |
| US3677766A (en) | Method of forming gelatin image | |
| US3247081A (en) | Electrolytic deposition of charged dyes for photoconductographic processes | |
| US3454415A (en) | Process for the manufacture of an electrophotographic material | |
| JPH0231379B2 (en) |